JPS5933181A - Heat-sensitive recording type ticket paper - Google Patents
Heat-sensitive recording type ticket paperInfo
- Publication number
- JPS5933181A JPS5933181A JP57143013A JP14301382A JPS5933181A JP S5933181 A JPS5933181 A JP S5933181A JP 57143013 A JP57143013 A JP 57143013A JP 14301382 A JP14301382 A JP 14301382A JP S5933181 A JPS5933181 A JP S5933181A
- Authority
- JP
- Japan
- Prior art keywords
- heat
- printing
- water
- sensitive
- ticket paper
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
- B41M5/26—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used
- B41M5/40—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used characterised by the base backcoat, intermediate, or covering layers, e.g. for thermal transfer dye-donor or dye-receiver sheets; Heat, radiation filtering or absorbing means or layers; combined with other image registration layers or compositions; Special originals for reproduction by thermography
- B41M5/42—Intermediate, backcoat, or covering layers
- B41M5/44—Intermediate, backcoat, or covering layers characterised by the macromolecular compounds
Abstract
Description
【発明の詳細な説明】
本発明社乗車外、回数券、定期券、等に有用な感熱記録
製券紙に係る。DETAILED DESCRIPTION OF THE INVENTION The present invention relates to a heat-sensitive recording ticket paper useful for non-boarding, coupon tickets, commuter passes, etc.
さらに詳しくは、感熱記録方式になる乗車券、回数券、
□定期券、等における印刷特性の改良に関する。
□
近年、旅行、通勤において乗車券、回数券、定期券、□
等の利用者が増大しておシ、・特に国電、私鉄、地下鉄
、等の都市交通網の発達している首都圏並びに大阪圏を
中心にその増大は著しい。For more details, please refer to thermal-recording tickets, coupon tickets,
□Related to improvements in printing characteristics for commuter passes, etc.
□ In recent years, for travel and commuting, tickets, coupon tickets, commuter passes, □
The number of users is increasing, especially in the Tokyo metropolitan area and the Osaka area, where urban transportation networks such as national electric lines, private railways, and subways are well-developed.
この為、これらの乗車券、回数券並びに定期券、等のチ
ケッ□ト（社）類作成に要される人員、並びに時間が漱
増しておシーこうしたととからこれらのチケット類の自
動販売化が検討され、一部では既に実用化されている。For this reason, the number of people and time required to create tickets such as train tickets, coupon tickets, and commuter passes has increased dramatically, making it difficult to sell these tickets automatically. have been studied, and some have already been put into practical use.
□
□従来のチケット類の印字配録方式としては電子写真方
式、□静電配録方式、２成分による化学反応を利用した
ジアゾ複写方式、キレート発色方式、或いは各種色イン
キを用いる印刷方式等が利用され七・いた。しかしな々
ｔらこれら従来の記録方式を自動販売機に採用した場合
には、現像、定着工程が必要とされ、□この為自動販売
機の印字機構が複雑で大きくな夛、これを内蔵した機械
本体も大型化、コスト高となりたシ、或いは印刷方式に
よるものはインキを使用するた込牟乾きメ植ンキが□手
に付着したシ、衣月ｉが汚□′□′□：□′れたシす不
等の次点が：・あった。 ：、、、、：′、□
□′□ ■。□ □ Conventional printing methods for tickets include electrophotography, □ electrostatic printing, diazo copying using a chemical reaction between two components, chelate coloring, and printing using various colored inks. I was taken advantage of. However, when these conventional recording methods are used in vending machines, developing and fixing processes are required, and for this reason, the printing mechanism of vending machines is complicated and large. The main body of the machine has become larger and the cost has increased, or the printing method uses ink. The unequal runner-up was:・There was. ：、、、、：′、□
□′□ ■.
