JPH0489422A - Solid powder cosmetic - Google Patents
Solid powder cosmeticInfo
- Publication number
- JPH0489422A JPH0489422A JP20389890A JP20389890A JPH0489422A JP H0489422 A JPH0489422 A JP H0489422A JP 20389890 A JP20389890 A JP 20389890A JP 20389890 A JP20389890 A JP 20389890A JP H0489422 A JPH0489422 A JP H0489422A
- Authority
- JP
- Japan
- Prior art keywords
- cosmetic
- powder
- oil
- pigment
- meth
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000002537 cosmetic Substances 0.000 title claims abstract description 29
- 239000000843 powder Substances 0.000 title claims abstract description 26
- 239000007787 solid Substances 0.000 title claims abstract description 18
- 239000000049 pigment Substances 0.000 claims abstract description 12
- 229910052731 fluorine Inorganic materials 0.000 claims abstract description 7
- 229920000642 polymer Polymers 0.000 claims abstract description 7
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 claims abstract description 6
- 239000011737 fluorine Substances 0.000 claims abstract description 6
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 4
- 239000004615 ingredient Substances 0.000 claims description 3
- 125000000217 alkyl group Chemical group 0.000 abstract description 8
- 239000007788 liquid Substances 0.000 abstract description 8
- PRAKJMSDJKAYCZ-UHFFFAOYSA-N squalane Chemical compound CC(C)CCCC(C)CCCC(C)CCCCC(C)CCCC(C)CCCC(C)C PRAKJMSDJKAYCZ-UHFFFAOYSA-N 0.000 abstract description 8
- 229920001577 copolymer Polymers 0.000 abstract description 6
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 abstract description 5
- JXTPJDDICSTXJX-UHFFFAOYSA-N n-Triacontane Natural products CCCCCCCCCCCCCCCCCCCCCCCCCCCCCC JXTPJDDICSTXJX-UHFFFAOYSA-N 0.000 abstract description 4
- 229940032094 squalane Drugs 0.000 abstract description 4
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 abstract description 2
- 238000000034 method Methods 0.000 abstract description 2
- 239000000126 substance Substances 0.000 abstract 2
- 239000000463 material Substances 0.000 abstract 1
- 239000003921 oil Substances 0.000 description 22
- 235000019198 oils Nutrition 0.000 description 22
- -1 sericite Chemical compound 0.000 description 7
- 239000001993 wax Substances 0.000 description 6
- 150000001252 acrylic acid derivatives Chemical class 0.000 description 4
- 229910052799 carbon Inorganic materials 0.000 description 4
- 239000000945 filler Substances 0.000 description 4
- 229910052751 metal Inorganic materials 0.000 description 4
- 239000002184 metal Substances 0.000 description 4
- 239000010445 mica Substances 0.000 description 4
- 229910052618 mica group Inorganic materials 0.000 description 4
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 3
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 3
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 3
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 3
- 235000014113 dietary fatty acids Nutrition 0.000 description 3
- 238000005562 fading Methods 0.000 description 3
- 239000000194 fatty acid Substances 0.000 description 3
- 229930195729 fatty acid Natural products 0.000 description 3
- 239000003205 fragrance Substances 0.000 description 3
- 230000014759 maintenance of location Effects 0.000 description 3
- SNVLJLYUUXKWOJ-UHFFFAOYSA-N methylidenecarbene Chemical compound C=[C] SNVLJLYUUXKWOJ-UHFFFAOYSA-N 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 239000000454 talc Substances 0.000 description 3
- 235000012222 talc Nutrition 0.000 description 3
- 229910052623 talc Inorganic materials 0.000 description 3
- 239000010936 titanium Substances 0.000 description 3
- 229910052719 titanium Inorganic materials 0.000 description 3
- 239000005995 Aluminium silicate Substances 0.000 description 2
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 2
- 239000004698 Polyethylene Substances 0.000 description 2
- 150000001298 alcohols Chemical class 0.000 description 2
- 235000012211 aluminium silicate Nutrition 0.000 description 2
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 description 2
- 125000004432 carbon atom Chemical group C* 0.000 description 2
- 239000004359 castor oil Substances 0.000 description 2
