JPH0467945B2 - - Google Patents
Info
- Publication number
- JPH0467945B2 JPH0467945B2 JP60267273A JP26727385A JPH0467945B2 JP H0467945 B2 JPH0467945 B2 JP H0467945B2 JP 60267273 A JP60267273 A JP 60267273A JP 26727385 A JP26727385 A JP 26727385A JP H0467945 B2 JPH0467945 B2 JP H0467945B2
- Authority
- JP
- Japan
- Prior art keywords
- glucomannan
- weight
- parts
- water
- film
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- LUEWUZLMQUOBSB-FSKGGBMCSA-N (2s,3s,4s,5s,6r)-2-[(2r,3s,4r,5r,6s)-6-[(2r,3s,4r,5s,6s)-4,5-dihydroxy-2-(hydroxymethyl)-6-[(2r,4r,5s,6r)-4,5,6-trihydroxy-2-(hydroxymethyl)oxan-3-yl]oxyoxan-3-yl]oxy-4,5-dihydroxy-2-(hydroxymethyl)oxan-3-yl]oxy-6-(hydroxymethyl)oxane-3,4,5-triol Chemical compound O[C@H]1[C@@H](O)[C@H](O)[C@@H](CO)O[C@H]1O[C@@H]1[C@@H](CO)O[C@@H](O[C@@H]2[C@H](O[C@@H](OC3[C@H](O[C@@H](O)[C@@H](O)[C@H]3O)CO)[C@@H](O)[C@H]2O)CO)[C@H](O)[C@H]1O LUEWUZLMQUOBSB-FSKGGBMCSA-N 0.000 claims description 20
- 229920002581 Glucomannan Polymers 0.000 claims description 20
- 229940046240 glucomannan Drugs 0.000 claims description 20
- 150000005846 sugar alcohols Polymers 0.000 claims description 12
- 239000000203 mixture Substances 0.000 claims description 11
- 150000002016 disaccharides Chemical class 0.000 claims description 7
- 229920001282 polysaccharide Polymers 0.000 claims description 7
- 239000005017 polysaccharide Substances 0.000 claims description 7
- 150000002772 monosaccharides Chemical class 0.000 claims description 6
- 229920001542 oligosaccharide Polymers 0.000 claims description 6
- 150000002482 oligosaccharides Chemical class 0.000 claims description 6
- 239000003513 alkali Substances 0.000 claims description 4
- 150000004676 glycans Chemical class 0.000 claims 2
- 238000004898 kneading Methods 0.000 claims 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 15
- 239000010408 film Substances 0.000 description 11
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 10
- 239000000243 solution Substances 0.000 description 6
- 238000000576 coating method Methods 0.000 description 5
- 235000011187 glycerol Nutrition 0.000 description 5
- 239000007788 liquid Substances 0.000 description 5
- 150000004804 polysaccharides Chemical class 0.000 description 5
- 239000000843 powder Substances 0.000 description 5
- 244000247812 Amorphophallus rivieri Species 0.000 description 4
- 239000013043 chemical agent Substances 0.000 description 4
- 239000011248 coating agent Substances 0.000 description 4
- 235000001206 Amorphophallus rivieri Nutrition 0.000 description 3
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 3
- 229920002752 Konjac Polymers 0.000 description 3
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 3
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 239000007864 aqueous solution Substances 0.000 description 3
- 235000010418 carrageenan Nutrition 0.000 description 3
- 239000000679 carrageenan Substances 0.000 description 3
- 229920001525 carrageenan Polymers 0.000 description 3
- 229940113118 carrageenan Drugs 0.000 description 3
- 239000003795 chemical substances by application Substances 0.000 description 3
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 3
- UHVMMEOXYDMDKI-JKYCWFKZSA-L zinc;1-(5-cyanopyridin-2-yl)-3-[(1s,2s)-2-(6-fluoro-2-hydroxy-3-propanoylphenyl)cyclopropyl]urea;diacetate Chemical compound [Zn+2].CC([O-])=O.CC([O-])=O.CCC(=O)C1=CC=C(F)C([C@H]2[C@H](C2)NC(=O)NC=2N=CC(=CC=2)C#N)=C1O UHVMMEOXYDMDKI-JKYCWFKZSA-L 0.000 description 3
- ATRRKUHOCOJYRX-UHFFFAOYSA-N Ammonium bicarbonate Chemical compound [NH4+].OC([O-])=O ATRRKUHOCOJYRX-UHFFFAOYSA-N 0.000 description 2
