JPH05154352A - Method of exhaust gas treatment - Google Patents
Method of exhaust gas treatmentInfo
- Publication number
- JPH05154352A JPH05154352A JP4080875A JP8087592A JPH05154352A JP H05154352 A JPH05154352 A JP H05154352A JP 4080875 A JP4080875 A JP 4080875A JP 8087592 A JP8087592 A JP 8087592A JP H05154352 A JPH05154352 A JP H05154352A
- Authority
- JP
- Japan
- Prior art keywords
- exhaust gas
- dust
- nitrogen oxides
- gas treatment
- porous ceramics
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000000034 method Methods 0.000 title description 6
- MWUXSHHQAYIFBG-UHFFFAOYSA-N nitrogen oxide Inorganic materials O=[N] MWUXSHHQAYIFBG-UHFFFAOYSA-N 0.000 claims abstract description 45
- 239000007789 gas Substances 0.000 claims abstract description 37
- 239000000428 dust Substances 0.000 claims abstract description 20
- XHCLAFWTIXFWPH-UHFFFAOYSA-N [O-2].[O-2].[O-2].[O-2].[O-2].[V+5].[V+5] Chemical compound [O-2].[O-2].[O-2].[O-2].[O-2].[V+5].[V+5] XHCLAFWTIXFWPH-UHFFFAOYSA-N 0.000 claims abstract description 5
- 238000011001 backwashing Methods 0.000 claims abstract description 5
- 229910001935 vanadium oxide Inorganic materials 0.000 claims abstract description 5
- 239000000919 ceramic Substances 0.000 claims description 13
- 239000004071 soot Substances 0.000 claims description 7
- 239000011149 active material Substances 0.000 claims description 6
- QGLKJKCYBOYXKC-UHFFFAOYSA-N nonaoxidotritungsten Chemical compound O=[W]1(=O)O[W](=O)(=O)O[W](=O)(=O)O1 QGLKJKCYBOYXKC-UHFFFAOYSA-N 0.000 claims description 5
- 229910001930 tungsten oxide Inorganic materials 0.000 claims description 5
- 238000003672 processing method Methods 0.000 claims 1
- 239000003054 catalyst Substances 0.000 abstract description 14
- 230000003197 catalytic effect Effects 0.000 abstract description 2
- 229910010293 ceramic material Inorganic materials 0.000 abstract 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 abstract 2
- 229910021529 ammonia Inorganic materials 0.000 abstract 1
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 abstract 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 4
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 description 4
- 239000012190 activator Substances 0.000 description 3
- 239000002245 particle Substances 0.000 description 3
- 239000000376 reactant Substances 0.000 description 3
- 229910052581 Si3N4 Inorganic materials 0.000 description 2
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 2
- 229910052878 cordierite Inorganic materials 0.000 description 2
- JSKIRARMQDRGJZ-UHFFFAOYSA-N dimagnesium dioxido-bis[(1-oxido-3-oxo-2,4,6,8,9-pentaoxa-1,3-disila-5,7-dialuminabicyclo[3.3.1]nonan-7-yl)oxy]silane Chemical compound [Mg++].[Mg++].[O-][Si]([O-])(O[Al]1O[Al]2O[Si](=O)O[Si]([O-])(O1)O2)O[Al]1O[Al]2O[Si](=O)O[Si]([O-])(O1)O2 JSKIRARMQDRGJZ-UHFFFAOYSA-N 0.000 description 2
- KZHJGOXRZJKJNY-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Si]=O.O=[Al]O[Al]=O.O=[Al]O[Al]=O.O=[Al]O[Al]=O KZHJGOXRZJKJNY-UHFFFAOYSA-N 0.000 description 2
- 229910052863 mullite Inorganic materials 0.000 description 2
- 239000008188 pellet Substances 0.000 description 2
- HBMJWWWQQXIZIP-UHFFFAOYSA-N silicon carbide Chemical compound [Si+]#[C-] HBMJWWWQQXIZIP-UHFFFAOYSA-N 0.000 description 2
- 229910010271 silicon carbide Inorganic materials 0.000 description 2
