JPH0475886B2 - - Google Patents
Info
- Publication number
- JPH0475886B2 JPH0475886B2 JP61111329A JP11132986A JPH0475886B2 JP H0475886 B2 JPH0475886 B2 JP H0475886B2 JP 61111329 A JP61111329 A JP 61111329A JP 11132986 A JP11132986 A JP 11132986A JP H0475886 B2 JPH0475886 B2 JP H0475886B2
- Authority
- JP
- Japan
- Prior art keywords
- hair
- acid
- damage
- present
- mono
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 9
- 239000000194 fatty acid Substances 0.000 claims description 9
- 229930195729 fatty acid Natural products 0.000 claims description 9
- 150000004665 fatty acids Chemical class 0.000 claims description 8
- 239000002537 cosmetic Substances 0.000 claims description 7
- 239000003112 inhibitor Substances 0.000 claims description 5
- 150000001875 compounds Chemical class 0.000 claims description 2
- 125000000217 alkyl group Chemical group 0.000 claims 2
- 125000004432 carbon atom Chemical group C* 0.000 claims 2
- 125000000956 methoxy group Chemical group [H]C([H])([H])O* 0.000 claims 1
- 229920006395 saturated elastomer Polymers 0.000 claims 1
- -1 P-methoxycinnamic acid compound Chemical class 0.000 description 20
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 9
- 238000001035 drying Methods 0.000 description 7
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 6
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 6
- 230000006378 damage Effects 0.000 description 6
- 230000000694 effects Effects 0.000 description 6
- 125000003976 glyceryl group Chemical group [H]C([*])([H])C(O[H])([H])C(O[H])([H])[H] 0.000 description 5
- 239000003676 hair preparation Substances 0.000 description 5
- AFDXODALSZRGIH-UHFFFAOYSA-N p-coumaric acid methyl ether Natural products COC1=CC=C(C=CC(O)=O)C=C1 AFDXODALSZRGIH-UHFFFAOYSA-N 0.000 description 5
- 238000011282 treatment Methods 0.000 description 5
- 206010044625 Trichorrhexis Diseases 0.000 description 4
- 150000001298 alcohols Chemical class 0.000 description 4
- 230000003700 hair damage Effects 0.000 description 4
- 239000000203 mixture Substances 0.000 description 4
- 239000003921 oil Substances 0.000 description 4
- 239000002904 solvent Substances 0.000 description 4
- 230000009182 swimming Effects 0.000 description 4
- 238000012360 testing method Methods 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- AFDXODALSZRGIH-QPJJXVBHSA-N (E)-3-(4-methoxyphenyl)prop-2-enoic acid Chemical class COC1=CC=C(\C=C\C(O)=O)C=C1 AFDXODALSZRGIH-QPJJXVBHSA-N 0.000 description 3
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 3
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 3
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- 239000000654 additive Substances 0.000 description 3
- 239000003054 catalyst Substances 0.000 description 3
- 238000006243 chemical reaction Methods 0.000 description 3
- 238000007796 conventional method Methods 0.000 description 3
- 150000002148 esters Chemical class 0.000 description 3
- 238000011156 evaluation Methods 0.000 description 3
- 239000003205 fragrance Substances 0.000 description 3
- 239000008266 hair spray Substances 0.000 description 3
- 238000002156 mixing Methods 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 150000005846 sugar alcohols Polymers 0.000 description 3
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical class C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 2
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 2
- 206010019030 Hair colour changes Diseases 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- 229910019142 PO4 Inorganic materials 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- 150000005215 alkyl ethers Chemical class 0.000 description 2
- 229920001577 copolymer Polymers 0.000 description 2
