JPH0523569A - Raw material granuation and its device - Google Patents

Raw material granuation and its device

Info

Publication number
JPH0523569A
JPH0523569A JP20728891A JP20728891A JPH0523569A JP H0523569 A JPH0523569 A JP H0523569A JP 20728891 A JP20728891 A JP 20728891A JP 20728891 A JP20728891 A JP 20728891A JP H0523569 A JPH0523569 A JP H0523569A
Authority
JP
Japan
Prior art keywords
raw material
granulating
stirring
vibration
water
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
JP20728891A
Other languages
Japanese (ja)
Inventor
Shoji Nitta
昭二 新田
Sadao Ebata
貞夫 江端
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
JFE Steel Corp
Original Assignee
Kawasaki Steel Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
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Application filed by Kawasaki Steel Corp filed Critical Kawasaki Steel Corp
Priority to JP20728891A priority Critical patent/JPH0523569A/en
Publication of JPH0523569A publication Critical patent/JPH0523569A/en
Withdrawn legal-status Critical Current

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Abstract

PURPOSE:To enhance granulation properties and processing capability without kneading for pressure-tight plasticizing for which the durability of a main machine system needs to be securely maintained and remedial measures to deal with the vibration of a bracket is needed to be taken when raw material is granulated. CONSTITUTION:A raw material granulation device is composed of a stirring blender 4 which adds an adequate amount of water for granulating a raw material depending on the type of the raw material and a vibration granulation machine 5 which conducts the raw material moistened by stirring and mixing of the stirring blender to a flat-bottom container 35, then applies a circular vibration in a direction along the discharge direction of the raw material and rotates/masses the raw material into mini-pellets.

Description

【発明の詳細な説明】Detailed Description of the Invention

【0001】[0001]

【産業上の利用分野】本発明は、原料の造粒方法及び装
置に関する。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a raw material granulating method and apparatus.

【0002】[0002]

【従来の技術】図11は従来の焼結プロセスを示す模式
図である。この従来技術では、微粉鉱石槽1に装入され
た原料を下部コンスタントフィーダ2により定量切出
し、これをベルトコンベア3で搬送し、混練機4、振動
造粒機5を経てミニペレットを製造している。他方、配
合槽6の下部コンスタントフィーダ7により定量切出さ
れた通常の焼結原料をベルトコンベア8上で多層積み配
合した後、上述の振動造粒されたミニペレットと上述の
通常の焼結原料とを、ドラムミキサ9にて混合し、これ
らを給鉱ホッパー10、ドラムフィーダ11を介してベ
ルトシュート12からDL式焼結機13のパレット14
へ装入し、点火炉15にて原料中のコークスに着火し、
焼結する。
2. Description of the Related Art FIG. 11 is a schematic view showing a conventional sintering process. In this conventional technique, a raw material charged in a fine ore tank 1 is cut out in a fixed amount by a lower constant feeder 2, which is conveyed by a belt conveyor 3, and a mini pellet is manufactured through a kneading machine 4 and a vibrating granulator 5. There is. On the other hand, after the normal sintering raw material quantitatively cut out by the lower constant feeder 7 of the mixing tank 6 is layered and mixed on the belt conveyor 8, the above-mentioned vibration-granulated mini-pellets and the above-mentioned normal sintering raw material are mixed. Are mixed in a drum mixer 9, and these are mixed from a belt chute 12 through a feed hopper 10 and a drum feeder 11 to a pallet 14 of a DL type sintering machine 13.
Charging into the ignition furnace 15, the coke in the raw material is ignited,
Sinter.

【0003】ここで、本出願人は、特願平1-269416号に
より、上述の混練機4、振動造粒機5の構成として図1
0の如くのものを開示している。
Here, the applicant of the present invention discloses, in Japanese Patent Application No. 1-269416, the construction of the above-mentioned kneader 4 and vibration granulator 5 as shown in FIG.
0 is disclosed.

【0004】即ち、混練機4は、ドラム40内に多数の
ロッド(圧密媒体)41を収納しており、ドラム40の
両側に加振機42を取付け、これらをバネ43上に載置
している。加振機42は、ドラム40の両側にて互いに
バランスして同期回転する如くに結合されて取付けられ
ており、バネ43との協働によりドラム40及び圧密媒
体41に円振動を付与する。
That is, the kneading machine 4 has a large number of rods (consolidation media) 41 housed in a drum 40, a vibrator 42 is attached to both sides of the drum 40, and these are placed on a spring 43. There is. The shaker 42 is attached to both sides of the drum 40 so as to be balanced and synchronized with each other so as to rotate synchronously, and cooperates with the spring 43 to impart circular vibration to the drum 40 and the consolidation medium 41.

【0005】また、振動造粒機5は、上記混練機4と同
様な、ドラム50回りに加振機52、バネ53を配設し
た加振機構を備え、ドラム50に円振動を付与し得るも
のである。
Further, the vibrating granulator 5 is provided with a vibrating mechanism in which a vibrating machine 52 and a spring 53 are arranged around the drum 50, similar to the kneading machine 4, and circular vibration can be applied to the drum 50. It is a thing.

【0006】従って、従来技術にあっては、焼結原料を
事前造粒するに際し、原料を第1の工程の上記混練機4
に供給し、適正造粒水分になるように水分添加し、ドラ
ム42内の圧密媒体41によって原料の粒子に圧密、剪
断、転動、圧潰、こね廻し混練等の総合作用を与え、粒
子内水分の絞り出し、表面水分の均一展拡作用を行な
い、これによって圧密可塑化されたフレークを第2の工
程の振動造粒機5に供給し、ドラム50の円振動により
これを転動造粒し、ミニペレットを製造していた。
Therefore, in the prior art, when the sintering raw material is pre-granulated, the raw material is kneaded in the kneading machine 4 in the first step.
Water is added to obtain a proper granulation water content, and the consolidation medium 41 in the drum 42 exerts a comprehensive action on the material particles such as consolidation, shearing, rolling, crushing, kneading by kneading, etc. Squeezing and uniform spreading of surface water, and thus the compacted and plasticized flakes are supplied to the vibrating granulator 5 in the second step, which is tumbled and granulated by the circular vibration of the drum 50. Manufactured mini pellets.

【0007】[0007]

【発明が解決しようとする課題】然しながら、従来技術
には、下記〜の問題点がある。
However, the prior art has the following problems.

