JPH05201839A - Hair rinse composition - Google Patents
Hair rinse compositionInfo
- Publication number
- JPH05201839A JPH05201839A JP3703892A JP3703892A JPH05201839A JP H05201839 A JPH05201839 A JP H05201839A JP 3703892 A JP3703892 A JP 3703892A JP 3703892 A JP3703892 A JP 3703892A JP H05201839 A JPH05201839 A JP H05201839A
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- Japan
- Prior art keywords
- hair
- group
- acid
- rinse composition
- composition
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Links
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- Cosmetics (AREA)
Abstract
Description
【０００１】[0001]
【産業上の利用分野】本発明は、毛髪に塗布し易く、且
つ毛髪に対し艶及び落ち着きを与え、風合を保つととも
に、自然に且つ均一に毛髪を着色する効果を有するヘア
ーリンス組成物に関する。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a hair rinse composition which is easy to apply to hair, imparts luster and calmness to the hair, maintains the texture, and has the effect of naturally and uniformly coloring the hair. .
【０００２】[0002]
【従来の技術及び発明が解決しようとする課題】従来、
洗髪処理した後の毛髪は艶及び風合いが悪くなる為に、
洗髪後の毛髪にコンディショニング効果を付与する為に
ヘアーリンスあるいはヘアーコンディショナーと呼ばれ
る毛髪処理剤を施す。それら処理剤は、塩化ステアリル
トリメチルアンモニウム等の第四級アンモニウム塩及び
高級アルコールを主成分としたものが一般的であり、更
にその効果を増強する為に種々の添加剤の配合が為され
ている。2. Description of the Related Art Conventionally, the problems to be solved by the invention
Since the hair after the hair washing treatment has poor gloss and texture,
A hair treatment agent called a hair conditioner or a hair conditioner is applied to give a conditioning effect to the hair after washing. These treating agents are generally those containing quaternary ammonium salts such as stearyltrimethylammonium chloride and higher alcohols as main components, and various additives are added to further enhance the effect. ..
【０００３】一方、これ毛髪処理組成物を利用する人の
なかには、高齢により毛髪が白髪化したり、あるいはブ
ラッシング、パーマ等により毛髪が損傷したりして、生
来の毛髪色が変化している場合がある。これらの人たち
が毛髪を本来の色に戻すには、酸性染料あるいは酸化染
料等の染毛剤により染毛するのが最も効果的である。し
かしながらそれらは操作が繁雑であり、又、急激に毛髪
色を変化させる為に第三者に染毛している事がすぐに判
ってしまう。更に、毛髪の成長に伴い施術している部分
と新生毛との間に境界が生じ、外観上好ましくない結果
となるという問題点があった。その為、それらの人たち
は、急激な色の変化を伴わずに自然に徐々に毛髪色が生
来の色に変化するものを望んでいた。更に、日常の生活
習慣となっている前述のヘアーリンス等の毛髪処理組成
物により、艶あるいは風合い等の高いコンディショニン
グ効果を毛髪に付与しながら、これらの事を行う事がで
きれば繁雑さが解消され、より有用であると考えられ
る。これらの事を達成する手段としては既に、特開昭４
７−２３５４３号公報および特開昭５９−２３１００９
号公報が提案されているが、これらは染料として酸化染
料を使用しており、感作性を有する人には使用できない
という問題がある。又、特開平１−１３２５１２号公報
では塩基性及び中性染料を使用したものが提案されてい
るが、充分な染色力は得られない。更に酸性染料を利用
したものとして、特開平１−３０８２１５号公報が提案
されているが、分岐鎖を有する第四級アンモニウム塩を
必須成分としており、ヘアーリンスとしての風合等の改
善には有効であろうが、アニオン性である酸性染料とカ
チオン性である第四級アンモニウムとが不溶性塩をつく
り、充分な染着力は得られず、安定性にも問題がある。
従って、充分に上述の効果を有する物は、現在まで得ら
れていないのが実情である。On the other hand, among those who use this hair treatment composition, there is a case where the natural hair color is changed due to graying of the hair due to aging, or damage to the hair due to brushing, perming or the like. is there. In order for these people to return their hair to the original color, it is most effective to dye the hair with a hair dye such as an acid dye or an oxidation dye. However, it is easy to see that they are complicated to operate and that they are dyed by a third party because the hair color changes abruptly. Further, there is a problem that a boundary is formed between the treated portion and new hair as the hair grows, resulting in an unfavorable appearance. As such, they wanted a gradual natural change in hair color without abrupt color change. Furthermore, if the hair treatment composition such as the above-described hair rinse, which has become a daily lifestyle, imparts a high conditioning effect such as luster or texture to the hair, it is possible to eliminate the complexity if it is possible to do these things. , Considered more useful. As means for achieving these things, Japanese Patent Laid-Open Publication No.
