JPH0475886B2 - - Google Patents

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Publication number
JPH0475886B2
JPH0475886B2 JP61111329A JP11132986A JPH0475886B2 JP H0475886 B2 JPH0475886 B2 JP H0475886B2 JP 61111329 A JP61111329 A JP 61111329A JP 11132986 A JP11132986 A JP 11132986A JP H0475886 B2 JPH0475886 B2 JP H0475886B2
Authority
JP
Japan
Prior art keywords
hair
acid
damage
present
mono
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
JP61111329A
Other languages
Japanese (ja)
Other versions
JPS62267219A (en
Inventor
Masanobu Tatsuta
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Shiseido Co Ltd
Original Assignee
Shiseido Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Shiseido Co Ltd filed Critical Shiseido Co Ltd
Priority to JP11132986A priority Critical patent/JPS62267219A/en
Publication of JPS62267219A publication Critical patent/JPS62267219A/en
Publication of JPH0475886B2 publication Critical patent/JPH0475886B2/ja
Granted legal-status Critical Current

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Classifications

    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61QSPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q17/00Barrier preparations; Preparations brought into direct contact with the skin for affording protection against external influences, e.g. sunlight, X-rays or other harmful rays, corrosive materials, bacteria or insect stings
    • A61Q17/04Topical preparations for affording protection against sunlight or other radiation; Topical sun tanning preparations
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/37Esters of carboxylic acids
    • A61K8/375Esters of carboxylic acids the alcohol moiety containing more than one hydroxy group

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  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Animal Behavior & Ethology (AREA)
  • General Health & Medical Sciences (AREA)
  • Public Health (AREA)
  • Veterinary Medicine (AREA)
  • Dermatology (AREA)
  • Emergency Medicine (AREA)
  • Birds (AREA)
  • Epidemiology (AREA)
  • Cosmetics (AREA)

Description

【発明の詳細な説明】[Detailed description of the invention]

