JPH0491200A - Cleanser composition - Google Patents
Cleanser compositionInfo
- Publication number
- JPH0491200A JPH0491200A JP20865890A JP20865890A JPH0491200A JP H0491200 A JPH0491200 A JP H0491200A JP 20865890 A JP20865890 A JP 20865890A JP 20865890 A JP20865890 A JP 20865890A JP H0491200 A JPH0491200 A JP H0491200A
- Authority
- JP
- Japan
- Prior art keywords
- cleaning
- alcohol
- polyethylene glycol
- glycol ester
- aliphatic
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 17
- 150000002148 esters Chemical class 0.000 claims abstract description 12
- 239000002202 Polyethylene glycol Substances 0.000 claims abstract description 10
- 229920001223 polyethylene glycol Polymers 0.000 claims abstract description 10
- 235000014113 dietary fatty acids Nutrition 0.000 claims abstract description 8
- 229930195729 fatty acid Natural products 0.000 claims abstract description 8
- 239000000194 fatty acid Substances 0.000 claims abstract description 8
- 150000004665 fatty acids Chemical class 0.000 claims abstract description 8
- 125000002947 alkylene group Chemical group 0.000 claims abstract description 6
- -1 aliphatic (un)saturated alcohol Chemical class 0.000 claims abstract description 5
- 125000001931 aliphatic group Chemical group 0.000 claims abstract description 5
- 239000004359 castor oil Substances 0.000 claims abstract description 5
- 235000019438 castor oil Nutrition 0.000 claims abstract description 5
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 claims abstract description 5
- ACIAHEMYLLBZOI-ZZXKWVIFSA-N Unsaturated alcohol Chemical compound CC\C(CO)=C/C ACIAHEMYLLBZOI-ZZXKWVIFSA-N 0.000 claims abstract description 4
- 238000004140 cleaning Methods 0.000 claims description 45
- 125000004432 carbon atom Chemical group C* 0.000 claims description 11
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 abstract description 6
- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 abstract description 6
- XXROGKLTLUQVRX-UHFFFAOYSA-N allyl alcohol Chemical compound OCC=C XXROGKLTLUQVRX-UHFFFAOYSA-N 0.000 abstract 2
- 238000013329 compounding Methods 0.000 abstract 1
- 230000001747 exhibiting effect Effects 0.000 abstract 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 11
- 235000019441 ethanol Nutrition 0.000 description 11
- 230000000694 effects Effects 0.000 description 10
- 230000004907 flux Effects 0.000 description 8
- 239000012459 cleaning agent Substances 0.000 description 7
- 230000007423 decrease Effects 0.000 description 6
- RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 description 5
- KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 description 5
- 239000003599 detergent Substances 0.000 description 5
- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 5
- AJDIZQLSFPQPEY-UHFFFAOYSA-N 1,1,2-Trichlorotrifluoroethane Chemical compound FC(F)(Cl)C(F)(Cl)Cl AJDIZQLSFPQPEY-UHFFFAOYSA-N 0.000 description 4
- 230000006866 deterioration Effects 0.000 description 4
- 239000003921 oil Substances 0.000 description 4
- 239000007921 spray Substances 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- 239000004215 Carbon black (E152) Substances 0.000 description 2
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 2
- 239000003513 alkali Substances 0.000 description 2
- POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical compound CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 description 2
- FUZZWVXGSFPDMH-UHFFFAOYSA-N hexanoic acid Chemical compound CCCCCC(O)=O FUZZWVXGSFPDMH-UHFFFAOYSA-N 0.000 description 2
- 229930195733 hydrocarbon Natural products 0.000 description 2
- 150000002430 hydrocarbons Chemical class 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 239000002736 nonionic surfactant Substances 0.000 description 2
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 239000000758 substrate Substances 0.000 description 2
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 1
- UOCLXMDMGBRAIB-UHFFFAOYSA-N 1,1,1-trichloroethane Chemical compound CC(Cl)(Cl)Cl UOCLXMDMGBRAIB-UHFFFAOYSA-N 0.000 description 1
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 description 1
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 239000005639 Lauric acid Substances 0.000 description 1
- 239000005642 Oleic acid Substances 0.000 description 1
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 description 1
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 description 1
- 235000021355 Stearic acid Nutrition 0.000 description 1
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000005886 esterification reaction Methods 0.000 description 1
- 238000005530 etching Methods 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- NBVXSUQYWXRMNV-UHFFFAOYSA-N fluoromethane Chemical compound FC NBVXSUQYWXRMNV-UHFFFAOYSA-N 0.000 description 1
- 239000002529 flux (metallurgy) Substances 0.000 description 1
- 238000007654 immersion Methods 0.000 description 1
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 1
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 1
- 230000000379 polymerizing effect Effects 0.000 description 1
- TVDSBUOJIPERQY-UHFFFAOYSA-N prop-2-yn-1-ol Chemical compound OCC#C TVDSBUOJIPERQY-UHFFFAOYSA-N 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 229910000679 solder Inorganic materials 0.000 description 1
- 238000002798 spectrophotometry method Methods 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 239000008117 stearic acid Substances 0.000 description 1
- 238000004506 ultrasonic cleaning Methods 0.000 description 1
Abstract
Description
本発明は、ロジン系フラックス洗浄用洗浄剤組成物に関
するものである。The present invention relates to a cleaning composition for cleaning rosin-based flux.