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 description 2
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 description 2
- 229920002472 Starch Polymers 0.000 description 2
- 125000002777 acetyl group Chemical group [H]C([H])([H])C(*)=O 0.000 description 2
- 239000001099 ammonium carbonate Substances 0.000 description 2
- 239000003429 antifungal agent Substances 0.000 description 2
- 229940121375 antifungal agent Drugs 0.000 description 2
- WQZGKKKJIJFFOK-VFUOTHLCSA-N beta-D-glucose Chemical compound OC[C@H]1O[C@@H](O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-VFUOTHLCSA-N 0.000 description 2
- AXCZMVOFGPJBDE-UHFFFAOYSA-L calcium dihydroxide Chemical compound [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 description 2
- 239000000920 calcium hydroxide Substances 0.000 description 2
- 229910001861 calcium hydroxide Inorganic materials 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000003205 fragrance Substances 0.000 description 2
- 239000008103 glucose Substances 0.000 description 2
- 239000008187 granular material Substances 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 239000000252 konjac Substances 0.000 description 2
- 235000010485 konjac Nutrition 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 125000002467 phosphate group Chemical group [H]OP(=O)(O[H])O[*] 0.000 description 2
- 230000000704 physical effect Effects 0.000 description 2
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Chemical compound [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 description 2
- 239000003755 preservative agent Substances 0.000 description 2
- 239000008107 starch Substances 0.000 description 2
- 235000019698 starch Nutrition 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- IXPNQXFRVYWDDI-UHFFFAOYSA-N 1-methyl-2,4-dioxo-1,3-diazinane-5-carboximidamide Chemical compound CN1CC(C(N)=N)C(=O)NC1=O IXPNQXFRVYWDDI-UHFFFAOYSA-N 0.000 description 1
- OWEGMIWEEQEYGQ-UHFFFAOYSA-N 100676-05-9 Natural products OC1C(O)C(O)C(CO)OC1OCC1C(O)C(O)C(O)C(OC2C(OC(O)C(O)C2O)CO)O1 OWEGMIWEEQEYGQ-UHFFFAOYSA-N 0.000 description 1
- 229920001817 Agar Polymers 0.000 description 1
- GUBGYTABKSRVRQ-XLOQQCSPSA-N Alpha-Lactose Chemical compound O[C@@H]1[C@@H](O)[C@@H](O)[C@@H](CO)O[C@H]1O[C@@H]1[C@@H](CO)O[C@H](O)[C@H](O)[C@H]1O GUBGYTABKSRVRQ-XLOQQCSPSA-N 0.000 description 1
- 229910000013 Ammonium bicarbonate Inorganic materials 0.000 description 1
- 241000209524 Araceae Species 0.000 description 1
- 229920000858 Cyclodextrin Polymers 0.000 description 1
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 description 1
- FBPFZTCFMRRESA-KVTDHHQDSA-N D-Mannitol Chemical compound OC[C@@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-KVTDHHQDSA-N 0.000 description 1
- FBPFZTCFMRRESA-JGWLITMVSA-N D-glucitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-JGWLITMVSA-N 0.000 description 1
- WQZGKKKJIJFFOK-QTVWNMPRSA-N D-mannopyranose Chemical compound OC[C@H]1OC(O)[C@@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-QTVWNMPRSA-N 0.000 description 1
- 241000196324 Embryophyta Species 0.000 description 1
- 102000004190 Enzymes Human genes 0.000 description 1
- 108090000790 Enzymes Proteins 0.000 description 1
- 229930091371 Fructose Natural products 0.000 description 1
- 239000005715 Fructose Substances 0.000 description 1
- RFSUNEUAIZKAJO-ARQDHWQXSA-N Fructose Chemical compound OC[C@H]1O[C@](O)(CO)[C@@H](O)[C@@H]1O RFSUNEUAIZKAJO-ARQDHWQXSA-N 0.000 description 1
- 229920002907 Guar gum Polymers 0.000 description 1
- 244000017020 Ipomoea batatas Species 0.000 description 1
- 235000002678 Ipomoea batatas Nutrition 0.000 description 1
