JPH05345976A - Cutting tool made of surface coated titanium carbonitride-based cermet excellent in chipping resistance - Google Patents

Cutting tool made of surface coated titanium carbonitride-based cermet excellent in chipping resistance

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Publication number
JPH05345976A
JPH05345976A JP17749892A JP17749892A JPH05345976A JP H05345976 A JPH05345976 A JP H05345976A JP 17749892 A JP17749892 A JP 17749892A JP 17749892 A JP17749892 A JP 17749892A JP H05345976 A JPH05345976 A JP H05345976A
Authority
JP
Japan
Prior art keywords
cutting tool
based cermet
average
cutting
coated
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP17749892A
Other languages
Japanese (ja)
Other versions
JP3136778B2 (en
Inventor
Jiro Kotani
二郎 小谷
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Mitsubishi Materials Corp
Original Assignee
Mitsubishi Materials Corp
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Filing date
Publication date
Application filed by Mitsubishi Materials Corp filed Critical Mitsubishi Materials Corp
Priority to JP04177498A priority Critical patent/JP3136778B2/en
Publication of JPH05345976A publication Critical patent/JPH05345976A/en
Application granted granted Critical
Publication of JP3136778B2 publication Critical patent/JP3136778B2/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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  • Cutting Tools, Boring Holders, And Turrets (AREA)
  • Chemical Vapour Deposition (AREA)
  • Other Surface Treatments For Metallic Materials (AREA)

Abstract

PURPOSE:To improve the chipping resistance of a cermet cutting tool by specifying the structures and layer thickness of hard coated multiple layers formed on the surface of a cermet substrate. CONSTITUTION:Coated layers formed on the surface of a TiC.N-based cermet substrate are formed of hard layers in which the average layer thickness is regulated to 2 to 20mum, and they are constituted of multiple layers of >= two kinds among the borides, carbides, nitrides and oxides of Ti, Al, Zr and Hf as well as the solid solution of >= two kinds of them. Then, it is constituted of an inside layer group with 0.5 to 5mum average layer thickness having a superfine-grained structure of <=0.05mum average grain size and an outside layer group having a granular structure of 0.1 to 5mum average grain size. In this way, the chipping resistance of the cutting tool made of the surface coated TiC.N base cermet can be improved.

Description

【発明の詳細な説明】Detailed Description of the Invention

【0001】[0001]

【産業上の利用分野】この発明は、例えば鋼の高速切削
などの苛酷な条件での切削ですぐれた耐チッピング性
(耐微小欠け性)を示す表面被覆炭窒化チタン(以下、
TiCNで示す)基サーメット製切削工具に関するもの
である。
BACKGROUND OF THE INVENTION The present invention relates to a surface-coated titanium carbonitride (hereinafter, referred to as "titanium carbonitride", which exhibits excellent chipping resistance (fine chipping resistance) in cutting under severe conditions such as high-speed cutting of steel.
(Denoted by TiCN) based cermet cutting tool.

【0002】[0002]

【従来の技術】従来、例えば特開昭56−62960号
公報に記載されるように、TiCN基サーメット基体の
表面に、化学蒸着法を用いて、Ti,Al,Zr、およ
びHfのほう化物、炭化物、窒化物、および酸化物、並
びにこれらの2種以上の固溶体のうちの2種以上の複層
からなる硬質被覆層を2〜20μmの平均層厚で形成し
てなる表面被覆TiCN基サーメット製切削工具が、例
えば鋼の切削に用いられていることは良く知られるとこ
ろである。
2. Description of the Related Art Conventionally, as described in, for example, Japanese Patent Application Laid-Open No. 56-62960, a boride of Ti, Al, Zr, and Hf is formed on the surface of a TiCN-based cermet substrate by chemical vapor deposition. Made of a surface-coated TiCN-based cermet, which is formed by forming a hard coating layer made of a carbide, a nitride, an oxide, and a multilayer of two or more of these two or more solid solutions with an average layer thickness of 2 to 20 μm. It is well known that cutting tools are used for cutting steel, for example.

【0003】[0003]

【発明が解決しようとする課題】一方、近年の切削機械
の高性能化および高速化はめざましく、これに伴ない、
これに用いられている切削工具にも苛酷な条件での切削
が余儀なくされる傾向にあるが、上記の従来表面被覆T
iCN基サーメット製切削工具を、例えば切削速度が5
00m/min.の高速で鋼を切削するのに用いた場合、切
刃にチッピング(微小欠け)が発生し易く、このチッピ
ングが原因できわめて短時間で使用寿命に至ることか
ら、鋼の高速切削に用いることができないのが現状であ
る。
On the other hand, in recent years, cutting machines have been remarkably improved in performance and speed, and accordingly,
The cutting tools used for this also tend to be forced to cut under severe conditions.
A cutting tool made of iCN-based cermet, for example, with a cutting speed of 5
When used to cut steel at a high speed of 00 m / min., Chipping (fine chipping) is likely to occur on the cutting edge, and this chipping leads to an extremely short service life, so high-speed cutting of steel The current situation is that it cannot be used for.

