JPH05331484A - Machining oil for metal - Google Patents
Machining oil for metalInfo
- Publication number
- JPH05331484A JPH05331484A JP16680592A JP16680592A JPH05331484A JP H05331484 A JPH05331484 A JP H05331484A JP 16680592 A JP16680592 A JP 16680592A JP 16680592 A JP16680592 A JP 16680592A JP H05331484 A JPH05331484 A JP H05331484A
- Authority
- JP
- Japan
- Prior art keywords
- oil
- machining
- processing
- heating
- metal
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Landscapes
- Lubricants (AREA)
Abstract
Description
【０００１】[0001]
【産業上の利用分野】この発明は、鉄、アルミニウム等
の種々の金属について行われる種々の金属加工、例えば
プレス加工、コルゲート／ルーバー加工、ロールフォー
ム加工等の際に、被加工品の加工性を良好ならしめると
共に、工具の摩耗を防止する目的で使用される加工油に
関する。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to the workability of a work piece in various metal workings performed on various metals such as iron and aluminum, for example, press working, corrugate / louver working, roll forming and the like. And a working oil used for the purpose of preventing wear of the tool.
【０００２】従来、この種の金属加工においては、一般
には機械加工油が使用されているが、この機械加工油
は、鉱物油、植物油、動物油等を基油とし、これに各種
の添加剤を配合して構成されていて揮発性がなく、加工
後には得られた製品についてこの機械加工油を除去する
ための洗浄が必要になり、この洗浄作業が極めて面倒な
作業であったほか、環境汚染の防止の観点から洗浄廃液
の処理が必要になり、この洗浄廃液処理にも多大な費用
を必要とするという問題があった。Conventionally, in this type of metal working, a machining oil is generally used. The machining oil is a mineral oil, a vegetable oil, an animal oil or the like as a base oil, to which various additives are added. The product, which is composed by blending it and has no volatility, requires cleaning to remove the machining oil from the product obtained after processing, and this cleaning work was extremely troublesome and also caused environmental pollution. There is a problem that the cleaning waste liquid needs to be treated from the viewpoint of preventing the above, and that the cleaning waste liquid treatment also requires a great deal of expense.
【０００３】[0003]
【発明が解決しようとする課題】そこで、本発明者ら
は、このような問題のない加工油剤の開発について鋭意
研究を重ねた結果、基油として所定の粘度のポリブテン
類を使用し、これに所定の油性向上剤を一定の割合で添
加したものが、加工油として優れた性能を有するだけで
なく、加工終了後に被加工品を所定の温度に加熱するこ
とにより容易に揮発し、被加工品から除去できることを
見出し、本発明を完成した。Therefore, as a result of intensive studies on the development of a processing oil which does not have such a problem, the present inventors have used polybutenes having a predetermined viscosity as a base oil, and Not only does a certain amount of a specified oiliness improver add as a processing oil, it also volatilizes easily by heating the processed product to a specified temperature after processing, and the processed product The present invention has been completed by finding that it can be removed from
【０００４】従って、本発明の目的は、加工中には加工
油として優れた性能を発揮するだけでなく、加工終了後
には被加工品を所定の温度に加熱することにより容易に
加工油を被加工品から除去できる新規な金属の加工油剤
を提供することにある。Therefore, an object of the present invention is not only to exhibit excellent performance as a processing oil during processing, but also to easily process the processing oil by heating the workpiece to a predetermined temperature after the processing is completed. It is to provide a novel metal processing oil agent that can be removed from a processed product.
【０００５】[0005]
【課題を解決するための手段】すなわち、本発明は、粘
度１．０〜１０．０センチストークス（ｃＳｔ）のポリ
ブテン類からなる基油に、炭素数４〜１８の脂肪酸、脂
肪族アルコール及びエステルから選ばれた１種又は２種
以上の混合物からなる油性向上剤を０．５〜１０重量％
の範囲で添加してなる金属の加工油剤である。That is, according to the present invention, a base oil comprising polybutene having a viscosity of 1.0 to 10.0 centistokes (cSt) is added to a fatty acid having 4 to 18 carbon atoms, an aliphatic alcohol and an ester. 0.5 to 10% by weight of an oiliness improver consisting of one kind or a mixture of two or more kinds selected from
It is a metal processing oil added in the range of.
