JPH05144734A - Vapor phase growth apparatus - Google Patents

Vapor phase growth apparatus

Info

Publication number
JPH05144734A
JPH05144734A JP30791791A JP30791791A JPH05144734A JP H05144734 A JPH05144734 A JP H05144734A JP 30791791 A JP30791791 A JP 30791791A JP 30791791 A JP30791791 A JP 30791791A JP H05144734 A JPH05144734 A JP H05144734A
Authority
JP
Japan
Prior art keywords
substrate
reaction furnace
phase growth
vapor phase
growth apparatus
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP30791791A
Other languages
Japanese (ja)
Inventor
Keiichi Akagawa
慶一 赤川
Takashi Kataoka
敬 片岡
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Toshiba Corp
Original Assignee
Toshiba Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Toshiba Corp filed Critical Toshiba Corp
Priority to JP30791791A priority Critical patent/JPH05144734A/en
Publication of JPH05144734A publication Critical patent/JPH05144734A/en
Pending legal-status Critical Current

Links

Abstract

PURPOSE:To provide a vapor phase growth apparatus wherein a reaction product which is grown inside a reactor is cleaned easily and, in addition, a high- quality thin film can be formed by vapor phase grown. CONSTITUTION:A cylindrical shielding plate 20 is arranged and installed so as to be close to the inner wall surface of an upper-part reactor 6. A reaction product 9 which is grown inside a reactor 1 in a vapor phase growth operation is deposited on the shielding plate 20. The vapor phase growth operation is performed the definite number of times. After that, the shielding plate 20 is detached; the reaction product 9 is cleaned. Since the surface area of the shielding plate 20 is smaller than that of the upper-part reactor 6, an influence on a degassed growth film after a cleaning operation is small and a high-quality thin film can be obtained.

Description

【発明の詳細な説明】Detailed Description of the Invention

【0001】[0001]

【産業上の利用分野】本発明は、例えばヘテロ構造の化
合物半導体等の製造に用いられる気相成長装置に関す
る。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a vapor phase growth apparatus used for manufacturing, for example, a compound semiconductor having a hetero structure.

【0002】[0002]

【従来の技術】基板上に半導体等の薄膜を気相成長させ
て半導体等を製造する従来の気相成長装置は、例えば図
8に示すように構成されている。
2. Description of the Related Art A conventional vapor phase growth apparatus for producing a semiconductor or the like by vapor-depositing a thin film of a semiconductor or the like on a substrate is constructed, for example, as shown in FIG.

【0003】この図に示すように従来の気相成長装置
は、反応炉1内に、基板2を載置する基板ホルダ3と、
基板ホルダ3を着脱自在に支持し回転駆動装置(図示省
略)が接続されている回転軸4と、基板2および基板ホ
ルダ3を加熱するヒータ5が配設されている。
As shown in this figure, a conventional vapor phase growth apparatus comprises a substrate holder 3 for mounting a substrate 2 in a reaction furnace 1,
A rotation shaft 4 to which the substrate holder 3 is detachably supported and a rotation driving device (not shown) is connected, and a heater 5 for heating the substrate 2 and the substrate holder 3 are provided.

【0004】反応管1は、上部反応炉6と下部反応炉7
に分割されており、上部反応炉6と下部反応炉7の上部
フランジ6aと下部フランジ7aをOリング8を介して
着脱自在に密着している。上部フランジ6aと下部フラ
ンジ7aの内壁面は段差なく接触している。
The reaction tube 1 comprises an upper reaction furnace 6 and a lower reaction furnace 7.
The upper flange 6a and the lower flange 7a of the upper reaction furnace 6 and the lower reaction furnace 7 are detachably adhered to each other via an O-ring 8. The inner wall surfaces of the upper flange 6a and the lower flange 7a are in contact with each other without steps.

【0005】上部反応炉6の上部には、供給部6bを介
して反応炉1内にガス(原料ガス、キャリアガス等)を
供給するガス供給装置(図示省略)が接続され、下部反
応炉7の下部には、排気口7bを介して反応炉1内の圧
力調整および未反応ガスを排出する排気装置(図示省
略)が接続されている。
A gas supply device (not shown) for supplying gas (raw material gas, carrier gas, etc.) into the reaction furnace 1 through a supply unit 6b is connected to the upper part of the upper reaction furnace 6, and the lower reaction furnace 7 is connected. An exhaust device (not shown) for adjusting the pressure in the reaction furnace 1 and exhausting unreacted gas is connected to the lower part of the exhaust gas via the exhaust port 7b.

【0006】従来の気相成長装置は上記のように構成さ
れており、基板2および基板ホルダ3をヒータ5の加熱
によって所定温度に上昇させると共に、回転駆動装置
(図示省略)の回転駆動によって所定の回転数で回転さ
せ、ガス供給装置(図示省略)から供給口6aを通して
反応炉1内に原料ガス(例えばSi H2 Cl2 )をキャ
リアガス(例えばH2 )と共に供給し、基板2上に化合
物半導体の薄膜を気相成長させる。
The conventional vapor phase growth apparatus is constructed as described above, and the substrate 2 and the substrate holder 3 are heated to a predetermined temperature by heating by the heater 5, and are also driven by a rotary driving device (not shown) to rotate them at a predetermined temperature. And a source gas (for example, Si H 2 Cl 2 ) is supplied together with a carrier gas (for example, H 2 ) into the reaction furnace 1 from a gas supply device (not shown) through the supply port 6a, and the gas is supplied onto the substrate 2. A compound semiconductor thin film is vapor-deposited.

【0007】ところで、上記した気相成長時には、上部
反応炉6と下部反応炉7の内壁面も加熱されて高温とな
るので、上部反応炉6および下部反応炉7の内壁面にも
反応生成物9が堆積し、成長回数を重ねる毎に厚くな
る。そして、堆積した反応生成物9の一部が剥離し粉塵
となって気相成長中の基板2上に落下すると、膜厚が不
均一となったり成長膜の組成が変わってしまう。
By the way, during the above-described vapor phase growth, the inner wall surfaces of the upper reaction furnace 6 and the lower reaction furnace 7 are also heated to a high temperature, so that the reaction products are also formed on the inner wall surfaces of the upper reaction furnace 6 and the lower reaction furnace 7. 9 is deposited and becomes thicker as the number of times of growth increases. Then, when a part of the deposited reaction product 9 is separated and becomes dust and falls onto the substrate 2 during vapor phase growth, the film thickness becomes non-uniform or the composition of the grown film changes.

