JPH0473183A - Transfer sheet for exterior decorative material - Google Patents
Transfer sheet for exterior decorative materialInfo
- Publication number
- JPH0473183A JPH0473183A JP2283632A JP28363290A JPH0473183A JP H0473183 A JPH0473183 A JP H0473183A JP 2283632 A JP2283632 A JP 2283632A JP 28363290 A JP28363290 A JP 28363290A JP H0473183 A JPH0473183 A JP H0473183A
- Authority
- JP
- Japan
- Prior art keywords
- transfer
- acrylic resin
- vehicle
- transfer sheet
- layer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000000463 material Substances 0.000 title claims abstract description 27
- 238000007639 printing Methods 0.000 claims abstract description 31
- 229920000178 Acrylic resin Polymers 0.000 claims abstract description 25
- 239000004925 Acrylic resin Substances 0.000 claims abstract description 25
- 239000000203 mixture Substances 0.000 claims abstract description 11
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 7
- 229920002433 Vinyl chloride-vinyl acetate copolymer Polymers 0.000 claims abstract description 6
- 239000007787 solid Substances 0.000 claims abstract description 6
- 239000010410 layer Substances 0.000 abstract description 32
- 239000011241 protective layer Substances 0.000 abstract description 5
- 238000000034 method Methods 0.000 abstract description 4
- 239000002985 plastic film Substances 0.000 abstract description 3
- 229920006255 plastic film Polymers 0.000 abstract description 3
- 239000000976 ink Substances 0.000 description 17
- 239000011347 resin Substances 0.000 description 7
- 229920005989 resin Polymers 0.000 description 7
- 238000004519 manufacturing process Methods 0.000 description 5
- -1 polyethylene terephthalate Polymers 0.000 description 4
- 229920000139 polyethylene terephthalate Polymers 0.000 description 4
- 239000005020 polyethylene terephthalate Substances 0.000 description 4
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- 239000011248 coating agent Substances 0.000 description 3
- 238000000576 coating method Methods 0.000 description 3
- 229920001577 copolymer Polymers 0.000 description 3
- 238000007646 gravure printing Methods 0.000 description 3
- 239000003973 paint Substances 0.000 description 3
- 239000002904 solvent Substances 0.000 description 3
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 2
- 229920002678 cellulose Polymers 0.000 description 2
- 239000001913 cellulose Substances 0.000 description 2
- 238000001723 curing Methods 0.000 description 2
- 239000010438 granite Substances 0.000 description 2
- 239000000123 paper Substances 0.000 description 2
- 229920002803 thermoplastic polyurethane Polymers 0.000 description 2
- 239000002966 varnish Substances 0.000 description 2
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 2
- 229920002554 vinyl polymer Polymers 0.000 description 2
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 description 1
- KRHYYFGTRYWZRS-UHFFFAOYSA-M Fluoride anion Chemical compound [F-] KRHYYFGTRYWZRS-UHFFFAOYSA-M 0.000 description 1
- 239000002033 PVDF binder Substances 0.000 description 1
- 239000004696 Poly ether ether ketone Substances 0.000 description 1
- 239000004952 Polyamide Substances 0.000 description 1
- 239000004642 Polyimide Substances 0.000 description 1
- 239000004793 Polystyrene Substances 0.000 description 1
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- QRUDEWIWKLJBPS-UHFFFAOYSA-N benzotriazole Chemical compound C1=CC=C2N[N][N]C2=C1 QRUDEWIWKLJBPS-UHFFFAOYSA-N 0.000 description 1
- 239000012964 benzotriazole Substances 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 238000002845 discoloration Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000005562 fading Methods 0.000 description 1
- XUCNUKMRBVNAPB-UHFFFAOYSA-N fluoroethene Chemical group FC=C XUCNUKMRBVNAPB-UHFFFAOYSA-N 0.000 description 1
- 239000011381 foam concrete Substances 0.000 description 1
- 239000011888 foil Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 230000005865 ionizing radiation Effects 0.000 description 1
- 238000013008 moisture curing Methods 0.000 description 1
- 238000010422 painting Methods 0.000 description 1
- 239000011088 parchment paper Substances 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 229920001230 polyarylate Polymers 0.000 description 1
- 229920000515 polycarbonate Polymers 0.000 description 1
- 239000004417 polycarbonate Substances 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 229920002530 polyetherether ketone Polymers 0.000 description 1
- 229920001721 polyimide Polymers 0.000 description 1
- 229920000098 polyolefin Polymers 0.000 description 1
- 229920005672 polyolefin resin Polymers 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 229920002981 polyvinylidene fluoride Polymers 0.000 description 1
- 238000007650 screen-printing Methods 0.000 description 1
- 239000002893 slag Substances 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 239000006097 ultraviolet radiation absorber Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Landscapes
- Printing Methods (AREA)
- Duplication Or Marking (AREA)
- Decoration By Transfer Pictures (AREA)
- Laminated Bodies (AREA)
Abstract
Description
本発明は、外装用の化粧材の製造に使用する転写シート
に関する。The present invention relates to a transfer sheet used for manufacturing decorative materials for exterior use.
