JPH05173300A - Halogenized silver color photograph photo-sensitive material - Google Patents

Abstract

PURPOSE:To provide a color proof in which similarity of image quality to that of a printed mater is improved, from net point image information, obtained through color dissolution and conversion of a net point image, with high productive efficiency by using development liquid suitable for security of good environment. CONSTITUTION:A halogenized silver color photograph photo-sensitive material is prepared on a support in such a way that at least one each layer out of a yellow image formative halogenized silver emulsion layer, a magenta image formative halogenized silver emulsion layer, and a cyan image formative halogenized silver emulsion layer, all containing halogenized silver particles and having different spectral sensitivity, and at least one layer black image forming layer containing halogenized silver particles. In the above mentioned halogenized silver color photograph photo-sensitive material, the black image forming layer the spectral sensitive region of each of and the spectral sensitive region, having a common part, of the yellow image formative halogenized silver emulsion layer, the magenta image formative halogenized silver emulsion layer, and the cyan image formative halogenized silver emulsion layer, and is treated by treatment liquid having a supply amount of coloring development liquid being 1000ml/m<2> or less.

Description

Detailed Description of the Invention

[0001]

BACKGROUND OF THE INVENTION The present invention is preferably used for producing a proof color image (color proof) from a plurality of black and white halftone images obtained by color separation and halftone image conversion in a color plate making / printing process. The present invention relates to a silver halide color photographic light-sensitive material that can be used.

[0002]

BACKGROUND OF THE INVENTION There are primarily two types of techniques known in the art for obtaining direct positive images. One of the types is to use an emulsion containing silver halide grains having fog nuclei in advance and destroy the fog nuclei or latent image in the exposed area by utilizing the solarization or Herschel effect, etc. You get a positive directly. The other type uses an emulsion containing an internal latent image type silver halide grain that does not cause fog (generally surface fog) until the time of image exposure, and performs fog after image exposure (nucleation treatment).
Then, surface development is performed, or after image exposure, a positive image is directly obtained by performing surface development while performing fog treatment.

The above-mentioned fog treatment may be performed by exposing the whole surface, chemically using a fog agent, using a strong developing solution, or by heat treatment. The emulsion containing the internal latent image type silver halide emulsion grains is a silver halide which has a photosensitive nucleus mainly inside the silver halide crystal grains and forms a latent image inside the grains upon exposure. A grain-containing emulsion.

Of the above two techniques for forming a positive image, the latter type generally has higher sensitivity than the former type and is suitable for applications requiring high sensitivity.
Various techniques have been known so far in this technical field. For example, U.S. Patents 2,592,250 and 2,466,957
No. 2, No. 2,497,875, No. 2,588,982, No. 3,761,266,
No. 3,761,276, No. 3,796,577 and British Patent 1,151,363
There is a method described in the issue.

Although the mechanism of forming a positive image is not always clear, for example, Photographic Science and Engineering (Photographic Science and Engineering)
andEngineering) Vol. 20, p. 158 (1976), describes as follows.

Photoelectrons generated in the silver halide crystal grains by imagewise exposure are selectively trapped inside the grains to form an internal latent image. Since this internal latent image acts as an effective trap center for electrons in the conduction band, in the exposed particles, the electrons injected in the subsequent fog development process are trapped inside and assist the latent image. Become. In this case, the latent image is not developed by surface development because it is inside. On the other hand, in particles that have not been subjected to image exposure, at least some of the injected electrons are captured on the surface of the particle and a latent image is formed there, so that the particle is developed by surface development.

Although a positive image can be formed by using the above-mentioned known technique, further improvement of photographic performance is desired for practical application of these photographic light-sensitive materials to various photographic fields.

On the other hand, as a method for obtaining a color proof from a plurality of black and white halftone dot images obtained by color separation and halftone dot image conversion in the conventional color plate making / printing process, a photopolymer or a diazo compound is used. An overlay method for forming a color image and a surprint method are known.

The overlay method is very simple and inexpensive to produce, and has the advantage that it can be used for proofreading simply by overlapping four color (subtractive primary colors and black) film sheets. There is a drawback in that gloss is generated by stacking, and therefore, a texture different from that of the printed matter is obtained.

In the surprint method, a colored image is superposed on one support, and a method of obtaining a colored image by toner development utilizing the adhesiveness of a photopolymerizable material is disclosed in US Pat. No. 3,582,327. Nos. 3,607,264 and 3,620,726.

Further, after transferring to a support using a photosensitive coloring sheet and forming an image by exposure and development, another coloring sheet is laminated thereon, and the same process is repeated to form a color proof. A method of doing this is known from Japanese Patent Publication No. 47-27441 and Japanese Patent Publication No. 56-501217.

Further, there is a method of forming a color image on a single support by transferring each color image obtained by exposing and developing the corresponding color separation film using a photosensitive color sheet.
-Known as No. 97140. As the colorant of the toner and the color sheet for forming these images, the same coloring material as the printing ink can be used, and thus the color tone of the obtained color proof becomes similar to that of the printed matter.

However, these methods have drawbacks that images must be superposed or transferred in the process of producing a color proof, which requires a long operation time and a high manufacturing cost.

As a solution to these drawbacks, a method for producing a color proof by using a silver salt color photographic light-sensitive material having a white support is disclosed in JP-A-56-113139 and JP-A-56-104335. 62-280746, 62-280747, 62-
280748, 62-280749, 62-280750, 62-28084
No. 9 etc.

In this method, a color-separated black-and-white halftone image composed of a plurality of sheets converted from a color original into a halftone image which has been color-separated is sequentially printed on one sheet of color paper by a method such as contact printing, and color development is performed. A color image formed by a dye formed from a coupler imagewise by color development is used as a proof image.

However, in this technique, when the color image is approximated to the printed matter, the density of the black image such as characters is insufficient as compared with the printed matter, and the density of the black image such as the characters is increased to approximate the density of the printed matter. If the measures are taken, there is a drawback that the degree of approximation of the color image of the printed matter deteriorates and it is difficult to satisfy both of them.

As a technique for improving this drawback, a technique of providing a fourth black plate layer having a spectral sensitivity different from that of any of the yellow color forming layer, the magenta color forming layer and the cyan color forming layer is conventionally known. There is. For example, in JP-A-3-122637,
A technique using four types of image forming layers of yellow, magenta, cyan, and black is disclosed. Further, JP-A-2-289846,
No. 2-183251 and the like also disclose a technique for improving this problem, but in any case, it cannot be put to practical use such as increasing the number of exposures, impairing productivity, and lacking image stability. Further improvements are needed.

