JP2672908B2 - Powder cosmetics - Google Patents
Powder cosmeticsInfo
- Publication number
- JP2672908B2 JP2672908B2 JP22044591A JP22044591A JP2672908B2 JP 2672908 B2 JP2672908 B2 JP 2672908B2 JP 22044591 A JP22044591 A JP 22044591A JP 22044591 A JP22044591 A JP 22044591A JP 2672908 B2 JP2672908 B2 JP 2672908B2
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- Japan
- Prior art keywords
- powder
- repellent
- oil
- water
- weight
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Description
【０００１】[0001]
【産業上の利用分野】本発明は、撥水性・撥油性板状粉
体及び単分散微小球状粉体を含有する粉体化粧料、更に
詳しくは、撥水性・撥油性に優れ、化粧崩れがなく、き
しみ感及びざらつき感がなく、肌への優れた密着性と延
展性を両立させた粉体化粧料に関する。FIELD OF THE INVENTION The present invention relates to a powder cosmetic containing a water-repellent / oil-repellent plate-like powder and a monodisperse fine spherical powder, and more specifically, it has excellent water-repellency / oil repellency and does not cause makeup collapse. The present invention relates to a powder cosmetic having both excellent adhesion to the skin and spreadability without causing a squeaky feeling and a rough feeling.
【０００２】[0002]
【従来の技術及び発明が解決しようとする課題】粉体を
含有する化粧料としては、ファンデーション、白粉、ほ
ほ紅、アイシャドー、アイブロー等のメイクアップ化粧
品、ボディーパウダー、ベビーパウダー等のボディー化
粧品等が市販されている。これらの化粧料用粉体を含有
する化粧料においては、肌上での伸び及び付着性の良
さ、平滑感及び化粧崩れ、中でも皮脂崩れなどの化粧性
能が、問題とされる。BACKGROUND OF THE INVENTION Cosmetics containing powder include makeup cosmetics such as foundation, white powder, blusher, eye shadow and eyebrow, body cosmetics such as body powder and baby powder. Is commercially available. In cosmetics containing these powders for cosmetics, the elongation and adhesion on the skin, smoothness, and makeup breakage, and especially cosmetic performance such as sebum breakdown are problems.
【０００３】これに対して近年、皮脂による化粧崩れを
防止する目的で、フッ素化合物で粉体を処理して、撥水
性・撥油性を付与することが提案されている（特開昭55
-167209 号、特開昭62-250074 号、特開平1-180811号、
米国特許第3632744 号等）。しかし、これらの撥水性・
撥油性粉体は使用感触の面で平滑性が、フッ素化合物で
処理する前に比べて極端に悪くなるという欠点を有して
いる。On the other hand, in recent years, it has been proposed to treat the powder with a fluorine compound to impart water repellency and oil repellency for the purpose of preventing makeup breakdown due to sebum (JP-A-55).
-167209, JP 62-250074, JP 1-180811,
U.S. Pat. No. 3632744). However, these water repellency
The oil-repellent powder has a drawback in that the smoothness in use feels extremely worse than that before the treatment with the fluorine compound.
【０００４】従って、本発明の目的は、撥水性・撥油性
に優れ、汗、皮脂に対する化粧崩れがなく、同時に粉体
の基本的性能である肌上での伸び及び付着性の良さ、平
滑感等を満足する粉体化粧料を提供することにある。Therefore, the object of the present invention is to have excellent water and oil repellency, to prevent makeup deterioration against sweat and sebum, and at the same time to have a basic performance of powder such as good spreadability and adhesion on the skin, and smooth feeling. It is to provide a powder cosmetic that satisfies the above requirements.