- 239000000118 hair dye Substances 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 239000006210 lotion Substances 0.000 description 2
- DXGLGDHPHMLXJC-UHFFFAOYSA-N oxybenzone Chemical compound OC1=CC(OC)=CC=C1C(=O)C1=CC=CC=C1 DXGLGDHPHMLXJC-UHFFFAOYSA-N 0.000 description 2
- 235000021317 phosphate Nutrition 0.000 description 2
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Chemical compound [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 description 2
- 239000003380 propellant Substances 0.000 description 2
- 238000011160 research Methods 0.000 description 2
- 150000004072 triols Chemical class 0.000 description 2
- PSBDWGZCVUAZQS-UHFFFAOYSA-N (dimethylsulfonio)acetate Chemical compound C[S+](C)CC([O-])=O PSBDWGZCVUAZQS-UHFFFAOYSA-N 0.000 description 1
- LBLYYCQCTBFVLH-UHFFFAOYSA-N 2-Methylbenzenesulfonic acid Chemical compound CC1=CC=CC=C1S(O)(=O)=O LBLYYCQCTBFVLH-UHFFFAOYSA-N 0.000 description 1
- REPIEBKWEFJLGB-UHFFFAOYSA-N 4,5-dihydroxy-2-[(4-methoxyphenyl)methylidene]pentanoic acid;2-ethylhexanoic acid Chemical compound CCCCC(CC)C(O)=O.COC1=CC=C(C=C(CC(O)CO)C(O)=O)C=C1 REPIEBKWEFJLGB-UHFFFAOYSA-N 0.000 description 1
- ILWGOCDXJYCPQQ-UHFFFAOYSA-N 5-(dimethylamino)-2-methylpent-1-en-3-one Chemical compound CN(C)CCC(=O)C(C)=C ILWGOCDXJYCPQQ-UHFFFAOYSA-N 0.000 description 1
- 229920002101 Chitin Polymers 0.000 description 1
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 description 1
- FBPFZTCFMRRESA-KVTDHHQDSA-N D-Mannitol Chemical compound OC[C@@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-KVTDHHQDSA-N 0.000 description 1
- FBPFZTCFMRRESA-JGWLITMVSA-N D-glucitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-JGWLITMVSA-N 0.000 description 1
- 229930195725 Mannitol Natural products 0.000 description 1
- 239000004909 Moisturizer Substances 0.000 description 1
- 239000004677 Nylon Substances 0.000 description 1
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 1
- YBGZDTIWKVFICR-JLHYYAGUSA-N Octyl 4-methoxycinnamic acid Chemical compound CCCCC(CC)COC(=O)\C=C\C1=CC=C(OC)C=C1 YBGZDTIWKVFICR-JLHYYAGUSA-N 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 239000002202 Polyethylene glycol Substances 0.000 description 1
- QOSMNYMQXIVWKY-UHFFFAOYSA-N Propyl levulinate Chemical compound CCCOC(=O)CCC(C)=O QOSMNYMQXIVWKY-UHFFFAOYSA-N 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- 239000006096 absorbing agent Substances 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 150000003973 alkyl amines Chemical class 0.000 description 1
- 125000005037 alkyl phenyl group Chemical group 0.000 description 1
- 150000008051 alkyl sulfates Chemical class 0.000 description 1
- SOGAXMICEFXMKE-UHFFFAOYSA-N alpha-Methyl-n-butyl acrylate Natural products CCCCOC(=O)C(C)=C SOGAXMICEFXMKE-UHFFFAOYSA-N 0.000 description 1
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 1
- 239000002280 amphoteric surfactant Substances 0.000 description 1
- 125000000129 anionic group Chemical group 0.000 description 1
- 239000003945 anionic surfactant Substances 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 238000003287 bathing Methods 0.000 description 1
- 239000012964 benzotriazole Substances 0.000 description 1
- 238000004061 bleaching Methods 0.000 description 1
- 230000001680 brushing effect Effects 0.000 description 1
- 125000002091 cationic group Chemical group 0.000 description 1
- 239000003093 cationic surfactant Substances 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 238000004040 coloring Methods 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 239000000645 desinfectant Substances 0.000 description 1
- 238000002845 discoloration Methods 0.000 description 1
- 229940079593 drug Drugs 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 230000032050 esterification Effects 0.000 description 1
