JPH047988Y2 - - Google Patents

Info

Publication number
JPH047988Y2
JPH047988Y2 JP1984193475U JP19347584U JPH047988Y2 JP H047988 Y2 JPH047988 Y2 JP H047988Y2 JP 1984193475 U JP1984193475 U JP 1984193475U JP 19347584 U JP19347584 U JP 19347584U JP H047988 Y2 JPH047988 Y2 JP H047988Y2
Authority
JP
Japan
Prior art keywords
layer
heat
support
sensitive
release paper
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
JP1984193475U
Other languages
Japanese (ja)
Other versions
JPS61107574U (en
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed filed Critical
Priority to JP1984193475U priority Critical patent/JPH047988Y2/ja
Priority to US06/767,432 priority patent/US4711874A/en
Priority to DE19853529781 priority patent/DE3529781A1/en
Priority to GB08520857A priority patent/GB2163562B/en
Publication of JPS61107574U publication Critical patent/JPS61107574U/ja
Application granted granted Critical
Publication of JPH047988Y2 publication Critical patent/JPH047988Y2/ja
Expired legal-status Critical Current

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  • Heat Sensitive Colour Forming Recording (AREA)

Description

【考案の詳細な説明】 〔技術分野〕 本考案は感熱記録型剥離紙に関する。[Detailed explanation of the idea] 〔Technical field〕 The present invention relates to a heat-sensitive recording release paper.

〔従来技術〕[Prior art]

感熱記録材料は、加熱によつて発色するいわゆ
る感熱発色層を紙、合成紙又は樹脂フイルム等の
支持体上に形成した構造の記録材料であつて、そ
の発色のための加熱にはヘツドを内蔵したサーマ
ルプリンター等が用いられる。このような記録材
料は、他の記録材料に比較して現像、定着等の煩
雑な処理を施すことなく比較的短時間で記録が得
られること、騒音の発生がないこと、比較的安価
である等の利点により図書、文書などの複写は勿
論のこと、電子計算機、フアクシミリ、テレツク
ス、医療計測機等の種々の情報並びに計測機器の
記録材料、又、駅務システムの乗車券や百貨店、
マーケツト等のPOSシステムのラベルとしても
広く使用されている。感熱記録型剥離紙は、表面
に加熱方式により印字や画像の記録を行うことが
でき、記録画像形成後の剥離紙を仮着されていた
剥離台紙から剥離して、所望の固体表面に対して
接着することのできるシートを意味し、番号札、
値札、薬ビン札などの各種ラベルやレツテルの
他、ネームプレート、シール等に利用されてい
る。
A thermosensitive recording material is a recording material with a structure in which a so-called thermosensitive coloring layer that develops color when heated is formed on a support such as paper, synthetic paper, or resin film, and has a built-in head for heating to develop the color. A thermal printer or the like is used. Compared to other recording materials, such recording materials can produce records in a relatively short time without complex processes such as development and fixing, do not generate noise, and are relatively inexpensive. Due to these advantages, it is useful not only for copying books and documents, but also for recording materials for various information and measuring instruments such as electronic computers, facsimiles, telex, medical measuring instruments, etc., as well as train tickets for station management systems, department stores, etc.
It is also widely used as a label for POS systems such as markets. Thermal recording type release paper allows printing and images to be recorded on the surface using a heating method, and after the recorded image has been formed, the release paper is peeled off from the release liner to which it has been temporarily attached, and then applied to the desired solid surface. Refers to sheets that can be glued together, such as number tags,
It is used for various labels such as price tags and medicine bottle tags, labels, name plates, stickers, etc.

一般に、剥離紙は、図案、線、文字等を予め印
刷しておくことが望まれる場合が多く、このよう
な場合、従来は、最上層にある感熱発色層又は保
護層に固体もしくは液体インクによる所望のパタ
ーンを印刷していた。しかしながら、これが感熱
記録型剥離紙の場合、サーマルヘツドで印字する
と、インクの印刷パターンがサーマルヘツドに接
触するためヘツドが汚れ易く、その結果、ヘツド
へのカス付着や熱印字部の汚れ(尾びき等)が生
じるという問題があつた。
Generally, it is often desirable to print patterns, lines, characters, etc. on release paper in advance, and in such cases, conventionally, the topmost heat-sensitive coloring layer or protective layer is printed with solid or liquid ink. The desired pattern was printed. However, in the case of heat-sensitive recording release paper, when printing with a thermal head, the ink print pattern comes into contact with the thermal head, making the head easily dirty.As a result, residue adheres to the head and the thermal printing area becomes dirty (tailing). etc.) occurred.

