JPH0525506B2 - - Google Patents
Info
- Publication number
- JPH0525506B2 JPH0525506B2 JP1134353A JP13435389A JPH0525506B2 JP H0525506 B2 JPH0525506 B2 JP H0525506B2 JP 1134353 A JP1134353 A JP 1134353A JP 13435389 A JP13435389 A JP 13435389A JP H0525506 B2 JPH0525506 B2 JP H0525506B2
- Authority
- JP
- Japan
- Prior art keywords
- water
- bamboo
- activated
- powder
- oxygen
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 235000017166 Bambusa arundinacea Nutrition 0.000 claims description 27
- 235000017491 Bambusa tulda Nutrition 0.000 claims description 27
- 241001330002 Bambuseae Species 0.000 claims description 27
- 235000015334 Phyllostachys viridis Nutrition 0.000 claims description 27
- 239000011425 bamboo Substances 0.000 claims description 27
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 23
- 239000000843 powder Substances 0.000 claims description 19
- 239000003205 fragrance Substances 0.000 claims description 18
- 238000001035 drying Methods 0.000 claims description 5
- 150000002926 oxygen Chemical class 0.000 claims description 4
- 238000004519 manufacturing process Methods 0.000 claims description 3
- 239000002250 absorbent Substances 0.000 claims description 2
- 230000002745 absorbent Effects 0.000 claims description 2
- 230000018044 dehydration Effects 0.000 claims description 2
- 238000006297 dehydration reaction Methods 0.000 claims description 2
- 235000019645 odor Nutrition 0.000 description 12
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 8
- 229910052760 oxygen Inorganic materials 0.000 description 8
- 239000001301 oxygen Substances 0.000 description 8
- 239000002994 raw material Substances 0.000 description 6
- 230000001877 deodorizing effect Effects 0.000 description 5
- 239000008187 granular material Substances 0.000 description 5
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 4
- 125000003118 aryl group Chemical group 0.000 description 3
- 230000002354 daily effect Effects 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 239000002245 particle Substances 0.000 description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 2
- 238000010000 carbonizing Methods 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 235000013305 food Nutrition 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 230000000717 retained effect Effects 0.000 description 2
- 239000002023 wood Substances 0.000 description 2
- 235000013162 Cocos nucifera Nutrition 0.000 description 1
- 244000060011 Cocos nucifera Species 0.000 description 1
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 1
- 229910021536 Zeolite Inorganic materials 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 230000003213 activating effect Effects 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 235000011114 ammonium hydroxide Nutrition 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 239000007961 artificial flavoring substance Substances 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 238000004332 deodorization Methods 0.000 description 1
- 238000010790 dilution Methods 0.000 description 1
- 239000012895 dilution Substances 0.000 description 1
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 1
- 229910001882 dioxygen Inorganic materials 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 229940079593 drug Drugs 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000003203 everyday effect Effects 0.000 description 1
- 239000000796 flavoring agent Substances 0.000 description 1
- 235000013355 food flavoring agent Nutrition 0.000 description 1
- 239000003915 liquefied petroleum gas Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 239000005445 natural material Substances 0.000 description 1