[産業上の利用分野] 本発明は毛髪になめらかさやしつとりさを賦与
し、毛髪の損傷、特に海やプールでの水泳後の髪
の変色、いたみ、枝毛、切毛、べたつき等を防止
する頭髪化粧料に関するものである。 [従来の技術] 一般に、毛髪はブラツシング、ヘアドライヤー
等の物理的処理、パーマ、ブリーチ、ヘアダイな
どの美容上の化合物処理等を受けることにより損
傷することが知られている。一方、海やプールで
の水泳後の毛髪の損傷、例えば、髪の変色、いた
み、枝毛、切毛、べたつき等も大きな問題となつ
ている。従来は、これらの物理的処理や化学的処
理による損傷毛に対しては、つやや、潤いを与え
るために油分や保湿剤を頭髪化粧料に配合し、改
善しようとする試みがなされてきた。 [発明が解決しようとする問題点] しかしながら、これらの油分や保湿剤を用いた
頭髪化粧料は、パーマ、ブリーチ、ヘアダイ等に
よる損傷の少ない、所謂健康毛に対しては、その
保湿効果により毛髪に柔軟性を賦与することがで
きるが、損傷の著しい、所謂ダメージ毛に対して
は、毛髪からの水分揮散を抑制することができ
ず、望ましい柔軟性を与えることはできなかつ
た。特に海やプールでの水泳後の毛髪は変色、い
たみ、枝毛、切毛、パサツキ、キシミがひどく、
著しく損傷しているにもかかわらず、この損傷を
改善する手段は未だ見つかつていない。 [問題点を解決するための手段] 本発明者等は上記の事情に鑑み、鋭意研究を重
ねた結果、毛髪の損傷に水等の溶媒が大きく影響
することを見出し、この水の影響についてさらに
研究を進めた結果、特定の物質、またはこの物質
とUV−A領域紫外線防止剤とを頭髪化粧料に配
合することにより、海やプールでの水泳後の髪の
変色、いたみ、枝毛、切毛、パサツキ、キシミ、
シヤンプー時の髪のもつれを防止し、なめらかさ
やしつとりさを賦与することを見出し、本発明を
完成するに至つた。 即ち、本発明は一般式()〜()で表され
るP−メトキシケイ皮酸化合物の一種または二種
以上を配合することを特徴とする頭髪化粧料を提
供するものである。 以下、本発明の構成について詳述する。 本発明のP−メトキシケイ皮酸化合物は、例え
ば以下のように合成することができる。P−メト
キシケイ皮酸、常温液状脂肪酸と、各種トリオー
ルを直接無触媒又は一般的なエステル化触媒を用
いて合成するか、P−メトキシケイ皮酸、常温液
状脂肪酸の低級アルコールエステル、例えばメチ
ルエステル、エチルエステル、プロピルエステル
等と各種トリオールとのエステル交換反応により
容易に合成することができる。ここで用いられる
触媒としては、例えば硫酸、塩酸、リン酸、P−
トルエンスルホン酸、水酸化ナトリウム、水酸化
カリウム、炭酸ナトリウム、炭酸カリウム等であ
る。反応は無溶媒又はトルエン、キシレン等の水
共沸溶媒中130℃〜250℃で行なわれるが、低温で
は反応の進行が遅く、また高温での反応は、反応
物の着色が著しくなるため、好ましくは160℃〜
220℃で行なうのが良い。 P−メトキシケイ皮酸化合物の配合量は、頭髪
化粧料全量の0.01〜10重量%が好ましく、さらに
好ましくは0.1〜3重量%である。 本発明においては、P−メトキシケイ皮酸化合
物単独で配合しても充分効果は発揮されるが、こ
れとUV−A領域紫外線(波長が320〜400ナノメ
ーター)防止剤とを併用すると、より優れた効果
が発揮されるので好ましい。 UV−A領域紫外線(波長が320〜400ナノメー
ター)防止剤としては、以下のようなものが挙げ
られる。例えば、4(1,1ジメチルエチル)−
4′−メトキシジベンゾイルメタン{商品名:パル
ソール(登録商標)1789、ジボダン社製}、2−
ヒドロキシ−4−メトキシベンゾフエノン及びそ
の誘導体や2,2′−ヒドロキシ−5−メチルフエ
ニル−ベンゾトリアゾール等が挙げられる。これ
らの中でも効果の面から4−(1,1ジメチルエ
チル)−4′−メトキシジベンゾイルメタンが、最
も好ましい。 UV−A領域紫外線(波長が320〜400ナノメー
ター)防止剤の配合量は、頭髪化粧料全量の0.01
〜10重量%が好ましく、さらに好ましくは0.1〜
3重量%である。 本発明の毛髪化粧料には上記必須成分に加え
て、必要により、脂肪酸と低級アルコールおよび
多価アルコールのエステル、パラフイン系炭化水
素、脂肪酸、直鎖あるいは分枝の高級アルコー
ル、アルキルグリセリンエーテル、シリコン油等
の油分、ポリオキシエチレンアルキルエーテル酢
酸塩、高級脂肪酸塩、N−アシルアミノ酸塩、ア
ルキル硫酸塩、アルキルアリル硫酸塩、α−オレ
フインスルホン酸塩、アシルイセチオン酸塩、ア
ルキルスルホコハク酸塩、N−アシルメチルタウ
リン塩、ポリオキシエチレンアルキルエーテル硫
酸塩、アルキルリン酸塩、ポリオキシエチレンア
ルキルエーテルリン酸塩等のアニオン性界面活性
剤、ポリオキシエチレンアルキルエーテル、脂肪
酸と低級アルコールおよび高級アルコールとのエ
ステルあるいはそれらのエチレンオキサイド付加
物、ポリオキシエチレンポリオキシプロピレンア
ルキルエーテル、ポリオキシエチレンアルキルフ
エニルエーテル、ポリオキシエチレンアルキルア
ミン、脂肪酸アルカノールアミド、脂肪酸と多価
アルコールのエステルのエチレンオキサイド付加
物およびその水素添加物等の非イオン性界面活性
剤、カルボキシベタイン、スルホベタイン、イミ
ダゾリン誘導体等の両性界面活性剤、モノアルキ
ルトリメチルアンモニウムの塩化物、ジアルキル
ジメチルアンモニウムの塩化物、モノアルケニル
トリメチルアンモニウムの塩化物等のカチオン性
界面活性剤、エチレングリコール、プロピレング
リコール、グリセリン、ソルビトール、マンニト
ールポリエチレングリコール等の多価アルコー
ル、低級アルコール、アニオン性、カチオン性、
非イオン性の水溶性高分子、ビタミン等の薬剤、
防腐剤、ジンクピリチオン、トリクロロカルバニ
リド、ピロクトンオラミン、イオウ等の殺菌剤、
PH調整剤、その他の紫外線吸収剤、酸化防止剤、
金属イオン封鎖剤、香料、色素、ナイロン、ポリ
エチレン、セルロース、キチン、無機化合物等の
不溶性微粉末等を配合することができる。 また、本発明の頭髪化粧料の用途も任意であ
り、例えばシヤンプー、ヘアリンス、ヘアトリー
トメント、ヘアスプレー、ヘアセツトローシヨ
ン、養毛剤、整髪剤等として使用される。 [発明の効果] 本発明の毛髪化粧料は毛髪になめらかさやしつ
とりさを賦与し、毛髪の水等の溶媒による損傷を
防止し、特に海水浴後の髪のゴワツキ、シヤンプ
ー時の髪のもつれを防止するものである。 [実施例] 次に実施例および比較例をあげて、本発明をさ
らに詳細に説明する。本発明はこれにより限定さ
れるものではない。配合量は重量%である。 毛髪の損傷の程度を測るために、以下の引つ張
り強度試験を行なつた。 引つ張り強度測定法 毛髪を試料に浸漬し、紫外線フエードメーター
(スガ試験機株式会社製)にて100時間照射後に、
オートグラフ(島津製作所製)にて、毛髪の引つ
張り強度を測定し、処理前の測定値との20%延伸
時での比を求めた。 結果を表1に示す。
[Industrial Application Field] The present invention imparts smoothness and moisture to hair, and prevents hair damage, especially discoloration, damage, split ends, cut hair, stickiness, etc. of hair after swimming in the sea or pool. The present invention relates to hair cosmetics. [Prior Art] It is generally known that hair is damaged by physical treatments such as brushing, hair drying, and cosmetic compound treatments such as perming, bleaching, and hair dye. On the other hand, damage to hair after swimming in the sea or pool, such as hair discoloration, damage, split ends, cut hair, and stickiness, has also become a major problem. In the past, attempts have been made to improve hair damaged by these physical and chemical treatments by adding oils and humectants to hair cosmetics to give shine and moisture. [Problems to be Solved by the Invention] However, hair cosmetics using these oils and moisturizers have a moisturizing effect on so-called healthy hair, which is less damaged by perms, bleaches, hair dyes, etc. However, for severely damaged hair, so-called damaged hair, moisture volatilization from the hair cannot be suppressed, and desired flexibility cannot be imparted. Especially after swimming in the sea or pool, hair becomes discolored, damaged, split ends, cut, dry, and creased.
Despite the significant damage, no means have yet been found to ameliorate this damage. [Means for Solving the Problems] In view of the above circumstances, the present inventors have conducted intensive research and found that solvents such as water have a large effect on hair damage, and have further investigated the effects of water. As a result of our research, we have found that by incorporating a specific substance or this substance and a UV-A UV inhibitor into hair cosmetics, hair discoloration, damage, split ends, and breakage after swimming in the sea or pool can be prevented. Hair, dryness, squeaks,