【0008】造粒のための第1の工程として、圧密媒
体を用いた振動型混練機を用いており、大量処理の場
合、振動体重量が大きく、それによる慣性力が大きくな
る結果、機械本体の耐久性確保及び架台の振動対策が問
題となる。
As a first step for granulation, a vibrating kneader using a compaction medium is used. In the case of a large amount of processing, the weight of the vibrating body becomes large and the resulting inertial force becomes large. It is a problem to secure the durability of and the measures against the vibration of the stand.

【0009】造粒のための第2の工程として、バネ上
に載架したドラムを加振機にて加振する振動造粒機を用
いており、バネの安定振動領域から振幅を 7〜 8mm以上
には大きくとれず、造粒性及び処理能力の向上に限界が
ある。即ち、粒径 2〜10mmのものの収率が60重量%以下
と低い。
As the second step for granulation, a vibrating granulator which vibrates a drum mounted on a spring by a vibrating machine is used, and the amplitude is 7 to 8 mm from the stable vibration region of the spring. The above cannot be obtained so much, and there is a limit in improving the granulation property and the processing capacity. That is, the yield of particles having a particle size of 2 to 10 mm is as low as 60% by weight or less.

【0010】振動造粒されたミニペレットと、通常の
焼結原料とをドラムミキサにて混合しているため、ミキ
サ内の原料の移動層と静止層との間で生ずる剪断力がミ
ニペレットを崩壊し、その残存率が低い。このため、焼
結原料をパレット上で焼結するに際し、通気性が悪く、
生産性の低下、主排風機の消費電力過多を招く。
Since the vibration-granulated mini-pellets and ordinary sintering raw materials are mixed in the drum mixer, the shearing force generated between the moving layer and the stationary layer of the raw materials in the mixer causes the mini-pellets to collapse. However, the residual rate is low. Therefore, when sintering the sintering raw material on the pallet, the air permeability is poor,
This leads to reduced productivity and excessive power consumption of the main exhaust fan.

【0011】本発明は、造粒に際し、機械本体の耐久性
確保や架台の振動対策を必要とする圧密可塑化混練を行
なわず、且つ造粒性及び処理能力を向上することを目的
とする。
It is an object of the present invention to improve the granulating property and the processing capacity without performing the consolidation plasticization kneading which requires the durability of the machine body and the measures against the vibration of the gantry during the granulation.

【0012】また、本発明は、焼結に際し、造粒したミ
ニペレットのハンドリング上での崩壊を防止することを
目的とする。
Another object of the present invention is to prevent the granulated mini-pellets from collapsing during handling during sintering.

【0013】[0013]

【課題を解決するための手段】請求項1に記載の本発明
は、原料に応じて定まる当該原料の造粒に必要な水分量
を添加し、該原料を攪拌混合する第1の工程と、第1の
工程の攪拌混合により湿潤化された原料を平板状底面容
器に導入し、当該原料の排出方向に沿う方向における円
振動を付与し、該原料を転動塊成化しミニペレットを得
る第2の工程とからなる原料の造粒方法である。
The present invention according to claim 1 comprises a first step of adding the amount of water necessary for granulating the raw material, which is determined according to the raw material, and stirring and mixing the raw material. The raw material moistened by stirring and mixing in the first step is introduced into a flat bottom container, circular vibration is applied in a direction along the discharge direction of the raw material, and the raw material is rolling agglomerated to obtain mini-pellets. It is a method of granulating a raw material, which comprises two steps.

【0014】請求項2に記載の本発明は、請求項1に記
載の本発明方法において更に、前記原料がDL式焼結機
に供給する焼結原料であり、平板状底面容器内の原料層
厚を15mm以下とする状態で、当該原料の排出方向に沿う
方向における振幅10〜30mmの円振動を 4秒以上付与する
ようにしたものである。
The present invention according to claim 2 is the method according to claim 1, wherein the raw material is a sintering raw material supplied to a DL type sintering machine, and a raw material layer in a flat bottom container. With the thickness of 15 mm or less, a circular vibration with an amplitude of 10 to 30 mm in the direction along the discharge direction of the raw material is applied for 4 seconds or more.

【0015】請求項3に記載の本発明は、請求項2に記
載の本発明方法において更に、前記原料が粒径63μm 未
満の粒子を60重量%以上含有する微粉鉄鉱石のみである
ようにしたものである。
According to a third aspect of the present invention, in the method of the present invention according to the second aspect, the raw material is only fine iron ore containing 60% by weight or more of particles having a particle size of less than 63 μm. It is a thing.

【0016】請求項4に記載の本発明は、請求項1〜3
のいずれかに記載の本発明方法において更に、前記添加
水分量が、原料に応じて定まる当該原料の造粒による粒
径2〜10mmのものの収率を60重量%とするに必要な水分
量から、当該原料の保有水分量を差し引いた不足水分量
であるようにしたものである。
The present invention according to claim 4 provides the invention according to claims 1 to 3.
In the method of the present invention according to any one of the above, further the amount of water added is from the amount of water necessary to make the yield of particles having a particle size of 2 to 10 mm by granulation of the raw material determined according to the raw material 60% by weight. The water content of the raw material is deducted from the water content.

【0017】請求項5に記載の本発明は、原料に応じて
定まる当該原料の造粒に必要な水分量を添加し、該原料
を攪拌混合する攪拌混合機と、攪拌混合機による攪拌混
合により湿潤化された原料を平板状底面容器に導入し、
当該原料の排出方向に沿う方向における円振動を付与
し、該原料を転動塊成化しミニペレットを得る振動造粒
機とを有して構成される原料の造粒装置である。
According to a fifth aspect of the present invention, the amount of water required for granulating the raw material, which is determined according to the raw material, is added, and the raw material is stirred and mixed by stirring and mixing with the stirring mixer. Introduce the moistened raw material into the flat bottom container,
It is a raw material granulating device configured to include a vibration granulator that imparts circular vibration in a direction along the discharge direction of the raw material and roll-agglomerates the raw material to obtain mini-pellets.

