JPH05200526A - Production of wear resistant composite material - Google Patents

Production of wear resistant composite material

Info

Publication number
JPH05200526A
JPH05200526A JP1112292A JP1112292A JPH05200526A JP H05200526 A JPH05200526 A JP H05200526A JP 1112292 A JP1112292 A JP 1112292A JP 1112292 A JP1112292 A JP 1112292A JP H05200526 A JPH05200526 A JP H05200526A
Authority
JP
Japan
Prior art keywords
mold
layer
wear
ceramic particles
resistant composite
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
JP1112292A
Other languages
Japanese (ja)
Inventor
Kiyoshi Watanabe
潔 渡辺
Shigeaki Yamamuro
繁昭 山室
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Mitsubishi Heavy Industries Ltd
Original Assignee
Mitsubishi Heavy Industries Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Mitsubishi Heavy Industries Ltd filed Critical Mitsubishi Heavy Industries Ltd
Priority to JP1112292A priority Critical patent/JPH05200526A/en
Publication of JPH05200526A publication Critical patent/JPH05200526A/en
Withdrawn legal-status Critical Current

Links

Landscapes

  • Ceramic Products (AREA)

Abstract

PURPOSE:To produce the wear resistant composite material having a combination of both advantages of the high toughness of an alloy system and the high hardness of ceramics. CONSTITUTION:A casting mold 1 consisting of a surface layer 2 formed by kneading an inorg. binder with coarse ceramic particles of about 1 to 3mm and molding the mixture and a back layer 3 formed by kneading the inorg. binder with ordinary fine ceramic particles and molding the mixture on the rear surface of this surface layer 2 is formed. This casting mold 1 is preheated to a high temp. and a molten metal is poured therein, by which a casting 6 having a wear resistant layer 5 combined with the ceramic particles on the surface is produced.

Description

【発明の詳細な説明】Detailed Description of the Invention

【0001】[0001]

【産業上の利用分野】本発明は耐ブラスト摩耗、耐摺動
摩耗部品などの耐摩耗複合材の製造方法に関する。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a method for producing a wear resistant composite material such as a blast wear resistant and a slide wear resistant part.

【0002】[0002]

【従来の技術】耐ブラスト摩耗、摺動摩耗部品は、従来
高クローム鋳鉄等、高硬度な合金もしくは、アルミナ、
窒化珪素等高硬度セラミックス部品が利用されて来た。
又、窒化、炭化等の方法により金属の表面のみ硬化させ
る。もしくは、セラミックス等高硬度な材料を溶射によ
り付着させる表面処理方法が採用されて来た。
2. Description of the Related Art Blast wear and sliding wear parts are conventionally made of high chrome cast iron or other high hardness alloy or alumina,
High hardness ceramic parts such as silicon nitride have been used.
Further, only the surface of the metal is hardened by a method such as nitriding or carbonization. Alternatively, a surface treatment method has been adopted in which a high hardness material such as ceramics is attached by thermal spraying.

【0003】[0003]

【発明が解決しようとする課題】しかし、これら従来部
材は、合金系では、十分な硬度が得られず、又、セラミ
ックス系では、硬度は十分であっても成形が困難であ
り、複雑な部品が作れずコストが高く実用的でないとい
う問題点があった。又、耐ブラスト摩耗に対しては、セ
ラミックスは、その靭性のなさから、衝突粒子が大き
く、質量が高い場合、微小かけ摩耗が生じかえって合金
系よりも摩耗が激しい事もある。
However, these conventional members cannot provide sufficient hardness in the alloy system, and in the ceramic system, molding is difficult even if the hardness is sufficient, and complicated parts are required. However, there was a problem that it was not practical because it could not be made. With respect to blast wear resistance, ceramics, due to their inferior toughness, may cause slight wear when the collision particles are large and the mass is high, and may be more severe than the alloy system.

【0004】本発明はこれら、従来の耐摩耗複合材の不
具合点に対し合金系の靭性の高さ、成形性の容易さとセ
ラミックスの高硬度の両方の長所をうまく組み合せた耐
摩耗複合材の製造方法を提案することを目的とする。
The present invention is directed to the production of a wear-resistant composite material which combines the advantages of the high toughness of the alloy system, the ease of formability and the high hardness of ceramics with respect to the disadvantages of the conventional wear-resistant composite materials. The purpose is to propose a method.