【0008】このため、反応炉1の上部反応炉6を一定
回数気相成長を行った後に下部反応炉7から分割して取
外した上部反応炉6の内壁面を洗浄し、堆積した反応生
成物9を除去した後に再び下部反応炉7を接続して吸着
ガスを脱ガスする必要がある。
For this reason, after the upper reaction furnace 6 of the reaction furnace 1 has been vapor-deposited a certain number of times, the inner wall surface of the upper reaction furnace 6 which has been separated from the lower reaction furnace 7 and removed is washed to deposit the reaction product. After removing 9, it is necessary to connect the lower reaction furnace 7 again to degas the adsorbed gas.

【0009】脱ガスをしないで温度上昇させて気相成長
を行うと、気相成長中に原料ガス以外の例えば空気中の
酸素等が反応炉1内に取込まれることにより、成長膜の
組成が変ってしまう。また、上部反応炉6が例えばガラ
ス等の場合は、運搬中および反応生成物9を洗浄中に破
損の危険性があり、また、金属製の場合は重量が重く取
扱いが厄介なため、上部反応炉6の内壁面に堆積した反
応生成物9が大気中に拡散される危険性があり、安全性
に問題があった。
When vapor phase growth is performed by increasing the temperature without degassing, oxygen other than the source gas, such as oxygen in the air, is taken into the reaction furnace 1 during the vapor phase growth, so that the composition of the grown film is increased. Will change. If the upper reaction furnace 6 is, for example, glass, there is a risk of damage during transportation and cleaning of the reaction product 9, and if the upper reaction furnace 6 is made of metal, it is heavy and difficult to handle. The reaction product 9 deposited on the inner wall surface of the furnace 6 may be diffused into the atmosphere, which is a safety problem.

【0010】また、図9に示すように、気相成長開始前
と気相成長終了後には上部反応炉6と下部反応炉7を分
離し、上部反応炉6を上昇させて基板2の搬入,搬出を
行う。この時、上部反応炉6の下部フランジ6a付近に
堆積している反応生成物9が剥離し粉塵9aとなって、
下部反応炉7内および下部フランジ7aに配設したOリ
ング8上に落下する。
Further, as shown in FIG. 9, the upper reaction furnace 6 and the lower reaction furnace 7 are separated before the start of the vapor phase growth and after the completion of the vapor phase growth, and the upper reaction furnace 6 is raised to carry in the substrate 2. Carry out. At this time, the reaction product 9 deposited in the vicinity of the lower flange 6a of the upper reaction furnace 6 peels off to become dust 9a,
It falls in the lower reaction furnace 7 and on the O-ring 8 arranged on the lower flange 7a.

【0011】このように、上部反応炉6と下部反応炉7
を分離して基板2の搬入,搬出を行う際に、粉塵9aが
Oリング8に落下するとリークの原因となる。そして、
上部反応炉6と下部反応炉7の上部フランジ6aと下部
フランジ7aをOリング8を介して密着させた時に、上
部フランジ6aと下部フランジ7a間でリークがある
と、気相成長中の薄膜に原料ガス以外の例えば空気中の
酸素等が取込まれることにより、例えば成長膜の抵抗が
高くなる等の問題が生じる。
Thus, the upper reaction furnace 6 and the lower reaction furnace 7
If the dust 9a falls on the O-ring 8 when the substrate 2 is carried in and carried out by separating the wafers, it causes a leak. And
When the upper flange 6a and the lower flange 7a of the upper reaction furnace 6 and the lower reaction furnace 7 are brought into close contact with each other through the O-ring 8, if there is a leak between the upper flange 6a and the lower flange 7a, the thin film during vapor phase growth may be formed. Incorporation of oxygen or the like in the air other than the source gas causes a problem such as an increase in the resistance of the growth film.

【0012】また、キャリアガスとしてH2 が使用され
ている場合には、リークがあると爆発の危険性があっ
た。
Further, when H 2 is used as the carrier gas, there is a risk of explosion if there is a leak.

【0013】また、従来の気相成長装置では、例えば図
10に示すように、基板ホルダ3内に設けた基板支持具
12にざぐり部12aを形成し、このさぐり部12aに
基板2の周縁部が載置されているものがある。基板支持
具12は、例えばシリコン,ガラス,セラミックス等の
材質で形成されており、ざぐり部12aの内側には穴1
3が形成されている。他の構成は図8に示した従来例の
気相成長装置と同様である。
Further, in the conventional vapor phase growth apparatus, as shown in FIG. 10, for example, a counterbore portion 12a is formed in the substrate support 12 provided in the substrate holder 3, and the peripheral portion of the substrate 2 is formed in the counterbore portion 12a. There are some that are placed. The substrate support 12 is made of, for example, a material such as silicon, glass, or ceramics, and the hole 1 is formed inside the counterbore 12a.
3 is formed. Other configurations are the same as those of the conventional vapor phase growth apparatus shown in FIG.

【0014】なお、基板支持具12がシリコン,ガラ
ス,セラミックス等で形成されている理由は、熱伝導率
が比較的悪いという理由で使用されている。つまり、熱
伝導率の良い金属等を用いた場合には、金属製の基板支
持具に接触する基板の周縁部の温度が極めて高くなり、
基板面内の温度分布の不均一をもたらす。
The substrate support 12 is made of silicon, glass, ceramics or the like because it has a relatively low thermal conductivity. In other words, when a metal or the like having good thermal conductivity is used, the temperature of the peripheral portion of the substrate that comes into contact with the substrate support made of metal becomes extremely high,
This results in non-uniform temperature distribution in the substrate plane.