- 238000005886 esterification reaction Methods 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- 125000004494 ethyl ester group Chemical group 0.000 description 1
- 235000011187 glycerol Nutrition 0.000 description 1
- 239000003906 humectant Substances 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 125000004435 hydrogen atom Chemical class [H]* 0.000 description 1
- 150000002462 imidazolines Chemical class 0.000 description 1
- 230000003752 improving hair Effects 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 150000002484 inorganic compounds Chemical class 0.000 description 1
- 229910010272 inorganic material Inorganic materials 0.000 description 1
- 229940057995 liquid paraffin Drugs 0.000 description 1
- 239000000594 mannitol Substances 0.000 description 1
- 235000010355 mannitol Nutrition 0.000 description 1
- 238000000691 measurement method Methods 0.000 description 1
- 150000004702 methyl esters Chemical class 0.000 description 1
- 230000001333 moisturizer Effects 0.000 description 1
- 230000003020 moisturizing effect Effects 0.000 description 1
- 239000002736 nonionic surfactant Substances 0.000 description 1
- 229920001778 nylon Polymers 0.000 description 1
- 229960001679 octinoxate Drugs 0.000 description 1
- 239000002304 perfume Substances 0.000 description 1
- 229940083254 peripheral vasodilators imidazoline derivative Drugs 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- BTSZTGGZJQFALU-UHFFFAOYSA-N piroctone olamine Chemical compound NCCO.CC(C)(C)CC(C)CC1=CC(C)=CC(=O)N1O BTSZTGGZJQFALU-UHFFFAOYSA-N 0.000 description 1
- 229940081510 piroctone olamine Drugs 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 229920002503 polyoxyethylene-polyoxypropylene Polymers 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 229910000027 potassium carbonate Inorganic materials 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 239000003755 preservative agent Substances 0.000 description 1
- 235000013772 propylene glycol Nutrition 0.000 description 1
- 239000000376 reactant Substances 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 239000013535 sea water Substances 0.000 description 1
- 230000001953 sensory effect Effects 0.000 description 1
- 239000003352 sequestering agent Substances 0.000 description 1
- 239000002453 shampoo Substances 0.000 description 1
- 229910000029 sodium carbonate Inorganic materials 0.000 description 1
- 239000000600 sorbitol Substances 0.000 description 1
- 235000010356 sorbitol Nutrition 0.000 description 1
- 229940117986 sulfobetaine Drugs 0.000 description 1
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 229960005349 sulfur Drugs 0.000 description 1
- 230000003664 tensile strength of the hair Effects 0.000 description 1
- 230000001256 tonic effect Effects 0.000 description 1
- 238000005809 transesterification reaction Methods 0.000 description 1
- ICUTUKXCWQYESQ-UHFFFAOYSA-N triclocarban Chemical compound C1=CC(Cl)=CC=C1NC(=O)NC1=CC=C(Cl)C(Cl)=C1 ICUTUKXCWQYESQ-UHFFFAOYSA-N 0.000 description 1
- 229960001325 triclocarban Drugs 0.000 description 1
- 239000011782 vitamin Substances 0.000 description 1
- 229940088594 vitamin Drugs 0.000 description 1
- 229930003231 vitamin Natural products 0.000 description 1
- 235000013343 vitamin Nutrition 0.000 description 1
- 229920003169 water-soluble polymer Polymers 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
- 229940043810 zinc pyrithione Drugs 0.000 description 1
- PICXIOQBANWBIZ-UHFFFAOYSA-N zinc;1-oxidopyridine-2-thione Chemical compound [Zn+2].[O-]N1C=CC=CC1=S.[O-]N1C=CC=CC1=S PICXIOQBANWBIZ-UHFFFAOYSA-N 0.000 description 1
- 239000004711 α-olefin Substances 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q17/00—Barrier preparations; Preparations brought into direct contact with the skin for affording protection against external influences, e.g. sunlight, X-rays or other harmful rays, corrosive materials, bacteria or insect stings