【0005】[0005]

【課題を解決するための手段】上記の目的を達成するた
めの本発明の構成を実施例に対応する図1及び図2を用
いて説明すると本発明は1〜3mm程度の粗いセラミッ
ク粒子に無機バインダーを混練して必要な耐摩耗複合層
の厚みの分だけ造型した表面層2と該表面層2の裏面に
通常の細いセラミック粒子に無機バインダーを混練して
造型したバック層3とからなる鋳型1を形成し、該鋳型
1を高温に予熱して、これに金属溶湯を流し込むことに
より、表面に前記表面層の厚みの分だけセラミック粒子
を複合した層5をもつ鋳造品6を製造することを特徴と
する。
The structure of the present invention for achieving the above object will be described with reference to FIGS. 1 and 2 corresponding to the embodiments. The present invention is based on coarse ceramic particles of about 1 to 3 mm and inorganic particles. A mold comprising a surface layer 2 which is formed by kneading a binder to form a wear resistant composite layer and a back layer 3 which is formed by kneading an inorganic binder with ordinary fine ceramic particles on the back surface of the surface layer 2. 1 is formed, the mold 1 is preheated to a high temperature, and a molten metal is poured into the mold 1 to produce a cast product 6 having a layer 5 on the surface of which composite particles of ceramic particles are formed by the thickness of the surface layer. Is characterized by.

【0006】[0006]

【作用】そして本発明は上記の手段により鋳造品の耐摩
耗部位の表層は、耐摩耗性を有する高硬度のセラミック
スと複合化されたものとなりかつ本体は従来の金属の性
質(高靭性、加工性)を有したものとなり、かつ本工法
によれば、いかなる複雑な形状でも製作が可能である。
According to the present invention, the surface layer of the wear-resistant portion of the cast product is made into a composite with wear-resistant and high-hardness ceramics by the above-mentioned means, and the main body has the conventional metal properties (high toughness, working property). In addition, according to this method, any complicated shape can be manufactured.

【0007】又本工法により製作された複合部位は、靭
性の高い金属が硬質のセラミックスをだき込んだ形とな
っているため、特にブラスト摩耗に対しては、セラミッ
クスのかけ摩耗による損傷が生じにくく、きわめて耐摩
耗性に優れた複合耐摩耗部品といえる。更に本工法によ
れば複合する高硬度セラミックスはアルミナ、窒化珪
素、炭化珪素、炭化ボロン等あるいは超硬合金材も含め
てあらゆる材質の複合化が可能である。これはこれらセ
ラミックス等を結合させて、鋳型を形成させる。コロイ
ダルシリカもしくはエチルシリケートの無機バインダー
をあらゆるものに対して十分な接着力を有するからであ
り、かつ溶湯の含浸により、この複合部位を形成すると
いう本工法の製造工法によるものである。
In addition, since the composite part manufactured by this method has a shape in which a metal having high toughness is filled with hard ceramics, damage to the ceramics due to wear of the ceramics is unlikely to occur, especially with respect to blast wear. It can be said that it is a composite wear resistant part with extremely excellent wear resistance. Further, according to the present method, the high hardness ceramics to be composited can be composited of all materials including alumina, silicon nitride, silicon carbide, boron carbide, etc. or cemented carbide materials. This combines these ceramics and the like to form a mold. This is because the inorganic binder of colloidal silica or ethyl silicate has a sufficient adhesive force to all the binders, and is due to the manufacturing method of the present method in which this composite portion is formed by impregnation of the molten metal.

【0008】更に鋳型を形成させるバインダーとして、
コロイダルシリカ、もしくはエチルシリケートの無機バ
インダーを選定したことにより本鋳型は、約1500°
Cまでの高温に変形を生ずることなく耐えることが出来
る。これにより、十分に高温に保持された鋳型に溶湯を
給湯することが可能となり、鋳型表層の粗粒、粒子間の
空げきに、安定的に溶湯を含浸させることが出来、安定
して、健全な耐摩耗複合表層を持った鋳造品が製造可能
となった。
Further, as a binder for forming a mold,
By selecting an inorganic binder such as colloidal silica or ethyl silicate, this mold is about 1500 °
It can withstand high temperatures up to C without deformation. This makes it possible to supply the molten metal to the mold that has been kept at a sufficiently high temperature, and it is possible to stably impregnate the molten metal into the coarse particles on the surface of the mold and the voids between the particles, making it stable and sound. It became possible to manufacture cast products with various wear-resistant composite surface layers.