In recent years, environmental problems have been highlighted, and from the viewpoint of environmental conservation, general silver salt color photographic light-sensitive materials for printing have a low replenishment rate in order to reduce the amount of developer. Has been done.

However, the conventional silver salt color photographic light-sensitive material for color proof is formed with black density of Y, M and C, and has a drawback that the black density and the balance are apt to change when the replenishment is low. It was difficult to apply supplementation.

[0020]

OBJECTS OF THE INVENTION Therefore, the object of the present invention is to provide a silver halide color photographic light-sensitive material (hereinafter also simply referred to as "light-sensitive material").
When making a color proof from the halftone image information obtained by color separation and halftone image conversion using, a color proof with an improved degree of approximation of the image quality to the printed matter is provided as a developer suitable for environmental protection. To provide a color proof photosensitive material which can be obtained with high production efficiency.

[0021]

The above object of the present invention is to provide, on a support, at least one yellow image forming silver halide emulsion layer containing silver halide grains having different spectral sensitivities and at least one magenta image forming property. A silver halide color photographic light-sensitive material having a silver halide emulsion layer, at least one cyan image forming silver halide emulsion layer and at least one black image forming layer containing silver halide grains, wherein the black image forming layer is Has a spectral sensitivity region having a common portion with the spectral sensitivity region of each of the yellow image forming silver halide emulsion layer, the magenta image forming silver halide emulsion layer and the cyan image forming silver halide emulsion layer,
It is also achieved by a silver halide color photographic light-sensitive material processed with a processing solution having a replenishing amount of a color developing solution of 1000 ml / m ² or less.

The present invention will be described in more detail below.

The non-pre-fogged internal latent image type silver halide grains according to the present invention mainly form a latent image inside the silver halide grains and have most of the photosensitive nuclei inside the grains. It is a particle. Particularly preferably, a portion of the sample coated on a transparent support so that the amount of coated silver is in the range of about 1 to 3.5 g / m ² is applied for a certain period of time from about 0.1 second to about 1 second. Of the same emulsion sample when exposed to a light intensity scale for 4 minutes at 20 ° C. using the surface developer A described below which develops only the surface image of the grains containing substantially no silver halide solvent. Expose another part as well,
It is an emulsion showing a maximum density which is not more than 1/5 of the maximum density obtained when developed at 20 ° C. for 4 minutes with the following internal developer B for developing the image inside the grain. More preferably, the maximum density obtained using surface developer A is no greater than 1/10 of the maximum density obtained with internal developer B.

(Surface developer A) Metol 2.5 g L-ascorbic acid 10.0 g Sodium metaborate (tetrahydrate) 35.0 g Potassium bromide 1.0 g Water was added to 1000 ml (internal developer B) Metol 2.0 g Sodium sulfite ( Anhydrous) 90.0 g Hydroquinone 8.0 g Sodium carbonate (monohydrate) 52.5 g Potassium bromide 5.0 g Potassium iodide 0.5 g Water is added to 1000 ml Also, the internal latent image type silver halide emulsion in the present invention can be prepared by various methods. Including those prepared in. For example US patent
Conversion type silver halide emulsions described in 2,592,250, or silver halide emulsions having internally chemically sensitized silver halide grains described in U.S. Patents 3,206,316, 3,317,322 and 3,367,778, or U.S. Patents 3,
No. 271,157, No. 3,447,927 and No. 3,53,291, emulsions having silver halide grains containing a polyvalent metal ion described therein, or silver halide grains containing a dopant described in U.S. Pat. A silver halide emulsion in which the grain surface is weakly chemically sensitized, or JP-A-50-8524 and 50-38525.
And the silver halide emulsions described in JP-A Nos. 53-2408 and 53-2408, and the silver halide emulsions described in JP-A Nos. 52-156614 and 55-127549.

The internal latent image type silver halide grain in the present invention is a silver halide having an arbitrary halogen composition, for example, silver bromide, silver chloride, silver chlorobromide, silver chloroiodide, silver iodobromide, chloroiodide. It may be silver bromide. The grains containing silver chloride have excellent developability and are suitable for rapid processing.

In the present invention, surface latent image type (also referred to as negative type) silver halide grains which mainly form a latent image can be used. These two types of silver halide grains are used properly according to the use of the light-sensitive material.

The shape of particles is cubic, octahedral, (100) plane
A tetrahedron composed of a mixture of (111) faces, a shape having a (110) face,
It may be spherical, flat, or the like. The average particle size is 0.
Those having a diameter of 05 to 3 μm can be preferably used. The grain size distribution may be a monodisperse emulsion having uniform grain size and crystal habit, or a polydisperse emulsion having no uniform grain size or crystal habit, but a monodisperse silver halide emulsion is preferred.

In the present invention, the monodisperse silver halide emulsion means that the weight of silver halide contained within a grain size range of ± 20% around the average grain size rm is the total weight of silver halide grains.
It means 60% or more, preferably 70% or more, and more preferably 80% or more. Here, the average particle size rm is
The product of the frequency ni and ri ^{3 of} particles having a particle size ri ni × ri ³
Is defined as the particle size ri when the maximum is (effective number 3
Digits and minimum digits are rounded to 4). In the case of spherical silver halide grains, the grain size means the diameter, or
In the case of particles having a shape other than spherical, it is the diameter when the projected image is converted into a circular image having the same area. The particle size can be obtained, for example, by magnifying the particles with an electron microscope at a magnification of 10,000 to 50,000 times and measuring the particle diameter on the print or the area at the time of projection (the number of measured particles is not measured). 1000 against discrimination
There shall be more than one).

A particularly preferred highly monodisperse emulsion is one having a distribution width of 20% or less defined by (grain size standard deviation / average grain diameter) × 100 = distribution breadth (%). Here, the average particle size and the particle size standard deviation are obtained from ri defined above.

The monodisperse emulsion is prepared by adding a water-soluble silver salt solution and a water-soluble halide solution to pAg and p in a gelatin solution containing seed grains.
It can be obtained by adding by the double jet method under the control of H 2. To determine the addition rate, refer to JP-A-54
-48521 and 58-49938 can be referred to. As a method for obtaining a more advanced monodisperse emulsion, the growth method in the presence of a tetrazaindene compound disclosed in JP-A-60-122935 can be applied.