- 235000019438 castor oil Nutrition 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 239000004205 dimethyl polysiloxane Substances 0.000 description 2
- 235000013870 dimethyl polysiloxane Nutrition 0.000 description 2
- NOPFSRXAKWQILS-UHFFFAOYSA-N docosan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCCCCCO NOPFSRXAKWQILS-UHFFFAOYSA-N 0.000 description 2
- 150000002148 esters Chemical class 0.000 description 2
- 150000004665 fatty acids Chemical class 0.000 description 2
- 239000003349 gelling agent Substances 0.000 description 2
- 230000004313 glare Effects 0.000 description 2
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 description 2
- BXWNKGSJHAJOGX-UHFFFAOYSA-N hexadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCO BXWNKGSJHAJOGX-UHFFFAOYSA-N 0.000 description 2
- 229940119170 jojoba wax Drugs 0.000 description 2
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 2
- 229940057995 liquid paraffin Drugs 0.000 description 2
- 238000000465 moulding Methods 0.000 description 2
- GLDOVTGHNKAZLK-UHFFFAOYSA-N octadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCO GLDOVTGHNKAZLK-UHFFFAOYSA-N 0.000 description 2
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 description 2
- 229920000573 polyethylene Polymers 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 239000000344 soap Substances 0.000 description 2
- 239000004094 surface-active agent Substances 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- 239000011787 zinc oxide Substances 0.000 description 2
- 235000014692 zinc oxide Nutrition 0.000 description 2
- OBETXYAYXDNJHR-SSDOTTSWSA-M (2r)-2-ethylhexanoate Chemical compound CCCC[C@@H](CC)C([O-])=O OBETXYAYXDNJHR-SSDOTTSWSA-M 0.000 description 1
- IIZPXYDJLKNOIY-JXPKJXOSSA-N 1-palmitoyl-2-arachidonoyl-sn-glycero-3-phosphocholine Chemical compound CCCCCCCCCCCCCCCC(=O)OC[C@H](COP([O-])(=O)OCC[N+](C)(C)C)OC(=O)CCC\C=C/C\C=C/C\C=C/C\C=C/CCCCC IIZPXYDJLKNOIY-JXPKJXOSSA-N 0.000 description 1
- DGSZGZSCHSQXFV-UHFFFAOYSA-N 2,3-bis(2-ethylhexanoyloxy)propyl 2-ethylhexanoate Chemical compound CCCCC(CC)C(=O)OCC(OC(=O)C(CC)CCCC)COC(=O)C(CC)CCCC DGSZGZSCHSQXFV-UHFFFAOYSA-N 0.000 description 1
- BGRXBNZMPMGLQI-UHFFFAOYSA-N 2-octyldodecyl tetradecanoate Chemical compound CCCCCCCCCCCCCC(=O)OCC(CCCCCCCC)CCCCCCCCCC BGRXBNZMPMGLQI-UHFFFAOYSA-N 0.000 description 1
- FJKROLUGYXJWQN-UHFFFAOYSA-N 4-hydroxybenzoic acid Chemical compound OC(=O)C1=CC=C(O)C=C1 FJKROLUGYXJWQN-UHFFFAOYSA-N 0.000 description 1
- 241001237961 Amanita rubescens Species 0.000 description 1
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- 102000008186 Collagen Human genes 0.000 description 1
- 108010035532 Collagen Proteins 0.000 description 1
- 239000004375 Dextrin Substances 0.000 description 1
- 229920001353 Dextrin Polymers 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- 239000004166 Lanolin Substances 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 1
- 239000004677 Nylon Substances 0.000 description 1
- 240000007594 Oryza sativa Species 0.000 description 1
- 235000007164 Oryza sativa Nutrition 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
- WGLPBDUCMAPZCE-UHFFFAOYSA-N Trioxochromium Chemical compound O=[Cr](=O)=O WGLPBDUCMAPZCE-UHFFFAOYSA-N 0.000 description 1
- 239000006096 absorbing agent Substances 0.000 description 1
- 238000010306 acid treatment Methods 0.000 description 1
- OBETXYAYXDNJHR-UHFFFAOYSA-N alpha-ethylcaproic acid Natural products CCCCC(CC)C(O)=O OBETXYAYXDNJHR-UHFFFAOYSA-N 0.000 description 1
- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- WMGSQTMJHBYJMQ-UHFFFAOYSA-N aluminum;magnesium;silicate Chemical compound [Mg+2].[Al+3].[O-][Si]([O-])([O-])[O-] WMGSQTMJHBYJMQ-UHFFFAOYSA-N 0.000 description 1
- 150000001413 amino acids Chemical class 0.000 description 1
- 239000002519 antifouling agent Substances 0.000 description 1
- 229910000410 antimony oxide Inorganic materials 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- IRERQBUNZFJFGC-UHFFFAOYSA-L azure blue Chemical compound [Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[S-]S[S-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-] IRERQBUNZFJFGC-UHFFFAOYSA-L 0.000 description 1