【０００５】[0005]
【問題点を解決するための手段】本発明者らは、上記目
的を達成すべく鋭意検討した結果、予め板状粉体を特定
の化合物で表面処理を行って得られる撥水性・撥油性板
状粉体と、特定の平均粒径の単分散微小球状粉体を併用
することにより、耐水性、耐皮脂性及び耐油性が極めて
良好で且つ皮脂または油分によって化粧成分が消失しに
くく、使用感触、特に平滑性及び密着性の優れた粉体化
粧料が得られることを知見した。[Means for Solving the Problems] As a result of intensive studies aimed at achieving the above object, the present inventors have made a water-repellent / oil-repellent plate obtained by subjecting plate-like powder to a surface treatment with a specific compound in advance. By using the powdery powder and monodisperse fine spherical powder with a specific average particle size in combination, the water resistance, sebum resistance, and oil resistance are extremely good, and the cosmetic ingredients are less likely to disappear due to sebum or oil, and the feeling of use is improved. It was found that a powder cosmetic having excellent smoothness and adhesiveness can be obtained.
【０００６】本発明は、上記知見に基づきなされたもの
で、下記の２成分（Ａ）及び（Ｂ）を含有することを特
徴とする粉体化粧料を提供するものである。 （Ａ）板状粉体を下記一般式（Ｉ）で示されるパーフル
オロアルキル基含有リン酸エステルによって表面処理し
て得られる撥水性・撥油性板状粉体５〜８０重量％。The present invention has been made based on the above findings, and provides a powder cosmetic containing the following two components (A) and (B). (A) 5 to 80% by weight of a water-repellent / oil-repellent plate-like powder obtained by surface-treating the plate-like powder with a perfluoroalkyl group-containing phosphate represented by the following general formula (I).
【０００７】 ［ＲｆＣn Ｈ2nＯ］y ＰＯ（ＯＭ）3-y （Ｉ） （式中、Ｒｆは炭素数３〜２１のパーフルオロアルキル
基またはパーフルオロオキシアルキル基を示し、直鎖状
あるいは分岐状であって、単一鎖長のものであっても混
合鎖長のものであってもよい。ｎは１〜１２の整数を示
し、ｙは１〜３の数を示す。Ｍは水素、アルカリ金属、
アンモニウム又は置換アンモニウムを示す。） （Ｂ）平均粒径0.01〜2 μm の単分散球状粉体０．５〜
５０重量％。[RfC n H 2n O] y PO (OM) 3-y (I) (In the formula, Rf represents a perfluoroalkyl group having 3 to 21 carbon atoms or a perfluorooxyalkyl group, and is linear or It may be branched and may have a single chain length or a mixed chain length, n represents an integer of 1 to 12, y represents a number of 1 to 3, and M represents hydrogen. , Alkali metal,
Indicates ammonium or substituted ammonium. ) (B) 0.5 ~ monodisperse spherical powder with an average particle size of 0.01 ~ 2 μm
50% by weight.
【０００８】以下、本発明の粉体化粧料について詳述す
る。本発明の（Ａ）成分に用いられる板状粉体として
は、例えばケイ酸、ケイ酸マグネシウム、タルク、セリ
サイト、マイカ、カオリン、シリカ、雲母チタン、オキ
シ塩化ビスマス、酸化セリウム、硫酸カルシウム、硫酸
バリウム、硫酸マグネシウム、炭酸カルシウム、炭酸マ
グネシウム、酸化クロム、水酸化クロム等の無機粉体、
Ｎ−モノ長鎖アシル塩基性アミノ酸、モノアルキルリン
酸亜鉛等の有機粉体等が挙げられ、特に、セリサイト、
マイカ、カオリン、タルク、シリカ等でアスペクト比の
大きいものが好ましい。The powder cosmetic of the present invention will be described in detail below. Examples of the plate-like powder used in the component (A) of the present invention include silicic acid, magnesium silicate, talc, sericite, mica, kaolin, silica, titanium mica, bismuth oxychloride, cerium oxide, calcium sulfate, and sulfuric acid. Inorganic powder such as barium, magnesium sulfate, calcium carbonate, magnesium carbonate, chromium oxide, chromium hydroxide,
Examples thereof include N-mono long-chain acyl basic amino acids, organic powders such as zinc monoalkylphosphate, and the like. In particular, sericite,
Mica, kaolin, talc, silica and the like having a large aspect ratio are preferable.