外装用化粧材の製造に当って、塗装では実現できないよ
うな意匠をもった製品をつくろうとする場合は、転写法
が利用されている。 一般にこの目的で使用する転写シ
ートは、離型性を有する転写台紙たとえばプラスチック
フィルムの上に、ビヒクルとしてセルロース誘導体、ス
チレン系樹脂またはビニル樹脂を用いたインキで絵柄を
印刷したものがほとんどである。
これらの転写シートは、それによって与えられる絵柄印
刷層が耐候性に乏しいため、外装用の化粧材や屋外で使
用する成形品の絵付けに使用したとき、製品は耐久性の
低いものである。
硬化性樹脂をビヒクルとするインキで絵柄を印刷した転
写シートは、耐候性のよい外装化粧材を与えることがで
きるが、その製造に加熱や電離敢剣線の照射などインキ
層の硬化工程を必要とするから、コスト高を免れない。
［発明が解決しようとする課題１
本発明の目的は、絵柄印刷層の耐候性か高く、従って耐
久性のよい外装用化粧材を与えることかでき、しかも製
造容易でコストの低い転写シートを提供することにおる
。
［課題を解決するための手段］
本発明の外装化粧材用転写シートは、基本的には、プラ
スチックフィルムなどの離型性を有する転写台紙上に、
アクリル樹脂またはアクリル樹脂と塩ビ−酢ビ共重合体
との混合物をビヒクルとするインキを用いるか、あるい
はフッ素樹脂またはフッ素樹脂とアクリル樹脂との混合
物をビヒクルとするインキを用いた絵柄印刷層を設【ブ
てなる。
被転写材の下地を隠蔽したいときや、転写に当って被転
写材に転写台紙が接着する心配があるときは、第１図に
示すように、絵柄印刷層（２）の上に、絵柄を印刷した
インキと同様なビヒクルを用いた着色インキで、ベタ印
刷層（３）をさらに設けるとよい。
第２図に示すように、絵柄印刷層（２）と転写台紙（１
）との剥離性を向上させるために、両者の間にアクリル
樹脂系の剥離剤層（４）を設けるとよい。 剥離剤層は
転写後に絵柄印刷層の保護層となって耐候性を向上ざぜ
るから、これは推奨される態様である。 剥離剤にベン
ゾトリアゾルや亜鉛粉末などの紫外線吸収剤を添加して
おくと、絵柄印刷層の変色、退色を防止でき好ましい。
第２図の例も、ベタ印刷層（３）を有する。
転写台紙は、従来から転写シートに使用して来たものと
同様でよい。 適当な材料の例をあげれば、プラスチッ
クフィルムでは、ポリエステル、ポリオレフィン、ポリ
アミド、ポリイミド、ビニル樹脂、セルロース、ポリス
チレン、ポリカーボネート、ポリエーテルエーテルケト
ン、ボリアリレートのフィルムであり、絵柄を印刷する
インキのビヒクルによっては、アクリル樹脂やフッ素樹
脂のフィルムを使用してもよい。 あるいは、薄葉紙、
上質紙、硫酸紙などの紙にポリオレフィン樹脂ヤシリ］
ン樹脂で離型層を設けたものも使用できる。 これらの
中でも、とくに二軸延伸したポリエチレンテレフタレー
トフィルムは、寸法安定性、耐熱性および離型性にすぐ
れている点て最適である。 転写台紙の厚さは、材料や
用途にもよるが、一般に５〜２００μｍか適当である。
絵柄の印刷および着色ペタ印刷に使用するインキのビヒ
クルとして、アクリル樹脂を単独で使用した場合、印刷
層か剛いために曲面への転写が難しい。 アクリル樹脂
と塩ビ−酢ビ共重合体との混合物を使用すればこの点は
改善されるか、塩ビ酢ビ共重合体の含有量が多くなると
耐候性が低下するから、両者の割合は、アクリル樹脂：
塩ビ酢ビ共重合体−５：５〜８：２の範囲にすることが
好ましい。 また、フッ素樹脂は溶剤への溶解度が小さ
いため、それを単独で使用したインキは厚膜の印刷層を
設けるには適しない。 アクリル樹脂を混合して使用す
ることにより、転写シートの用途が広がり好ましい。
混合比は重量で、アクリル樹脂：フッ素樹脂−８：２〜
３ニアの範囲が適当である。 とくにインキ層の耐候性
と可撓性とを両立させるためには、アクリル樹脂：フッ
素樹脂−８：２〜５：５か好ましい。
本発明で使用するフッ素樹脂は、溶剤に比較的よく溶け
るもの、たとえばポリフッ化ヒニリデンまたはフッ化エ
チレン−ビニルエーテル共重合体か好ましい。
転写台紙への印刷は、グラビア印刷法、スクリーン印刷
法、フレキソ印刷法なと既知の手段でよい。
［作 用］
本発明の転写シートは、絵柄を印刷するインキのビヒク
ルとして耐候性のよい樹脂を用いたことにより、日光や
風雨にざらされても変色したり層間剥離をおこしたりす
ることのない絵柄印刷層を、被転写材に与えることかで
きる。
［実施例１１
定尺の軽量発泡コンクリート板（小野田ニーニルシー製
）の全面に、アクリル系エマルジョンの水性弾性塗料の
塗膜を形成し、表面を研摩して外装用化粧材の基材を用
意した。
一方、メチルエチルケトンとトルエンを１：１に混合し
た溶剤に、ポリフッ化ビニリデン３０重量％およびアク
リル樹脂７０重量％からなるビヒクルを顔料とともに分
散した絵柄印刷インキを用意した。 厚さ２５μｍのポ
リエチレンテレフタレートフィルムｒｓ＃２５１ （
ダイヤホイル製）を転写台紙とし、花崗岩の絵柄をグラ
ビア印刷して本発明の転写シートを得た。
上記基材にプライマーｒＡＬｃプライマー」（昭和イン
ク工業所製）を塗布し、その上に本発明の転写シートを
重ね、１４５°Ｃに加熱したロールを５ Ｋ９ ／ ｃ
ｔｉの圧力で加圧した。 転写速度２ｍ／分で転写台紙
を剥離したのち、フッ化エチレン／ビニルエーテル共重
合体系のフッ素樹脂塗料ｒＬ−１０フロール」 （大阪
ワニス製）をロールコートして、表面保護層を形成した
。
［実施例２］
定尺の繊維強化′６青スラグボード「タフウオール」
（朝日防火板製）を湿気硬化ウレタン塗料「Ｖセラン＃
１００１ （大日本塗料製）で防水処理し、アクリル