- 239000000377 silicon dioxide Substances 0.000 description 2
- HQVNEWCFYHHQES-UHFFFAOYSA-N silicon nitride Chemical compound N12[Si]34N5[Si]62N3[Si]51N64 HQVNEWCFYHHQES-UHFFFAOYSA-N 0.000 description 2
- 238000004056 waste incineration Methods 0.000 description 2
- 239000002699 waste material Substances 0.000 description 2
- 238000000151 deposition Methods 0.000 description 1
- GNTDGMZSJNCJKK-UHFFFAOYSA-N divanadium pentaoxide Chemical compound O=[V](=O)O[V](=O)=O GNTDGMZSJNCJKK-UHFFFAOYSA-N 0.000 description 1
- 239000010813 municipal solid waste Substances 0.000 description 1
- 150000004767 nitrides Chemical class 0.000 description 1
- 238000005245 sintering Methods 0.000 description 1
Landscapes
- Filtering Of Dispersed Particles In Gases (AREA)
- Exhaust Gas Treatment By Means Of Catalyst (AREA)
- Catalysts (AREA)
- Chimneys And Flues (AREA)
- Filtering Materials (AREA)
Abstract
Description
【０００１】[0001]
【産業上の利用分野】本発明は排ガス処理方法に関し、
特にボイラ、ディーゼル、都市ごみ焼却炉、焼結炉など
の窒素酸化物除去排ガス処理設備に有用なものである。FIELD OF THE INVENTION The present invention relates to a method for treating exhaust gas,
In particular, it is useful for nitrogen oxide removal exhaust gas treatment equipment such as boilers, diesel, municipal waste incinerators, and sintering furnaces.
【０００２】[0002]
【従来の技術】従来、上述した窒素酸化物除去用排ガス
処理設備から排出される窒素酸化物を除去し、かつばい
じんを捕集するためには次のように行なう。即ち、ハニ
カムまたはペレット状担体に触媒活性体を担持した触媒
を使って、反応剤としてＮＨ3を注入し、窒素酸化物を
除去する。そして、ばいじんは電気集塵機またはバグフ
ィルターにより捕集するシステムをとっている。2. Description of the Related Art Conventionally, in order to remove the nitrogen oxides discharged from the above-mentioned exhaust gas treatment equipment for removing nitrogen oxides and to collect the soot and dust, the following steps are performed. That is, NH 3 is injected as a reactant to remove nitrogen oxides by using a catalyst in which a catalytically active material is supported on a honeycomb or pellet carrier. And soot and dust has a system to collect by an electric dust collector or a bag filter.
【０００３】[0003]
【発明が解決しようとする課題】しかしながら、従来技
術によれば、排ガス中の窒素酸化物とばいじんを除去す
るためには、各々の除去を目的に、触媒機能及び集塵機
能を別々に備えた設備を必要としていた。However, according to the prior art, in order to remove nitrogen oxides and dust in the exhaust gas, an equipment having a catalyst function and a dust collecting function separately for the purpose of each removal. Was needed.
【０００４】本発明は上記事情に鑑みてなされたもの
で、従来のように触媒機能及び集塵機能を別々に備えた
設備を必要とすることなく、排ガス中の窒素酸化物とば
いじんを同時に除去して連続運転を可能にしえる排ガス
処理方法を提供することを目的とする。The present invention has been made in view of the above circumstances, and removes nitrogen oxides and dust in exhaust gas at the same time without the need for conventional equipment having a catalyst function and a dust collection function separately. It is an object of the present invention to provide an exhaust gas treatment method that enables continuous operation in a continuous manner.
【０００５】[0005]
【課題を解決するための手段】本発明者らは、ペレット
タイプやフロースルータイプのハニカム形状をした、Ｎ
Ｈ3 を反応剤とする窒化酸化物除去触媒（脱硝触媒）の
改善を目的に、集じん機能を兼備したフィルター型触媒
を見出だすべく、研究を進めてきたところ、The present inventors have developed a pellet type or flow-through type honeycomb shape with N
With the aim of improving a nitride oxide removal catalyst (denitration catalyst) that uses H 3 as a reactant, research has been conducted to find a filter-type catalyst that also has a dust collection function.