- A61Q17/04—Topical preparations for affording protection against sunlight or other radiation; Topical sun tanning preparations
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/37—Esters of carboxylic acids
- A61K8/375—Esters of carboxylic acids the alcohol moiety containing more than one hydroxy group
Landscapes
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Dermatology (AREA)
- Emergency Medicine (AREA)
- Birds (AREA)
- Epidemiology (AREA)
- Cosmetics (AREA)
Description
[産業上の利用分野]
本発明は毛髪になめらかさやしつとりさを賦与
し、毛髪の損傷、特に海やプールでの水泳後の髪
の変色、いたみ、枝毛、切毛、べたつき等を防止
する頭髪化粧料に関するものである。
[従来の技術]
一般に、毛髪はブラツシング、ヘアドライヤー
等の物理的処理、パーマ、ブリーチ、ヘアダイな
どの美容上の化合物処理等を受けることにより損
傷することが知られている。一方、海やプールで
の水泳後の毛髪の損傷、例えば、髪の変色、いた
み、枝毛、切毛、べたつき等も大きな問題となつ
ている。従来は、これらの物理的処理や化学的処
理による損傷毛に対しては、つやや、潤いを与え
るために油分や保湿剤を頭髪化粧料に配合し、改
善しようとする試みがなされてきた。
[発明が解決しようとする問題点]
しかしながら、これらの油分や保湿剤を用いた
頭髪化粧料は、パーマ、ブリーチ、ヘアダイ等に
よる損傷の少ない、所謂健康毛に対しては、その
保湿効果により毛髪に柔軟性を賦与することがで
きるが、損傷の著しい、所謂ダメージ毛に対して
は、毛髪からの水分揮散を抑制することができ
ず、望ましい柔軟性を与えることはできなかつ
た。特に海やプールでの水泳後の毛髪は変色、い
たみ、枝毛、切毛、パサツキ、キシミがひどく、
著しく損傷しているにもかかわらず、この損傷を
改善する手段は未だ見つかつていない。
[問題点を解決するための手段]
本発明者等は上記の事情に鑑み、鋭意研究を重
ねた結果、毛髪の損傷に水等の溶媒が大きく影響
することを見出し、この水の影響についてさらに
研究を進めた結果、特定の物質、またはこの物質
とUV−A領域紫外線防止剤とを頭髪化粧料に配
合することにより、海やプールでの水泳後の髪の
変色、いたみ、枝毛、切毛、パサツキ、キシミ、
シヤンプー時の髪のもつれを防止し、なめらかさ
やしつとりさを賦与することを見出し、本発明を
完成するに至つた。
即ち、本発明は一般式()〜()で表され
るP−メトキシケイ皮酸化合物の一種または二種
以上を配合することを特徴とする頭髪化粧料を提
供するものである。
以下、本発明の構成について詳述する。
本発明のP−メトキシケイ皮酸化合物は、例え
ば以下のように合成することができる。P−メト
キシケイ皮酸、常温液状脂肪酸と、各種トリオー
ルを直接無触媒又は一般的なエステル化触媒を用
いて合成するか、P−メトキシケイ皮酸、常温液
状脂肪酸の低級アルコールエステル、例えばメチ
ルエステル、エチルエステル、プロピルエステル
等と各種トリオールとのエステル交換反応により
容易に合成することができる。ここで用いられる
触媒としては、例えば硫酸、塩酸、リン酸、P−
トルエンスルホン酸、水酸化ナトリウム、水酸化
カリウム、炭酸ナトリウム、炭酸カリウム等であ
る。反応は無溶媒又はトルエン、キシレン等の水
共沸溶媒中130℃〜250℃で行なわれるが、低温で
は反応の進行が遅く、また高温での反応は、反応
物の着色が著しくなるため、好ましくは160℃〜
220℃で行なうのが良い。
P−メトキシケイ皮酸化合物の配合量は、頭髪
化粧料全量の0.01〜10重量%が好ましく、さらに
好ましくは0.1〜3重量%である。
本発明においては、P−メトキシケイ皮酸化合
物単独で配合しても充分効果は発揮されるが、こ
れとUV−A領域紫外線(波長が320〜400ナノメ
ーター)防止剤とを併用すると、より優れた効果
が発揮されるので好ましい。
UV−A領域紫外線(波長が320〜400ナノメー
ター)防止剤としては、以下のようなものが挙げ
られる。例えば、4(1,1ジメチルエチル)−
4′−メトキシジベンゾイルメタン{商品名:パル
ソール(登録商標)1789、ジボダン社製}、2−
ヒドロキシ−4−メトキシベンゾフエノン及びそ
の誘導体や2,2′−ヒドロキシ−5−メチルフエ
ニル−ベンゾトリアゾール等が挙げられる。これ
らの中でも効果の面から4−(1,1ジメチルエ
チル)−4′−メトキシジベンゾイルメタンが、最
も好ましい。
UV−A領域紫外線(波長が320〜400ナノメー
ター)防止剤の配合量は、頭髪化粧料全量の0.01
〜10重量%が好ましく、さらに好ましくは0.1〜
3重量%である。
本発明の毛髪化粧料には上記必須成分に加え
て、必要により、脂肪酸と低級アルコールおよび
多価アルコールのエステル、パラフイン系炭化水
素、脂肪酸、直鎖あるいは分枝の高級アルコー
ル、アルキルグリセリンエーテル、シリコン油等
の油分、ポリオキシエチレンアルキルエーテル酢
酸塩、高級脂肪酸塩、N−アシルアミノ酸塩、ア
ルキル硫酸塩、アルキルアリル硫酸塩、α−オレ
フインスルホン酸塩、アシルイセチオン酸塩、ア
ルキルスルホコハク酸塩、N−アシルメチルタウ
リン塩、ポリオキシエチレンアルキルエーテル硫
酸塩、アルキルリン酸塩、ポリオキシエチレンア
ルキルエーテルリン酸塩等のアニオン性界面活性
剤、ポリオキシエチレンアルキルエーテル、脂肪
酸と低級アルコールおよび高級アルコールとのエ
ステルあるいはそれらのエチレンオキサイド付加
物、ポリオキシエチレンポリオキシプロピレンア
ルキルエーテル、ポリオキシエチレンアルキルフ
エニルエーテル、ポリオキシエチレンアルキルア
ミン、脂肪酸アルカノールアミド、脂肪酸と多価
アルコールのエステルのエチレンオキサイド付加
物およびその水素添加物等の非イオン性界面活性
剤、カルボキシベタイン、スルホベタイン、イミ
ダゾリン誘導体等の両性界面活性剤、モノアルキ
ルトリメチルアンモニウムの塩化物、ジアルキル
ジメチルアンモニウムの塩化物、モノアルケニル
トリメチルアンモニウムの塩化物等のカチオン性
界面活性剤、エチレングリコール、プロピレング
リコール、グリセリン、ソルビトール、マンニト
ールポリエチレングリコール等の多価アルコー
ル、低級アルコール、アニオン性、カチオン性、
非イオン性の水溶性高分子、ビタミン等の薬剤、
防腐剤、ジンクピリチオン、トリクロロカルバニ
リド、ピロクトンオラミン、イオウ等の殺菌剤、
PH調整剤、その他の紫外線吸収剤、酸化防止剤、
金属イオン封鎖剤、香料、色素、ナイロン、ポリ
エチレン、セルロース、キチン、無機化合物等の
不溶性微粉末等を配合することができる。
また、本発明の頭髪化粧料の用途も任意であ
り、例えばシヤンプー、ヘアリンス、ヘアトリー
トメント、ヘアスプレー、ヘアセツトローシヨ
ン、養毛剤、整髪剤等として使用される。
[発明の効果]
本発明の毛髪化粧料は毛髪になめらかさやしつ
とりさを賦与し、毛髪の水等の溶媒による損傷を
防止し、特に海水浴後の髪のゴワツキ、シヤンプ
ー時の髪のもつれを防止するものである。
[実施例]
次に実施例および比較例をあげて、本発明をさ
らに詳細に説明する。本発明はこれにより限定さ
れるものではない。配合量は重量%である。
毛髪の損傷の程度を測るために、以下の引つ張
り強度試験を行なつた。
引つ張り強度測定法
毛髪を試料に浸漬し、紫外線フエードメーター
(スガ試験機株式会社製)にて100時間照射後に、
オートグラフ(島津製作所製)にて、毛髪の引つ
張り強度を測定し、処理前の測定値との20%延伸
時での比を求めた。
結果を表1に示す。