〔目的〕〔the purpose〕

本考案は、印刷パターンによるサーマルヘツド
の汚れや印字部の汚れが生じない上、インクの支
持体への浸み込みによる印刷パターンの滲みやイ
ンクの感熱発色層への浸み込みによる感熱発色層
の発色(地肌発色)もない感熱記録型剥離紙を提
供することを目的とする。
This invention eliminates staining of the thermal head and printing area due to the printed pattern, and prevents the printed pattern from bleeding due to the ink seeping into the support, and preventing the thermal coloring layer from smearing due to the ink seeping into the heat-sensitive coloring layer. An object of the present invention is to provide a heat-sensitive recording type release paper that does not develop any color (ground color).

〔構成〕〔composition〕

本考案によれば、支持体の裏面に設けたバツク
コート層の表面に固体又は液体インクによる印刷
パターンを形成し、その上に接着剤層を設けると
共に、支持体の表面に感熱発色層並びに、必要に
応じ、その上に水溶性高分子保護層及び/又は支
持体と感熱発色層との間にアンダーコート層を設
け、更に該接着剤層を剥離台紙に仮着してなる感
熱記録型剥離紙が提供される。
According to the present invention, a printing pattern is formed using solid or liquid ink on the surface of the back coat layer provided on the back surface of the support, an adhesive layer is provided thereon, and a heat-sensitive coloring layer and the necessary Depending on the requirements, a water-soluble polymer protective layer and/or an undercoat layer is provided between the support and the heat-sensitive coloring layer, and the adhesive layer is temporarily attached to a release mount. is provided.

本考案においては、支持体の裏面(剥離台紙
側)に設けた水溶性高分子又は疎水性高分子を主
成分とするバツクコート層に固体又は液体インク
による線、図形、絵等の印刷パターンを形成させ
る。支持体は、該印刷パターンが感熱発色層側か
ら透視もしくは認識できるものであれば任意のも
のを用いることができ、紙、フイルム等が通常用
いられる。印刷パターンはいかなるものでもよ
く、白ヌキ印刷やベタ印刷とすることもできる。
In this invention, printing patterns such as lines, figures, pictures, etc. are formed using solid or liquid ink on the back coat layer, which is mainly composed of water-soluble polymers or hydrophobic polymers, and is provided on the back side of the support (release mount side). let Any support can be used as long as the printed pattern can be seen through or recognized from the heat-sensitive coloring layer side, and paper, film, etc. are usually used. The printing pattern may be of any type, and may be white blank printing or solid printing.

本考案に適用される感熱発色層としては、種々
のものが使用でき、例えば、次のような熱発色系
が採用できる。
Various types of heat-sensitive coloring layers can be used as the heat-sensitive coloring layer applied to the present invention, and for example, the following heat-coloring systems can be employed.

(1) ステアリン酸第2鉄、ミステリン酸第2鉄の
ような長鎖脂肪族鉄塩と、タンニン酸、没食子
酸、サリチル酸アンモニウムのようなフエノー
ル類との組合せからなる熱発色系。
(1) A thermochromic system consisting of a combination of long-chain aliphatic iron salts such as ferric stearate and ferric mysterate and phenols such as tannic acid, gallic acid, and ammonium salicylate.

(2) 銀、鉛、水銀、トリウムの硫酸塩のような重
金属硫酸塩と、Na−テトラチオネート、チオ
硫酸ソーダ、チオ尿素のような硫黄化合物との
組合せからなる熱発色系。
(2) A thermochromic system consisting of a combination of heavy metal sulfates, such as silver, lead, mercury, and thorium sulfates, and sulfur compounds, such as Na-tetrathionate, sodium thiosulfate, and thiourea.