【０００９】この板状粉体としては、長径が好ましくは
０．５〜５０μm 、更に好ましくは５〜２０μm 、短径
が好ましくは０．５〜２０μm 、更に好ましくは１〜１
０μm のものが用いられる。前記一般式（Ｉ）で示され
るリン酸エステルとしては、具体的には、ジヘプタデカ
フルオロデシルリン酸［（Ｃ8 Ｆ17Ｃ2 Ｈ4 Ｏ）2 ＰＯ
（ＯＨ）］、ヘプタデカフルオロデシルリン酸［Ｃ8 Ｆ
17Ｃ2 Ｈ4 ＯＰＯ（ＯＨ）2 ］、ジヘプタデカフルオロ
デシルリン酸とヘプタデカフルオロデシルリン酸のセス
キ体［（Ｃ8 Ｆ17Ｃ2 Ｈ4 Ｏ）1.5 ＰＯ（ＯＨ）1.5 ］
等のリン酸エステル及びこれらのアルカリ金属塩、アン
モニウム塩、置換アンモニウム塩等が挙げられる。ここ
で置換アンモニウム塩とはモノエタノールアミン、ジエ
タノールアミン等のアルカノールアミンや塩基性アミノ
酸等の塩をいう。The plate-like powder preferably has a major axis of 0.5 to 50 μm, more preferably 5 to 20 μm, and a minor axis of 0.5 to 20 μm, more preferably 1 to 1.
One having a thickness of 0 μm is used. Specific examples of the phosphoric acid ester represented by the general formula (I) include diheptadecafluorodecylphosphoric acid [(C 8 F 17 C 2 H 4 O) 2 PO.
(OH)], heptadecafluorodecyl phosphate [C 8 F
17 C 2 H 4 OPO (OH) 2 ], a sesqui form of diheptadecafluorodecylphosphate and heptadecafluorodecylphosphate [(C 8 F 17 C 2 H 4 O) 1.5 PO (OH) 1.5 ].
And phosphoric acid esters thereof and their alkali metal salts, ammonium salts, substituted ammonium salts and the like. Here, the substituted ammonium salt refers to salts of alkanolamines such as monoethanolamine and diethanolamine and basic amino acids.
【００１０】上述の板状粉体への上記リン酸エステルの
処理法は通常用いられる種々の工程を採用することがで
きる。例えば、ヘンシェルミキサー、振動式ボールミ
ル、回転式ボールミル、スーパーミキサー等の混合攪拌
装置内で粉体を混合しながらパーフルオロアルキル基を
有するリン酸エステルをそのまま、または適当な溶剤
（例えば、水、エタノール、イソプロピルアルコール、
クロロホルム、フロンＲ１１３及びそれらの混合溶媒
等）に溶解させて噴霧あるいは滴下により添加し、均一
分散させた後室温または加熱乾燥を行う。ただし、リン
酸エステルのパーフルオロアルキル基の炭素数が８以上
になると化合物の流動性が著しく低下するので、フロン
Ｒ１１３、ヘキサフルオロメタキシレン等のフッ素系の
溶媒が好ましい。As the method for treating the above plate-like powder with the above phosphoric acid ester, various commonly used steps can be adopted. For example, while mixing the powder in a mixing and stirring device such as a Henschel mixer, a vibrating ball mill, a rotary ball mill, or a super mixer, the phosphate ester having a perfluoroalkyl group is used as it is, or in a suitable solvent (for example, water or ethanol). ,Isopropyl alcohol,
It is dissolved in chloroform, Freon R113 and a mixed solvent thereof, and added by spraying or dropping, and after uniformly dispersing, it is dried at room temperature or by heating. However, if the number of carbon atoms in the perfluoroalkyl group of the phosphoric acid ester is 8 or more, the fluidity of the compound is significantly reduced, so a fluorine-based solvent such as Freon R113 or hexafluoromethaxylene is preferable.