【０００６】本発明において、基油として使用するポリ
ブテン類としては、ポリブテンの他に、同様な性質を有
する例えばポリブテン−１、ポリイソブチレン等を挙げ
ることができ、これらはその１種のみを単独で使用でき
るほか、２種以上の混合物としても使用することができ
る。このポリブテン類としてはポリブテンが最も好まし
い。このホリブテンは、主としてイソブチレンに少量の
ｎ−ブテンが共重合した構造を有する粘稠な液状重合体
であり、不純物や重金属の含有量が極めて低く、毒性や
刺激性もなく、しかも、そのうちの常温での粘度が１．
０〜１０．０ｃＳｔのものは、２００〜３５０℃に加熱
することにより、容易に揮発し、この際に硬化したり熱
解重合を起こし難いものである。本発明で使用するポリ
ブテン類は、その常温での粘度が１．０〜１０．０ｃＳ
ｔ、好ましくは１．０〜５．０ｃＳｔのものであり、粘
度が１．０ｃＳｔより低いと基油としての耐荷重性能が
不足し、また、引火点が低くなりすぎて引火の危険が生
じ、また、１０．０ｃＳｔを越えると加工後に硬化や熱
解重合を生起させることなく加熱して揮発除去せしめる
ことが困難になり、洗浄剤を使用して洗浄を行う必要が
生じる。In the present invention, as the polybutene used as the base oil, in addition to polybutene, there can be mentioned, for example, polybutene-1, polyisobutylene and the like having similar properties, and only one of them can be used alone. Besides being usable, they can also be used as a mixture of two or more kinds. The polybutenes are most preferably polybutenes. This holybten is a viscous liquid polymer mainly having a structure in which a small amount of n-butene is copolymerized with isobutylene, has a very low content of impurities and heavy metals, is free from toxicity and irritation, and has a normal temperature. Viscosity at 1.
Those having 0 to 10.0 cSt are easily volatilized by heating at 200 to 350 ° C., and are hard to be hardened or thermally depolymerized at this time. The polybutenes used in the present invention have a viscosity at room temperature of 1.0 to 10.0 cS.
t, preferably 1.0 to 5.0 cSt, when the viscosity is lower than 1.0 cSt, the load bearing performance as the base oil is insufficient, and the flash point becomes too low, causing a risk of ignition. Further, if it exceeds 10.0 cSt, it becomes difficult to heat and volatilize and remove it without causing hardening or thermal depolymerization after processing, and it becomes necessary to perform cleaning with a cleaning agent.
【０００７】また、本発明においては、上記基油として
のポリブテン類に脂肪酸、脂肪族アルコール及びエステ
ルから選ばれた１種又は２種以上の混合物からなる油性
向上剤を添加する。この油性向上剤は、基油の不足する
油性、すなわち境界潤滑状態における油膜の強度を改善
し、摩擦係数を低下させて加工中における耐荷重性能を
向上させるものである。本発明で油性向上剤として使用
する脂肪酸、脂肪族アルコール及びエステルは、その炭
素数が４〜１８の範囲のものである必要があり、その種
類によっても異なるが、好ましくは８〜１２の範囲のも
のである。炭素数が４より少ないと油性向上作用が不足
し、また、１８より多くなると加工後に加熱して加工油
を除去する際に残渣が残り、この加熱残渣を除去するた
めに洗浄剤を使用して洗浄を行う必要が生じる。Further, in the present invention, an oiliness improver comprising one kind or a mixture of two or more kinds selected from fatty acids, aliphatic alcohols and esters is added to the polybutenes as the base oil. This oiliness improver improves the oiliness of the base oil, that is, the strength of the oil film in the boundary lubrication state, lowers the friction coefficient, and improves the load bearing performance during processing. The fatty acids, aliphatic alcohols and esters used as the oiliness improver in the present invention are required to have a carbon number in the range of 4-18, and although it varies depending on the type, it is preferably in the range of 8-12. It is a thing. When the carbon number is less than 4, the oiliness improving effect is insufficient, and when it is more than 18, a residue remains when the processing oil is removed by heating after processing, and a cleaning agent is used to remove the heating residue. It becomes necessary to perform washing.