【0004】[0004]

【課題を解決するための手段】そこで、本発明者等は、
上述のような観点から、上記の従来表面被覆TiCN基
サーメット製切削工具に着目し、これの耐チッピング性
向上をはかるべく研究を行なった結果、従来の表面被覆
TiCN基サーメット製切削工具を構成する硬質被覆層
は、いずれも0.1〜5μmの平均粒径を有する粒状組
織からなるが、これの内側部分を、特に物理蒸着法を用
いて形成した、平均粒径:0.05μm以下の超微粒組
織を有する硬質被覆層で構成すると、この結果の表面被
覆TiCN基サーメット製切削工具は、切削速度が50
0m/min.以上の高速で鋼を切削しても、前記超微粒組
織を有する硬質被覆層の介在によって切刃にチッピング
が発生することがなく、長期に亘ってすぐれた耐摩耗性
を発揮するようになるという研究結果を得たのである。
Therefore, the present inventors have
From the above viewpoints, focusing on the above-mentioned conventional surface-coated TiCN-based cermet cutting tool, and conducting research to improve the chipping resistance thereof, a conventional surface-coated TiCN-based cermet cutting tool is constructed. Each of the hard coating layers is composed of a granular structure having an average particle size of 0.1 to 5 μm, and the inner part of the hard coating layer is formed by using a physical vapor deposition method, and the average particle size is more than 0.05 μm. When the hard coating layer having a fine grain structure is used, the resulting surface-coated TiCN-based cermet cutting tool has a cutting speed of 50.
Even if steel is cut at a high speed of 0 m / min. Or more, chipping does not occur in the cutting edge due to the inclusion of the hard coating layer having the ultrafine grain structure, and excellent wear resistance is exhibited for a long period of time. The result of the research was that

【0005】この発明は、上記の研究結果にもとづいて
なされたものであって、TiCN基サーメット基体の表
面に、Ti,Al,Zr、およびHfのほう化物、炭化
物、窒化物、および酸化物、並びにこれらの2種以上の
固溶体のうちの2種以上の複層からなる硬質被覆層を2
〜20μmの平均層厚で形成してなる表面被覆TiCN
基サーメット製切削工具において、上記硬質被覆層を、
1層または2層以上からなる内側層グループと、同じく
1層または2層以上からなる外側層グループに分け、上
記内側層グループを、平均粒径:0.05μm以下の超
微粒組織を有する平均層厚:0.5〜5μmの硬質被覆
層で構成し、一方、上記外側層グループを、平均粒径:
0.1〜5μmの粒状組織を有する硬質被覆層で構成し
てなる、耐チッピング性にすぐれた表面被覆TiCN基
サーメット製切削工具に特徴を有するものである。
The present invention has been made based on the above-mentioned research results, and boride, carbide, nitride, and oxide of Ti, Al, Zr, and Hf are formed on the surface of a TiCN-based cermet substrate. And a hard coating layer composed of two or more layers of these two or more solid solutions.
Surface-coated TiCN formed with an average layer thickness of ˜20 μm
In the base cermet cutting tool, the hard coating layer,
An inner layer group consisting of one layer or two or more layers, and an outer layer group consisting of one layer or two or more layers, and the inner layer group is an average layer having an ultrafine grain structure with an average grain size of 0.05 μm or less. Thickness: 0.5-5 μm of hard coating layer, while the outer layer group has an average particle size:
It is characterized by a surface-coated TiCN-based cermet cutting tool having excellent chipping resistance, which is composed of a hard coating layer having a granular structure of 0.1 to 5 μm.

【0006】つぎに、この発明の表面被覆TiCN基サ
ーメット製切削工具において、これを構成する硬質被覆
層に関し、平均層厚および平均粒径を上記の通りに限定
した理由を説明する。
Next, in the surface-coated TiCN-based cermet cutting tool of the present invention, the reason for limiting the average layer thickness and the average grain size of the hard coating layer constituting the cutting tool will be described.