【００１１】板状粉体に対するパーフルオロアルキル基
を有するリン酸エステルの処理量は0.01〜30重量％であ
り、好ましくは0.5 〜15重量％である。0.01％未満では
充分な耐水性及び耐油性が得られず、30％を越えると使
用感が悪くなり好ましくない。また、本発明のＢ成分で
ある単分散球状粉体としては、例えば球状アルミナ、球
状シリカ、球状ジルコニア、球状酸化チタン、球状酸化
亜鉛等の金属酸化物；ポリエステル、ポリエチレン、ポ
リスチレン、メタクリル酸メチル樹脂、スチレンとアク
リル酸の共重合体、ポリプロピレン、アクリルビーズ、
ポリオレフィン、ナイロン等のプラスチック；シリカ系
複合酸化物、シリコン樹脂、ケイ酸アルミニウム、セル
ロース等が挙げられる。ここで、単分散球状粉体とは粒
子形が真球状で、粒度分布が狭い粉体をいい、変動係数
（粒子径の標準偏差／平均粒子径×１００）が１０％以
下、特に５％以下のものをいう。単分散球状粉体は、体
積累積平均粒径が、０．０１〜２μｍのものが用いら
れ、特に０．１〜１μｍが好ましい。この球状粉体はそ
のまま用いてもよいが、特に前述の板状粉体の処理のご
とく撥水撥油処理して用いるのが好ましい。The amount of the phosphoric acid ester having a perfluoroalkyl group treated with respect to the plate-like powder is 0.01 to 30% by weight, preferably 0.5 to 15% by weight. If it is less than 0.01%, sufficient water resistance and oil resistance cannot be obtained. Examples of the monodisperse spherical powder which is the component B of the present invention include metal oxides such as spherical alumina, spherical silica, spherical zirconia, spherical titanium oxide and spherical zinc oxide; polyester, polyethylene, polystyrene, methyl methacrylate resin. , Styrene-acrylic acid copolymer, polypropylene, acrylic beads,
Examples include plastics such as polyolefin and nylon; silica-based composite oxides, silicon resins, aluminum silicate, cellulose and the like. Here, the monodisperse spherical powder means a powder having a true spherical shape and a narrow particle size distribution, and the coefficient of variation (standard deviation of particle diameter / average particle diameter × 100) is 10% or less, particularly 5% or less. I mean one. The monodisperse spherical powder has a volume cumulative average particle diameter of 0.01 to 2 μm, and preferably 0.1 to 1 μm. This spherical powder may be used as it is, but it is particularly preferable to use it after water and oil repellency treatment like the treatment of the plate-like powder described above.
【００１２】本発明に用いられる（Ａ）成分の撥水性・
撥油性板状粉体の配合量は、本発明の粉体化粧量中の５
〜８０重量％、特に１０〜７０重量％が好ましい。
（Ｂ）成分の平均粒径0.01〜2 μm の単分散微小球状粉
体の配合量は、粉体化粧量中の０．５〜５０重量％、特
に１〜２０重量％が好ましい。また、本発明の粉体化粧
料中の（Ａ）及び（Ｂ）成分の合計量は、好ましくは６
０〜９５重量％、特に好ましくは８０〜９０重量％であ
る。The water repellency of the component (A) used in the present invention
The compounding amount of the oil-repellent plate-like powder is 5 in the powder cosmetic amount of the present invention.
-80% by weight, especially 10-70% by weight are preferred.
The blending amount of the component (B) of the monodisperse fine spherical powder having an average particle diameter of 0.01 to 2 μm is preferably 0.5 to 50% by weight, and particularly preferably 1 to 20% by weight based on the amount of powder makeup. The total amount of the components (A) and (B) in the powder cosmetic of the present invention is preferably 6
0 to 95% by weight, particularly preferably 80 to 90% by weight.
