JPH0226692Y2 - - Google Patents
Info
- Publication number
- JPH0226692Y2 JPH0226692Y2 JP12608984U JP12608984U JPH0226692Y2 JP H0226692 Y2 JPH0226692 Y2 JP H0226692Y2 JP 12608984 U JP12608984 U JP 12608984U JP 12608984 U JP12608984 U JP 12608984U JP H0226692 Y2 JPH0226692 Y2 JP H0226692Y2
- Authority
- JP
- Japan
- Prior art keywords
- heat
- release paper
- support
- adhesive layer
- printed pattern
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 238000004040 coloring Methods 0.000 claims description 9
- 239000010410 layer Substances 0.000 claims description 9
- 239000012790 adhesive layer Substances 0.000 claims description 7
- 239000011241 protective layer Substances 0.000 claims description 6
- 239000007787 solid Substances 0.000 claims description 6
- 239000007788 liquid Substances 0.000 claims description 4
- 229920003169 water-soluble polymer Polymers 0.000 claims description 3
- 239000000463 material Substances 0.000 description 5
- -1 aliphatic iron salts Chemical class 0.000 description 3
- YQUVCSBJEUQKSH-UHFFFAOYSA-N 3,4-dihydroxybenzoic acid Chemical compound OC(=O)C1=CC=C(O)C(O)=C1 YQUVCSBJEUQKSH-UHFFFAOYSA-N 0.000 description 2
- QIGBRXMKCJKVMJ-UHFFFAOYSA-N Hydroquinone Chemical compound OC1=CC=C(O)C=C1 QIGBRXMKCJKVMJ-UHFFFAOYSA-N 0.000 description 2
- LNTHITQWFMADLM-UHFFFAOYSA-N gallic acid Chemical compound OC(=O)C1=CC(O)=C(O)C(O)=C1 LNTHITQWFMADLM-UHFFFAOYSA-N 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 150000007524 organic acids Chemical class 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- UMGDCJDMYOKAJW-UHFFFAOYSA-N thiourea Chemical compound NC(N)=S UMGDCJDMYOKAJW-UHFFFAOYSA-N 0.000 description 2
- TUSDEZXZIZRFGC-UHFFFAOYSA-N 1-O-galloyl-3,6-(R)-HHDP-beta-D-glucose Natural products OC1C(O2)COC(=O)C3=CC(O)=C(O)C(O)=C3C3=C(O)C(O)=C(O)C=C3C(=O)OC1C(O)C2OC(=O)C1=CC(O)=C(O)C(O)=C1 TUSDEZXZIZRFGC-UHFFFAOYSA-N 0.000 description 1
- BURBNIPKSRJAIQ-UHFFFAOYSA-N 2-azaniumyl-3-[3-(trifluoromethyl)phenyl]propanoate Chemical compound OC(=O)C(N)CC1=CC=CC(C(F)(F)F)=C1 BURBNIPKSRJAIQ-UHFFFAOYSA-N 0.000 description 1
- PDQAZBWRQCGBEV-UHFFFAOYSA-N Ethylenethiourea Chemical compound S=C1NCCN1 PDQAZBWRQCGBEV-UHFFFAOYSA-N 0.000 description 1
- 239000001263 FEMA 3042 Substances 0.000 description 1
- LRBQNJMCXXYXIU-PPKXGCFTSA-N Penta-digallate-beta-D-glucose Natural products OC1=C(O)C(O)=CC(C(=O)OC=2C(=C(O)C=C(C=2)C(=O)OC[C@@H]2[C@H]([C@H](OC(=O)C=3C=C(OC(=O)C=4C=C(O)C(O)=C(O)C=4)C(O)=C(O)C=3)[C@@H](OC(=O)C=3C=C(OC(=O)C=4C=C(O)C(O)=C(O)C=4)C(O)=C(O)C=3)[C@H](OC(=O)C=3C=C(OC(=O)C=4C=C(O)C(O)=C(O)C=4)C(O)=C(O)C=3)O2)OC(=O)C=2C=C(OC(=O)C=3C=C(O)C(O)=C(O)C=3)C(O)=C(O)C=2)O)=C1 LRBQNJMCXXYXIU-PPKXGCFTSA-N 0.000 description 1
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Natural products NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 229940063284 ammonium salicylate Drugs 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 229940116224 behenate Drugs 0.000 description 1
- UKMSUNONTOPOIO-UHFFFAOYSA-M behenate Chemical compound CCCCCCCCCCCCCCCCCCCCCC([O-])=O UKMSUNONTOPOIO-UHFFFAOYSA-M 0.000 description 1