- 229920000515 polycarbonate Polymers 0.000 description 1
- 239000004417 polycarbonate Substances 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 230000009257 reactivity Effects 0.000 description 1
- 238000002791 soaking Methods 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 238000010025 steaming Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000010457 zeolite Substances 0.000 description 1
Landscapes
- Disinfection, Sterilisation Or Deodorisation Of Air (AREA)
Description
〔産業上の利用分野〕
この発明は脱臭性を有するとともに芳香性を有
する吸放出性粉粒体の製造方法に関する。
〔従来の技術〕
一般に、有機物の腐敗臭、体臭、煙草臭、ペツ
ト臭その他の生活雑臭の脱臭剤として、活性炭、
沸石その他の多孔性物質が使用されている。
このうち活性炭は、木材、ヤシ殻、液化石油ガ
スその他を原料とし、この原料を炭化させ、さら
に水蒸気や薬品によつて活性化して製造されてい
る。
一方、生活雑臭に対する香料、または、衣類、
食品その他の生活用品に添加される香料として、
天然香料または人造香料が使用されている。この
人造香料は、天然香料に比較して香りが単調であ
り、また他の香りと混合された場合に異臭化し易
い欠点を有していた。
また、前記した脱臭剤は必ずしも人体に無害で
なく、そのために生活用品としての用途に制限が
あり、さらに前記した香料と別個に使用しなけれ
ば有効に機能しないものであつた。
さらにまた、人体に無害の天然素材である竹を
利用した脱臭剤も知られており（特開昭63−
109864号、特開昭63−150075号）、このものは、
竹材を加圧下で蒸煮または乾留することによつて
製造されている。
〔発明が解決しようとする課題〕
しかし、上記した従来の脱臭剤の製造方法によ
ると、製造されたものに若干の竹の香りが残るた
め、さらに人造香料を添加した場合に、複数のに
おい成分が混合されて異臭化し易いという問題点
がある。
この発明は、上記した問題点を解決し、人体に
対し安全性の高い竹を原料として、原材料の香り
が全くない状態で脱臭性（吸着性）の薬剤を製造
し、また異臭化を防止しつつ芳香性を合せ持つた
吸放出性の薬剤を製造することを課題としてい
る。
〔課題を解決するための手段〕
上記の課題を解決するため、この発明において
は、磁界中を通過して準活性化された酸素を水に
溶存させ、この水に水蒸気によつて活性化された
竹の粉粒体を浸漬した後、前記粉粒体を脱水乾燥
する手段を採用したものである。
また、磁界中を通過して準活性化された酸素を
水に溶存させかつ香料を添加し、この水に水蒸気
によつて活性化された竹の粉粒体を浸漬した後、
前記粉粒体を脱水乾燥する手段を採用することも
できる。
〔作用〕
上記した様に、この発明に係る竹の粉粒体は、
磁気処理により準活性化された酸素を溶存させた
水に、水蒸気によつて活性化された竹を浸漬し、
脱水乾燥することによつて製造される。
この場合、磁気処理によつて準活性化した酸素
は、反応性が若干高められて、常温、常圧下にお
ける酸素飽和量を越えて水に相当量溶存でき、こ
の溶存酸素が前記した竹の組織内に保持されたに
おい成分と作用し、このにおい成分を水中へ溶出
しやすくするものと推定される。
したがつて、このにおい成分が溶出した水を脱
水乾燥した竹は、多孔質組織間に竹そのものの匂
いが全くなくなり、さらに、竹のにおい成分に代
えて、香料を保持させて、におい成分同士の混合
がなく、異臭を発生しないものとなる。
〔実施例〕
この発明の吸放出性粉粒体は、活性化された竹
を素材とし、このような竹をさらに脱臭すること
によつて製造される。
この場合、素材となる活性化された竹は、孟宋
竹その他の竹を種類を限らずに用い、蒸気温度80
〜150℃で高圧の水蒸気によつて蒸煮して、その
後、乾燥、粉砕して粉粒体（平均粒径0.5μm〜４
mm）としたものである。このような粉粒体とし
て、乾留竹（たとえば竹泉産業社製：きよら）を
用いることができる。
この活性化された竹は、竹のにおいを未だ残し
ており、このにおいを除去するために、脱臭処理
が以下の手順で行なわれる。すなわち、空気磁化
器（中央熱研社製：エヤー磁化器Ａ型）を通過し
た空気を水中に曝気させ、ついでこの水に活性化
された竹の粉粒体を浸漬し、その後、この竹の粉
粒体を脱水し、さらに加熱して乾燥を行なう。前
記した空気磁化器は、複数の永久磁石を組み合わ
せて、内部に約7200ガウスの磁界を形成したもの
であつて、この強磁界中に流路を狭めて空気を高
速で通し、空気中に含まれる酸素分子の電子を賦
活して、分子状態の酸素を準活性化している。
上記のようにして活性化され、かつ脱臭された
竹に対して添加される香料は、たとえば水溶性香
料（太陽香料社製：フレグランEGC−１）など
の人造香料のほか、天然香料も用いることができ
る。この場合、液体の香料は、直接に吸放出性粉
粒体に含ませるほか別途、吸放出性粉粒体に含浸
処理した後、乾燥して混合することができ、固体
の香料は粉砕して混合する。このような香料の配
合量は、香料の種類によつて一律に規定されるも
のではないが、おおよそ吸放出性粉粒体100重量
部に対し、５〜10重量部を添加して良好な結果を
得ている。
実験例：
水蒸気によつて活性化された平均粒径0.5mmの
竹の微粉末（竹泉産業社製：きよら）を脱臭する
ため、空気磁化器（中央熱研社製：エアー磁化器
Ａ型）によつて準活性化された酸素を水温26℃で
9.6mg／１（同温の酸素飽和度7.99mg／１）溶存さ
せた水100リツトルに、前記した竹の微粉末５Kg
を24時間浸漬し、その後、ろ別して水分を除くと
ともに、200℃で60分間温風乾燥した。
このようにして得られた吸放出性粉粒体の脱臭
性を確認するために、ポリカーボネイト製デシケ
ータ（全体内容積18リツトル）に試薬特級アンモ
ニア水の10倍希釈液0.4mlと試供品を入れ密閉し
た後、乾燥器内で105℃を保ち、それぞれ15分間、
25分間、35分間、50分間放置し、アンモニア水溶
液を蒸発させる。ついで、乾燥器から取り出し、
残留アンモニア濃度を検知管法により測定した。
この結果を第１表に示す。
[Industrial Field of Application] The present invention relates to a method for producing absorbing and releasing powder having deodorizing properties and aromatic properties. [Prior Art] Activated carbon,
Zeolite and other porous materials are used. Among these, activated carbon is manufactured by using wood, coconut shells, liquefied petroleum gas, and other raw materials as raw materials, carbonizing the raw materials, and activating the raw materials with steam or chemicals. On the other hand, fragrances for everyday life odors or clothes,
As a flavoring agent added to food and other daily necessities,
