JPH0489196A - Composite wire for electrogas arc welding - Google Patents

Composite wire for electrogas arc welding

Info

Publication number
JPH0489196A
JPH0489196A JP20407090A JP20407090A JPH0489196A JP H0489196 A JPH0489196 A JP H0489196A JP 20407090 A JP20407090 A JP 20407090A JP 20407090 A JP20407090 A JP 20407090A JP H0489196 A JPH0489196 A JP H0489196A
Authority
JP
Japan
Prior art keywords
composite wire
flux
wire
arc welding
weld metal
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP20407090A
Other languages
Japanese (ja)
Other versions
JP2729529B2 (en
Inventor
Hirotoshi Ishide
石出 博俊
Kiyoshi Kato
清 加藤
Tsukasa Yoshimura
司 吉村
Hiroyuki Kyo
京 広之
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Nippon Steel Corp
Original Assignee
Nippon Steel Corp
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Filing date
Publication date
Application filed by Nippon Steel Corp filed Critical Nippon Steel Corp
Priority to JP2204070A priority Critical patent/JP2729529B2/en
Publication of JPH0489196A publication Critical patent/JPH0489196A/en
Application granted granted Critical
Publication of JP2729529B2 publication Critical patent/JP2729529B2/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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Abstract

PURPOSE:To obtain the composite wire for electrogas arc welding which can improve the low-temp. toughness in the reheated part of a weld metal and heat affected zone by filling a flux contg. a slag forming agent consisting of only the metal fluoride into a steel sheath and specifying the component compsn. of the filled flux by the total weight of a composite wire. CONSTITUTION:The flux contg. the slag forming agent consisting of only the metal fluoride is filled in the steel sheath and 0.7 to 1.5% metal fluoride, by the total weight of the composite wire, 0.7 to 1.5% Mn, 0.15 to 0.5% Si, 0.1 to O.6% Mg, 0.05 to 0.25% Ti, 1.5 to 4.5% Ni, 0.002 to 0.02% B, 10 to 25% iron power and further, 0.005 to 0.25% Al at need in addition to the above- mentioned components are incorporated into this flux. The filling rate of the flux is most adequately in a 20 to 30% range by the total weight of the wire.

Description

【発明の詳細な説明】 〔産業上の利用分野〕 本発明は、溶接金属または熱影響部に対して、低温靭性
、特にCOD特性に優れたエレクトロガスアーク溶接用
複合ワイヤに関するものである。
DETAILED DESCRIPTION OF THE INVENTION [Field of Industrial Application] The present invention relates to a composite wire for electrogas arc welding that has excellent low-temperature toughness, particularly COD characteristics, for weld metal or heat affected zone.

〔従来の技術〕[Conventional technology]

現在、エレクトロガスアーク溶接は、溶接の高速度化や
低入熱化が可能であるところから、軟鋼から原油タンク
の側板型継手に代表される様な調質型60kg/m”扱
高張力鋼の溶接にも採用されている。
At present, electrogas arc welding is capable of high welding speeds and low heat input, so it can be used to process everything from mild steel to tempered 60 kg/m" high tensile strength steel, such as the side plate type joints of crude oil tanks. It is also used for welding.

しかし、−20℃以下の低温状態で溶接するに当って、
従来のエレクトロガスアーク溶接用複合ワイヤでは、溶
接金属自体および熱影響部の再熱部の靭性を確保するこ
とができず、溶接能率の優秀性にもかかわらず適用不可
とされている。そのため、低温での多層盛やX開先継手
などの適用には困難とされていた。
However, when welding at low temperatures below -20℃,
Conventional composite wires for electrogas arc welding cannot ensure the toughness of the weld metal itself and the reheated part of the heat-affected zone, and are not applicable despite their excellent welding efficiency. Therefore, it has been considered difficult to apply it to multi-layer stacking or X-groove joints at low temperatures.