【0018】請求項6に記載の本発明は、請求項5に記
載の本発明装置において更に、前記攪拌混合機が、 2本
の互いに反対方向に回転する螺旋羽根軸を容器内に並設
し、容器の螺旋羽根軸始端側には原料投入口を設け、螺
旋羽根軸終端側には原料排出口を設け、原料投入口の下
流側には加湿装置を設けて構成されるようにしたもので
ある。
According to a sixth aspect of the present invention, in the apparatus of the present invention according to the fifth aspect, the agitating mixer further comprises two spiral blade shafts rotating in opposite directions in a container. The container is provided with a raw material inlet on the spiral blade shaft starting end side, a raw material discharging port on the spiral blade shaft end side, and a humidifying device downstream of the raw material charging port. is there.

【0019】請求項7に記載の本発明は、請求項5に記
載の本発明装置において更に、前記振動造粒機が、平板
状底面容器を偏心軸により支持し、容器内の原料に偏心
軸の回転による円振動を付与するように構成されるよう
にしたものである。
According to a seventh aspect of the present invention, in the apparatus of the present invention according to the fifth aspect, the vibrating granulator further supports the flat bottom container by an eccentric shaft, and the raw material in the container has an eccentric shaft. It is configured so as to impart circular vibration due to the rotation of.

【0020】請求項8に記載の本発明は、請求項1〜4
のいずれかに記載の原料の造粒方法により振動造粒され
たミニペットを、ドラムミキサを経由しないで直送し、
焼結機のパレットへ装入する原料の焼結方法である。
The present invention according to claim 8 is defined by claims 1 to 4.
The mini-pets that have been vibrated and granulated by the granulation method of the raw material according to any one of 1 above, are directly sent without passing through a drum mixer,
This is a method of sintering raw materials to be charged into a pallet of a sintering machine.

【0021】[0021]

【作用】本発明の原理について、図2に示した原料含水
率と振動エネルギーによる単一粒子内の結合状態を用い
て説明する。
The principle of the present invention will be described with reference to the raw material water content and the binding state in a single particle due to vibration energy shown in FIG.

【0022】図2に示す如く、ある含水率を持つ微粉原
料を容器内に収納し、これを圧縮する方向に振動加速度
を与えると容器内の微粉の密度が上昇することが知られ
ている。このとき、容器内の微粉原料の含水率及び加振
エネルギーの大小に応じて粒子の充填状態が変化し、こ
の充填状態に応じて密度が上昇する。図2のグラフはこ
れを示すものである。
As shown in FIG. 2, it is known that when a fine powder raw material having a certain water content is stored in a container and vibration acceleration is applied in the direction of compressing the raw material, the density of the fine powder in the container increases. At this time, the filling state of the particles changes depending on the water content of the fine powder raw material in the container and the magnitude of the excitation energy, and the density increases according to the filling state. The graph of FIG. 2 shows this.

【0023】微粉原料の含水率が少ないときは、粉体の
粒子間には空気のある空隙が存在し、粉体はパサパサの
混合物の状態である。微粉原料の含水率を増加させて加
振すると、粒子の表面に水分が一様均一に拡展され、空
気層の空隙がなくなり、粒体全体はねばねばした可塑化
状態となり、微粉原料の乾燥密度は空隙率ゼロの曲線に
近づく。
When the water content of the fine powder raw material is low, voids with air exist between the particles of the powder, and the powder is in a dry mixture. When the water content of the fine powder raw material is increased and vibrated, the water is uniformly and uniformly spread on the surface of the particles, voids in the air layer are eliminated, and the entire granules are in a sticky plasticized state, resulting in a dry density of the fine powder raw material. Approaches a curve with zero porosity.

【0024】更に含水率が増加すると、粉体はどろどろ
のスラリー状態となる。このスラリー状態より水分が少
なく、空気層の空隙が最も少ない可塑物状態は、キャピ
ラリー域と呼ばれ、粉体の乾燥密度が最も高く高密度な
フレーク状態となっている。
When the water content further increases, the powder becomes a thick slurry. The plastic state in which the water content is less than that in the slurry state and the voids in the air layer are the smallest is called a capillary region, and the powder has the highest dry density and a high density flake state.

【0025】このキャピラリー域の粉体を得るには、粒
体の粒子の性状に応じた最も適正な含水率と、適正なエ
ネルギーの振動を加えることによって得ることができ
る。本発明は、この原理を利用した原料の造粒方法であ
って、まず第1の工程で、攪拌混合を行ない、適正な水
分量を添加することにて適正造粒水分状態に加湿し、且
つ均一水分に湿潤化した粉体を得る。そして、第2の工
程で、上記適正造粒水分に調合され、且つ均一水分に湿
潤化した粉体に円振動を与えることにて粒子中の水分を
表面に透出せしめ、この水分による粒子の付着、成長を
生じさせ、転動造粒するものである。
In order to obtain the powder in the capillary region, it is possible to obtain it by applying the vibration of the most appropriate water content and the appropriate energy according to the properties of the particles of the granules. The present invention is a method of granulating a raw material using this principle, in which in the first step, stirring and mixing are performed to add an appropriate amount of water to moisturize to an appropriate granulated water state, and A powder moistened with uniform water is obtained. Then, in a second step, circular moisture is applied to the powder that has been mixed with the proper granulation water and moistened with uniform water to cause the water in the particles to permeate to the surface. Adhesion and growth are caused, and rolling granulation is performed.

【0026】尚、第1の工程で、原料に添加する水分量
は、粒径 2〜10mmのミニペレットの収率が60重量%以上
得られるときの水分量(適正造粒水分)から、原料が元
々保有している水分量を差し引いた不足水分量であり、
原料の銘柄によって異なる。一例として、クドレムク鉱
石は保有水分が8.8 %、適正造粒水分が10.6%であるた
め、添加水分としては1.8 %である。また、MBR鉱石
では、保有水分が9.5%、適正造粒水分が11.5%である
ため、添加水分は2.0 %である。
In the first step, the amount of water added to the raw material is based on the amount of water (appropriate granulation water) when the yield of mini-pellets having a particle size of 2 to 10 mm is 60% by weight or more. Is the deficit of water that is subtracted from the amount of water originally held by
It depends on the brand of raw material. As an example, Kudrem ore has a water content of 8.8% and an appropriate granulation water content of 10.6%, so the added water content is 1.8%. For MBR ore, the water content is 9.5% and the proper granulation water content is 11.5%, so the added water content is 2.0%.