- POJOORKDYOPQLS-UHFFFAOYSA-L barium(2+) 5-chloro-2-[(2-hydroxynaphthalen-1-yl)diazenyl]-4-methylbenzenesulfonate Chemical compound [Ba+2].C1=C(Cl)C(C)=CC(N=NC=2C3=CC=CC=C3C=CC=2O)=C1S([O-])(=O)=O.C1=C(Cl)C(C)=CC(N=NC=2C3=CC=CC=C3C=CC=2O)=C1S([O-])(=O)=O POJOORKDYOPQLS-UHFFFAOYSA-L 0.000 description 1
- 235000013871 bee wax Nutrition 0.000 description 1
- 235000015278 beef Nutrition 0.000 description 1
- 239000012166 beeswax Substances 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 229910052796 boron Inorganic materials 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- 239000001506 calcium phosphate Substances 0.000 description 1
- 229910000389 calcium phosphate Inorganic materials 0.000 description 1
- 235000011010 calcium phosphates Nutrition 0.000 description 1
- 239000004204 candelilla wax Substances 0.000 description 1
- 235000013868 candelilla wax Nutrition 0.000 description 1
- 229940073532 candelilla wax Drugs 0.000 description 1
- 239000004203 carnauba wax Substances 0.000 description 1
- 235000013869 carnauba wax Nutrition 0.000 description 1
- 239000012185 ceresin wax Substances 0.000 description 1
- 229960000541 cetyl alcohol Drugs 0.000 description 1
- 229910000423 chromium oxide Inorganic materials 0.000 description 1
- VQWFNAGFNGABOH-UHFFFAOYSA-K chromium(iii) hydroxide Chemical compound [OH-].[OH-].[OH-].[Cr+3] VQWFNAGFNGABOH-UHFFFAOYSA-K 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 229910052570 clay Inorganic materials 0.000 description 1
- 229920001436 collagen Polymers 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 238000013329 compounding Methods 0.000 description 1
- 230000006835 compression Effects 0.000 description 1
- 238000007906 compression Methods 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 238000007334 copolymerization reaction Methods 0.000 description 1
- 125000004122 cyclic group Chemical group 0.000 description 1
- 235000019425 dextrin Nutrition 0.000 description 1
- PGZIKUPSQINGKT-UHFFFAOYSA-N dialuminum;dioxido(oxo)silane Chemical compound [Al+3].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O.[O-][Si]([O-])=O PGZIKUPSQINGKT-UHFFFAOYSA-N 0.000 description 1
- 229960000735 docosanol Drugs 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000010696 ester oil Substances 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 239000010419 fine particle Substances 0.000 description 1
- 125000003709 fluoroalkyl group Chemical group 0.000 description 1
- IUJAMGNYPWYUPM-UHFFFAOYSA-N hentriacontane Chemical compound CCCCCCCCCCCCCCCCCCCCCCCCCCCCCCC IUJAMGNYPWYUPM-UHFFFAOYSA-N 0.000 description 1
- 239000003906 humectant Substances 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- IGHXQFUXKMLEAW-UHFFFAOYSA-N iron(2+) oxygen(2-) Chemical compound [O-2].[Fe+2].[Fe+2].[O-2] IGHXQFUXKMLEAW-UHFFFAOYSA-N 0.000 description 1
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
- 235000019388 lanolin Nutrition 0.000 description 1
- 229940039717 lanolin Drugs 0.000 description 1
- 239000000787 lecithin Substances 0.000 description 1
- 229940067606 lecithin Drugs 0.000 description 1
- 235000010445 lecithin Nutrition 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- ZLNQQNXFFQJAID-UHFFFAOYSA-L magnesium carbonate Chemical compound [Mg+2].[O-]C([O-])=O ZLNQQNXFFQJAID-UHFFFAOYSA-L 0.000 description 1
- 239000001095 magnesium carbonate Substances 0.000 description 1
- 229910000021 magnesium carbonate Inorganic materials 0.000 description 1
- 239000000395 magnesium oxide Substances 0.000 description 1
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 1
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 239000004200 microcrystalline wax Substances 0.000 description 1
- 235000019808 microcrystalline wax Nutrition 0.000 description 1
- 239000011812 mixed powder Substances 0.000 description 1
- 229940105132 myristate Drugs 0.000 description 1
- GOQYKNQRPGWPLP-UHFFFAOYSA-N n-heptadecyl alcohol Natural products CCCCCCCCCCCCCCCCCO GOQYKNQRPGWPLP-UHFFFAOYSA-N 0.000 description 1
- 150000004767 nitrides Chemical class 0.000 description 1
- 229920001778 nylon Polymers 0.000 description 1
- 229940073665 octyldodecyl myristate Drugs 0.000 description 1
- BARWIPMJPCRCTP-UHFFFAOYSA-N oleic acid oleyl ester Natural products CCCCCCCCC=CCCCCCCCCOC(=O)CCCCCCCC=CCCCCCCCC BARWIPMJPCRCTP-UHFFFAOYSA-N 0.000 description 1