[Industrial Application Field] The present invention imparts smoothness and moisture to hair, and prevents hair damage, especially discoloration, damage, split ends, cut hair, stickiness, etc. of hair after swimming in the sea or pool. The present invention relates to hair cosmetics. [Prior Art] It is generally known that hair is damaged by physical treatments such as brushing, hair drying, and cosmetic compound treatments such as perming, bleaching, and hair dye. On the other hand, damage to hair after swimming in the sea or pool, such as hair discoloration, damage, split ends, cut hair, and stickiness, has also become a major problem. In the past, attempts have been made to improve hair damaged by these physical and chemical treatments by adding oils and humectants to hair cosmetics to give shine and moisture. [Problems to be Solved by the Invention] However, hair cosmetics using these oils and moisturizers have a moisturizing effect on so-called healthy hair, which is less damaged by perms, bleaches, hair dyes, etc. However, for severely damaged hair, so-called damaged hair, moisture volatilization from the hair cannot be suppressed, and desired flexibility cannot be imparted. Especially after swimming in the sea or pool, hair becomes discolored, damaged, split ends, cut, dry, and creased.
Despite the significant damage, no means have yet been found to ameliorate this damage. [Means for Solving the Problems] In view of the above circumstances, the present inventors have conducted intensive research and found that solvents such as water have a large effect on hair damage, and have further investigated the effects of water. As a result of our research, we have found that by incorporating a specific substance or this substance and a UV-A UV inhibitor into hair cosmetics, hair discoloration, damage, split ends, and breakage after swimming in the sea or pool can be prevented. Hair, dryness, squeaks,
The inventors have discovered that hair can be prevented from becoming tangled during shampooing and impart smoothness and moisture, leading to the completion of the present invention. That is, the present invention provides a hair cosmetic characterized by blending one or more types of P-methoxycinnamic acid compounds represented by general formulas () to (). Hereinafter, the configuration of the present invention will be explained in detail. The P-methoxycinnamic acid compound of the present invention can be synthesized, for example, as follows. P-methoxycinnamic acid, a fatty acid that is liquid at room temperature, and various triols are directly synthesized without a catalyst or using a general esterification catalyst, or a lower alcohol ester of P-methoxycinnamic acid, a fatty acid that is liquid at room temperature, such as methyl ester. , ethyl ester, propyl ester, etc., and various triols can be easily synthesized by transesterification. Examples of catalysts used here include sulfuric acid, hydrochloric acid, phosphoric acid, P-
These include toluenesulfonic acid, sodium hydroxide, potassium hydroxide, sodium carbonate, potassium carbonate, etc. The reaction is carried out without a solvent or in an aqueous azeotropic solvent such as toluene or xylene at 130°C to 250°C, but the reaction progresses slowly at low temperatures, and reaction at high temperatures is not preferred because the coloring of the reactants becomes significant. is 160℃~
It is best to do this at 220℃. The blending amount of the P-methoxycinnamic acid compound is preferably 0.01 to 10% by weight, more preferably 0.1 to 3% by weight, based on the total amount of the hair cosmetic. In the present invention, even if the P-methoxycinnamic acid compound is blended alone, it is sufficiently effective, but when combined with a UV-A region ultraviolet (wavelength: 320 to 400 nanometers) inhibitor, it becomes even more effective. It is preferable because it exhibits excellent effects. Examples of UV-A region ultraviolet (wavelength: 320 to 400 nanometers) inhibitors include the following. For example, 4(1,1 dimethylethyl)-