樹脂とウレタン樹脂を含むサーフエサ−ｒ４００ＧＡｌ
（人日本塗料製〉をフロコートして塗膜を形成し、
表面を研摩して外装用化粧材の基材とした。
アクリル樹脂をビヒクルとするインキで、転写台紙とす
る厚ざ２５μ仇の二軸延伸ポリエチレンテレフタレート
フィルムｒｓ＃２５Ｊ （タイヤホイル製）に、抽像
柄および背理をグラビア印刷して本発明の転写シートを
得た。
上記基材に、アクリル樹脂−ウレタン樹脂系プライマー
「］ニニシン２２０ （大阪ワニス製）を塗布し、この
転写シートを用いて実施例１と同様に印刷層を転写し、
さらに表面保護層を形成して外装用の化粧材を得た。
［実施例３］
実施例２と同様な外装用化粧材の基材を用意した。
厚さ２５μ■の二軸延伸ポリエチレンテレフタレートフ
ィルムｒｓ＃２５Ｊ （ダイヤホイル製）を転写台紙
として使用した。 転写台紙上に、アクリル樹脂系剥離
剤（諸早インキ製）をグラビアコートし、ついてその上
に実施例１と同様な絵柄印刷インキで、花崗岩の絵柄を
印刷して本発明の転写シートを得た。
実施例２と同様に、上記基材へのプライマーの塗イｂ、
得られた転写シートによる印刷層の転写および表面保護
層の形成を行なって、外装用の化粧材を得た。
［発明の効果１
本発明の転写シー１〜は、所望の意匠の絵柄印刷層をも
ら、耐候性のよい外装用の化粧材を与えることかできる
。
この転写シートの製造は印刷だけで足り、印刷層の硬化
か不要であるから工程か簡単であって、低いコストで実
施できる。When manufacturing decorative exterior materials, transfer methods are used to create products with designs that cannot be achieved by painting. Generally, most transfer sheets used for this purpose have a pattern printed on a releasable transfer mount, such as a plastic film, with ink using a cellulose derivative, styrene resin, or vinyl resin as a vehicle. Since the pattern printing layer provided by these transfer sheets has poor weather resistance, the product has low durability when used for decorating exterior decorative materials or molded products for outdoor use. Transfer sheets printed with designs using ink with a curable resin vehicle can provide exterior decorative materials with good weather resistance, but their production requires a curing process for the ink layer, such as heating and irradiation with ionizing radiation. Therefore, high costs cannot be avoided. [Problem to be Solved by the Invention 1] The object of the present invention is to provide a transfer sheet that has a pattern printing layer that has high weather resistance, can provide a highly durable exterior decorative material, is easy to manufacture, and is inexpensive. I'm going to do it. [Means for Solving the Problem] The transfer sheet for exterior decorative materials of the present invention basically consists of a transfer sheet having releasability such as a plastic film,
A pattern printing layer is provided using an ink whose vehicle is an acrylic resin or a mixture of an acrylic resin and a vinyl chloride-vinyl acetate copolymer, or an ink whose vehicle is a fluororesin or a mixture of a fluororesin and an acrylic resin. [It's going to go off. When you want to hide the base of the transfer material, or if you are worried that the transfer mount will adhere to the transfer material during transfer, print the pattern on top of the pattern printing layer (2) as shown in Figure 1. It is preferable to further provide a solid printing layer (3) with colored ink using the same vehicle as the printed ink. As shown in Figure 2, the pattern printing layer (2) and the transfer mount (1