【００１３】本発明の化粧料には、上記の（Ａ）及び
（Ｂ）の必須成分に加えて、必要に応じて通常の化粧料
に配合される成分を配合し得る。例えば、ワセリン、ラ
ノリン、セレシン、マイクロクリスタリンワックス、カ
ルナバロウ、キャンデリラロウ、高級脂肪酸、高級アル
コール等の固形・半固形油分；スクワラン、流動パラフ
ィン、エステル油、ジグリセライド、トリグリセライ
ド、シリコン油等の流動油分；パーフルオロポリエーテ
ル、パーフルオロデカリン、パーフルオロオクタン等の
フッ素系油剤；水溶性及び油溶性ポリマー、界面活性
剤、無機及び有機顔料、シリコンまたはフッ素化合物で
処理された無機及び有機顔料、有機染料等の色剤、エタ
ノール、防腐剤、酸化防止剤、色素、増粘剤、ｐＨ調整
剤、香料、紫外線吸収剤、保湿剤、血行促進剤、制汗
剤、殺菌剤、皮膚賦活剤等は本発明の目的、効果を損な
わない質的、量的範囲内で配合可能である。In addition to the above-mentioned essential components (A) and (B), the cosmetics of the present invention may contain, if necessary, components that are usually incorporated in cosmetics. For example, solid / semi-solid oils such as petrolatum, lanolin, ceresin, microcrystalline wax, carnauba wax, candelilla wax, higher fatty acids and higher alcohols; liquid oils such as squalane, liquid paraffin, ester oils, diglycerides, triglycerides and silicone oils; Fluorine-based oil agents such as perfluoropolyether, perfluorodecalin and perfluorooctane; water-soluble and oil-soluble polymers, surfactants, inorganic and organic pigments, inorganic and organic pigments treated with silicon or fluorine compounds, organic dyes, etc. Colorants, ethanol, preservatives, antioxidants, pigments, thickeners, pH adjusters, fragrances, UV absorbers, moisturizers, blood circulation promoters, antiperspirants, bactericides, skin activating agents, etc. It can be blended within the qualitative and quantitative range that does not impair the purpose and effect of.
【００１４】本発明の化粧料は、通常の方法にしたがっ
て製造することができ、ファンデーション、アイシャド
ー、ほほ紅等のメイクアップ化粧料やボディーパウダ
ー、ベビーパウダー等に適用することができる。The cosmetic of the present invention can be produced by a conventional method, and can be applied to makeup cosmetics such as foundation, eye shadow, blusher, body powder, baby powder and the like.
【００１５】[0015]
【作用】本発明の粉体化粧料は、撥水性・撥油性に優
れ、且つ使用感、特に平滑性及び密着性に優れているた
め、粉体化粧料として、使用時に優れた作用を呈する。The powder cosmetic of the present invention is excellent in water repellency and oil repellency, and is excellent in feeling of use, particularly smoothness and adhesion, and thus exhibits an excellent effect when used as a powder cosmetic.
【００１６】次に実施例を製造例と共に挙げて、本発明
を更に詳細に説明するが、本発明はこれらの実施例に限
定されるものではない。配合量は全て重量％である。 製造例１ マイカ１５０ｇを丸底フラスコ（またはニーダー）に入
れる。これにC8F17CH2CH2OP(O)(OH)2 と(C8F17CH2O)2P
(O)OHのほぼ１：１の混合物７．５ｇをイソプロピルア
ルコール１５００ｇに加熱溶解（５０℃）しておいたも
のを加え、６０℃で４時間混合する。その後、４０〜５
０℃にてイソプロピルアルコールを減圧留去し、乾燥し
て撥水性・撥油性マイカ１５５ｇを得た。Next, the present invention will be described in more detail with reference to Examples and Production Examples, but the present invention is not limited to these Examples. All amounts are by weight. Production Example 1 150 g of mica is placed in a round bottom flask (or kneader). This includes C 8 F 17 CH 2 CH 2 OP (O) (OH) 2 and (C 8 F 17 CH 2 O) 2 P
A mixture of 7.5 g of an approximately 1: 1 mixture of (O) OH dissolved in 1500 g of isopropyl alcohol by heating (50 ° C.) is added, and the mixture is mixed at 60 ° C. for 4 hours. Then 40-5
Isopropyl alcohol was distilled off under reduced pressure at 0 ° C. and dried to obtain 155 g of water-repellent / oil-repellent mica .
