JPH049121A - Lotion paper and its manufacturing - Google Patents
Lotion paper and its manufacturingInfo
- Publication number
- JPH049121A JPH049121A JP2190424A JP19042490A JPH049121A JP H049121 A JPH049121 A JP H049121A JP 2190424 A JP2190424 A JP 2190424A JP 19042490 A JP19042490 A JP 19042490A JP H049121 A JPH049121 A JP H049121A
- Authority
- JP
- Japan
- Prior art keywords
- paper
- skin
- lotion
- solution
- emulsifying solution
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000006210 lotion Substances 0.000 title claims abstract description 31
- 238000004519 manufacturing process Methods 0.000 title claims description 12
- 239000003974 emollient agent Substances 0.000 claims abstract description 24
- 230000001804 emulsifying effect Effects 0.000 claims description 65
- 238000000034 method Methods 0.000 claims description 17
- 238000007639 printing Methods 0.000 claims description 14
- 239000007787 solid Substances 0.000 claims description 8
- 239000004745 nonwoven fabric Substances 0.000 claims description 5
- 238000001035 drying Methods 0.000 claims description 4
- 239000000835 fiber Substances 0.000 claims description 4
- 238000009827 uniform distribution Methods 0.000 claims 1
- 238000010521 absorption reaction Methods 0.000 abstract description 5
- 238000001704 evaporation Methods 0.000 abstract description 5
- 239000007788 liquid Substances 0.000 abstract description 5
- 210000004243 sweat Anatomy 0.000 abstract description 5
- 239000002699 waste material Substances 0.000 abstract description 5
- 230000008020 evaporation Effects 0.000 abstract description 3
- 239000000203 mixture Substances 0.000 description 12
- 230000000694 effects Effects 0.000 description 11
- 229940079593 drug Drugs 0.000 description 7
- 239000003814 drug Substances 0.000 description 7
- GLDOVTGHNKAZLK-UHFFFAOYSA-N octadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCO GLDOVTGHNKAZLK-UHFFFAOYSA-N 0.000 description 6
- 230000035807 sensation Effects 0.000 description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 6
- 238000004140 cleaning Methods 0.000 description 4
- BXWNKGSJHAJOGX-UHFFFAOYSA-N hexadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCO BXWNKGSJHAJOGX-UHFFFAOYSA-N 0.000 description 4
- 239000004615 ingredient Substances 0.000 description 4
- 229920002522 Wood fibre Polymers 0.000 description 3
- 239000002250 absorbent Substances 0.000 description 3
- 230000002745 absorbent Effects 0.000 description 3
- 238000010586 diagram Methods 0.000 description 3
- 239000003205 fragrance Substances 0.000 description 3
- GOQYKNQRPGWPLP-UHFFFAOYSA-N n-heptadecyl alcohol Natural products CCCCCCCCCCCCCCCCCO GOQYKNQRPGWPLP-UHFFFAOYSA-N 0.000 description 3
- 239000012188 paraffin wax Substances 0.000 description 3
- 239000002025 wood fiber Substances 0.000 description 3
- 239000003463 adsorbent Substances 0.000 description 2
- 229960000541 cetyl alcohol Drugs 0.000 description 2
- 238000000576 coating method Methods 0.000 description 2
- 230000007423 decrease Effects 0.000 description 2
- 239000003995 emulsifying agent Substances 0.000 description 2
- 208000014617 hemorrhoid Diseases 0.000 description 2
- 238000009474 hot melt extrusion Methods 0.000 description 2
- 229940057995 liquid paraffin Drugs 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 238000005507 spraying Methods 0.000 description 2
- PRAKJMSDJKAYCZ-UHFFFAOYSA-N squalane Chemical compound CC(C)CCCC(C)CCCC(C)CCCCC(C)CCCC(C)CCCC(C)C PRAKJMSDJKAYCZ-UHFFFAOYSA-N 0.000 description 2
- 206010028980 Neoplasm Diseases 0.000 description 1
- 206010052428 Wound Diseases 0.000 description 1
- 208000027418 Wounds and injury Diseases 0.000 description 1
- 239000003638 chemical reducing agent Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 239000002537 cosmetic Substances 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 239000002781 deodorant agent Substances 0.000 description 1
- 239000000645 desinfectant Substances 0.000 description 1
- 230000002500 effect on skin Effects 0.000 description 1
- 238000004945 emulsification Methods 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000003822 epoxy resin Substances 0.000 description 1
- 238000007667 floating Methods 0.000 description 1
- 230000006870 function Effects 0.000 description 1
- 238000009499 grossing Methods 0.000 description 1
- 239000002075 main ingredient Substances 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 210000003097 mucus Anatomy 0.000 description 1
- JXTPJDDICSTXJX-UHFFFAOYSA-N n-Triacontane Natural products CCCCCCCCCCCCCCCCCCCCCCCCCCCCCC JXTPJDDICSTXJX-UHFFFAOYSA-N 0.000 description 1
- 239000008194 pharmaceutical composition Substances 0.000 description 1
- 229920000647 polyepoxide Polymers 0.000 description 1
- 206010039083 rhinitis Diseases 0.000 description 1
- 238000007650 screen-printing Methods 0.000 description 1
- 229920002545 silicone oil Polymers 0.000 description 1
- 238000002791 soaking Methods 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 229940032094 squalane Drugs 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 239000003206 sterilizing agent Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000012209 synthetic fiber Substances 0.000 description 1
- 229920002994 synthetic fiber Polymers 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
Landscapes
- Making Paper Articles (AREA)
- Cosmetics (AREA)
- Sanitary Thin Papers (AREA)
Abstract
Description
【発明の詳細な説明】
〔産業上の利用分野〕
本発明は皮膚に接触させて清拭する際に皮膚に付着して
いる水分や老廃物の払拭効果に優れており且つ皮膚接触
感覚にも優れた風合を有する薄葉紙から成るローション
ペーパー及びその製造方法に関するものである。[Detailed Description of the Invention] [Industrial Application Field] The present invention has an excellent effect of wiping away moisture and waste matter adhering to the skin when it comes into contact with the skin and wipes it, and also has a good effect on skin contact sensation. The present invention relates to a lotion paper made of thin paper having an excellent texture and a method for manufacturing the same.
