JPH0523803A - Method for casting cast slab having little defect of surface and inner part - Google Patents

Method for casting cast slab having little defect of surface and inner part

Info

Publication number
JPH0523803A
JPH0523803A JP20227291A JP20227291A JPH0523803A JP H0523803 A JPH0523803 A JP H0523803A JP 20227291 A JP20227291 A JP 20227291A JP 20227291 A JP20227291 A JP 20227291A JP H0523803 A JPH0523803 A JP H0523803A
Authority
JP
Japan
Prior art keywords
inclusions
mold
slab
meniscus
cast slab
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
JP20227291A
Other languages
Japanese (ja)
Inventor
Hiroyuki Tanaka
宏幸 田中
Ryoji Nishihara
良治 西原
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Nippon Steel Corp
Original Assignee
Nippon Steel Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Nippon Steel Corp filed Critical Nippon Steel Corp
Priority to JP20227291A priority Critical patent/JPH0523803A/en
Publication of JPH0523803A publication Critical patent/JPH0523803A/en
Withdrawn legal-status Critical Current

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  • Continuous Casting (AREA)
  • Casting Support Devices, Ladles, And Melt Control Thereby (AREA)

Abstract

PURPOSE:To produce a high clean cast slab by preventing accumulation of inclusions at meniscus part and below a mold in a continuous caster. CONSTITUTION:At the time of continuously casting a steel by using the continuous caster having vertical part, an electromagnetic stirrer is used so as to obtain flowing speed of molten steel at 0.1-0.4m/sec in the mold, and further, the uniform static magnetic field is acted in width direction of the cast slab at position in interval from 1.5m below the meniscus to start of changing the shape from the vertical part to the bending part in the continuous caster. By this method, as the accumulation of inclusions to the cast slab surface and the inner part is restrained, the cast slab having excellent cleanness can be produced.

Description

【発明の詳細な説明】Detailed Description of the Invention

【0001】[0001]

【産業上の利用分野】本発明は、鋼の連続鋳造法におい
て、鋳型内に侵入した介在物の鋳片内への集積を防止す
る事により高清浄な鋳片を製造する方法に関する。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a method for producing a highly clean slab by preventing accumulation of inclusions penetrating into a mold in the slab in a continuous casting method of steel.

【0002】[0002]

【従来の技術】周知のように、鋼の連続鋳造においては
鋳型内に浸漬ノズルより溶鋼を供給する方法を用いてい
る。
As is well known, in continuous casting of steel, a method of supplying molten steel from a dipping nozzle into a mold is used.

【0003】さらに、鋳型内における介在物の浮上分離
効果を向上させるために精錬時における溶鋼の清浄化や
鋳造時のノズル形状を変更する事により鋼の清浄化を図
っている。
Further, in order to improve the floating separation effect of inclusions in the mold, the steel is cleaned by cleaning the molten steel during refining and changing the nozzle shape during casting.

【0004】しかしながら、ノズルからの吐出流速が速
いためにこれらの対策のみでは、介在物が鋳型深くに侵
入して凝固シェルに捕捉されるために、内質欠陥の抜本
的な改善にはならない。
However, since the discharge flow rate from the nozzle is high, these measures alone cannot drastically improve the internal defects because inclusions penetrate deep into the mold and are trapped in the solidified shell.

【0005】また、鋳片内を浮上した介在物がメニスカ
ス直下においてシェルに捕捉されるために鋳片の表面欠
陥を防止することもできない。
Further, since the inclusions floating in the slab are captured by the shell immediately below the meniscus, surface defects of the slab cannot be prevented.

【0006】この、鋳片内凝固シェルへの介在物の捕捉
を抑制し、高い清浄性を有する鋳片を製造するために種
々の提案がなされている。
[0006] Various proposals have been made to suppress the trapping of inclusions in the solidified shell in a slab and produce a slab with high cleanliness.