), it is preferable to provide an acrylic resin-based release agent layer (4) between the two. This is a recommended embodiment because the release agent layer serves as a protective layer for the pattern printing layer after transfer and improves weather resistance. It is preferable to add an ultraviolet absorber such as benzotriazole or zinc powder to the release agent in order to prevent discoloration and fading of the pattern printing layer. The example in FIG. 2 also has a solid printing layer (3). The transfer mount may be the same as those conventionally used for transfer sheets. Examples of suitable materials include films of polyesters, polyolefins, polyamides, polyimides, vinyl resins, cellulose, polystyrene, polycarbonates, polyetheretherketones, and polyarylates, which can be processed by the ink vehicle in which the image is printed. Alternatively, an acrylic resin or fluororesin film may be used. Or tissue paper,
Polyolefin resin palm on high-quality paper, parchment paper, etc.]
It is also possible to use a mold release layer made of resin. Among these, biaxially stretched polyethylene terephthalate film is particularly suitable since it has excellent dimensional stability, heat resistance, and mold releasability. The thickness of the transfer mount is generally 5 to 200 μm or appropriate, although it depends on the material and the purpose. When acrylic resin is used alone as an ink vehicle for pattern printing and colored peta printing, it is difficult to transfer onto curved surfaces because the printing layer is stiff. This problem can be improved by using a mixture of acrylic resin and vinyl chloride-vinyl acetate copolymer, or as the weather resistance decreases as the content of vinyl chloride-vinyl acetate copolymer increases, the ratio of the two resin:
Vinyl chloride/vinyl acetate copolymer - It is preferred that the ratio be in the range of 5:5 to 8:2. Furthermore, since fluororesin has low solubility in solvents, inks using it alone are not suitable for providing thick printing layers. By mixing and using an acrylic resin, the applications of the transfer sheet can be expanded, which is preferable.