【0009】[0009]

【実施例】以下本発明の一実施例を図1及び図2に基づ
いて説明すると、本発明は図1に示すように鋳型1の表
面に鋳造部材の耐摩耗性を要求される耐摩耗複合層の厚
みの分だけ1〜3mm程度の粗いセラミック粒子に無機
バインダーを混練して表面層2を造型し、該表面層2の
裏面に通常の細かいセラミック粒子に無機バインダーを
混練してバック層3を形成し、この鋳型に溶湯を流し込
むと溶湯が鋳型表面の砂粒間に侵入し、図2に示すよう
に表面にセラミック粒子4を複合した耐摩耗層5を持つ
鋳造部品6が製造される。
DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS An embodiment of the present invention will be described below with reference to FIGS. 1 and 2. The present invention is, as shown in FIG. 1, a wear resistant composite in which the surface of a mold 1 is required to have wear resistance of a cast member. The surface layer 2 is formed by kneading the inorganic binder into coarse ceramic particles having a thickness of about 1 to 3 mm, and the back surface of the surface layer 2 is kneaded with inorganic binder into ordinary fine ceramic particles. And the molten metal is poured into this mold, the molten metal penetrates between the sand grains on the surface of the mold, and as shown in FIG. 2, a cast part 6 having a wear resistant layer 5 in which ceramic particles 4 are compounded is produced on the surface.

【0010】なお無機バインダーはコロイダルシリカ、
エチルシリケートの高温焼成に耐え得る無機系のバイン
ダーと、これに粗粒の粒子を混練し、木型上に必要な耐
摩耗複合層の厚みの分だけ造型して表面層を形成する。
この厚みは3〜10mm程度であり、成形したい複合部
位の厚みの分だけ造型すればよい。但し10mm以上に
なると溶湯の含浸が十分でなくなるため健全な複合部位
を安定的に得るには10mm以下にすることが望まし
い。
The inorganic binder is colloidal silica,
An inorganic binder capable of withstanding high-temperature firing of ethyl silicate and coarse particles are kneaded, and a surface layer is formed by molding a wooden mold for the thickness of the abrasion-resistant composite layer required.
This thickness is about 3 to 10 mm, and molding may be performed by the thickness of the composite portion to be molded. However, when the thickness is 10 mm or more, the molten metal is not sufficiently impregnated, so that it is preferably 10 mm or less in order to stably obtain a sound composite part.

【0011】その後、通常の鋳物砂たとえばジルコン砂
にコロイダルシリカを5〜20%配合、混練し、前述の
表層の上にバッフアップ層として、造型する。自然乾燥
の後、木型より抜型し、1000°Cで焼成し、強固な
鋳型を形成させる。焼成温度は無機バインダー、コロイ
ダルシリカの強度発現の面から900°C以上が望まし
く、1000°Cで十分な強度を発現し、それ以上であ
る必要はない。
Then, 5 to 20% of colloidal silica is mixed and kneaded with usual foundry sand such as zircon sand, and kneaded, and a mold is formed as a buff-up layer on the above-mentioned surface layer. After air-drying, it is removed from the wooden mold and baked at 1000 ° C to form a strong mold. The firing temperature is preferably 900 ° C. or higher from the viewpoint of strength development of the inorganic binder and colloidal silica, and sufficient strength is expressed at 1000 ° C., and need not be higher than that.

【0012】この様にして造型した鋳型を上型、下型、
必要であれば中子組み合せて溶湯を鋳込む空間を有す
る、鋳型を組立てる。この鋳型を1000°Cにて再度
焼成、予熱する。予熱の温度は、溶湯が十分に含浸する
温度である必要があるが、鋳型の変形から1500°C
以下が望ましい。
The mold produced in this manner is used as an upper mold, a lower mold,
If necessary, assemble a mold having a space for pouring molten metal by combining cores. This mold is fired again at 1000 ° C. and preheated. The preheating temperature needs to be a temperature at which the molten metal is sufficiently impregnated, but 1500 ° C from the deformation of the mold.
The following is desirable.

【0013】この様にして予熱した鋳型を焼成炉より取
り出し、すみやかにSUS310材の溶湯を1600°
Cにて鋳込んだ。鋳込む材質は、その部品の使用される
用途に応じて高クローム鋳鉄、耐熱鋼、ステンレス鋼等
選定すれば良く鋳造可能な材質なら全て可能である。鋳
込んだ後、自然冷却し、鋳型をばらし、製品を取り出
す。耐摩耗部位以外は、通常の鋳造品と同様であるか
ら、押湯切断、機械加工等、可能である。
The mold preheated in this way was taken out of the firing furnace, and the molten metal of SUS310 was immediately cooled to 1600 °.
Cast in C. The material to be cast can be selected from high-chromium cast iron, heat-resistant steel, stainless steel, etc. depending on the intended use of the part, and any material that can be cast can be used. After casting, it is naturally cooled, the mold is disassembled, and the product is taken out. Except for the wear resistant part, it is the same as a normal cast product, so that it is possible to cut the riser, machine it, and so on.