4'-Methoxydibenzoylmethane {trade name: Parsol (registered trademark) 1789, manufactured by Givaudan}, 2-
Examples include hydroxy-4-methoxybenzophenone and its derivatives, and 2,2'-hydroxy-5-methylphenyl-benzotriazole. Among these, 4-(1,1 dimethylethyl)-4'-methoxydibenzoylmethane is most preferred from the viewpoint of effectiveness. The amount of UV-A region ultraviolet rays (wavelength: 320 to 400 nanometers) inhibitor is 0.01 of the total amount of hair cosmetics.
~10% by weight is preferred, more preferably 0.1~
It is 3% by weight. In addition to the above-mentioned essential ingredients, the hair cosmetic of the present invention may include, if necessary, esters of fatty acids and lower alcohols and polyhydric alcohols, paraffinic hydrocarbons, fatty acids, linear or branched higher alcohols, alkylglycerin ethers, and silicone. Oil such as oil, polyoxyethylene alkyl ether acetate, higher fatty acid salt, N-acylamino acid salt, alkyl sulfate, alkylaryl sulfate, α-olefin sulfonate, acyl isethionate, alkyl sulfosuccinate, N- Anionic surfactants such as acyl methyl taurine salts, polyoxyethylene alkyl ether sulfates, alkyl phosphates, polyoxyethylene alkyl ether phosphates, polyoxyethylene alkyl ethers, esters of fatty acids and lower and higher alcohols or ethylene oxide adducts thereof, polyoxyethylene polyoxypropylene alkyl ethers, polyoxyethylene alkyl phenyl ethers, polyoxyethylene alkyl amines, fatty acid alkanolamides, ethylene oxide adducts of esters of fatty acids and polyhydric alcohols, and their hydrogen Nonionic surfactants such as additives, amphoteric surfactants such as carboxybetaine, sulfobetaine, imidazoline derivatives, monoalkyltrimethylammonium chloride, dialkyldimethylammonium chloride, monoalkenyltrimethylammonium chloride, etc. Cationic surfactants, polyhydric alcohols such as ethylene glycol, propylene glycol, glycerin, sorbitol, mannitol, polyethylene glycol, lower alcohols, anionic, cationic,
nonionic water-soluble polymers, drugs such as vitamins,
Preservatives, disinfectants such as zinc pyrithione, trichlorocarbanilide, piroctone olamine, sulfur,
PH adjusters, other ultraviolet absorbers, antioxidants,
Sequestering agents, fragrances, pigments, insoluble fine powders of nylon, polyethylene, cellulose, chitin, inorganic compounds, etc. can be blended. Further, the hair cosmetic composition of the present invention can be used as desired, and for example, it can be used as shampoo, hair rinse, hair treatment, hair spray, hair setting lotion, hair tonic, hair styling agent, and the like. [Effects of the Invention] The hair cosmetic of the present invention imparts smoothness and moisture to hair, prevents hair from being damaged by solvents such as water, and particularly reduces stiffness of hair after bathing in the sea and tangles during shampooing. It is intended to prevent [Example] Next, the present invention will be explained in more detail by referring to Examples and Comparative Examples. The present invention is not limited thereby. The blending amount is in weight%. To measure the extent of hair damage, the following tensile strength test was conducted. Tensile strength measurement method Hair was immersed in the sample, and after 100 hours of irradiation with an ultraviolet fade meter (manufactured by Suga Test Instruments Co., Ltd.),
The tensile strength of the hair was measured using an Autograph (manufactured by Shimadzu Corporation), and the ratio of the measured value before treatment to the measured value at 20% stretching was determined. The results are shown in Table 1.