【０００８】このような油性向上剤となる脂肪酸として
は、例えば、カプリン酸、ラウリン酸、オレイン酸等を
挙げることができ、また、脂肪族アルコールとしては、
例えば、オクチルアルコール、デシルアルコール、ラウ
リルアルコール等を挙げることができ、さらに、エステ
ルとしては、例えば、ラウリン酸メチル、ステアリン酸
ブチル等を挙げることができる。この油性加工剤の添加
量は、通常０．５〜１０重量％、好ましくは１．０〜
５．０重量％の範囲であり、０．５重量％より少ないと
期待する油性加工作用が発揮されず、また、１０重量％
より多くなると加工後の加熱時にオイル・スティン等の
残渣が残るという問題が生じる。Examples of the fatty acid which serves as the oiliness improver include capric acid, lauric acid and oleic acid, and the aliphatic alcohol includes
Examples thereof include octyl alcohol, decyl alcohol, lauryl alcohol, and the like, and examples of the ester include methyl laurate, butyl stearate, and the like. The amount of the oily processing agent added is usually 0.5 to 10% by weight, preferably 1.0 to
It is in the range of 5.0% by weight, and if it is less than 0.5% by weight, the expected oiliness processing action is not exhibited, and 10% by weight
If the amount is larger, there arises a problem that residues such as oil and tin remain after heating after processing.
【０００９】本発明においては、金属加工の際における
工具の磨耗を軽減する目的で、必要に応じて極圧添加剤
を添加することができる。この極圧添加剤としては、加
工後に加工油を除去する目的で加熱する際に同時に揮発
して除去されるものであるのがよく、例えば、有機ホス
ファイト、有機ホォスフェート及びリン含有界面活性剤
から選ばれた１種又は２種以上の混合物を使用すること
ができる。具体的には、有機ホスファイトとしては、例
えばジラウリルハイドロジェンフォスファイト、トリオ
レイルフォスファイト等を挙げることができ、有機ホォ
スフェートとしては、例えばラウリルフォスフェート、
オレイルフォスフェート等を挙げることができ、また、
リン含有界面活性剤としては、例えばポリエチレングリ
コールエーテル、リン酸エステル等を挙げることができ
る。このような極圧添加剤を添加する場合における添加
量は通常５重量％以下であり、好ましくは０．０１〜
１．０重量％の範囲である。５重量％を越えて添加する
と加工後に加熱しただけでは完全に揮発させて除去する
ことが困難である。In the present invention, an extreme pressure additive may be added if necessary for the purpose of reducing wear of the tool during metal working. The extreme pressure additive is preferably one that is volatilized and removed at the same time when heated for the purpose of removing the processing oil after processing, for example, from organic phosphite, organic phosphate and phosphorus-containing surfactant. One kind or a mixture of two or more kinds selected can be used. Specifically, examples of the organic phosphite include dilauryl hydrogen phosphite, trioleyl phosphite, and the like, and examples of the organic phosphate include lauryl phosphate,
Examples include oleyl phosphate, and
Examples of the phosphorus-containing surfactant include polyethylene glycol ether and phosphoric acid ester. When such an extreme pressure additive is added, the addition amount is usually 5% by weight or less, preferably 0.01 to
It is in the range of 1.0% by weight. If it is added in excess of 5% by weight, it is difficult to completely volatilize and remove it only by heating after processing.