The mixing ratio is by weight: acrylic resin: fluororesin - 8:2 ~
A range of 3 near is appropriate. In particular, in order to achieve both weather resistance and flexibility of the ink layer, a ratio of acrylic resin:fluororesin of 8:2 to 5:5 is preferable. The fluororesin used in the present invention is preferably one that is relatively well soluble in a solvent, such as polyhynylidene fluoride or fluorinated ethylene-vinyl ether copolymer. Printing on the transfer mount may be performed by known means such as gravure printing, screen printing, and flexographic printing. [Function] The transfer sheet of the present invention uses a resin with good weather resistance as a vehicle for the ink used to print the pattern, so it does not discolor or peel between layers even when exposed to sunlight, wind and rain. A pattern printing layer can be applied to the transferred material. [Example 11] A coating film of an acrylic emulsion water-based elastic paint was formed on the entire surface of a regular-sized lightweight foamed concrete board (manufactured by Onoda Ninil Sea Co., Ltd.), and the surface was polished to prepare a base material for an exterior decorative material. On the other hand, a pattern printing ink was prepared in which a vehicle consisting of 30% by weight of polyvinylidene fluoride and 70% by weight of an acrylic resin was dispersed together with a pigment in a solvent containing a 1:1 mixture of methyl ethyl ketone and toluene. 25μm thick polyethylene terephthalate film rs#251 (
A transfer sheet of the present invention was obtained by gravure printing a granite pattern using Diafoil) as a transfer mount. Primer "rALc Primer" (manufactured by Showa Ink Kogyo Co., Ltd.) was applied to the above substrate, the transfer sheet of the present invention was layered on top of it, and a roll heated to 145°C was rolled for 5K9/c.
Pressure was applied at a pressure of ti. After peeling off the transfer mount at a transfer speed of 2 m/min, a surface protective layer was formed by roll coating a fluoroethylene/vinyl ether copolymer-based fluororesin paint rL-10 Fluor (manufactured by Osaka Varnish). [Example 2] Standard length fiber-reinforced '6 blue slag board "Tough Wall"
(manufactured by Asahi Fire Board) is a moisture-curing urethane paint "V Ceran #
1001 (manufactured by Dainippon Paint Co., Ltd.), a surf bait containing acrylic resin and urethane resin - r400GAl
(manufactured by Nippon Toyo) is flow coated to form a coating film.
The surface was polished and used as a base material for exterior decorative materials. The transfer sheet of the present invention was prepared by gravure printing an abstract pattern and a background using an ink using an acrylic resin vehicle on a biaxially stretched polyethylene terephthalate film RS#25J (manufactured by Tire Foil) with a thickness of 25 μm, which was used as a transfer mount. Obtained. An acrylic resin-urethane resin primer "Ninishin 220" (manufactured by Osaka Varnish) was applied to the above base material, and the printing layer was transferred using this transfer sheet in the same manner as in Example 1.
Furthermore, a surface protective layer was formed to obtain a decorative material for exterior use. [Example 3] A base material for an exterior decorative material similar to that in Example 2 was prepared. A biaxially stretched polyethylene terephthalate film RS#25J (manufactured by Diafoil) having a thickness of 25 μm was used as a transfer mount. An acrylic resin release agent (manufactured by Morohaya Ink) was gravure coated on the transfer mount, and then a granite pattern was printed on it using the same pattern printing ink as in Example 1 to obtain the transfer sheet of the present invention. Ta. As in Example 2, applying a primer to the base material b,
The printed layer was transferred using the obtained transfer sheet and a surface protective layer was formed to obtain a decorative material for exterior use. [Effects of the Invention 1] The transfer sheets 1 to 1 of the present invention can provide a decorative material for exterior use that has a pattern printing layer with a desired design and has good weather resistance. The production of this transfer sheet requires only printing and no curing of the printed layer is required, so the process is simple and can be carried out at low cost.