また、エレクトロガスアーク溶接における溶接金属の靭
性改善手段としては、例えば、特開昭5548495号
公報に見られる様に、鋼製外皮に囲まれるフラックス中
にCaF、およびNaFを必須とするスラグ剤にMo、
 Ti+  Bを添加したワイヤを用いる方法等が旋案
されているが、十分な方策とはなっていない。
In addition, as a means for improving the toughness of weld metal in electrogas arc welding, for example, as seen in Japanese Patent Application Laid-Open No. 5,548,495, Mo ,
A method using a wire doped with Ti+B has been proposed, but it is not a sufficient solution.

〔発明が解決しようとする課題〕[Problem to be solved by the invention]

本発明は、溶接金属と熱影響部の再熱部の低温靭性を良
好にすることを目的としたもので、溶接金属中の酸素量
を低減し、併せて溶接金属の再加熱に対して、結晶組織
の粗大化を抑えることにより、溶接金属と熱影響部の再
熱部の低温靭性を改善して従来ワイヤの欠点を解消し、
適用分野を拡大することが出来るエレクトロガスアーク
溶接用複合ワイヤを提供するものである。
The purpose of the present invention is to improve the low-temperature toughness of the weld metal and the reheated zone of the heat-affected zone. By suppressing the coarsening of the crystal structure, it improves the low-temperature toughness of the weld metal and the reheated part of the heat-affected zone, eliminating the drawbacks of conventional wires.
The present invention provides a composite wire for electrogas arc welding that can expand the field of application.

〔課題を解決するための手段〕[Means to solve the problem]

本発明の要旨とするところは、スラグ生成剤が金属弗化
物のみからなるフラックスを鋼製外皮中に充填して、複
合ワイヤ全重量に対して、金属弗化物:0.7〜1.5
%、Mn:0.7〜1.5%、Si:0.15〜0.5
%、Mg : 0.1〜0.6%、Ti:0.05〜0
.25%、Ni:1.5〜4.5%、B : O,OO
2〜0.02%、鉄粉:10〜25%、さらに上記に加
えて、Al : 0.005〜0.25%含有させたこ
とを特徴とするエレクトロガスアーク溶接用複合ワイヤ
にある。
The gist of the present invention is to fill a steel outer sheath with a flux in which the slag forming agent consists only of metal fluoride, so that the amount of metal fluoride is 0.7 to 1.5 with respect to the total weight of the composite wire.
%, Mn: 0.7-1.5%, Si: 0.15-0.5
%, Mg: 0.1-0.6%, Ti: 0.05-0
.. 25%, Ni: 1.5-4.5%, B: O, OO
2 to 0.02%, iron powder: 10 to 25%, and in addition to the above, Al: 0.005 to 0.25%.

〔作 用〕[For production]

本発明者は、長年、エレクトロガスアーク溶接の研究に
携わっている者であり、長年にわたりワイヤの試作を重
ね研究した結果、溶接金属および熱影響部の再熱部の低
温靭性を向上させるためには、溶接金属中に存在するM
oは再加熱時にミクロ組織を粗大化する作用があるため
極力添加しないこと、再加熱に対しても粗大化がおこら
ず、ミクロ組織を微細化、均一化するNiを添加するこ
と、また溶接金属中の酸素量が増加するとミクロ組織が
粗大化するため、その酸素源となるスラグ生成剤として
添加する酸化物をすべて除き、スラグ生成剤を金属弗化
物のみとすることの3点が有効であるとの知見が得られ
た。
The present inventor has been involved in research on electrogas arc welding for many years, and as a result of repeated research and manufacturing of wire prototypes over the years, he has found that in order to improve the low-temperature toughness of the weld metal and the reheated part of the heat-affected zone. , M present in the weld metal
O has the effect of coarsening the microstructure during reheating, so it should be avoided as much as possible; Ni, which does not coarsen even when reheated and makes the microstructure finer and more uniform, should be added; As the amount of oxygen increases, the microstructure becomes coarser, so three effective methods are to remove all oxides added as slag-forming agents that serve as oxygen sources, and to use only metal fluoride as the slag-forming agent. The following findings were obtained.