【００１０】本発明の加工油剤は、上記ポリブテン類か
らなる基油中に所定の量の油性向上剤と必要に応じて添
加される極圧添加剤とを添加し、全体を均一に混合する
ことにより調製される。そして、本発明の加工油剤は、
その常温での粘度が１．０〜１０．０ｃＳｔ、好ましく
は１．０〜５．０ｃＳｔの範囲であるのがよい。そし
て、本発明の加工油剤は、鉄、アルミニウム等の種々の
金属についてのプレス加工、コルゲート／ルーバー加
工、ロールフォーム加工等の金属加工の際に、従来の機
械加工油と全く同様の方法で使用することができる。ま
た、本発明の加工油剤は、金属の冷間加工に限らず、熱
間加工についても適用可能である。また、加工終了後の
被加工品の洗浄については、この被加工品を通常２００
〜３５０℃、好ましくは２００〜３００℃の温度で加熱
し、加工油剤を揮発させることにより容易に脱脂するこ
とができる。The processing oil of the present invention is prepared by adding a predetermined amount of an oiliness improver and an extreme pressure additive, which is added as necessary, to a base oil composed of the above polybutenes and uniformly mixing the whole. Is prepared by. And the processing oil agent of the present invention,
The viscosity at room temperature is 1.0 to 10.0 cSt, preferably 1.0 to 5.0 cSt. The processing oil of the present invention is used in the same manner as conventional machining oils when performing metal working such as press working, corrugate / louver working, and roll form working on various metals such as iron and aluminum. can do. Further, the processing oil of the present invention is applicable not only to cold working of metal but also to hot working. In addition, when cleaning the work piece after processing, the
Degreasing can be easily performed by heating at a temperature of ˜350 ° C., preferably 200 ° C. to 300 ° C., and volatilizing the processing oil.
【００１１】[0011]
【作用】本発明の加工油剤によれば、基油として使用す
るポリブテン類が従来の機械加工油で使用されていた低
粘度鉱物油と同等あるいはそれ以上の潤滑性能を有する
のでこの機械加工油と同様に金属加工の潤滑油として使
用でき、しかも、このポリブテン類は、不純物や重金属
の含有量が極めて低く、毒性や刺激性もなく、また、加
熱することにより硬化や熱解重合を引き起こすことなく
容易に揮発する性質があるので、加工終了後に被加工品
を所定の温度に加熱することによりこの加工油を揮発さ
せて除去することができ、このために面倒な加工後の洗
浄作業が不要になる。According to the processing oil of the present invention, the polybutene used as the base oil has a lubricating performance equal to or higher than that of the low-viscosity mineral oil used in the conventional machining oil. Similarly, it can be used as a lubricating oil for metal processing, and this polybutene has extremely low content of impurities and heavy metals, has no toxicity or irritation, and does not cause hardening or thermal depolymerization by heating. Since it has the property of volatilizing easily, it is possible to volatilize and remove this processing oil by heating the work piece to a prescribed temperature after processing, which eliminates the need for troublesome cleaning work after processing. Become.
【００１２】[0012]
【実施例】以下、実施例に基づいて、本発明を具体的に
説明する。EXAMPLES The present invention will be specifically described below based on examples.
【００１３】実施例１ 粘度１．３ｃＳｔ（３７．８℃）、引火点４９℃及び芳
香族炭化水素０．１体積％以下である留分１６５〜２０
４℃のポリブテン〔出光興産（株）製商品名：ダフニー
クリーナーＭ〕に、油性向上剤としてラウリルアルコー
ル３重量％と、極圧添加剤としてジラウリルハイドロジ
ェンフォスファイト０．１重量％とを添加し、均一に混
合して加工油剤とした。Example 1 Fractions 165 to 20 having a viscosity of 1.3 cSt (37.8 ° C.), a flash point of 49 ° C. and an aromatic hydrocarbon content of 0.1% by volume or less.
3% by weight of lauryl alcohol as an oiliness improver and 0.1% by weight of dilauryl hydrogen phosphite as an extreme pressure additive were added to polybutene (trade name: Daphne Cleaner M manufactured by Idemitsu Kosan Co., Ltd.) at 4 ° C. And mixed evenly to obtain a processing oil.