The silver halide in the present invention can be optically sensitized with a commonly used sensitizing dye.
It is also useful for the silver halide emulsion of the present invention to use a combination of sensitizing dyes used for supersensitization such as an internal latent image type silver halide emulsion and a negative type silver halide emulsion. Regarding sensitizing dyes, Research Disclosure (hereinafter abbreviated as RD) No. 15162 and
Reference can be made to No. 17643.

In the present invention, the yellow image forming layer, the magenta image forming layer and the cyan image forming layer have mutually different spectral sensitivities. This is at least 4 times higher than the spectral sensitivities of the other layers at any wavelength in the spectral sensitivity range of each layer.
It suffices that there be a wavelength exhibiting a double sensitivity, and preferably a wavelength exhibiting at least a 8 times sensitivity.

In one of the preferred embodiments, for example, the yellow image forming layer contains a blue sensitive silver halide emulsion,
The magenta image forming layer contains a green-sensitive silver halide emulsion and the cyan image forming layer contains a red-sensitive silver halide emulsion.

In the present invention, for the black image forming layer, any conventionally known method can be used as long as a black image is formed after development. For example, it is possible to use an image formed by leaving a silver image after development processing,
It is also possible to use a black coupler which forms a black image by color development. Further, a black image can be obtained by mixing a yellow coupler, a magenta coupler and a cyan coupler.

In the present invention, the black image forming layer is in common with the spectral sensitivity region of each of the yellow image forming silver halide emulsion layer, the magenta image forming silver halide emulsion layer and the cyan image forming silver halide emulsion layer. It has a spectral sensitivity region having a portion. That is, the black image forming layer of the present invention has sensitivity to light having any wavelength in the spectral sensitivity wavelength range of the yellow image forming layer, and has any wavelength in the spectral sensitivity wavelength range of the magenta image forming layer. Of the cyan image forming layer, and also has sensitivity to light of any wavelength in the spectral sensitivity wavelength range of the cyan image forming layer.

In one preferred embodiment of the present invention, for example, the yellow image-forming layer contains a blue-sensitive emulsion, the magenta image-forming layer contains a green-sensitive emulsion, and the cyan image-forming layer contains a red-sensitive emulsion. The emulsion contains an emulsion, and the black image forming layer contains an emulsion sensitive to any of blue light, green light and red light.

Such an emulsion can be realized by selecting a spectral sensitizing dye. For example, an emulsion having sensitivity to any of blue light, green light, and red light as described above can be prepared, for example, by combining an emulsion having sensitivity to blue with a green-sensitizing dye and a red-sensitizing dye. .

The yellow image forming layer, the magenta image forming layer, the cyan image forming layer and the black image forming layer of the present invention are laminated and coated on a support, but the order from the support may be any order. One preferred embodiment is, for example, from the side closer to the support, a cyan image forming layer, a magenta image forming layer,
It becomes a yellow image forming layer and a black image forming layer. In addition to these, an intermediate layer, a filter layer, a protective layer and the like can be arranged as required.

The fog treatment in the present invention can be carried out by exposing the entire surface or by using a compound which produces fog nuclei, that is, a fog agent.

The whole surface exposure is carried out by immersing the imagewise exposed light-sensitive material in a developing solution or other aqueous solution or moistening it and then uniformly exposing the whole surface. The light source used here may be any light source as long as it has light in the photosensitive wavelength region of the photosensitive material,
High illuminance light such as flash light may be applied for a short time, or weak light may be applied for a long time.

The total exposure time can be varied over a wide range depending on the photosensitive material, the development processing conditions, the type of light source used, etc. so as to finally obtain the best positive image.

Further, it is most preferable that the exposure amount of the whole surface exposure gives a certain range of exposure amount in combination with the photosensitive material. Usually, if the exposure amount is excessively increased, the minimum density is increased or desensitized, and the image quality tends to be deteriorated.

Next, the fog agent preferably used in the present invention will be described.

A wide variety of compounds can be used as the fog agent used in the present invention, and the fog agent only needs to be present at the time of development processing. For example, in the constituent layers other than the support of the light-sensitive material (in particular It is preferably contained in a silver halide emulsion layer) or in a developing solution or a processing solution prior to the developing processing. The amount used can be varied over a wide range according to the purpose. The preferable amount added is 1 to 1,500 mg, preferably 10 to 10 mg per mol of silver halide when added to the silver halide emulsion layer. 1,0
It is 00 mg. When it is added to a processing solution such as a developing solution, the preferable addition amount is 0.01 to 5 g / l, particularly preferably 0.05 to 1 g.
/ L.

Examples of the fogging agent used in the present invention include hydrazines described in US Pat. Nos. 2,563,785 and 2,588,982 or US Pat.
Hydrazide or hydrazine compound described in US Pat. No. 3,615,615, US Pat. Nos. 3,615,615, 3,718,479, 3,719,49
No. 4, 3,734,738 and 3,759,901, heterocyclic quaternary nitrogen salt compounds; further compounds having an adsorption group on the surface of silver halide such as acylhydrazinophenylthioureas described in US Pat. No. 4,030,925. Is mentioned.
Further, these fogging agents can be used in combination. For example, the above-mentioned RD15162 describes that a non-adsorption type fogging agent is used in combination with an adsorption type fogging agent, and this combination technique is also effective in the present invention. In the present invention, both an adsorption type and a non-adsorption type can be used, or they can be used in combination.

Specific examples of useful fogging agents include hydrazine hydrochloride, 4-methylphenylhydrazine hydrochloride, 1-acetyl-2-phenylhydrazine, 1-formyl-2- (4-methylphenyl) hydrazine, 1- Hydrazine compounds such as methylsulfonyl-2-phenylhydrazine, 1-methylsulfonyl-2- (3-phenylsulfonamidophenyl) hydrazine, 1-benzoyl-2-phenylhydrazine, formaldehydephenylhydrazine; 3- (2-formylethyl) -2-methylbenzothiazolium bromide, 3- (2-acetylethyl) -2-benzyl-5-phenylbenzoxazolium bromide, 3- (2-acetylethyl) -2-benzylbenzoselenazolium bromide, 2-Methyl-3- [3- (phenylhydrazino) propyl] benzothiazolium bromide, 1,2
-Dihydro-3-methyl-4-phenylpyrido [2,1-b] benzothiazolium bromide, 1,2-dihydro-3-methyl-4-phenylpyrido [2,1-b] benzoselenazolium bromide,
4,4'-Ethylenebis (1,2-dihydro-3-methylpyrido [2,1
-b] N-substituted quaternary cycloammonium salts such as benzothiazolium bromide; 5- (3-ethyl-2-benzothiazolinylidene) -3- [4- (2-formylhydrazino) phenyl] Rhodanine, 1,3-bis [4- (2-formylhydrazino) phenyl] thiourea, 7- (3-ethoxythiocarbonylaminobenzamide) -9-methyl-10-propargyl-1,2,3,4- Examples thereof include latrahydroacridinium trifluoromethanesulfonate and 1-formyl-2- [4- {3- (2-methoxyphenyl) ureido} phenyl] hydrazine.