- GUBGYTABKSRVRQ-QKKXKWKRSA-N Lactose Natural products OC[C@H]1O[C@@H](O[C@H]2[C@H](O)[C@@H](O)C(O)O[C@@H]2CO)[C@H](O)[C@@H](O)[C@H]1O GUBGYTABKSRVRQ-QKKXKWKRSA-N 0.000 description 1
- 229920000161 Locust bean gum Polymers 0.000 description 1
- GUBGYTABKSRVRQ-PICCSMPSSA-N Maltose Natural products O[C@@H]1[C@@H](O)[C@H](O)[C@@H](CO)O[C@@H]1O[C@@H]1[C@@H](CO)OC(O)[C@H](O)[C@H]1O GUBGYTABKSRVRQ-PICCSMPSSA-N 0.000 description 1
- 229930195725 Mannitol Natural products 0.000 description 1
- 206010027146 Melanoderma Diseases 0.000 description 1
- HDSBZMRLPLPFLQ-UHFFFAOYSA-N Propylene glycol alginate Chemical compound OC1C(O)C(OC)OC(C(O)=O)C1OC1C(O)C(O)C(C)C(C(=O)OCC(C)O)O1 HDSBZMRLPLPFLQ-UHFFFAOYSA-N 0.000 description 1
- 239000004373 Pullulan Substances 0.000 description 1
- 229920001218 Pullulan Polymers 0.000 description 1
- 244000061456 Solanum tuberosum Species 0.000 description 1
- 235000002595 Solanum tuberosum Nutrition 0.000 description 1
- 235000004298 Tamarindus indica Nutrition 0.000 description 1
- 240000004584 Tamarindus indica Species 0.000 description 1
- TVXBFESIOXBWNM-UHFFFAOYSA-N Xylitol Natural products OCCC(O)C(O)C(O)CCO TVXBFESIOXBWNM-UHFFFAOYSA-N 0.000 description 1
- 240000008042 Zea mays Species 0.000 description 1
- 235000005824 Zea mays ssp. parviglumis Nutrition 0.000 description 1
- 235000002017 Zea mays subsp mays Nutrition 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 239000008272 agar Substances 0.000 description 1
- 235000010419 agar Nutrition 0.000 description 1
- 235000010443 alginic acid Nutrition 0.000 description 1
- 239000000783 alginic acid Substances 0.000 description 1
- 229920000615 alginic acid Polymers 0.000 description 1
- 229960001126 alginic acid Drugs 0.000 description 1
- 150000004781 alginic acids Chemical class 0.000 description 1
- WQZGKKKJIJFFOK-PHYPRBDBSA-N alpha-D-galactose Chemical compound OC[C@H]1O[C@H](O)[C@H](O)[C@@H](O)[C@H]1O WQZGKKKJIJFFOK-PHYPRBDBSA-N 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 150000001413 amino acids Chemical class 0.000 description 1
- 235000012538 ammonium bicarbonate Nutrition 0.000 description 1
- 235000012501 ammonium carbonate Nutrition 0.000 description 1
- 239000013556 antirust agent Substances 0.000 description 1
- RQPZNWPYLFFXCP-UHFFFAOYSA-L barium dihydroxide Chemical compound [OH-].[OH-].[Ba+2] RQPZNWPYLFFXCP-UHFFFAOYSA-L 0.000 description 1
- 229910001863 barium hydroxide Inorganic materials 0.000 description 1
- GUBGYTABKSRVRQ-QUYVBRFLSA-N beta-maltose Chemical compound OC[C@H]1O[C@H](O[C@H]2[C@H](O)[C@@H](O)[C@H](O)O[C@@H]2CO)[C@H](O)[C@@H](O)[C@@H]1O GUBGYTABKSRVRQ-QUYVBRFLSA-N 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- 150000001720 carbohydrates Chemical class 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 235000010980 cellulose Nutrition 0.000 description 1
- 230000015271 coagulation Effects 0.000 description 1
- 238000005345 coagulation Methods 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 235000005822 corn Nutrition 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- SZXQTJUDPRGNJN-UHFFFAOYSA-N dipropylene glycol Chemical compound OCCCOCCCO SZXQTJUDPRGNJN-UHFFFAOYSA-N 0.000 description 1
- 150000002148 esters Chemical group 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- 229930182830 galactose Natural products 0.000 description 1
- 235000010417 guar gum Nutrition 0.000 description 1
- 239000000665 guar gum Substances 0.000 description 1
- 229960002154 guar gum Drugs 0.000 description 1
- 239000012770 industrial material Substances 0.000 description 1
- 230000002427 irreversible effect Effects 0.000 description 1
- 239000008101 lactose Substances 0.000 description 1