Natural or artificial flavors are used. This artificial fragrance has a monotonous fragrance compared to natural fragrances, and also has the disadvantage that it tends to give off a strange odor when mixed with other fragrances. Further, the above-mentioned deodorizing agents are not necessarily harmless to the human body, and therefore their use as daily necessities is limited, and furthermore, they do not function effectively unless they are used separately from the above-mentioned fragrances. Furthermore, deodorizers using bamboo, which is a natural material that is harmless to the human body, are also known (Japanese Patent Application Laid-Open No. 1983-1999).
No. 109864, JP-A No. 63-150075), this one is
It is manufactured by steaming or carbonizing bamboo wood under pressure. [Problems to be Solved by the Invention] However, according to the above-mentioned conventional method for producing deodorizers, a slight bamboo scent remains in the produced product, so when artificial fragrances are added, multiple odor components There is a problem in that it is easy to mix and cause off-odor. This invention solves the above-mentioned problems, uses bamboo as a raw material that is highly safe for the human body, and produces a deodorizing (absorptive) agent without any scent from the raw material, and also prevents the formation of off-odor. The goal is to produce a drug that has both absorption and release properties and is aromatic. [Means for Solving the Problems] In order to solve the above problems, in the present invention, semi-activated oxygen is dissolved in water by passing through a magnetic field, and oxygen activated by water vapor is dissolved in water. This method employs a method of soaking bamboo powder and then dehydrating and drying the powder. In addition, after passing through a magnetic field to dissolve semi-activated oxygen in water and adding fragrance, and immersing bamboo powder activated by water vapor in this water,
It is also possible to employ means for dehydrating and drying the granular material. [Function] As mentioned above, the bamboo powder according to the present invention has the following properties:
Bamboo activated by water vapor is immersed in water with dissolved oxygen that has been semi-activated by magnetic treatment.
Manufactured by dehydration and drying. In this case, the reactivity of oxygen semi-activated by magnetic treatment is slightly increased, and a considerable amount of oxygen can be dissolved in water, exceeding the oxygen saturation amount at room temperature and pressure, and this dissolved oxygen is absorbed into the bamboo tissue described above. It is presumed that it acts on the odor components retained in the water and makes it easier to elute these odor components into the water. Therefore, in bamboo that has been dehydrated and dried from the water in which this odor component has been eluted, there is no smell of bamboo itself between the porous structures, and in addition, instead of the odor component of bamboo, the fragrance is retained and the odor components are mixed together. There is no mixing of the two, and no strange odors are generated. [Example] The absorptive and granular material of the present invention is produced by using activated bamboo as a material and further deodorizing such bamboo. In this case, the activated bamboo used as the material is Meng-Song bamboo and other types of bamboo without limitation, and the steam temperature is 80°C.
Steamed with high-pressure steam at ~150℃, then dried and crushed to produce powder (average particle size 0.5μm ~ 4μm).