【0015】上記理由により、基板支持具12はシリコ
ン,ガラス,セラミックス等で形成されているので、ざ
ぐり部12aの加工は一般にそれらの材料の加工に適し
た超音波加工によって行われる。このざぐり部12aを
超音波加工する際、超音波加工ツールと加工部(ざぐり
部12a)間に研摩材を入れて超音波振動で加工するた
め、超音波加工ツールの先端部に最初に研摩材が入る。
このため、どうしても超音波加工ツールの先端部が丸く
なるために、このような超音波加工ツールで加工される
基板支持具12のざぐり部12aの基板2が載置される
角部12bも丸くなってしまう(図11参照)。
For the above reasons, since the substrate support 12 is made of silicon, glass, ceramics or the like, the counterbore 12a is generally processed by ultrasonic processing suitable for processing those materials. When ultrasonically machining the countersunk portion 12a, an abrasive material is put between the ultrasonic processing tool and the processing portion (the countersunk portion 12a) to be processed by ultrasonic vibration. Therefore, the abrasive material is first attached to the tip of the ultrasonic processing tool. Goes in.
For this reason, since the tip of the ultrasonic machining tool is inevitably rounded, the corner 12b of the counterbore 12a of the substrate support tool 12 that is machined by such an ultrasonic machining tool is also rounded. (See FIG. 11).

【0016】そして、このざぐり部12aの角部12b
に基板2の周縁部が載置されることによって、高速回転
している基板2は、図11に示すように、遠心力により
一端側(図では左側)がざぐり部12aの上部に移動す
ることによって傾斜するので、基板2の面内温度分布が
変化する(図12参照)。即ち、基板2の左端の方が右
端に比べてヒータ5からの距離が遠くなるので、基板2
の左端の方が右端より温度が低くなる。このように、基
板2の面内温度分布が変化すると、気相成長によって得
られる例えばIn Ga A1P等の半導体レーザの発振波
長が一定とならず、希望する発振波長が得られない等の
問題があった。
Then, the corner portion 12b of the countersunk portion 12a.
As shown in FIG. 11, one edge side (left side in the figure) of the substrate 2 which is rotating at a high speed is moved to the upper part of the counterbore portion 12a by placing the peripheral edge portion of the substrate 2 on the substrate. As a result, the in-plane temperature distribution of the substrate 2 changes (see FIG. 12). That is, since the left end of the substrate 2 is farther from the heater 5 than the right end, the substrate 2
The temperature at the left end is lower than that at the right end. As described above, when the in-plane temperature distribution of the substrate 2 changes, the oscillation wavelength of a semiconductor laser such as InGaA1P obtained by vapor phase growth does not become constant, and a desired oscillation wavelength cannot be obtained. there were.

【0017】[0017]

【発明が解決しようとする課題】上記したように従来の
気相成長装置では、上部反応炉6の内壁面に堆積した反
応生成物の洗浄が厄介な問題があった。
As described above, the conventional vapor phase growth apparatus has a problem that cleaning the reaction products deposited on the inner wall surface of the upper reaction furnace 6 is difficult.

【0018】また、上部反応炉6と下部反応炉7の着脱
時に上部フランジ6aと下部フランジ7a間を気密状態
に接続するOリング8に、上部フランジ6a付近に堆積
した反応生成物9の粉塵9aが付着すると、リークが発
生する恐れがあった。
Further, the dust 9a of the reaction product 9 deposited in the vicinity of the upper flange 6a is attached to the O-ring 8 which connects the upper flange 6a and the lower flange 7a in an airtight state when the upper reactor 6 and the lower reactor 7 are attached and detached. If adhered, there was a risk that a leak would occur.

【0019】また、基板支持具12のざぐり部12aの
基板2が載置される角部12bは、加工時に丸くなるの
で、気相成長時に基板2および基板ホルダ3が回転する
と、遠心力により基板2の周縁部が角部12bに沿って
移動して傾き、基板2の面内温度分布が不均一になる問
題があった。
Further, since the corner 12b of the counterbore 12a of the substrate support 12 on which the substrate 2 is placed is rounded during processing, when the substrate 2 and the substrate holder 3 rotate during vapor phase growth, the substrate is rotated by centrifugal force. There is a problem that the peripheral edge of No. 2 moves and tilts along the corner 12b, and the in-plane temperature distribution of the substrate 2 becomes non-uniform.

【0020】本発明は、上記した課題を解決する目的で
なされ、反応炉内に堆積する反応生成物の洗浄と除去を
容易にし、また、反応炉の分割面を気密状態に接続する
シール手段に反応生成物の粉塵が落下することを防止
し、また、基板の面内温度分布を一定にして高品質な薄
膜を得ることができる気相成長装置を提供しようとする
ものである。
The present invention has been made for the purpose of solving the above-mentioned problems, and facilitates cleaning and removal of reaction products deposited in the reaction furnace, and a sealing means for connecting the divided surfaces of the reaction furnace in an airtight state. An object of the present invention is to provide a vapor phase growth apparatus capable of preventing the dust of the reaction product from falling down and keeping the in-plane temperature distribution of the substrate constant to obtain a high quality thin film.

【0021】[0021]

【課題を解決するための手段】前記した課題を解決する
ために請求項1に記載の発明では、反応炉内に配設した
基板ホルダ上に載置された基板を加熱手段により加熱す
るとともに、前記反応炉内に原料ガスを供給して前記基
板に薄膜を気相成長させる気相成長装置において、気相
成長時に前記反応炉内で成長する反応生成物を堆積させ
る遮蔽板を前記反応炉の内壁面に近接させて配設したこ
とを特徴としている。
In order to solve the above-mentioned problems, in the invention described in claim 1, the substrate mounted on the substrate holder arranged in the reaction furnace is heated by the heating means, and In a vapor phase growth apparatus for supplying a raw material gas into the reaction furnace to perform vapor phase growth of a thin film on the substrate, a shield plate for depositing a reaction product growing in the reaction furnace during the vapor phase growth is provided in the reaction furnace. It is characterized in that it is arranged close to the inner wall surface.

【0022】また、請求項2に記載の発明では、第1の
反応炉構成体と第2の反応炉構成体とに分割可能でその
分割面がシール手段を介して気密に接続される反応炉を
備え、前記反応炉内に配設した基板ホルダ上に載置され
た基板を加熱手段により加熱するとともに、前記反応炉
内に原料ガスを供給して前記基板に薄膜を気相成長させ
る気相成長装置において、前記原料ガスの流れ方向上流
側に位置する前記第1の反応炉構成体の前記第2の反応
炉構成体と接する端部に、前記第2の反応炉構成体の内
壁面に沿って挿入される遮蔽部を形成したことを特徴と
している。
According to the second aspect of the invention, the reactor is divisible into the first reactor constituent and the second reactor constituent, and the dividing surface is hermetically connected via the sealing means. A vapor phase for heating a substrate placed on a substrate holder arranged in the reaction furnace by a heating means, and supplying a source gas into the reaction furnace to vapor-deposit a thin film on the substrate. In the growth apparatus, at an end portion of the first reactor structure located upstream of the raw material gas in the flow direction in contact with the second reactor structure, and at an inner wall surface of the second reactor structure. It is characterized in that a shielding portion to be inserted along is formed.