The light-sensitive material having a silver halide emulsion layer according to the present invention forms a positive image directly after imagewise exposure or by developing treatment in the presence of a fogging agent.

Next, the color developing agent used in the present invention will be described.

The color developing agent used in the color developing solution of the present invention is preferably a p-phenylenediamine compound having a water-soluble group, and the water-soluble group is at least on the amino group or benzene nucleus of the p-phenylenediamine compound. There is one.

A preferable water-soluble group is-(CH ₂ ) _n CH ₂ O.
H, − (CH ₂ ) _m NHSO ₂ (CH ₂ ) _n CH ₃ , − (CH ₂ ) _m O (CH ₂ ) _n CH ₃ , −
Examples thereof include (CH ₂ CH ₂ O) _n C _m H _{2m + 1} (m and n each represent an integer of 0 or more), —COOH, —SO ₃ H and the like.

Typical specific examples are shown below, but the present invention is not limited thereto.

[0052]

[Chemical 1]

Among these, the color developing agent represented by CD-2 is particularly preferable.

The amount of color developing agent added is 0.01 mol / l or more, preferably 0.015 to 0.03 mol / l.

To the color developing solution, known alkali agents, preservatives, antifoggants, fluorescent whitening agents, antifoaming agents, color accelerators and the like can be added.

Although the color developing time is not particularly limited, it is usually
It is 30 seconds to 4 minutes, and the color developing temperature is usually 20 to 45 ° C. The replenishing amount of the color developing solution is preferably ²⁰ to 600 ml / m ² , and more preferably 50 to 400 ml / m ² .

The developer used in the present invention may further contain a specific antifoggant and development inhibitor, or these developer additives may be optionally incorporated in the constituent layers of the photographic light-sensitive material. Is also possible.

Known photographic additives can be used in the light-sensitive material of the present invention.

Known photographic additives include, for example, the compounds described in RD17643 and RD18716 shown below.

Additives RD17643 RD18716 Page classification Page classification Chemical sensitizer 23 III 648 Upper right sensitizing dye 23 IV 648 Upper right development accelerator 29 XXI 648 Upper right antifoggant 24 VI 649 Lower right stabilizer Stabilization 〃 Color contamination prevention Agent 25 VII 650 Left-right Image stabilizer 25 VII UV absorber 25-26 VII 649 Right-650 left Filter dye 〃 〃 Whitening agent 24 V Hardener 26 X 651 Right Coating aid 26-27 XI 650 Right interface Activator 26-27 XI 650 Right Plasticizer 27 XII 650 Right Sliding agent 〃 〃 Static inhibitor 〃 〃 Matting agent 28 XVI 650 Right binder 29 IX 651 Right In the emulsion layer of the light-sensitive material according to the present invention, a color developing agent is used. A dye-forming coupler capable of forming a dye by a coupling reaction with an oxidant thereof can be used. The dye-forming couplers are usually selected for each emulsion layer so that a dye that absorbs the light in the light-sensitive spectrum of the emulsion layer is formed, and in the blue-sensitive emulsion layer the yellow dye-forming coupler is the green dye. A magenta dye forming coupler is used in the sensitive emulsion layer and a cyan dye forming coupler is used in the red sensitive emulsion layer. However, the color light-sensitive material may be produced by a method different from the above combination depending on the purpose.

These dye-forming couplers preferably have a group called a ballast group having a carbon number of 8 or more, which makes the coupler non-diffusible, in the molecule. Also, these dye-forming couplers need only reduce 4 molecules of silver ions in order to form 1 molecule of dye, but they need only reduce 2 molecules of silver ion even if they are 4 equivalence. Either of two equivalence may be used. Releases a development inhibitor along with development, releases a development inhibitor at the same time as a DIR coupler that improves image sharpness and image graininess, and produces a colorless compound by coupling reaction with an oxidized product of a developing agent. DIR compounds may be used.

The DIR coupler and the DIR compound used have an inhibitor directly bound to the coupling position and an inhibitor bound to the coupling position via a divalent group, and are separated by the coupling reaction. Those which are bonded so as to release the inhibitor by intramolecular nucleophilic reaction, intramolecular electron transfer reaction and the like (referred to as timing DIR coupler and timing DIR compound) are included.

A colorless coupler (also referred to as a competing coupler) which undergoes a coupling reaction with an oxidized product of an aromatic primary amine developer but does not form a dye can be used in combination with the dye-forming coupler.

As the yellow dye-forming coupler, known acylacetanilide type couplers can be preferably used. Among these, benzoylacetanilide compounds and pivaloylacetanilide compounds are advantageous.

As the magenta dye-forming coupler, known 5-pyrazolone type couplers, pyrazolobenzimidazole type couplers, pyrazoloazole type couplers, acylacetonitrile type couplers, indazolone type couplers and the like can be used. A magenta coupler represented by the formula [MI] is preferred.

[0066]

[Chemical 2]

In the formula, Z represents a non-metal atom group necessary for forming a nitrogen-containing heterocycle, and the ring formed by Z may have a substituent. X represents a hydrogen atom or a group capable of splitting off upon reaction with an oxidized product of a color developing agent, and R represents a hydrogen atom or a substituent.

In the above general formula [MI], the substituent represented by R is not particularly limited, but is typically alkyl, aryl, anilino, acylamino, sulfonamide, alkylthio, arylthio, alkenyl, cycloalkyl. Other groups such as halogen atom and cycloalkenyl, alkynyl, heterocycle, sulfonyl, sulfinyl, phosphonyl, acyl, carbamoyl, sulfamoyl, cyano, alkoxy, aryloxy, heterocycleoxy, siloxy, acyloxy, and the like. Carbamoyloxy, amino, alkylamino, imide, ureido, sulfamoylamino, alkoxycarbonylamino, aryloxycarbonylamino, alkoxycarbonyl, aryloxycarbonyl, heterocyclic thio groups, and spiro formation Compound residues, bridged hydrocarbon compound residues and the like are also included.