7-23543 and JP-A-59-231009.
Although the publications have been proposed, they use an oxidative dye as a dye and have a problem that they cannot be used by a person having a sensitizing property. Further, JP-A-1-132512 proposes a dye using a basic dye and a neutral dye, but a sufficient dyeing power cannot be obtained. Further, Japanese Patent Laid-Open No. 1-308215 has been proposed as a method using an acid dye, but it contains a quaternary ammonium salt having a branched chain as an essential component and is effective for improving the texture as a hair rinse. However, an acidic dye which is anionic and a quaternary ammonium which is cationic form an insoluble salt, so that sufficient dyeing power cannot be obtained and there is a problem in stability.
Therefore, it is the actual situation that a product having the above-mentioned effect is not obtained until now.
【０００４】即ち、本発明は、毛髪に塗布し易く、且つ
毛髪に対し艶及び落ち着きを与え風合いを保つととも
に、白髪の人においては白髪を均一に黒髪化して白髪を
目立たなくするといった、自然に且つ均一に毛髪を着色
する事ができるヘアーリンス組成物を提供する事を目的
としている。That is, according to the present invention, it is easy to apply to hair, and it gives gloss and calmness to the hair to maintain the texture, and in the case of a person with gray hair, the gray hair is uniformly blackened to make the gray hair inconspicuous. Moreover, it is an object of the present invention to provide a hair rinse composition capable of uniformly coloring hair.
【０００５】[0005]
【課題を解決するための手段】上記の目的を達成する本
発明のヘアーリンス組成物は、次のような構成をとって
いる。即ち、（Ａ）下記一般式（１）The hair rinse composition of the present invention which achieves the above object has the following constitution. That is, (A) the following general formula (1)
【化２】 ［式中、Ｒ1 は水素原子、メチル基またはメトキシ基、
Ｒ2 は−ＣＨ2 ＯＨ基、−ＣＨ2 ＣＨ2 ＯＨ基、−ＣＨ
（ＣＨ3 ）ＯＨ基、−ＣＨ2 ＣＨ2 ＣＨ2 ＯＨ基−Ｃ
（ＣＨ3 ）2 ＯＨ基、−ＣＨ2 ＣＨ（ＣＨ3 ）ＯＨ基、
−ＣＨ（ＣＨ3 ）ＣＨ2 ＯＨ基、−ＣＨ＝ＣＨＣＨ2 基
または−ＯＣＨ2 ＣＨ2 ＯＨ基を表す。］の郡から選ば
れる芳香族アルコールの一種または二種以上と、（Ｂ）
直鎖又は分岐鎖を有した脂肪族炭化水素又は一般式
（２）Ｒ−ＯＨ（Ｒは炭素数１２〜２４の直鎖又は分岐
鎖を有した脂肪族炭化水素）で表せる脂肪族アルコール
の郡から選ばれる成分の一種又は二種以上と、（Ｃ）キ
サンタンガムまたは／およびヒドロキシエチルセルロー
スと、（Ｄ）平均分子量２０，０００〜８００，０００
のポリエチレングリコールと、（Ｅ）酸性染料と、
（Ｆ）酸を含有し、ｐＨが２．０〜５．５である事を特
徴としたヘアーリンス組成物である。[Chemical 2] [Wherein R 1 is a hydrogen atom, a methyl group or a methoxy group,
R 2 is a —CH 2 OH group, a —CH 2 CH 2 OH group, a —CH
(CH 3) OH group, -CH 2 CH 2 CH 2 OH group -C
(CH 3) 2 OH group, -CH 2 CH (CH 3) OH group,
It represents a -CH (CH 3) CH 2 OH group, -CH = CHCH 2 group or -OCH 2 CH 2 OH group. ] One or more aromatic alcohols selected from the group of
A group of aliphatic hydrocarbons having a straight chain or a branched chain or an aliphatic alcohol represented by the general formula (2) R-OH (R is an aliphatic hydrocarbon having a straight chain or a branched chain having 12 to 24 carbon atoms). One or more components selected from the following, (C) xanthan gum and / or hydroxyethyl cellulose, and (D) average molecular weight of 20,000 to 800,000.