【0007】例えば特開昭49―52725号公報に開
示されているように、鋳型内に電磁攪拌を作用させて溶
鋼を攪拌することによりメニスカス部における凝固シェ
ルへの介在物の捕捉を抑制させる方法や、特開昭61―
1459号公報に開示されているようにノズルからの吐
出流を低減させて介在物の侵入を防止する方法がある。
For example, as disclosed in Japanese Patent Laid-Open No. 49-52725, a method of suppressing inclusion of inclusions in a solidified shell in a meniscus portion by stirring molten steel by electromagnetic stirring in a mold. And JP-A-61-
As disclosed in Japanese Patent No. 1459, there is a method of preventing the intrusion of inclusions by reducing the discharge flow from the nozzle.

【0008】あるいは、特開昭56―160862号公
報に開示されているように、浸漬ノズルからの吐出流に
平行に移動磁界を作用させることにより吐出流速を低下
させる方法がある。
Alternatively, as disclosed in Japanese Patent Application Laid-Open No. 56-160862, there is a method in which a moving magnetic field is applied in parallel with the discharge flow from the immersion nozzle to reduce the discharge flow velocity.

【0009】[0009]

【発明が解決しようとする課題】しかしながら、これら
の介在物低減技術は、鋳型内での介在物の捕捉の制御を
目的としているために、浸漬ノズルからの吐出流に乗っ
て鋳型深くに侵入してしまう介在物には効果がない。
However, these techniques for reducing inclusions aim to control the trapping of inclusions in the mold, and therefore, they penetrate into the mold deeply along with the discharge flow from the immersion nozzle. It has no effect on the inclusions that end up.

【0010】即ち、鋳型内に電磁攪拌を作用させる方法
では鋳片表面部の介在物の集積は抑制できるものの、反
面、鋳型下方への介在物の侵入が防止できないために、
鋳型まで浮上してきた介在物を再び深くまでメニスカス
の下方深くまで押し込んでしまう事になり、鋳片の内質
を悪化させる事になる。
That is, although the method of applying electromagnetic stirring in the mold can suppress the accumulation of inclusions on the surface of the slab, it cannot prevent the inclusions from entering the lower part of the mold.
The inclusions that have floated to the mold will be pushed deeper and deeper below the meniscus, and the quality of the slab will be deteriorated.

【0011】また、これらの方法で用いている電磁力の
設置方法が、ノズルからの吐出流の方向が鋳造中に常に
一定方向に出ている事を想定し、これに直接作用するよ
うに電磁力を使用して流れを沈静化させる事を目的とし
ているために、ノズルからの吐出方向が変動する鋼の鋳
造操業においては安定性に欠ける等の問題点を抱えてお
り、とくに、鋳造末期においてノズルからの溶鋼の供給
が不安定となる場合には、これらの方法は操業を悪化さ
せる原因となってしまう。
Further, the electromagnetic force installation method used in these methods assumes that the direction of the discharge flow from the nozzle is always in a constant direction during casting, and the electromagnetic force is applied directly to this. Since the purpose is to calm the flow by using force, there are problems such as lack of stability in the casting operation of steel where the discharge direction from the nozzle fluctuates, especially at the end of casting. When the supply of molten steel from the nozzle becomes unstable, these methods cause deterioration of the operation.

【0012】本発明は前記従来法の問題点の抜本的な解
決を図り、鋳片表面および内部における介在物の集積の
無い、清浄性の優れた鋳片を製造し得る鋼の製造法を提
供するものである。
The present invention seeks to radically solve the above-mentioned problems of the conventional method, and provides a method for producing steel capable of producing a cast slab having excellent cleanliness without accumulation of inclusions on the surface and inside of the cast slab. To do.

【0013】[0013]

【課題を解決するための手段】前記問題点を解決するた
め、本発明は垂直部を有する連鋳機を使用して鋼を連続
鋳造するに際して、鋳型内において0.1から0.4m
/secの溶鋼流速が得られるように電磁攪拌を使用
し、さらにメニスカス部の下方1.5m部から連鋳機内
において垂直部から湾曲部へ形状が変化し始める位置の
間に鋳片幅方向に均一な静磁界を作用させることを特徴
とする、高清浄鋳片の鋳造方法である。
SUMMARY OF THE INVENTION In order to solve the above-mentioned problems, the present invention provides a continuous casting of steel using a continuous casting machine having a vertical portion, in which 0.1 to 0.4 m is cast in a mold.
Electromagnetic stirring was used to obtain a molten steel flow velocity of 1 / sec. Furthermore, in the width direction of the slab between the position 1.5m below the meniscus part and the position where the shape started to change from the vertical part to the curved part in the continuous casting machine. It is a method for casting a highly clean slab, which is characterized by applying a uniform static magnetic field.