The substituent represented by R, the group represented by X which can be split off by the reaction with the oxidation product of the color developing agent, the nitrogen-containing heterocycle formed by Z and the ring formed by Z may have. The preferred range and specific examples of the substituents, and the preferred range of the magenta coupler represented by the general formula [MI] are the same as those described in EP 0327272, page 5, line 23 to page 8, line 52. ..

Typical specific examples of the magenta coupler represented by the general formula [MI] are shown below.

[0071]

[Chemical 3]

[0072]

[Chemical 4]

[0073]

[Chemical 5]

[0074]

[Chemical 6]

As another specific example, European Patent Publication 0273
Compounds M-1 to M-6 described in No. 712, pages 6 to 21.
1 and Compound 1 described in No. 0235913, pages 36 to 92
~ 223 other than the above representative examples.

The above-mentioned couplers can be used in combination with other types of magenta couplers, and usually 1 × 10 ⁻³ to 1 mol, preferably 1 × 10 ⁻² to 8 × 10 1 mol per mol of silver halide.
It can be used in the range of ^-1 mol.

As the cyan dye-forming coupler, known phenol-based, naphthol-based or imidazole-based couplers can be used. Typical examples are phenol-based couplers substituted with an alkyl group, an acylamino group, or a ureido group, naphthol-based couplers formed from a 5-aminonaphthol skeleton, and 2-equivalent naphthol-based couplers having an oxygen atom introduced as a leaving group. To be done.

The support which can be used in the light-sensitive material of the present invention includes, for example, RD17643, page 28 and RD18716 described above.
Those described on page 647 can be mentioned. Suitable supports are polymer films, papers and the like, which may be treated for enhancing the adhesiveness, antistatic property and the like.

[0079]

The present invention will be described in detail below with reference to examples, but the present invention is not limited thereto.

Example 1 (Preparation of Emulsion EM-1) While controlling the aqueous solution containing ossein gelatin at 40 ° C., the aqueous solution containing ammonia and silver nitrate, potassium bromide and sodium chloride (KB in molar ratio).
An aqueous solution containing r: NaCl = 95: 5) was simultaneously added by the control double jet method to obtain a cubic silver chlorobromide core emulsion having a grain size of 0.30 μm. At that time, pH and pAg were controlled so as to obtain a cubic particle shape. The obtained core emulsion further contains an aqueous solution containing ammonia and silver nitrate, potassium bromide and sodium chloride (in molar ratio KBr: N
An aqueous solution containing aCl = 40: 60) was simultaneously added by the control double jet method to form a shell until the average particle size became 0.42 μm. At that time, pH and pAg were controlled so as to obtain a cubic particle shape.

After washing with water to remove water-soluble salts, gelatin was added to obtain an emulsion EM-1. The breadth of distribution of emulsion EM-1 was 8%.

(Preparation of Blue Sensitive Emulsion EM-B) After sensitizing EM-1 with sensitizing dye D-1, 600 mg of stabilizer T-1 was added per mol of silver to prepare blue sensitive emulsion EM-B. It was made.

(Preparation of Green Sensitive Emulsion EM-G) A green sensitive emulsion EM-G was prepared in the same manner as the blue sensitive emulsion except that the sensitizing dye D-2 was added to EM-1 for color sensitization.

(Preparation of Red Sensitive Emulsion EM-R) A red sensitive emulsion EM-R was prepared in the same manner as the blue sensitive emulsion except that the sensitizing dye D-3 was added to EM-1 for color sensitization.

(Preparation of Pan-Sensitive Emulsion EM-P) A pan-sensitive emulsion was prepared in the same manner as in the blue-sensitive emulsion except that sensitizing dyes D-1, D-2 and D-3 were added to EM-1 for color sensitization. Emulsion EM-P was prepared.

(Preparation of Infrared Sensitive EM-I) A pan-sensitive emulsion EM-I was prepared in the same manner as the blue-sensitive emulsion except that the sensitizing dye D-4 was added to EM-1 for color sensitization. ..

T-1: 4-hydroxy-6-methyl-1,3,3a, 7
-Tetrazaindene

[0088]

[Chemical 7]

Using the above EM-B, EM-G and EM-R, the 1st to 8th layers were coated in the following constitution on the surface of a support laminated on both sides with polyethylene. Sample-1 was prepared using SA-1 and SA-2 as the coating aid and H-1 as the hardener. The applied amount is
It is shown in g / m ² .

Layer composition Coating amount Eighth layer Gelatin 0.78 (UV absorbing layer) UV absorber (UV-1) 0.065 UV absorbing layer (UV-2) 0.195 Solvent (SO-2) 0.1 Colloidal silica 0.03 Seventh layer Gelatin 1.43 (Blue sensitive layer) Blue sensitive emulsion EM-B (Amount of coated silver) 0.50 Yellow coupler (YC-1) 0.82 Anti-staining agent (AS-2) 0.025 Solvent (SO-1) 0.82 Inhibitor (ST-1, ST-2, T-1) Sixth layer Gelatin 0.54 (Intermediate layer) Anti-color mixing agent (AS-1) 0.055 Solvent (SO-2) 0.072 Fifth layer Gelatin 0.42 (Yellow yellow colloidal silver 0.10 Colloidal silver layer) Color mixing prevention Agent (AS-1) 0.04 Solvent (SO-2) 0.049 Polyvinylpyrrolidone (PVP) 0.047 Fourth layer gelatin 0.54 (Intermediate layer) Color mixture inhibitor (AS-1) 0.055 Solvent (SO-2) 0.072 Third layer gelatin 1.43 (green Sensitive layer) Green-sensitive emulsion EM-G (coating silver amount) 0.50 Magenta coupler (MC-1) 0.25 Anti-staining agent (AS-2) 0.019 Solvent (SO-1) 0.31 Anti-irradiation dye (AI-1) 0.01 Inhibitors (ST-1, ST-2, T-1) Second layer Gelatin 0.75 (Intermediate layer) Color mixture inhibitor (AS-1) 0.055 Solvent (SO-2) 0.072 First layer Gelatin 1.38 (Red sensitive layer) ) Red-sensitive emulsion EM-R (amount of coated silver) 0.30 Cyan coupler (CC-1) 0.44 Solvent (SO-1) 0.31 Anti-stain agent (AS-2) 0.015 Anti-irradiation dye (AI-2) 0.01 Inhibitor ( ST-1, ST-2, T-1) In the same manner as the above-mentioned Sample-1, the EM-B, EM-G, E
A color light-sensitive material sample-2 having the following constitution was prepared by using MR and EM-P. The applied amount is shown in g / m ² .