【００１７】製造例２ 体積累積平均粒径０．４μｍの単分散球状ポリメチルメ
タクリレート１５０ｇを丸底フラスコ（またはニーダ
ー）に入れる。これに〔(Cm F2m+1C2H4O) 1.5 PO(OH)
1.5 〕〔ｍ＝６〜１８、平均９〕７．５ｇをイソプロピ
ルアルコール１５００ｇに加熱溶解（５０℃）しておい
たものを加え、６０℃で４時間混合する。その後、４０
〜５０℃にてイソプロピルアルコールを減圧留去し、乾
燥して目的の撥水性・撥油性球状ポリメチルメタクリレ
ート１５５ｇを得た。Production Example 2 150 g of monodisperse spherical polymethylmethacrylate having a volume cumulative average particle size of 0.4 μm is placed in a round bottom flask (or kneader). In addition to this, ((C m F 2m + 1 C 2 H 4 O) 1.5 PO (OH)
1.5 ] [m = 6 to 18, average of 9] 7.5 g of isopropyl alcohol 1500 g heated and dissolved (50 ° C.) is added, and mixed at 60 ° C. for 4 hours. Then 40
Isopropyl alcohol was distilled off under reduced pressure at -50 ° C and dried to obtain 155 g of the target water-repellent / oil-repellent spherical polymethylmethacrylate.
【００１８】実施例１．パウダーファンデーション 下記表１に示す組成のパウダーファンデーションを下記
（製法）により製造し、汗及び皮脂に対する化粧持ち、
使用感について下記（評価方法）により評価した。その
結果を下記表２に示す。 （製法）粉体成分を混合粉砕して、これをヘンシェルミ
キサーに移し、油剤と香料を加えて均一になる様に混合
した。これを金皿にプレス成型して製品を得た。Embodiment 1 FIG. Powder Foundation A powder foundation having the composition shown in Table 1 below is manufactured by the following (manufacturing method), and has makeup retention against sweat and sebum.
The feeling of use was evaluated by the following (evaluation method). The results are shown in Table 2 below. (Manufacturing method) Powder components were mixed and pulverized, transferred to a Henschel mixer, and an oil agent and a fragrance were added and mixed to be uniform. This was press-molded on a metal plate to obtain a product.
【００１９】[0019]
【表１】 (1) 綜研化学 ＭＰ−２２００ （評価方法）１０人の専門パネラ─により化粧持ち、使
用感の官能評価をおこない、次の基準で示した。[Table 1] (1) Soken Kagaku MP-2200 (Evaluation method) 10 professional panelists carried out a sensory evaluation of the make-up and feeling of use, and showed the following criteria.
【００２０】○ ．．．．．８人以上良い。 △ ．．．．．４人〜７人良い。 × ．．．．．４人未満良い。○. . . . . Eight or more are good. △. . . . . 4 to 7 people are good. ×. . . . . Less than 4 people are good.
【００２１】[0021]
【表２】 上記表２から明らかなように、本発明品は、比較品
と比べて化粧持ち及び使用感に優れたパウダーファンデ
ーションであった。 実施例２． ほほ紅 実施例１と同様にして目的のほほ紅を得た。[Table 2] As is apparent from Table 2 above, the product of the present invention was a powder foundation having a longer lasting makeup and a better feeling in use than the comparative product. Embodiment 2. FIG. Cheek red The desired cheek red was obtained in the same manner as in Example 1.
【００２２】 ・撥水性・撥油性板状粉体顔料 重量％ （下記顔料を、それぞれ製造例１と同様にして 処理したものの混合粉体） カオリン バランス マイカ ２０．０ 酸化チタン １０．０ 赤色２０２号 ２．４ 酸化鉄（赤、黒、黄） ５．０ ・平均粒径０．４μｍのポリメチルメタクリレート １０．０ ・スクワラン ７．５ ・ジメチルポリシロキサン ７．５ ・防腐剤 ０．１ ・香料 ０．０５ 実施例３．パウダーアイシャドー 雲母チタン以外の顔料を先に混合、粉砕した後、雲母チ
タンを混合する。その他は実施例１と同様にして目的の
パウダーアイシャドーを得た。Water-repellent / oil-repellent plate powder pigment weight% ( mixed powder of the following pigments treated in the same manner as in Production Example 1 ) Kaolin balance mica 20.0 titanium oxide 10.0 red No. 202 2.4 Iron oxide (red, black, yellow) 5.0-Polymethylmethacrylate with an average particle size of 0.4 μm 10.0-Squalane 7.5-Dimethylpolysiloxane 7.5-Preservative 0.1-Perfume 0 .05 Example 3. Powder eye shadow A pigment other than titanium mica is mixed and crushed first, and then titanium mica is mixed. Others were the same as that of Example 1, and the target powder eye shadow was obtained.