The inventors have discovered that hair can be prevented from becoming tangled during shampooing and impart smoothness and moisture, leading to the completion of the present invention. That is, the present invention provides a hair cosmetic characterized by blending one or more types of P-methoxycinnamic acid compounds represented by general formulas () to (). Hereinafter, the configuration of the present invention will be explained in detail. The P-methoxycinnamic acid compound of the present invention can be synthesized, for example, as follows. P-methoxycinnamic acid, a fatty acid that is liquid at room temperature, and various triols are directly synthesized without a catalyst or using a general esterification catalyst, or a lower alcohol ester of P-methoxycinnamic acid, a fatty acid that is liquid at room temperature, such as methyl ester. , ethyl ester, propyl ester, etc., and various triols can be easily synthesized by transesterification. Examples of catalysts used here include sulfuric acid, hydrochloric acid, phosphoric acid, P-
These include toluenesulfonic acid, sodium hydroxide, potassium hydroxide, sodium carbonate, potassium carbonate, etc. The reaction is carried out without a solvent or in an aqueous azeotropic solvent such as toluene or xylene at 130°C to 250°C, but the reaction progresses slowly at low temperatures, and reaction at high temperatures is not preferred because the coloring of the reactants becomes significant. is 160℃~
It is best to do this at 220℃. The blending amount of the P-methoxycinnamic acid compound is preferably 0.01 to 10% by weight, more preferably 0.1 to 3% by weight, based on the total amount of the hair cosmetic. In the present invention, even if the P-methoxycinnamic acid compound is blended alone, it is sufficiently effective, but when combined with a UV-A region ultraviolet (wavelength: 320 to 400 nanometers) inhibitor, it becomes even more effective. It is preferable because it exhibits excellent effects. Examples of UV-A region ultraviolet (wavelength: 320 to 400 nanometers) inhibitors include the following. For example, 4(1,1 dimethylethyl)-
4'-Methoxydibenzoylmethane {trade name: Parsol (registered trademark) 1789, manufactured by Givaudan}, 2-
Examples include hydroxy-4-methoxybenzophenone and its derivatives, and 2,2'-hydroxy-5-methylphenyl-benzotriazole. Among these, 4-(1,1 dimethylethyl)-4'-methoxydibenzoylmethane is most preferred from the viewpoint of effectiveness. The amount of UV-A region ultraviolet rays (wavelength: 320 to 400 nanometers) inhibitor is 0.01 of the total amount of hair cosmetics.
~10% by weight is preferred, more preferably 0.1~
It is 3% by weight. In addition to the above-mentioned essential ingredients, the hair cosmetic of the present invention may include, if necessary, esters of fatty acids and lower alcohols and polyhydric alcohols, paraffinic hydrocarbons, fatty acids, linear or branched higher alcohols, alkylglycerin ethers, and silicone. Oil such as oil, polyoxyethylene alkyl ether acetate, higher fatty acid salt, N-acylamino acid salt, alkyl sulfate, alkylaryl sulfate, α-olefin sulfonate, acyl isethionate, alkyl sulfosuccinate, N- Anionic surfactants such as acyl methyl taurine salts, polyoxyethylene alkyl ether sulfates, alkyl phosphates, polyoxyethylene alkyl ether phosphates, polyoxyethylene alkyl ethers, esters of fatty acids and lower and higher alcohols or ethylene oxide adducts thereof, polyoxyethylene polyoxypropylene alkyl ethers, polyoxyethylene alkyl phenyl ethers, polyoxyethylene alkyl amines, fatty acid alkanolamides, ethylene oxide adducts of esters of fatty acids and polyhydric alcohols, and their hydrogen Nonionic surfactants such as additives, amphoteric surfactants such as carboxybetaine, sulfobetaine, imidazoline derivatives, monoalkyltrimethylammonium chloride, dialkyldimethylammonium chloride, monoalkenyltrimethylammonium chloride, etc. Cationic surfactants, polyhydric alcohols such as ethylene glycol, propylene glycol, glycerin, sorbitol, mannitol, polyethylene glycol, lower alcohols, anionic, cationic,
nonionic water-soluble polymers, drugs such as vitamins,
Preservatives, disinfectants such as zinc pyrithione, trichlorocarbanilide, piroctone olamine, sulfur,
PH adjusters, other ultraviolet absorbers, antioxidants,
Sequestering agents, fragrances, pigments, insoluble fine powders of nylon, polyethylene, cellulose, chitin, inorganic compounds, etc. can be blended. Further, the hair cosmetic composition of the present invention can be used as desired, and for example, it can be used as shampoo, hair rinse, hair treatment, hair spray, hair setting lotion, hair tonic, hair styling agent, and the like. [Effects of the Invention] The hair cosmetic of the present invention imparts smoothness and moisture to hair, prevents hair from being damaged by solvents such as water, and particularly reduces stiffness of hair after bathing in the sea and tangles during shampooing. It is intended to prevent [Example] Next, the present invention will be explained in more detail by referring to Examples and Comparative Examples. The present invention is not limited thereby. The blending amount is in weight%. To measure the extent of hair damage, the following tensile strength test was conducted. Tensile strength measurement method Hair was immersed in the sample, and after 100 hours of irradiation with an ultraviolet fade meter (manufactured by Suga Test Instruments Co., Ltd.),
The tensile strength of the hair was measured using an Autograph (manufactured by Shimadzu Corporation), and the ratio of the measured value before treatment to the measured value at 20% stretching was determined. The results are shown in Table 1.