９の士うな欠点を改、善する為に、単に加熱す乏だけで
鮮明々Σ発色記録の苛能雇染料ロイコ体と酸性物質を発
色成分□としで用いた感熱記録 □方式を採用す鼠２
とが試みられ゛て来ｉおシ、それに：よって上述の欠点
を解消する上では大きな効果があうたが、なお以下の如
き問題が残されている。 □
一般に回数券、定期券、は有効期間が３ケ月ないし６ケ
月と長くこの間透明樹脂製フィルム懲戒いは透明樹脂製
の芒イフ或□いは定期合れそ保管されて使用されるが：
回数券、定期−のｉ録に感熱記録方式が採用された場合
には、該方式で記録された感熱発色層の発色部と透明樹
脂フィルム層中に存在する可塑剤、例えはジオクチルア
ジペイ） （ＤＯＰ）或いはジオクチルアジペイ）（Ｄ
ＯＡ）との相互作用によシ発色部が消色され、実用に耐
え得なかった。In order to improve the disadvantages of 9, we adopted a heat-sensitive recording method using caustic dye leuco substance and acidic substance as color-forming ingredients, which can produce clear Σ color recording simply by heating. 2
Although many attempts have been made to overcome the above-mentioned drawbacks, the following problems still remain. □ Generally, coupon tickets and commuter passes have a long validity period of 3 to 6 months, during which time they are stored in a transparent resin film, a transparent resin awning case, or a commuter pass.
When a heat-sensitive recording method is adopted for the i-recording of coupon tickets and commuter passes, the plasticizer present in the coloring part of the heat-sensitive coloring layer and the transparent resin film layer recorded by the method, such as dioctylazipei) (DOP) or dioctyl adipei) (D
Due to the interaction with OA), the colored part was decolored and could not be put to practical use.
この可塑剤による発色部の消色を防ぐために“ 感熱
発色層上に有機溶媒に可溶な有機四指被覆・、、、、ど
璽榊を設けたシ、水溶性高分子化合物の被覆層を、！ｔ
ｆｆＡｊｉ’下竺、−：行′６１“号？、、。In order to prevent the color development area from being discolored by the plasticizer, a coating layer of a water-soluble polymer compound is provided on the heat-sensitive color development layer. ,!t
ffAji'bottom, -: line '61''?...
一方乗車券類は使用される各電鉄会社により、各々異な
った乗車赤類への地紋印刷ががされている。On the other hand, different background patterns are printed on tickets, depending on the railway company that uses them.
この地紋印刷について述べれば、印刷インキは一□般に
乾燥の□はやい有機溶剤可溶タイプのインキが用いられ
る。しかしこの有機溶剤可溶夛イブのインキでは水性塗
工になる感熱層や水溶性高分子化合物か七′カる被覆層
に地紋印刷を□行なうと、イレ瑯が感熱：膚や、’ １
．、 ’ＦＪｔＪ、覆門に仰−に、のらなかった夛、感
熱層を発色にせたカ、あるい□ □、・、 −，１
・１．１
は減感させｆＣ，！ｌｌするという支障が生ずる。Regarding this tint pattern printing, printing ink is generally an organic solvent-soluble type ink that dries quickly. However, with this organic solvent-soluble ink, when tint pattern printing is performed on a water-based heat-sensitive layer or a water-soluble polymer compound coating layer, the surface of the ink becomes heat-sensitive: skin, etc.
．． , 'FJtJ, the one who didn't get on the cover gate, the one who made the heat-sensitive layer colored, or □ □, ・, -, 1
・1.1 desensitizes fC,! This will cause a problem.
したがって本発明における印刷においては、使用するイ
ンキは水溶性樹脂もしくは水性エマルジョン樹脂を含む
物が好ましい。Therefore, in printing in the present invention, the ink used preferably contains a water-soluble resin or an aqueous emulsion resin.
また、感熱発色層の上へ水溶性高分子化合物の被覆層を
設けこの上に地紋印刷を行なった場命印刷時のインキの
吸収かわる（、また印刷後ぬれた指先でこすると地紋印
刷が落ちると給う欠点がある。 、 ・
・、こ９ため被覆層顛無機顔料類を添加し、インキ吸収
をはやめたシ、・インキ組成物中の樹脂分に耐水性のめ
るアクリル系樹脂を用いることでイ、ンキ吸収性や水ぬ
れによるインキの色落ちを改良するという試＋４おこな
われている。In addition, a coating layer of a water-soluble polymer compound is placed on top of the heat-sensitive coloring layer, and the ink absorption during printing is changed by printing a tint pattern on top of this (and if you rub it with a wet fingertip after printing, the tint pattern print will come off). For this reason, inorganic pigments are added to the coating layer to prevent ink absorption, and acrylic resin is used to add water resistance to the resin component of the ink composition. , +4 trials have been conducted to improve ink absorption and ink color fading due to water exposure.
