JP3009959B2 - Hair rinse composition - Google Patents
Hair rinse compositionInfo
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- JP3009959B2 JP3009959B2 JP4037038A JP3703892A JP3009959B2 JP 3009959 B2 JP3009959 B2 JP 3009959B2 JP 4037038 A JP4037038 A JP 4037038A JP 3703892 A JP3703892 A JP 3703892A JP 3009959 B2 JP3009959 B2 JP 3009959B2
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- hair
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Description
【０００１】[0001]
【産業上の利用分野】本発明は、毛髪に塗布し易く、且
つ毛髪に対し艶及び落ち着きを与え、風合を保つととも
に、自然に且つ均一に毛髪を着色する効果を有するヘア
ーリンス組成物に関する。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a hair rinse composition which is easy to apply to hair, imparts luster and calm to hair, maintains a feeling of hand, and has an effect of coloring hair naturally and uniformly. .
【０００２】[0002]
【従来の技術及び発明が解決しようとする課題】従来、
洗髪処理した後の毛髪は艶及び風合いが悪くなる為に、
洗髪後の毛髪にコンディショニング効果を付与する為に
ヘアーリンスあるいはヘアーコンディショナーと呼ばれ
る毛髪処理剤を施す。それら処理剤は、塩化ステアリル
トリメチルアンモニウム等の第四級アンモニウム塩及び
高級アルコールを主成分としたものが一般的であり、更
にその効果を増強する為に種々の添加剤の配合が為され
ている。2. Description of the Related Art
Because the hair after shampooing treatment has poor gloss and texture,
A hair treatment agent called a hair rinse or a hair conditioner is applied to impart a conditioning effect to the hair after washing. These treating agents are generally based on quaternary ammonium salts such as stearyltrimethylammonium chloride and higher alcohols, and various additives have been added to enhance their effects. .
【０００３】一方、これ毛髪処理組成物を利用する人の
なかには、高齢により毛髪が白髪化したり、あるいはブ
ラッシング、パーマ等により毛髪が損傷したりして、生
来の毛髪色が変化している場合がある。これらの人たち
が毛髪を本来の色に戻すには、酸性染料あるいは酸化染
料等の染毛剤により染毛するのが最も効果的である。し
かしながらそれらは操作が繁雑であり、又、急激に毛髪
色を変化させる為に第三者に染毛している事がすぐに判
ってしまう。更に、毛髪の成長に伴い施術している部分
と新生毛との間に境界が生じ、外観上好ましくない結果
となるという問題点があった。その為、それらの人たち
は、急激な色の変化を伴わずに自然に徐々に毛髪色が生
来の色に変化するものを望んでいた。更に、日常の生活
習慣となっている前述のヘアーリンス等の毛髪処理組成
物により、艶あるいは風合い等の高いコンディショニン
グ効果を毛髪に付与しながら、これらの事を行う事がで
きれば繁雑さが解消され、より有用であると考えられ
る。これらの事を達成する手段としては既に、特開昭４
７−２３５４３号公報および特開昭５９−２３１００９
号公報が提案されているが、これらは染料として酸化染
料を使用しており、感作性を有する人には使用できない
という問題がある。又、特開平１−１３２５１２号公報
では塩基性及び中性染料を使用したものが提案されてい
るが、充分な染色力は得られない。更に酸性染料を利用
したものとして、特開平１−３０８２１５号公報が提案
されているが、分岐鎖を有する第四級アンモニウム塩を
必須成分としており、ヘアーリンスとしての風合等の改
善には有効であろうが、アニオン性である酸性染料とカ
チオン性である第四級アンモニウムとが不溶性塩をつく
り、充分な染着力は得られず、安定性にも問題がある。
従って、充分に上述の効果を有する物は、現在まで得ら
れていないのが実情である。[0003] On the other hand, some people who use the hair treatment composition may change their natural hair color due to graying of the hair due to aging or damage to the hair due to brushing, perm, etc. is there. In order for these people to return the hair to its original color, it is most effective to dye the hair with a hair dye such as an acid dye or an oxidation dye. However, they are complicated to operate, and it is immediately apparent that a third party has dyed the hair in order to rapidly change the hair color. Further, there is a problem in that a boundary is formed between the part to be treated and the new hair as the hair grows, which results in an undesirable result in appearance. As such, they wanted a hair color that gradually changed naturally to a natural color without a sudden change in color. Furthermore, the hair treatment composition such as the above-mentioned hair rinse, which has become a daily life habit, can impart complexity to the hair while imparting a high conditioning effect such as gloss or texture to the hair, thereby eliminating complexity. , Would be more useful. As means for achieving these things, Japanese Unexamined Patent Publication No.