そこで、3点の知見を組合せ、充填フラックス中から従
来添加しているMoを除き、Niを添加し、スラグ生成
剤を金属弗化物のみにして、実験をくり返したところ、
従来ワイヤには見られなかった溶接金属および熱影響部
の再熱部の低温靭性の優れた複合ワイヤを得ることがで
き、本発明を構成するにに至った。
Therefore, by combining three points of knowledge, we removed the conventionally added Mo from the filling flux, added Ni, and used only metal fluoride as the slag forming agent, and repeated the experiment.
A composite wire with excellent low-temperature toughness of the weld metal and the reheated part of the heat-affected zone, which has not been seen in conventional wires, can be obtained, and the present invention has been completed.

以下、充填フラックスの成分組成について説明する。The composition of the filling flux will be explained below.

金属弗化物はアーク安定性を高めると共に脱水素作用に
よって溶接金属の低温靭性を向上させる作用がある。こ
れらの作用は金属弗化物で0.7%以上添加することに
より有効に発揮される。しかし、1.5%を超えるとス
ラグの流動性が過大となり、スラグ被包性が悪く、ビー
ド形状が悪化する。
Metal fluorides have the effect of increasing arc stability and improving the low-temperature toughness of weld metal through dehydrogenation. These effects can be effectively exhibited by adding 0.7% or more of metal fluoride. However, if it exceeds 1.5%, the fluidity of the slag becomes excessive, the slag envelopment is poor, and the bead shape deteriorates.

従って0.7〜1.5%の範囲とする。金属弗化物とし
ては、Na、  K、 Li+ Mg、 Ca等のアル
カリ金属およびアルカリ土類金属の弗化物が一般的に用
いられる。
Therefore, it should be in the range of 0.7 to 1.5%. As the metal fluoride, fluorides of alkali metals and alkaline earth metals such as Na, K, Li+Mg, and Ca are generally used.

Mnはスラグの流動性を調整し、ビード形状を改善する
と共に溶接金属の脱酸を促進し、かつ溶接継手に適した
強度を与えるために添加される。
Mn is added to adjust the fluidity of the slag, improve the bead shape, promote deoxidation of the weld metal, and provide suitable strength to the welded joint.

0.7%未満では、必要な強度が得られない。一方1.
5%を超えると強度は向上するが逆に靭性を劣化させる
。従ってMnの添加量は0.7〜1.5%とする。なお
、Mnは単体で用いられる他、Fe−Mn、Fe51−
Mn等の鉄合金の形態でも使用できる。
If it is less than 0.7%, the required strength cannot be obtained. On the other hand 1.
If it exceeds 5%, the strength will improve, but the toughness will deteriorate. Therefore, the amount of Mn added is set to 0.7 to 1.5%. In addition, Mn is used alone, as well as in Fe-Mn, Fe51-
It can also be used in the form of an iron alloy such as Mn.

Siは有効な脱酸剤であると共に、ビード外観、および
溶接作業性を改善するが、0.15%未満では、これら
の効果が得られない。しかし、0.5%を超えると溶接
金属中のSiが過剰となって靭性を劣化させるので好ま
しくない。従ってSiは0.15〜0.5%とする。な
お、Siは単体あるいは、FeSi、 FeFe−5i
−等の鉄合金の形態でも使用できる。
Si is an effective deoxidizing agent and improves bead appearance and welding workability, but if it is less than 0.15%, these effects cannot be obtained. However, if it exceeds 0.5%, Si in the weld metal becomes excessive and deteriorates toughness, which is not preferable. Therefore, Si should be 0.15 to 0.5%. In addition, Si is a simple substance, FeSi, FeFe-5i
It can also be used in the form of iron alloys such as -.

Mgは強力な脱酸剤である。特に溶接金属中の酸素量を
低減するのには、最良である。添加量が0、1%未満で
はその効果が十分得られず、一方、0.6%を超えると
溶接作業性が悪化して、スパッタ発生量が多くなると共
に低温靭性も劣化させる。
Mg is a strong deoxidizer. In particular, it is best for reducing the amount of oxygen in weld metal. If the addition amount is less than 0.1%, the effect will not be sufficiently obtained, while if it exceeds 0.6%, welding workability will deteriorate, the amount of spatter will increase, and low-temperature toughness will also deteriorate.