【0027】然るに、本発明によれば、下記〜の作
用効果がある。 造粒のための第1の工程が、圧密媒体を用いた振動型
混練機等による圧密可塑化混練を行なわず、適正な水分
添加と均一な攪拌混合を行なうものであり、振動発生を
伴わないから、格別な機械本体の耐久性確保や架台の振
動対策が不要である。
Therefore, according to the present invention, the following operational effects are obtained. The first step for granulation is to perform proper plasticization and kneading by a vibration-type kneader using a compaction medium, etc., and to perform proper water addition and uniform stirring and mixing, without causing vibration. Therefore, it is not necessary to secure the durability of the special machine body or take measures against the vibration of the frame.

【0028】尚、第1の工程で用いる攪拌混合機が、 2
本の螺旋羽根軸の回転により原料を攪拌混合するもので
あるとき、わずかな滞溜時間で均一な湿潤体を得ること
ができ、且つ振動を発生させることがない。
The stirring and mixing machine used in the first step is
When the raw material is agitated and mixed by the rotation of the spiral blade shaft of the book, a uniform wet body can be obtained in a short staying time, and vibration is not generated.

【0029】造粒のための第2の工程が、平板状底面
容器の原料層厚を10mm以下に薄くし、且つ振幅を10〜30
mmの如くに大きくする円振動により造粒性及び処理能力
を向上し、例えば粒径63μmm未満の粒子を60重量%以上
含有する微粉鉄鉱石のみを原料として、粒径 2〜10mmの
ものの収率を60重量%以上に高くできる。
In the second step for granulation, the raw material layer thickness of the flat bottom container is reduced to 10 mm or less and the amplitude is 10 to 30.
Granularity and processing capacity are improved by circular vibrations such as mm to increase the yield of particles of 2-10 mm using only fine iron ore containing 60 wt% or more of particles with a particle size of less than 63 μmm as raw material. Can be increased to over 60% by weight.

【0030】尚、第2の工程で用いる振動造粒機が、偏
心軸の回転による円振動を、平板状底面容器内の原料に
付与するものであるとき、偏心軸の偏心量を調整するこ
とにより、振幅は従来のものに比して 2倍以上にも大き
くとれる。
When the vibrating granulator used in the second step imparts circular vibration due to the rotation of the eccentric shaft to the raw material in the flat bottom container, the eccentric amount of the eccentric shaft should be adjusted. As a result, the amplitude can be more than twice as large as the conventional one.

【0031】また、振動造粒機の容器には余分な荷重が
作用しないので振動体重量を軽減でき、且つバランスウ
エイトを設けることにより架台へ伝達される振動を軽減
化できるので、機械の耐久性向上及び架台の振動防止が
図れ、設備の簡素化と機械の信頼性向上が図れる。
Further, since no excessive load is applied to the container of the vibrating granulator, the weight of the vibrating body can be reduced, and the vibration transmitted to the gantry can be reduced by providing the balance weight, so that the durability of the machine is improved. It is possible to improve and prevent the vibration of the gantry, simplify the equipment and improve the reliability of the machine.

【0032】振動造粒機を焼結機の給鉱部に近接配置
する等により、振動造粒されたミニペレットを、ドラム
ミキサを経由しないで直送し、焼結機のパレットへ装入
することから、ミニペレットのハンドリング上での崩壊
を防止できる。これにより、残存率が高く、グリーンボ
ールの強度は 100〜120gを確保できる。このため、焼結
原料をパレット上で焼結するに際し、通気性が良く、生
産性の向上、主排風機の消費電力節減を図ることができ
る。
Since the vibrating granulator is directly arranged without passing through the drum mixer by placing the vibrating granulator close to the ore feeding section of the sintering machine or the like, it is charged into the pallet of the sintering machine. , It is possible to prevent the collapse of the mini pellet during handling. As a result, the remaining rate is high and the strength of the green ball can be secured at 100 to 120 g. Therefore, when the sintering raw material is sintered on the pallet, the air permeability is good, the productivity is improved, and the power consumption of the main air exhauster can be reduced.

【0033】尚、焼結時の通気性改善の結果、PFを多
量に配合でき、原料コストの低減を図ることもできる。
As a result of improving the air permeability during sintering, a large amount of PF can be blended and the raw material cost can be reduced.

【0034】[0034]

【実施例】図1は本発明方法の一実施例を示す焼結工程
図、図2は原料含水率と振動エネルギーによる単一粒子
間の結合状態を示す模式図、図3は攪拌混合機の一例を
示す側断面図、図4は図3のIV−IV線に沿う断面図、図
5は振動造粒機の一例を示す側面図、図6は図5の正面
図、図7は多層型振動造粒機を示す側面図、図8は図7
の正面図、図9は本発明方法による造粒成績を示す線
図、図10は従来の振動造粒装置を示す斜視図、図11
は従来方法の焼結工程図である。
EXAMPLE FIG. 1 is a sintering process diagram showing an embodiment of the method of the present invention, FIG. 2 is a schematic diagram showing the bonding state between single particles due to the water content of raw materials and vibration energy, and FIG. Fig. 4 is a side sectional view showing an example, Fig. 4 is a sectional view taken along line IV-IV in Fig. 3, Fig. 5 is a side view showing an example of a vibrating granulator, Fig. 6 is a front view of Fig. 5, and Fig. 7 is a multilayer type. FIG. 8 is a side view showing the vibrating granulator, and FIG.
Of FIG. 9, FIG. 9 is a diagram showing a granulation result by the method of the present invention, FIG. 10 is a perspective view of a conventional vibrating granulator, and FIG.
FIG. 4 is a sintering process diagram of a conventional method.

