JPH048402B2 - - Google Patents
Info
- Publication number
- JPH048402B2 JPH048402B2 JP58150228A JP15022883A JPH048402B2 JP H048402 B2 JPH048402 B2 JP H048402B2 JP 58150228 A JP58150228 A JP 58150228A JP 15022883 A JP15022883 A JP 15022883A JP H048402 B2 JPH048402 B2 JP H048402B2
- Authority
- JP
- Japan
- Prior art keywords
- present
- compound
- snails
- slugs
- methylisothiazolin
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 241000237858 Gastropoda Species 0.000 claims description 22
- 239000003795 chemical substances by application Substances 0.000 claims description 6
- PUSPAPGHKSLKKH-UHFFFAOYSA-N 2-methyl-1,2-thiazolidin-3-one Chemical compound CN1SCCC1=O PUSPAPGHKSLKKH-UHFFFAOYSA-N 0.000 claims description 3
- 229910052739 hydrogen Inorganic materials 0.000 claims description 3
- 239000001257 hydrogen Substances 0.000 claims description 3
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 3
- -1 metal complex compound Chemical class 0.000 claims description 3
- 125000005843 halogen group Chemical group 0.000 claims description 2
- 239000004480 active ingredient Substances 0.000 claims 1
- 150000001875 compounds Chemical class 0.000 description 9
- 241001465754 Metazoa Species 0.000 description 4
- 238000005507 spraying Methods 0.000 description 4
- 241000196324 Embryophyta Species 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 241000238631 Hexapoda Species 0.000 description 2
- TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 description 2
- 241000607479 Yersinia pestis Species 0.000 description 2
- 239000005667 attractant Substances 0.000 description 2
- YIXJRHPUWRPCBB-UHFFFAOYSA-N magnesium nitrate Chemical compound [Mg+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O YIXJRHPUWRPCBB-UHFFFAOYSA-N 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- JIAARYAFYJHUJI-UHFFFAOYSA-L zinc dichloride Chemical compound [Cl-].[Cl-].[Zn+2] JIAARYAFYJHUJI-UHFFFAOYSA-L 0.000 description 2
- UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 description 1
- 241000041238 Eulota Species 0.000 description 1
- 240000001549 Ipomoea eriocarpa Species 0.000 description 1
- 235000005146 Ipomoea eriocarpa Nutrition 0.000 description 1
- 239000005956 Metaldehyde Substances 0.000 description 1
- 241000237852 Mollusca Species 0.000 description 1
- 241000699670 Mus sp. Species 0.000 description 1
- 240000004808 Saccharomyces cerevisiae Species 0.000 description 1
- 241000209140 Triticum Species 0.000 description 1
- 235000021307 Triticum Nutrition 0.000 description 1
- 230000000844 anti-bacterial effect Effects 0.000 description 1
- 230000000843 anti-fungal effect Effects 0.000 description 1
- 229940121375 antifungal agent Drugs 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 239000012752 auxiliary agent Substances 0.000 description 1
- 239000001110 calcium chloride Substances 0.000 description 1
- 229910001628 calcium chloride Inorganic materials 0.000 description 1
- 239000005018 casein Substances 0.000 description 1
- BECPQYXYKAMYBN-UHFFFAOYSA-N casein, tech. Chemical compound NCCCCC(C(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(CC(C)C)N=C(O)C(CCC(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(C(C)O)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(COP(O)(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(N)CC1=CC=CC=C1 BECPQYXYKAMYBN-UHFFFAOYSA-N 0.000 description 1
- 235000021240 caseins Nutrition 0.000 description 1
- DHNRXBZYEKSXIM-UHFFFAOYSA-N chloromethylisothiazolinone Chemical compound CN1SC(Cl)=CC1=O DHNRXBZYEKSXIM-UHFFFAOYSA-N 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 229910000365 copper sulfate Inorganic materials 0.000 description 1