- BARWIPMJPCRCTP-CLFAGFIQSA-N oleyl oleate Chemical compound CCCCCCCC\C=C/CCCCCCCCOC(=O)CCCCCCC\C=C/CCCCCCCC BARWIPMJPCRCTP-CLFAGFIQSA-N 0.000 description 1
- 239000004006 olive oil Substances 0.000 description 1
- 235000008390 olive oil Nutrition 0.000 description 1
- VTRUBDSFZJNXHI-UHFFFAOYSA-N oxoantimony Chemical compound [Sb]=O VTRUBDSFZJNXHI-UHFFFAOYSA-N 0.000 description 1
- 239000012188 paraffin wax Substances 0.000 description 1
- 125000005010 perfluoroalkyl group Chemical group 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- 235000011007 phosphoric acid Nutrition 0.000 description 1
- 150000003016 phosphoric acids Chemical class 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 235000009566 rice Nutrition 0.000 description 1
- 239000000741 silica gel Substances 0.000 description 1
- 229910002027 silica gel Inorganic materials 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 229920002545 silicone oil Polymers 0.000 description 1
- 235000002316 solid fats Nutrition 0.000 description 1
- 229940012831 stearyl alcohol Drugs 0.000 description 1
- 150000005846 sugar alcohols Polymers 0.000 description 1
- 239000003760 tallow Substances 0.000 description 1
- TUNFSRHWOTWDNC-UHFFFAOYSA-N tetradecanoic acid Chemical compound CCCCCCCCCCCCCC(O)=O TUNFSRHWOTWDNC-UHFFFAOYSA-N 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- QORWJWZARLRLPR-UHFFFAOYSA-H tricalcium bis(phosphate) Chemical compound [Ca+2].[Ca+2].[Ca+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O QORWJWZARLRLPR-UHFFFAOYSA-H 0.000 description 1
- 229940099259 vaseline Drugs 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Landscapes
- Cosmetics (AREA)
Abstract
Description
【発明の詳細な説明】
〔産業上の利用分野〕
本発明は、顔料を主成分とし、これを少量の液体油で固
形化した固形粉末化粧料に関する。DETAILED DESCRIPTION OF THE INVENTION [Industrial Application Field] The present invention relates to a solid powder cosmetic containing a pigment as a main component and solidified with a small amount of liquid oil.
〔従来の技術及び発明が解決しようとする課題〕粉末を
主成分として固形油及び／又は液体油を含む油分を含有
し、中皿等の容器にプレス成形又は流し込み成形によっ
て充填されてなる主にメークアップ用に使用される化粧
料は、一般に固形粉末化粧料と称される。[Prior art and problems to be solved by the invention] Mainly powder-based oil containing solid oil and/or liquid oil, which is filled into a container such as a medium plate by press molding or pour molding. Cosmetics used for make-up are generally referred to as solid powder cosmetics.
このような固形粉末化粧料には、通常粉っぽさを防止し
、しっとりした感触を得る目的で固体脂（固形油）と液
体油を併せて２５％位までの油分が配合されている。Such solid powder cosmetics usually contain up to about 25% oil content, including solid fats (solid oils) and liquid oils, in order to prevent powderiness and provide a moist feel.
しかしながら、これらの化粧料において、液体油をバイ
ンダーとし、油剤を多量に用いると、ケーキング現象を
生じたり、肌につけたときにギラついてしまい、また少
量にすると、充填物の強度が弱く、耐衝撃性に劣り、肌
への密着性も良くないという問題があった。However, in these cosmetics, if liquid oil is used as a binder and a large amount of oil is used, it may cause a caking phenomenon or cause glare when applied to the skin, and if a small amount is used, the strength of the filler will be weak and impact resistance There were problems in that it was inferior in quality and did not adhere well to the skin.
従って、充填物の強度が高く、耐衝撃性に優れ、しかも
肌への密着性が良好でギラつかない固形粉体化粧料が望
まれていた。Therefore, there has been a demand for solid powder cosmetics with high filler strength, excellent impact resistance, good adhesion to the skin, and no glare.
かかる実情において、本発明者らは鋭意研究を行なった
結果、化粧品用顔料、化粧品用油剤及びワックス状フッ
素含有ポリマーを組合わせて用いれば、皮膚への密着性
に優れ、撥油性が向上して化粧もちが良く、しかも充填
物の強度が増し、耐衝撃性にも優れた固形粉末化粧料が
得られることを見出し、本発明を完成した。Under these circumstances, the inventors of the present invention have conducted intensive research and found that if a cosmetic pigment, a cosmetic oil, and a wax-like fluorine-containing polymer are used in combination, it has excellent adhesion to the skin and improves oil repellency. The present invention was completed based on the discovery that it is possible to obtain a solid powder cosmetic that has good makeup retention, increased filler strength, and excellent impact resistance.
すなわち、本発明は、次の成分（Ａ）、（Ｂ）及び（Ｃ
）（Ａ）化粧品用顔料 ７０〜９４．９重
量％（Ｂ）化粧品用油剤 ５〜２５ 重
量％（Ｃ）ワックス状フッ素含有ポリマー
０．１〜５ 重量％
を含有することを特徴とする固形粉末化粧料を提供する
ものである。That is, the present invention comprises the following components (A), (B) and (C).