7-23543 and JP-A-59-231009.
However, there is a problem that these dyes use an oxidation dye as a dye and cannot be used by persons having sensitization. Japanese Patent Application Laid-Open No. 1-132512 proposes a device using a basic and neutral dye, but does not provide sufficient dyeing power. Further, Japanese Patent Application Laid-Open No. Hei 1-308215 has been proposed as one utilizing an acidic dye, but a quaternary ammonium salt having a branched chain is an essential component and is effective for improving the feeling as a hair rinse. However, an anionic acid dye and a cationic quaternary ammonium form an insoluble salt, so that sufficient dyeing power cannot be obtained and there is a problem in stability.
Therefore, a substance having the above-mentioned effects has not been obtained until now.
【０００４】即ち、本発明は、毛髪に塗布し易く、且つ
毛髪に対し艶及び落ち着きを与え風合いを保つととも
に、白髪の人においては白髪を均一に黒髪化して白髪を
目立たなくするといった、自然に且つ均一に毛髪を着色
する事ができるヘアーリンス組成物を提供する事を目的
としている。[0004] That is, the present invention is easy to apply to the hair, gives the hair a luster and calmness, keeps the texture, and, in the case of gray hair, makes the gray hair evenly black and makes the gray hair inconspicuous. Another object of the present invention is to provide a hair rinse composition that can uniformly color hair.
【０００５】[0005]
【課題を解決するための手段】上記の目的を達成する本
発明のヘアーリンス組成物は、次のような構成をとって
いる。即ち、 （Ａ）下記一般式（１）The hair rinse composition of the present invention which achieves the above object has the following constitution. That is, (A) the following general formula (1)
【化２】 ［式中、Ｒ1 は水素原子、メチル基またはメトキシ基、
Ｒ2 は−ＣＨ2 ＯＨ基、−ＣＨ2 ＣＨ2 ＯＨ基、−ＣＨ
（ＣＨ3 ）ＯＨ基、−ＣＨ2 ＣＨ2 ＣＨ2 ＯＨ基、−Ｃ
（ＣＨ3 ）2 ＯＨ基、−ＣＨ2 ＣＨ（ＣＨ3 ）ＯＨ基、
−ＣＨ（ＣＨ3 ）ＣＨ2 ＯＨ基、−ＣＨ＝ＣＨＣＨ2 Ｏ
Ｈ基または−ＯＣＨ2 ＣＨ2 ＯＨ基を表す。］で表され
る群より選ばれる芳香族アルコールの一種または二種以
上と、 （Ｂ）直鎖又は分岐鎖を有した脂肪族炭化水素又は一般
式（２）Ｒ−ＯＨ（Ｒは炭素数１２〜２４の直鎖又は分
岐鎖を有した脂肪族炭化水素）で表せる脂肪族アルコー
ルの群から選ばれる化合物の一種または二種以上と、 （Ｃ）キサンタンガムおよび／またはヒドロキシエチル
セルロースと、 （Ｄ）平均分子量２０，０００〜８００，０００のポリ
エチレングリコールと、 （Ｅ）酸性染料と、 （Ｆ）酸を含有し、ｐＨが２．０〜５．５である事を特
徴としたヘアーリンス組成物である。Embedded image [Wherein, R 1 represents a hydrogen atom, a methyl group or a methoxy group,
R 2 represents —CH 2 OH group, —CH 2 CH 2 OH group, —CH
(CH 3 ) OH group, —CH 2 CH 2 CH 2 OH group , —C
A (CH 3 ) 2 OH group, a —CH 2 CH (CH 3 ) OH group,
-CH (CH 3) CH 2 OH group, -CH = CHCH 2 O
Represents an H group or an —OCH 2 CH 2 OH group. Represented by]
One or two or more aromatic alcohols selected from the group consisting of: (B) a linear or branched aliphatic hydrocarbon or a general formula (2) R-OH (R is a straight-chain having 12 to 24 carbon atoms) and one or more compounds selected from the group consisting of aliphatic alcohols represented by having a chain or branched chain aliphatic hydrocarbon), and (C) xanthan gum and / or hydroxyethyl cellulose, (D) average molecular weight of 20,000 A hair rinse composition comprising polyethylene glycol of about 800,000, (E) an acid dye, and (F) an acid, and having a pH of 2.0 to 5.5.