【００２３】 ・撥水性・撥油性板状粉体顔料 重量％ （実施例２と同様の混合粉体） 雲母チタン ４．９ セリサイト バランス マイカ ２４．７ 酸化鉄（赤、黄、黒） ２．０ 群青 ９．８ 紺青 １４．６ 平均粒径０．４μｍのポリメチルメタクリレート １０．０ ・ジメチルポリシロキサン １．９ ・スクワラン １．９ ・ワセリン １．９ ・ソルビタントリオレエート １．０ ・防腐剤 １．０ ・香料 ０．１ 実施例４． 両用パウダーファンデーション 実施例１と同様にして目的の両用パウダーファンデーシ
ョンを得た。Water-repellent / oil-repellent plate powder pigment weight% ( mixed powder similar to that in Example 2 ) Mica titanium 4.9 sericite balance mica 24.7 iron oxide (red, yellow, black) 2. 0 Ultramarine 9.8 Dark blue 14.6 Polymethylmethacrylate with an average particle size of 0.4 μm 10.0-Dimethylpolysiloxane 1.9-Squalane 1.9-Vaseline 1.9-Sorbitan trioleate 1.0-Preservative 1 .0 Perfume 0.1 Example 4. Dual-use powder foundation The desired dual-use powder foundation was obtained in the same manner as in Example 1.
【００２４】 ・撥水性・撥油性板状粉体顔料 重量％ （実施例２と同様の混合粉体） マイカ バランス タルク ４．８ 酸化チタン １４．０ 雲母チタン ３．５ 酸化鉄（赤、黄、黒） ８．２ 酸化亜鉛 ４．５ 酸化アルミニウム １０．０ 硫酸バリウム ５．０ ・平均粒径０．１μｍのポリ １０．０ メチルメタクリレート ・ジメチルポリシロキサン ４．０ ・ラノリン ６．０ ・ワセリン １．０ ・流動パラフィン １．０ ・イソプロピリミリステート １．０ ・防腐剤 １．５ ・香料 ０．１ 実施例２〜４で得られた本発明の化粧料は、いずれも、
使用感に優れ、化粧持ちが極めて良好なものであった。Water-repellent / oil-repellent plate-like powder pigment wt% ( mixed powder similar to that in Example 2 ) Mica balance talc 4.8 titanium oxide 14.0 mica titanium 3.5 iron oxide (red, yellow, Black) 8.2 Zinc oxide 4.5 Aluminum oxide 10.0 Barium sulfate 5.0 ・ Poly 10.0 with an average particle size of 0.1 µm Methyl methacrylate ・ Dimethyl polysiloxane 4.0 ・ Lanolin 6.0 ・ Vaseline 1. 0 Liquid paraffin 1.0 Isopropyrimyristate 1.0 Preservative 1.5 Perfume 0.1 The cosmetics of the present invention obtained in Examples 2 to 4 are
The feeling of use was excellent and the durability of the makeup was extremely good.
【００２５】[0025]
【発明の効果】本発明の粉体化粧料は、撥水性・撥油性
に優れ、汗、皮脂に対する化粧崩れがなく、同時に粉体
の基本的性能である肌上での伸び及び付着性の良さ、平
滑感等を満足するものである。EFFECTS OF THE INVENTION The powder cosmetics of the present invention have excellent water and oil repellency, do not lose makeup against sweat and sebum, and at the same time have good spreadability and adhesiveness on the skin, which are the basic properties of powders. , Smoothness, etc. are satisfied.