) (A) Cosmetic pigment 70-94.9% by weight (B) Cosmetic oil agent 5-25% by weight (C) Waxy fluorine-containing polymer 0.1-5% by weight Solid powder characterized by containing It provides cosmetics.
本発明に用いられるい）成分の化粧品顔料としては、従
来より化粧料用粉体として用いられている粉体が使用で
き、例えば酸化チタン、酸化亜鉛（亜鉛華）、酸化鉄、
群青、セリサイト、シリカアルミナ、シリカゲル、カオ
リン、タルク、マイカ、クレー、ナイロンパウダー、雲
母チタン、酸化マグネシウム、酸化クロム、酸化アンチ
モン、炭酸マグネシウム、炭酸カルシウム、燐酸カルシ
ウム、硫酸バリウム、水酸化アルミニウム、窒化ホウ素
、水酸化クロム、メタケイ酸アルミン酸マグネシウム、
ケイ酸アルミン酸マグネシウム、ポリエチレン粉体、赤
色２０２号、赤色２０４号、赤色２２６号、オレンジ２
０１号、青色４０４号、黄色４０１号等の顔料を挙げる
ことができる。またこれらの顔料は微粒子にしたものを
用いてもよく、これらの顔料の２種以上をメカノケミカ
ル的手段を用いて複合化した粉体を用いることもできる
。さらに上述の粉体の表面を金属石鹸処理、シリコン処
理、ジアルキルリン酸処理、パーフルオロ基含有化合物
による処理、アミノ酸処理、レシチン処理、コラーゲン
処理等で処理したものを使用してもよい。As the cosmetic pigment of component (i) used in the present invention, powders conventionally used as powders for cosmetics can be used, such as titanium oxide, zinc oxide (zinc white), iron oxide,
Ultramarine, sericite, silica alumina, silica gel, kaolin, talc, mica, clay, nylon powder, mica titanium, magnesium oxide, chromium oxide, antimony oxide, magnesium carbonate, calcium carbonate, calcium phosphate, barium sulfate, aluminum hydroxide, nitride Boron, chromium hydroxide, magnesium aluminate metasilicate,
Magnesium aluminate silicate, polyethylene powder, Red No. 202, Red No. 204, Red No. 226, Orange 2
Examples include pigments such as No. 01, Blue No. 404, and Yellow No. 401. Further, these pigments may be used in the form of fine particles, or a powder obtained by compounding two or more of these pigments using mechanochemical means may also be used. Furthermore, the surface of the above-mentioned powder may be treated with metal soap treatment, silicon treatment, dialkyl phosphate treatment, treatment with a perfluoro group-containing compound, amino acid treatment, lecithin treatment, collagen treatment, or the like.
これらの化粧品粉体は、１種又は２種以上を組合わせて
用いることができ、全組成中に７０〜９４．９重量％（
以下、単に「％」で示す）、好ましくは８０〜９２％配
合される。These cosmetic powders can be used alone or in combination of two or more, and account for 70 to 94.9% by weight (
(hereinafter simply expressed as "%"), preferably 80 to 92%.
（Ｂ）成分の化粧品用油剤としては、液体油を主体とす
るのが好ましく、液体油のみでも良いが、さらにワック
ス又はゲル化剤を適宜添加することができる。かかる液
体油としては、例えば流動パラフィン、スクワラン、低
沸点イソパラフィン等の炭化水素油；オリーブ油、ヒマ
シ油、２−エチルヘキサン酸トリグリセリド、２−エチ
ルヘキサン酸ジグリセリド等のトリまたはジグリセリド
油；ホホバ油、イソプロピルミリステート、オレイルオ
レート等の脂肪酸と一価アルコールとのエステル油；ジ
メチルポリシロキサン、メチルフェニルポリシロキサン
、環状シリコーン等のシリコーン油等が挙げられる。ま
た、半固型を呈するラノリン、ワセリン等を使用するこ
ともできる。It is preferable that the cosmetic oil agent (B) is mainly composed of liquid oil, and liquid oil alone may be used, but a wax or a gelling agent may be added as appropriate. Such liquid oils include, for example, hydrocarbon oils such as liquid paraffin, squalane, and low-boiling isoparaffins; tri- or diglyceride oils such as olive oil, castor oil, 2-ethylhexanoic acid triglyceride, and 2-ethylhexanoic acid diglyceride; jojoba oil, isopropyl Examples include ester oils of fatty acids and monohydric alcohols such as myristate and oleyl oleate; silicone oils such as dimethylpolysiloxane, methylphenylpolysiloxane, and cyclic silicones. Further, semi-solid lanolin, vaseline, etc. can also be used.