【0007】(a) 硬質被覆層の平均層厚 その平均層厚が2μm未満では所望のすぐれた耐摩耗性
を確保することができず、一方その平均層厚が20μm
を越えると、切刃に欠けやチッピングが発生し易くなる
ことから、その平均層厚を2〜20μmと定めた。
(A) Average layer thickness of hard coating layer If the average layer thickness is less than 2 μm, desired excellent wear resistance cannot be secured, while the average layer thickness is 20 μm.
If it exceeds, the cutting edge is likely to be chipped or chipped, so that the average layer thickness is set to 2 to 20 μm.

【0008】(b) 内側層グループの平均層厚 その平均層厚が0.5μm未満では、所望のすぐれた耐
チッピング性を確保することができず、一方その平均層
厚が5μmを越えると、外側層グループの層厚が相対的
に薄くなり、これによってもたらされるすぐれた耐摩耗
性を確保することができなくなることから、その平均層
厚を0.5〜5μmと定めた。
(B) Average Layer Thickness of Inner Layer Group If the average layer thickness is less than 0.5 μm, desired excellent chipping resistance cannot be secured, while if the average layer thickness exceeds 5 μm, Since the layer thickness of the outer layer group becomes relatively thin and it is not possible to secure the excellent wear resistance brought about by this, the average layer thickness was set to 0.5 to 5 μm.

【0009】(b) 内側層グループの平均粒径 これの粒径が、平均粒径で0.05μmを越えて大きく
なると、耐チッピング性が急激に低下するようになるこ
とから、その平均粒径を0.05μm以下に定めた。
(B) Average particle size of the inner layer group If the average particle size is larger than 0.05 μm, the chipping resistance will be sharply reduced. Was set to 0.05 μm or less.

【0010】(c) 外側層グループの平均粒径 その平均粒径が0.1μm未満になると耐摩耗性が低下
するようになり、一方その平均粒径が5μmを越えると
硬質被覆層自体の強度が低下するようになり、チッピン
グが発生し易くなることから、その平均粒径を0.1〜
5μmと定めた。
(C) Average particle size of the outer layer group If the average particle size is less than 0.1 μm, the wear resistance becomes poor, while if the average particle size exceeds 5 μm, the strength of the hard coating layer itself. Is decreased and chipping is likely to occur.
It was set to 5 μm.

【0011】[0011]

【実施例】この発明の表面被覆TiCN基サーメット製
切削工具を実施例により具体的に説明する。まず、いず
れも1〜2.5μmの範囲内の平均粒径を有し、かつ表
1に示される各種組成の原料粉末を用意し、これら原料
粉末を同じく表1に示される配合組成に配合し、ボール
ミルで72時間湿式混合し、乾燥した後、圧粉体にプレ
ス成形し、この圧粉体を、10torrの窒素ガス雰囲気
中、温度:1500℃に1時間保持の条件で焼結するこ
とによりISO・CNMG120408のスローアウェ
イチップ形状をもったTiCN基サーメット基体(以
下、サーメット基体という)A〜Dを製造した。
EXAMPLES The surface-coated TiCN-based cermet cutting tool of the present invention will be specifically described by way of examples. First of all, raw material powders having an average particle diameter within the range of 1 to 2.5 μm and having various compositions shown in Table 1 were prepared, and these raw material powders were blended into the blending composition also shown in Table 1. By wet-mixing in a ball mill for 72 hours, drying and press forming into a green compact, and sintering the green compact in a nitrogen gas atmosphere of 10 torr at a temperature of 1500 ° C. for 1 hour. TiCN-based cermet substrates (hereinafter referred to as cermet substrates) A to D having the throwaway chip shape of ISO / CNMG120408 were manufactured.

【0012】ついで、上記サーメット基体A〜Dのそれ
ぞれの表面に、まず物理蒸着法を用い、表2,3に示さ
れる組成、平均層厚、および平均粒径を有する1層また
は2層以上の硬質被覆層からなる内側層グループを、表
4に示される条件(バイアス電圧:−100v)で形成
し、引続いて化学蒸着法にて、同じく表2,3に示され
る組成、平均層厚、および平均粒径を有する1層または
2層以上の硬質被覆層からなる外側層グループを表5に
示される条件で形成することにより本発明表面被覆Ti
CN基サーメット製切削工具(以下、本発明被覆切削工
具という)1〜8をそれぞれ製造した。
Then, on each surface of the cermet substrates A to D, first, using physical vapor deposition, one or more layers having the compositions, average layer thicknesses and average particle diameters shown in Tables 2 and 3 were formed. An inner layer group consisting of a hard coating layer was formed under the conditions shown in Table 4 (bias voltage: -100 v), and subsequently, by chemical vapor deposition, the composition, average layer thickness, and the like shown in Tables 2 and 3, And the surface-coated Ti of the present invention by forming an outer layer group consisting of one or more hard coating layers having an average particle size under the conditions shown in Table 5.
CN-based cermet cutting tools (hereinafter referred to as the present invention coated cutting tools) 1 to 8 were manufactured.