Polyethylene glycol of (E) and acid dye,
(F) A hair rinse composition containing an acid and having a pH of 2.0 to 5.5.
【０００６】本発明における前記一般式（１）で表され
る芳香族アルコールとしては、例えばベンジルアルコー
ル、フェネチルアルコール、γ−フェニルプロピルアル
コール、桂皮アルコール、アニスアルコール、Ｐ−メチ
ルベンジルアルコール、α−α−ジメチルフェネチルア
ルコール、α−フェニルエタノール、フェノキシエタノ
ールなどがあげらる。Examples of the aromatic alcohol represented by the general formula (1) in the present invention include benzyl alcohol, phenethyl alcohol, γ-phenylpropyl alcohol, cinnamic alcohol, anis alcohol, P-methylbenzyl alcohol and α-α. -Dimethylphenethyl alcohol, α-phenylethanol, phenoxyethanol and the like.
【０００７】本発明のヘアーリンス組成物には、これら
芳香族アルコールの一種または二種以上を組成物総量を
基準として、好ましくは０．５〜１５．０重量％（以下
ｗｔ％と略記する）が配合される。配合量が０．５ｗｔ
％未満では、毛髪を着色するのに充分な効果が得られに
くく、１５ｗｔ％を超えると、べたつき及び強烈な芳香
族アルコール臭が生じ、官能上好ましくない傾向とな
る。In the hair rinse composition of the present invention, one or more of these aromatic alcohols is preferably 0.5 to 15.0% by weight (hereinafter abbreviated as wt%) based on the total amount of the composition. Is blended. 0.5 wt%
If it is less than 0.1%, it is difficult to obtain a sufficient effect for coloring hair, and if it exceeds 15% by weight, stickiness and a strong aromatic alcohol odor occur, which tends to be sensory unfavorable.
【０００８】本発明における脂肪族炭化水素又は一般式
（２）の脂肪族アルコールとしてはワセリン、流動パラ
フィン、流動イソパラフィン、スクワラン、スクワレ
ン、ラウリルアルコール、２−ヘキシルデカノール、オ
レイルアルコール、２−オクチルドデカノール、イソス
テアリルアルコール等がある。As the aliphatic hydrocarbon or the aliphatic alcohol of the general formula (2) in the present invention, petrolatum, liquid paraffin, liquid isoparaffin, squalane, squalene, lauryl alcohol, 2-hexyldecanol, oleyl alcohol, 2-octyldodecanol, Isostearyl alcohol and the like.
【０００９】本発明のヘアーリンス組成物には、これら
成分の一種または二種以上を組成物総量の好ましくは、
０．１〜５．０ｗｔ％配合される。０．１ｗｔ％未満で
は、毛髪に艶及び落ち着きをを与え、風合いを保つのに
充分な効果が得られにくく、５．０ｗｔ％を超えると、
べたつきを生じ官能上好ましくない傾向にあるととも
に、組成物の安定性が維持しにくくなる。In the hair rinse composition of the present invention, one or more of these components are preferably contained in the total amount of the composition,
0.1 to 5.0 wt% is blended. If it is less than 0.1 wt%, it is difficult to obtain sufficient effect to give the hair gloss and calmness and keep the texture. If it exceeds 5.0 wt%,
It tends to be sticky and is not functionally preferable, and it becomes difficult to maintain the stability of the composition.
【００１０】本発明における水溶性高分子化合物である
キサンタンガムおよびヒドロキシエチルセルロースは、
毛髪に塗布しやすくするとともに系を安定化させる事を
目的として配合されるものであり、たとえば平均重合度
４００〜１０００のヒドロキシエチルセルロース、米国
ＫＥＬＣＯ社からケルトロールという商品名で発売され
ているようなＤ−グルコース、Ｄ−マンノース、Ｄ−グ
ルクロン酸から構成される多糖類であるキサンタンガム
等がある。Xanthan gum and hydroxyethyl cellulose, which are water-soluble polymer compounds in the present invention, are
It is blended for the purpose of making it easy to apply to hair and stabilizing the system. For example, hydroxyethyl cellulose having an average degree of polymerization of 400 to 1000, such as that sold by KELCO, USA under the trade name of keltrol. There is xanthan gum, which is a polysaccharide composed of D-glucose, D-mannose, and D-glucuronic acid.