- 239000003638 chemical reducing agent Substances 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- PSYDSRLQABJJAD-UHFFFAOYSA-N dodecylthiourea Chemical compound CCCCCCCCCCCCNC(N)=S PSYDSRLQABJJAD-UHFFFAOYSA-N 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 235000004515 gallic acid Nutrition 0.000 description 1
- 229940074391 gallic acid Drugs 0.000 description 1
- 229910001385 heavy metal Inorganic materials 0.000 description 1
- FUZZWVXGSFPDMH-UHFFFAOYSA-M hexanoate Chemical compound CCCCCC([O-])=O FUZZWVXGSFPDMH-UHFFFAOYSA-M 0.000 description 1
- XHQSLVIGPHXVAK-UHFFFAOYSA-K iron(3+);octadecanoate Chemical compound [Fe+3].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O XHQSLVIGPHXVAK-UHFFFAOYSA-K 0.000 description 1
- IMRZFEJNJIFRDU-UHFFFAOYSA-K iron(3+);tetradecanoate Chemical compound [Fe+3].CCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCC([O-])=O IMRZFEJNJIFRDU-UHFFFAOYSA-K 0.000 description 1
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 1
- 229910052753 mercury Inorganic materials 0.000 description 1
- 229910000510 noble metal Inorganic materials 0.000 description 1
- 150000002989 phenols Chemical class 0.000 description 1
- 238000001454 recorded image Methods 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920002050 silicone resin Polymers 0.000 description 1
- 229910052709 silver Inorganic materials 0.000 description 1
- 239000004332 silver Substances 0.000 description 1
- AQRYNYUOKMNDDV-UHFFFAOYSA-M silver behenate Chemical compound [Ag+].CCCCCCCCCCCCCCCCCCCCCC([O-])=O AQRYNYUOKMNDDV-UHFFFAOYSA-M 0.000 description 1
- ORYURPRSXLUCSS-UHFFFAOYSA-M silver;octadecanoate Chemical compound [Ag+].CCCCCCCCCCCCCCCCCC([O-])=O ORYURPRSXLUCSS-UHFFFAOYSA-M 0.000 description 1
- AKHNMLFCWUSKQB-UHFFFAOYSA-L sodium thiosulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=S AKHNMLFCWUSKQB-UHFFFAOYSA-L 0.000 description 1
- 235000019345 sodium thiosulphate Nutrition 0.000 description 1
- 150000003464 sulfur compounds Chemical class 0.000 description 1
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
- 235000015523 tannic acid Nutrition 0.000 description 1
- LRBQNJMCXXYXIU-NRMVVENXSA-N tannic acid Chemical compound OC1=C(O)C(O)=CC(C(=O)OC=2C(=C(O)C=C(C=2)C(=O)OC[C@@H]2[C@H]([C@H](OC(=O)C=3C=C(OC(=O)C=4C=C(O)C(O)=C(O)C=4)C(O)=C(O)C=3)[C@@H](OC(=O)C=3C=C(OC(=O)C=4C=C(O)C(O)=C(O)C=4)C(O)=C(O)C=3)[C@@H](OC(=O)C=3C=C(OC(=O)C=4C=C(O)C(O)=C(O)C=4)C(O)=C(O)C=3)O2)OC(=O)C=2C=C(OC(=O)C=3C=C(O)C(O)=C(O)C=3)C(O)=C(O)C=2)O)=C1 LRBQNJMCXXYXIU-NRMVVENXSA-N 0.000 description 1
- 229940033123 tannic acid Drugs 0.000 description 1
- 229920002258 tannic acid Polymers 0.000 description 1
- 150000003585 thioureas Chemical class 0.000 description 1
- RUJLHPZAKCVICY-UHFFFAOYSA-J thorium(4+);disulfate Chemical class [Th+4].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O RUJLHPZAKCVICY-UHFFFAOYSA-J 0.000 description 1
Landscapes
- Heat Sensitive Colour Forming Recording (AREA)
Description
【考案の詳細な説明】 〔技術分野〕 本考案は感熱記録型剥離紙に関する。[Detailed explanation of the idea] 〔Technical field〕 The present invention relates to a heat-sensitive recording release paper.