日常生活において、皮膚の清拭には所謂ティッシュペー
パーが広く使用されているが、清拭操作を行う際に痔疾
、傷口、腫等に刺激を与えないために、殺菌消毒用薬剤
及び／又は消臭用薬剤を浸漬乾燥させたドライ状であっ
て使用時に水を含ま一
せてウェット状にして使用する清拭用ドライティッシュ
ペーパー（特開昭６３−６３４１９号参照）や、流動パ
ラフィン、セチルアルコール、ステアリルアルコールの
１種以上と柔軟性油剤とを混合したものをスプレー散布
又はロールコート等で塗布した痔疾皮膚清浄用紙製品（
特開昭６２−８７１１７号参照）や、油分吸着剤粒子、
水分吸着剤粒子、消臭剤及び香料を含有する組成物を吸
収性シート上にマイヤーロッド、フローティングローラ
ー又はドクターブレードにより塗布したり、ステンレス
スチールローラーによりロール塗布したり、スプレー塗
布したりして上記組成物を含浸させた後に乾燥した化粧
用具（特表昭６０−５００１２４号参照）等が知られて
いる。In daily life, so-called tissue paper is widely used for cleaning the skin, but in order to avoid irritating hemorrhoids, wounds, tumors, etc. when performing the cleaning operation, sterilizing agents and/or disinfectants are used. Dry tissue paper for cleaning, which is made by soaking and drying an odor-reducing agent and is wetted with water before use (see Japanese Patent Application Laid-open No. 63-63419), liquid paraffin, and cetyl alcohol. , Hemorrhoid skin cleaning paper products coated with a mixture of one or more types of stearyl alcohol and a softening oil by spraying or roll coating (
JP-A No. 62-87117), oil adsorbent particles,
A composition containing moisture adsorbent particles, a deodorant and a fragrance is applied onto an absorbent sheet by a Meyer rod, a floating roller or a doctor blade, by a roll application by a stainless steel roller, or by spray application. Cosmetic tools that are impregnated with a composition and then dried (see Japanese Patent Application No. 500124/1983) are known.
更に、このような各種薬剤組成物の全面塗布後の不完全
乾燥部分の発生による″ペタツキ感を防いだり、薬剤組
成物の全面塗布によるティッシュペーパーの湿潤強度の
低下を防いだりするために、常温固形の薬剤組成物を熱
溶融押出し法で塗布する方法も従来から広〈実施されて
きている。Furthermore, in order to prevent the ``sticky feeling'' caused by the occurrence of incompletely dry areas after the entire surface application of various drug compositions, and to prevent the wet strength of the tissue paper from decreasing due to the entire surface application of the drug composition, it is necessary to keep the tissue paper at room temperature. A method of applying a solid drug composition by hot melt extrusion has also been widely practiced.
しかしながら、これらの方法により製造される皮膚清浄
用紙製品は、製品面から見るとティッシュペーパーの全
面に薬剤組成物が含浸又は塗布されたものであるため、
吸水吸湿性が阻害され特別な吸湿剤を用いなければ皮膚
に接触させた際に汗や老廃物の吸収が悪かったり、ティ
ッシュペーパーの全面に薬剤組成物がフィルム状に存在
しているためにゴワゴワして風合が悪かったりし、この
欠点を除去しようとして常温液体の薬剤組成物をティッ
シュペーパーの全面に含浸、散布、塗布のいずれかを行
った後に乾燥させると乾燥した製品に“ペタツキ感が残
るという不具合が生じる。However, skin cleansing paper products manufactured by these methods are tissue paper impregnated or coated with a pharmaceutical composition on the entire surface, so
Water absorption and hygroscopicity are inhibited, and if a special moisture absorbent is not used, sweat and waste products may not be absorbed well when the tissue comes into contact with the skin, and the drug composition may be present in a film form on the entire surface of the tissue paper, making it stiff. If you try to remove this defect by impregnating, spraying, or applying a room-temperature liquid drug composition over the entire surface of tissue paper and then drying it, the dry product will have a "sticky" feel. A problem arises in that it remains.
そこでこの対策として前述したように常温固形の薬剤組
成物を塗布する技術が慣用されているが、この方法は特
殊な熱溶融押出し機、すなわちエクストルーダーやＴダ
イを使用しなければならないという欠点があった。As a countermeasure to this problem, the technique of applying a solid drug composition at room temperature is commonly used as described above, but this method has the disadvantage that it requires the use of a special hot melt extrusion machine, that is, an extruder or a T-die. there were.
そしてこれらの従来方法においては、製造工程において
ティッシュペーパーの全面に薬剤組成物を含浸、散布、
塗布のいずれかを行うのでテイツ＝３−
シュペーパーの湿潤強度が低下して生産性に支障を来す
ため、これを防ぐために水に溶解しないティッシュペー
パー、例えばエポキシ樹脂処理紙を使用したりしたが、
このような処理紙は水に不溶性であるためにトイレット
ペーパーに応用した場合に水洗トイレに流すことができ
ないという問題点が生じていた。In these conventional methods, the entire surface of the tissue paper is impregnated with a drug composition, sprayed, or
Since either of the coating methods is applied, the wet strength of the paper decreases, which hinders productivity. To prevent this, tissue paper that does not dissolve in water, such as epoxy resin-treated paper, is used. but,
Since such treated paper is insoluble in water, when it is used as toilet paper, there is a problem that it cannot be flushed into a flush toilet.
本発明は前述したような従来の欠点を解消し、皮膚に接
触させて清拭する際に皮膚に付着している水分や老廃物
の払拭効果に優れており且つ皮膚接触感覚にも優れた風
合を有し“ペタツキ感が残らない特殊加工を施さない薄
葉紙から成るローションペーパー及びこのローションペ
ーパーを特別な吸湿剤や特別な設備を使用すること無く
製造することのできる方法を提供することを課題とする
ものである。The present invention solves the above-mentioned conventional drawbacks, and has an excellent effect of wiping away moisture and wastes adhering to the skin when it comes into contact with the skin and cleansing it, and also has an excellent skin contact sensation. It is an object of the present invention to provide a lotion paper made of thin paper that is not specially processed and does not leave a sticky feeling, and a method for manufacturing this lotion paper without using a special moisture absorbent or special equipment. That is.