【0023】また、請求項3に記載の発明では、反応炉
内に配設した基板支持部材上に載置された基板を加熱手
段により加熱するとともに、前記反応炉内に原料ガスを
供給して前記基板に薄膜を気相成長させる気相成長装置
において、前記基板支持部材に前記基板の周縁部を支持
するざぐり部を形成し、前記ざぐり部の前記基板底面の
周縁部が接する角部に溝を形成したことを特徴としてい
る。
According to the third aspect of the present invention, the substrate placed on the substrate supporting member arranged in the reaction furnace is heated by the heating means, and the source gas is supplied into the reaction furnace. In a vapor phase growth apparatus for vapor-depositing a thin film on the substrate, a counterbore portion for supporting a peripheral portion of the substrate is formed on the substrate supporting member, and a groove is formed at a corner portion of the counterbore portion where the peripheral portion of the substrate bottom surface contacts. Is formed.

【0024】[0024]

【作用】請求項1に記載の発明によれば、反応炉の内壁
面に近接して配設した遮蔽板に、気相成長中に成長する
反応生成物が堆積することにより、反応生成物が堆積し
た遮蔽板を取外すだけで容易に、且つ安全に洗浄を行う
ことができる。
According to the first aspect of the present invention, the reaction product that grows during the vapor phase growth is deposited on the shield plate disposed in the vicinity of the inner wall surface of the reaction furnace. Cleaning can be performed easily and safely simply by removing the accumulated shielding plate.

【0025】また、遮蔽板は反応炉内に配設されること
により、反応炉の内壁面に比べて表面積が小さいので洗
浄後の脱ガスの吸着量が小さくなるため気相成長時のガ
ス放出量が少なく、高品質な薄膜を得ることができる。
Further, since the shielding plate is arranged in the reaction furnace, its surface area is smaller than that of the inner wall surface of the reaction furnace, so that the adsorbed amount of degas after cleaning becomes small, so that gas is released during vapor phase growth. A small amount and a high quality thin film can be obtained.

【0026】また、請求項2に記載の発明によれば、第
1の反応炉構成体に形成した遮蔽部を第2の反応炉構成
体の内壁面に沿って挿入することにより、気相成長時に
分割面付近で成長する反応生成物が遮蔽部に堆積するこ
とによって、第1,第2の反応炉構成体を分割して基板
を搬入,搬出する際に分割面をシールするシール手段上
に分割面付近に堆積した反応生成物が落下することがな
くなるので、気相成長時のリークが防止されて高品質な
薄膜を得ることができる。
According to the second aspect of the invention, the vapor phase growth is performed by inserting the shield portion formed in the first reactor structure along the inner wall surface of the second reactor structure. At times, reaction products that grow near the dividing surface are deposited on the shielding portion, so that the first and second reaction furnace constituents are divided and the sealing means is provided to seal the dividing surface when the substrate is loaded or unloaded. Since the reaction products deposited near the dividing surface do not drop, leakage during vapor phase growth is prevented and a high quality thin film can be obtained.

【0027】また、請求項3に記載の発明によれば、基
板支持部材のざぐり部の基板周縁部の下部が接する角部
に溝を形成したことにより、基板底面の周縁部がざぐり
部に密接するので、気相成長時に基板、基板支持部材を
高速回転させても基板の周縁部がずれたり傾くことなく
確実に支持されるので、基板面内温度分布が均一になり
高品質な薄膜を得ることができる。
According to the third aspect of the present invention, the groove is formed at the corner of the countersunk portion of the substrate support member where the lower portion of the peripheral edge of the substrate contacts, so that the peripheral edge of the bottom surface of the substrate closely contacts the countersink. Therefore, even if the substrate and the substrate supporting member are rotated at high speed during vapor phase growth, the peripheral edge of the substrate is reliably supported without being displaced or tilted, so that the temperature distribution in the substrate surface becomes uniform and a high quality thin film is obtained. be able to.

【0028】[0028]

【実施例】以下、本発明を図示の実施例に基づいて詳細
に説明する。尚、従来と同一部材には同一符号を付して
説明する。
DESCRIPTION OF THE PREFERRED EMBODIMENTS The present invention will be described in detail below based on the illustrated embodiments. It should be noted that the same members as those of the related art will be described with the same reference numerals.

【0029】<第1実施例>図1は、第1実施例に係る
気相成長装置を示す概略断面図である。この図に示すよ
うに、反応炉1は上部反応炉6と下部反応炉7に分割さ
れており、上部反応炉6の上部フランジ6aと下部反応
炉7の下部フランジ7aは、Oリング8を介して着脱自
在に密着している。
<First Embodiment> FIG. 1 is a schematic sectional view showing a vapor phase growth apparatus according to the first embodiment. As shown in this figure, the reaction furnace 1 is divided into an upper reaction furnace 6 and a lower reaction furnace 7. The upper flange 6a of the upper reaction furnace 6 and the lower flange 7a of the lower reaction furnace 7 have an O-ring 8 therebetween. It is attached in a detachable manner.

【0030】反応炉1内には、基板2を載置する基板ホ
ルダ3と、基板ホルダ3を着脱自在に支持し回転駆動装
置(図示省略)が接続されている回転軸4と、基板2お
よび基板ホルダ3を加熱するヒータ5が配設されてい
る。
In the reaction furnace 1, a substrate holder 3 on which the substrate 2 is placed, a rotary shaft 4 to which the substrate holder 3 is detachably supported and a rotation driving device (not shown) is connected, the substrate 2 and A heater 5 for heating the substrate holder 3 is provided.

【0031】上部反応炉6の上部には、供給口6bを介
して反応炉1内にガス(原料ガス,キャリアガス等)を
供給するガス供給装置(図示省略)が接続され、下部反
応炉7の下部には、排気口7bを介して反応炉1内の圧
力調整および未反応ガスを排出する排気装置(図示省
略)が接続されている。
A gas supply device (not shown) for supplying gas (raw material gas, carrier gas, etc.) into the reaction furnace 1 through a supply port 6b is connected to the upper part of the upper reaction furnace 6, and the lower reaction furnace 7 is connected. An exhaust device (not shown) for adjusting the pressure in the reaction furnace 1 and exhausting unreacted gas is connected to the lower part of the exhaust gas via the exhaust port 7b.