【０００６】ボイラ，ディーゼルプラント，都市ごみ焼
却プラントなどから排出される大容量の排ガスの処理に
は、酸化バナジウムと酸化タングステンからなる触媒活
性体を被覆した多孔質セラミックスに、ＮＨ3 を注入し
た排ガスを流通させることが有効であることを究明する
に至った。For treating a large amount of exhaust gas discharged from a boiler, a diesel plant, a municipal waste incineration plant, etc., an exhaust gas obtained by injecting NH 3 into a porous ceramics coated with a catalytically active material composed of vanadium oxide and tungsten oxide is used. It has been clarified that it is effective to distribute.
【０００７】即ち、本発明は、酸化バナジウムと酸化タ
ングステンからなる触媒活性体を被覆した多孔質セラミ
ックスに、ＮＨ3 を注入した排ガスを流通し、排ガス中
の窒素酸化物を前記触媒活性体により除去すると同時
に、排ガス中のばいじんを多孔質セラミックス表面に堆
積させて逆洗操作により払い落すことを特徴とする排ガ
ス処理方法である。That is, according to the present invention, the exhaust gas in which NH 3 is injected is circulated through the porous ceramics coated with the catalytically active material composed of vanadium oxide and tungsten oxide, and the nitrogen oxides in the exhaust gas are removed by the catalytically active material. At the same time, it is a method of treating exhaust gas, characterized by depositing soot and dust in the exhaust gas on the surface of the porous ceramics and removing it by backwashing.
【０００８】本発明ににおいて、多孔質セラミックスと
しては、例えばコ−ジライト、ムライト、ジルコニア、
アルミナ、シリカ、炭化珪素、窒化珪素、サイアロンが
挙げられる。In the present invention, examples of the porous ceramics include cordierite, mullite, zirconia,
Alumina, silica, silicon carbide, silicon nitride and sialon can be mentioned.
【０００９】[0009]
【作用】本発明によれば、酸化バナジウムと酸化タング
ステンからなる触媒活性体を被覆した多孔質セラミック
スに、ＮＨ3 を注入した排ガスを流通することにより、
排ガス中の窒素酸化物とばいじんとを同時に除去し、上
記多孔質セラミックス表面に堆積したばいじんを逆風又
は逆圧による逆洗操作により払い落し、連続運転を可能
にできる。According to the present invention, the exhaust gas in which NH 3 is injected is circulated through the porous ceramics coated with the catalytically active material composed of vanadium oxide and tungsten oxide,
Nitrogen oxides and soot and dust in the exhaust gas are removed at the same time, and the soot and dust that has accumulated on the surface of the porous ceramics can be blown off by backwashing by backwind or backpressure to enable continuous operation.
【００１０】[0010]
【実施例】以下、本発明の一実施例を図を参照して説明
する。An embodiment of the present invention will be described below with reference to the drawings.
【００１１】まず、本発明に係る排ガス処理用触媒フィ
ルターの構成について説明する。図１は本発明に係る排
ガス処理用触媒フィルターの外観図、図２は図１を縦方
向に切断した部分断面図、図３は同フィルターをミクロ
的に見た概念図である。First, the structure of the catalyst filter for treating exhaust gas according to the present invention will be described. FIG. 1 is an external view of a catalyst filter for treating exhaust gas according to the present invention, FIG. 2 is a partial cross-sectional view obtained by cutting FIG. 1 in a vertical direction, and FIG. 3 is a conceptual view of the filter as seen microscopically.
【００１２】図中の１は、多孔質セラミックスからなる
筒状のフィルター本体である。ここで、前記多孔質セラ
ミックスとしては、例えばコ−ジライト、ムライト、ジ
ルコニア、アルミナ、シリカ、炭化珪素、窒化珪素、サ
イアロンが挙げられる。前記フィルター本体１の全部
（又は全体）には、酸化バナジウム（Ｖ2 Ｏ5 ）と酸化
タングステンからなる触媒活性体２が担持されている。
なお、図において、Ｇ1は窒素酸化物とばいじんと反応
剤ＮＨ3 を含む原ガスであり、Ｇ2 はフィルター本体１
を通過した処理されたクリーンなガスである。また、こ
うした構造のフィルターをミクロ的に見ると、図３のよ
うに前記多孔質セラミックスを構成する粒子３に触媒活
性体２が担持されている。即ち、原ガスＧ1 がこの粒子
３の間隙を流れるときに、窒素酸化物の除去及び集塵が
行われる。Reference numeral 1 in the figure denotes a cylindrical filter body made of porous ceramics. Here, examples of the porous ceramics include cordierite, mullite, zirconia, alumina, silica, silicon carbide, silicon nitride, and sialon. A catalytic activator 2 composed of vanadium oxide (V 2 O 5 ) and tungsten oxide is carried on the whole (or the whole) of the filter body 1.