【表】 表1より明らかなように、ジ−パラメトキシケ
イ皮酸−モノ−2−エチルヘキサン酸グリセリル
を配合したものは、無添加のものと比べてかなり
毛髪の損傷を防止していることがわかる。また、
4−(1,1ジメチルエチル)−4′−メトキシジベ
ンゾイルメタンと併用した場合はさらにその効果
が増加していることがわかる。 次に使用後のなめらかさ等を評価するために以
下の使用テストを行なつた。 使用テスト パネルを12名を選出し、通常のシヤンプーを行
ない、乾燥する。次に試料を頭髪の右半分に塗布
し、海に入り、海水で髪をぬらし、その後自然乾
燥する(3時間)。この操作を2回繰り返し、乾
燥時の官能評価と、乾燥後さらにシヤンプーする
時の官能評価を行なつた。評価基準は以下の通り
である。 乾燥時のなめらかさ ◎……12名中10名以上が頭髪の右半分が左半分よ
りなめらかであると答えた場合 ○……12名中7名以上9名未満が頭髪の右半分が
左半分よりなめらかであると答えた場合 △……12名中4名以上6名未満が頭髪の右半分が
左半分よりなめらかであると答えた場合 ×……12名中3名未満が頭髪の右半分が左半分よ
りなめらかであると答えた場合 乾燥時のしつとりさ、きしみ、およびシヤンプ
ー時のなめらかさ、髪のもつれについても同様の
評価を行なつた。
[Table] As is clear from Table 1, products containing glyceryl di-paramethoxycinnamate-mono-2-ethylhexanoate significantly prevent hair damage compared to products without additives. I understand. Also,
It can be seen that the effect is further increased when used in combination with 4-(1,1 dimethylethyl)-4'-methoxydibenzoylmethane. Next, the following usage test was conducted to evaluate the smoothness etc. after use. Use test A panel of 12 people was selected and subjected to normal shampooing and drying. Next, apply the sample to the right half of the hair, go into the sea, wet the hair with seawater, and then let it dry naturally (3 hours). This operation was repeated twice, and a sensory evaluation was performed during drying and when shampooing was performed after drying. The evaluation criteria are as follows. Smoothness when drying ◎... 10 or more out of 12 people answered that the right half of their hair is smoother than the left half ○... 7 or more out of 12 but less than 9 people answered that the right half of their hair is smoother than the left half If you answered that the right half of your hair is smoother △...If at least 4 out of 12 people but less than 6 people answered that the right half of your hair is smoother than the left half...If less than 3 out of 12 people answered that the right half of your hair is smoother than the left half... If the person answered that the hair was smoother than the left half, the same evaluation was made for the firmness and squeaking when drying, the smoothness when shampooing, and the tangles of the hair.