- 235000010420 locust bean gum Nutrition 0.000 description 1
- 239000000711 locust bean gum Substances 0.000 description 1
- ZLNQQNXFFQJAID-UHFFFAOYSA-L magnesium carbonate Chemical compound [Mg+2].[O-]C([O-])=O ZLNQQNXFFQJAID-UHFFFAOYSA-L 0.000 description 1
- 239000001095 magnesium carbonate Substances 0.000 description 1
- 229910000021 magnesium carbonate Inorganic materials 0.000 description 1
- 235000014380 magnesium carbonate Nutrition 0.000 description 1
- VTHJTEIRLNZDEV-UHFFFAOYSA-L magnesium dihydroxide Chemical compound [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 description 1
- 239000000347 magnesium hydroxide Substances 0.000 description 1
- 229910001862 magnesium hydroxide Inorganic materials 0.000 description 1
- 239000000845 maltitol Substances 0.000 description 1
- 235000010449 maltitol Nutrition 0.000 description 1
- VQHSOMBJVWLPSR-WUJBLJFYSA-N maltitol Chemical compound OC[C@H](O)[C@@H](O)[C@@H]([C@H](O)CO)O[C@H]1O[C@H](CO)[C@@H](O)[C@H](O)[C@H]1O VQHSOMBJVWLPSR-WUJBLJFYSA-N 0.000 description 1
- 229940035436 maltitol Drugs 0.000 description 1
- 239000000594 mannitol Substances 0.000 description 1
- 235000010355 mannitol Nutrition 0.000 description 1
- 229960001855 mannitol Drugs 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- HEBKCHPVOIAQTA-UHFFFAOYSA-N meso ribitol Natural products OCC(O)C(O)C(O)CO HEBKCHPVOIAQTA-UHFFFAOYSA-N 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 235000010987 pectin Nutrition 0.000 description 1
- 239000001814 pectin Substances 0.000 description 1
- 229920001277 pectin Polymers 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229910000027 potassium carbonate Inorganic materials 0.000 description 1
- 235000012015 potatoes Nutrition 0.000 description 1
- 235000010409 propane-1,2-diol alginate Nutrition 0.000 description 1
- 239000000770 propane-1,2-diol alginate Substances 0.000 description 1
- 235000019423 pullulan Nutrition 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 235000021067 refined food Nutrition 0.000 description 1
- 239000005871 repellent Substances 0.000 description 1
- 230000002940 repellent Effects 0.000 description 1
- HFHDHCJBZVLPGP-UHFFFAOYSA-N schardinger α-dextrin Chemical compound O1C(C(C2O)O)C(CO)OC2OC(C(C2O)O)C(CO)OC2OC(C(C2O)O)C(CO)OC2OC(C(O)C2O)C(CO)OC2OC(C(C2O)O)C(CO)OC2OC2C(O)C(O)C1OC2CO HFHDHCJBZVLPGP-UHFFFAOYSA-N 0.000 description 1
- 235000010413 sodium alginate Nutrition 0.000 description 1
- 239000000661 sodium alginate Substances 0.000 description 1
- 229940005550 sodium alginate Drugs 0.000 description 1
- 229910000030 sodium bicarbonate Inorganic materials 0.000 description 1
- 235000017557 sodium bicarbonate Nutrition 0.000 description 1
- 229910000029 sodium carbonate Inorganic materials 0.000 description 1
- 239000000600 sorbitol Substances 0.000 description 1
- 229960002920 sorbitol Drugs 0.000 description 1
- 235000010356 sorbitol Nutrition 0.000 description 1
- 230000008961 swelling Effects 0.000 description 1
- 150000004044 tetrasaccharides Chemical class 0.000 description 1
- 239000010409 thin film Substances 0.000 description 1
- 150000004043 trisaccharides Chemical class 0.000 description 1
- 229920001285 xanthan gum Polymers 0.000 description 1
- 235000010493 xanthan gum Nutrition 0.000 description 1
- 239000000230 xanthan gum Substances 0.000 description 1
- 229940082509 xanthan gum Drugs 0.000 description 1
- 235000010447 xylitol Nutrition 0.000 description 1
- 239000000811 xylitol Substances 0.000 description 1
- HEBKCHPVOIAQTA-SCDXWVJYSA-N xylitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)CO HEBKCHPVOIAQTA-SCDXWVJYSA-N 0.000 description 1