１Ｌ−力゛１・被覆層に無機顔料類を苗゛カロしてイ２
キ吸収性を数珠するには添加量もある程度の量以上入れ
ないと効果はす、＜、また添加することによシ逆に可塑
剤が被覆層に入ってきて、・発色部を消色してしまう欠
点ｔｒ＝ｈる。またアクリル系樹脂を用いたインチを使
用することで、水ぬれによるインキの色落ちは改良され
る。しかし、アクリル系樹脂を吊輪たインキ、で地紋印
刷をした券紙類を券売機にて発券すると１．、地紋印刷
に使用したインキが券売機のサーマルヘッ、ドに付着ｊ
、ｆｃ 夛、ステッキングをおこルたシ：して、発券時
の印字陣容となる。 ・ 。1L - Power (1) Add inorganic pigments to the coating layer (2)
In order to increase the absorbency, it will not be effective unless you add more than a certain amount.Additionally, adding plasticizer will cause the plasticizer to enter the coating layer and erase the coloring area. The disadvantage of tr=h. Furthermore, by using an inch made of acrylic resin, the color fading of the ink due to wetting with water is improved. However, when a ticket machine prints a background pattern using acrylic resin-based ink and issues it with a ticket vending machine, 1. , the ink used for background pattern printing is attached to the thermal head of the ticket vending machine.
, fc 夛, stickering is performed and becomes the printing lineup at the time of ticket issuance.・ .
このため、・、本発明者は更に研究を進め、可塑剤によ
る発色部の消色を防ぐために感熱・層の上に水溶性高分
子化合物の被覆層・を、設けるタイプの巻紙類の地紋印
刷については、感熱層、の上に直接水溶性樹脂を含むイ
ンキによる印刷を施し、次いでその上に被覆層を設ける
ことによシ、可塑剤によ・る・発色部の消色も防ぎ・、
水濡れによるインキの色落ちも無（印字障害も・無い、
上述の問題点が全て解消さ・れた感熱記録型券紙が得ら
・れる・ごとが判明し、曽木発明を成すに至り・た。For this reason, the present inventor conducted further research and conducted background pattern printing on wrapping paper of a type in which a coating layer of a water-soluble polymer compound is provided on the heat-sensitive layer in order to prevent the colored part from being discolored by the plasticizer. For this purpose, printing is performed directly on the heat-sensitive layer using an ink containing a water-soluble resin, and then a coating layer is provided on top of the heat-sensitive layer to prevent decolorization of the colored area due to plasticizers.
No fading of ink due to water exposure (no printing problems,
It was discovered that a heat-sensitive recording ticket paper could be obtained which solved all of the above-mentioned problems, leading to Sogi's invention.
即ち本発明は、支持体上に設けた通常無色又・は淡、色
の・染・料ｉ・、イコ体と加熱によル該ロイコ体・□を
発色させる酸性物質とを、発色成分として含有する感熱
発色・・層、上に・、・水溶性樹脂もしぐは水性上・÷
ルジ□ｌｌｌ□１〕・樹脂を含む水性イ、・ンキ・に、
よる印刷□・を施し、・次・いて・その上に被覆層を設
けたことを特徴とする感熱記録型券紙を提供するもので
あ、る。 ：・・ □□ｉ−，−□□ ・
： □本発明について更に記述すると、・、・感熱記
録型券紙に使用される通、・常無色又はやや淡色の染料
口イコ体としては、トリフェニルメタン系、フルオラン
系、フェノチアニシン系、オニシ建ン基、スピロピラン
系染料のｐイシ体でアシ、これには例、ｔば、３．３−
ビス（Ｐ−ジメチルナミノフェニル）−６ニジノチ宛ア
ミノラタリド、３．３−ビス（’Ｐ−ジメチルナミノフ
エエル）フタリド、３，３−ビス（Ｉ’−ジメチルアミ
：ノフェニル）−６−ジニチルアミノフ□タリド、３．
３ ＝ ヒス（Ｐ−ジエチルアミノズエニ１）−６−ク
ロロフタリド、３−’（ｕ＝Ｐ−トリル−Ｎ−エチルア
ミ／）−６−メチル−７−（Ｎ−フェニルアミノ）フル
オラン、３．−ジエチルアミ□ノー６−メテルー７−ア
ニリノフルオラン、３−ジエチルアミノ−７−クロロフ
ルオラン、３−ジエチルアミノ−７ｆ−（３−ｊｔｑオ
シチ、ニル）フェニルアミノフルオラン、ペンライルロ
イコメｊレンブルー、６′−クロμｍ８′−メトキシ−
ベンゾインドリノ−ビリロスビラ７．６’−プロキーｉ
′−メトキシーペンゾイント旬ノービリロスビラン、２
−（３，６−ビス（ジエチルアミノ）−９−（δ二りｍ