(3) ベヘン酸銀、ステアリン酸銀のような有機酸
貴金属塩と、プロトカテキン酸、スピロインダ
ン、ハイドロキノンのような芳香族有機還元剤
との組合せからなる熱発色系。
(3) A thermochromic system consisting of a combination of a noble metal salt of an organic acid such as silver behenate or silver stearate and an aromatic organic reducing agent such as protocatechuic acid, spiroindane, or hydroquinone.

(4) カプロン酸鉛、ベラルゴン酸鉛、ベヘン酸鉛
のような有機酸鉛塩とエチレンチオ尿素、N−
ドデシルチオ尿素のようなチオ尿素誘導体との
組合せからなる熱発色系。
(4) Organic acid lead salts such as lead caproate, lead belargonate, and lead behenate and ethylenethiourea, N-
A thermochromic system consisting of a combination with a thiourea derivative such as dodecylthiourea.

(5) ロイコ染料と顕色剤との組合せからなる熱発
色系。
(5) A thermochromic system consisting of a combination of leuco dye and color developer.

鮮明な発色画像を与える点で、上記(5)の発色系
が好ましく用いられる。
The above coloring system (5) is preferably used because it provides a clear colored image.

本考案を次に図面により詳細に説明する。 The invention will now be explained in detail with reference to the drawings.

第1図は本考案による感熱記録型剥離紙の斜視
説明図、及び第2図は第1図のX−X′部分断面
図である。図中、2は支持体で、その上にアンダ
ーコート層7、感熱発色層1及び水溶性高分子保
護層6がその順に塗設、積層されている。尚、こ
のアンダーコート層7及び保護層6は、必要に応
じて設けられるもので、両方又はどちらか一方を
省くこともできる。
FIG. 1 is a perspective explanatory view of a heat-sensitive recording type release paper according to the present invention, and FIG. 2 is a partial sectional view taken along line X-X' in FIG. In the figure, 2 is a support, on which an undercoat layer 7, a thermosensitive coloring layer 1, and a water-soluble polymer protective layer 6 are coated and laminated in that order. Note that the undercoat layer 7 and the protective layer 6 are provided as necessary, and either or both can be omitted.

支持体2の下面にはバツクコート層8を介して
印刷パターン5が形成され、その表面に接着剤層
3が設けられている。4は剥離台紙であつて、一
方の表面にシリコーン樹脂等の被膜(図示せず)
を有し、そこに接着剤層3により上記構成の感熱
紙が仮着される。
A printed pattern 5 is formed on the lower surface of the support 2 via a back coat layer 8, and an adhesive layer 3 is provided on the surface thereof. 4 is a release mount, one surface of which is coated with silicone resin or the like (not shown)
The thermal paper having the above structure is temporarily attached thereto by the adhesive layer 3.

〔効果〕〔effect〕

本考案の感熱記録型剥離紙は、上記の如く構成
したことにより、熱記録時における印刷パターン
によるヘツドマツチング性低下の問題は皆無であ
る。又、バツクコート層を設けたことにより、例
えば水や有機溶剤に接した場合等において、イン
クが支持体や感熱発色層に浸み込むことが防止さ
れ、これにより、インクの滲みや感熱発色層の発
色(地肌発色)が皆無となる。更に、印刷パター
ンは表面から目視、判読できる。
Since the heat-sensitive recording type release paper of the present invention is constructed as described above, there is no problem of deterioration of head matching properties due to the printed pattern during thermal recording. In addition, by providing a back coat layer, the ink is prevented from penetrating into the support and the thermosensitive coloring layer when it comes into contact with water or organic solvents, thereby preventing ink bleeding and the heatsensitive coloring layer. There is no color development (color development on the skin). Furthermore, the printed pattern is visible and readable from the surface.

【図面の簡単な説明】[Brief explanation of drawings]

第1図は本考案による感熱記録型剥離紙の一例
を示す斜視図、及び第2図は第1図のX−X′部
分断面図である。 1……感熱発色層、2……支持体、3……接着
剤層、4……剥離台紙、5……印刷パターン、6
……保護層、7……アンダーコート層、8……バ
ツクコート層。
FIG. 1 is a perspective view showing an example of a heat-sensitive recording type release paper according to the present invention, and FIG. 2 is a partial sectional view taken along line X-X' in FIG. DESCRIPTION OF SYMBOLS 1...Thermosensitive coloring layer, 2...Support, 3...Adhesive layer, 4...Peelable mount, 5...Print pattern, 6
...Protective layer, 7...Undercoat layer, 8...Back coat layer.