- ARUVKPQLZAKDPS-UHFFFAOYSA-L copper(II) sulfate Chemical compound [Cu+2].[O-][S+2]([O-])([O-])[O-] ARUVKPQLZAKDPS-UHFFFAOYSA-L 0.000 description 1
- 239000010730 cutting oil Substances 0.000 description 1
- 239000000645 desinfectant Substances 0.000 description 1
- 235000013399 edible fruits Nutrition 0.000 description 1
- 239000003995 emulsifying agent Substances 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 230000008029 eradication Effects 0.000 description 1
- 239000003337 fertilizer Substances 0.000 description 1
- 239000004088 foaming agent Substances 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- 235000012055 fruits and vegetables Nutrition 0.000 description 1
- 239000000417 fungicide Substances 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 239000004009 herbicide Substances 0.000 description 1
- 239000002917 insecticide Substances 0.000 description 1
- FBAFATDZDUQKNH-UHFFFAOYSA-M iron chloride Chemical compound [Cl-].[Fe] FBAFATDZDUQKNH-UHFFFAOYSA-M 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 229910001629 magnesium chloride Inorganic materials 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- GKKDCARASOJPNG-UHFFFAOYSA-N metaldehyde Chemical compound CC1OC(C)OC(C)OC(C)O1 GKKDCARASOJPNG-UHFFFAOYSA-N 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 239000006072 paste Substances 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 235000018102 proteins Nutrition 0.000 description 1
- 102000004169 proteins and genes Human genes 0.000 description 1
- 108090000623 proteins and genes Proteins 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 239000005871 repellent Substances 0.000 description 1
- 230000002940 repellent Effects 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 238000003892 spreading Methods 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 230000004083 survival effect Effects 0.000 description 1
- 239000000341 volatile oil Substances 0.000 description 1
- 239000000080 wetting agent Substances 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
- 239000011592 zinc chloride Substances 0.000 description 1
- 235000005074 zinc chloride Nutrition 0.000 description 1
- NWONKYPBYAMBJT-UHFFFAOYSA-L zinc sulfate Chemical compound [Zn+2].[O-]S([O-])(=O)=O NWONKYPBYAMBJT-UHFFFAOYSA-L 0.000 description 1
- 229910000368 zinc sulfate Inorganic materials 0.000 description 1
- 229960001763 zinc sulfate Drugs 0.000 description 1
Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
Description
本発明は有害腹足類動物の駆除剤に関するもの
であり、更に詳くは、一般式
The present invention relates to a pest control agent for harmful gastropods, and more specifically, the present invention relates to an agent for controlling harmful gastropods.
【式】
（但し、Ｒは水素又はハロゲン原子を示す。）
にて示される２−メチルイソチアゾリン−３−オ
ン又は／及びその金属錯塩化合物からなる有害腹
足類動物駆除剤に係るものである。
有害軟体動物、特にナメグジ、カタツムリ、マ
イマイ等の腹足類は畑地、温室、庭園、厨房、家
屋、壁面、青果貯蔵所等のいたるところに出没し
て諸種の植物類の茎葉、果実、根茎あるいは紙、
木材等植物加工品を舐食し、多大なる損害を与え
ている。また、台所等の湿気のある場所に侵入
し、食物を食害する。それらに対して従来よりメ
タアルデヒド製剤が誘引剤として使用されている
が充分な効果を挙げ得ない欠点がある。
本発明者等は、有害腹足類動物であるナメク
ジ、カタツムリ、マイマイ等の駆除試験を行つた
結果、本発明に係る化合物が駆除効果の極めて高
いことを認めた。即ち、本発明の一般式にて示さ
れる化合物は、ナメクジ、カタツムリ、マイマイ
等を接触後、短期間のうちに殺滅せしめることを
認めた。
本発明の一般式に係る化合物は、工業用殺菌剤
として塗料、製紙、切削油、冷却用水素等の場面
において防菌、防黴を目的としてその用途が開発
されている。しかしながら本発明化合物は腹足類
動物の駆除作用についての開示は未だみられな
い。
前記一般式にて示される２−メチルイソチアゾ
リン−３−オン化合物としては、５−クロロ−２
−メチルイソチアゾリン−３−オン、２−メチル
イソチアゾリン−３−オン等が挙げられ、また、
これらと金属錯塩を形成せる金属塩としては、塩
化亜鉛、塩化マグネシウム、塩化カルシウム、硝
酸マグネシウム、塩化鉄、硫酸亜鉛、硫酸銅等が
挙げられる。
本発明化合物は、実際に使用するにあたつて
は、原体そのものを散布してもよく、通常の製剤
の如く、乳剤、粒剤、水和剤、水溶剤、液剤、ペ