- 229960002675 xylitol Drugs 0.000 description 1
Landscapes
- General Preparation And Processing Of Foods (AREA)
- Jellies, Jams, And Syrups (AREA)
- Manufacture Of Macromolecular Shaped Articles (AREA)
- Preparation Of Fruits And Vegetables (AREA)
Description
【発明の詳細な説明】
〔産業上の利用分野〕
本発明組成物は、湿り気のある粉体であり、水
を添加すると粘稠な溶液となる。この溶液は常温
で放置、凍結または加熱により不可逆的に凝固す
る性質を有する。しかも得られた凝固体は水の添
加量により任意の物性、特に硬度、粘弾性を調整
することができる。得られた凝固体は耐水性、耐
熱性であり、ブロツク、被膜など任意の形態に成
形することができる。DETAILED DESCRIPTION OF THE INVENTION [Industrial Application Field] The composition of the present invention is a moist powder, and when water is added, it becomes a viscous solution. This solution has the property of irreversibly solidifying when left at room temperature, frozen, or heated. Moreover, the physical properties of the obtained coagulated body, particularly hardness and viscoelasticity, can be adjusted by adjusting the amount of water added. The obtained coagulated material is water resistant and heat resistant, and can be formed into any desired shape such as a block or a film.
この特性を利用すれば、各種物品への防カビ
剤、防錆剤、防腐剤、防湿剤、香料などの化学薬
剤の添加が極めて容易になる。すなわち、本発明
組成物に水を加え、未だ流動性を有する間に化学
薬剤を添加、配合することにより、任意の配合量
で化学薬剤を添加することができる。 Utilizing this property, it becomes extremely easy to add chemical agents such as antifungal agents, antirust agents, preservatives, moisture repellents, and fragrances to various articles. That is, by adding water to the composition of the present invention and adding and blending the chemical agent while it still has fluidity, the chemical agent can be added in any amount.
従来、グルコマンナンは水の系、すなわち水溶
液中でアルカリと反応させた後、加熱処理によつ
て凝固体、すなわちコンニヤクを製造する用途に
用いられていた。しかしながら、水の系でグルコ
マンナンを反応させる従来の方法によれば、凝固
体の組織が不均一なためその用途がもつぱらコン
ニヤクに限定されていた。
Conventionally, glucomannan has been used to produce a coagulated product, ie, konjac, by reacting it with an alkali in an aqueous system, ie, an aqueous solution, and then subjecting it to heat treatment. However, according to the conventional method of reacting glucomannan in an aqueous system, the structure of the coagulum is non-uniform, so its use is limited to konjac.
本発明は、グルコマンナンを原料としながらコ
ンニヤクとは異なり、強度と耐水性を有するブロ
ツクやフイルム、顆粒などに成形容易なグルコマ
ンナン組成物を製造し、グルコマンナンの用途の
拡大を図ることを目的とする。
The purpose of the present invention is to produce a glucomannan composition that uses glucomannan as a raw material and, unlike konnyaku, has strength and water resistance and can be easily formed into blocks, films, granules, etc., and to expand the uses of glucomannan. shall be.
本発明は、多価アルコール、糖アルコール、単
糖類、二糖類及びオリゴ糖から選ばれた少なくと
も１種からなる系の中でグルコマンナン或いはグ
ルコマンナンと他の天然多糖類を、アルカリの存
在下或いは不存在下に混練させることを特徴とす
る。
The present invention relates to glucomannan or glucomannan and other natural polysaccharides in the presence of an alkali or in a system consisting of at least one selected from polyhydric alcohols, sugar alcohols, monosaccharides, disaccharides and oligosaccharides It is characterized by being kneaded in its absence.
本発明に係るグルコマンナンは、サトイモ科に
属する草木の地下球茎でコンニヤク芋
（Amorphop hallus Konjac K.Koch）に含まれ
る多糖類であり、異形細胞とよばれる長径0.5〜
1.05mm、短径0.37〜0.05mmの粒子である。化学構
造はグルコースとマンノースが１：２の割合で鎖
状に結合し、更にアセチル基とリン酸基が側鎖と
してエステル結合している高分子多糖類である。 Glucomannan according to the present invention is a polysaccharide contained in Amorphop hallus Konjac K.Koch, which is an underground corm of a plant belonging to the family Araceae, and has a major diameter of 0.5~
The particles are 1.05 mm and the minor axis is 0.37 to 0.05 mm. It is a high-molecular polysaccharide with a chemical structure in which glucose and mannose are bonded in a chain at a ratio of 1:2, and an acetyl group and a phosphate group are ester bonded as side chains.