【0014】ここで、連鋳機下部に設置する幅方向に均
一な静磁界において、本発明の効果が有効に作用する磁
束密度は1500ガウス以上である。
Here, in a uniform static magnetic field installed in the lower part of the continuous casting machine in the width direction, the magnetic flux density at which the effect of the present invention works effectively is 1500 gauss or more.

【0015】[0015]

【作用】以下作用とともに本発明を詳述する。The operation of the present invention will be described in detail below.

【0016】図2は従来の連続鋳造時の介在物の移動挙
動を表わした図である。鋳型(2)の中央部には浸漬ノ
ズル(1)が挿入されている。
FIG. 2 is a diagram showing the movement behavior of inclusions during conventional continuous casting. An immersion nozzle (1) is inserted in the center of the mold (2).

【0017】鋳造時には、介在物(4)は浸漬ノズルに
よって生じる下降流(7)によって鋳型下方深くまで侵
入する。
During casting, the inclusions (4) penetrate deep into the lower part of the mold by the downward flow (7) generated by the immersion nozzle.

【0018】ここで、侵入した介在物は重力と反対方向
に浮上するため、連鋳機が湾曲型連鋳機の場合には溶融
部の上部凝固シェルに捕捉される。一方、垂直部を有す
る連鋳機の場合にはメニスカス(9)方向に浮上する。
Here, since the intruding inclusions float in the direction opposite to the gravity, when the continuous casting machine is a curved type continuous casting machine, the inclusions are captured by the upper solidified shell of the melting portion. On the other hand, in the case of a continuous casting machine having a vertical portion, it floats in the meniscus (9) direction.

【0019】この介在物の中で、浮上速度が鋳造中の鋳
片(3)の移動速度である鋳造速度以上の径を有する介
在物(4)については、引き抜き速度に逆らって溶融部
内をメニスカス方向に浮上するため、ほぼ完全に浮上分
離される。
Among these inclusions, the inclusion (4) having a diameter whose floating speed is equal to or higher than the casting speed, which is the moving speed of the slab (3) during casting, opposes the drawing speed and causes a meniscus inside the molten portion. Since it floats in the direction, it is almost completely separated.

【0020】一方、それ以下の径の介在物は溶鋼中の浮
上速度が鋳造速度よりも小さいために、それ自体の浮上
だけではメニスカス(9)まで到着することはできず、
吐出流によって生じた下降流に乗って鋳型深くまで侵入
する。
On the other hand, the inclusions having a diameter smaller than that cannot reach the meniscus (9) only by ascending because the ascending speed in the molten steel is smaller than the casting speed.
It rides on the downward flow generated by the discharge flow and penetrates deep into the mold.

【0021】この鋳型深くまで侵入した介在物の何割か
は、鋳片の移動によりさらに深くまで運ばれた後に湾曲
部において鋳片内上面に浮上し捕捉されてしまう。
Some of the inclusions that have penetrated deep into the mold are carried further deeply by the movement of the slab, and then float up to the upper surface inside the slab at the curved portion and are captured.

【0022】一方、介在物の残り何割かは反転流(8)
に乗って再びメニスカス(9)近傍まで運ばれるが、そ
の際にメニスカス部の流れの淀み部に捕捉されてしま
う。
On the other hand, some of the remaining inclusions are reverse flow (8).
It is carried to the vicinity of the meniscus (9) again, but at that time, it is captured by the stagnation part of the flow of the meniscus part.

【0023】図1は本発明に基づく、垂直部を有する連
鋳機における磁界の位置を示す図である。
FIG. 1 is a diagram showing the position of a magnetic field in a continuous casting machine having a vertical portion according to the present invention.