本発明者らは上記課題を解決すべく鋭意研究の結果、薄
葉紙の表面に少なくともエモリエント剤を成分中に含有
する乳化溶液を、塗布されている部分と塗布されていな
い部分とが５〜５０％：９５〜５０％の面積比でほぼ均
一に分布しておればよく、このように薄葉紙の表面に乳
化溶液を塗布されている部分と塗布されていない部分と
を形成させるには凸部と凹部とが５〜５０％：９５〜５
０％の面積比でほぼ均一に分布している印刷版の凸部に
付着させた少なくともエモリエント剤を成分中に含有す
る乳化溶液を薄葉紙の表面に塗布し乾燥すればよいこと
を究明して本発明を完成したのである。As a result of intensive research to solve the above problems, the present inventors have found that an emulsifying solution containing at least an emollient agent is applied to the surface of tissue paper so that the difference between the coated area and the uncoated area is 5 to 50%. : It is sufficient to distribute the emulsifying solution almost uniformly with an area ratio of 95 to 50%, and in order to form parts coated with the emulsifying solution and parts not coated on the surface of the thin paper in this way, it is necessary to have a convex part and a concave part. and 5-50%: 95-5
The authors discovered that it is sufficient to apply an emulsified solution containing at least an emollient agent to the surface of thin paper and dry it, which is applied to the convex portions of a printing plate that are almost uniformly distributed with an area ratio of 0%. He completed his invention.
以下１本発明に係るローションペーパー及びその製造方
法について詳細に説明する。The lotion paper and method for manufacturing the same according to the present invention will be explained in detail below.
本発明において、薄葉紙とは木質繊維や木質繊維に合成
繊維を混入した薄紙や更にその他の繊維を混入したもの
やこれらの薄紙例えばティッシュペーパーを複数枚積層
したものや不織布を言い、エモリエント剤とは固形パラ
フィンや流動パラフィンなどのパラフィン、ステアリル
アルコール。In the present invention, thin paper refers to wood fibers, wood fibers mixed with synthetic fibers, wood fibers mixed with other fibers, these thin papers such as tissue paper laminated with multiple sheets, and nonwoven fabrics. Paraffin, such as solid paraffin and liquid paraffin, and stearyl alcohol.
セチルアルコール、スクワラン、シリコーンオイル、ス
テアリス等を主成分とする皮膚等の柔軟剤を言い、少な
くともエモリエント剤を成分中に含有する乳化溶液とは
このようなエモリエント剤に乳化剤、香料、水等を添加
した乳化溶液を言う。An emulsified solution that contains at least an emollient is a softener for skin, etc. whose main ingredients are cetyl alcohol, squalane, silicone oil, stearis, etc., and an emulsified solution that contains at least an emollient as an ingredient is an emulsifier, fragrance, water, etc. added to such an emollient. An emulsified solution.
この乳化溶液は成分的には一般にローションペーパーを
製造するのに使用さ九ている乳化溶液と変わるところは
ないが、その粘度が５００〜３，０００センチポアズ、
好ましくは１．（ｔｏ（１〜２，０００センチポアズと
いう従来使用されていた乳化溶液より高粘度のものが好
ましく用いられる。The composition of this emulsified solution is the same as the emulsified solution generally used for manufacturing lotion paper, but its viscosity is 500 to 3,000 centipoise.
Preferably 1. (to(1 to 2,000 centipoise), which has a higher viscosity than conventionally used emulsified solutions, is preferably used.
本発明に係るローションペーパーは、第１〜３図の薄葉
紙の表面に乳化溶液が塗布されている例を示す各説明図
に示すように、薄葉紙１の表面に、少なくともエモリエ
ント剤を成分中に含有する乳化溶液が塗布されている部
分Ａと塗布されていない部分Ｂとが５〜５０％＝９５〜
５０％の面積比でほぼ均一に分布していることを特徴と
するものであり、薄葉紙１の表面に少なくともエモリエ
ント剤を成分中に含有する乳化溶液が塗布されている部
分Ａと塗布されていない部分Ｂとの面積比が５〜５０％
：９５〜５０％でなければならないのは、従来のローシ
ョンペーパーのように乳化溶液が薄葉紙の表面全面に塗
布されていたのでは乳化溶液が薄葉紙の表面全面をフィ
ルム状に覆う状態に付着して塗布した乳化溶液の完全な
乾燥が困難で″ベタツキ”感が残りしかも皮膚に接触さ
せて清拭する際に皮膚に付着している水分の吸収能が薄
葉紙が本来所有している水分の吸収能に比べて格段に低
下してしまうと共にゴワゴワして皮膚接触感覚が低下す
るので、塗布した乳化溶液の乾燥を確実に行い且つ水分
の吸収能が優れている薄葉紙の表面をそのままの状態で
残しておくためであり、乳化溶液が塗布されている部分
Ａが５％未満であると乳化溶液が塗布されている部分Ａ
が少なすぎてエモリエント剤を成分中に含有する乳化溶
液を塗布したことによる皮膚面を滑らかにし且つ皮膚水
分の蒸発を防ぐ効果が不充分となって乳化溶液を塗布し
ていない通常の薄葉紙と変わるところがなくなるためで
あり、また乳化溶液が塗布されていない部分Ｂが５０％
を越えると乳化溶液が塗布されている部分Ｂが多すぎて
ゴワゴワして皮膚接触感覚が低下−７＝
すると共に薄葉紙１が本来所有している水分の吸収能を
充分に発揮させることができないからである。また、薄
葉紙ｌの表面に少なくともエモリエント剤を成分中に含
有する乳化溶液が塗布されている部分Ａと塗布されてい
ない部分Ｂとがほぼ均一に分布していなければならない
のは、乳化溶液が塗布されている部分Ａと塗布されてい
ない部分Ｂとの面積比が５〜５０％二９５〜５０％であ
っても成る部分では殆ど全面が乳化溶液を塗布されてい
る部分Ａとなったのではその部分ではゴワゴワして皮膚
接触感覚が低下すると共に薄葉紙が本来所有している水
分の吸収能を充分に発揮させることができなくなるため
に乳化溶液が塗布されている部分Ａと塗布されていない
部分Ｂとがほぼ均一に分布していなければならないので
ある。なお、本発明で乳化溶液が塗布されている部分Ａ
と塗布されていない部分Ｂとがほぼ均一に分布している
ということは、一般にローションペーパーはその大きさ
が幅１００〜３００＋ｕ＋ Ｘ長さ１００〜３００ｍｍ
であるので、このような大きさにおいて乳化溶液が塗布
さ九ている部分Ａの繰返しパターンが充分把握できる程
度に表われることを言う、また乳化溶液が塗布されてい
る部分Ａは１例えば第１図や第２図に示すように全てが
線状を成している場合には上記した如く乳化溶液が塗布
されている部分Ａと塗布されていない部分Ｂとの面積比
が５〜５０％：９５〜５０％であってほぼ均一に分布し
ていれば良いが、例えば第３図に示す如く円形状や多角
形状などに乳化溶液が塗布されていない部分Ｂを残すよ
うに乳化溶液が塗布されている場合には乳化溶液が塗布
されていない部分Ｂの面積が２５ｃｄを越えると一般に
ローションペーパーはその大きさが幅ｌｏｏ〜３００ｍ
ｍ×長さ１００〜３００鵬鵬であるのでローションペー
パーを使用した際に乳化溶液を塗布されていない部分Ｂ
が皮膚に殆ど接触しない現象が生じてエモリエント剤の
皮膚面を滑らかにし且つ皮膚水分の蒸発を防ぐ効果が発
揮されない場合が生じるので、２５ｄ以下にすることが
好ましい。The lotion paper according to the present invention contains at least an emollient agent as a component on the surface of the thin paper 1, as shown in each explanatory diagram showing an example in which an emulsified solution is applied to the surface of the thin paper 1 in FIGS. Part A where the emulsifying solution is applied and part B where it is not applied are 5-50% = 95-50%