Layer composition Coating amount 10th layer Gelatin 0.78 (UV absorbing layer) UV absorber (UV-1) 0.065 UV absorbing layer (UV-2) 0.195 Solvent (SO-2) 0.10 Colloidal silica 0.03 9th layer Gelatin 1.05 (pan-sensitive layer) Pan-sensitive emulsion EM-P (coating silver amount) 0.30 Yellow coupler (YC-1) 0.21 Magenta coupler (MC-1) 0.063 Cyan coupler (CC-1) 0.110 Anti-stain agent (AS-2) ) 0.019 Solvent (SO-1) 0.615 Eighth layer Gelatin 0.75 (Intermediate layer) Color mixing inhibitor (AS-1) 0.055 Solvent (SO-2) 0.072 Seventh layer Gelatin 1.14 (Blue sensitive layer) Blue sensitive emulsion EM -B (Amount of coated silver) 0.4 Yellow coupler (YC-1) 0.656 Anti-stain agent (AS-2) 0.02 Solvent (SO-1) 0.656 Inhibitor (ST-1, ST-2, T-1) 6th layer Gelatin 0.54 (middle layer) mixed Color inhibitor (AS-1) 0.055 Solvent (SO-2) 0.072 Fifth layer Gelatin 0.42 (YC layer) Yellow colloidal silver 0.1 Color mixture inhibitor (AS-1) 0.04 Solvent (SO-2) 0.049 Polyvinylpyrrolidone (PVP) ) 0.047 4th layer Gelatin 0.54 (Intermediate layer) Anti-color mixing agent (AS-1) 0.055 Solvent (SO-2) 0.072 3rd layer Gelatin 1.14 (Green-sensitive layer) Green-sensitive emulsion EM-G (Amount of coated silver) 0.40 Magenta Coupler (MC-1) 0.20 Anti-staining agent (AS-2) 0.012 Solvent (SO-1) 0.248 Anti-irradiation dye (AI-1) 0.01 Inhibitor (ST-1, ST-2, T-1) Second Layer Gelatin 0.75 (Intermediate layer) Anti-color mixing agent (AS-1) 0.055 Solvent (SO-2) 0.072 First layer Gelatin 1.10 (Red sensitive layer) Red sensitive emulsion EM-R (Amount of coated silver) 0.24 Cyan coupler ( CC-2) 0.352 Solvent (SO-1 ) 0.248 Anti-staining agent (AS-2) 0.012 Anti-irradiation dye (AI-2) 0.01 Inhibiting agent (ST-1, ST-2, T-1) In the same manner as in Sample-1, the above EM-B, EM -G, EM-
Using R and EM-I, a color light-sensitive material sample-3 having the following constitution was prepared. The applied amount is shown in g / m ² .

Layer composition Coating amount 10th layer Gelatin 0.78 (UV absorbing layer) UV absorber (UV-1) 0.065 UV absorbing layer (UV-2) 0.195 Solvent (SO-2) 0.10 Colloidal silica 0.03 9th layer Gelatin 1.14 (Blue-sensitive layer) Blue-sensitive emulsion EM-B (Amount of coated silver) 0.4 Yellow coupler (YC-1) 0.656 Anti-stain agent (AS-2) 0.02 Solvent (SO-1) 0.656 Inhibitor (ST-1, ST-2, T-1) Eighth layer Gelatin 0.54 (Intermediate layer) Anti-color mixing agent (AS-1) 0.055 Solvent (SO-2) 0.072 Seventh layer Gelatin 0.42 (YC layer) Yellow colloidal silver 0.10 Color mixing prevention Agent (AS-1) 0.04 Solvent (SO-2) 0.049 Polyvinylpyrrolidone (PVP) 0.047 6th layer Gelatin 0.54 (Intermediate layer) Color mixture inhibitor (AS-1) 0.055 Solvent (SO-2) 0.072 5th layer Gelatin 1.14 (Green layer) Green Emulsion EM-G (coated silver amount) 0.40 Magenta coupler (MC-1) 0.20 Anti-staining agent (AS-2) 0.0152 Solvent (SO-1) 0.248 Anti-irradiation dye (AI-1) 0.01 Inhibitor (ST- 1, ST-2, T-1) 4th layer gelatin 0.75 (intermediate layer) Anti-color mixing agent (AS-1) 0.055 solvent (SO-2) 0.072 3rd layer gelatin 1.10 (red sensitive layer) red sensitive emulsion EM- R (coated silver amount) 0.24 Cyan coupler (CC-2) 0.352 Solvent (SO-1) 0.248 Anti-staining agent (AS-2) 0.012 Anti-irradiation dye (AI-2) 0.01 Inhibitor (ST-1, ST-) 2, T-1) Second layer gelatin 0.75 (intermediate layer) Color mixing inhibitor (AS-1) 0.055 Solvent (SO-2) 0.072 First layer gelatin 1.05 (infrared photosensitive layer) Infrared photosensitive emulsion EM-I (Amount of coated silver) 0.30 Yellow coupler (YC-1) 0.21 Magenta Puller (MC-1) 0.063 Cyan coupler (CC-1) 0.110 Stain preventing agent (AS-2) 0.019 solvent (SO-1) additives used in 0.615 sample preparation is as follows.

SA-1: sulfosuccinic acid di (2-ethylhexyl) ester-sodium SA-2: sulfosuccinic acid di (2,2,3,3,4,4,5,5-octafluoropentyl) ester- Sodium H-1: 2,4-dichloro-6-hydroxy-s-triazine / sodium AS-1: 2,5-di-t-octylhydroquinone AS-2: 2,5-di-t-butylhydroquinone SO- 1: Trioctyl phosphate SO-2: Dioctyl phthalate ST-1: 1- (3-acetamido) phenyl-5-mercaptotetrazole ST-2: N-benzyladenine

[0094]

[Chemical 8]

[0095]

[Chemical 9]

For the sample-1 obtained as described above,
Of the original halftone dots, a black plate and a cyan plate were brought into close contact with each other and exposed under the exposure condition-1 shown below. Next, the black plate and the magenta plate were brought into close contact with the sample and exposed under the exposure condition-2 shown below. Further, the black plate and the yellow plate were brought into close contact with the sample and exposed under the exposure condition-3 shown below.