【0013】また、比較の目的で、化学蒸着法を用い、
表6,7に示される組成、平均層厚、および平均層厚を
有する1層または2層以上の硬質被覆層を表5に示され
る条件で形成する以外は同一の条件で従来表面被覆Ti
CN基サーメット製切削工具(以下、従来被覆切削工具
という)1〜8をそれぞれ製造した。
For the purpose of comparison, a chemical vapor deposition method is used,
Conventional surface-coated Ti under the same conditions, except that the compositions, average layer thicknesses, and one or more hard coating layers having the average layer thicknesses shown in Tables 6 and 7 are formed under the conditions shown in Table 5.
CN-based cermet cutting tools (hereinafter referred to as conventional coated cutting tools) 1 to 8 were manufactured.

【0014】つぎに、この結果得られた各種の被覆切削
工具について、 被削材:JIS・SCM440の丸棒、 切削速度:300m/min.、 切込み:1mm、 送り:0.2mm/rev.、 切削時間:30分、 の条件での鋼の連続切削試験、並びに、 被削材:JIS・SCM440の4本縦溝入り丸棒、 切削速度:500m/min.、 切込み:0.5mm、 送り:0.1mm/rev.、 切削時間:5分、 の条件での鋼の断続高速切削試験を行ない、逃げ面摩耗
幅を測定した。これらの測定結果を表8に示した。
Next, regarding the various coated cutting tools obtained as a result, the work material: round bar of JIS SCM440, cutting speed: 300 m / min., Depth of cut: 1 mm, feed: 0.2 mm / rev., Cutting time: 30 minutes, continuous cutting test of steel under the conditions, Work material: JIS SCM440 4 round bar with vertical groove, Cutting speed: 500 m / min., Depth of cut: 0.5 mm, Feed: An intermittent high-speed cutting test of steel was performed under the conditions of 0.1 mm / rev., Cutting time: 5 minutes, and the flank wear width was measured. The results of these measurements are shown in Table 8.

【0015】[0015]

【表1】 [Table 1]

【0016】[0016]

【表2】 [Table 2]

【0017】[0017]

【表3】 [Table 3]

【0018】[0018]

【表4】 [Table 4]

【0019】[0019]

【表5】 [Table 5]

【0020】[0020]

【表6】 [Table 6]

【0021】[0021]

【表7】 [Table 7]

【0022】[0022]

【表8】 [Table 8]

【0023】[0023]

【発明の効果】表8には、本発明被覆切削工具1〜8お
よび従来被覆切削工具1〜8とも、鋼の通常の切削速度
である300m/min.の切削速度では切刃にチッピング
の発生なく、しかし前者の方が後者に比してすぐれた耐
摩耗性を示すことが示されており、しかしながら切削速
度が500m/min.の鋼の断続高速切削では、本発明被
覆切削工具1〜8はいずれも切刃にチッピングの発生な
く、すぐれた耐摩耗性を発揮するのに対して、従来被覆
切削工具1〜8では、いずれも切刃にチッピングが発生
し、短時間で使用寿命に至ることが示されている。
Table 8 shows that both the coated cutting tools 1 to 8 of the present invention and the conventional coated cutting tools 1 to 8 are chipped at the cutting edge at a cutting speed of 300 m / min. However, the former has been shown to exhibit better wear resistance than the latter, however, in intermittent high speed cutting of steel with a cutting speed of 500 m / min. While all of them show excellent wear resistance without chipping on the cutting edge, all of the conventional coated cutting tools 1-8 chip on the cutting edge and reach the end of their useful life in a short time. Has been shown.

【0024】上述のように、この発明の表面被覆TiC
N基サーメット製切削工具は、すぐれた耐チッピング性
を有するので、例えば切削速度が500m/min.以上の
鋼の高速切削などの苛酷な条件下での切削においても切
刃にチッピングの発生なく、すぐれた切削性能を著しく
長期に亘って発揮するのである。
As mentioned above, the surface coated TiC of the present invention.
Since the N-based cermet cutting tool has excellent chipping resistance, chipping does not occur in the cutting edge even under severe conditions such as high-speed cutting of steel with a cutting speed of 500 m / min. It excels in cutting performance over a long period of time.