従来のロジン系フラックス洗浄用洗浄剤としては、例え
ばＣＦＣ−１１３に代表される通称フロン溶剤又は１，
１．ｌ−トリクロロエタンに代表される塩素系溶剤が主
として用いられていた。Conventional rosin-based flux cleaning agents include, for example, commonly known fluorocarbon solvents such as CFC-113, or 1,
1. Chlorinated solvents such as l-trichloroethane have been mainly used.
しかしながら、このような従来のＣＦＣ−１１３或いは
１，１．１−トリクロロエタンにあっては、オゾン層を
破壊する原因物質として厳しい使用削減を計らねばなら
ず、当該洗浄に用いる事か不可能となってきたため、代
替洗浄剤が広く要望されてきている。
代替洗浄には、オゾン破壊係数の少ない或いは無い代替
フロンや、アルコール或いは炭化水素油を主成分とする
水系洗浄剤又はアルカリを主成分とする水系洗浄剤が広
く提案されている。しかしながらこれら代替フロンｆｃ
、浄は、安全性・洗浄性・経済性の点において充分に満
足するレベルには到っておらず、アルコール（系）洗浄
は引火点の低い事より操業安全性に懸念が残り、炭化水
素油を主体とする水系洗浄又はアルカリを圧体とする水
系洗浄剤は被洗浄素材選択性すなわち被洗浄素材への影
響が懸念されるという問題点があった。However, as conventional CFC-113 or 1,1,1-trichloroethane is a substance that destroys the ozone layer, strict measures must be taken to reduce its use, making it impossible to use it for cleaning. As a result, there has been a wide demand for alternative cleaning agents. As alternative cleaning methods, alternative chlorofluorocarbons with low or no ozone depletion coefficients, water-based detergents containing alcohol or hydrocarbon oil as a main component, or aqueous detergents containing alkali as a main component have been widely proposed. However, these alternative CFC fc
However, alcohol cleaning has not reached a fully satisfactory level in terms of safety, cleaning efficiency, and economic efficiency, and concerns remain about operational safety due to the low flash point of alcohol (based) cleaning, and hydrocarbon cleaning Water-based cleaning agents mainly containing oil or aqueous cleaning agents containing alkali as a pressurizer have a problem in that there is concern about the selectivity of the material to be cleaned, that is, the influence on the material to be cleaned.