【００１４】この加工油剤を使用し、実際にアルミ製熱
交換器フィン（フィン材：三層クラッド材、寸法：厚さ
０．１ｍｍ×幅２０ｍｍ）のコルゲート／ルーバー加工
を行った。加工油の除去は、被加工品を２５０℃に加熱
して加工油を揮発させ、揮発した加工油を回収する方法
で行った。結果は、５，０００山／分の加工速度で累積
５億山の加工を行った後に加工状況を観測したが、製品
の熱交換器フィンにばりの発生が認められず、また、工
具にも実質的な摩耗は認められなかった。また、加熱に
よる脱脂も充分に行われており、コンデンサーコアを組
付けた後にフラックスとしてＫＡｌＦ4 とＫ3 ＡｌＦ6
の混合物を使用して実施したロウ付けでのロウ付け率も
１００％であった。Using this processing oil, an aluminum heat exchanger fin (fin material: three-layer clad material, dimensions: thickness 0.1 mm × width 20 mm) was actually subjected to corrugation / louver processing. The processing oil was removed by heating the workpiece to 250 ° C. to volatilize the processing oil and collect the volatilized processing oil. The result was that after processing a cumulative total of 500 million threads at a processing speed of 5,000 threads / min, the processing status was observed, but no burr was found on the heat exchanger fins of the product, and the tool was also used. No substantial wear was observed. Also, degreasing by heating is sufficiently performed, and after the condenser core is assembled, KAlF 4 and K 3 AlF 6 are used as flux.
The brazing rate in brazing performed using the mixture of was also 100%.
【００１５】実施例２ 粘度２．６ｃＳｔ（３７．８℃）及び引火点８７℃であ
る留分２１３〜２６３℃のポリブテン〔出光興産（株）
製商品名：ダフニークリーナーＨ〕に、油性向上剤とし
てラウリルアルコール３重量％及びオレイン酸１重量％
と、極圧添加剤としてジラウリルハイドロジェンフォス
ファイト０．３重量％とを添加し、均一に混合して加工
油剤とした。Example 2 Polybutene having a viscosity of 2.6 cSt (37.8 ° C.) and a flash point of 87 ° C. and a fraction of 213 to 263 ° C. [Idemitsu Kosan Co., Ltd.]
Product name: Daphne Cleaner H] with 3% by weight of lauryl alcohol and 1% by weight of oleic acid as an oiliness improver
And 0.3% by weight of dilauryl hydrogen phosphite as an extreme pressure additive were added and uniformly mixed to obtain a processing oil.
【００１６】この加工油剤を使用し、実際にアルミ管プ
レス加工（Ｈ／Ｐピアシング加工）を行った。加工油の
除去は、被加工品を３００℃に加熱して加工油を揮発さ
せ、揮発した加工油を回収する方法で行った。結果は、
１０，０００回のＨ／Ｐピアシング加工を行った後に加
工状況を観測したが、製品のヘッダーパイプのアルミの
焼き付やダイスの摩耗は認められなかった。また、加熱
による脱脂も充分に行われており、コンデンサーコアを
組付けた後にフラックスとしてＫＡｌＦ4 とＫ3 ＡｌＦ
6 の混合物を使用して実施したロウ付けでのロウ付け率
も１００％であった。Using this processing oil, aluminum pipe press processing (H / P piercing processing) was actually performed. The processing oil was removed by heating the workpiece to 300 ° C. to volatilize the processing oil and collect the volatilized processing oil. Result is,
After performing H / P piercing processing 10,000 times, the processing state was observed, but no seizure of aluminum on the header pipe of the product or abrasion of the die was observed. Also, degreasing by heating is sufficiently performed, and after the condenser core is assembled, KAlF 4 and K 3 AlF are used as flux.
The brazing rate in the brazing carried out using the mixture of 6 was also 100%.