第１図および第２図は、本発明の転写シートの好ましい
態様を説明するための、模式的な断面図である。
１・・・転写台紙 ２・・・絵柄印刷層３・
・・ベタ印刷層 ４・・・剥離剤層特許出願人
大日本印刷株式会社
代理人 弁理士 須 賀 総 大
筒１
第２図FIGS. 1 and 2 are schematic cross-sectional views for explaining preferred embodiments of the transfer sheet of the present invention. 1...Transfer mount 2...Picture printing layer 3.
... Solid printing layer 4 ... Release agent layer Patent applicant Dai Nippon Printing Co., Ltd. Representative Patent attorney Sou Suga Otsutsu 1 Figure 2
Claims (1)
はアクリル樹脂と塩ビ−酢ビ共重合体との混合物をビヒ
クルとするインキを用いた絵柄印刷層を設けてなる外装
化粧材用転写シート。 （２）離型性を有する転写台紙上に、フッ素樹脂または
フッ素樹脂とアクリル樹脂との混合物をビヒクルとする
インキを用いた絵柄印刷層を設けてなる外装化粧材用転
写シート。（３）転写台紙と絵印刷層との間に、アクリ
ル樹脂系剥離剤層を設けてなる請求項１または２の転写
シート。 （４）絵柄印刷層の上に、アクリル樹脂またはアクリル
樹脂と塩ビ−酢ビ共重合体との混合物をビヒクルとする
インキを用いた着色ベタ印刷層をさらに設けてなる請求
項１ないし３のいずれかの転写シート。 （５）絵柄印刷層の上に、フッ素樹脂またはフッ素樹脂
とアクリル樹脂との混合物をビヒクルとするインキを用
いた着色ベタ印刷層をさらに設けてなる請求項１ないし
３のいずれかの転写シート。[Scope of Claims] (1) A pattern printing layer using an ink whose vehicle is an acrylic resin or a mixture of an acrylic resin and a vinyl chloride-vinyl acetate copolymer is provided on a transfer mount having mold releasability. Transfer sheet for exterior decorative materials. (2) A transfer sheet for exterior decorative materials, comprising a pattern printing layer using an ink containing a fluororesin or a mixture of a fluororesin and an acrylic resin as a vehicle, on a transfer mount having releasability. (3) The transfer sheet according to claim 1 or 2, further comprising an acrylic resin release agent layer between the transfer mount and the picture printing layer. (4) Any of claims 1 to 3, further comprising a colored solid printing layer using an ink containing an acrylic resin or a mixture of an acrylic resin and a vinyl chloride-vinyl acetate copolymer as a vehicle on the pattern printing layer. A transfer sheet. (5) The transfer sheet according to any one of claims 1 to 3, further comprising a colored solid printing layer using an ink containing a fluororesin or a mixture of a fluororesin and an acrylic resin as a vehicle on the pattern printing layer.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2-140307 | 1990-05-30 | ||
| JP14030790 | 1990-05-30 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH0473183A true JPH0473183A (en) | 1992-03-09 |
| JP3084739B2 JP3084739B2 (en) | 2000-09-04 |
Family
ID=15265747
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP02283632A Expired - Lifetime JP3084739B2 (en) | 1990-05-30 | 1990-10-22 | Transfer sheet for exterior decorative material |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP3084739B2 (en) |
Cited By (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH06198824A (en) * | 1992-12-28 | 1994-07-19 | Dainippon Printing Co Ltd | Transfer sheet for exterior material composed of vinyl chloride resin molded object |
| JPH0732718A (en) * | 1993-07-19 | 1995-02-03 | Dainippon Printing Co Ltd | Transfer foil for vinyl chloride resin base material |
| JPH0781298A (en) * | 1993-07-19 | 1995-03-28 | Dainippon Printing Co Ltd | Transfer foil for substrate of vinyl chloride |
| JPH07156568A (en) * | 1993-12-10 | 1995-06-20 | Mitsubishi Chem Corp | Image protective member and image protective method |
| JPH07205597A (en) * | 1994-01-21 | 1995-08-08 | Dainippon Printing Co Ltd | Covering transfer foil |