【０００６】本発明における前記一般式（１）で表され
る芳香族アルコールとしては、例えばベンジルアルコー
ル、フェネチルアルコール、γ−フェニルプロピルアル
コール、桂皮アルコール、アニスアルコール、Ｐ−メチ
ルベンジルアルコール、α−α−ジメチルフェネチルア
ルコール、α−フェニルエタノール、フェノキシエタノ
ールなどがあげらる。The aromatic alcohol represented by the general formula (1) in the present invention includes, for example, benzyl alcohol, phenethyl alcohol, γ-phenylpropyl alcohol, cinnamon alcohol, anis alcohol, P-methylbenzyl alcohol, α-α -Dimethylphenethyl alcohol, α-phenylethanol, phenoxyethanol and the like.
【０００７】本発明のヘアーリンス組成物には、これら
芳香族アルコールの一種または二種以上を組成物総量を
基準として、好ましくは０．５〜１５．０重量％（以下
ｗｔ％と略記する）が配合される。配合量が０．５ｗｔ
％未満では、毛髪を着色するのに充分な効果が得られに
くく、１５ｗｔ％を超えると、べたつき及び強烈な芳香
族アルコール臭が生じ、官能上好ましくない傾向とな
る。The hair rinse composition of the present invention preferably contains one or more of these aromatic alcohols in an amount of 0.5 to 15.0% by weight (hereinafter abbreviated as wt%) based on the total amount of the composition. Is blended. 0.5wt
If it is less than 15%, it is difficult to obtain a sufficient effect for coloring hair, and if it exceeds 15% by weight, stickiness and intense aromatic alcohol odor are generated, which tends to be unfavorably functional.
【０００８】本発明における脂肪族炭化水素又は一般式
（２）の脂肪族アルコールとしてはワセリン、流動パラ
フィン、流動イソパラフィン、スクワラン、スクワレ
ン、ラウリルアルコール、２−ヘキシルデカノール、オ
レイルアルコール、２−オクチルドデカノール、イソス
テアリルアルコール等がある。The aliphatic hydrocarbon or the aliphatic alcohol of the general formula (2) according to the present invention includes petrolatum, liquid paraffin, liquid isoparaffin, squalane, squalene, lauryl alcohol, 2-hexyldecanol, oleyl alcohol, 2-octyldodecanol, Isostearyl alcohol and the like.
【０００９】本発明のヘアーリンス組成物には、これら
成分の一種または二種以上を組成物総量の好ましくは、
０．１〜５．０ｗｔ％配合される。０．１ｗｔ％未満で
は、毛髪に艶及び落ち着きをを与え、風合いを保つのに
充分な効果が得られにくく、５．０ｗｔ％を超えると、
べたつきを生じ官能上好ましくない傾向にあるととも
に、組成物の安定性が維持しにくくなる。The hair rinse composition of the present invention comprises one or more of these components, preferably in the total amount of the composition,
0.1 to 5.0 wt% is blended. If it is less than 0.1 wt%, it gives the hair gloss and calmness, and it is difficult to obtain a sufficient effect to maintain the texture, and if it exceeds 5.0 wt%,
The composition tends to be sticky and unfavorably functional, and it is difficult to maintain the stability of the composition.