ワックスとしては、常温（２５℃）で固型で、通常４０
℃以上で溶融する油であり、代表的な例としてカルナウ
バワックス、キャンデリラワックス、ライスワックス、
モクロウ、ミツロウ、セレシンワックス、ミクロクリス
タリンワックス、パラフィンワックス、硬化牛脂、硬化
ヒマシ油、硬化ホホバ油、ポリエチレンワックス等が挙
げられる。As a wax, it is solid at room temperature (25℃) and usually has a
It is an oil that melts at temperatures above ℃, and typical examples include carnauba wax, candelilla wax, rice wax,
Examples include Japanese wax wax, beeswax, ceresin wax, microcrystalline wax, paraffin wax, hardened beef tallow, hardened castor oil, hardened jojoba oil, and polyethylene wax.
一方、油ゲル化剤とは油溶性の界面活性剤であり、代表
的な例として脂肪酸の多価金属塩（金属石鹸）、ジアル
キルリン酸の多価金属塩、デキストリン脂肪酸エステル
等が挙げられる。On the other hand, the oil gelling agent is an oil-soluble surfactant, and typical examples include polyvalent metal salts of fatty acids (metal soaps), polyvalent metal salts of dialkyl phosphoric acids, and dextrin fatty acid esters.
これら化粧品用油剤は１種又は２種以上を組合わせて用
いることができ、全組成中に５〜２５％、好ましくは８
〜２０％配合される。These cosmetic oils can be used alone or in combination, and should be present in an amount of 5 to 25%, preferably 8% in the total composition.
~20% is blended.
（Ｃ）成分のワックス状フッ素含有ポリマーとしては、
長鎖アルキル（メタ）アクリレートとフッ化アルキル基
を結合している（メタ）アクリレートとの共重合体が好
ましい。かかる共重合体としては、例えば炭素数１６〜
２２のアルキル基を有する（メタ）アクリレートと、炭
素数４以上のパーフルオロアルキル基又はポリフルオロ
アルキル基を有する（メタ）アクリレートの共重合体が
挙げられる。炭素数１６〜２２のアルキル基を有するア
ルキル（メタ）アクリレートとしては、例えばセチルア
ルコール、ステアリルアルコール、ベヘニルアルコール
等のアルコールと（メタ）アクリル酸トのエステルが挙
げられ、また、パーフルオロアルキル基又はポリフルオ
ロアルキル基を有する（メタ）アクリレートとしては、
例えば以下の化合物が挙げられる。As the waxy fluorine-containing polymer as component (C),
A copolymer of a long-chain alkyl (meth)acrylate and a (meth)acrylate to which a fluorinated alkyl group is bonded is preferred. Such a copolymer has, for example, a carbon number of 16 to
Examples include copolymers of (meth)acrylates having 22 alkyl groups and (meth)acrylates having perfluoroalkyl groups or polyfluoroalkyl groups having 4 or more carbon atoms. Examples of alkyl (meth)acrylates having an alkyl group having 16 to 22 carbon atoms include esters of alcohols such as cetyl alcohol, stearyl alcohol, and behenyl alcohol and (meth)acrylic acid; As the (meth)acrylate having a fluoroalkyl group,
Examples include the following compounds.
ＣＨｚ＝ＣＨＣＤＯＣＪ４ＣｓＦ＋３． ’ＣＨｓ＝Ｃ
）ＩＣＤＯＣＪ−Ｃ−Ｆ＋７゜［”）Ｉ２”ＣＨＣＯＤ
ＣＪ４Ｃ＋。ＦＢＩ、 Ｃ）ｌｚ＝ｃＨｃＯＯｃＪ−Ｃ
＋２Ｆｚｓ。CHz=CHCDOCJ4CsF+3. 'CHs=C
)ICDOCJ-C-F+7゜[”)I2”CHCOD
CJ4C+. FBI, C)lz=cHcOOcJ-C
+2Fzs.
ＣＨ２＝Ｃ（ＣＨ３） ＣＤ０Ｃ２）１−Ｃ６Ｐ １−
。CH2=C(CH3) CD0C2)1-C6P 1-
.
［：Ｈ，＝Ｃ（ＣＨ３）Ｃ００Ｃ２）１．Ｃ，Ｆ、ｔ。[:H,=C(CH3)C00C2)1. C, F, t.
ＣＨ，＝Ｃ（Ｃ１１３）ＣＯＯＣ，Ｈ，Ｃ，ＯＦ２．。CH,=C(C113)COOC,H,C,OF2. .
ＣＨ，＝Ｃ（ＣＨ３）Ｃ００Ｃ，Ｈ，Ｃ，２Ｆ２Ｓ。CH,=C(CH3)C00C,H,C,2F2S.
ＣＨ２＝ＣＨＣ００Ｃ２Ｈ，−（ＣＦ２） 、−Ｈ。CH2=CHC00C2H, -(CF2), -H.
ＣＨ２＝ＣＨＣ００ＣａＨ−−（ＣＦ２） ｓ Ｈ。CH2=CHC00CaH--(CF2)sH.
ＣＨ２＝Ｃ（ＣＨ３） Ｃ００Ｃ２Ｈ４−（ＣＦ２）
４−Ｈ。CH2=C(CH3) C00C2H4-(CF2)
4-H.