【００１１】本発明のヘアーリンス組成物には、これら
高分子化合物を単独または両方が配合されるが、組成物
の外観、塗布しやすさの点で両者を含有した方がより好
ましい。更に、これらは、組成物総量に対し、好ましく
は０．２〜４．０ｗｔ％が配合される。０．２ｗｔ％未
満では系が不安定となり経時で分離するとともに液だれ
がして毛髪へ塗布しずらく、４．０ｗｔ％を超えるとべ
たつきが生じ、組成物の粘度が高くなり、やはり塗布し
づらくなる傾向にある。The hair rinse composition of the present invention may contain one or both of these polymer compounds, but it is more preferable to contain both of them in terms of appearance of the composition and ease of application. Further, these are preferably blended in an amount of 0.2 to 4.0 wt% with respect to the total amount of the composition. If it is less than 0.2 wt%, the system becomes unstable, and it separates over time and it is difficult to apply it to the hair. If it exceeds 4.0 wt%, stickiness occurs and the viscosity of the composition increases, so It tends to be difficult.
【００１２】本発明におけるポリエチレングリコール
は、塗布時にすべりを与える事により、毛髪に塗布し易
くするとともに、毛髪上に組成物が均一に塗布される為
に毛髪をムラなく均一に着色する事を目的として配合さ
れるものであり、その平均分子量は、２０，０００〜８
００，０００である。平均分子量が２０，０００未満で
は、効果がなく、８００，０００を超えるとべたつきを
生じ、官能上、使用に耐え難い。又、その配合量は組成
物総量に対し、０．００１ｗｔ％〜０．１ｗｔ％が好ま
しく、０．００１ｗｔ％未満ではその効果がなく、０．
１ｗｔ％を超えるとべたつきを生じ、官能上好ましくな
い傾向にある。The polyethylene glycol in the present invention is intended to make it easy to apply to hair by giving a slip during application, and to evenly color the hair because the composition is applied evenly on the hair. The average molecular weight is 20,000 to 8
It is 0,000. If the average molecular weight is less than 20,000, there is no effect, and if it exceeds 800,000, stickiness occurs, and it is organoleptically difficult to use. Further, the blending amount thereof is preferably 0.001 wt% to 0.1 wt% with respect to the total amount of the composition, and if it is less than 0.001 wt%, the effect is not obtained and
If it exceeds 1 wt%, stickiness is generated, and it tends to be sensory unfavorable.
【００１３】本発明における酸性染料は主としてタール
系色素であり、化学構造から大別すると、ニトロ染料、
アゾ染料、ニトロソ染料、トリフェニルメタン染料、キ
サンテン染料、キノリン染料、アントラキノン染料、イ
ンジゴイド染料などがあげられる。The acid dye in the present invention is mainly a tar-based dye, and is roughly classified into a nitro dye and a chemical structure.
Examples include azo dyes, nitroso dyes, triphenylmethane dyes, xanthene dyes, quinoline dyes, anthraquinone dyes and indigoid dyes.
【００１４】本発明のヘアーリンス組成物には、これら
酸性染料の一種または二種以上を組成物総量に対し、好
ましくは０．００５〜０．２ｗｔ％が配合される。The hair rinse composition of the present invention contains one or more of these acidic dyes, preferably 0.005 to 0.2 wt% based on the total amount of the composition.
【００１５】本発明における酸としては、クエン酸、サ
リチル酸、酢酸、乳酸、プロピオン酸、酒石酸、リン
酸、塩酸等があげられ、その配合量は組成物のｐＨが
２．０〜５．５に調整するにたる必要量である。ｐＨが
２．０より低いと、安定性上問題があり、ｐＨが５．５
より高いと毛髪を着色するに充分な効果が得られない。Examples of the acid in the present invention include citric acid, salicylic acid, acetic acid, lactic acid, propionic acid, tartaric acid, phosphoric acid, hydrochloric acid and the like, and the compounding amount thereof is such that the pH of the composition is 2.0 to 5.5. It is a necessary amount to adjust. If the pH is lower than 2.0, there is a problem in stability, and the pH is 5.5.
If it is higher, sufficient effect for coloring hair cannot be obtained.
【００１６】また、本発明のヘアーリンス組成物は、上
述した成分を必須成分とするが、当該組成物には、本発
明の目的を達成する範囲で他の成分を適宜配合すること
ができる。Further, the hair rinse composition of the present invention contains the above-mentioned components as essential components, but other components can be appropriately added to the composition within a range that achieves the object of the present invention.