従ってMgの適正範囲は0.1〜0.6%とする。Mg
は単体もしくは、Ni −Mg、 Ca−Mg、 Fe
−Mg+Fe −51Mg等のMg合金の形態で添加し
てもよい。
Therefore, the appropriate range of Mg is 0.1 to 0.6%. Mg
is alone or Ni-Mg, Ca-Mg, Fe
-Mg+Fe It may be added in the form of an Mg alloy such as -51Mg.

TiはTi酸化物を形成し、溶接金属のミクロ組織を微
細化し、低温靭性改善に有効であるが、0.05%未満
ではこの効果が望めないので下限を0.05%とする。
Ti forms Ti oxide, refines the microstructure of the weld metal, and is effective in improving low-temperature toughness, but if it is less than 0.05%, this effect cannot be expected, so the lower limit is set at 0.05%.

また0、25%を超えると低温靭性を著しく損なうので
、上限を0.25%とする。Tiは金属Tiの他にFe
−Ti等の合金として添加してもよい。
Moreover, if it exceeds 0.25%, low-temperature toughness will be significantly impaired, so the upper limit is set to 0.25%. Ti is Fe in addition to metal Ti.
-It may be added as an alloy such as Ti.

Bは強力な脱酸性炭化物生成元素であるから、これをワ
イヤに添加することによって溶接金属における結晶粒は
微細化する。また溶接金属の焼入れ性を高める効果があ
り、この様な効果を得るためには、最小限0. OO2
%のB量が必要で、それ未満では、効果がな(、また多
すぎると溶接金属の高温割れが発生し易くなるので、上
限を0.02%とする。B源としてはFe−B、  ア
トマイズB等の合金として添加することもできる。
Since B is a strong deoxidizing carbide-forming element, adding it to the wire refines the crystal grains in the weld metal. It also has the effect of increasing the hardenability of the weld metal, and in order to obtain such an effect, a minimum of 0. OO2
% of B is required, and if it is less than that, there is no effect (and if it is too much, hot cracking of the weld metal is likely to occur, so the upper limit is set to 0.02%. As a B source, Fe-B, It can also be added as an alloy such as Atomized B.

Niは溶接金属の靭性を上昇させるのに有効であり、特
に再加熱しても靭性が低下しない利点を有するが、1.
5%未満では効果がなく、また4、5%超であると溶接
金属の高温割れを起こすので、下限を1.5%とし、上
限を4.5%とする。
Ni is effective in increasing the toughness of weld metal, and has the advantage that the toughness does not deteriorate even after reheating.
If it is less than 5%, there will be no effect, and if it exceeds 4.5%, hot cracking will occur in the weld metal, so the lower limit is set to 1.5% and the upper limit is set to 4.5%.

八!の添加は、TiおよびBの効果を助長する作用があ
るが、O,OO5%未満では効果がなく、逆に0.25
%超では溶接金属を脆化させ靭性を低下させる。従って
、下限をO,OO5%とし、上限を0.25%とする。
Eight! The addition of O has the effect of promoting the effects of Ti and B, but it has no effect when O and OO are less than 5%, and on the contrary, when O and O are less than 5%,
If it exceeds %, the weld metal becomes brittle and its toughness decreases. Therefore, the lower limit is set to 5% O,OO, and the upper limit is set to 0.25%.

尚、Alの添加方法としては単体もしくはAl −Mg
、 Fe−Al等の合金の形で添加することができる。
In addition, as for the addition method of Al, Al alone or Al-Mg
, Fe-Al, etc. can be added in the form of an alloy.

また、フラックスの充填率は特に限定されないが、伸線
性を考慮してワイヤ全重量に対して20〜30%の範囲
が最も適当である。
Further, the filling rate of flux is not particularly limited, but in consideration of wire drawability, a range of 20 to 30% based on the total weight of the wire is most appropriate.