＆アニリノ）キ垂ジチル〕□安息香酸う゛レタ―などが
拳けら・れる。・ ・−・・□・・又、前妃築料ロ′イ
ブ体と熱時発色反応を起し、該ｉイコ体を発色せしめ名
酸性物賀どしては例□えば、□′ａ１」デフドール、→
ニチ７）ニル、□・４−ｔ−ブチルフェノール、４−１
−オクチルフェノール、２，２−ビス（Ｐ−ヒドロキシ
２霊□ニル）プロパン、２．２′−ビス（Ｐニヒドロ亭
しフェニル）ブタン、４．４’−−／り’ｃｔへΦシリ
デンジフェノール；２，２−ビス（２，５−ジブロム−
４−ヒドロキシフェニル）プロパン、４．４’−イソグ
ロビリデンビ玉（２−′ｔ−ブナ′ルフェノール）、２
、２’ −スチレンビス（４ニクロ□ロフエノール）、
安息香酸、□サリチル酸、泗石酸、没食子酸等が挙げら
れ名。−□
以上の発色成分を結合剤とともに感熱発色層ｉ液と成し
、支ｉ体上に塗布、乾燥口感熱発色；―を綬ける□。
□ −□
結合剤としては例えば以下のよう□な本の・が挙げら１
れる♂ ・′ □ ・ポリビニルアルコール
、メトキシセルロース、ヒドロキシエチルセル四−ス、
カルボキシメチルセルロース、ポリビニルピロリドン、
ポリアクリルアミド、ポリアクリル酸、デンプン、ゼラ
チン、メチルセルロースなどの水溶性のもの、あるいは
ポリスチレン、塩化ビニル−酢酸ビニル共重合体、ポリ
ブチルメタクリレート、スチレンブタジェンラテックス
などのような水性エマルジョン樹脂。That is, the present invention uses a usually colorless or light colored dye i, which is provided on a support, as a coloring component, and an acidic substance that causes the leuco form to develop color when heated. Contains heat-sensitive coloring...layer, on top...water-soluble resin or water-based layer/÷
water-based resin containing resin,
The present invention provides a heat-sensitive recording type ticket paper, which is characterized in that it has been printed with □, and then has a coating layer thereon. ：・・ □□i−，−□□ ・
： □To further describe the present invention,... Normally colorless or slightly light-colored dyes used in heat-sensitive recording ticket paper include triphenylmethane, fluoran, phenothianisine, Onishi group, p-isomer of spiropyran dye, for example, t, 3.3-
Bis(P-dimethylnaminophenyl)-6-dinithylaminophthalide, 3,3-bis('P-dimethylnaminophthalide) phthalide, 3,3-bis(I'-dimethylaminophenyl)-6-dinithylaminophthalide, 3.
3 = His(P-diethylaminozueni1)-6-chlorophthalide, 3-'(u=P-tolyl-N-ethylami/)-6-methyl-7-(N-phenylamino)fluoran, 3. -diethylamino-7-anilinofluorane, 3-diethylamino-7-chlorofluorane, 3-diethylamino-7f-(3-jtq-ocyti,yl)phenylaminofluorane, penlyl leucomelene blue, 6'-Chloμm8'-Methoxy-
Benzoindolino-virirosvira 7.6'-prokyi
′-Methoxypenzoint seasonal nobilirosviran, 2
-(3,6-bis(diethylamino)-9-(δ2m
& Anilino) Kitare dithyl] □ Benzoic acid ゛ letter, etc. are punched.・ ・－・・□・・It also causes a color reaction when heated with the former Ico compound, causing the Ico compound to develop color, and is used as a famous acidic compound, for example, □'a1. Def Doll →
7) Nil, □・4-t-butylphenol, 4-1
-octylphenol, 2,2-bis(P-hydroxy2-hydroxyphenyl)propane, 2,2'-bis(P-nihydroteiphenyl)butane, Φcylidene diphenol to 4.4'-/ri'ct; 2,2-bis(2,5-dibromo-
4-hydroxyphenyl)propane, 4,4'-isoglopylidene (2-'t-bunalphenol), 2
, 2'-styrene bis(4nicro□lophenol),
Names include benzoic acid, salicylic acid, saccharic acid, and gallic acid. -□ Form a heat-sensitive color-forming layer I liquid with the above color-forming components together with a binder, apply it on the support body, and apply dry mouth heat-sensitive color development.