【００１７】実施例３ 油性向上剤としてラウリルアルコール３重量％及びステ
アリン酸ブチル３重量％を使用した以外は、上記実施例
１と同様にして加工油剤を調製した。この加工油剤を使
用し、実施例１と同様に、実際にアルミ製熱交換器フィ
ンのコルゲート／ルーバー加工を行った。結果は、実施
例１と同様に、５，０００山／分の加工速度で累積５億
山の加工を行った後に加工状況を観測したが、製品の熱
交換器フィンにばりの発生は認められず、また、工具に
も実質的な摩耗は認められなかった。また、加熱による
脱脂も充分に行われており、コンデンサーコアを組付け
た後にフラックスとしてＫＡｌＦ4 とＫ3 ＡｌＦ6 の混
合物を使用して実施したロウ付けでのロウ付け率も１０
０％であった。Example 3 A processing oil was prepared in the same manner as in Example 1 except that 3% by weight of lauryl alcohol and 3% by weight of butyl stearate were used as the oiliness improver. Using this processing oil, corrugation / louver processing of the aluminum heat exchanger fins was actually performed in the same manner as in Example 1. As a result, similar to Example 1, the processing situation was observed after processing a cumulative 500 million mountains at a processing speed of 5,000 mountains / minute, but burrs were found on the heat exchanger fins of the product. In addition, no substantial wear was observed on the tool. Also, degreasing by heating is sufficiently performed, and the brazing rate in brazing performed by using a mixture of KAlF 4 and K 3 AlF 6 as a flux after assembling the capacitor core is 10
It was 0%.
【００１８】[0018]
【発明の効果】本発明の金属の加工油剤は、加工油とし
て優れた性能を有するだけでなく、加工終了後に被加工
品を所定の温度に加熱するだけで容易に脱脂することが
でき、洗浄剤を使用する洗浄作業を行う必要がなく、工
業的に極めて有用なものである。INDUSTRIAL APPLICABILITY The metal working oil agent of the present invention not only has excellent performance as a working oil, but also can be easily degreased by heating a work piece to a predetermined temperature after the end of working, and can be washed. It is extremely useful industrially because it is not necessary to carry out a cleaning operation using an agent.
───────────────────────────────────────────────────── フロントページの続き (51)Int.Cl.5 識別記号 庁内整理番号 ＦＩ 技術表示箇所 Ｃ１０Ｍ 129:70 137:04 137:02） Ｃ１０Ｎ 20:02 30:06 40:24 ─────────────────────────────────────────────────── ─── Continuation of front page (51) Int.Cl. 5 Identification code Office reference number FI technical display location C10M 129: 70 137: 04 137: 02) C10N 20:02 30:06 40:24
Claims (2)
のポリブテン類からなる基油に、炭素数４〜１８の脂肪
酸、脂肪族アルコール及びエステルから選ばれた１種又
は２種以上の混合物からなる油性向上剤を０．５〜１０
重量％の範囲で添加してなる金属の加工油剤。1. A base oil composed of polybutenes having a viscosity of 1.0 to 10.0 centistokes, and one or a mixture of two or more selected from fatty acids having 4 to 18 carbon atoms, aliphatic alcohols and esters. The oiliness improver is 0.5 to 10
Metal processing oil added in the range of wt%.