Claims (1)

【実用新案登録請求の範囲】[Scope of utility model registration request] 支持体の裏面に設けたバツクコート層の表面に
固体又は液体インクによる印刷パターンを形成
し、その上に接着剤層を設けると共に、支持体の
表面に感熱発色層並びに、必要に応じ、その上に
水溶性高分子保護層及び/又は支持体と感熱発色
層との間にアンダーコート層を設け、更に該接着
剤層を剥離台紙に仮着してなる感熱記録型剥離
紙。
A printing pattern is formed using solid or liquid ink on the surface of the back coat layer provided on the back side of the support, and an adhesive layer is provided on the back coat layer. A heat-sensitive recording type release paper comprising an undercoat layer provided between a water-soluble polymer protective layer and/or support and a heat-sensitive color forming layer, and the adhesive layer temporarily attached to a release mount.
JP1984193475U 1984-08-20 1984-12-20 Expired JPH047988Y2 (en)

Priority Applications (4)

Application Number Priority Date Filing Date Title
JP1984193475U JPH047988Y2 (en) 1984-12-20 1984-12-20
US06/767,432 US4711874A (en) 1984-08-20 1985-08-20 Thermosensitive recording adhesive sheet
DE19853529781 DE3529781A1 (en) 1984-08-20 1985-08-20 HEAT-SENSITIVE ADHESIVE RECORDING MATERIAL
GB08520857A GB2163562B (en) 1984-08-20 1985-08-20 Adhesive thermosensitive recording sheet

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP1984193475U JPH047988Y2 (en) 1984-12-20 1984-12-20

Publications (2)

Publication Number Publication Date
JPS61107574U JPS61107574U (en) 1986-07-08
JPH047988Y2 true JPH047988Y2 (en) 1992-02-28

Family

ID=30750900

Family Applications (1)

Application Number Title Priority Date Filing Date
JP1984193475U Expired JPH047988Y2 (en) 1984-08-20 1984-12-20

Country Status (1)

Country Link
JP (1) JPH047988Y2 (en)

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5626272B2 (en) * 1975-01-20 1981-06-17
JPS5769091A (en) * 1980-10-17 1982-04-27 Ricoh Co Ltd Peel-off type heatsensitive recording paper
JPS5853484A (en) * 1981-09-26 1983-03-30 Mitsubishi Paper Mills Ltd Chemical-resistant heat-sensitive paper
JPS58203092A (en) * 1982-05-24 1983-11-26 Ricoh Co Ltd Heat-sensitive recording sheet
JPS599091A (en) * 1982-07-09 1984-01-18 Ricoh Co Ltd Heat-sensitive recording sheet
JPS5933181A (en) * 1982-08-18 1984-02-22 Mitsubishi Paper Mills Ltd Heat-sensitive recording type ticket paper

Family Cites Families (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS49120242U (en) * 1973-01-06 1974-10-15
JPS52141951U (en) * 1976-04-22 1977-10-27
JPS52152746U (en) * 1976-05-17 1977-11-19
JPS55113559U (en) * 1979-02-06 1980-08-09
JPS5626272U (en) * 1979-08-03 1981-03-11
JPS57174067U (en) * 1981-04-27 1982-11-02
JPS58196162U (en) * 1982-06-25 1983-12-27 株式会社リコー Thermal recording release paper

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5626272B2 (en) * 1975-01-20 1981-06-17
JPS5769091A (en) * 1980-10-17 1982-04-27 Ricoh Co Ltd Peel-off type heatsensitive recording paper
JPS5853484A (en) * 1981-09-26 1983-03-30 Mitsubishi Paper Mills Ltd Chemical-resistant heat-sensitive paper
JPS58203092A (en) * 1982-05-24 1983-11-26 Ricoh Co Ltd Heat-sensitive recording sheet
JPS599091A (en) * 1982-07-09 1984-01-18 Ricoh Co Ltd Heat-sensitive recording sheet
JPS5933181A (en) * 1982-08-18 1984-02-22 Mitsubishi Paper Mills Ltd Heat-sensitive recording type ticket paper

Also Published As

Publication number Publication date
JPS61107574U (en) 1986-07-08

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