【００１７】即ち、イソプロピルミリステート、イソプ
ロピルパルミテート等のエステル油ツバキ油、オリーブ
油、アボガド油、ホホバ油等の植物油、ポリオキシエチ
レン硬化ヒマシ油、ポリオキシエチレンアルキルエーテ
ル、ポリオキシエチレンソルビタンモノラウレート等の
非イオン界面活性剤、プロピレングリコール、ジプロピ
レングリコール、１．３−ブチレングリコール、グリセ
リン等の保湿剤、防腐剤、キレート剤、香料などがあげ
られ、これらの一種または二種以上を配合する事ができ
る。That is, ester oil such as isopropyl myristate and isopropyl palmitate, camellia oil, vegetable oil such as olive oil, avocado oil, jojoba oil, polyoxyethylene hydrogenated castor oil, polyoxyethylene alkyl ether, and polyoxyethylene sorbitan monolaurate. Nonionic surfactants such as propylene glycol, dipropylene glycol, 1.3-butylene glycol, humectants such as glycerin, preservatives, chelating agents, fragrances, etc., and one or more of these are blended. I can do things.
【００１８】[0018]
【実施例】次に、本発明を実施例をもって詳細に説明す
るが、本発明はこれにより限定されるものではない。
尚、実施例および比較例中の数値は重量％である。ここ
で、実施例の説明に先立ち、各例において採用した試験
方法について説明する。EXAMPLES Next, the present invention will be described in detail with reference to examples, but the present invention is not limited thereto.
The numerical values in Examples and Comparative Examples are% by weight. Here, prior to the description of the examples, the test method adopted in each example will be described.
【００１９】（１）毛髪着色効果試験 （イ）サンプル試験毛 毛束（白色毛髪の束）５ｇを市販のシャンプーにて２分
間洗浄し、１分間温湯にてすすいだ後、試験試料ヘアー
リンス２ｇを塗布し、３分放置後、水洗いし、風乾し
た。これを１サイクルとし、５サイクル行った。 （ロ）評価法 試験試料リンス処理前及び処理後のサンプル試験毛束に
ついて、高速色彩計（村上色材（株）製ＣＭＳ−１００
０型）を用いて測色を行い、各サンプル試験毛のＸ，
Ｙ，Ｚ値をＨｕｎｔｅｒのＬ，ａ，ｂ表色系へ変換し、
下記の式により処理前と処理後の色差（△Ｅ）を求め、
その数値から、下記基準により評価した。△Ｅが大きい
程、毛髪が着色した事になる。 △Ｅ＝｛（Ｌ−Ｌ0 ）2 ＋（ａ−ａ0 ）2 ＋（ｂ−
ｂ0 ）2 ｝1/2 Ｌ0 ，ａ0 ，ｂ0 ：処理前のサンプル毛のＬ，ａ，ｂ値 Ｌ，ａ，ｂ ：処理後のサンプル毛のＬ，ａ，ｂ値 ×；△Ｅ値が５以下 「ほとんど着色効果がない」 △；△Ｅ値が６〜１５ 「やや着色効果がある。」 ○；△Ｅ値が１６〜２５ 「着色効果がある。」 ◎；△Ｅ値が２５以上 「非常に着色効果がある。(1) Hair coloring effect test (a) Sample test hair 5 g of a hair bundle (a bundle of white hair) was washed with a commercial shampoo for 2 minutes, rinsed with warm water for 1 minute, and then a test sample hair rinse 2 g Was applied, left for 3 minutes, washed with water, and air dried. This was set as one cycle, and 5 cycles were performed. (B) Evaluation method For the test sample hair bundle before and after the test sample rinse treatment, a high-speed colorimeter (CMS-100 manufactured by Murakami Colorant Co., Ltd.)
(0 type) is used to measure the color, and X,
Convert Y and Z values to Hunter's L, a, b color system,
Calculate the color difference (△ E) before and after processing by the following formula,
From the numerical value, the following criteria were evaluated. The larger the ΔE, the more colored the hair. ΔE = {(L−L 0 ) 2 + (a−a 0 ) 2 + (b−
b 0 ) 2 } 1/2 L 0 , a 0 , b 0 : L, a, b values of sample hair before treatment L, a, b: L, a, b values of sample hair after treatment ×; Δ E value is 5 or less "There is almost no coloring effect"Δ; ΔE value is 6 to 15 "There is a slight coloring effect"○; ΔE value is 16 to 25 "There is a coloring effect"◎; ΔE value Is 25 or more "It has a very coloring effect.