【００１０】本発明における水溶性高分子化合物である
キサンタンガムおよびヒドロキシエチルセルロースは、
毛髪に塗布しやすくするとともに系を安定化させる事を
目的として配合されるものであり、たとえば平均重合度
４００〜１０００のヒドロキシエチルセルロース、米国
ＫＥＬＣＯ社からケルトロールという商品名で発売され
ているようなＤ−グルコース、Ｄ−マンノース、Ｄ−グ
ルクロン酸から構成される多糖類であるキサンタンガム
等がある。The water-soluble polymer compounds xanthan gum and hydroxyethyl cellulose in the present invention are:
It is formulated for the purpose of facilitating application to the hair and stabilizing the system. For example, hydroxyethylcellulose having an average degree of polymerization of 400 to 1000, such as that sold under the trade name Celtrol by KELCO, USA There are xanthan gum, which is a polysaccharide composed of D-glucose, D-mannose, and D-glucuronic acid.
【００１１】本発明のヘアーリンス組成物には、これら
高分子化合物を単独または両方が配合されるが、組成物
の外観、塗布しやすさの点で両者を含有した方がより好
ましい。更に、これらは、組成物総量に対し、好ましく
は０．２〜４．０ｗｔ％が配合される。０．２ｗｔ％未
満では系が不安定となり経時で分離するとともに液だれ
がして毛髪へ塗布しずらく、４．０ｗｔ％を超えるとべ
たつきが生じ、組成物の粘度が高くなり、やはり塗布し
づらくなる傾向にある。The hair rinse composition of the present invention contains one or both of these high molecular compounds, but it is more preferable to contain both in terms of the appearance and ease of application of the composition. Further, these are preferably blended in an amount of 0.2 to 4.0% by weight based on the total amount of the composition. If it is less than 0.2 wt%, the system becomes unstable and separates with the passage of time, and it drips and it is difficult to apply it to the hair. If it exceeds 4.0 wt%, it becomes sticky and the viscosity of the composition becomes high. It tends to be difficult.
【００１２】本発明におけるポリエチレングリコール
は、塗布時にすべりを与える事により、毛髪に塗布し易
くするとともに、毛髪上に組成物が均一に塗布される為
に毛髪をムラなく均一に着色する事を目的として配合さ
れるものであり、その平均分子量は、２０，０００〜８
００，０００である。平均分子量が２０，０００未満で
は、効果がなく、８００，０００を超えるとべたつきを
生じ、官能上、使用に耐え難い。又、その配合量は組成
物総量に対し、０．００１ｗｔ％〜０．１ｗｔ％が好ま
しく、０．００１ｗｔ％未満ではその効果がなく、０．
１ｗｔ％を超えるとべたつきを生じ、官能上好ましくな
い傾向にある。[0012] The polyethylene glycol in the present invention is intended to make it easy to apply to hair by giving a slip at the time of application, and to color the hair evenly and uniformly because the composition is applied uniformly on the hair. The average molecular weight is from 20,000 to 8
00,000. If the average molecular weight is less than 20,000, there is no effect. The compounding amount is preferably 0.001 wt% to 0.1 wt% with respect to the total amount of the composition.
If it exceeds 1% by weight, stickiness occurs, and it tends to be unfavorable in terms of functionality.
【００１３】本発明における酸性染料は主としてタール
系色素であり、化学構造から大別すると、ニトロ染料、
アゾ染料、ニトロソ染料、トリフェニルメタン染料、キ
サンテン染料、キノリン染料、アントラキノン染料、イ
ンジゴイド染料などがあげられる。The acid dyes of the present invention are mainly tar dyes.