mm). As such a granular material, carbonized bamboo (for example, Kiyora, manufactured by Takeizumi Sangyo Co., Ltd.) can be used. This activated bamboo still retains a bamboo odor, and in order to remove this odor, deodorization treatment is performed in the following steps. That is, air that has passed through an air magnetizer (manufactured by Chuo Nekken Co., Ltd.: Air Magnetizer Type A) is aerated into water, and then activated bamboo powder is immersed in this water. The powder is dehydrated and further heated to dry it. The above-mentioned air magnetizer combines multiple permanent magnets to form a magnetic field of about 7200 Gauss inside.The air magnetizer narrows the flow path in this strong magnetic field and passes air at high speed to remove the particles contained in the air. This activates the electrons of the oxygen molecules that are present in the atmosphere, making the molecular oxygen quasi-activated. The fragrance added to the activated and deodorized bamboo as described above may be an artificial fragrance such as a water-soluble fragrance (Fragran EGC-1 manufactured by Taiyo Kogyo Co., Ltd.) or a natural fragrance. I can do it. In this case, the liquid fragrance can be directly included in the absorptive powder or granules, or can be separately impregnated into the absorptive powder and then dried and mixed, and the solid fragrance can be crushed and mixed. Mix. The blending amount of such fragrances is not uniformly prescribed depending on the type of fragrance, but good results can be obtained by adding 5 to 10 parts by weight to 100 parts by weight of absorbent/release powder. I am getting . Experimental example: In order to deodorize fine bamboo powder (manufactured by Takeizumi Sangyo Co., Ltd.: Kiyora) with an average particle size of 0.5 mm activated by water vapor, an air magnetizer (manufactured by Chuo Nekken Co., Ltd.: Air Magnetizer A) was used. type) at a water temperature of 26°C.
Add 5 kg of the above fine bamboo powder to 100 liters of water dissolved in 9.6 mg/1 (oxygen saturation 7.99 mg/1 at the same temperature).
was soaked for 24 hours, and then filtered to remove moisture and dried with hot air at 200°C for 60 minutes. In order to confirm the deodorizing properties of the absorptive powder and granules thus obtained, 0.4 ml of a 10-fold dilution of reagent-grade ammonia water and a sample were placed in a polycarbonate desiccator (total internal volume: 18 liters) and the sample was sealed. After that, keep it at 105℃ in the dryer for 15 minutes each.
Leave for 25 minutes, 35 minutes, and 50 minutes to evaporate the ammonia aqueous solution. Then, remove it from the dryer and
The residual ammonia concentration was measured by the detector tube method.
The results are shown in Table 1.
以上の説明からも明らかなように、この発明の
吸放出性粉粒体は、臭気成分の吸着性と芳香性を
それぞれ有効に機能するよう併せ持ち、しかも人
体に対して安全な竹を素材として製造されている
ので、食品その他の生活用品に混入して使用でき
る産業上利用価値の高いものである。
As is clear from the above description, the absorbing and releasing powder of the present invention has both adsorption and aromatic properties for odor components, and is manufactured from bamboo, which is safe for the human body. Therefore, it has high industrial utility value as it can be mixed into food and other daily necessities.
Claims (1)
溶存させ、この水に水蒸気によつて活性化された
竹の粉粒体を浸漬した後、前記粉粒体を脱水乾燥
する吸放出性粉粒体の製造方法。 ２ 磁界中を通過して準活性化された酸素を水に
溶存させかつ香料を添加し、この水に水蒸気によ
つて活性化された竹の粉粒体を浸漬した後、前記
粉粒体を脱水乾燥する吸放出性粉粒体の製造方
法。[Claims] 1. After passing through a magnetic field to dissolve semi-activated oxygen in water and immersing bamboo powder activated by water vapor in this water, A method for producing absorbent-release powder by dehydrating and drying. 2 Dissolve semi-activated oxygen in water by passing it through a magnetic field, add fragrance, and immerse the bamboo powder activated by water vapor in this water. A method for producing absorbing and releasing powder by dehydration and drying.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP1134353A JPH0368A (en) | 1989-05-26 | 1989-05-26 | Granule having absorbing and discharging properties |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP1134353A JPH0368A (en) | 1989-05-26 | 1989-05-26 | Granule having absorbing and discharging properties |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH0368A JPH0368A (en) | 1991-01-07 |
| JPH0525506B2 true JPH0525506B2 (en) | 1993-04-13 |
Family
ID=15126382
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP1134353A Granted JPH0368A (en) | 1989-05-26 | 1989-05-26 | Granule having absorbing and discharging properties |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH0368A (en) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2011000428A (en) * | 2009-05-20 | 2011-01-06 | Chuniti Seiko Kk | Method of manufacturing deodorant and deodorant composition |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS63109864A (en) * | 1986-10-27 | 1988-05-14 | 清岡 高敏 | Production of odorless powdery dry undistilled bamboo |
| JPS63150075A (en) * | 1986-12-16 | 1988-06-22 | オルガノ株式会社 | Deodorizing material |
-
1989
- 1989-05-26 JP JP1134353A patent/JPH0368A/en active Granted
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS63109864A (en) * | 1986-10-27 | 1988-05-14 | 清岡 高敏 | Production of odorless powdery dry undistilled bamboo |
| JPS63150075A (en) * | 1986-12-16 | 1988-06-22 | オルガノ株式会社 | Deodorizing material |
Also Published As
| Publication number | Publication date |
|---|---|
| JPH0368A (en) | 1991-01-07 |
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