【表】 表2より明らかなように、ジ−パラメトキシケ
イ皮酸−モノ−2−エチルヘキサン酸グリセリル
を配合したものは、無添加のものと比べてかなり
毛髪がしつとりしていたり、シヤンプー時の髪の
もつれを防止していることがわかる。また、4−
(1,1ジメチルエチル)−4′−メトキシジベンゾ
イルメタンと併用した場合はさらにそれらの効果
が増加していることがわかる。 実施例 5 次の配合組成より成るヘアスプレー(セツト)
を常法により調製した。 ジ−パラメトキシケイ皮酸−モノ−2−エチルヘ
キサン酸グリセリル 2.0% 4−(1,1ジメチルエチル)−4′−メトキシジベ
ンゾイルメタン 1.0 N−メタクリロイルエチルN,N−ジメチルアン
モニウム・α−N−メチルカルボキシベタイン・
メタクリル酸ブチル共重合体 3.0 エタノール 85.0 噴射剤 9.0 香 料 適量 実施例 6 次の配合組成より成るヘアスプレー(グロー)
を常法により調製した。 ジ−パラメトキシケイ皮酸−モノ−2−エチルヘ
キサン酸グリセリル 1.425% モノ−パラメトキシケイ皮酸−モノ−2−エチル
ヘキサン酸グリセリル 0.075 4−(1,1ジメチルエチル)−4′−メトキシジベ
ンゾイルメタン 0.5 プロピレングリコール 0.5 メチルフエニルポリシロキサン 0.5 流動パラフイン 3.0 エタノール 85.0 噴射剤 9.0 香 料 適量 実施例 7 次の配合組成より成るヘアセツトローシヨンを
常法により調製した。 ジ−パラメトキシケイ皮酸−モノ−2−エチルヘ
キサン酸グリセリル 0.1% 2−ヒドロキシ−4−メトキシベンゾフエノン
1.0 ビニルエチルエーテルマレイン酸エチル共重合体
1.0 プロピレングリコール 0.5 エタノール 50.0 香 料 適量 色 素 適量 水 残余 実施例5〜7はいずれも、乾燥時のなめらか
さ、しつとりさに優れ、またシヤンプー時の髪の
もつれ防止等の効果に優れていた。
[Table] As is clear from Table 2, the product containing glyceryl di-paramethoxycinnamate-mono-2-ethylhexanoate had significantly moisturized hair compared to the product without the additive. It can be seen that it prevents hair from getting tangled when shampooing. Also, 4-
It can be seen that these effects are further increased when used in combination with (1,1 dimethylethyl)-4'-methoxydibenzoylmethane. Example 5 Hairspray (set) consisting of the following composition
was prepared by a conventional method. Glyceryl di-paramethoxycinnamate-mono-2-ethylhexanoate 2.0% 4-(1,1 dimethylethyl)-4'-methoxydibenzoylmethane 1.0 N-methacryloylethyl N,N-dimethylammonium α-N -Methylcarboxybetaine・
Butyl methacrylate copolymer 3.0 Ethanol 85.0 Propellant 9.0 Fragrance Appropriate amount Example 6 Hairspray (Glow) consisting of the following composition
was prepared by a conventional method. Glyceryl di-paramethoxycinnamic acid-mono-2-ethylhexanoate 1.425% Glyceryl mono-paramethoxycinnamic acid-mono-2-ethylhexanoate 0.075 4-(1,1 dimethylethyl)-4'-methoxydi Benzoylmethane 0.5 Propylene glycol 0.5 Methylphenylpolysiloxane 0.5 Liquid paraffin 3.0 Ethanol 85.0 Propellant 9.0 Perfume Appropriate amount Example 7 A hair setting lotion having the following composition was prepared by a conventional method. Glyceryl di-paramethoxycinnamic acid-mono-2-ethylhexanoate 0.1% 2-hydroxy-4-methoxybenzophenone
1.0 Vinyl ethyl ether ethyl maleate copolymer
1.0 Propylene Glycol 0.5 Ethanol 50.0 Fragrance Appropriate amount Colorant Appropriate amount Water Residual Examples 5 to 7 were all excellent in smoothness and moisture when drying, and were also excellent in preventing hair from tangling during shampooing. .