Examples include azo dyes, nitroso dyes, triphenylmethane dyes, xanthene dyes, quinoline dyes, anthraquinone dyes and indigoid dyes.
【００１４】本発明のヘアーリンス組成物には、これら
酸性染料の一種または二種以上を組成物総量に対し、好
ましくは０．００５〜０．２ｗｔ％が配合される。The hair rinse composition of the present invention contains one or more of these acid dyes, preferably in an amount of 0.005 to 0.2% by weight based on the total amount of the composition.
【００１５】本発明における酸としては、クエン酸、サ
リチル酸、酢酸、乳酸、プロピオン酸、酒石酸、リン
酸、塩酸等があげられ、その配合量は組成物のｐＨが
２．０〜５．５に調整するにたる必要量である。ｐＨが
２．０より低いと、安定性上問題があり、ｐＨが５．５
より高いと毛髪を着色するに充分な効果が得られない。Examples of the acid in the present invention include citric acid, salicylic acid, acetic acid, lactic acid, propionic acid, tartaric acid, phosphoric acid, hydrochloric acid and the like. The amount of the compound is adjusted so that the pH of the composition is 2.0 to 5.5. It is a necessary amount to adjust. When the pH is lower than 2.0, there is a problem in stability, and the pH is 5.5.
If it is higher, a sufficient effect for coloring hair cannot be obtained.
【００１６】また、本発明のヘアーリンス組成物は、上
述した成分を必須成分とするが、当該組成物には、本発
明の目的を達成する範囲で他の成分を適宜配合すること
ができる。The hair rinse composition of the present invention contains the above-mentioned components as essential components, but other components can be appropriately added to the composition as long as the object of the present invention is achieved.
【００１７】即ち、イソプロピルミリステート、イソプ
ロピルパルミテート等のエステル油ツバキ油、オリーブ
油、アボガド油、ホホバ油等の植物油、ポリオキシエチ
レン硬化ヒマシ油、ポリオキシエチレンアルキルエーテ
ル、ポリオキシエチレンソルビタンモノラウレート等の
非イオン界面活性剤、プロピレングリコール、ジプロピ
レングリコール、１．３−ブチレングリコール、グリセ
リン等の保湿剤、防腐剤、キレート剤、香料などがあげ
られ、これらの一種または二種以上を配合する事ができ
る。That is, ester oils such as isopropyl myristate and isopropyl palmitate, vegetable oils such as olive oil, avocado oil, jojoba oil, etc., polyoxyethylene hydrogenated castor oil, polyoxyethylene alkyl ether, polyoxyethylene sorbitan monolaurate And the like, humectants such as propylene glycol, dipropylene glycol, 1.3-butylene glycol and glycerin, preservatives, chelating agents, fragrances, etc., and one or more of these are compounded. Can do things.
【００１８】[0018]
【実施例】次に、本発明を実施例をもって詳細に説明す
るが、本発明はこれにより限定されるものではない。
尚、実施例および比較例中の数値は重量％である。ここ
で、実施例の説明に先立ち、各例において採用した試験
方法について説明する。Next, the present invention will be described in detail with reference to examples, but the present invention is not limited thereto.
The numerical values in Examples and Comparative Examples are% by weight. Here, prior to the description of the examples, test methods adopted in each example will be described.