ーストあるいは発泡剤などとしても使用できる。
又、補助剤、例えば、展着剤、乳化剤、湿展剤、
固着剤等の界面活性剤を混用して効果の確実を期
することは勿論好ましい。目的によつて他の殺菌
剤、殺虫剤、除草剤又は肥料等と混用して同時に
処理、施用することも可能である。麦皮、蛋白質
生成物、カゼイン、乾燥酵母および精油の如き天
然および合成誘引剤と組合せて誘引性駆除剤とす
ることもできる。
実施例 １
鉢もの植木育成場に樓息中のナメクジを供試し
て、散布試験を行つた。
本発明化合物を水で所定濃度に希釈し、小型噴
霧器を用いてナメクジの体によくかかるように散
布した。１区10頭とし３区反復した。調査は処理
後24時間目に生きているものの頭数及び死亡した
ものの頭数をかぞえた。試験期間中の気温は20〜
27℃であつた。[Formula] (However, R represents hydrogen or a halogen atom.)
This invention relates to a harmful gastropod repellent comprising 2-methylisothiazolin-3-one and/or its metal complex compound as shown in the following. Harmful molluscs, especially gastropods such as slugs, snails, and snails, infest fields, greenhouses, gardens, kitchens, houses, walls, fruit and vegetable storage areas, etc., and cause damage to the stems, leaves, fruits, rhizomes, and paper of various plants.
They lick wood and other processed plant products, causing great damage. They also invade humid areas such as kitchens and damage food. Metaldehyde preparations have conventionally been used as attractants for these, but they have the drawback of not being sufficiently effective. The present inventors conducted a test to exterminate harmful gastropods such as slugs, snails, and snails, and as a result, they found that the compound according to the present invention has an extremely high extermination effect. That is, it has been confirmed that the compound represented by the general formula of the present invention kills slugs, snails, snails, etc. within a short period of time after coming into contact with it. The compound according to the general formula of the present invention has been developed to be used as an industrial disinfectant for the purpose of antibacterial and antifungal applications in paints, paper manufacturing, cutting oil, cooling hydrogen, and the like. However, no disclosure has yet been made regarding the exterminating action of the compound of the present invention against gastropods. The 2-methylisothiazolin-3-one compound represented by the above general formula includes 5-chloro-2
-Methylisothiazolin-3-one, 2-methylisothiazolin-3-one, etc., and
Examples of metal salts that form metal complexes with these include zinc chloride, magnesium chloride, calcium chloride, magnesium nitrate, iron chloride, zinc sulfate, copper sulfate, and the like. When the compound of the present invention is actually used, the raw material itself may be sprayed, and it can be used in the form of emulsions, granules, wettable powders, aqueous solutions, liquids, pastes, or foaming agents, etc., as in conventional preparations. It can also be used as
In addition, auxiliary agents such as spreading agents, emulsifiers, wetting agents,
It is of course preferable to use a surfactant such as a fixing agent in order to ensure the effect. Depending on the purpose, it may be mixed with other fungicides, insecticides, herbicides, fertilizers, etc. and treated and applied at the same time. It can also be combined with natural and synthetic attractants such as wheat hides, protein products, casein, dried yeast and essential oils to form attractive pest control agents. Example 1 A spraying test was conducted using slugs in a potted plant nursery. The compound of the present invention was diluted with water to a predetermined concentration, and sprayed onto the slug's body using a small sprayer. The test was repeated for 3 sections with 10 animals per section. The survey counted the number of live and dead animals 24 hours after treatment. The temperature during the test period is 20~
It was 27℃.