二の発明は、このような従来の問題点に着目してなされ
たものである。すなわち、−炭素数１〜４の脂肪族飽和
アルコール及び／又は炭素数１〜４の脂肪族不飽和アル
コールのアルキレンオキシド付加物を６０重量部〜９５
重量部と、ＨＬＢ８〜１２のヒマシ油ポリエチレングリ
コールエステル及び／又は炭素数６〜２２の高級脂肪酸
ポリエチレングリコールエステルを５重量部〜４０重量
部からなることを特徴とする洗浄剤組成物である。
（手段を構成する要件）
本発明の洗浄剤組成物は、アルコール成分（り下Ａ成分
という）と、エステル型非イオン界面活性剤（以下Ｂ成
分という）の混合物である。
Ａ成分として炭素数１〜４の脂肪族飽和アルコール及び
／又は炭素数１〜４の脂肪族不飽和アルコールのアルキ
レンオキシド付加物か使用される。炭素数１〜４の脂肪
族飽和アルコールには、メチルアルコール、エチルアル
コール、プロピルアルコール、ブチルアルコールが挙げ
られ、炭素Ｗ９１〜４の脂肪族不飽チロアルコールに１
寸、マリ；１アルコール、プロパルギルアルコール等が
挙げられる。
又、上記アルコールに付加合成するアルキレンオキンド
はエチレンオキシド、プロビレシオキンド、ブチレンオ
キシドか挙げられ、その付加モル数は１〜５モルが好ま
しい。そ２′１等アルキＬンオキシドは単独或いは併用
付加合成する事も何らさしつかえない。
Ａ成分の配合量としては組成物中６０〜９５重量部であ
り、６０重量部未満或は９５重量部を赳えるときは洗浄
液劣化時の洗浄性が劣る。
次にＢ成分はエステル型非イオン界面活性剤として、Ｈ
ＬＢ８〜１２のヒマシ油のポリエチレングリコールエス
テル及び／又はＨＬＢ８〜１２の炭素数６〜２２の高級
脂肪酸のポリエチレングリコールエステルが使用される
。
炭素数６〜２２の高級脂肪酸としては、カプロン酸、ラ
ウリン酸、ステアリン酸、オレイン酸等の単独或いは併
用した高級脂肪酸が挙げらねる。
ポリエチレングリコールエステルは、エチレシオキシド
３〜３０モルをヒマシ油及び／又は高級脂肪酸に付加さ
せて製造しても良いし、あるいはエチレンオキシドを先
に重合させ、その後エステル化反応させて製造しても良
い。
Ｂ成分の配合量は組成物中５〜４０重量部であり、５重
量部未満では劣化時洗浄性が劣り、又４ＯＮ量部を越え
たときは洗浄全般に劣る。又Ｂ成分のＨＬＢは８〜１２
である必要があり、ＨＬＢが８未満のときは全般に洗浄
性が劣り、特に劣化時洗浄性が大幅に低下し、又ＨＬＢ
が１２を越えるときは全ＦＩ９．に洗浄性か劣る。
本願発明洗浄剤組成物はそのまま或は水に希釈して、浸
漬、超音波、噴霧等の洗浄方式に基づき、ロジン系フラ
ックスの付着した基板の洗浄処理を行う。The second invention was made by focusing on such conventional problems. That is, - 60 parts by weight to 95 parts by weight of an alkylene oxide adduct of an aliphatic saturated alcohol having 1 to 4 carbon atoms and/or an aliphatic unsaturated alcohol having 1 to 4 carbon atoms;
and 5 parts by weight to 40 parts by weight of castor oil polyethylene glycol ester having an HLB of 8 to 12 and/or higher fatty acid polyethylene glycol ester having 6 to 22 carbon atoms. (Requirements constituting means) The cleaning composition of the present invention is a mixture of an alcohol component (hereinafter referred to as component A) and an ester type nonionic surfactant (hereinafter referred to as component B). As component A, an alkylene oxide adduct of an aliphatic saturated alcohol having 1 to 4 carbon atoms and/or an aliphatic unsaturated alcohol having 1 to 4 carbon atoms is used. Examples of aliphatic saturated alcohols having 1 to 4 carbon atoms include methyl alcohol, ethyl alcohol, propyl alcohol, and butyl alcohol;
Examples include alcohol, alcohol, propargyl alcohol, and the like. The alkylene oxide to be added and synthesized to the above-mentioned alcohol may be ethylene oxide, propylene oxide, or butylene oxide, and the number of moles added is preferably 1 to 5 moles. There is no problem in addition-synthesizing the 2'1-iso-alkylene oxides alone or in combination. The blending amount of component A is 60 to 95 parts by weight in the composition, and if it is less than 60 parts by weight or 95 parts by weight, the cleaning performance when the cleaning liquid deteriorates will be poor. Next, component B is an ester type nonionic surfactant, H
A polyethylene glycol ester of castor oil having an LB of 8 to 12 and/or a polyethylene glycol ester of a higher fatty acid having a carbon number of 6 to 22 and an HLB of 8 to 12 is used. Examples of higher fatty acids having 6 to 22 carbon atoms include higher fatty acids such as caproic acid, lauric acid, stearic acid, and oleic acid, which may be used alone or in combination. Polyethylene glycol ester may be produced by adding 3 to 30 moles of ethylene oxide to castor oil and/or higher fatty acids, or may be produced by first polymerizing ethylene oxide and then carrying out an esterification reaction. . The blending amount of component B is 5 to 40 parts by weight in the composition, and if it is less than 5 parts by weight, the cleaning performance during deterioration will be poor, and if it exceeds 4 parts by weight, the overall cleaning will be poor. Also, the HLB of component B is 8 to 12.