感熱記録材料は、加熱によつて発色するいわゆ
る感熱発色層を紙、合成紙又は樹脂フイルム等の
支持体上に形成した構造の記録材料であつて、そ
の発色のための加熱には熱ヘツドを内蔵したサー
マルプリンター等が用いられる。このような記録
材料は、他の記録材料に比較して現像、定着等の
煩雑な処理を施すことなく比較的短時間で記録が
得られること、騒音の発生がないこと、比較的安
価である等の利点により図書、文書などの複写は
勿論のこと、電子計算機、フアクシミリ、テレツ
クス、医療計測機等の種々の情報並びに計測機器
の記録材料、又は、駅務システムの乗車券や百貨
店、マーケツト等のPOSシステムのラベルとし
ても広く使用されている。感熱記録型剥離紙は、
表面に加熱方式により印字や画像の記録を行うこ
とができ、記録画像形成後の剥離紙を仮着されて
いた剥離台紙から剥離して、所望の固体表面に対
して接着することのできるシートを意味し、番号
札、値札、薬ビン札などの各種ラベルやレツテル
の他、ネームプレート、シール等に利用されてい
る。
A thermosensitive recording material is a recording material having a structure in which a so-called thermosensitive coloring layer that develops color when heated is formed on a support such as paper, synthetic paper, or resin film, and a thermal head is used for heating to develop the color. A built-in thermal printer is used. Compared to other recording materials, such recording materials can produce records in a relatively short time without complex processes such as development and fixing, do not generate noise, and are relatively inexpensive. Due to these advantages, it is useful not only for copying books and documents, but also for recording materials of various information and measuring instruments such as electronic computers, facsimiles, telex, medical measuring instruments, tickets for station management systems, department stores, markets, etc. It is also widely used as a label for POS systems. Thermal recording type release paper is
A sheet that can print or record images on the surface using a heating method, and after the recorded image is formed, the release paper can be peeled off from the release liner to which it was temporarily attached and adhered to the desired solid surface. It is used for various labels such as number tags, price tags, medicine bottle tags, labels, name plates, stickers, etc.
一般に、剥離紙は、図案、線、文字等を予め印
刷しておくことが望まれる場合が多く、このよう
な場合、従来は、最上層にある感熱発色層又は保
護層に固体もしくは液体インクによる所望のパタ
ーンを印刷していた。しかしながら、これが感熱
記録型剥離紙の場合、サーマルヘツドで印字する
と、インクの印刷パターンがサーマルヘツドに接
触するためヘツドが汚れ易く、その結果、ヘツド
へのガス付着や熱印字部の汚れ（尾びき等）が生
じるという問題があつた。 Generally, it is often desirable to print patterns, lines, characters, etc. on release paper in advance, and in such cases, conventionally, the topmost heat-sensitive coloring layer or protective layer is printed with solid or liquid ink. The desired pattern was printed. However, in the case of heat-sensitive recording release paper, when printing with a thermal head, the ink print pattern comes into contact with the thermal head, which tends to stain the head, resulting in gas adhesion to the head and stains (tails) on the thermal print area. etc.) occurred.
本考案は、上記した従来の感熱記録型剥離紙の
問題点を解決すること、即ち、印刷パターンによ
るサーマルヘツドの汚れや印字部の汚れを生じな
い感熱記録型剥離紙を提供することを目的とす
る。
The purpose of the present invention is to solve the above-mentioned problems with the conventional heat-sensitive recording type release paper, that is, to provide a heat-sensitive recording type release paper that does not cause stains on the thermal head or printed area due to printed patterns. do.
本考案によれば、表面又は裏面に固体又は液体
インクによる印刷パターンを形成した支持体の表
面に感熱発色層及び、必要に応じ、その上に水溶
性高分子保護層を設けると共に、裏面に接着剤層
を設け、更に該接着剤層を剥離台紙に仮着してな
る感熱記録型剥離紙が提供される。
According to the present invention, a heat-sensitive coloring layer is provided on the surface of a support having a printed pattern made of solid or liquid ink on the front or back side, and if necessary, a water-soluble polymer protective layer is provided thereon, and an adhesive is attached to the back side. A heat-sensitive recording type release paper is provided by providing an adhesive layer and temporarily adhering the adhesive layer to a release mount.