尚、ワイヤの断面形状には何らの制限もなく、2mmφ
以下の細径の場合は比較的単純な円筒状のものが、また
2、4〜3.2++unφ程度の大径ワイヤの場合は鞘
材を内部へ複雑に折り込んだ構造のものが一般的である
。また、シームレスワイヤにおいては、表面にCu等メ
ツキ処理を施すことも有効である。
There is no limit to the cross-sectional shape of the wire, and the wire has a diameter of 2 mmφ.
In the case of small diameter wires below, a relatively simple cylindrical wire is generally used, and in the case of large diameter wires of approximately 2.4 to 3.2++ unφ, wires with a structure in which the sheath material is folded in a complicated manner are generally used. . Furthermore, it is also effective to perform a plating treatment such as Cu on the surface of the seamless wire.

〔実施例〕〔Example〕

第1表に示す成分の外皮を用い、第2表に示すフラック
ス組成にて試作したワイヤを用いて溶接をおこなった。
Welding was carried out using a wire having the composition shown in Table 1 and a wire prototyped with the flux composition shown in Table 2.

その結果を第3表に示す。The results are shown in Table 3.

第2表、第3表において、ワイヤ記号阻1〜5は比較例
、Nα6〜Nα15が本発明になるワイヤの実施例であ
る。
In Tables 2 and 3, wire symbols 1 to 5 are comparative examples, and wires Nα6 to Nα15 are examples of the present invention.

いずれも厚さ0.8mo+、幅11.1 mmの軟鋼フ
ープを圧延加工しながらフラックスを充填し、1.6 
mmφワイヤに仕上げたワイヤを使用し、下記の条件で
溶接して得た溶接金属の引張特性、衝撃特性、COD特
性、X線性能を調べたところ第3表の結果が得られた。
In both cases, a mild steel hoop with a thickness of 0.8mo+ and a width of 11.1mm is filled with flux while being rolled.
The tensile properties, impact properties, COD properties, and X-ray performance of the weld metal obtained by welding the wire finished into mmφ wire under the following conditions were investigated, and the results shown in Table 3 were obtained.

溶接条件 溶接電流=380A 溶接電圧:39V 溶接速度:10cm/領in シールドガス:COz 、  35 ffi/win開
先形状:X型継手(第1図参照) 母    材:板厚40■。
Welding conditions Welding current = 380A Welding voltage: 39V Welding speed: 10cm/in Shielding gas: COz, 35ffi/win Groove shape: X-shaped joint (see Figure 1) Base material: Plate thickness 40mm.

材質:低温用YP42鋼。Material: YP42 steel for low temperature.

積 層 法:両面1パス 尚、溶接金属の特性は、板厚方向および開先幅方向の中
央部からとり出した試験片を用いて調査した。
Lamination method: 1 pass on both sides The properties of the weld metal were investigated using test pieces taken from the center in the plate thickness direction and the groove width direction.

第3表の試験結果から明らかな様に、本発明外であるワ
イヤは低温靭性が低く、COD値も低く、X線性能が悪
いことが確認された。
As is clear from the test results in Table 3, it was confirmed that wires other than those of the present invention had low low temperature toughness, low COD values, and poor X-ray performance.

これに対して、本発明の実施例のワイヤは低温靭性、C
OD値、X線性能が良好なことが確認された。
In contrast, the wire of the embodiment of the present invention has low temperature toughness, C
It was confirmed that the OD value and X-ray performance were good.

第  1  表(ワイヤ外皮成分) (賀t%) 〔発明の効果〕 以上の如く、本発明のフランクス入すワイヤによれば、
溶接金属および熱影響部の再熱部の低温靭性を改善する
ことができ、その結果、エレクトロガスアーク溶接用複
合ワイヤの欠点を解消し、その用途を大幅に拡大し得る
ものであるから、本発明は産業上極めて有用である。
Table 1 (Wire outer skin components) (T%) [Effects of the invention] As described above, according to the wire with franks of the present invention,
The present invention can improve the low-temperature toughness of the weld metal and the reheated zone of the heat-affected zone, thereby eliminating the drawbacks of composite wire for electrogas arc welding and greatly expanding its applications. is extremely useful in industry.

【図面の簡単な説明】[Brief explanation of the drawing]

第1図は実施例における開先形状(X型継手)の説明図
である。
FIG. 1 is an explanatory diagram of the groove shape (X-shaped joint) in the example.