【0032】また、上記反応炉6内には、その内壁面に
近接(例えば0.01〜0.3mmの間隔)するようにし
て円筒状の石英ガラスから成る遮蔽板20が配設されて
おり、上部フランジ6a上にネジ止め等で固定した支え
板21上に支持されている。
Further, in the reaction furnace 6, a shielding plate 20 made of cylindrical quartz glass is arranged so as to be close to the inner wall surface (for example, at a distance of 0.01 to 0.3 mm). , Is supported on a support plate 21 fixed to the upper flange 6a by screwing or the like.

【0033】本実施例に係る気相成長装置は上記のよう
に構成されており、基板2および基板ホルダ3をヒータ
5の加熱によって所定温度に上昇させると共に、回転駆
動装置(図示省略)の回転駆動によって所定の回転数で
回転させ、ガス供給装置(図示省略)から供給口6bを
通して反応炉1内に原料ガス(例えばSi H2 Cl2
をキャリアガス(例えばH2 )と共に供給し、基板2上
に化合物半導体の薄膜を気相成長させる。
The vapor phase growth apparatus according to this embodiment is configured as described above, and the substrate 2 and the substrate holder 3 are heated to a predetermined temperature by heating the heater 5, and the rotation drive device (not shown) is rotated. The raw material gas (for example, Si H 2 Cl 2 ) is driven into the reactor 1 through a supply port 6b from a gas supply device (not shown).
Are supplied together with a carrier gas (for example, H 2 ) to vapor-deposit a thin film of a compound semiconductor on the substrate 2.

【0034】この時、上部反応炉6の内壁面に近接して
配設して配設されている遮蔽板20も加熱されて高温に
なるので、この遮蔽板20でも結晶成長して反応生成物
9が堆積する。
At this time, since the shielding plate 20 disposed close to the inner wall surface of the upper reaction furnace 6 is also heated to a high temperature, the shielding plate 20 also grows in crystal and the reaction product is produced. 9 is deposited.

【0035】そして、上記したような気相成長を所定回
数行った後、上部反応炉6の上部フランジ6aと下部反
応炉7の下部フランジ7a間を分離して上部反応炉6を
上昇させ、遮蔽板10を取外す。反応生成物9が堆積し
ている遮蔽板20は、洗浄液が入っている容器(図示省
略)で洗浄した後再び上記反応炉6内に配設される。
After the vapor phase growth as described above is performed a predetermined number of times, the upper flange 6a of the upper reaction furnace 6 and the lower flange 7a of the lower reaction furnace 7 are separated to raise the upper reaction furnace 6 and shield it. Remove the plate 10. The shielding plate 20 on which the reaction product 9 is deposited is washed in a container (not shown) containing a washing liquid, and then placed in the reaction furnace 6 again.

【0036】このように、本実施例では、上部反応炉6
の上部フランジ6aに近接して配設した遮蔽板20に反
応生成物9を堆積させて、定期的に上部反応炉6内の遮
蔽板20を取出して洗浄するだけでよいので、反応生成
物9の洗浄を容易に、且つ安全に行うことができ、ま
た、遮蔽板20は上部反応炉6の内壁面に比べて表面積
が小さいので、洗浄後の脱ガスの吸着量が小さくなるた
め気相成長時のガス放出量が少なくなり、高品質な薄膜
を得ることができる。
As described above, in this embodiment, the upper reaction furnace 6
The reaction product 9 may be deposited on the shield plate 20 disposed in the vicinity of the upper flange 6a of the above, and the shield plate 20 in the upper reaction furnace 6 may be periodically taken out and cleaned. Can be easily and safely cleaned, and since the shield plate 20 has a smaller surface area than the inner wall surface of the upper reaction furnace 6, the amount of degassed adsorbed after cleaning is small, so that vapor phase growth is possible. The amount of gas released at that time is reduced, and a high quality thin film can be obtained.

【0037】また、遮蔽板20は、上部反応炉6の内壁
面にほぼ0.01〜0.3mm以下の隙間を設けて配設さ
れるが、この隙間が狭い(上部反応炉6の内壁面の表面
粗さで0.01mm程度が最小)ほど上部反応炉6の内壁
面への反応生成物9の堆積が少くなり、更に、原料ガス
の種類を変えた場合でも前の原料ガスの影響を小さくす
ることができる。
The shield plate 20 is arranged on the inner wall surface of the upper reaction furnace 6 with a gap of approximately 0.01 to 0.3 mm or less, but this gap is narrow (the inner wall surface of the upper reaction furnace 6). The surface roughness of 0.01 mm is the minimum), the less the amount of the reaction product 9 deposited on the inner wall surface of the upper reaction furnace 6, the more the effect of the previous source gas is changed even when the type of the source gas is changed. Can be made smaller.

【0038】また、前記実施例では、遮蔽板20をガス
放出の少ない石英ガラスで形成したが、これに限定され
ることなくガス放出の少ない金属,セラミックス等で形
成してもよい。
Further, in the above-mentioned embodiment, the shielding plate 20 is made of quartz glass which emits little gas, but it is not limited to this and may be made of metal, ceramics or the like which emits little gas.

【0039】<第2実施例>図2は、第2実施例に係る
気相成長装置を示す概略断面図である。この図に示すよ
うに本実施例では、上部反応炉(第1の反応炉構成体)
6の上部フランジ6aに、下方に突出した筒状の遮蔽部
6cを形成した構成である。他の構成は図8に示した従
来例の気相成長装置と同様である。
<Second Embodiment> FIG. 2 is a schematic sectional view showing a vapor phase growth apparatus according to the second embodiment. As shown in this figure, in this embodiment, the upper reactor (first reactor structure) is used.
The upper flange 6a of 6 has a cylindrical shielding portion 6c protruding downward. Other configurations are the same as those of the conventional vapor phase growth apparatus shown in FIG.