【0035】本発明方法を用いたDL式焼結機のための
焼結プロセスでは、図1に示す如く、微粉鉱石槽1に装
入された微粉原料を下部コンスタントフィーダ2により
定量に切出し、これをベルトコンベア3で搬送し、この
原料を攪拌混合機4に供給し、適正造粒水分に調合、且
つ均一水分となるように攪拌混合する。更に、この原料
を振動造粒機5に供給し、粒径 2〜10mmの収率が60重量
%以上であるミニペレットを事前造粒する。他方、配合
槽6の下部コンスタントフィーダ7により定量に切出さ
れた通常の焼結原料(返鉱、石灰石、コークス、粉鉱
等)を、ベルトコンベア8上で多層積み配合した後、ド
ラム形ミキサ9にて原料全体の水分が 5〜7%になるよ
うに水分を添加し、ドラムの回転により混合、転動造粒
し、給鉱ホッパー10へ搬送し、ドラムフィーダ11に
て定量切出す。そして、前記振動造粒されたミニペレッ
トと2次配合原料をベルトシュート12上で混合し、D
L式焼結機13のパレット14へ装入した後、点火炉1
5にて原料中のコークスに着火し焼結する。
In the sintering process for the DL type sintering machine using the method of the present invention, as shown in FIG. 1, the fine powder raw material charged in the fine ore tank 1 is cut out in a fixed amount by the lower constant feeder 2 and Is conveyed by a belt conveyer 3 and this raw material is supplied to a stirring and mixing machine 4 to be mixed with proper granulation water and stirred and mixed so as to obtain a uniform water content. Further, this raw material is supplied to the vibrating granulator 5 to pre-granulate mini-pellets having a particle size of 2 to 10 mm and a yield of 60% by weight or more. On the other hand, ordinary sintering raw materials (returned ore, limestone, coke, powder ore, etc.) quantitatively cut by the lower constant feeder 7 of the compounding tank 6 are stacked and compounded on the belt conveyor 8 and then mixed in a drum mixer. At 9, the water is added so that the water content of the entire raw material becomes 5 to 7%, mixed by the rotation of the drum, tumbled and granulated, conveyed to the ore hopper 10, and cut out quantitatively by the drum feeder 11. Then, the vibration-granulated mini-pellets and the secondary compounding raw materials are mixed on the belt chute 12, and D
After charging to the pallet 14 of the L-type sintering machine 13, the ignition furnace 1
At 5, the coke in the raw material is ignited and sintered.

【0036】ここで、上記攪拌混合機4は図3、図4に
示す如くである。即ち、攪拌混合機4は、台座16を介
し架台17に固定された双U形容器18内に、2本の互
いに反対方向(上半部が外向きの回転)に回転する螺旋
羽根軸19、20を並設し、該螺旋羽根軸19、20に
攪拌用の羽根21を螺旋状に固着している。各螺旋羽根
軸19、20はそれらの両側軸端部を軸受22に支承さ
れ、給鉱側の軸端部には軸継手23を介し、駆動用モー
タ24が接続されている。また、双U形容器18の螺旋
羽根軸19、20始端側には原料投入口25を設け、螺
旋羽根軸19、20終端側には原料排出口26を設け、
また原料投入口25の下流側には加湿装置27を設けて
いる。
Here, the stirring and mixing machine 4 is as shown in FIGS. That is, the agitation mixer 4 has two twin U-shaped containers 18 fixed to a pedestal 17 via a pedestal 16 and two spiral blade shafts 19, which rotate in mutually opposite directions (the upper half is rotated outward). 20 are arranged side by side, and stirring blades 21 are spirally fixed to the spiral blade shafts 19 and 20. The respective spiral blade shafts 19 and 20 are supported by bearings 22 on both side shaft ends, and a drive motor 24 is connected to the shaft ends on the mining side via a shaft joint 23. Further, a raw material inlet 25 is provided on the start side of the spiral blade shafts 19 and 20 of the twin U-shaped container 18, and a raw material discharge port 26 is provided on the end side of the spiral blade shafts 19 and 20.
A humidifier 27 is provided downstream of the raw material charging port 25.

【0037】また、上記振動造粒機5は図5〜図6に示
す如くである。即ち、振動造粒機5は、架台30上に、
軸受31、32を介して、 2本の偏心軸33、34を軸
支し、それらの偏心軸33、34により広幅角トラフ状
の平板状底面容器35を支持する。尚、36はブラケッ
ト、37は連結ピンである。
The vibrating granulator 5 is as shown in FIGS. That is, the vibrating granulator 5 is mounted on the pedestal 30.
Two eccentric shafts 33 and 34 are supported via bearings 31 and 32, and a wide-angle trough-shaped flat bottom container 35 is supported by these eccentric shafts 33 and 34. Incidentally, 36 is a bracket and 37 is a connecting pin.

【0038】そして、偏心軸33は軸継手38を介して
駆動用モータ39にて駆動され、偏心軸34はタイミン
グベルト41を介して偏心軸33と同期駆動せしめられ
る。これにより、振動造粒機5は、容器35内の原料に
偏心軸33、34による振動加速度3G〜 10Gの当該原料
の排出方向に沿う方向における円振動(振幅10〜30mm、
振動数 400〜1000回/分)を付与する。
The eccentric shaft 33 is driven by a drive motor 39 via a shaft joint 38, and the eccentric shaft 34 is driven synchronously with the eccentric shaft 33 via a timing belt 41. As a result, the vibrating granulator 5 causes the raw material in the container 35 to have a circular vibration (amplitude 10 to 30 mm;
Vibration frequency of 400 to 1000 times / min.

【0039】このとき、平板状底面容器35は、ブラケ
ット36に略水平支持され、前述の偏心軸33、34の
図5における反時計方向回りの方向の円振動を付与され
る状態下で、原料投入部35Aから原料を供給され、こ
の原料を原料排出部35Bの側へ給送せしめる。ここ
で、容器35内の原料は、その層厚を15mm以下とするよ
うに設定されている。これにより、容器35内の原料
は、振幅10〜30mmの円振動を 4秒以上付与され、転動塊
成化され、ミニペレットとなる。
At this time, the plate-shaped bottom container 35 is supported substantially horizontally by the bracket 36, and the eccentric shafts 33 and 34 are subjected to circular vibration in the counterclockwise direction in FIG. The raw material is supplied from the charging unit 35A, and the raw material is fed to the raw material discharging unit 35B. Here, the raw material in the container 35 is set to have a layer thickness of 15 mm or less. As a result, the raw material in the container 35 is subjected to circular vibration with an amplitude of 10 to 30 mm for 4 seconds or more, rolling-agglomerated, and becomes mini-pellets.