【００２０】（２）着色効果実用テスト 各例におけるヘアーリンスを白髪交じりのパネラー２０
名に５回使用してもらい、着色効果を、白髪隠し効果に
より下記基準で評価を行った。 ◎；自然に均一に白髪が目立たなくなったと答えた人が
１８人以上の場合 ○；自然に均一に白髪が目立たなくなったと答えた人が
１４〜１７人の場合 △；自然に均一に白髪が目立たなくなったと答えた人が
８〜１３人の場合 ×；自然に均一に白髪が目立たなくなったと答えた人が
７人以下の場合(2) Practical test for coloring effect In each example, the hair rinse was performed using a panelist 20 with white hair.
The name was used 5 times, and the coloring effect was evaluated based on the gray hair hiding effect according to the following criteria. ⊚: 18 or more people answered that the gray hair naturally disappeared uniformly ○: 14 to 17 people answered that the gray hair naturally disappeared △: naturally evenly noticeable 8 to 13 people answered that they lost their hair; 7 or less people answered that the gray hair naturally disappeared uniformly
【００２１】（３）毛髪への塗布し易さ及びヘアーリン
ス後の仕上がり効果（艶、落ち着き、風合） 各例におけるヘアーリンス後の仕上がりについて
「艶」、「落ち着き」「風合い」を２０名のパネラ−に
より官能的に比較し、下記基準で評価を行った。 ◎；良いまたはあると答えた人が１８人以上の場合 ○；良いまたはあると答えた人が１４〜１７人の場合 △；良いまたはあると答えた人が８〜１３人の場合 ×；良いまたはあると答えた人が７人以下の場合(3) Ease of application to hair and finishing effect after hair rinsing (luster, calm, and texture) In each case, the finish after hair rinsing was 20 for "luster", "calm" and "texture". Sensory comparison was performed by the panel of No. 1 and evaluated according to the following criteria. ⊚: 18 or more people answered good or yes ○: 14 to 17 people replied good or there △: 8 to 13 people replied good or yes ×; good Or if there are less than 7 people
【００２２】実施例１〜７、比較例１〜６ 表１及び表２に示す配合組成のヘアーリンス組成物を通
常の方法で調製し、前記諸試験を行い表３にその結果を
示した。Examples 1 to 7 and Comparative Examples 1 to 6 Hair rinse compositions having the formulations shown in Tables 1 and 2 were prepared by the usual method, and the above-mentioned various tests were conducted. The results are shown in Table 3.
【００２３】[0023]
【表１】 [Table 1]
【００２４】[0024]
【表２】 [Table 2]
【００２５】[0025]
【表３】 [Table 3]
【００２６】[0026]
【発明の効果】以上記載のごとく、本発明は、毛髪に塗
布し易く、且つ毛髪に対し艶と落ち着きを与え風合いを
保つとともに、自然に且つ均一に毛髪を着色する効果に
優れたヘアーリンス組成物を提供する事は明らかであ
る。As described above, the present invention is a hair rinse composition which is easy to apply to hair and has an excellent effect of coloring hair naturally and evenly while giving gloss and calmness to hair and maintaining texture. It is clear to provide the thing.