Claims (1)

【特許請求の範囲】 1 下記一般式()〜()で表される化合物
の一種または二種以上と、UV−A領域紫外線
(波長が320〜400ナノメーター)防止剤の一種ま
たは二種以上とを配合することを特徴とする頭髪
化粧料。 (式中のR1は炭素数7〜17の飽和側鎖状脂肪酸
に由来するアルキル基を示し、R2は炭素数1〜
2のアルキル基を示し、R3はオルト又はパラ位
の−OCH3基を示す。
[Scope of Claims] 1. One or more compounds represented by the following general formulas () to () and one or more UV-A region ultraviolet (wavelength: 320 to 400 nanometers) inhibitors. A hair cosmetic characterized by containing the following. (R1 in the formula represents an alkyl group derived from a saturated side chain fatty acid having 7 to 17 carbon atoms, and R2 has 1 to 17 carbon atoms.
2 represents an alkyl group, and R3 represents an -OCH3 group at the ortho or para position.
JP11132986A 1986-05-15 1986-05-15 Hair cosmetic Granted JPS62267219A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP11132986A JPS62267219A (en) 1986-05-15 1986-05-15 Hair cosmetic

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP11132986A JPS62267219A (en) 1986-05-15 1986-05-15 Hair cosmetic

Publications (2)

Publication Number Publication Date
JPS62267219A JPS62267219A (en) 1987-11-19
JPH0475886B2 true JPH0475886B2 (en) 1992-12-02

Family

ID=14558447

Family Applications (1)

Application Number Title Priority Date Filing Date
JP11132986A Granted JPS62267219A (en) 1986-05-15 1986-05-15 Hair cosmetic

Country Status (1)

Country Link
JP (1) JPS62267219A (en)

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS60231607A (en) * 1984-04-28 1985-11-18 Kobayashi Kooc:Kk Antisuntan cosmetic
JPS619360A (en) * 1984-06-21 1986-01-16 Isuke Iizuka Setting checker for seat belt

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS60231607A (en) * 1984-04-28 1985-11-18 Kobayashi Kooc:Kk Antisuntan cosmetic
JPS619360A (en) * 1984-06-21 1986-01-16 Isuke Iizuka Setting checker for seat belt

Also Published As

Publication number Publication date
JPS62267219A (en) 1987-11-19

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