【0040】尚、平板状底面容器35は、原料投入部3
5Aから原料排出部35Bの側に向けて例えば10度の下
り勾配を付与され、且つ図5における時計方向の円振動
を付与されるものであっても良い。これによれば、容器
35内において、細粒は原料投入部35A側に移動し、
攪拌されて核粒子となり、他方、成長した粒子は重力に
より原料排出部35B側に移動し、粒度を揃えられる状
態で排出されることとなる。
The flat bottom container 35 is provided in the raw material charging section 3
For example, a downward gradient of, for example, 10 degrees may be applied from 5A toward the raw material discharge part 35B, and a clockwise circular vibration in FIG. 5 may be applied. According to this, in the container 35, the fine particles move to the raw material charging unit 35A side,
The particles are agitated to become core particles, while the grown particles are moved to the side of the raw material discharge part 35B by gravity and discharged in a state where the particle sizes are made uniform.

【0041】図7、図8の多層型振動造粒機は、図5、
図6の振動造粒機5を積層配置したものである。各振動
造粒機5は比較的扁平状であるため、多層化により、設
備のスペース効率を向上し得る。
The multi-layer vibrating granulator shown in FIGS.
The vibrating granulator 5 of FIG. 6 is arranged in layers. Since each of the vibrating granulators 5 has a relatively flat shape, the space efficiency of the equipment can be improved due to the multilayer structure.

【0042】次に、本発明によるDL式焼結機に供給す
る焼結原料、特に粒径63μm 未満の粒子を60重量%以上
含有する微粉鉄鉱石のみの原料の造粒成績について説明
する。
Next, the granulation results of the sintering raw material supplied to the DL type sintering machine according to the present invention, particularly the raw material only of fine iron ore containing 60% by weight or more of particles having a particle size of less than 63 μm will be described.

【0043】図9(A)は振動造粒機5の平板状底面容
器35に振幅16mm、振動数 900回/分一定の円振動を付
与し、且つトラフ長さを種々変えて滞溜時間を求め、こ
の滞溜時間と造粒産物中の粒径 2〜10mmのグリーンボー
ルの収率との関係を示したものである。これより、粒径
2〜10mmのものの収率60重量%以上を得るには、少なく
も 1.5秒以上の滞留時間が、収率80重量%以上を得るに
は 4秒以上の滞溜時間が必要となることが認められる。
In FIG. 9 (A), a circular vibration having an amplitude of 16 mm and a constant frequency of 900 times / minute is applied to the flat bottom container 35 of the vibrating granulator 5, and the trough length is variously changed to keep the staying time. The relationship between this retention time and the yield of green balls with a particle size of 2 to 10 mm in the granulated product is shown. From this, the particle size
It was confirmed that a residence time of at least 1.5 seconds was required to obtain a yield of 60% by weight or more for 2 to 10 mm, and a retention time of 4 seconds or more was required to obtain a yield of 80% by weight or more. To be

【0044】また、図9(B)は振動造粒機5の平板状
底面容器35に振動数900回/分、滞溜時間 5秒一定の
円振動を付与し、且つ振幅を種々変え、この振幅と造粒
産物中の粒径 2〜10mmのグリーンボールの収率との関係
を示したものである。これより、振幅を大きくするほ
ど、粒径 2〜10mmのものの収率は向上するが、粒径 2〜
10mmのものの収率60重量%以上を得るには、振幅 5mm以
下でも良いが収率80重量%以上を得るには振幅10〜30m
m、好ましくは15mm以上が適正と考えられる。
Further, FIG. 9B shows that the flat bottom container 35 of the vibrating granulator 5 was subjected to a circular vibration with a vibration frequency of 900 times / minute and a dwell time of 5 seconds, and the amplitude was variously changed. The relationship between the amplitude and the yield of green balls with a particle size of 2 to 10 mm in the granulated product is shown. From this, the larger the amplitude, the better the yield of particles with a particle size of 2-10 mm, but
To obtain a yield of 60% or more for 10 mm, an amplitude of 5 mm or less is acceptable, but to obtain a yield of 80% or more, an amplitude of 10 to 30 m
m, preferably 15 mm or more is considered appropriate.

【0045】更に、図9(C)は振動造粒機5の平板状
底面容器35に振幅16mm、振動数 900回/分、滞溜時間
5秒一定の円振動を付与し、原料投入量を種々変えたと
きの原料層厚と造粒産物中の粒径 2〜10mmのグリーンボ
ールの収率との関係を示したものである。これより原料
層厚は薄いほど良いが、15mm以下が適正と考えられる。
Further, FIG. 9C shows that the flat bottom container 35 of the vibrating granulator 5 has an amplitude of 16 mm, a vibration frequency of 900 times / minute, and a retention time.
This figure shows the relationship between the raw material layer thickness and the yield of green balls with a particle size of 2 to 10 mm in the granulated product when a constant circular vibration is applied for 5 seconds and the amount of the raw material input is variously changed. The thinner the raw material layer, the better, but 15 mm or less is considered appropriate.

【0046】上記実施例によれば、下記〜の作用効
果がある。 造粒のための第1の工程が、圧密媒体を用いた振動型
混練機等による圧密可塑化混練を行なわず、適正な水分
添加と均一な攪拌混合を行なうものであり、振動発生を
伴わないから、格別な機械本体の耐久性確保や架台の振
動対策が不要である。
According to the above embodiment, the following effects are obtained. The first step for granulation is to perform proper plasticization and kneading by a vibration-type kneader using a compaction medium, etc., and to perform proper water addition and uniform stirring and mixing, without causing vibration. Therefore, it is not necessary to secure the durability of the special machine body or take measures against the vibration of the frame.

【0047】尚、第1の工程で用いる攪拌混合機4が、
2本の螺旋羽根軸19、20の回転により原料を攪拌混
合するものであるとき、わずかな滞溜時間で均一な湿潤
体を得ることができ、且つ振動を発生させることがな
い。
The stirring and mixing machine 4 used in the first step is
When the raw materials are agitated and mixed by the rotation of the two spiral blade shafts 19 and 20, a uniform wet body can be obtained in a short staying time and no vibration is generated.

【0048】造粒のための第2の工程が、平板状底面
容器35の原料層厚を15mm以下に薄くし、且つ振幅を 5
mm程度をとる円振動により造粒性及び処理能力を向上
し、例えば粒径63μmm未満の粒子を60重量%以上含有す
る微粉鉄鉱石のみを原料として、粒径 2〜10mmのものの
収率を60重量%以上に高くできる。
The second step for granulation is to reduce the thickness of the raw material layer of the flat bottom container 35 to 15 mm or less and set the amplitude to 5 mm.
Granularity and processing capacity are improved by circular vibration taking about mm.For example, using only fine iron ore containing 60 wt% or more of particles with a particle size of 63 μmm or more as a raw material, the yield of particles with a particle size of 2-10 mm is 60%. It can be increased to more than weight%.