It is characterized by being almost uniformly distributed with an area ratio of 50%, and there are areas A where an emulsifying solution containing at least an emollient as an ingredient is applied to the surface of the thin paper 1 and areas A where it is not applied. Area ratio with part B is 5-50%
: The reason why it must be 95-50% is that if the emulsifying solution is applied to the entire surface of the tissue paper like in conventional lotion paper, the emulsifying solution will adhere to the entire surface of the tissue paper in a film-like state. It is difficult to completely dry the applied emulsified solution, leaving a sticky feeling, and when it is brought into contact with the skin and wiped, the ability to absorb moisture adhering to the skin is not the same as that of tissue paper. As the emulsion becomes stiff and the skin contact sensation is reduced, it is necessary to ensure that the applied emulsified solution dries and leave the surface of the tissue paper, which has excellent moisture absorption ability, as it is. If the area A to which the emulsifying solution is applied is less than 5%, the area A to which the emulsifying solution is applied is
is too low, and the effect of applying an emulsifying solution containing an emollient in its ingredients to smooth the skin surface and prevent skin moisture from evaporating is insufficient, and the paper changes to normal tissue paper without an emulsifying solution applied. However, this is because the emulsifying solution disappears, and the portion B where the emulsifying solution is not applied is 50%
If it exceeds the area B where the emulsified solution is applied, it becomes stiff and the skin contact sensation decreases -7 = and the tissue paper 1 is unable to fully utilize its inherent ability to absorb moisture. It is. In addition, the area A where the emulsifying solution containing at least an emollient agent is coated on the surface of the thin paper L and the area B where it is not coated must be distributed almost uniformly because the emulsifying solution is coated. Even if the area ratio of part A coated with part B to uncoated part B is 5 to 50% or 95 to 50%, almost the entire surface of the part is part A coated with the emulsifying solution. In that area, the skin becomes stiff and the sensation of contact with the skin is reduced, and the tissue paper is no longer able to fully utilize its inherent ability to absorb moisture. B must be distributed almost uniformly. In addition, in the present invention, the part A where the emulsifying solution is applied
The fact that the uncoated portion B and the uncoated portion B are almost uniformly distributed means that the size of lotion paper is generally 100 to 300 mm in width and 100 to 300 mm in length.
Therefore, in such a size, the repeating pattern of the part A to which the emulsifying solution is applied is clearly visible. As shown in the figure and FIG. 2, when everything is linear, the area ratio of the area A where the emulsifying solution is applied and the area B where the emulsifying solution is not applied is 5 to 50% as described above. It is sufficient that the emulsifying solution is 95 to 50% and distributed almost uniformly, but for example, as shown in Fig. 3, the emulsifying solution is applied so as to leave a portion B in a circular or polygonal shape where the emulsifying solution is not applied. If the area of part B to which the emulsifying solution is not applied exceeds 25 cd, the lotion paper generally has a width of loo to 300 m.
Since the length is 100 to 300 m x length, part B is not coated with emulsifying solution when using lotion paper.
It is preferable to set the emollient to 25 d or less, since this may cause the emollient to hardly come into contact with the skin, and the effect of the emollient to smooth the skin surface and prevent skin moisture from evaporating may not be exhibited.
このような本発明に係るローションペーパーを製造する
方法は、凸部と凹部とが５〜５０％＝９５〜−１〇−
５０％の面積比でほぼ均一に分布している印刷版の凸部
に付着させた少なくともエモリエント剤を成分中に含有
する乳化溶液を薄葉紙の表面に塗布し乾燥することを特
徴とする。The method for manufacturing the lotion paper according to the present invention is to produce a printing plate in which the convex portions and concave portions are almost uniformly distributed with an area ratio of 5 to 50% = 95 to -10-50%. The method is characterized in that an emulsified solution containing at least an emollient as a component is applied onto the surface of thin paper and dried.