Claims (1)
２．０〜５．５である事を特徴とするヘアーリンス組成
物。 （Ａ）下記一般式（１） 【化１】 ［式中、Ｒ1 は水素原子、メチル基またはメトキシ基、
Ｒ2 は−ＣＨ2 ＯＨ基、−ＣＨ2 ＣＨ2 ＯＨ基、−ＣＨ
（ＣＨ3 ）ＯＨ基、−ＣＨ2 ＣＨ2 ＣＨ2 ＯＨ基、−Ｃ
（ＣＨ3 ）2 ＯＨ基、−ＣＨ2 ＣＨ（ＣＨ3 ）ＯＨ基、
−ＣＨ（ＣＨ3 ）ＣＨ2 ＯＨ基、−ＣＨ＝ＣＨＣＨ2 Ｏ
Ｈ基または−ＯＣＨ2 ＣＨ2 ＯＨ基を表す。］の郡から
選ばれる芳香族アルコールの一種または二種以上 （Ｂ）直鎖又は分岐鎖を有した脂肪族炭化水素又は一般
式（２）Ｒ−ＯＨ（Ｒは炭素数１２〜２４の直鎖又は分
岐鎖を有した脂肪族炭化水素）で表せる脂肪族アルコー
ルの郡から選ばれる成分の一種又は二種以上 （Ｃ）キサンタンガムおよび／またはヒドロキシエチル
セルロース （Ｄ）平均分子量２０，０００〜８００，０００のポリ
エチレングリコール （Ｅ）酸性染料 （Ｆ）酸1. A hair rinse composition containing the following (A) to (F) and having a pH of 2.0 to 5.5. (A) The following general formula (1): [Wherein R 1 is a hydrogen atom, a methyl group or a methoxy group,
R 2 is a —CH 2 OH group, a —CH 2 CH 2 OH group, a —CH
(CH 3) OH group, -CH 2 CH 2 CH 2 OH groups, -C
(CH 3) 2 OH group, -CH 2 CH (CH 3) OH group,
-CH (CH 3) CH 2 OH group, -CH = CHCH 2 O
It represents H group or -OCH 2 CH 2 OH group. ] One or two or more aromatic alcohols selected from the group (B) Aliphatic hydrocarbon having a straight chain or a branched chain or a general formula (2) R-OH (R is a straight chain having 12 to 24 carbon atoms) Or one or more components selected from the group of aliphatic alcohols represented by branched aliphatic hydrocarbons) (C) xanthan gum and / or hydroxyethyl cellulose (D) having an average molecular weight of 20,000 to 800,000 Polyethylene glycol (E) Acid dye (F) Acid
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP4037038A JP3009959B2 (en) | 1992-01-27 | 1992-01-27 | Hair rinse composition |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP4037038A JP3009959B2 (en) | 1992-01-27 | 1992-01-27 | Hair rinse composition |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH05201839A true JPH05201839A (en) | 1993-08-10 |
| JP3009959B2 JP3009959B2 (en) | 2000-02-14 |
Family
ID=12486450
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP4037038A Expired - Fee Related JP3009959B2 (en) | 1992-01-27 | 1992-01-27 | Hair rinse composition |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP3009959B2 (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5997851A (en) * | 1994-02-02 | 1999-12-07 | The Procter & Gamble Company | Hair care compositions containing low melting point fatty alcohol and ethylene oxide/propylene oxide polymer |
| JP2002205927A (en) * | 2001-01-05 | 2002-07-23 | Kao Corp | Semipermanent hair dye composition |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106456487B (en) | 2014-06-17 | 2020-01-31 | 宝洁公司 | Composition for reducing hair frizz |
| WO2016090206A1 (en) | 2014-12-05 | 2016-06-09 | The Procter & Gamble Company | Composition for hair frizz reduction |
| US10660835B2 (en) | 2015-04-02 | 2020-05-26 | The Procter And Gamble Company | Method for hair frizz reduction |
| US10632054B2 (en) | 2015-04-02 | 2020-04-28 | The Procter And Gamble Company | Method for hair frizz reduction |
| JP6657403B2 (en) | 2015-12-04 | 2020-03-04 | ザ プロクター アンド ギャンブル カンパニーＴｈｅ Ｐｒｏｃｔｅｒ ＆ Ｇａｍｂｌｅ Ｃｏｍｐａｎｙ | Composition for reducing curly hair |
| US10561591B2 (en) | 2015-12-04 | 2020-02-18 | The Procter And Gamble Company | Hair care regimen using compositions comprising moisture control materials |
| EP3435964B1 (en) | 2016-04-01 | 2024-05-15 | The Procter & Gamble Company | Composition for fast dry of hair |
| US10980723B2 (en) | 2017-04-10 | 2021-04-20 | The Procter And Gamble Company | Non-aqueous composition for hair frizz reduction |
-
1992
- 1992-01-27 JP JP4037038A patent/JP3009959B2/en not_active Expired - Fee Related
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5997851A (en) * | 1994-02-02 | 1999-12-07 | The Procter & Gamble Company | Hair care compositions containing low melting point fatty alcohol and ethylene oxide/propylene oxide polymer |
| JP2002205927A (en) * | 2001-01-05 | 2002-07-23 | Kao Corp | Semipermanent hair dye composition |
Also Published As
| Publication number | Publication date |
|---|---|
| JP3009959B2 (en) | 2000-02-14 |
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