When the HLB is less than 8, the cleaning performance is generally poor, especially when it deteriorates, and the cleaning performance is significantly reduced.
When exceeds 12, the total FI9. Cleanability is poor. The cleaning composition of the present invention may be used as it is or diluted with water to perform a cleaning treatment on a substrate to which rosin-based flux has been adhered based on a cleaning method such as immersion, ultrasonic waves, or spraying.
本発明洗浄剤組成物は、ＣＦＣ−１１３或いは１、ｌ、
ｌ−トリクロロエタン等ロジン系フラックス洗浄用に用
いられる水溶性洗浄剤組成物でオゾン層破壊に原因する
物質を全く含有せず、アルコール系洗浄剤に比較し、高
い引火点を有し取扱いが容易であり且つ、優れた洗浄効
果と寿命を有し、水系洗浄剤に比較し取り扱いが安全且
つ優れた洗浄性と洗浄寿命を有し、更に水洗し易い事で
ファイン化の進む基板に付着するロジン系フラックスの
洗浄が容易となる。The cleaning composition of the present invention contains CFC-113 or 1,1,
A water-soluble detergent composition used for cleaning rosin-based fluxes such as l-trichloroethane, which does not contain any substances that cause ozone layer depletion, has a higher flash point than alcohol-based detergents, and is easy to handle. A rosin-based product that has superior cleaning effects and longevity, and is safer to handle and has superior cleaning performance and cleaning life compared to water-based cleaning agents.In addition, it is easy to wash with water and adheres to increasingly finer substrates. Cleaning of flux becomes easy.
効果 −１超１゛洗 ）
油性フラックス付着モデル基板を表−１の各々洗浄剤で
６０℃、６０秒間超音波洗浄、超音波リンスを行い、乾
燥後、残存フラックスを紫外分光光度法にて測定、以下
式により洗浄（％）を求めた。
洗浄性（％）
（但しＣＦＣ−１１３は３０℃洗浄とする。）効 例−
２（スプレー洗浄
効果例−１と同様条件にて超音波洗浄に替え、２ｋｇ／
ｃｍ２圧のスプレー洗浄を行う。評価法は効果例−１と
同様に洗浄性Ｃ％）−で示す。
表−１に示す各々洗浄剤組成物中に被洗浄油性フラック
スを２０％添加し劣化洗浄液とし、効果例−１と同様操
作を行い劣化洗浄液洗浄効果を測定する。
（以下余白）本発明洗浄剤組成物１〜３はいず
れの洗浄性についても優れた効果がある。一方比較洗浄
剤組成物について、
（イ＋ ［７１は超音波及びスプレー洗浄性能ル干の
低下と共に劣化洗浄性の大巾低下が観られる。
（ハ）は、Ａ成分のアルコールの炭素数が大きく、著し
い効果の低下が観られた。
（ニ）は、Ｂ成分のＨＬＢが低い為、特に劣化洗浄性に
劣る。
（本）は、Ｂ成分のＨＬＢが高い為、全Ｅｊに洗浄性低
下が伺える。
（へ）ｉｔ−）は、Ｂ成分の組成の違いの為、全般に洗
浄性が低下傾向にあり、特に、劣化洗浄性が低い。
（手）は、洗浄性は全般に優れるもののオゾン層破壊原
因物質である。
（ワ）は、引火点が低い事の懸念と共に、劣化時の性能
低下が大きい。
（ヌ）は、スプレー洗浄性能の低さと、劣化時の大巾性
能低下か問題である。
（１し）は、劣化時性能の低下と共にハンダ部分へのエ
ツチング影響が著しく実用的な洗浄に速さない。
【発明の効果ン
本発明洗浄剤組成物は、オゾン層を破壊する原因物質に
該当せず、安全かつ優れた洗浄性を特徴するEffect -1 super 1゛ cleaning) The oil-based flux attached model board was ultrasonically cleaned and rinsed at 60℃ for 60 seconds with each cleaning agent listed in Table-1, and after drying, the residual flux was measured by ultraviolet spectrophotometry. The cleaning (%) was determined using the following formula. Cleanability (%) (However, CFC-113 should be cleaned at 30°C.) Effectiveness example -
2 (Same conditions as spray cleaning effect example-1, instead of ultrasonic cleaning, 2 kg/
Perform spray cleaning at cm2 pressure. The evaluation method is shown in terms of detergency C%) as in Effect Example-1. 20% of the oil-based flux to be cleaned was added to each of the cleaning agent compositions shown in Table 1 to obtain a deteriorated cleaning liquid, and the same operation as in Effect Example 1 was carried out to measure the cleaning effect of the deteriorated cleaning liquid.