【0014】この表面に耐摩耗複合層を有する鋳造品に
サンドブラスト摩耗試験を実施した結果、複合化してい
ないSUS310材に対して、3倍の耐摩耗性を示し
た。
As a result of a sandblasting wear test conducted on a cast product having a wear resistant composite layer on its surface, the wear resistance was three times higher than that of the uncomposited SUS310 material.

【0015】[0015]

【発明の効果】このように本発明によるときは1〜3m
m程度の粗いセラミック粒子に無機バインダーを混練し
て必要な耐摩耗複合層の厚みの分だけ造型した表面層と
該表面層の裏面に通常の細かいセラミック粒子に無機バ
インダーを混練して造型したバック層とからなる鋳型を
形成し、該鋳型を高温に予熱して、これに金属溶湯を流
し込むことにより、表面に前記表面層の厚みの分だけセ
ラミック粒子を複合した層をもつ鋳造品を製造したもの
であるから表面にセラミック粒子を複合した耐摩耗鋳造
品を、安定して製造することが出来ると共にセラミック
スと金属が複合化された耐摩耗層は耐摩耗性かつ靭性を
有し、従来のセラミックスのみ金属のみの部品に比較し
て、高い耐摩耗性を有する。
As described above, according to the present invention, 1 to 3 m
A back surface formed by kneading an inorganic binder with coarse ceramic particles of about m to form a wear-resistant composite layer by a required thickness and a back surface of the surface layer by kneading an inorganic binder with ordinary fine ceramic particles. By forming a mold consisting of layers and preheating the mold to a high temperature, and pouring a molten metal into the mold, a cast product having a layer on the surface of which a composite of ceramic particles corresponding to the thickness of the surface layer was produced. Therefore, it is possible to stably manufacture a wear-resistant cast product in which ceramic particles are compounded on the surface, and the wear-resistant layer in which ceramics and metal are compounded has wear resistance and toughness, and It has higher wear resistance than parts made of only metal.

【図面の簡単な説明】[Brief description of drawings]

【図1】本発明一実施例に係る鋳型の断面図である。FIG. 1 is a sectional view of a mold according to an embodiment of the present invention.

【図2】本発明の一実施例に係る鋳物の断面図である。FIG. 2 is a sectional view of a casting according to an embodiment of the present invention.

【符号の説明】[Explanation of symbols]

1 鋳型 2 表面層 3 バック層 4 セラミック粒子 5 耐摩耗層 6 鋳造品 1 mold 2 surface layer 3 back layer 4 ceramic particles 5 wear-resistant layer 6 cast product

Claims (1)

【特許請求の範囲】[Claims] 【請求項1】 1〜3mm程度の粗いセラミック粒子に
無機バインダーを混練して必要な耐摩耗複合層の厚みの
分だけ造型した表面層と該表面層の裏面に通常の細かい
セラミック粒子に無機バインダーを混練して造型したバ
ック層とからなる鋳型を形成し、該鋳型を高温に予熱し
て、これに金属溶湯を流し込むことにより、表面に前記
表面層の厚みの分だけセラミック粒子を複合した耐摩耗
層をもつ鋳造品を製造することを特徴とする耐摩耗複合
材の製造方法。
1. A surface layer formed by kneading a coarse ceramic particle having a size of about 1 to 3 mm with an inorganic binder to a required thickness of a wear-resistant composite layer and an ordinary fine ceramic particle on the back surface of the surface layer. To form a mold comprising a back layer formed by kneading, and preheating the mold to a high temperature, and pouring a molten metal into the mold, so that the surface is coated with ceramic particles in an amount corresponding to the thickness of the surface layer. A method for producing an abrasion resistant composite material, which comprises producing a cast product having an abrasion layer.
JP1112292A 1992-01-24 1992-01-24 Production of wear resistant composite material Withdrawn JPH05200526A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP1112292A JPH05200526A (en) 1992-01-24 1992-01-24 Production of wear resistant composite material

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP1112292A JPH05200526A (en) 1992-01-24 1992-01-24 Production of wear resistant composite material

Publications (1)

Publication Number Publication Date
JPH05200526A true JPH05200526A (en) 1993-08-10

Family

ID=11769214

Family Applications (1)