Claims (1)
ることを特徴とする粉体化粧料。 （Ａ）板状粉体を下記一般式（Ｉ）で示されるパーフル
オロアルキル基含有リン酸エステルによって表面処理し
て得られる撥水性・撥油性板状粉体５〜８０重量％。 ［ＲｆＣn Ｈ2nＯ］y ＰＯ（ＯＭ）3-y （Ｉ） （式中、Ｒｆは炭素数３〜２１のパーフルオロアルキル
基またはパーフルオロオキシアルキル基を示し、直鎖状
あるいは分岐状であって、単一鎖長のものであっても混
合鎖長のものであってもよい。ｎは１〜１２の整数を示
し、ｙは１〜３の数を示す。Ｍは水素、アルカリ金属、
アンモニウム又は置換アンモニウムを示す。） （Ｂ）平均粒径0.01〜2 μm の単分散球状粉体０．５〜
５０重量％。1. A powder cosmetic comprising the following two components (A) and (B). (A) 5 to 80% by weight of a water-repellent / oil-repellent plate-like powder obtained by surface-treating the plate-like powder with a perfluoroalkyl group-containing phosphate represented by the following general formula (I). [RfC n H 2n O] y PO (OM) 3-y (I) (In the formula, Rf represents a perfluoroalkyl group having 3 to 21 carbon atoms or a perfluorooxyalkyl group, which may be linear or branched. And may have a single chain length or a mixed chain length, n represents an integer of 1 to 12, y represents a number of 1 to 3, M represents hydrogen or an alkali metal. ,
Indicates ammonium or substituted ammonium. ) (B) 0.5 ~ monodisperse spherical powder with an average particle size of 0.01 ~ 2 μm
50% by weight.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP22044591A JP2672908B2 (en) | 1991-08-30 | 1991-08-30 | Powder cosmetics |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP22044591A JP2672908B2 (en) | 1991-08-30 | 1991-08-30 | Powder cosmetics |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH0558841A JPH0558841A (en) | 1993-03-09 |
| JP2672908B2 true JP2672908B2 (en) | 1997-11-05 |
Family
ID=16751228
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP22044591A Expired - Fee Related JP2672908B2 (en) | 1991-08-30 | 1991-08-30 | Powder cosmetics |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP2672908B2 (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2007123115A1 (en) | 2006-04-17 | 2007-11-01 | Mitsubishi Pencil Company, Limited | Water-based liquid makeup cosmetic |
Families Citing this family (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP3025567B2 (en) * | 1991-12-16 | 2000-03-27 | 花王株式会社 | Oral composition |
| JP3455066B2 (en) * | 1997-06-30 | 2003-10-06 | 花王株式会社 | UV reflective powder and cosmetic containing it |
| JPH11222414A (en) * | 1998-02-04 | 1999-08-17 | Shiseido Co Ltd | Makeup cosmetic |
| JP2006169123A (en) * | 2004-12-13 | 2006-06-29 | Pola Chem Ind Inc | Makeup cosmetic |
| JP4902192B2 (en) * | 2005-12-21 | 2012-03-21 | 株式会社コーセー | Solid powder cosmetic |
| EP2198835A4 (en) * | 2007-09-19 | 2011-06-22 | Ohken Co Ltd | Powder cosmetic and process for production of flaky calcium sulfate dihydrate to be used in the cosmetic |
| KR102644813B1 (en) * | 2016-08-31 | 2024-03-07 | (주)아모레퍼시픽 | Highly adhesive eye make-up cosmetic composition |
-
1991
- 1991-08-30 JP JP22044591A patent/JP2672908B2/en not_active Expired - Fee Related
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2007123115A1 (en) | 2006-04-17 | 2007-11-01 | Mitsubishi Pencil Company, Limited | Water-based liquid makeup cosmetic |
| US8663666B2 (en) | 2006-04-17 | 2014-03-04 | Mitsubishi Pencil Company, Limited | Water based liquid makeup cosmetic |
Also Published As
| Publication number | Publication date |
|---|---|
| JPH0558841A (en) | 1993-03-09 |
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