In the figure, G 1 is a raw gas containing nitrogen oxides, soot and dust, and NH 3 as a reactant, and G 2 is a filter body 1
It is a treated clean gas that has passed through. Further, when the filter having such a structure is viewed microscopically, as shown in FIG. 3, the catalytically active body 2 is carried on the particles 3 constituting the porous ceramics. That is, when the raw gas G 1 flows through the gaps between the particles 3, nitrogen oxides are removed and dust is collected.
【００１３】本実施例では、前記触媒活性体２を被覆し
た多孔質セラミックスからなる筒状のフィルター本体１
に、ＮＨ3 を注入した排ガスを流通することにより、排
ガス中の窒素酸化物を前記触媒活性体２により除去する
と同時に、排ガス中のばいじんを多孔質セラミックス表
面に堆積させて逆洗操作により払い落し、クリーンなガ
スＧ2 を得ることができる。その結果、ボイラや都市ゴ
ミ焼却炉等で大容量のガスを連続的に運転して処理する
ことが可能となる。In this embodiment, a cylindrical filter body 1 made of porous ceramics coated with the catalytically active body 2 is used.
The nitrogen oxide in the exhaust gas is removed by the catalyst activator 2 by circulating the exhaust gas in which NH 3 is injected, and at the same time, the dust in the exhaust gas is deposited on the surface of the porous ceramics and removed by backwashing operation. Therefore, clean gas G 2 can be obtained. As a result, it becomes possible to continuously operate and process a large amount of gas in a boiler, a municipal waste incinerator, or the like.
【００１４】[0014]
【発明の効果】以上詳述した如く本発明によれば、従来
のように触媒機能及び集塵機能を別々に備えた設備を必
要とすることなく、排ガス中の窒素酸化物とばいじんを
同時に除去して連続運転を可能にし、ボイラ，ディーゼ
ルプラント，都市ごみ焼却プラントなどから排出される
大容量の排ガスを処理しえる信頼性の高い排ガス処理方
法を提供できる。As described above in detail, according to the present invention, nitrogen oxides and dust in exhaust gas can be simultaneously removed without the need for separate equipment having a catalyst function and a dust collecting function as in the prior art. It is possible to provide a highly reliable exhaust gas treatment method that enables continuous operation and can treat a large amount of exhaust gas emitted from a boiler, a diesel plant, a municipal solid waste incineration plant, or the like.
【図１】本発明に係る排ガス処理用触媒フィルターの外
観図。FIG. 1 is an external view of a catalyst filter for treating exhaust gas according to the present invention.
【図２】図１を縦方向に切断した部分断面図。FIG. 2 is a partial cross-sectional view of FIG. 1 cut in the vertical direction.
【図３】図１のフィルターをミクロ的に見た概念図。FIG. 3 is a conceptual view of the filter of FIG. 1 viewed microscopically.
１…フィルター本体、２…触媒活性体、３…粒子。 1 ... Filter body, 2 ... Catalyst activator, 3 ... Particles.
Claims (1)
なる触媒活性体を被覆した多孔質セラミックスに、ＮＨ
3 を注入した排ガスを流通し、排ガス中の窒素酸化物を
前記触媒活性体により除去すると同時に、排ガス中のば
いじんを多孔質セラミックス表面に堆積させて逆洗操作
により払い落すことを特徴とする排ガス処理方法。1. A porous ceramics coated with a catalytically active material composed of vanadium oxide and tungsten oxide is treated with NH.