Claims (2)

【特許請求の範囲】[Claims] (1)スラグ生成剤が金属弗化物のみからなるフラック
スを鋼製外皮中に充填して、複合ワイヤ全重量に対して
、 金属弗化物:0.7〜1.5% Mn:0.7〜1.5% Si:0.15〜0.5% Mg:0.1〜0.6% Ti:0.05〜0.25% Ni:1.5〜4.5% B:0.002〜0.02% 鉄粉:10〜25% を含有させたことを特徴とするエレクトロガスアーク溶
接用複合ワイヤ。
(1) A flux containing only metal fluoride as a slag forming agent is filled into the steel outer shell, and based on the total weight of the composite wire, metal fluoride: 0.7 to 1.5% Mn: 0.7 to 1.5% Si: 0.15-0.5% Mg: 0.1-0.6% Ti: 0.05-0.25% Ni: 1.5-4.5% B: 0.002- A composite wire for electrogas arc welding, characterized in that it contains 0.02% iron powder: 10 to 25%.
(2)請求項1項記載の複合ワイヤにおいて、充填フラ
ックス中に複合ワイヤ全重量に対して、Alを0.00
5〜0.25%含有してなるエレクトロガスアーク溶接
用複合ワイヤ。
(2) In the composite wire according to claim 1, 0.00% Al is added to the total weight of the composite wire in the filling flux.
A composite wire for electrogas arc welding containing 5 to 0.25%.
JP2204070A 1990-08-01 1990-08-01 Composite wire for electrogas arc welding Expired - Lifetime JP2729529B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP2204070A JP2729529B2 (en) 1990-08-01 1990-08-01 Composite wire for electrogas arc welding

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP2204070A JP2729529B2 (en) 1990-08-01 1990-08-01 Composite wire for electrogas arc welding

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2010064087A (en) * 2008-09-09 2010-03-25 Nippon Steel & Sumikin Welding Co Ltd Flux cored wire for gas-shielded arc welding
JP2019104020A (en) * 2017-12-11 2019-06-27 日本製鉄株式会社 Flux-cored wire for vertical electrogas arc welding, and method for producing weld joint

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS49115951A (en) * 1973-03-10 1974-11-06
JPS556759A (en) * 1978-06-30 1980-01-18 Omron Tateisi Electronics Co Electromagnetic relay
JPS597559A (en) * 1982-06-28 1984-01-14 ウイルヘルム・ヘ−ゲンシヤイト・ゲゼルシヤフト・ミト・ベシユレンクテル・ハフツング Machining machine for crankshaft
JPS59189097A (en) * 1983-04-11 1984-10-26 Nippon Steel Corp Composite wire for electrogas arc welding
JPS6011600A (en) * 1983-06-30 1985-01-21 ユシロ化学工業株式会社 Removing agent for automobile anticorrosive
JPS61259894A (en) * 1985-05-11 1986-11-18 Kobe Steel Ltd Cored wire for electrogas arc welding

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS49115951A (en) * 1973-03-10 1974-11-06
JPS556759A (en) * 1978-06-30 1980-01-18 Omron Tateisi Electronics Co Electromagnetic relay
JPS597559A (en) * 1982-06-28 1984-01-14 ウイルヘルム・ヘ−ゲンシヤイト・ゲゼルシヤフト・ミト・ベシユレンクテル・ハフツング Machining machine for crankshaft
JPS59189097A (en) * 1983-04-11 1984-10-26 Nippon Steel Corp Composite wire for electrogas arc welding
JPS6011600A (en) * 1983-06-30 1985-01-21 ユシロ化学工業株式会社 Removing agent for automobile anticorrosive
JPS61259894A (en) * 1985-05-11 1986-11-18 Kobe Steel Ltd Cored wire for electrogas arc welding

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2010064087A (en) * 2008-09-09 2010-03-25 Nippon Steel & Sumikin Welding Co Ltd Flux cored wire for gas-shielded arc welding
JP2019104020A (en) * 2017-12-11 2019-06-27 日本製鉄株式会社 Flux-cored wire for vertical electrogas arc welding, and method for producing weld joint

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