【表】【table】
【表】
実施例 ２
本発明化合物のナメクジ、マイマイに対する効
果試験を行つた。
ナメクジには、ハタナメクジ（Agriolimax
agrestis）、マイマイにはウスカワマイマイ
（Eulota sieboldiana）を用いた。
供試化合物の所定濃度希釈液をそれぞれ噴霧処
理したのち径９cmの網蓋付き腰高シヤーレに放飼
し、処理24時間後の生死を調査した。対照無処理
は水を用いて散布したのち上記同様シヤーレに放
飼した。[Table] Example 2 An effect test of the compound of the present invention against slugs and snails was conducted. Slugs include the Japanese slug (Agriolimax)
agrestis) and the snail snail (Eulota sieboldiana) were used. After spraying a diluted solution of the test compound at a predetermined concentration, the animals were released into a waist-high cage with a mesh lid, 9 cm in diameter, and the animals were examined for survival or death 24 hours after the treatment. For the untreated control, the mice were sprayed with water and then released in a shear cage in the same manner as above.
【表】
実施例 ３
本発明化合物の1000倍、2000倍希釈液を鉢植え
栽培中のアサガオに寄生樓息しているウスカワマ
イマイに小型手押式噴霧器を用いて散布駆除試験
を行つた。調査は散布後24時間目に行い、散布前
の樓息数及び調査時の樓息数を調べ、これから駆
除率を算出した。[Table] Example 3 A 1000-fold and 2000-fold diluted solution of the compound of the present invention was sprayed and exterminated by using a small hand-held sprayer on the Usukawa snail, which was infesting a potted morning glory. The survey was conducted 24 hours after spraying, and the number of insects before spraying and the number of insects at the time of the survey were measured, and the eradication rate was calculated from this.
【表】
処理前 処理後
−
棲息数 棲息数
＊ 駆除率＝[Table] Before treatment After treatment
−
Number of habitats Number of habitats * Extermination rate =
Claims (1)
にて示される２−メチルイソチアゾリン−３−オ
ン又は／及びその金属錯塩化合物を有効成分とし
て含有することを特徴とする陸生の有害腹足類動
物駆除剤。[Claims] 1 General formula [Formula] (However, R represents hydrogen or a halogen atom.)
An agent for controlling harmful terrestrial gastropods, which contains 2-methylisothiazolin-3-one or/and its metal complex compound as an active ingredient.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP58150228A JPS6042307A (en) | 1983-08-19 | 1983-08-19 | Agent for controlling noxious mollusk |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP58150228A JPS6042307A (en) | 1983-08-19 | 1983-08-19 | Agent for controlling noxious mollusk |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS6042307A JPS6042307A (en) | 1985-03-06 |
| JPH048402B2 true JPH048402B2 (en) | 1992-02-17 |
Family
ID=15492342
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP58150228A Granted JPS6042307A (en) | 1983-08-19 | 1983-08-19 | Agent for controlling noxious mollusk |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS6042307A (en) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP3061348A1 (en) * | 2015-02-27 | 2016-08-31 | Kenogard, S.A. | Method for removing a plague of apple snail from a rice crop |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS545037A (en) * | 1977-06-13 | 1979-01-16 | Katayama Chemical Works Co | Gell state preparation for controlling harmful organism in sea water |
-
1983
- 1983-08-19 JP JP58150228A patent/JPS6042307A/en active Granted
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS545037A (en) * | 1977-06-13 | 1979-01-16 | Katayama Chemical Works Co | Gell state preparation for controlling harmful organism in sea water |
Also Published As
| Publication number | Publication date |
|---|---|
| JPS6042307A (en) | 1985-03-06 |
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