【表】
表1より明らかなように、ジ−パラメトキシケ
イ皮酸−モノ−2−エチルヘキサン酸グリセリル
を配合したものは、無添加のものと比べてかなり
毛髪の損傷を防止していることがわかる。また、
4−(1,1ジメチルエチル)−4′−メトキシジベ
ンゾイルメタンと併用した場合はさらにその効果
が増加していることがわかる。
次に使用後のなめらかさ等を評価するために以
下の使用テストを行なつた。
使用テスト
パネルを12名を選出し、通常のシヤンプーを行
ない、乾燥する。次に試料を頭髪の右半分に塗布
し、海に入り、海水で髪をぬらし、その後自然乾
燥する(3時間)。この操作を2回繰り返し、乾
燥時の官能評価と、乾燥後さらにシヤンプーする
時の官能評価を行なつた。評価基準は以下の通り
である。
乾燥時のなめらかさ
◎……12名中10名以上が頭髪の右半分が左半分よ
りなめらかであると答えた場合
○……12名中7名以上9名未満が頭髪の右半分が
左半分よりなめらかであると答えた場合
△……12名中4名以上6名未満が頭髪の右半分が
左半分よりなめらかであると答えた場合
×……12名中3名未満が頭髪の右半分が左半分よ
りなめらかであると答えた場合
乾燥時のしつとりさ、きしみ、およびシヤンプ
ー時のなめらかさ、髪のもつれについても同様の
評価を行なつた。[Table] As is clear from Table 1, products containing glyceryl di-paramethoxycinnamate-mono-2-ethylhexanoate significantly prevent hair damage compared to products without additives. I understand. Also,
It can be seen that the effect is further increased when used in combination with 4-(1,1 dimethylethyl)-4'-methoxydibenzoylmethane. Next, the following usage test was conducted to evaluate the smoothness etc. after use. Use test A panel of 12 people was selected and subjected to normal shampooing and drying. Next, apply the sample to the right half of the hair, go into the sea, wet the hair with seawater, and then let it dry naturally (3 hours). This operation was repeated twice, and a sensory evaluation was performed during drying and when shampooing was performed after drying. The evaluation criteria are as follows. Smoothness when drying ◎... 10 or more out of 12 people answered that the right half of their hair is smoother than the left half ○... 7 or more out of 12 but less than 9 people answered that the right half of their hair is smoother than the left half If you answered that the right half of your hair is smoother △...If at least 4 out of 12 people but less than 6 people answered that the right half of your hair is smoother than the left half...If less than 3 out of 12 people answered that the right half of your hair is smoother than the left half... If the person answered that the hair was smoother than the left half, the same evaluation was made for the firmness and squeaking when drying, the smoothness when shampooing, and the tangles of the hair.
【表】
表2より明らかなように、ジ−パラメトキシケ
イ皮酸−モノ−2−エチルヘキサン酸グリセリル
を配合したものは、無添加のものと比べてかなり
毛髪がしつとりしていたり、シヤンプー時の髪の
もつれを防止していることがわかる。また、4−
(1,1ジメチルエチル)−4′−メトキシジベンゾ
イルメタンと併用した場合はさらにそれらの効果
が増加していることがわかる。
実施例 5
次の配合組成より成るヘアスプレー(セツト)
を常法により調製した。
ジ−パラメトキシケイ皮酸−モノ−2−エチルヘ
キサン酸グリセリル 2.0%
4−(1,1ジメチルエチル)−4′−メトキシジベ
ンゾイルメタン 1.0
N−メタクリロイルエチルN,N−ジメチルアン
モニウム・α−N−メチルカルボキシベタイン・
メタクリル酸ブチル共重合体 3.0
エタノール 85.0
噴射剤 9.0
香 料 適量
実施例 6
次の配合組成より成るヘアスプレー(グロー)
を常法により調製した。
ジ−パラメトキシケイ皮酸−モノ−2−エチルヘ
キサン酸グリセリル 1.425%
モノ−パラメトキシケイ皮酸−モノ−2−エチル
ヘキサン酸グリセリル 0.075
4−(1,1ジメチルエチル)−4′−メトキシジベ
ンゾイルメタン 0.5
プロピレングリコール 0.5
メチルフエニルポリシロキサン 0.5
流動パラフイン 3.0
エタノール 85.0
噴射剤 9.0
香 料 適量
実施例 7
次の配合組成より成るヘアセツトローシヨンを
常法により調製した。
ジ−パラメトキシケイ皮酸−モノ−2−エチルヘ
キサン酸グリセリル 0.1%
2−ヒドロキシ−4−メトキシベンゾフエノン
1.0
ビニルエチルエーテルマレイン酸エチル共重合体
1.0
プロピレングリコール 0.5
エタノール 50.0
香 料 適量
色 素 適量
水 残余
実施例5〜7はいずれも、乾燥時のなめらか
さ、しつとりさに優れ、またシヤンプー時の髪の
もつれ防止等の効果に優れていた。[Table] As is clear from Table 2, the product containing glyceryl di-paramethoxycinnamate-mono-2-ethylhexanoate had significantly moisturized hair compared to the product without the additive. It can be seen that it prevents hair from getting tangled when shampooing. Also, 4-