Claims (1)

【特許請求の範囲】[Claims] 【請求項1】 炭窒化チタン基サーメット基体の表面
に、Ti,Al,Zr、およびHfのほう化物、炭化
物、窒化物、おび酸化物、並びにこれらの2種以上の固
溶体のうちの2種以上の複層からなる硬質被覆層を2〜
20μmの平均層厚で形成してなる表面被覆炭窒化チタ
ン基サーメット製切削工具において、 上記硬質被覆層を、1層または2層以上からなる内側層
グループと、同じく1層または2層以上からなる外側層
グループに分け、 上記内側層グループを平均粒径:0.05μm以下の超
微粒組織を有する平均層厚:0.5〜5μmの硬質被覆
層で構成し、 一方上記外側層グループを平均粒径:0.1〜5μmの
粒状組織を有する硬質被覆層で構成したことを特徴とす
る耐チッピング性にすぐれた表面被覆炭窒化チタン基サ
ーメット製切削工具。
1. A titanium carbonitride-based cermet substrate having two or more of Ti, Al, Zr, and Hf borides, carbides, nitrides, and oxides, and two or more of these solid solutions on the surface thereof. 2 to 2 hard coating layers consisting of
A surface-coated titanium carbonitride-based cermet cutting tool formed with an average layer thickness of 20 μm, wherein the hard coating layer comprises an inner layer group consisting of one or more layers, and also one layer or two or more layers. The outer layer group is divided into outer layer groups, and the inner layer group is composed of a hard coating layer having an average particle diameter of 0.5 μm or less and an average layer thickness of 0.5 to 5 μm. Diameter: a surface-coated titanium carbonitride-based cermet cutting tool having excellent chipping resistance, characterized by comprising a hard coating layer having a granular structure of 0.1 to 5 μm.
JP04177498A 1992-06-11 1992-06-11 Surface coated titanium carbonitride based cermet cutting tool with excellent chipping resistance Expired - Lifetime JP3136778B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP04177498A JP3136778B2 (en) 1992-06-11 1992-06-11 Surface coated titanium carbonitride based cermet cutting tool with excellent chipping resistance

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP04177498A JP3136778B2 (en) 1992-06-11 1992-06-11 Surface coated titanium carbonitride based cermet cutting tool with excellent chipping resistance

Publications (2)

Publication Number Publication Date
JPH05345976A true JPH05345976A (en) 1993-12-27
JP3136778B2 JP3136778B2 (en) 2001-02-19

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Cited By (16)

* Cited by examiner, † Cited by third party
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US5972495A (en) * 1996-07-03 1999-10-26 Hitachi Metals, Ltd. Alumina coated tool and production method thereof
US6472060B1 (en) * 2000-01-19 2002-10-29 Seco Tools Ab Coated body with nanocrystalline CVD coating for enhanced edge toughness and reduced friction
DE19752644C2 (en) * 1996-11-29 2003-06-26 Hitachi Metals Ltd Tool coated with alumina and manufacturing process therefor
EP1471166A2 (en) * 2003-04-24 2004-10-27 Seco Tools Ab Layer with controlled grain size and morphology for enhanced wear resistance
EP1471165A2 (en) * 2003-04-24 2004-10-27 Seco Tools Ab Coating with controlled grain size and morphology for enhanced wear resistance and toughness
JP2008296290A (en) * 2007-05-29 2008-12-11 Kyocera Corp Surface coated cutting tool
US20110159279A1 (en) * 2008-08-29 2011-06-30 Showa Denko K.K. Surface-covered cermet member and method for manufacturing same
JP2011218542A (en) * 2010-03-23 2011-11-04 Mitsubishi Materials Corp Surface-coated cutting tool having hard coating layer exhibiting superior chipping resistance
JP2011218543A (en) * 2009-12-25 2011-11-04 Mitsubishi Materials Corp Surface-coated cutting tool having hard coating layer exhibiting superior chipping resistance
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US20110159279A1 (en) * 2008-08-29 2011-06-30 Showa Denko K.K. Surface-covered cermet member and method for manufacturing same
JP2011218543A (en) * 2009-12-25 2011-11-04 Mitsubishi Materials Corp Surface-coated cutting tool having hard coating layer exhibiting superior chipping resistance
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JP2014166672A (en) * 2013-01-31 2014-09-11 Mitsubishi Materials Corp Surface-clad cutting tool and method for production thereof
US9752230B2 (en) 2013-12-23 2017-09-05 Korloy Inc. Alpha alumina thin film for processing difficult-to-cut material and cast iron
DE112014005858B4 (en) 2013-12-23 2021-08-05 Korloy Inc. Alpha aluminum oxide thin film for machining difficult-to-cut material and cast iron
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