【００１９】（１）毛髪着色効果試験 （イ）サンプル試験毛 毛束（白髪毛髪の束）５ｇを市販のシャンプーにて２分
間洗浄し、１分間温湯にてすすいだ後、試験試料ヘアー
リンス２ｇを塗布し、３分放置後、水洗いし、風乾し
た。これを１サイクルとし、５サイクル行った。 （ロ）評価法 試験試料リンス処理前及び処理後のサンプル試験毛束に
ついて、高速色彩計（村上色材（株）製ＣＭＳ−１００
０型）を用いて測色を行い、各サンプル試験毛のＸ，
Ｙ，Ｚ値をＨｕｎｔｅｒのＬ，ａ，ｂ表色系へ変換し、
下記の式により処理前と処理後の色差（△Ｅ）を求め、
その数値から、下記基準により評価した。△Ｅが大きい
程、毛髪が着色した事になる。 △Ｅ＝｛（Ｌ−Ｌ0 ）2 ＋（ａ−ａ0 ）2 ＋（ｂ−ｂ0 ）2 ｝1/2 Ｌ0 ，ａ0 ，ｂ0 ：処理前のサンプル毛のＬ，ａ，ｂ値 Ｌ，ａ，ｂ ：処理後のサンプル毛のＬ，ａ，ｂ値 ×；△Ｅ値が５以下 「ほとんど着色効果がない。」 △；△Ｅ値が６〜１５ 「やや着色効果がある。」 ○；△Ｅ値が１６〜２５ 「着色効果がある。」 ◎；△Ｅ値が２６以上 「非常に着色効果がある。」 (1) Hair coloring effect test (a) Sample test hair 5 g of a hair bundle (a bundle of white hair) was washed with a commercially available shampoo for 2 minutes, rinsed with warm water for 1 minute, and then 2 g of a test sample hair rinse. Was applied, left for 3 minutes, washed with water, and air-dried. This was defined as one cycle, and five cycles were performed. (B) Evaluation method For the sample test hair bundle before and after the test sample rinse treatment, a high-speed colorimeter (CMS-100 manufactured by Murakami Color Materials Co., Ltd.)
0 type) and measure the X,
Convert the Y, Z values to Hunter's L, a, b color system,
The color difference (△ E) before and after the processing is calculated by the following equation,
From the numerical values, evaluation was made according to the following criteria. The larger the ΔE, the more the hair is colored. ΔE = ｛(L−L 0 ) 2 + (a−a 0 ) 2 + (b−b 0 ) 2 ｝ 1/2 L 0 , a 0 , b 0 : L, a, and L of the sample hair before treatment B value L, a, b: L, a, b value of sample hair after treatment ×; ΔE value is 5 or less “There is almost no coloring effect . ” Δ; ΔE value is 6 to 15 “Slight coloring effect ○: ΔE value is 16 to 25 “There is a coloring effect”. △; ΔE value is 26 or more “It has a very coloring effect. ”
【００２０】（２）着色効果実用テスト 各例におけるヘアーリンスを白髪交じりのパネラー２０
名に５回使用してもらい、着色効果を、白髪隠し効果に
より下記基準で評価を行った。 ◎；自然に均一に白髪が目立たなくなったと答えた人が
１８人以上の場合 ○；自然に均一に白髪が目立たなくなったと答えた人が
１４〜１７人の場合 △；自然に均一に白髪が目立たなくなったと答えた人が
８〜１３人の場合 ×；自然に均一に白髪が目立たなくなったと答えた人が
７人以下の場合(2) Coloring Effect Practical Test The hair rinse in each example was replaced with a gray haired panel 20.