【0040】遮蔽部6cは、下部反応炉(第2の反応炉
構成体)7の下部フランジ7aの内壁面にほぼ接するよ
うにして形成されており、遮蔽部6cの下部フランジ7
a側と接する先端側には、下部反応炉7内への挿入がス
ムーズに行えるようにテーパ部6dを形成し、遮蔽部6
cの先端側を鋭角にしている。
The shielding portion 6c is formed so as to be almost in contact with the inner wall surface of the lower flange 7a of the lower reaction furnace (second reactor constituent body) 7, and the lower flange 7 of the shielding portion 6c is formed.
A taper portion 6d is formed on the tip side in contact with the a side so that the insertion into the lower reaction furnace 7 can be smoothly performed, and the shield portion 6d is formed.
The tip side of c is made into an acute angle.

【0041】本実施例に係る気相成長装置は上記のよう
に構成されており、基板2への気相成長は第1実施例と
同様にして行われるので、ここでは省略する。
The vapor phase growth apparatus according to the present embodiment is constructed as described above, and vapor phase growth on the substrate 2 is carried out in the same manner as in the first embodiment, so it is omitted here.

【0042】基板2への気相成長時には上部反応炉6お
よび下部反応炉7の内壁面も加熱されて高温になるの
で、上部反応炉6の内壁面でも結晶成長して反応生成物
9が堆積する。反応生成物9は、基板2への成長回数を
重ねる毎に厚くなる。
During vapor phase growth on the substrate 2, the inner wall surfaces of the upper reaction furnace 6 and the lower reaction furnace 7 are also heated to a high temperature, so that crystal growth also occurs on the inner wall surface of the upper reaction furnace 6 and the reaction product 9 is deposited. To do. The reaction product 9 becomes thicker as the number of times of growth on the substrate 2 increases.

【0043】そして、上部反応炉6の内壁面に反応生成
物9が堆積した状態で、図3に示すように、上部反応炉
6の上部フランジ6aと下部反応炉7の下部フランジ7
aを分離して上部反応炉6を上昇させ、基板2の搬入,
搬出を行う。
Then, with the reaction product 9 deposited on the inner wall surface of the upper reaction furnace 6, as shown in FIG. 3, the upper flange 6a of the upper reaction furnace 6 and the lower flange 7 of the lower reaction furnace 7 are connected.
a is separated, the upper reaction furnace 6 is raised, and the substrate 2 is loaded.
Carry out.

【0044】この時、上部反応炉6の上部フランジ6a
と下部反応炉7の下部フランジ7aの接続部付近は、上
部フランジ6aに形成した遮蔽部6bで覆われているの
で、この付近の反応生成物9は遮蔽部6bに堆積する。
また、遮蔽部6bの先端の下部フランジ7a側が鋭角状
に形成されているので、この部分には反応生成物9が堆
積しにくい。
At this time, the upper flange 6a of the upper reaction furnace 6
Since the vicinity of the connecting portion of the lower flange 7a of the lower reaction furnace 7 is covered with the shielding portion 6b formed on the upper flange 6a, the reaction product 9 in this vicinity is deposited on the shielding portion 6b.
Further, since the lower flange 7a side of the tip of the shielding portion 6b is formed in an acute angle shape, the reaction product 9 is less likely to deposit on this portion.

【0045】このため、上部反応炉6を上方に分離した
時に、上部反応炉6の内壁面および遮蔽部6bに堆積し
ている反応生成物9の粉塵はほとんど落下することはな
い。
Therefore, when the upper reaction furnace 6 is separated upward, the dust of the reaction product 9 deposited on the inner wall surface of the upper reaction furnace 6 and the shielding portion 6b hardly falls.

【0046】従って、再び上部反応炉6の上部フランジ
6aと下部反応炉7の下部フランジ7aをOリング8を
介して気密に接続して気相成長を行う場合にリークしな
いので、空気中の酸素等が取込まれることもなく、高品
質な薄膜を得ることができる。
Therefore, when the upper flange 6a of the upper reaction furnace 6 and the lower flange 7a of the lower reaction furnace 7 are airtightly connected to each other through the O-ring 8 and vapor phase growth is performed, no oxygen leaks from the oxygen in the air. It is possible to obtain a high quality thin film without taking in the above.

【0047】また、キャリアガスにH2 を使用する場合
でもリークがなくなるので、気相成長中に空気(酸素)
が取込まれることはなく、爆発の危険性もない。
Further, even when H 2 is used as the carrier gas, the leak is eliminated, so that air (oxygen) is generated during vapor phase growth.
Are not captured and there is no danger of explosion.

【0048】また、遮蔽部6bの長さは特に限定されな
いが、基板2の搬入および搬出に支障のない範囲で、で
きるだけ長い方がよい。
The length of the shielding portion 6b is not particularly limited, but it is preferable that the length is as long as possible so long as it does not hinder the loading and unloading of the substrate 2.

【0049】図4は、本実施例の変形例に係る遮蔽部6
bと下部フランジ7aの断面図であり、この実施例では
遮蔽部6cのテーパ部6dの傾斜に合わせて下部反応炉
7の下部フランジ7aの内壁面にも同様のテーパ部7c
を設けた構成である。本実施例においては上部フランジ
6の遮蔽部6cを、下部反応炉7内によりスムーズに挿
入することができる。
FIG. 4 shows a shield portion 6 according to a modification of this embodiment.
2B is a cross-sectional view of the lower flange 7a, and in this embodiment, the same taper portion 7c is formed on the inner wall surface of the lower flange 7a of the lower reactor 7 in accordance with the inclination of the taper portion 6d of the shielding portion 6c.
Is provided. In this embodiment, the shielding portion 6c of the upper flange 6 can be inserted into the lower reaction furnace 7 more smoothly.

【0050】<第3実施例>図5は、第3実施例に係る
気相成長装置を示す概略断面図、図6は、その要部を示
す拡大断面図である。両図に示すように本実施例では、
基板ホルダ3内に設けた基板支持具12のざぐり部12
aの角部12bに沿って溝22を形成し、ざぐり部12
aで基板2の周縁部の底面を支持した構成であり、基板
ホルダ3と基板支持具12とで基板支持部材23が形成
されている。他の構成は図10に示した従来例の気相成
長装置と同様である。
<Third Embodiment> FIG. 5 is a schematic sectional view showing a vapor phase growth apparatus according to the third embodiment, and FIG. 6 is an enlarged sectional view showing a main part thereof. In this embodiment, as shown in both figures,
Counterbore 12 of substrate support 12 provided in substrate holder 3
The groove 22 is formed along the corner 12b of the a, and the counterbore 12
The bottom surface of the peripheral edge of the substrate 2 is supported by a, and the substrate holder 3 and the substrate support 12 form a substrate support member 23. Other configurations are similar to those of the conventional vapor phase growth apparatus shown in FIG.