本発明に係る、狭義の多価アルコールとして、
プロピレングリコール、グリセリン、エチレング
リコール、ジエチレングリコール、ジプロピレン
グリコール等が挙げられる。糖アルコールとして
は、ソルビトール、マンニトール、マルチトー
ル、キシリトール、還元澱粉糖化物等が挙げられ
る。単糖類としてはグルコース、フラクトース、
ガラクトース、キシローズ等が使用される。二糖
類としてはサツカロース、マルトース、ラクトー
ス等が使用される。オリゴ糖としてはさつま芋、
じやが芋、とうもろこし等の澱粉の酵素、酸など
による分解産物が使用され、二糖類、三糖類、四
糖類、五糖類、六糖類等が含まれている。 As a narrowly defined polyhydric alcohol according to the present invention,
Examples include propylene glycol, glycerin, ethylene glycol, diethylene glycol, dipropylene glycol, and the like. Examples of the sugar alcohol include sorbitol, mannitol, maltitol, xylitol, reduced starch saccharide, and the like. Monosaccharides include glucose, fructose,
Galactose, xyrose, etc. are used. Sutucarose, maltose, lactose, etc. are used as disaccharides. As oligosaccharides, sweet potato,
The products used are the decomposition products of starch from potatoes, corn, etc., using enzymes, acids, etc., and include disaccharides, trisaccharides, tetrasaccharides, pentasaccharides, hexasaccharides, etc.
本発明は、これら多価アルコール、糖アルコー
ル、単糖類、二糖類及びオリゴ糖から選ばれた少
なくとも１種からなる系の中で行われることに特
徴がある。これらの系の中でとは、それ自体液状
のものはそのまま、あるいはわずかに希釈して使
用し、粉体のものは60〜90％水溶液、好ましくは
70〜80％水溶液として、この中にグルコマンナン
或いはグルコマンナンと他の多糖類を混練してい
く。 The present invention is characterized in that it is carried out in a system consisting of at least one selected from these polyhydric alcohols, sugar alcohols, monosaccharides, disaccharides, and oligosaccharides. Among these systems, liquid ones are used as is or slightly diluted, and powder ones are used as a 60-90% aqueous solution, preferably
Glucomannan or glucomannan and other polysaccharides are kneaded into this to form a 70-80% aqueous solution.
グルコマンナンと多価アルコール、糖アルコー
ル、単糖類、二糖類及びオリゴ糖から選ばれた少
なくとも１種の化合物との配合比は、グルコマン
ナン１重量部に対し、これら化合物0.2〜20重量
部、好ましくは0.5〜15重量部である。 The blending ratio of glucomannan and at least one compound selected from polyhydric alcohols, sugar alcohols, monosaccharides, disaccharides, and oligosaccharides is preferably 0.2 to 20 parts by weight, based on 1 part by weight of glucomannan. is 0.5 to 15 parts by weight.
本発明に係るアルカリは通常の無機、有機のア
ルカリ性物質であればよく、例えば、水酸化ナト
リウム、水酸化カリウム、水酸化カルシウム、水
酸化マグネシウム、水酸化バリウム、炭酸ナトリ
ウム、炭酸カリウム、炭酸カルシウム、炭酸アン
モニウム、炭酸マグネシウム、炭酸水素ナトリウ
ム、炭酸水素アンモニウム、塩基性アミノ酸、ア
ミンなどが挙げられる。 The alkali according to the present invention may be any ordinary inorganic or organic alkaline substance, such as sodium hydroxide, potassium hydroxide, calcium hydroxide, magnesium hydroxide, barium hydroxide, sodium carbonate, potassium carbonate, calcium carbonate, Examples include ammonium carbonate, magnesium carbonate, sodium hydrogen carbonate, ammonium hydrogen carbonate, basic amino acids, and amines.