【0049】更に、原料層厚を10mm以下に薄くし、且つ
振幅を10〜30mmの如くに大きくする円振動により、粒径
2〜10mmのものの収率を80重量%以上に高くできる。
Further, the grain size is reduced by circular vibration that reduces the thickness of the raw material layer to 10 mm or less and increases the amplitude to 10 to 30 mm.
The yield of 2 to 10 mm can be increased to 80% by weight or more.

【0050】尚、第2の工程で用いる振動造粒機5が、
偏心軸33、34の回転による円振動を平板状底面容器
35内の原料に付与するものであるとき、偏心軸33、
34の偏心量を調整することにより、振幅は従来のもの
に比して 2倍以上にも大きくとれる。
The vibration granulator 5 used in the second step is
When circular vibration due to the rotation of the eccentric shafts 33, 34 is applied to the raw material in the flat bottom container 35, the eccentric shaft 33,
By adjusting the eccentricity of 34, the amplitude can be more than doubled compared to the conventional one.

【0051】また、振動造粒機5の容器35には余分な
荷重が作用しないので振動体重量を軽減でき、且つバラ
ンスウエイトを設けることにより架台30へ伝達される
振動を軽減化できるので、機械の耐久性向上及び架台3
0の振動防止が図れ、設備の簡素化と機械の信頼性向上
が図れる。
Since no extra load is applied to the container 35 of the vibrating granulator 5, the weight of the vibrating body can be reduced, and the vibration transmitted to the gantry 30 can be reduced by providing the balance weight. Improvement of the durability and stand 3
Zero vibration can be prevented, equipment can be simplified and machine reliability can be improved.

【0052】振動造粒機5を焼結機13の給鉱部に近
接配置する等により、振動造粒されたミニペレットを、
ドラムミキサを経由しないで直送し、焼結機13のパレ
ット14へ装入することから、ミニペレットのハンドリ
ング上での崩壊を防止できる。これにより、残存率が高
く、グリーンボールの強度は 100〜120gを確保できる。
このため、焼結原料をパレット14上で焼結するに際
し、通気性が良く、生産性の向上、主排風機の消費電力
節減を図ることができる。
By placing the vibrating granulator 5 close to the ore feeding section of the sintering machine 13, etc.
Since it is directly sent without passing through the drum mixer and is loaded into the pallet 14 of the sintering machine 13, it is possible to prevent collapse of the mini pellets in handling. As a result, the remaining rate is high and the strength of the green ball can be secured at 100 to 120 g.
Therefore, when the sintering raw material is sintered on the pallet 14, the air permeability is good, the productivity is improved, and the power consumption of the main air exhauster can be reduced.

【0053】尚、焼結時の通気性改善の結果、PFを多
量に配合でき、原料コストの低減を図ることもできる。
As a result of improving the air permeability during sintering, a large amount of PF can be blended, and the raw material cost can be reduced.

【0054】尚、本発明方法の成績は従来法に比して表
1の如くである。ここで、焼結機の生産率は、(a) 粒径
2〜10mmの収率向上により、通気性良く、焼結時間を短
縮できること、(b) 圧潰強度の向上により、崩壊が少な
く、通気性確保でき、焼結時間を短縮できることによ
り、1.7 (トン/時間・m2)に向上できたものと考えら
れる。
The results of the method of the present invention are shown in Table 1 as compared with the conventional method. Here, the production rate of the sintering machine is (a) grain size
By improving the yield by 2-10 mm, the air permeability is good and the sintering time can be shortened. (B) By improving the crushing strength, there is little disintegration, the air permeability can be secured, and the sintering time can be shortened to 1.7 (ton / ton / It is thought that the time has been improved to m 2 ).

【0055】[0055]

【表1】 [Table 1]

【0056】[0056]

【発明の効果】以上のように本発明によれば、造粒に際
し、機械本体の耐久性確保や架台の振動対策を必要とす
る圧密可塑化混練を行なわず、且つ造粒性及び処理能力
を向上することができる。
As described above, according to the present invention, during granulation, the compaction plasticizing and kneading, which requires the durability of the machine body and the measures against the vibration of the gantry, is not performed, and the granulation property and the processing capacity are improved. Can be improved.

【0057】また、本発明によれば、焼結に際し、造粒
したミニペレットのハンドリング上での崩壊を防止する
ことができる。
Further, according to the present invention, it is possible to prevent the granulated mini-pellets from collapsing during handling during sintering.

【図面の簡単な説明】[Brief description of drawings]

【図1】図1は本発明方法の一実施例を示す焼結工程図
である。
FIG. 1 is a sintering process diagram showing an embodiment of the method of the present invention.

【図2】図2は原料含水率と振動エネルギーによる単一
粒子間の結合状態を示す模式図である。
FIG. 2 is a schematic diagram showing a bonding state between single particles due to a water content of a raw material and vibration energy.

【図3】図3は攪拌混合機の一例を示す側断面図であ
る。
FIG. 3 is a side sectional view showing an example of a stirring mixer.

【図4】図4は図3のIV−IV線に沿う断面図である。FIG. 4 is a sectional view taken along line IV-IV in FIG.

【図5】図5は振動造粒機の一例を示す側面図である。FIG. 5 is a side view showing an example of a vibrating granulator.

【図6】図6は図5の正面図である。FIG. 6 is a front view of FIG.

【図7】図7は多層型振動造粒機を示す側面図である。FIG. 7 is a side view showing a multilayer vibrating granulator.

【図8】図8は図7の正面図である。FIG. 8 is a front view of FIG. 7.

【図9】図9は本発明方法による造粒成績を示す線図で
ある。
FIG. 9 is a diagram showing granulation results by the method of the present invention.

【図10】図10は従来の振動造粒装置を示す斜視図で
ある。
FIG. 10 is a perspective view showing a conventional vibrating granulator.

【図11】図11は従来方法の焼結工程図である。FIG. 11 is a sintering process diagram of a conventional method.