【0024】図において、鋳型(2)内に電磁攪拌装置
(5)を設置し、鋳型内の溶鋼流速が0.1〜0.4m
/sec内になるように攪拌することによりメニスカス
部への介在物の集積を防止する。
In the figure, an electromagnetic stirrer (5) is installed in the mold (2) and the molten steel flow velocity in the mold is 0.1 to 0.4 m.
The inclusion is prevented from being accumulated on the meniscus portion by stirring so that it is within / sec.

【0025】ここで、溶鋼流速が0.1m/sec未満
の場合には、鋳型内においてデッケルが発生する原因に
なる。また0.4m/sec以上では鋳造時に連鋳パウ
ダーを巻き込むためである。
Here, if the molten steel flow velocity is less than 0.1 m / sec, deckling may occur in the mold. Further, it is because continuous casting powder is involved during casting at 0.4 m / sec or more.

【0026】一方、鋳型内の溶鋼を攪拌するだけでは、
メニスカス部の介在物は鋳型内に生じる下降流により、
鋳型下方深くまで運ばれてしまう。
On the other hand, if the molten steel in the mold is simply stirred,
Inclusions in the meniscus part are generated by the downward flow generated in the mold,
It is carried deep down the mold.

【0027】そこで、鋳型下方に侵入した介在物が湾曲
部まで侵入せず、連鋳機の垂直部内でのみ循環し、さら
に、磁界の下部の領域では溶鋼流動が均一になるよう
に、鋳片幅方向に均一な静磁界(6)を鋳型の下方部に
設置する。
Therefore, inclusions that have penetrated into the lower part of the mold do not penetrate into the curved part, but circulate only in the vertical part of the continuous casting machine, and further, in the region under the magnetic field, the molten steel flow is uniform, A static magnetic field (6) that is uniform in the width direction is placed in the lower part of the mold.

【0028】ここで、鋳型下方の均一磁界は浸漬ノズル
吐出口の下方1.5mから連鋳機の形状が垂直より湾曲
し始める範囲内に設置することが望ましい。
Here, it is desirable to set the uniform magnetic field below the mold within a range where the shape of the continuous casting machine begins to curve from the vertical direction 1.5 m below the discharge nozzle of the immersion nozzle.

【0029】図3に、浸漬ノズル部からの均一磁界の距
離に対する、鋳片内侵入介在物の浮上率を示すが、連鋳
機内の均一磁界の位置がノズルから1.5m以上間隔を
開ける事が必要な理由は、前述したように浮上速度が小
さい介在物はそれ自身の浮上速度では浮上できず、連鋳
機内の上昇流に乗ってメニスカス部まで浮上している。
FIG. 3 shows the levitation ratio of inclusions penetrating in the slab with respect to the distance of the uniform magnetic field from the immersion nozzle. The position of the uniform magnetic field in the continuous casting machine should be 1.5 m or more away from the nozzle. The reason is that, as described above, the inclusion having a small floating speed cannot float at its own floating speed, and floats up to the meniscus portion by riding on the upward flow in the continuous casting machine.

【0030】しかしながら静磁界をノズル近くに設置す
ると、磁界以降では溶鋼が均一流になり、上昇流の生成
が抑えられてしまうため、浮上速度が鋳片の下降する速
度以下の介在物については浮上が全く行なえなくなるた
めである。
However, when the static magnetic field is installed near the nozzle, the molten steel becomes a uniform flow after the magnetic field and the generation of the upward flow is suppressed, so that the inclusions whose levitation speed is lower than the descending speed of the slab are levitation. This is because it cannot be done at all.

【0031】一方、均一磁界の位置を垂直部以降の湾曲
部内に設置すると、湾曲部において溶鋼流速が急激に低
下するために、介在物は湾曲部における溶融部の上部シ
ェルに捕捉されてしまい、均一磁界を設置する効果が無
くなるためである。
On the other hand, when the position of the uniform magnetic field is set in the curved portion after the vertical portion, the molten steel flow velocity sharply decreases in the curved portion, so that the inclusions are trapped in the upper shell of the molten portion in the curved portion, This is because the effect of setting a uniform magnetic field is lost.