Next, Sample-2 was exposed under the exposure conditions of 1-3 in the same manner as Sample-1.

Further, similarly to the sample-1, the sample-3 was sequentially exposed under the exposure conditions 1 to 3, and only the black plate of the original document was brought into close contact with it, and exposed under the exposure condition-4 shown below.

The exposed light-sensitive material thus obtained was processed by the development processing steps shown below, and the density of the obtained dye image was measured. Compared with the proof density. The concentration was measured with PD-65 manufactured by Konica Corporation.

(Exposure condition-1) When each photosensitive material was exposed to white light through a red filter (Ratten No. 26) and an ND filter, the density of the ND filter was adjusted so that the red light density after the following development treatment was With minimum exposure
Expose for 0.5 seconds.

(Exposure condition-2) When each photosensitive material was exposed to white light through a green filter (Ratten No. 58) and an ND filter, the density of the ND filter was adjusted so that the green light density after the following development treatment was With minimum exposure
Expose for 0.5 seconds.

(Exposure condition-3) Each of the light-sensitive materials was passed through a blue filter (Ratten No. 47B) and an ND filter, and when the white light was exposed, the ND filter density was adjusted so that the green light density after the following development processing was Expose for a minimum of 0.5 seconds with the minimum exposure.

(Exposure condition-4) The ND filter density was adjusted when the tungsten light was exposed through the infrared filter and the ND filter to the samples which were sequentially exposed with the respective light-sensitive materials under the above exposure conditions-1 to 3. Then, it is exposed for 0.5 seconds with the minimum exposure amount that minimizes the visible light density after the development processing described below. Exposure condition only through the infrared filter-
Set to 4.

A daylight fluorescent lamp was used as a light source under exposure conditions-1 to 3.

Processing was performed according to the following processing steps to obtain a photographic image. However, the fog exposure was carried out with the surface of the photosensitive material uniformly exposed through the layer of the developing solution having a thickness of 3 mm while being immersed in the developing solution.

Processing Step-1 Temperature Time Immersion (Developer) 37 ° C 12 seconds Fog exposure-12 seconds (1 lux) Image 37 ° C 95 seconds Bleach-fixing 35 ° C 45 seconds Stabilization 25-30 ° C 90 seconds Dry 60-85 ° C 40 seconds Treatment liquid composition is as follows.

(Color developer) Benzyl alcohol 15.0 ml Cerium sulfate 0.015 g Ethylene glycol 8.0 ml Potassium sulfite 2.5 g Potassium bromide 0.6 g Sodium chloride 0.2 g Potassium carbonate 25.0 g T-1 0.1 g Hydroxylamine sulfate 5.0 g Diethylenetriamine 5 Sodium acetate 2.0g Color developing agent (CD-2) 4.5g Optical brightener (4,4'-diaminostilbene disulfonic acid derivative) 1.0g Potassium hydroxide 2.0g Diethylene glycol 15.0ml Add water to make the total volume 1000ml, pH To 10.15.

(Bleach-fixing solution) Diethylenetriamine 5 ferric ammonium acetate 90.0 g Diethylenetriamine 5 acetic acid 3.0 g Ammonium thiosulfate (70% aqueous solution) 180.0 ml Ammonium sulfite (40% aqueous solution) 27.5 ml 3-Mercapto-1,2,4- Triazole 0.15g Adjust the pH to 7.1 with potassium carbonate or glacial acetic acid and add water to bring the total volume to 1000 ml.

(Stabilizing liquid) o-Phenylphenol 0.3 g Potassium sulfite (50% aqueous solution) 12 ml Ethylene glycol 10.0 g 1-Hydroxyethylidene-1,1-diphosphonic acid 2.5 g Bismuth chloride 0.2 g Zinc sulfate heptahydrate 0.7 g Ammonium hydroxide (28% aqueous solution) 2.0 g Polyvinylpyrrolidone (K-17) 0.2 g Fluorescent brightener (4,4'-diaminostilbene disulfonic acid derivative) 2.0 g Add water to make 1000 ml, and add ammonium hydroxide or Adjust the pH to 7.5 with sulfuric acid.

The stabilization treatment was a countercurrent system having a two-tank construction. The developing treatment was continuously performed until the replenishing amount of the color developing solution became three times the developing tank capacity (3 rounds).

The results are shown in Table 1.

[0112]

[Table 1]

As is clear from the results shown in Table 1, the sample-2 of the present invention has a density close to that of proof printing (printing) even if the replenishment amount is decreased, and a good color tone can be obtained by three times of exposure. It was On the other hand, it can be seen that the comparatively good Sample-3 requires a large number of exposures, and thus the workability is heavily burdened.

Example 2 Example 1 was repeated except that the emulsion used was changed from EM-1 to EM-2 below, and the effect of the present invention was obtained.

(Preparation of emulsion EM-2) An equimolar silver nitrate aqueous solution and potassium bromide aqueous solution were added to a gelatin aqueous solution at 50 ° C.
Simultaneous addition by the double jet method over 50 minutes,
An emulsion consisting of cubic silver bromide grains having an average grain size of 0.3 μm was obtained. To this emulsion, 6.5 mg of sodium thiosulfate and 3 mg of potassium chloroaurate were added per 1 mol of silver, and the mixture was chemically ripened at 70 ° C. for 70 minutes, followed by further addition of an aqueous silver nitrate solution and sodium chloride.
-A potassium bromide mixed solution (molar ratio 1: 9) was added at the same time to prepare a cubic core / shell type emulsion consisting of a silver bromide core having an average particle size of 0.45 µm and a silver chlorobromide shell. After desalting with water, 2.0 mg of sodium thiosulfate and 1.0 mg of potassium chloroaurate per mol of silver were added to this emulsion, and the emulsion was heated to 60 ° C. for 50 minutes.
Direct positivity silver halide emulsion EM-
Got 2. The breadth of distribution of emulsion EM-2 was 12%.

Example 3 Using EM-1 used in Example 1, the following emulsion was prepared.

(Preparation of Green Sensitive Emulsion EM-1G) EM-1
After the color sensitization by adding sensitizing dye D-2, 600 mg of T-1 was added per mol of silver, and FA-1 and FA-2 were further added to silver 1.
A green-sensitive emulsion EM-1G was prepared by adding 8 × 10 ⁻⁵ mol and 5 × 10 ⁻⁴ mol, respectively, per mol.