It can be seen that these effects are further increased when used in combination with (1,1 dimethylethyl)-4'-methoxydibenzoylmethane. Example 5 Hairspray (set) consisting of the following composition
was prepared by a conventional method. Glyceryl di-paramethoxycinnamate-mono-2-ethylhexanoate 2.0% 4-(1,1 dimethylethyl)-4'-methoxydibenzoylmethane 1.0 N-methacryloylethyl N,N-dimethylammonium α-N -Methylcarboxybetaine・
Butyl methacrylate copolymer 3.0 Ethanol 85.0 Propellant 9.0 Fragrance Appropriate amount Example 6 Hairspray (Glow) consisting of the following composition
was prepared by a conventional method. Glyceryl di-paramethoxycinnamic acid-mono-2-ethylhexanoate 1.425% Glyceryl mono-paramethoxycinnamic acid-mono-2-ethylhexanoate 0.075 4-(1,1 dimethylethyl)-4'-methoxydi Benzoylmethane 0.5 Propylene glycol 0.5 Methylphenylpolysiloxane 0.5 Liquid paraffin 3.0 Ethanol 85.0 Propellant 9.0 Perfume Appropriate amount Example 7 A hair setting lotion having the following composition was prepared by a conventional method. Glyceryl di-paramethoxycinnamic acid-mono-2-ethylhexanoate 0.1% 2-hydroxy-4-methoxybenzophenone
1.0 Vinyl ethyl ether ethyl maleate copolymer
1.0 Propylene Glycol 0.5 Ethanol 50.0 Fragrance Appropriate amount Colorant Appropriate amount Water Residual Examples 5 to 7 were all excellent in smoothness and moisture when drying, and were also excellent in preventing hair from tangling during shampooing. .
Claims (1)
の一種または二種以上と、UV−A領域紫外線
(波長が320〜400ナノメーター)防止剤の一種ま
たは二種以上とを配合することを特徴とする頭髪
化粧料。 (式中のR1は炭素数7〜17の飽和側鎖状脂肪酸
に由来するアルキル基を示し、R2は炭素数1〜
2のアルキル基を示し、R3はオルト又はパラ位
の−OCH3基を示す。[Scope of Claims] 1. One or more compounds represented by the following general formulas () to () and one or more UV-A region ultraviolet (wavelength: 320 to 400 nanometers) inhibitors. A hair cosmetic characterized by containing the following. (R1 in the formula represents an alkyl group derived from a saturated side chain fatty acid having 7 to 17 carbon atoms, and R2 has 1 to 17 carbon atoms.
2 represents an alkyl group, and R3 represents an -OCH3 group at the ortho or para position.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP11132986A JPS62267219A (en) | 1986-05-15 | 1986-05-15 | Hair cosmetic |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP11132986A JPS62267219A (en) | 1986-05-15 | 1986-05-15 | Hair cosmetic |
Publications (2)
Publication Number | Publication Date |
---|---|
JPS62267219A JPS62267219A (en) | 1987-11-19 |
JPH0475886B2 true JPH0475886B2 (en) | 1992-12-02 |
Family
ID=14558447
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP11132986A Granted JPS62267219A (en) | 1986-05-15 | 1986-05-15 | Hair cosmetic |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPS62267219A (en) |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS60231607A (en) * | 1984-04-28 | 1985-11-18 | Kobayashi Kooc:Kk | Antisuntan cosmetic |
JPS619360A (en) * | 1984-06-21 | 1986-01-16 | Isuke Iizuka | Setting checker for seat belt |
-
1986
- 1986-05-15 JP JP11132986A patent/JPS62267219A/en active Granted
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS60231607A (en) * | 1984-04-28 | 1985-11-18 | Kobayashi Kooc:Kk | Antisuntan cosmetic |
JPS619360A (en) * | 1984-06-21 | 1986-01-16 | Isuke Iizuka | Setting checker for seat belt |
Also Published As
Publication number | Publication date |
---|---|
JPS62267219A (en) | 1987-11-19 |
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