【符号の説明】[Explanation of symbols]

4 攪拌混合機 5 振動造粒機 13 焼結機 18 容器 19、20 螺旋羽根軸 25 原料投入口 26 原料排出口 27 加湿装置 33、34 偏心軸 35 平板状底面容器 4 stirring mixer 5 Vibration granulator 13 Sintering machine 18 containers 19, 20 spiral blade shaft 25 Raw material inlet 26 Raw material outlet 27 Humidifier 33, 34 Eccentric shaft 35 Flat bottom container

Claims (8)

【特許請求の範囲】[Claims] 【請求項1】 原料に応じて定まる当該原料の造粒に必
要な水分量を添加し、該原料を攪拌混合する第1の工程
と、第1の工程の攪拌混合により湿潤化された原料を平
板状底面容器に導入し、当該原料の排出方向に沿う方向
における円振動を付与し、該原料を転動塊成化しミニペ
レットを得る第2の工程とからなる原料の造粒方法。
1. A first step of adding a necessary amount of water for granulation of the raw material, which is determined according to the raw material, and stirring and mixing the raw material, and a raw material moistened by the stirring and mixing in the first step. A method of granulating a raw material, which comprises a second step of introducing the raw material into a flat bottom container, applying circular vibration in a direction along the discharge direction of the raw material, and rolling agglomerating the raw material to obtain mini-pellets.
【請求項2】 前記原料がDL式焼結機に供給する焼結
原料であり、平板状底面容器内の原料層厚を15mm以下と
する状態で、当該原料の排出方向に沿う方向における振
幅10〜30mmの円振動を 4秒以上付与する請求項1記載の
原料の造粒方法。
2. The raw material is a sintering raw material supplied to a DL type sintering machine, and an amplitude of 10 in a direction along the discharge direction of the raw material in a state where the raw material layer thickness in the flat bottom container is 15 mm or less. The method for granulating a raw material according to claim 1, wherein a circular vibration of -30 mm is applied for 4 seconds or more.
【請求項3】 前記原料が粒径63μm 未満の粒子を60重
量%以上含有する微粉鉄鉱石のみである請求項2記載の
原料の造粒方法。
3. The method for granulating a raw material according to claim 2, wherein the raw material is only fine iron ore containing 60% by weight or more of particles having a particle size of less than 63 μm.
【請求項4】 前記添加水分量が、原料に応じて定まる
当該原料の造粒による粒径2 〜10mmのものの収率を60重
量%とするに必要な水分量から、当該原料の保有水分量
を差し引いた不足水分量である請求項1〜3のいずれか
に記載の原料の造粒方法。
4. The amount of water added to the raw material is determined from the amount of water necessary for adjusting the yield of the product having a particle size of 2 to 10 mm by granulation of the raw material, which is determined depending on the raw material, to 60% by weight. 4. The method of granulating a raw material according to claim 1, wherein the water content is the amount of water deficit less than.
【請求項5】 原料に応じて定まる当該原料の造粒に必
要な水分量を添加し、該原料を攪拌混合する攪拌混合機
と、攪拌混合機による攪拌混合により湿潤化された原料
を平板状底面容器に導入し、当該原料の排出方向に沿う
方向における円振動を付与し、該原料を転動塊成化しミ
ニペレットを得る振動造粒機とを有して構成される原料
の造粒装置。
5. A tabular mixture of a stirring mixer for adding the amount of water necessary for granulating the raw material, which is determined according to the raw material, and stirring and mixing the raw material, and the raw material moistened by stirring and mixing with the stirring mixer. A raw material granulating apparatus configured to have a vibrating granulator that is introduced into a bottom container and is subjected to circular vibration in a direction along the discharge direction of the raw material to roll-agglomerate the raw material to obtain mini-pellets .
【請求項6】 前記攪拌混合機が、 2本の互いに反対方
向に回転する螺旋羽根軸を容器内に並設し、容器の螺旋
羽根軸始端側には原料投入口を設け、螺旋羽根軸終端側
には原料排出口を設け、原料投入口の下流側には加湿装
置を設けて構成される請求項5記載の原料の造粒装置。
6. The agitator / mixer comprises two spiral blade shafts that rotate in mutually opposite directions side by side in a container, a raw material inlet is provided on the spiral blade shaft starting end side of the container, and the spiral blade shaft end is formed. The raw material granulating apparatus according to claim 5, wherein the raw material discharging port is provided on the side, and the humidifying device is provided on the downstream side of the raw material charging port.
【請求項7】 前記振動造粒機が、平板状底面容器を偏
心軸により支持し、容器内の原料に偏心軸の回転による
円振動を付与するように構成される請求項5記載の原料
の造粒装置。
7. The raw material according to claim 5, wherein the vibrating granulator is configured to support the flat bottom container by an eccentric shaft and impart circular vibration to the raw material in the container by rotation of the eccentric shaft. Granulator.
【請求項8】 請求項1〜4のいずれかに記載の原料の
造粒方法により振動造粒されたミニペットを、ドラムミ
キサを経由しないで直送し、焼結機のパレットへ装入す
る原料の焼結方法。
8. A mini-pet vibrated and granulated by the method for granulating a raw material according to any one of claims 1 to 4, which is directly fed without passing through a drum mixer and charged into a pallet of a sintering machine. Sintering method.
JP20728891A 1991-07-25 1991-07-25 Raw material granuation and its device Withdrawn JPH0523569A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP20728891A JPH0523569A (en) 1991-07-25 1991-07-25 Raw material granuation and its device

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP20728891A JPH0523569A (en) 1991-07-25 1991-07-25 Raw material granuation and its device

Publications (1)

Publication Number Publication Date
JPH0523569A true JPH0523569A (en) 1993-02-02

Family

ID=16537316

Family Applications (1)

Application Number Title Priority Date Filing Date
JP20728891A Withdrawn JPH0523569A (en) 1991-07-25 1991-07-25 Raw material granuation and its device

Country Status (1)

Country Link
JP (1) JPH0523569A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2008104963A (en) * 2006-10-26 2008-05-08 Ajinomoto Co Inc Method and device for controlling bulk density of flocculated granule

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2008104963A (en) * 2006-10-26 2008-05-08 Ajinomoto Co Inc Method and device for controlling bulk density of flocculated granule

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Effective date: 19981008