このように本発明方法において薄葉紙の表面に乳化溶液
を塗布する手段として印刷版を使用するのは、前述した
ように乳化溶液が塗布されている部分と塗布されていな
い部分とが所定の面積比でほぼ均一に分布するように工
業的に薄葉紙の表面に乳化溶液を塗布するには凸部と凹
部とを有する印刷版を使用する印刷技術を応用すること
が最も適しているからであり、特にロール外面に印刷版
を有するゴム製ロール例えばフレ謳ソロールを使用する
か又はロール外面に印刷版を有する金属製ロール例えば
オフセットロールを使用することが好ましく、後者の場
合にはオフセットロールへの乳化溶液の供給を転写ロー
ルとバックアップロールを介して行うために少量の乳化
溶液を薄葉紙の表面にムラなく塗布することができて好
ましい。In this way, in the method of the present invention, a printing plate is used as a means for applying an emulsifying solution to the surface of thin paper. This is because it is most suitable to industrially apply an emulsifying solution to the surface of thin paper so that it is almost uniformly distributed on the surface of tissue paper, using a printing technique that uses a printing plate with convex and concave areas. It is preferable to use a rubber roll with a printing plate on the outside of the roll, such as a flexo roll, or a metal roll with a printing plate on the outside of the roll, such as an offset roll, in the latter case applying the emulsified solution to the offset roll. It is preferable that the emulsifying solution is supplied via a transfer roll and a backup roll so that a small amount of the emulsifying solution can be evenly applied to the surface of the thin paper.
また、グラビアロールを使用すると乳化溶液の塗布量を
簡単に調整することができる利点がある。Furthermore, the use of a gravure roll has the advantage that the amount of emulsifying solution applied can be easily adjusted.
なお、上述したように版ロールを使用するのではなく、
平版例えばシルクスクリーンの如き所謂プロセス印刷技
術を採用してもよいが、ローションペーパーの大量生産
を行うには生産効率の点で劣る欠点がある。Note that instead of using a plate roll as described above,
Although so-called process printing techniques such as lithographic printing, for example silk screen printing, may be employed, they have the drawback of being inferior in production efficiency when mass-producing lotion paper.
このように本発明方法では薄葉紙の表面に乳化溶液を塗
布するのに印刷版を使用するのであるが。Thus, in the method of the present invention, a printing plate is used to apply the emulsified solution to the surface of the tissue paper.
使用する乳化溶液としてはその粘度が５００〜３ 、０
００センチポアズ、好ましくは１ 、０００〜２，００
０センチポアズのものを使用するのが良い、これは乳化
溶液の粘度が５００センチポアズ未満では薄葉紙への乳
化溶液の浸透が速いために薄葉紙の表面に乳化溶液が塗
布されている部分と塗布されていない部分とがほぼ均一
に分布するように塗布しようとしても乳化溶液が塗布さ
れている部分と塗布されていない部分との境界が不鮮明
となって乳化溶液が塗布されている部分と塗布されてい
ない部分との面積比を５〜５０％：９５〜５０％とする
ことが困難になり、乳化溶液の粘度が３ 、０００セン
チポアズを超えると薄葉紙への乳化溶液の塗布ムラが生
じて薄葉紙の表面に乳化溶液が塗布されている部分と塗
布されていない部分とがほぼ均一に分布するように塗布
しようとしても乳化溶液が塗布されている部分と塗布さ
れていない部分との境界が不鮮明となって乳化溶液が塗
布されている部分と塗布されていない部分との面積比を
５〜５０％：９５〜５０％とすることが困難になるから
である。なお、このように乳化溶液を薄葉紙へ塗布する
に当って、乳化溶液の塗布量は薄葉紙の繊維固形分に対
して乾燥固形分として４〜２０％が好ましい。The emulsifying solution used has a viscosity of 500 to 3.0
00 centipoise, preferably 1,000 to 2,00
It is better to use one with 0 centipoise. This is because when the viscosity of the emulsifying solution is less than 500 centipoise, the emulsifying solution penetrates into the tissue paper quickly, so there are areas where the emulsifying solution is applied to the surface of the tissue paper and areas where it is not. Even if you try to apply the emulsifying solution so that it is distributed almost uniformly, the boundaries between the areas that are coated with the emulsifying solution and the areas that are not coated become unclear, and the areas that are coated with the emulsifying solution and the areas that are not coated with the emulsifying solution become unclear. If the viscosity of the emulsifying solution exceeds 3,000 centipoise, uneven application of the emulsifying solution to the tissue paper will occur and the emulsification will occur on the surface of the tissue paper. Even if you try to apply the solution so that the areas where the solution is applied and the areas where it is not applied are almost evenly distributed, the boundaries between the areas where the emulsifying solution is applied and the areas where the emulsifying solution is not applied become unclear and the emulsifying solution This is because it becomes difficult to set the area ratio of the coated portion to the uncoated portion to 5 to 50%:95 to 50%. In applying the emulsified solution to the thin paper in this way, the amount of the emulsified solution applied is preferably 4 to 20% as a dry solid content based on the fiber solid content of the thin paper.
上述したような本発明に係るローションペーパーにおい
ては、薄葉紙の表面に乳化溶液が塗布されている部分と
塗布されていない部分とが５〜５０％：９５〜５０％の
面積比でほぼ均一に分布しているから、皮膚を払拭する
際にローションペーパーの半分以上の面積を占める乳化
溶液が塗布されていない部分は薄葉紙の本来所有してい
る優れた水分の吸収能により汗や皮膚に付着している老
廃物等を充分に吸収させることができ、また乳化溶液が
塗布されている部分では乳化溶液中のエモリエント剤に
より皮膚面を滑らかにし且つ皮膚水分の蒸発を防ぐ効果
が発揮されるのである。そして薄葉紙が不織布か複数枚
のティッシュペーパーを積層したものである場合には、
不織布の有するバルキー性や複数枚のティッシュペーパ
ーによる柔軟性及び嵩高性により皮膚に接触させた際の
風合をより良好ならしめることができるのである。更に
、乳化溶液は水溶性であることから、皮膚に過剰に付着
した場合などは水洗により舘単に払拭できるという作用
も有している。In the lotion paper according to the present invention as described above, the areas where the emulsifying solution is applied and the areas where the emulsifying solution is not applied on the surface of the thin paper are almost uniformly distributed with an area ratio of 5 to 50%: 95 to 50%. Therefore, when wiping the skin, the area where the emulsified solution, which occupies more than half of the area of the lotion paper, is not applied is free from sweat and adhesion to the skin due to the tissue paper's inherent excellent moisture absorption ability. In addition, in areas where the emulsified solution is applied, the emollient agent in the emulsified solution has the effect of smoothing the skin surface and preventing evaporation of skin moisture. And if the tissue paper is a non-woven fabric or a stack of multiple sheets of tissue paper,
The bulkiness of the non-woven fabric and the flexibility and bulkiness of the multiple sheets of tissue paper make it possible to improve the feel when it comes into contact with the skin. Furthermore, since the emulsified solution is water-soluble, it also has the effect that if it adheres excessively to the skin, it can be easily wiped off by washing with water.