【0032】以上の方法により、連鋳機内に2種類の磁
界を作用させることにより鋳片内部への介在物の集積を
抑制して、表面および内部欠陥の少ない鋳片を安定して
製造することが可能になる。
By the above method, two kinds of magnetic fields are applied in the continuous casting machine to suppress the accumulation of inclusions inside the slab and stably produce a slab with few surface and internal defects. Will be possible.

【0033】[0033]

【実施例】前記した図1に基づいて説明すると、本実験
例では湾曲部の上部に3mの垂直部を有する連鋳機を用
い、この連鋳機の鋳型(2)内に電磁攪拌(5)を設置
し、さらに、浸漬ノズル(1)の下方2.5m位置に鋳
片幅方向に均一静磁界(6)を使用した。
EXAMPLE Referring to FIG. 1 described above, in this experimental example, a continuous casting machine having a vertical portion of 3 m above a curved portion was used, and an electromagnetic stirring (5) was used in a mold (2) of the continuous casting machine. ) Was installed, and a uniform static magnetic field (6) was used 2.5 m below the immersion nozzle (1) in the width direction of the slab.

【0034】本実験の操業条件は、鋳片サイズが幅98
0mm、厚み250mm、鋳造速度1.0m/分で低炭
アルミキルド鋼を連続鋳造するものである。
The operating condition of this experiment is that the slab size is 98 width.
A low carbon aluminum killed steel is continuously cast at 0 mm, a thickness of 250 mm and a casting speed of 1.0 m / min.

【0035】鋳型内に使用した電磁攪拌装置はメニスカ
ス部の流速を0.2〜0.3m/秒にするように作用さ
せた。
The electromagnetic stirrer used in the mold was operated so that the flow velocity of the meniscus was 0.2 to 0.3 m / sec.

【0036】また、鋳型下方の均一静磁界は3000ガ
ウスの発生能力を有するものを用い、本実験例では最高
7000ガウス前後の磁束密度を発生させ鋳片内幅方向
の溶融部に均一に磁束が作用するように付与した。
The uniform static magnetic field below the mold has a generating capacity of 3000 gauss. In this experimental example, a maximum magnetic flux density of about 7,000 gauss is generated, and the magnetic flux is evenly distributed in the molten portion in the width direction of the slab. Granted to work.

【0037】図4(a)は本実験例により製造された鋳
片の厚み方向の清浄性を従来法と比較して示したもので
ある。
FIG. 4 (a) shows the cleanliness in the thickness direction of the slab produced by this experimental example in comparison with the conventional method.

【0038】図中に、電磁力を使用しないで鋳造を行な
う場合(b)と、鋳型内電磁攪拌のみを作用させた場合
(c)と、メニスカス下方1m部に均一磁界のみを作用
させた場合(d)の結果を併せて示すが、図に示される
ように鋳型内電磁攪拌のみを作用させると、鋳片表面部
の介在物の集積は抑制できる反面、メニスカス部に浮上
した介在物を下降流により鋳片内に押し込むために、鋳
片内部に介在物が集積している。
In the figure, casting is performed without using electromagnetic force (b), only electromagnetic stirring in the mold is applied (c), and only a uniform magnetic field is applied 1 m below the meniscus. The results of (d) are also shown. However, as shown in the figure, when only electromagnetic stirring in the mold is applied, the accumulation of inclusions on the surface of the slab can be suppressed, but the inclusions floating on the meniscus descend. Inclusions are accumulated inside the slab to be pushed into the slab by the flow.

【0039】また、メニスカス下方1m部に均一静磁界
のみを使用して鋳造を行なう場合、連鋳機内を浮上した
介在物がメニスカス近傍で捕捉されるために鋳片表層部
に介在物が集積すること、また、均一磁界の設置位置が
メニスカス部に近いために微小介在物の浮上分離が完全
には行なわれず、鋳片内の介在物の除去効果が低下して
しまった。
When casting is performed using only a uniform static magnetic field 1 m below the meniscus, inclusions floating in the continuous casting machine are trapped near the meniscus, so that the inclusions accumulate on the surface layer of the slab. In addition, since the installation position of the uniform magnetic field is close to the meniscus portion, the floating separation of the minute inclusions cannot be performed completely, and the effect of removing the inclusions in the cast piece deteriorates.