□ −□ Examples of binding agents include books such as □ below.1
♂ ・′ □ ・Polyvinyl alcohol, methoxycellulose, hydroxyethyl cellulose,
Carboxymethylcellulose, polyvinylpyrrolidone,
Water-soluble ones such as polyacrylamide, polyacrylic acid, starch, gelatin, methyl cellulose, or water-based emulsion resins such as polystyrene, vinyl chloride-vinyl acetate copolymer, polybutyl methacrylate, styrene-butadiene latex, etc.
なお、上記感熱発色層中に、通常用いられている填料、
潤滑剤、等の添加剤を用いてもよい。In addition, in the heat-sensitive coloring layer, commonly used fillers,
Additives such as lubricants may also be used.
以上の感熱発色層上に水溶性樹脂もしくは水性エマルジ
ョン樹脂を含む水性インキによる印刷特に地紋印刷を施
す。Printing, especially tint pattern printing, is performed on the above heat-sensitive coloring layer using a water-based ink containing a water-soluble resin or a water-based emulsion resin.
次いで、印刷面の上に水溶性高分子化合物からなる被覆
層を形成させる。該層を形成する水溶性高分子化合物と
しては、ポリビニルアルコール、メチルセルロース、カ
ルボキシメチルセルロース、デンプン、デンプン誘導体
、ポリビニルピロリドン、ゼラチン、イソブチレン−無
水マレイン酸共重合体、アルギン鹸ソーダ等が挙げられ
る。Next, a coating layer made of a water-soluble polymer compound is formed on the printed surface. Examples of the water-soluble polymer compound forming the layer include polyvinyl alcohol, methylcellulose, carboxymethylcellulose, starch, starch derivatives, polyvinylpyrrolidone, gelatin, isobutylene-maleic anhydride copolymer, alginic soda, and the like.
以下に本発明の実施例を示す。□
実施−Ｆ□・ □ ・・・ □ ・
。Examples of the present invention are shown below. □ Implementation-F□・ □ ・・・ □ ・
.
下記配合のム液並びにＢ液を□そパぞれ別々にアトライ
ｉ−を用いてｉ詩画分：散じ是後混□合して、感熱発色
層塗液とし、これを支持体に乾燥塗布量が７ ｊ’／ｒ
ｔｌと々る様に塗布、乾燥して感熱発色層を形成した。□ Sprinkle the liquid and B liquid of the following composition separately using Atry i-, then mix them to make a heat-sensitive coloring layer coating liquid, and dry coat this on the support. The amount is 7 j'/r
It was applied in a rapid manner and dried to form a heat-sensitive coloring layer.
Ａ液；
ブラック発色染料ロイコ体
ＦＢＩ）−１５０（新旧曹化工）２．０重量部炭酸カル
シウム １０重量部２０％ポリビニルア
ルコール水溶液 ２５重量部Ｂ液液
；スフェノールＡ ５．０重量部ステア
リン酸アミド ３．０重鐘部２０チボリビニ
ルアルコール水溶液 ２．０重量部水
１４重音部次に、上述の感熱層
上にカルボキシメチルセル、ロニロを含む水性の色イン
喫でグラビア印刷方式により乗車券用地紋印刷を行ない
、更に速覆層形成に用いる。塗液を以下の組、成として
、乾燥時塗布量２．５１１／ｌｒｌとネる工う（塗布、
乾燥して被覆ｊｊを形成し本発明の感熱記録型券紙を作
製した。Liquid A: Black coloring dye leuco body FBI)-150 (old and new Sokako) 2.0 parts by weight Calcium carbonate 10 parts by weight 20% polyvinyl alcohol aqueous solution 25 parts by weight Liquid B: Sphenol A 5.0 parts by weight Stearic acid amide 3.0 parts by weight 20 parts by weight of vinyl alcohol aqueous solution 2.0 parts by weight water
14 double notes Next, a tint pattern for a ticket is printed on the above-mentioned heat-sensitive layer by a gravure printing method using an aqueous color ink containing carboxymethyl cell and roniro, and is further used to form a quick covering layer. The coating liquid has the following composition, and the dry coating amount is 2.511/lrl (coating,
This was dried to form a coating jj to produce a heat-sensitive recording ticket paper of the present invention.