The name was used five times, and the coloring effect was evaluated based on the following criteria based on the gray hair hiding effect. ◎: 18 or more people answered that the gray hair became less noticeable naturally uniformly ○: 14 to 17 people answered that the gray hair became less noticeable uniformly △: White hair was naturally noticeable uniformly 8 to 13 people who answered that the hair disappeared ×: 7 or less people who answered that the gray hair became less noticeable evenly naturally
【００２１】（３）毛髪への塗布し易さ及びヘアーリン
ス後の仕上がり効果（艶、落ち着き、風合） 各例におけるヘアーリンス後の仕上がりについて
「艶」、「落ち着き」「風合い」を２０名のパネラ−に
より官能的に比較し、下記基準で評価を行った。 ◎；良いまたはあると答えた人が１８人以上の場合 ○；良いまたはあると答えた人が１４〜１７人の場合 △；良いまたはあると答えた人が８〜１３人の場合 ×；良いまたはあると答えた人が７人以下の場合(3) Ease of application to hair and finishing effect after hair rinsing (gloss, soothing, feeling) For each finishing after hair rinsing in each example, "gloss", "calmness" and "hand" were 20 persons. Were evaluated organoleptically according to the following criteria. ◎: 18 or more respondents who answered “good” or “existent” ○: 14 to 17 respondents who answered “good” or “existent” △: 8 to 13 respondents who answered “good” or “existent” ×: good Or if there are 7 or fewer people
【００２２】実施例１〜７、比較例１〜６ 表１及び表２に示す配合組成のヘアーリンス組成物を通
常の方法で調製し、前記諸試験を行い表３にその結果を
示した。Examples 1 to 7 and Comparative Examples 1 to 6 A hair rinse composition having the composition shown in Tables 1 and 2 was prepared by a conventional method, subjected to the above-mentioned tests, and the results are shown in Table 3.
【００２３】[0023]
【表１】 [Table 1]
【００２４】[0024]
【表２】 [Table 2]
【００２５】[0025]
【表３】 [Table 3]
【００２６】[0026]
【発明の効果】以上記載のごとく、本発明は、毛髪に塗
布し易く、且つ毛髪に対し艶と落ち着きを与え風合いを
保つとともに、自然に且つ均一に毛髪を着色する効果に
優れたヘアーリンス組成物を提供する事は明らかであ
る。As described above, the present invention provides a hair rinse composition which is easy to apply to hair, gives the hair a luster and calmness, keeps the texture, and is excellent in the effect of coloring the hair naturally and uniformly. It is clear that we will provide things.
Claims (1)
２．０〜５．５である事を特徴とするヘアーリンス組成
物。 （Ａ）下記一般式（１） 【化１】 ［式中、Ｒ1 は水素原子、メチル基またはメトキシ基、
Ｒ2 は−ＣＨ2 ＯＨ基、−ＣＨ2 ＣＨ2 ＯＨ基、−ＣＨ
（ＣＨ3 ）ＯＨ基、−ＣＨ2 ＣＨ2 ＣＨ2 ＯＨ基、−Ｃ
（ＣＨ3 ）2 ＯＨ基、−ＣＨ2 ＣＨ（ＣＨ3 ）ＯＨ基、
−ＣＨ（ＣＨ3 ）ＣＨ2 ＯＨ基、−ＣＨ＝ＣＨＣＨ2 Ｏ
Ｈ基または−ＯＣＨ2 ＣＨ2 ＯＨ基を表す。］で表され
る群より選ばれる芳香族アルコールの一種または二種以
上 （Ｂ）直鎖又は分岐鎖を有した脂肪族炭化水素又は一般
式（２）Ｒ−ＯＨ（Ｒは炭素数１２〜２４の直鎖又は分
岐鎖を有した脂肪族炭化水素）で表せる脂肪族アルコー
ルの群から選ばれる化合物の一種または二種以上 （Ｃ）キサンタンガムおよび／またはヒドロキシエチル
セルロース （Ｄ）平均分子量２０，０００〜８００，０００のポリ
エチレングリコール （Ｅ）酸性染料 （Ｆ）酸1. A hair rinse composition comprising the following (A) to (F) and having a pH of 2.0 to 5.5. (A) The following general formula (1) [Wherein, R 1 represents a hydrogen atom, a methyl group or a methoxy group,
R 2 represents —CH 2 OH group, —CH 2 CH 2 OH group, —CH
(CH 3 ) OH group, —CH 2 CH 2 CH 2 OH group, —C
A (CH 3 ) 2 OH group, a —CH 2 CH (CH 3 ) OH group,
-CH (CH 3) CH 2 OH group, -CH = CHCH 2 O
Represents an H group or an —OCH 2 CH 2 OH group. Represented by]
One or more aromatic alcohols selected from the group consisting of: (B) a linear or branched aliphatic hydrocarbon or a general formula (2) R-OH (R is a linear or branched one or more compounds selected from the group consisting of aliphatic alcohols represented by having a branched-chain aliphatic hydrocarbon) (C) xanthan gum and / or hydroxyethylcellulose (D) polyethylene having an average molecular weight 20,000～800,000 Glycol (E) Acid dye (F) Acid