ＣＨ２＝Ｃ（ＣＨ３） Ｃ００Ｃ，Ｈ，−（ＣＦ２）
５−Ｈこれらの長鎖アルキル（メタ）アクリレートとフ
ッ化アルキル基を結合している（メタ）アクリレートと
の共重合比は、溶解性、分散性及びペタツキ感などの点
から１０＝１〜１：５ （重量比）、特に７：１〜１：
１が好ましい。また、この共重合体の分子量は、耐摩擦
性、ペタツキ感などの点から１．０００〜２．０００．
０００ 、特に１０．０００〜５００．０００が好まし
い。CH2=C(CH3) C00C,H,-(CF2)
5-H The copolymerization ratio of these long-chain alkyl (meth)acrylates and the (meth)acrylate bonding a fluorinated alkyl group is 10 = 1 to 1 from the viewpoint of solubility, dispersibility, and sticky feeling. :5 (weight ratio), especially 7:1 to 1:
1 is preferred. In addition, the molecular weight of this copolymer is 1.000 to 2.000.
000, especially 10.000 to 500.000.
これらの共重合体は、例えば特開昭６１−２８９００９
号に記載の方法に従って製造することができる。These copolymers are disclosed in, for example, JP-A No. 61-289009.
It can be manufactured according to the method described in No.
（Ｃ）成分のワックス状フッ素含有ポリマーは、１種又
は２種以上を組合わせて用いることができ、全組成中に
０．１〜５％、好ましくは０．５〜３，０％配合される
。The waxy fluorine-containing polymer as component (C) can be used alone or in combination of two or more, and is blended in an amount of 0.1 to 5%, preferably 0.5 to 3.0% in the total composition. Ru.
また、本発明の固形粉末化粧料には、前記必須成分のほ
か、通常の化粧料に用いられる成分、例えば界面活性剤
、酸化防止剤、香料、色素、アルコール、多価アルコー
ル、防汚剤、紫外線吸収剤、保湿剤、水等を適宜配合す
ることができる。In addition to the above-mentioned essential ingredients, the solid powder cosmetic of the present invention also includes ingredients used in ordinary cosmetics, such as surfactants, antioxidants, fragrances, pigments, alcohol, polyhydric alcohols, antifouling agents, Ultraviolet absorbers, humectants, water, etc. can be added as appropriate.
本発明の固形粉末化粧料は、常法に従って製造すること
ができ、フェイスパウダー、ボディーパウダー、パウダ
ーファンデーション、頬紅、アイシャドウなどとして適
用することができる。The solid powder cosmetic of the present invention can be manufactured according to conventional methods, and can be applied as face powder, body powder, powder foundation, blusher, eye shadow, and the like.
本発明の固形粉末化粧料は、充填物の強度が高く、耐衝
撃性に優れ、また肌への密着性が良好で、しかも撥油性
が向上し、化粧もちが良い優れたものである。The solid powder cosmetic of the present invention has high filler strength, excellent impact resistance, good adhesion to the skin, improved oil repellency, and good makeup retention.
次に、実施例を挙げ、本発明を更に詳細に説明する。 Next, the present invention will be explained in more detail by giving examples.
実施例１ アイシャドウ：
第１表に示す組成のアイシャドウを製造し、落下試験及
び春闘パネラ−による化粧もちについて評価した。Example 1 Eyeshadow: Eyeshadows having the compositions shown in Table 1 were manufactured and evaluated for makeup durability by a drop test and Shunto Panel.
（製 法）
成分（１）〜（７）をヘンシェルミキサー等で均一に混
合する。成分（８）〜（社）を６０〜７０℃に加温して
溶解し、成分（１）〜（７）の均一混合粉体を加え、ヘ
ンシェルミキサーで混合したのち、粉砕機により粉砕混
合し、合冊に圧縮成型する。(Production method) Components (1) to (7) are mixed uniformly using a Henschel mixer or the like. Components (8) to (Company) are heated to 60 to 70°C and dissolved, a uniform mixed powder of components (1) to (7) is added, mixed in a Henschel mixer, and then pulverized and mixed in a pulverizer. , compression molded into a combined volume.
第
表
以下余白
＊：特開昭６１−２８９００９号の参考例１で得られる
もの
（評 価）
落下試験：
５０ｃｍの高さからアイシャドウを落下させ、アイシャ
ドウの割れるまでの回数を調べた。結果を第２表に示す
。Margins below the table*: Obtained from Reference Example 1 of JP-A No. 61-289009 (Evaluation) Drop test: Eye shadow was dropped from a height of 50 cm, and the number of times it took for the eye shadow to break was determined. The results are shown in Table 2.
第２表
第２表から明らかなように、本発明のアイシャドウは、
耐衝撃性に優れたものであった。Table 2 As is clear from Table 2, the eye shadow of the present invention is
It had excellent impact resistance.