被覆ａ塗液：
１５／ｓカルボキシメチルセルロース水溶液 ３３．３
重量部５％アルギン酸ソーダ水溶液 ２０重
量部水 ６，７重量部末節
例２
実施例１と同様の感熱層上にアクリル系エマルジジンを
含む水性の色インキでグラビア印刷を管ない、更に実施
例１と同様の被覆Ｊｑを設け、本発明の感熱記録型券紙
を作成した。Coating a coating liquid: 15/s carboxymethyl cellulose aqueous solution 33.3
Parts by weight 5% sodium alginate aqueous solution 20 parts by weight Water 6.7 parts by weight End Section Example 2 Gravure printing was performed on the same heat-sensitive layer as in Example 1 using a water-based color ink containing acrylic emulsion. A similar coating Jq was provided to prepare a heat-sensitive recording ticket paper according to the present invention.
比較例１〜２
実、流側１，２と同様の感熱層を設け、更叫笑流側１，
２と同様の被覆層を設けた。この被覆層の上に、実施例
１．２で用いたインキでグラビア印刷（各々比較例１．
２）を行ない、比較用感熱記録型券紙ケ作成し穴。
、 。Comparative Examples 1 to 2 In fact, a heat-sensitive layer similar to that of flow sides 1 and 2 was provided, and
A coating layer similar to No. 2 was provided. On this coating layer, gravure printing was performed using the ink used in Example 1.2 (Comparative Example 1.
Perform 2) to create a heat-sensitive recording ticket for comparison.
, .
以上よシ得られた４種類の券紙について、印ｊｉｆｉさ
れ牟イイキや耐水性テストと印字適性をテストした。The four types of ticket paper obtained above were tested for printing quality, water resistance test, and printing suitability.
耐水性のテストは上記感熱記録型券紙を２０’Ｃの水に
５分間浸漬後とり出し、指先でとすシ印刷ノ負落ちをテ
ストした。Water resistance was tested by immersing the heat-sensitive recording ticket paper in water at 20'C for 5 minutes, taking it out, and testing the printability with a fingertip.
次に印字適性は感熱式ファクシミリ機である沖ＦＡＴ７
０００で印字を行表い、サーマルヘッドへのカスの付着
、ステッキングの有無をテストした。Next, the printing suitability is Oki FAT7, which is a thermal facsimile machine.
000, and the adhesion of residue to the thermal head and the presence or absence of sticking were tested.
それらの結果を表１に示す。The results are shown in Table 1.
○：良好
Δ：やや不良
×：不良
表１よシ、本発明になる感熱記録型券紙は印刷イくキの
獣水性１．印字適性、共に十分満足でき、実用上極めて
好ましいことがわかる。○: Good Δ: Slightly poor ×: Poor According to Table 1, the heat-sensitive recording ticket paper according to the present invention has a high water resistance during printing. It can be seen that both printability and printability are fully satisfactory and are extremely desirable in practical terms.