(Hereinafter, blank) Cleaning compositions 1 to 3 of the present invention have excellent effects on all cleaning properties. On the other hand, regarding the comparative detergent compositions, (I + [71] shows a decrease in ultrasonic and spray cleaning performance as well as a large decrease in deterioration and cleaning performance. (C) has a large number of carbon atoms in the alcohol of component A. , a significant decrease in effectiveness was observed. In (d), the HLB of the B component is low, so the deterioration and cleaning performance is particularly poor. In (this), the HLB of the B component is high, so there is a decrease in the cleaning performance for all Ej. Because of the difference in the composition of the B component, the cleaning performance of ()it-) generally tends to decrease, and in particular, the deterioration cleaning performance is low. (Hands) have excellent cleaning properties in general, but they are substances that cause ozone layer depletion. (W) is concerned about its low flash point, and there is a large drop in performance when it deteriorates. (N) is a problem of low spray cleaning performance and a decline in wide width performance when it deteriorates. In case (1), the performance deteriorates when it deteriorates, and the etching effect on the solder portion is significant, making it difficult to perform practical cleaning. [Effects of the Invention] The cleaning composition of the present invention does not fall under the category of substances that destroy the ozone layer, and is characterized by safe and excellent cleaning properties.
Claims (1)
数１〜４の脂肪族不飽和アルコールのアルキレンオキシ
ド付加物を６０重量部〜９５重量部と、ＨＬＢ８〜１２
のヒマシ油ポリエチレングリコールエステル及び／又は
炭素数６〜２２の高級脂肪酸ポリエチレングリコールエ
ステルを５重量部〜４０重量部からなることを特徴とす
る洗浄剤組成物。60 to 95 parts by weight of an alkylene oxide adduct of an aliphatic saturated alcohol having 1 to 4 carbon atoms and/or an aliphatic unsaturated alcohol having 1 to 4 carbon atoms, and HLB 8 to 12.
A cleaning composition comprising 5 to 40 parts by weight of castor oil polyethylene glycol ester and/or higher fatty acid polyethylene glycol ester having 6 to 22 carbon atoms.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2208658A JPH0668118B2 (en) | 1990-08-06 | 1990-08-06 | Cleaning composition |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2208658A JPH0668118B2 (en) | 1990-08-06 | 1990-08-06 | Cleaning composition |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH0491200A true JPH0491200A (en) | 1992-03-24 |
| JPH0668118B2 JPH0668118B2 (en) | 1994-08-31 |
Family
ID=16559904
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2208658A Expired - Lifetime JPH0668118B2 (en) | 1990-08-06 | 1990-08-06 | Cleaning composition |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH0668118B2 (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2009149903A (en) * | 2006-04-27 | 2009-07-09 | Intezyne Technologies Inc | Poly (ethylene glycol) containing chemically different terminal groups |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH01291905A (en) * | 1988-05-20 | 1989-11-24 | Chichibu Cement Co Ltd | Raw material blending system |
| JPH03227400A (en) * | 1989-11-08 | 1991-10-08 | Arakawa Chem Ind Co Ltd | Detergent for washing rosin-based soldering flux and washing method of same flux |
-
1990
- 1990-08-06 JP JP2208658A patent/JPH0668118B2/en not_active Expired - Lifetime
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH01291905A (en) * | 1988-05-20 | 1989-11-24 | Chichibu Cement Co Ltd | Raw material blending system |
| JPH03227400A (en) * | 1989-11-08 | 1991-10-08 | Arakawa Chem Ind Co Ltd | Detergent for washing rosin-based soldering flux and washing method of same flux |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2009149903A (en) * | 2006-04-27 | 2009-07-09 | Intezyne Technologies Inc | Poly (ethylene glycol) containing chemically different terminal groups |
| JP2011058001A (en) * | 2006-04-27 | 2011-03-24 | Intezyne Technologies Inc | Poly(ethylene glycol) containing chemically disparate end group |
Also Published As
| Publication number | Publication date |
|---|---|
| JPH0668118B2 (en) | 1994-08-31 |
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