Application Number Title Priority Date Filing Date
JP1112292A Withdrawn JPH05200526A (en) 1992-01-24 1992-01-24 Production of wear resistant composite material

Country Status (1)

Country Link
JP (1) JPH05200526A (en)

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1998015373A1 (en) * 1996-10-01 1998-04-16 Hubert Francois Composite wear part
EP0838288A1 (en) * 1996-10-01 1998-04-29 Hubert Francois Wear resistant composite cast pieces
JP2007270170A (en) * 2006-03-30 2007-10-18 Kurimoto Mec Ltd Sinter cake-supporting stand
US7513295B2 (en) 2001-12-04 2009-04-07 Magotteaux International Sa Cast parts with enhanced wear resistance
US8147980B2 (en) 2006-11-01 2012-04-03 Aia Engineering, Ltd. Wear-resistant metal matrix ceramic composite parts and methods of manufacturing thereof
CN103357853A (en) * 2013-08-06 2013-10-23 宁国市华丰耐磨材料有限公司 Strengthened abrasion proof steel ball made of nano materials
CN103394671A (en) * 2013-08-01 2013-11-20 河北海钺耐磨材料科技有限公司 Preparation technology for lost foam casting high manganese steel wear-resisting surface composite materials

Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1998015373A1 (en) * 1996-10-01 1998-04-16 Hubert Francois Composite wear part
EP0838288A1 (en) * 1996-10-01 1998-04-29 Hubert Francois Wear resistant composite cast pieces
USRE39998E1 (en) 1996-10-01 2008-01-08 Magotteaux International S.A. Composite wear component
US7513295B2 (en) 2001-12-04 2009-04-07 Magotteaux International Sa Cast parts with enhanced wear resistance
US7935431B2 (en) 2001-12-04 2011-05-03 Magotteaux International Sa Cast parts with enhanced wear resistance
JP2007270170A (en) * 2006-03-30 2007-10-18 Kurimoto Mec Ltd Sinter cake-supporting stand
US8147980B2 (en) 2006-11-01 2012-04-03 Aia Engineering, Ltd. Wear-resistant metal matrix ceramic composite parts and methods of manufacturing thereof
CN103394671A (en) * 2013-08-01 2013-11-20 河北海钺耐磨材料科技有限公司 Preparation technology for lost foam casting high manganese steel wear-resisting surface composite materials
CN103357853A (en) * 2013-08-06 2013-10-23 宁国市华丰耐磨材料有限公司 Strengthened abrasion proof steel ball made of nano materials

Similar Documents

Publication Publication Date Title
AU2002340644B2 (en) Cast part with enhanced wear resistance
US5052464A (en) Method of casting a member having an improved surface layer
US20040216860A1 (en) Ceramic casting mold for casting metal and process for production thereof
CN102618772B (en) Metal-matrix composite ceramic liner plate and preparation method thereof
JP3142560B2 (en) Reaction-sintered mullite-containing ceramic compact, method for producing the compact and use of the compact
GB2149057A (en) Non-uniform reinforced cast pistons
CN103143708A (en) Preparation method of hard alloy preform and method for preparing composite wear-resistant part by using hard alloy preform
JP7354289B2 (en) In-situ manufactured tungsten carbide-reinforced alloy-based composite materials and their manufacturing methods.
JPH05200526A (en) Production of wear resistant composite material
CN102676956B (en) Method for preparing iron-based surface composite material by virtue of in-situ synthesis
NO115813B (en)
JP2002530220A (en) Low pressure injection molding of metals and ceramics using flexible molds
JPS59147769A (en) Production of composite casting
JPH0688120B2 (en) Molten metal injection molding sleeve
You-wei et al. In-situ synthesis and characteristics of TiC− Fe cermet graded composite coating on a steel substrate
JP2023010380A (en) Casting method and casting using the same
US881645A (en) Mold and mold-lining.
JPS5830265B2 (en) Refractories for continuous casting
SU916043A1 (en) Base filler for casting shell mould
JPH10211541A (en) Durable mold
JPS62263842A (en) Molding sand for shell mold
JPS59120356A (en) Composite casting and its production
Semchenko et al. Resistant corundum-graphite materials for metallurgy
JP2006212642A (en) Method for manufacturing casting mold for precision casting
JPH08117925A (en) Heat insulating pad for casting, its production and material for producing the pad

Legal Events

Date Code Title Description
A300 Withdrawal of application because of no request for examination

Free format text: JAPANESE INTERMEDIATE CODE: A300

Effective date: 19990408