【0051】基板支持具12のざぐり部12aの角部1
2bに形成される溝22は、例えば深さが0.2mm、幅
が1mmであり、この溝22上に基板2の周縁部の底面が
載置され、基板2の外周面はざぐり部12aの内壁面に
ほぼ接している。
Corner 1 of counterbore 12a of substrate support 12
The groove 22 formed in 2b has, for example, a depth of 0.2 mm and a width of 1 mm, the bottom surface of the peripheral edge of the substrate 2 is placed on the groove 22, and the outer peripheral surface of the substrate 2 has a counterbore portion 12a. It is almost in contact with the inner wall surface.

【0052】本実施例に係る気相成長装置は上記のよう
に構成されており、基板2への気相成長は第1実施例と
同様にして行われるので、ここでは省略する。
The vapor phase growth apparatus according to the present embodiment is constructed as described above, and vapor phase growth on the substrate 2 is carried out in the same manner as in the first embodiment, so it is omitted here.

【0053】そして、気相成長時に基板2が高速回転し
ても、ざぐり部12aの角部12bに形成した溝22に
よって角部12bは丸くなっていないので、基板2の周
縁部の底面および外周面がざぐり部12aにほぼ隙間な
く接することにより、基板2に傾きやずれが生じること
はない。従って、図7に示すように、基板2の面内温度
分布が均一になって良好な薄膜を得ることができるの
で、気相成長によって得られる例えばIn Ga A1P等
の半導体レーザの発振波長の均一性がよくなる。
Even if the substrate 2 rotates at high speed during vapor phase growth, the corners 12b are not rounded due to the grooves 22 formed in the corners 12b of the counterbore 12a. Since the surface is in contact with the spot facing portion 12a with almost no gap, the substrate 2 is not tilted or displaced. Therefore, as shown in FIG. 7, since the in-plane temperature distribution of the substrate 2 becomes uniform and a good thin film can be obtained, the oscillation wavelength of a semiconductor laser such as InGaA1P obtained by vapor phase growth becomes uniform. Sexuality improves.

【0054】また、本実施例では別体で形成される基板
ホルダ3と基板支持具12とで基板支持部材23を形成
したが、基板ホルダ3と基板支持具12を一体に形成す
ることもできる。
In this embodiment, the substrate holder 3 and the substrate supporting member 12 which are separately formed form the substrate supporting member 23, but the substrate holder 3 and the substrate supporting member 12 may be integrally formed. ..

【0055】[0055]

【発明の効果】以上、実施例に基づいて具体的に説明し
たように、請求項1に記載の第1の発明によれば、反応
炉の内壁面に近接して配設した遮蔽板により反応炉内で
成長する反応生成物の洗浄,除去を容易にし、且つ安全
に行うことができ、また、遮蔽板の方が反応炉の内壁面
よりも表面積が小さいので、洗浄後の脱ガスが少なくな
り、高品質な薄膜を得ることができる。
As described above in detail with reference to the embodiments, according to the first aspect of the present invention, the reaction is effected by the shield plate arranged in the vicinity of the inner wall surface of the reaction furnace. Cleaning and removal of reaction products growing in the furnace can be performed easily and safely, and since the shielding plate has a smaller surface area than the inner wall surface of the reaction furnace, less degassing occurs after cleaning. Therefore, a high quality thin film can be obtained.

【0056】また、請求項2に記載の発明によれば、分
割される第1の反応炉構成体と第2の反応炉構成体の分
割面を覆うようにして第2の反応炉構成体内に挿入され
る遮蔽部を第1の反応炉構成体に形成したことにより、
分割面付近の反応生成物は遮蔽部に堆積するので、第1
の反応炉構成体と第2の反応炉構成体を分割した時に分
割面をシールするシール手段に反応生成物が落下して付
着することはない。
Further, according to the invention described in claim 2, in the second reactor structure, the divided surfaces of the first reactor structure and the second reactor structure to be divided are covered. By forming the shield part to be inserted in the first reactor structure,
Since reaction products near the dividing surface are deposited on the shielding part, the first
The reaction product does not drop and adhere to the sealing means that seals the divided surfaces when the reaction furnace constituent body and the second reaction furnace constituent body are divided.

【0057】従って、気相成長時にリークしないため原
料ガス以外のガスが取込まれることが防止されて高品質
な薄膜を得ることができる。
Therefore, since gas does not leak during vapor phase growth, gas other than the source gas is prevented from being taken in, and a high quality thin film can be obtained.

【0058】また、請求項3に記載の発明によれば、基
板支持部材のざぐり部の基板周縁部の底面が接する角部
に溝を形成したことにより、基板周縁部の底面がざぐり
部の角部に傾きやずれが生じることなく安定して支持さ
れるので、基板の面内温度分布が均一になって高品質な
薄膜を得ることができきる。
According to the third aspect of the present invention, since the groove is formed at the corner portion of the countersunk portion of the substrate supporting member which is in contact with the bottom surface of the peripheral edge portion of the substrate, the bottom surface of the peripheral edge portion of the substrate is at the corner of the counterbore portion. Since the substrate is stably supported without being tilted or displaced, the in-plane temperature distribution of the substrate becomes uniform and a high quality thin film can be obtained.

【図面の簡単な説明】[Brief description of drawings]

【図1】本発明の第1実施例に係る気相成長装置を示す
概略断面図である。
FIG. 1 is a schematic cross-sectional view showing a vapor phase growth apparatus according to a first embodiment of the present invention.

【図2】本発明の第2実施例に係る気相成長装置を示す
概略断面図である。
FIG. 2 is a schematic cross-sectional view showing a vapor phase growth apparatus according to a second embodiment of the present invention.

【図3】図2に示した気相成長装置の反応炉を分割した
状態を示す概略断面図である。
3 is a schematic cross-sectional view showing a state in which the reaction furnace of the vapor phase growth apparatus shown in FIG. 2 is divided.

【図4】第2実施例に係る気相成長装置の変形例の要部
を示す断面図である。
FIG. 4 is a sectional view showing an essential part of a modified example of the vapor phase growth apparatus according to the second embodiment.