本考案においては、表面（感熱発色層側）又は
裏面（剥離台紙側）に固体又は液体インクによる
線、図形、絵等の印刷パターンを形成した支持体
を用いる。裏面に印刷パターンを形成する場合の
支持体は、該印刷パターンが感熱発色層側から透
視もしくは認識できるものであれば任意のものを
用いることができる。支持体は、紙、フイルム等
が通常用いられる。印刷パターンは抄紙時等、支
持体製造時に着色加工してもよいし、製造後印刷
してもよい。印刷パターンはいかなるものでもよ
く、白ヌキ印刷やベタ印刷とすることもできる。 In the present invention, a support is used which has a printed pattern such as lines, figures, pictures, etc. formed with solid or liquid ink on the front surface (thermosensitive coloring layer side) or the back surface (release mount side). When a printed pattern is formed on the back side, any support can be used as long as the printed pattern can be seen through or recognized from the heat-sensitive coloring layer side. Paper, film, etc. are usually used as the support. The printed pattern may be colored during papermaking or during support production, or may be printed after production. The printing pattern may be of any type, and may be white blank printing or solid printing.
本考案に適用される感熱発色層としては、種々
のものが使用でき、例えば、次のような熱発色系
が採用できる。 Various types of heat-sensitive coloring layers can be used for the present invention, and for example, the following thermocoloring systems can be employed.
(1) ステアリン酸第２鉄、ミリスチン酸第２鉄の
ような長鎖脂肪族鉄塩と、タンニン酸、没食子
酸、サリチル酸アンモニウムのようなフエノー
ル類との組合せからなる熱発色系。(1) A thermochromic system consisting of a combination of long-chain aliphatic iron salts such as ferric stearate and ferric myristate and phenols such as tannic acid, gallic acid, and ammonium salicylate.
(2) 銀、鉛、水銀、トリウムの硫酸塩のような重
金属硫酸塩と、Na−テトラチオネート、チオ
硫酸ソーダ、チオ尿素のような硫黄化合物との
組合せからなる熱発色系。(2) A thermochromic system consisting of a combination of heavy metal sulfates, such as silver, lead, mercury, and thorium sulfates, and sulfur compounds, such as Na-tetrathionate, sodium thiosulfate, and thiourea.
(3) ベヘン酸銀、ステアリン酸銀のような有機酸
貴金属塩と、プロトカテキン酸、スピロインダ
ン、ハイドロキノンのような芳香族有機還元剤
との組合せからなる熱発色系。(3) A thermochromic system consisting of a combination of a noble metal salt of an organic acid such as silver behenate or silver stearate and an aromatic organic reducing agent such as protocatechuic acid, spiroindane, or hydroquinone.
(4) カプロン酸鉛、ベラルゴン酸鉛、ベヘン酸鉛
のような有機酸鉛塩とエチレンチオ尿素、Ｎ−
ドデシルチオ尿素のようなチオ尿素誘導体との
組合せからなる熱発色系。(4) Organic acid lead salts such as lead caproate, lead belargonate, and lead behenate and ethylenethiourea, N-
A thermochromic system consisting of a combination with a thiourea derivative such as dodecylthiourea.
(5) ロイコ染料と顕色剤との組合せからなる熱発
色系。(5) A thermochromic system consisting of a combination of leuco dye and color developer.
本考案を次に図面により詳細に説明する。 The invention will now be explained in detail with reference to the drawings.
第１図は本考案による感熱記録型剥離紙の斜視
説明図、及び第２図は第１図の−部分断面図
である。図中、２は支持体で、その上に感熱発色
層１及び水溶性高分子保護層６がその順に塗設、
積層されている。尚、この保護層６は、必要に応
じて設けられるもので、省くこともできる。 FIG. 1 is a perspective explanatory view of a heat-sensitive recording type release paper according to the present invention, and FIG. 2 is a partial cross-sectional view of FIG. 1. In the figure, 2 is a support, on which a thermosensitive coloring layer 1 and a water-soluble polymer protective layer 6 are coated in that order.