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP4037038A JP3009959B2 (en) | 1992-01-27 | 1992-01-27 | Hair rinse composition |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP4037038A JP3009959B2 (en) | 1992-01-27 | 1992-01-27 | Hair rinse composition |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH05201839A JPH05201839A (en) | 1993-08-10 |
| JP3009959B2 true JP3009959B2 (en) | 2000-02-14 |
Family
ID=12486450
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP4037038A Expired - Fee Related JP3009959B2 (en) | 1992-01-27 | 1992-01-27 | Hair rinse composition |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP3009959B2 (en) |
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US10111815B2 (en) | 2014-06-17 | 2018-10-30 | The Procter And Gamble Company | Composition for hair frizz reduction |
| US10117819B2 (en) | 2014-12-05 | 2018-11-06 | The Procter And Gamble Company | Composition for hair frizz reduction |
| US10258555B2 (en) | 2015-12-04 | 2019-04-16 | The Procter And Gamble Company | Composition for hair frizz reduction |
| US10406094B2 (en) | 2016-04-01 | 2019-09-10 | The Procter And Gamble Company | Composition for fast dry of hair |
| US10561591B2 (en) | 2015-12-04 | 2020-02-18 | The Procter And Gamble Company | Hair care regimen using compositions comprising moisture control materials |
| US10632054B2 (en) | 2015-04-02 | 2020-04-28 | The Procter And Gamble Company | Method for hair frizz reduction |
| US10660835B2 (en) | 2015-04-02 | 2020-05-26 | The Procter And Gamble Company | Method for hair frizz reduction |
| US10980723B2 (en) | 2017-04-10 | 2021-04-20 | The Procter And Gamble Company | Non-aqueous composition for hair frizz reduction |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| ES2150554T3 (en) * | 1994-02-02 | 2000-12-01 | Procter & Gamble | HAIR CARE COMPOSITIONS CONTAINING A LOW MELTING FATTY ALCOHOL AND A POLYMER OF ETHYLENE OXIDE / PROPYLENE OXIDE. |
| JP4181749B2 (en) * | 2001-01-05 | 2008-11-19 | 花王株式会社 | Semi-permanent hair dye composition |
-
1992
- 1992-01-27 JP JP4037038A patent/JP3009959B2/en not_active Expired - Fee Related
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US10111815B2 (en) | 2014-06-17 | 2018-10-30 | The Procter And Gamble Company | Composition for hair frizz reduction |
| US10117819B2 (en) | 2014-12-05 | 2018-11-06 | The Procter And Gamble Company | Composition for hair frizz reduction |
| US10632054B2 (en) | 2015-04-02 | 2020-04-28 | The Procter And Gamble Company | Method for hair frizz reduction |
| US10660835B2 (en) | 2015-04-02 | 2020-05-26 | The Procter And Gamble Company | Method for hair frizz reduction |
| US10258555B2 (en) | 2015-12-04 | 2019-04-16 | The Procter And Gamble Company | Composition for hair frizz reduction |
| US10561591B2 (en) | 2015-12-04 | 2020-02-18 | The Procter And Gamble Company | Hair care regimen using compositions comprising moisture control materials |
| US10406094B2 (en) | 2016-04-01 | 2019-09-10 | The Procter And Gamble Company | Composition for fast dry of hair |
| US10980723B2 (en) | 2017-04-10 | 2021-04-20 | The Procter And Gamble Company | Non-aqueous composition for hair frizz reduction |
Also Published As
| Publication number | Publication date |
|---|---|
| JPH05201839A (en) | 1993-08-10 |
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