【0040】一方、本発明に従って鋳造を行なうと、鋳
片の表面部、内部共に介在物の集積の無い清浄精度高い
鋳片の製造が可能になった。
On the other hand, when casting is performed according to the present invention, it is possible to manufacture a slab with high cleanliness accuracy without accumulating inclusions on the surface and inside of the slab.

【0041】[0041]

【発明の効果】以上説明したように、本発明の実施によ
り鋳片表層、内層部への介在物の捕捉を抑制できるため
に、清浄性の優れた鋳片の製造が可能になる。
As described above, since the inclusion of inclusions in the surface layer and inner layer of the slab can be suppressed by carrying out the present invention, a slab with excellent cleanliness can be manufactured.

【図面の簡単な説明】[Brief description of drawings]

【図1】本発明に基づく連鋳機内状態を説明する図であ
る。
FIG. 1 is a diagram illustrating an internal state of a continuous casting machine according to the present invention.

【図2】従来の連続鋳造における連鋳機内の介在物の浮
上状態を説明する図である。
FIG. 2 is a diagram illustrating a floating state of inclusions in a continuous casting machine in conventional continuous casting.

【図3】浸漬ノズルと鋳型下方の均一静磁界との距離と
鋳片内に侵入した介在物の浮上率との関係を示す図であ
る。
FIG. 3 is a diagram showing the relationship between the distance between the immersion nozzle and the uniform static magnetic field below the mold and the levitation rate of inclusions that have penetrated into the slab.

【図4】本発明に従って鋳造を実施する事により鋳片表
面部と内部への介在物の集積を防止できることを説明す
る図である。
FIG. 4 is a diagram illustrating that it is possible to prevent the accumulation of inclusions on the surface and inside of the slab by performing casting according to the present invention.

【符号の説明】 1 浸漬ノズル 2 鋳型 3 凝固シェル 4 介在物 5 電磁攪拌 6 均一静磁界 7 下降流 8 反転流 9 メニスカス[Explanation of symbols] 1 immersion nozzle 2 mold 3 solidification shell 4 inclusions 5 electromagnetic stirring 6 uniform static magnetic field 7 downflow 8 reverse flow 9 meniscus

Claims (1)

【特許請求の範囲】 【請求項1】 垂直部を有する連鋳機を使用して鋼を連
続鋳造するに際して、鋳型内において0.1から0.4
m/secの溶鋼流速が得られるように電磁攪拌を使用
し、さらにメニスカス部の下方1.5m部から連鋳機内
において垂直部から湾曲部へ形状が変化し始めるまでの
場所に、鋳片の幅方向に均一な静磁界を作用させること
を特徴とする、高清浄鋳片の鋳造方法。
Claim: What is claimed is: 1. When continuously casting steel using a continuous casting machine having a vertical portion, 0.1 to 0.4 in a mold.
Electromagnetic stirring was used to obtain a molten steel flow velocity of m / sec, and the slab was squeezed at a location 1.5 m below the meniscus until the shape started to change from a vertical portion to a curved portion in the continuous casting machine. A method for casting a highly clean cast slab, which comprises applying a uniform static magnetic field in the width direction.
JP20227291A 1991-07-18 1991-07-18 Method for casting cast slab having little defect of surface and inner part Withdrawn JPH0523803A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP20227291A JPH0523803A (en) 1991-07-18 1991-07-18 Method for casting cast slab having little defect of surface and inner part

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP20227291A JPH0523803A (en) 1991-07-18 1991-07-18 Method for casting cast slab having little defect of surface and inner part

Publications (1)

Publication Number Publication Date
JPH0523803A true JPH0523803A (en) 1993-02-02

Family

ID=16454793

Family Applications (1)

Application Number Title Priority Date Filing Date
JP20227291A Withdrawn JPH0523803A (en) 1991-07-18 1991-07-18 Method for casting cast slab having little defect of surface and inner part

Country Status (1)

Country Link
JP (1) JPH0523803A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2017131934A (en) * 2016-01-28 2017-08-03 新日鐵住金株式会社 Continuous casting method

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2017131934A (en) * 2016-01-28 2017-08-03 新日鐵住金株式会社 Continuous casting method

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Effective date: 19981008