【図5】本発明の第3実施例に係る気相成長装置を示す
概略断面図である。
FIG. 5 is a schematic sectional view showing a vapor phase growth apparatus according to a third embodiment of the present invention.

【図6】図5で示した気相成長装置の要部を示す断面図
である。
6 is a cross-sectional view showing a main part of the vapor phase growth apparatus shown in FIG.

【図7】本発明の第3実施例に係る気相成長装置による
基板面内温度分布を示す図である。
FIG. 7 is a diagram showing a temperature distribution in a substrate surface by a vapor phase growth apparatus according to a third embodiment of the present invention.

【図8】従来の気相成長装置を示す概略断面図である。FIG. 8 is a schematic sectional view showing a conventional vapor phase growth apparatus.

【図9】図8で示した気相成長装置の反応炉を分割した
状態を示す概略断面図である。
9 is a schematic cross-sectional view showing a state in which the reaction furnace of the vapor phase growth apparatus shown in FIG. 8 is divided.

【図10】従来の気相成長装置を示す概略断面図であ
る。
FIG. 10 is a schematic cross-sectional view showing a conventional vapor phase growth apparatus.

【図11】図10に示した気相成長装置の要部を示す拡
大断面図である。
11 is an enlarged cross-sectional view showing a main part of the vapor phase growth apparatus shown in FIG.

【図12】図10に示した従来の気相成長装置による基
板面内温度分布を示す図である。
12 is a diagram showing a temperature distribution in a substrate surface by the conventional vapor phase growth apparatus shown in FIG.

【符号の説明】[Explanation of symbols]

1 反応炉 2 基板 3 基板ホルダ 5 ヒータ 6 上部反応炉(第1の反応炉構成体) 6a 上部フランジ 6c 遮蔽板 6d テーパ部 7 下部反応炉(第2の反応炉構成体) 7b 下部フランジ 8 Oリング(シール手段) 9 反応生成物 12 基板支持具 12a ざぐり部 12b 角部 20 遮蔽板 22 溝 23 基板支持部材 1 Reactor 2 Substrate 3 Substrate Holder 5 Heater 6 Upper Reactor (First Reactor Constituent) 6a Upper Flange 6c Shielding Plate 6d Tapered Part 7 Lower Reactor (Second Reactor Constituent) 7b Lower Flange 8 O Ring (seal means) 9 Reaction product 12 Substrate support 12a Counterbore 12b Corner 20 Shielding plate 22 Groove 23 Substrate support member

Claims (3)

【特許請求の範囲】[Claims] 【請求項1】 反応炉内に配設した基板ホルダ上に載置
された基板を加熱手段により加熱するとともに、前記反
応炉内に原料ガスを供給して前記基板に薄膜を気相成長
させる気相成長装置において、気相成長時に前記反応炉
内で成長する反応生成物を堆積させる遮蔽板を前記反応
炉の内壁面に近接させて配設したことを特徴とする気相
成長装置。
1. A gas for heating a substrate placed on a substrate holder arranged in a reaction furnace by a heating means and supplying a source gas into the reaction furnace to vapor-deposit a thin film on the substrate. In the phase growth apparatus, a shield plate for depositing a reaction product that grows in the reaction furnace at the time of vapor phase growth is arranged close to the inner wall surface of the reaction furnace.
【請求項2】 第1の反応炉構成体と第2の反応炉構成
体とに分割可能でその分割面がシール手段を介して気密
に接続される反応炉を備え、前記反応炉内に配設した基
板ホルダ上に載置された基板を加熱手段により加熱する
とともに、前記反応炉内に原料ガスを供給して前記基板
に薄膜を気相成長させる気相成長装置において、前記原
料ガスの流れ方向上流側に位置する前記第1の反応炉構
成体の前記第2の反応炉構成体と接する端部に、前記第
2の反応炉構成体の内壁面に沿って挿入される遮蔽部を
形成したことを特徴とする気相成長装置。
2. A reaction furnace, which is divisible into a first reactor structure and a second reactor structure, and whose dividing surface is hermetically connected via a sealing means, is provided in the reactor. In a vapor phase growth apparatus for heating a substrate placed on an established substrate holder by a heating means and supplying a source gas into the reaction furnace to vapor-deposit a thin film on the substrate, the flow of the source gas A shield part to be inserted along the inner wall surface of the second reactor structure at the end of the first reactor structure located upstream in the direction in contact with the second reactor structure. A vapor phase growth apparatus characterized in that
【請求項3】 反応炉内に配設した基板支持部材上に載
置された基板を加熱手段により加熱するとともに、前記
反応炉内に原料ガスを供給して前記基板に薄膜を気相成
長させる気相成長装置において、前記基板支持部材に前
記基板の周縁部を支持するざぐり部を形成し、前記ざぐ
り部の前記基板底面の周縁部が接する角部に溝を形成し
たことを特徴とする気相成長装置。
3. A substrate placed on a substrate supporting member arranged in a reaction furnace is heated by a heating means, and a source gas is supplied into the reaction furnace to vapor-deposit a thin film on the substrate. In the vapor phase growth apparatus, the substrate supporting member is provided with a countersunk portion for supporting the peripheral portion of the substrate, and a groove is formed at a corner portion of the countersunk portion which is in contact with the peripheral portion of the substrate bottom surface. Phase growth equipment.
JP30791791A 1991-11-22 1991-11-22 Vapor phase growth apparatus Pending JPH05144734A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP30791791A JPH05144734A (en) 1991-11-22 1991-11-22 Vapor phase growth apparatus

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP30791791A JPH05144734A (en) 1991-11-22 1991-11-22 Vapor phase growth apparatus

Publications (1)

Publication Number Publication Date
JPH05144734A true JPH05144734A (en) 1993-06-11

Family

ID=17974725

Family Applications (1)

Application Number Title Priority Date Filing Date
JP30791791A Pending JPH05144734A (en) 1991-11-22 1991-11-22 Vapor phase growth apparatus

Country Status (1)

Country Link
JP (1) JPH05144734A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2009027021A (en) * 2007-07-20 2009-02-05 Nuflare Technology Inc Vapor-phase growing device and vapor-phase growing method

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2009027021A (en) * 2007-07-20 2009-02-05 Nuflare Technology Inc Vapor-phase growing device and vapor-phase growing method

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