| JPH07257012A (en) * | 1994-03-25 | 1995-10-09 | Oike Ind Co Ltd | Transparent ultraviolt blocking protective transfer foil |
| JPH07276896A (en) * | 1994-04-08 | 1995-10-24 | Toyo Ink Mfg Co Ltd | Transfer sheet |
| WO1996010491A1 (en) * | 1994-09-30 | 1996-04-11 | Kimberly-Clark Corporation | Composite for transfer of durable graphics |
| JPH1035195A (en) * | 1996-07-18 | 1998-02-10 | Dainippon Printing Co Ltd | Hydraulic pressure transfer sheet, hydraulic pressure transfer method using the sheet and molded body with transfer layer formed by the sheet |
| JP2006142742A (en) * | 2004-11-24 | 2006-06-08 | Toppan Printing Co Ltd | Decorative sheet |
| JP2012037511A (en) * | 2010-08-05 | 2012-02-23 | Xerox Corp | Non-polar solid inks for biomedical applications |
| JP2016068275A (en) * | 2014-09-26 | 2016-05-09 | 大日本印刷株式会社 | Decorative sheet and decorative resin molding |
| JP2018079637A (en) * | 2016-11-17 | 2018-05-24 | 藤野 勲次 | Method for producing resin concrete product |
| JP2022033011A (en) * | 2020-08-11 | 2022-02-25 | 正清國際有限公司 | Thermal transfer film component |
-
1990
- 1990-10-22 JP JP02283632A patent/JP3084739B2/en not_active Expired - Lifetime
Cited By (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH06198824A (en) * | 1992-12-28 | 1994-07-19 | Dainippon Printing Co Ltd | Transfer sheet for exterior material composed of vinyl chloride resin molded object |
| JPH0732718A (en) * | 1993-07-19 | 1995-02-03 | Dainippon Printing Co Ltd | Transfer foil for vinyl chloride resin base material |
| JPH0781298A (en) * | 1993-07-19 | 1995-03-28 | Dainippon Printing Co Ltd | Transfer foil for substrate of vinyl chloride |
| JPH07156568A (en) * | 1993-12-10 | 1995-06-20 | Mitsubishi Chem Corp | Image protective member and image protective method |
| JPH07205597A (en) * | 1994-01-21 | 1995-08-08 | Dainippon Printing Co Ltd | Covering transfer foil |
| JPH07257012A (en) * | 1994-03-25 | 1995-10-09 | Oike Ind Co Ltd | Transparent ultraviolt blocking protective transfer foil |
| JPH07276896A (en) * | 1994-04-08 | 1995-10-24 | Toyo Ink Mfg Co Ltd | Transfer sheet |
| WO1996010491A1 (en) * | 1994-09-30 | 1996-04-11 | Kimberly-Clark Corporation | Composite for transfer of durable graphics |
| JPH1035195A (en) * | 1996-07-18 | 1998-02-10 | Dainippon Printing Co Ltd | Hydraulic pressure transfer sheet, hydraulic pressure transfer method using the sheet and molded body with transfer layer formed by the sheet |
| JP2006142742A (en) * | 2004-11-24 | 2006-06-08 | Toppan Printing Co Ltd | Decorative sheet |
| JP4539305B2 (en) * | 2004-11-24 | 2010-09-08 | 凸版印刷株式会社 | Decorative sheet |
| JP2012037511A (en) * | 2010-08-05 | 2012-02-23 | Xerox Corp | Non-polar solid inks for biomedical applications |
| JP2016068275A (en) * | 2014-09-26 | 2016-05-09 | 大日本印刷株式会社 | Decorative sheet and decorative resin molding |
| JP2018079637A (en) * | 2016-11-17 | 2018-05-24 | 藤野 勲次 | Method for producing resin concrete product |
| JP2022033011A (en) * | 2020-08-11 | 2022-02-25 | 正清國際有限公司 | Thermal transfer film component |
Also Published As
| Publication number | Publication date |
|---|---|
| JP3084739B2 (en) | 2000-09-04 |
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