Claims (1)
により該ロイコ体を発色させる酸性物質とを発色成分と
して含有する感熱発色層を設け、該発色層上に印刷を施
し、しかる後に該印刷面上に 透
明・な被覆層を設けた事を特徴とする感熱記録型券紙。 ・ 、・ ・、・２、印刷に用いる
インキが水溶性樹脂又は水性エマルジ璽ン樹脂を含む水
性イン中である特許請求の範囲第１項記載の感熱記録型
券紙０３、 Ｍ熱発色層上に施す印刷が地紋印刷であ
る特許請求の範囲第１項記載の感熱配録型券紙。[Claims] l= A thermosensitive coloring layer containing a usually colorless or light-colored dye leuco body and an acidic substance that causes the leuco body to develop color when heated as a coloring component is provided on a support, and printing is performed on the coloring layer. 1. A heat-sensitive recording ticket paper, characterized in that a transparent coating layer is provided on the printed surface after the printing is applied.・ ・ ・ ・ 2. Thermal recording type ticket paper 03 according to claim 1, wherein the ink used for printing is in an aqueous ink containing a water-soluble resin or an aqueous emulsion resin, on the M thermochromic layer. 2. The heat-sensitive printed ticket paper according to claim 1, wherein the printing applied to the heat-sensitive printed ticket is background pattern printing.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP57143013A JPS5933181A (en) | 1982-08-18 | 1982-08-18 | Heat-sensitive recording type ticket paper |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP57143013A JPS5933181A (en) | 1982-08-18 | 1982-08-18 | Heat-sensitive recording type ticket paper |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS5933181A true JPS5933181A (en) | 1984-02-22 |
| JPH024434B2 JPH024434B2 (en) | 1990-01-29 |
Family
ID=15328910
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP57143013A Granted JPS5933181A (en) | 1982-08-18 | 1982-08-18 | Heat-sensitive recording type ticket paper |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS5933181A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS61107574U (en) * | 1984-12-20 | 1986-07-08 | ||
| JPS62113587A (en) * | 1985-11-14 | 1987-05-25 | Tomoegawa Paper Co Ltd | Production of thermal recording paper provided with pattern |
| JPS6283666U (en) * | 1985-11-14 | 1987-05-28 |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5667293A (en) * | 1979-11-07 | 1981-06-06 | Honshu Paper Co Ltd | Method of improving recording and preserving qualities for tickets and cards by use of heat-sensitive recording sheet |
| JPS56125354U (en) * | 1980-02-25 | 1981-09-24 | ||
| JPS57120488A (en) * | 1981-01-19 | 1982-07-27 | Ricoh Co Ltd | Heat-sensing recording type magnetized security paper |
-
1982
- 1982-08-18 JP JP57143013A patent/JPS5933181A/en active Granted
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5667293A (en) * | 1979-11-07 | 1981-06-06 | Honshu Paper Co Ltd | Method of improving recording and preserving qualities for tickets and cards by use of heat-sensitive recording sheet |
| JPS56125354U (en) * | 1980-02-25 | 1981-09-24 | ||
| JPS57120488A (en) * | 1981-01-19 | 1982-07-27 | Ricoh Co Ltd | Heat-sensing recording type magnetized security paper |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS61107574U (en) * | 1984-12-20 | 1986-07-08 | ||
| JPH047988Y2 (en) * | 1984-12-20 | 1992-02-28 | ||
| JPS62113587A (en) * | 1985-11-14 | 1987-05-25 | Tomoegawa Paper Co Ltd | Production of thermal recording paper provided with pattern |
| JPS6283666U (en) * | 1985-11-14 | 1987-05-28 | ||
| JPH0412236B2 (en) * | 1985-11-14 | 1992-03-03 | Tomoegawa Paper Co Ltd |
Also Published As
| Publication number | Publication date |
|---|---|
| JPH024434B2 (en) | 1990-01-29 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| JPH0355317B2 (en) | ||
| JPH0372476B2 (en) | ||
| CN100430239C (en) | Heat-sensitive recording medium | |
| JPS5933181A (en) | Heat-sensitive recording type ticket paper | |
| JPH0320355B2 (en) | ||
| JPH0157679B2 (en) | ||
| JPH046935Y2 (en) | ||
| JPS5967081A (en) | Heat sensitive recordng sheet | |
| JPS60101078A (en) | Image recording method | |
| JPS6347881Y2 (en) | ||
| JPH0280285A (en) | Thermosensitive recording material | |
| JPS5910317B2 (en) | Heat-sensitive recording magnetic ticket paper | |
| JPH0335575Y2 (en) | ||
| JPS6240198B2 (en) | ||
| JPH046936Y2 (en) | ||
| JPS591294A (en) | Multicolor heat-sensitive recording material | |
| JPS63147683A (en) | High-quality thermal recording sheet and production thereof | |
| JPH0632048A (en) | Pressure-sensitive recording paper | |
| JPS6223366B2 (en) | ||
| JPS5945193A (en) | Heat sensitive recording material | |
| JPH03205183A (en) | Method for preventing erasure of image of thermal recording type magnetic ticket paper | |
| JPH0242678B2 (en) | ||
| JPS5942995A (en) | Heat sensitive recording element | |
| JPH03181572A (en) | Heat-sensitive recording ink | |
| JPS63257681A (en) | Heat-sensitive recording member |