Laminated. Note that this protective layer 6 is provided as needed and can be omitted.
支持体２の下面には印刷パターン５が形成さ
れ、その表面に接着剤層３が設けられている。４
は剥離台紙であつて、一方の表面にシリコーン樹
脂等の被膜（図示せず）を有し、そこに接着剤層
により上記構成の感熱紙が仮着される。 A printed pattern 5 is formed on the lower surface of the support 2, and an adhesive layer 3 is provided on the surface thereof. 4
is a release mount having a coating (not shown) of silicone resin or the like on one surface, to which the thermal paper having the above structure is temporarily attached by an adhesive layer.
第３図は、本考案による感熱記録型剥離紙の他
の実施例を示すもので、図中、第２図と同じ符号
は同一の構成要素を示す。本例では、印刷パター
ン５が支持体２の表面に形成されている以外は第
２図のものと同一である。 FIG. 3 shows another embodiment of the heat-sensitive recording type release paper according to the present invention, in which the same reference numerals as in FIG. 2 indicate the same components. This example is the same as that in FIG. 2 except that the printed pattern 5 is formed on the surface of the support 2.
本考案の感熱記録型剥離紙は、上記の如く構成
したことにより、熱記録時における印刷パターン
によるヘツドマツチング性低下の問題は皆無であ
り、しかも印刷パターンは表面から目視、判読で
きる。
Since the heat-sensitive recording type release paper of the present invention is constructed as described above, there is no problem of deterioration of head matching properties due to the printed pattern during thermal recording, and the printed pattern can be visually observed and read from the surface.
第１図は本考案による感熱記録型剥離紙の一例
を示す斜視図、及び第２図は第１図のＸ−X′部
分断面図、及び第３図は本考案の他の実施例を示
す部分断面図である。
１……感熱発色層、２……支持体、３……接着
剤層、４……剥離台紙、５……印刷パターン、６
……保護層。
FIG. 1 is a perspective view showing an example of a heat-sensitive recording type release paper according to the present invention, FIG. 2 is a partial sectional view taken along line X-X' in FIG. 1, and FIG. 3 is a perspective view showing another embodiment of the present invention. FIG. DESCRIPTION OF SYMBOLS 1...Thermosensitive coloring layer, 2...Support, 3...Adhesive layer, 4...Peelable mount, 5...Print pattern, 6
...protective layer.
Claims (1)
パターンを形成した支持体の表面に感熱発色層及
び、必要に応じ、その上に水溶性高分子保護層を
設けると共に、裏面に接着剤層を設け、更に該接
着剤層を剥離台紙に仮着してなる感熱記録型剥離
紙。 A heat-sensitive coloring layer is provided on the surface of the support having a printed pattern formed with solid or liquid ink on the front or back side, and if necessary, a water-soluble polymer protective layer is provided thereon, and an adhesive layer is provided on the back side, and further A heat-sensitive recording type release paper made by temporarily adhering the adhesive layer to a release mount.
Priority Applications (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP12608984U JPS6140262U (en) | 1984-08-20 | 1984-08-20 | Thermal recording release paper |
| DE19853529781 DE3529781A1 (en) | 1984-08-20 | 1985-08-20 | HEAT-SENSITIVE ADHESIVE RECORDING MATERIAL |
| US06/767,432 US4711874A (en) | 1984-08-20 | 1985-08-20 | Thermosensitive recording adhesive sheet |
| GB08520857A GB2163562B (en) | 1984-08-20 | 1985-08-20 | Adhesive thermosensitive recording sheet |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP12608984U JPS6140262U (en) | 1984-08-20 | 1984-08-20 | Thermal recording release paper |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS6140262U JPS6140262U (en) | 1986-03-14 |
| JPH0226692Y2 true JPH0226692Y2 (en) | 1990-07-19 |
Family
ID=30684774
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP12608984U Granted JPS6140262U (en) | 1984-08-20 | 1984-08-20 | Thermal recording release paper |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS6140262U (en) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0662006B2 (en) * | 1986-06-10 | 1994-08-17 | 株式会社巴川製紙所 | Thermal recording type card |
-
1984
- 1984-08-20 JP JP12608984U patent/JPS6140262U/en active Granted
Also Published As
| Publication number | Publication date |
|---|---|
| JPS6140262U (en) | 1986-03-14 |
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