及びリン含有界面活性剤から選ばれた極圧添加剤を５重
量％以下の範囲で添加してなる請求項１記載の金属の加
工油剤。2. The metal working oil agent according to claim 1, wherein an extreme pressure additive selected from organic phosphite, organic phosphate and a phosphorus-containing surfactant is added in an amount of 5% by weight or less.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP16680592A JPH05331484A (en) | 1992-06-03 | 1992-06-03 | Machining oil for metal |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP16680592A JPH05331484A (en) | 1992-06-03 | 1992-06-03 | Machining oil for metal |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH05331484A true JPH05331484A (en) | 1993-12-14 |
Family
ID=15838009
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP16680592A Pending JPH05331484A (en) | 1992-06-03 | 1992-06-03 | Machining oil for metal |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH05331484A (en) |
Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP1123968A1 (en) * | 2000-02-08 | 2001-08-16 | Mobil Oil Francaise | Aluminium and aluminium alloys cold rolling oil composition |
| WO2005095562A1 (en) * | 2004-03-31 | 2005-10-13 | Nippon Oil Corporation | Lubricating oil composition for use in working aluminum tube |
| JP2006131726A (en) * | 2004-11-05 | 2006-05-25 | Daido Chem Ind Co Ltd | Lubricant composition for warm and hot working of magnesium and/or magnesium alloy |
| JP2006225595A (en) * | 2005-02-21 | 2006-08-31 | Nippon Oil Corp | Lubricant composition |
| JP2008050515A (en) * | 2006-08-28 | 2008-03-06 | Sumitomo Light Metal Ind Ltd | Aluminum pipe-drawing lubricating oil, and drawing method of aluminum pipe by using it |
| JP2010065231A (en) * | 2009-12-15 | 2010-03-25 | Nippon Oil Corp | Lubricating oil composition for aluminum pipe processing |
| JP2018168259A (en) * | 2017-03-29 | 2018-11-01 | Ｊｘｔｇエネルギー株式会社 | Metal processing oil composition |
| JP2019112475A (en) * | 2017-12-20 | 2019-07-11 | 出光興産株式会社 | Metal processing oil composition, and method of producing metal plate laminate |
| WO2024009989A1 (en) * | 2022-07-07 | 2024-01-11 | Ｅｎｅｏｓ株式会社 | Base oil for metal processing oil composition, and metal processing oil composition |
| WO2024009951A1 (en) * | 2022-07-07 | 2024-01-11 | Ｅｎｅｏｓ株式会社 | Base oil for metalworking oil composition, and metalworking oil composition |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS58187493A (en) * | 1982-04-28 | 1983-11-01 | Nippon Oil Co Ltd | Lubricant for metal working |
| JPS6126695A (en) * | 1984-07-17 | 1986-02-05 | Idemitsu Kosan Co Ltd | Lubricating composition for both rust prevention and metal working |
-
1992
- 1992-06-03 JP JP16680592A patent/JPH05331484A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS58187493A (en) * | 1982-04-28 | 1983-11-01 | Nippon Oil Co Ltd | Lubricant for metal working |
| JPS6126695A (en) * | 1984-07-17 | 1986-02-05 | Idemitsu Kosan Co Ltd | Lubricating composition for both rust prevention and metal working |
Cited By (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP1123968A1 (en) * | 2000-02-08 | 2001-08-16 | Mobil Oil Francaise | Aluminium and aluminium alloys cold rolling oil composition |
| WO2005095562A1 (en) * | 2004-03-31 | 2005-10-13 | Nippon Oil Corporation | Lubricating oil composition for use in working aluminum tube |
| JP2005290160A (en) * | 2004-03-31 | 2005-10-20 | Nippon Oil Corp | Aluminum pipe working lubricating oil composition |
| JP2006131726A (en) * | 2004-11-05 | 2006-05-25 | Daido Chem Ind Co Ltd | Lubricant composition for warm and hot working of magnesium and/or magnesium alloy |
| JP2006225595A (en) * | 2005-02-21 | 2006-08-31 | Nippon Oil Corp | Lubricant composition |
| JP2008050515A (en) * | 2006-08-28 | 2008-03-06 | Sumitomo Light Metal Ind Ltd | Aluminum pipe-drawing lubricating oil, and drawing method of aluminum pipe by using it |
| JP2010065231A (en) * | 2009-12-15 | 2010-03-25 | Nippon Oil Corp | Lubricating oil composition for aluminum pipe processing |
| JP2018168259A (en) * | 2017-03-29 | 2018-11-01 | Ｊｘｔｇエネルギー株式会社 | Metal processing oil composition |
| JP2019112475A (en) * | 2017-12-20 | 2019-07-11 | 出光興産株式会社 | Metal processing oil composition, and method of producing metal plate laminate |
| WO2024009989A1 (en) * | 2022-07-07 | 2024-01-11 | Ｅｎｅｏｓ株式会社 | Base oil for metal processing oil composition, and metal processing oil composition |
| WO2024009951A1 (en) * | 2022-07-07 | 2024-01-11 | Ｅｎｅｏｓ株式会社 | Base oil for metalworking oil composition, and metalworking oil composition |
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