Exhaust gas is characterized in that the exhaust gas injected with 3 is circulated and nitrogen oxides in the exhaust gas are removed by the catalytically active body, and at the same time, soot and dust in the exhaust gas are deposited on the surface of the porous ceramics and removed by backwashing operation. Processing method.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP4080875A JPH084714B2 (en) | 1992-04-02 | 1992-04-02 | Exhaust gas treatment method |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP4080875A JPH084714B2 (en) | 1992-04-02 | 1992-04-02 | Exhaust gas treatment method |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH05154352A true JPH05154352A (en) | 1993-06-22 |
| JPH084714B2 JPH084714B2 (en) | 1996-01-24 |
Family
ID=13730525
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP4080875A Expired - Fee Related JPH084714B2 (en) | 1992-04-02 | 1992-04-02 | Exhaust gas treatment method |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH084714B2 (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104532440A (en) * | 2014-12-18 | 2015-04-22 | 鑫立达机器（常熟）有限公司 | Forming method for high-strength and fracture-prevention fiber cloth |
| CN104941348A (en) * | 2015-05-29 | 2015-09-30 | 中国科学院过程工程研究所 | Continuous industrial dust collector |
| CN108472584A (en) * | 2015-12-22 | 2018-08-31 | 国际壳牌研究有限公司 | Catalyst bed and method for nitrogen oxides reduction |
| JP2019505370A (en) * | 2015-12-22 | 2019-02-28 | シエル・インターナシヨナル・リサーチ・マートスハツペイ・ベー・ヴエー | Catalyst bed and method for reducing nitric oxide |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS61268332A (en) * | 1985-05-20 | 1986-11-27 | Asahi Glass Co Ltd | Dust removal purifying apparatus |
| JPH0212412U (en) * | 1988-07-04 | 1990-01-25 | ||
| JPH03169326A (en) * | 1989-11-28 | 1991-07-23 | Mitsubishi Heavy Ind Ltd | Porous ceramic filter for treatment of exhaust gas and exhaust gas treatment apparatus |
-
1992
- 1992-04-02 JP JP4080875A patent/JPH084714B2/en not_active Expired - Fee Related
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS61268332A (en) * | 1985-05-20 | 1986-11-27 | Asahi Glass Co Ltd | Dust removal purifying apparatus |
| JPH0212412U (en) * | 1988-07-04 | 1990-01-25 | ||
| JPH03169326A (en) * | 1989-11-28 | 1991-07-23 | Mitsubishi Heavy Ind Ltd | Porous ceramic filter for treatment of exhaust gas and exhaust gas treatment apparatus |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104532440A (en) * | 2014-12-18 | 2015-04-22 | 鑫立达机器（常熟）有限公司 | Forming method for high-strength and fracture-prevention fiber cloth |
| CN104941348A (en) * | 2015-05-29 | 2015-09-30 | 中国科学院过程工程研究所 | Continuous industrial dust collector |
| CN108472584A (en) * | 2015-12-22 | 2018-08-31 | 国际壳牌研究有限公司 | Catalyst bed and method for nitrogen oxides reduction |
| JP2019505372A (en) * | 2015-12-22 | 2019-02-28 | シエル・インターナシヨナル・リサーチ・マートスハツペイ・ベー・ヴエー | Catalyst bed and method for reducing nitric oxide |
| JP2019505370A (en) * | 2015-12-22 | 2019-02-28 | シエル・インターナシヨナル・リサーチ・マートスハツペイ・ベー・ヴエー | Catalyst bed and method for reducing nitric oxide |
| US10960352B2 (en) | 2015-12-22 | 2021-03-30 | Shell Oil Company | Catalyst bed and method for reducing nitrogen oxides |
| US11020732B2 (en) | 2015-12-22 | 2021-06-01 | Shell Oil Company | Catalyst bed and method for reducing nitrogen oxides |
Also Published As
| Publication number | Publication date |
|---|---|
| JPH084714B2 (en) | 1996-01-24 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| A01 | Written decision to grant a patent or to grant a registration (utility model) |
Free format text: JAPANESE INTERMEDIATE CODE: A01 Effective date: 19960716 |
|
| LAPS | Cancellation because of no payment of annual fees |