以下に本発明を更に詳細に説明するために実施例を示す
が１本発明は下記の実施例によって何らｆｆＩＪｗｋを
受けるものではない、
実施例１〜３
山陽スコツト社製２枚重ねのティッシュペーパー（商品
名：カシミツ９坪量１５ｇ／ｎｆ）から成る薄葉紙の表
面に対繊維固形分重量が１０％となるようにホールケリ
ー社製プレキソプリンテイング印刷機で下記に示すエモ
リエント剤を成分中に含有する乳化溶液を、乳化溶液が
塗布されている部分と塗布されていない部分とがほぼ均
一に分布しており且つ乳化溶液が塗布されていない部分
の面積が約３４で且つ乳化溶液が塗布さ九ている部分と
塗布されていない部分との面積比が１０％＝９０％とな
るように塗布した後に、送風乾燥機で４０℃、３０分間
乾燥させて３種のローションペーパーを製造した。Examples 1 to 3 Two-ply tissue paper manufactured by Sanyo Scotto Co., Ltd. The following emollient agent is added to the surface of the tissue paper (product name: Kashimitsu 9, basis weight 15 g/nf) using a Hall Kelly Plexo printing machine so that the solid content of the fiber is 10%. The emulsifying solution to be applied is applied to an area where the areas where the emulsifying solution is applied and the areas where the emulsifying solution is not applied are almost evenly distributed, the area of the area where the emulsifying solution is not applied is approximately 34, and the area where the emulsifying solution is applied is approximately 9. The lotion paper was coated so that the area ratio between the coated area and the uncoated area was 10%=90%, and then dried in a blow dryer at 40°C for 30 minutes to produce three types of lotion paper.
以下余白
第１表 乳化溶液の構成
（重量％）
”１：パラフィンは関東化学製薬社製（臘、ｐ、：５２
〜５４℃）＊′″ニスクワランは大洋漁業社製
＊３＝ステアリルアルコールは和光純薬社製ｔｈ４：乳
化剤は版本薬品工業社製ＳＹグリスター以上の成分から
成る乳化溶液を使用して製造した３種のローションペー
パーと、乳化溶液を使用しない積層ティッシュペーパー
とについて、鼻炎患者１０名に鼻水を払拭させることに
よりローションペーパー及び積層ティッシュペーパーの
風合等の使用感及び払拭機能を評価させた。その結果を
下表に示す。Table 1 with blank space below Composition of emulsified solution (wt%) 1: Paraffin is manufactured by Kanto Kagaku Seiyaku Co., Ltd. (臘, p.: 52
~54℃) *''' Nisqualane is manufactured by Taiyo Fishery Co., Ltd. *3 = Stearyl alcohol is manufactured by Wako Pure Chemical Industries, Ltd. th4: Emulsifier is manufactured using an emulsifying solution consisting of components equal to or higher than SY Glister manufactured by Hanhon Yakuhin Kogyo Co., Ltd.3 Regarding the lotion paper and the laminated tissue paper that does not use an emulsifying solution, 10 rhinitis patients were asked to wipe away mucus from their nose to evaluate the feeling of use such as the texture and wiping function of the lotion paper and the laminated tissue paper. The results are shown in the table below.
積層ティッシュペーパーと比較して
Ｏ：非常に優れている ５点（平均４．１〜５）０：優
れている ４点（平均３．１〜４）Δ：普通
３点（平均２．１〜３）ム：劣る
２点（平均１．１〜２）×：非常に劣る １
点（平均０〜１）この結果から明らかなように本発明に
係るローションペーパーはその特性が単なる積層ティッ
シュペーパーと比較して非常に優れていることが判る。Compared to laminated tissue paper O: Very good 5 points (average 4.1 to 5) 0: Excellent 4 points (average 3.1 to 4) Δ: Average
3 points (average 2.1-3): Poor
2 points (average 1.1-2) ×: Very poor 1
Score (Average: 0 to 1) As is clear from the results, it is clear that the lotion paper according to the present invention has extremely superior properties compared to simple laminated tissue paper.
以上詳述した如く本発明に係るローションペーパーは、
薄葉紙の表面に少なくともエモリエント剤を成分中に含
有する乳化溶液が、塗布されている部分と塗布されてい
ない部分とが５〜５０％＝９５〜５０％の面積比でほぼ
均一に分布しているから、ローションペーパーを皮膚に
接触させた際に必ず半分以上の面積を占める乳化溶液が
塗布されていない部分が接触して薄葉紙の本来所有して
いる優れた水分の吸収能により汗や皮膚に付着している
老廃物等を効果的に払拭することができ、また残りの半
分以下の乳化溶液が塗布されている部分において乳化溶
液中のエモリエント剤により皮膚面を滑らかにし且つ皮
膚水分の蒸発を防ぐ効果が発揮されるのであり、しかも
乳化溶液が塗布されている部分の面積割合が小さいので
塗布された乳化溶液が確実に乾燥されるので１ベタツキ
″感が残らないと共にゴワゴワして風合が悪いという欠
点がなく皮膚接触感覚にも優れた風合を有し、しかもト
イレットペーパーに応用した場合に水洗トイレに流すこ
とができるという効果を有しているのである。そして薄
葉紙が不織布か複数枚のテイツシュペーパーを積層した
ものである場合には、不織布の有するバルキー性や複数
枚のティッシュペーパーによる柔軟性及び嵩高性により
皮膚に接触させた際の風合をより良好ならしめることが
できるのである。As detailed above, the lotion paper according to the present invention is
The emulsifying solution containing at least an emollient as a component is distributed almost uniformly on the surface of the tissue paper with an area ratio of 5 to 50% = 95 to 50% between the coated area and the uncoated area. Therefore, when the lotion paper comes into contact with the skin, the area that is not coated with the emulsified solution, which occupies more than half of the surface area, comes into contact with the lotion paper, and due to the excellent moisture absorption ability of tissue paper, it adheres to sweat and the skin. The emollient agent in the emulsified solution smoothes the skin surface and prevents evaporation of skin moisture in the area where less than half of the remaining emulsified solution is applied. The effect is demonstrated, and since the area ratio of the area to which the emulsifying solution is applied is small, the applied emulsifying solution is reliably dried, so it does not leave a sticky feeling and has a stiff and bad texture. It has a texture with excellent skin contact sensation, and when applied to toilet paper, it has the effect of being able to be flushed down a flush toilet. When the tissue paper is laminated, the bulkiness of the nonwoven fabric and the flexibility and bulkiness of the multiple sheets of tissue paper can provide a better texture when it comes into contact with the skin. .