(Preparation of Red Sensitive Emulsion EM-1R) EM-1
A red-sensitive emulsion EM-1R was prepared in the same manner as the green-sensitive emulsion except that the sensitizing dye D-3 was added to the mixture to carry out color sensitization.

(Preparation of Infrared Photosensitive Emulsion EM-1I) EM
An infrared-sensitive emulsion EM-1I was prepared in the same manner as the green-sensitive emulsion except that the sensitizing dye D-4 was added to -1 for color sensitization.

(Preparation of pan-sensitive emulsion EM-1P) EM-2
General Sensitive Emulsion EM-1P was prepared in the same manner as the green sensitive emulsion except that the sensitizing dyes D-2, D-3 and D-4 were added to the emulsion.
Was produced.

[0121]

[Chemical 10]

(Preparation of Sample-4) Sample of Example 1-
In the same manner as 1 above, EM-1G, EM-1R, EM-1
A color light-sensitive material sample-4 having the following constitution was prepared using I and EM-1P. The coating amount is also shown in g / m ² .

Layer composition Coating amount Eighth layer Gelatin 0.78 (UV absorbing layer) UV absorber (UV-1) 0.065 UV absorbing layer (UV-2) 0.195 Solvent (SO-2) 0.10 Colloidal silica 0.03 Seventh layer Gelatin 1.05 (pan-sensitive layer) Pan-sensitive emulsion EM-1P (amount of coated silver) 0.30 Yellow coupler (YC-1) 0.21 Magenta coupler (MC-1) 0.063 Cyan coupler (CC-1) 0.110 Anti-stain agent (AS-2) ) 0.019 Solvent (SO-1) 0.615 6th layer Gelatin 0.75 (Intermediate layer) Anti-color mixing agent (AS-1) 0.055 Solvent (SO-2) 0.072 5th layer Gelatin 1.14 (Green-sensitive layer) Green-sensitive emulsion EM-1G (Amount of coated silver) 0.40 Yellow coupler (YC-1) 0.656 Anti-stain agent (AS-2) 0.02 Solvent (SO-1) 0.656 Anti-irradiation dye (AI-1) 0.01 Inhibitor (ST-1, ST-2) , -1) Fourth layer Gelatin 0.75 (Intermediate layer) Color mixture inhibitor (AS-1) 0.055 Solvent (SO-2) 0.072 Third layer Gelatin 1.14 (Red sensitive layer) Red sensitive emulsion EM-1R (Coating) Silver amount) 0.40 Magenta coupler (MC-1) 0.20 Anti-staining agent (AS-2) 0.0152 Solvent (SO-1) 0.248 Anti-irradiation dye (AI-2) 0.01 Inhibitor (ST-1, ST-2, T) -1) Second layer gelatin 0.75 (intermediate layer) Color mixing inhibitor (AS-1) 0.055 Solvent (SO-2) 0.072 First layer gelatin 1.10 (infrared photosensitive layer) Infrared photosensitive emulsion EM-1I (coated silver) Amount) 0.24 Cyan coupler (CC-3) 0.352 Solvent (SO-1) 0.248 Anti-staining agent (AS-2) 0.012 Inhibitor (ST-1, ST-2, T-1) Sample-4, halftone dot Stick the black and cyan plates of the original manuscript together and It was exposed under the condition -5. Next, the black plate and the magenta plate were brought into close contact with the sample and exposed under exposure condition -6. Further, the black plate and the yellow plate were brought into close contact with the sample and exposed under exposure condition -7.

[0124] The treatment steps shown below for the exposed sample-
2, the density of the obtained dye image is measured,
Further, it was compared with the density of the proof print obtained from the halftone dot original document 4th edition. The concentration is measured by Konica PD-65.
It was used.

(Exposure condition-5) When exposing the sample-4 to the tungsten light through the infrared filter and the ND filter, the ND filter density is adjusted to minimize the red density after the development process. Expose for 0.5 seconds.

(Exposure condition-6) When the sample-4 is exposed to tungsten light through a red filter (Ratten No. 26) and an ND filter, the ND filter density is adjusted to minimize the green density after development processing. 0.5 with minimum exposure
Expose for a second.

(Exposure condition-7) When the sample-4 is exposed to tungsten light through a green filter (Ratten No.58) and an ND filter, the ND filter density is adjusted to minimize the blue density after development processing. 0.5 with minimum exposure
Expose for a second.

Processing Step-2 Temperature Time Image 37 ° C. 130 seconds Bleaching / fixing 35 ° C. 45 seconds Stabilization 25-30 ° C. 90 seconds Drying 60-85 ° C. 40 seconds Developing solution, bleach-fixing solution, stable The formulation of each treatment liquid of the chemical liquid is exactly the same as that used in Example 1.
The stabilization treatment was a countercurrent system with a two tank structure. The results obtained are shown in Table 2.

[0129]

[Table 2]

From the comparison with the proof, as in the first embodiment,
Sample-4 of the present invention was able to obtain a good color tone close to that of proof printing after three exposures, even if the replenishment amount was small.

Example 4 Example 3 was repeated except that the emulsion was replaced with EM-2 used in Example 2, and the effect of the present invention was obtained.

Example 5 In Example 1, the color-developing agent used is exemplified as CD-
When Example 1 was repeated in exactly the same manner except that it was changed to 1, the effect of the present invention was obtained.

[0133]

By using the silver halide color photographic light-sensitive material of the present invention, it is possible to obtain a color proof in which the degree of approximation of the image quality with the printed matter is improved by three exposures. Further, the replenishment of the color developing solution was reduced, and the environmental suitability was improved.

Claims (1)

[Claims] 1. A support comprising at least one yellow image-forming silver halide emulsion layer containing silver halide grains having different spectral sensitivities, at least one magenta image-forming silver halide emulsion layer, and at least one layer. In a silver halide color photographic light-sensitive material having one cyan image forming silver halide emulsion layer and at least one black image forming layer containing silver halide grains, the black image forming layer is the yellow image forming layer. The silver halide emulsion layer, the magenta image-forming silver halide emulsion layer, and the cyan image-forming silver halide emulsion layer each have a spectral sensitivity region having a common part with the spectral sensitivity region, and the replenishing amount of the color developing solution is A silver halide color photographic light-sensitive material, which is processed with a processing solution of 1000 ml / m ² or less.