化粧もち：
２０名の専門パネラ−により、本発明品及び比較品を塗
布したときの、経時で６色くすみ、色うすれ及び色うつ
つを比較評価した。結果を第３表に示す。Makeup retention: A panel of 20 experts compared and evaluated the dullness, fading, and fading of six colors over time when the products of the present invention and comparative products were applied. The results are shown in Table 3.
以下余白
第３表から明らかなように、本発明のアイシャドウは、
経時での色くすみ、色うすれ及び色うつりが少なく、化
粧もちが良いものであった。As is clear from Table 3 below, the eyeshadow of the present invention is
There was little color dullness, color fading, or color transfer over time, and the makeup lasted well.
実施例２ 固型はぼ紅：
タルク
マイカ
雲母チタン
疎水化処理赤色２２６号
疎水化処理赤色２０２号
流動パラフィン
スクワラン
（％）
６２．８
１０．０
２０、０
１．０
０．５
２．０
３．０
（９）パラベン ０．１
αＱ 香 料
０．１＊：特開昭６１−２８９００９号の参考例１で
得られるもの
実施例３
固型ファンデーション：
セリサイト
カオリン
二酸化チタン
タルク
ベンガラ
黄酸化鉄
雲母チタン
ジメチルポリシロキサン
（％）
２７．７
１５．０
１０．０
３０．０
０．８
０．５
５．０
４．０
ミリスチン酸オクチルドデシル
スクワラン
パラオキシ安息香酸エステル
香 料
富：特開昭６１−２８９００９号の参考例もの
本本：特開昭６１−２８９００９号の参考例５で得られ
る
ものExample 2 Solid pink: Talcum mica titanium hydrophobized red No. 226 Hydrophobized red No. 202 Liquid paraffin squalane (%) 62.8 10.0 20, 0 1.0 0.5 2.0 3. 0 (9) Paraben 0.1
αQ fragrance
0.1*: Obtained in Reference Example 1 of JP-A No. 61-289009 Example 3 Solid foundation: Sericite kaolin Titanium dioxide Talcum Red iron oxide Iron mica Titanium dimethylpolysiloxane (%) 27.7 15. 0 10.0 30.0 0.8 0.5 5.0 4.0 Octyldodecyl myristate squalane paraoxybenzoate ester fragrance Reference example of JP-A-61-289009 This book: JP-A-61-289009 What is obtained in Reference Example 5 of No. 289009
Claims (1)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP20389890A JPH0489422A (en) | 1990-08-02 | 1990-08-02 | Solid powder cosmetic |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP20389890A JPH0489422A (en) | 1990-08-02 | 1990-08-02 | Solid powder cosmetic |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH0489422A true JPH0489422A (en) | 1992-03-23 |
Family
ID=16481544
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP20389890A Pending JPH0489422A (en) | 1990-08-02 | 1990-08-02 | Solid powder cosmetic |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH0489422A (en) |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH06183946A (en) * | 1992-12-21 | 1994-07-05 | Kao Corp | Cutaneous agent for external application |
| EP0609132A1 (en) * | 1993-01-25 | 1994-08-03 | L'oreal | Anhydrous solid dispersion containing organofluorinated hydrocarbons and its use in cosmetic |
| JPH1045535A (en) * | 1996-07-30 | 1998-02-17 | Kao Corp | Production of solid powder cosmetic |
| JPH11322543A (en) * | 1998-05-08 | 1999-11-24 | Kao Corp | Cosmetic |
| JP2002370932A (en) * | 2001-06-12 | 2002-12-24 | Kao Corp | Solid powder cosmetic |
| JP2009242260A (en) * | 2008-03-28 | 2009-10-22 | Shiseido Co Ltd | Solid powder cosmetic and manufacturing process thereof |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS61289009A (en) * | 1985-06-14 | 1986-12-19 | Kao Corp | Cosmetic |
-
1990
- 1990-08-02 JP JP20389890A patent/JPH0489422A/en active Pending
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS61289009A (en) * | 1985-06-14 | 1986-12-19 | Kao Corp | Cosmetic |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH06183946A (en) * | 1992-12-21 | 1994-07-05 | Kao Corp | Cutaneous agent for external application |
| EP0609132A1 (en) * | 1993-01-25 | 1994-08-03 | L'oreal | Anhydrous solid dispersion containing organofluorinated hydrocarbons and its use in cosmetic |
| JPH1045535A (en) * | 1996-07-30 | 1998-02-17 | Kao Corp | Production of solid powder cosmetic |
| JPH11322543A (en) * | 1998-05-08 | 1999-11-24 | Kao Corp | Cosmetic |
| JP2002370932A (en) * | 2001-06-12 | 2002-12-24 | Kao Corp | Solid powder cosmetic |
| JP2009242260A (en) * | 2008-03-28 | 2009-10-22 | Shiseido Co Ltd | Solid powder cosmetic and manufacturing process thereof |
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