また本発明に係るローションペーパーの製造方法は、凸
部と凹部とが５〜５０％＝９５〜５０％の面積比でほぼ
均一に分布している印刷版の凸部に付着させた少なくと
もエモリエント剤を成分中に含有する乳化溶液を薄葉紙
の表面に塗布し乾燥する方法であり、薄葉紙の表面に塗
布するエモリエント剤を成分中に含有する組成物が乳化
溶液であるので薄葉紙の表面への塗布に特別の装置を必
要とせず、また薄葉紙の表面に乳化溶液が塗布されてい
る部分と塗布されていない部分とを所定の面積比となる
ようにほぼ均一に分布させるのを印刷版の凸部に乳化溶
液を付着させて行うことにより工業的に確実に実施する
ことができるのである。Further, the method for producing lotion paper according to the present invention includes at least an emollient agent attached to the convex portions of a printing plate in which the convex portions and concave portions are almost uniformly distributed with an area ratio of 5 to 50% = 95 to 50%. This is a method of applying an emulsifying solution containing an emollient as an ingredient to the surface of tissue paper and drying it. It does not require any special equipment, and it is possible to distribute the emulsifying solution almost uniformly on the surface of the thin paper so that the area where the emulsifying solution is applied and the area where it is not applied is a predetermined area ratio on the convex portion of the printing plate. By attaching an emulsified solution to the process, it can be carried out reliably on an industrial scale.
更に使用する乳化溶液に香料を加えることにより商品価
値を高めることも極めて容易に行うことができるのであ
る。Furthermore, it is extremely easy to increase the commercial value by adding fragrance to the emulsifying solution used.
このように種々の効果を有する本発明の産業上の効果は
極めて高いものである。The industrial effects of the present invention having various effects as described above are extremely high.
第１図及び第２図は薄葉紙の表面に乳化溶液が線状に塗
布されている例を示す説明図、第３図は薄葉紙の表面に
乳化溶液が円形状に乳化溶液が塗布されていない部分を
残すように乳化溶液が塗布されている例を示す説明図で
ある。
図面中
１・・・・薄葉紙
Ａ・・・・乳化溶液が塗布さ九でいる部分Ｂ・・・・乳
化溶液が塗布されていない部分特許出願人 山陽国策パ
ルプ株式会社
山陽スコツト株式会社
代理人 弁理士 野 間 忠 夫Figures 1 and 2 are explanatory diagrams showing an example where the emulsifying solution is applied linearly on the surface of the tissue paper, and Figure 3 is a circular part of the surface of the tissue paper where the emulsifying solution is not applied. FIG. 3 is an explanatory diagram showing an example in which an emulsifying solution is applied so as to leave a . In the drawing 1: Tissue paper A: Part where emulsifying solution is applied B: Part where emulsifying solution is not applied Patent applicant: Sanyo Kokusaku Pulp Co., Ltd. Sanyo Scotto Co., Ltd. Agent Patent attorney Tadao Shinoma
Claims (1)
中に含有する乳化溶液が塗布されている部分と塗布され
ていない部分とが５〜５０％：９５〜５０％の面積比で
ほぼ均一に分布していることを特徴とするローシヨンペ
ーパー。 ２ 薄葉紙が不織布である請求項１に記載のローシヨン
ペーパー。 ３ 薄葉紙が複数枚のテイツシユペーパーを積層したも
のである請求項１に記載のローシヨンペーパー。 ４ 凸部と凹部とが５〜５０％：９５〜５０％の面積比
でほぼ均一に分布している印刷版の凸部に付着させた少
なくともエモリエント剤を成分中に含有する乳化溶液を
薄葉紙の表面に塗布し乾燥することを特徴とするローシ
ヨンペーパーの製造方法。 ５ エモリエント剤を成分中に含有する乳化溶液として
、粘度が５００〜３，０００センチポアズのものを使用
する請求項４に記載のローシヨンペーパーの製造方法。 ６ 乳化溶液を薄葉紙の繊維固形分に対して乾燥固形分
として４〜２０％塗布する請求項４又は５に記載のロー
シヨンペーパーの製造方法。[Scope of Claims] 1. On the surface of the thin paper, the areas to which an emulsified solution containing at least an emollient agent is applied and the areas to which it is not applied are in an area ratio of 5 to 50%: 95 to 50%. A lotion paper characterized by almost uniform distribution. 2. The lotion paper according to claim 1, wherein the thin paper is a nonwoven fabric. 3. The lotion paper according to claim 1, wherein the thin paper is a stack of multiple sheets of tissue paper. 4 An emulsifying solution containing at least an emollient agent attached to the convex portions of a printing plate in which the convex portions and concave portions are almost uniformly distributed with an area ratio of 5 to 50%: 95 to 50% is applied to the thin paper. A method for producing lotion paper, which is characterized by applying it to the surface and drying it. 5. The method for producing lotion paper according to claim 4, wherein the emulsified solution containing the emollient as a component has a viscosity of 500 to 3,000 centipoise. 6. The method for manufacturing lotion paper according to claim 4 or 5, wherein the emulsified solution is applied in an amount of 4 to 20% as a dry solid content based on the fiber solid content of the thin paper.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2190424A JP2780059B2 (en) | 1990-04-18 | 1990-07-20 | Lotion paper and manufacturing method thereof |
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP10023090 | 1990-04-18 | ||
| JP2-100230 | 1990-04-18 | ||
| JP2190424A JP2780059B2 (en) | 1990-04-18 | 1990-07-20 | Lotion paper and manufacturing method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH049121A true JPH049121A (en) | 1992-01-13 |
| JP2780059B2 JP2780059B2 (en) | 1998-07-23 |
Family
ID=26441290
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2190424A Expired - Fee Related JP2780059B2 (en) | 1990-04-18 | 1990-07-20 | Lotion paper and manufacturing method thereof |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP2780059B2 (en) |
Cited By (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0919224A1 (en) * | 1997-10-20 | 1999-06-02 | Chemisch Adviesbureau Drs. J.C.P. Schreuder B.V. | Cleaning nose oil |
| EP1306073A2 (en) | 2001-10-24 | 2003-05-02 | Kawano Paper Co., Ltd. | Fibrous web product and method of manufacture thereof |
| US6860967B2 (en) | 2001-01-19 | 2005-03-01 | Sca Hygiene Products Gmbh | Tissue paper penetrated with softening lotion |
| US6905697B2 (en) | 2001-01-19 | 2005-06-14 | Sca Hygiene Products Gmbh | Lotioned fibrous web having a short water absorption time |
| JP2005530740A (en) * | 2002-04-26 | 2005-10-13 | ユニリーバー・ナームローゼ・ベンノートシヤープ | Body care products with identifiable active zones |
| JP2006149952A (en) * | 2004-12-01 | 2006-06-15 | Daio Paper Corp | Toilet paper coated with lotion and method for manufacturing toilet paper coated with lotion |
| JP2006517205A (en) * | 2003-01-08 | 2006-07-20 | ジョンソン・アンド・ジョンソン・ゲーエムベーハー | Products containing sheet material and wax dispersion |
| JP2006521410A (en) * | 2003-01-08 | 2006-09-21 | ジョンソン・アンド・ジョンソン・ゲーエムベーハー | Products containing applicators and wax dispersions |
| JP2007534853A (en) * | 2004-04-23 | 2007-11-29 | ザ プロクター アンド ギャンブル カンパニー | Fibrous structure comprising a surface treatment composition and a lotion composition |
| WO2012117842A1 (en) * | 2011-02-28 | 2012-09-07 | 大王製紙株式会社 | Toilet paper production method and toilet paper |
| JP2018050966A (en) * | 2016-09-29 | 2018-04-05 | 丸富製紙株式会社 | Method for forming pattern to sanitary tissue paper |
| US9956750B2 (en) | 2010-06-30 | 2018-05-01 | Daio Paper Corporation | Tissue paper and method of producing tissue paper |
| JP2019042520A (en) * | 2018-10-03 | 2019-03-22 | ユニ・チャーム株式会社 | Absorbent article |
| JP2019118709A (en) * | 2018-01-10 | 2019-07-22 | 王子ホールディングス株式会社 | Sanitary paper |
-
1990
- 1990-07-20 JP JP2190424A patent/JP2780059B2/en not_active Expired - Fee Related
Cited By (17)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0919224A1 (en) * | 1997-10-20 | 1999-06-02 | Chemisch Adviesbureau Drs. J.C.P. Schreuder B.V. | Cleaning nose oil |
| US6860967B2 (en) | 2001-01-19 | 2005-03-01 | Sca Hygiene Products Gmbh | Tissue paper penetrated with softening lotion |
| US6905697B2 (en) | 2001-01-19 | 2005-06-14 | Sca Hygiene Products Gmbh | Lotioned fibrous web having a short water absorption time |
| US8545861B2 (en) | 2001-01-19 | 2013-10-01 | Sca Hygiene Products Gmbh | Lotioned fibrous web having a short water absorption time |
| EP1306073A2 (en) | 2001-10-24 | 2003-05-02 | Kawano Paper Co., Ltd. | Fibrous web product and method of manufacture thereof |
| JP2005530740A (en) * | 2002-04-26 | 2005-10-13 | ユニリーバー・ナームローゼ・ベンノートシヤープ | Body care products with identifiable active zones |
| JP2006517205A (en) * | 2003-01-08 | 2006-07-20 | ジョンソン・アンド・ジョンソン・ゲーエムベーハー | Products containing sheet material and wax dispersion |
| JP2006521410A (en) * | 2003-01-08 | 2006-09-21 | ジョンソン・アンド・ジョンソン・ゲーエムベーハー | Products containing applicators and wax dispersions |
| JP2007534853A (en) * | 2004-04-23 | 2007-11-29 | ザ プロクター アンド ギャンブル カンパニー | Fibrous structure comprising a surface treatment composition and a lotion composition |
| JP2006149952A (en) * | 2004-12-01 | 2006-06-15 | Daio Paper Corp | Toilet paper coated with lotion and method for manufacturing toilet paper coated with lotion |
| US9956750B2 (en) | 2010-06-30 | 2018-05-01 | Daio Paper Corporation | Tissue paper and method of producing tissue paper |
| WO2012117842A1 (en) * | 2011-02-28 | 2012-09-07 | 大王製紙株式会社 | Toilet paper production method and toilet paper |
| JP2012179071A (en) * | 2011-02-28 | 2012-09-20 | Daio Paper Corp | Toilet paper production method, and toilet paper |
| US9668620B2 (en) | 2011-02-28 | 2017-06-06 | Daio Paper Corporation | Toilet paper production method and toilet paper |
| JP2018050966A (en) * | 2016-09-29 | 2018-04-05 | 丸富製紙株式会社 | Method for forming pattern to sanitary tissue paper |
| JP2019118709A (en) * | 2018-01-10 | 2019-07-22 | 王子ホールディングス株式会社 | Sanitary paper |
| JP2019042520A (en) * | 2018-10-03 | 2019-03-22 | ユニ・チャーム株式会社 | Absorbent article |
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| Publication number | Publication date |
|---|---|
| JP2780059B2 (en) | 1998-07-23 |
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