また、他の天然多糖類としては、サイクロデキ
ストリン、カラギナン、ローカストビーンガム、
グアーガム、セルロース、アルギン酸、アルギン
酸ソーダ、アルギン酸プロピレングリコールエス
テル、プルラン、寒天、タマリンド、ペクチン、
キサンタンガム、などが挙げられる。 Other natural polysaccharides include cyclodextrin, carrageenan, locust bean gum,
Guar gum, cellulose, alginic acid, sodium alginate, propylene glycol alginate, pullulan, agar, tamarind, pectin,
Examples include xanthan gum.
本発明組成物は、一般に多少湿り気のある粉体
である。これを水に溶解したものは粘稠な溶液で
あり、常温放置、凍結、冷蔵または加熱により不
可逆的に凝固する性質を有する。しかも得られた
凝固体は水の添加量により任意の物性、特に硬
度、粘弾性を調整することができる。得られた凝
固体は耐水性、耐熱性であり、ブロツク、被膜、
顆粒など任意の形態に成形することができる。 The compositions of the present invention are generally somewhat moist powders. A solution obtained by dissolving this in water is a viscous solution, which has the property of irreversibly solidifying when left at room temperature, frozen, refrigerated, or heated. Moreover, the physical properties of the obtained coagulated body, particularly hardness and viscoelasticity, can be adjusted by adjusting the amount of water added. The obtained coagulated material is water resistant and heat resistant, and is suitable for blocks, coatings,
It can be formed into any form such as granules.
グルコマンナンは上述の通りアセチル基やリン
酸基を有する複雑な構造であるため、グリセリン
の系の中で反応し、複雑なマトリツクスを形成す
るものと考えられる。ここに水を加えることによ
り三次元構造がより発達し、不可逆的凝固体を形
成するに至る。
As mentioned above, glucomannan has a complex structure containing acetyl groups and phosphate groups, so it is thought that it reacts in the glycerin system to form a complex matrix. By adding water here, the three-dimensional structure is further developed and an irreversible coagulation is formed.
本発明に係るグルコマンナンと多価アルコー
ル、糖アルコール、単糖類、二糖類及びオリゴ糖
から選ばれた少なくとも１種からなる組成物に水
および種々の化学薬剤を添加することにより、任
意の硬度、粘弾性を有する耐水性かつ耐熱性の凝
固体や被膜を形成することができる。更に、この
特性を利用して工業材料、農水産物、加工食品、
日用品などに防カビ剤、防錆剤、防腐剤、防湿
剤、香料などの化学薬剤を容易に添加することが
できる。
Any hardness, A water-resistant and heat-resistant coagulated body or film having viscoelasticity can be formed. Furthermore, this property can be used to produce industrial materials, agricultural and marine products, processed foods,
Chemical agents such as anti-mold agents, anti-corrosion agents, preservatives, moisture-proofing agents, and fragrances can be easily added to daily necessities.
〔実施例 １〕
グルコマンナン５重量部、グリセリン15重量
部、水酸化カルシウム0.1重量部を混練した。黄
褐色の粘稠な本発明組成物が得られた。得られた
組成物10重量部と水100重量部を加えたものに対
し、防カビ剤（バイエル・ジヤパン(株)製、商標
名：プリベントールA3 85重量部とプリベントー
ルOC−3015 15重量部との混合物）を0.5重量％
添加して塗布液を調製した。浴場のプラスチツク
スからなる壁の一部に、得られた塗布液を刷毛に
より塗布し、室温20℃にて２日間放置したところ
厚さ約50μの耐水性被膜が得られた。このまま２
ケ月間使用したところ、被膜を塗布した部位は清
潔に保たれたが、被膜を塗布しなかつた部位には
黒色斑点状のカビが発生した。更に、この被膜は
剥離せず、熱にも安定であつた。[Example 1] 5 parts by weight of glucomannan, 15 parts by weight of glycerin, and 0.1 part by weight of calcium hydroxide were kneaded. A yellowish brown viscous composition of the invention was obtained. To a mixture of 10 parts by weight of the obtained composition and 100 parts by weight of water, 85 parts by weight of antifungal agents (manufactured by Bayer Japan Ltd., trade name: Priventol A3 and 15 parts by weight of Priventol OC-3015) were added. (mixture with) 0.5% by weight
A coating solution was prepared. The resulting coating solution was applied with a brush to a part of a plastic wall in a bathhouse and left at room temperature of 20°C for 2 days, resulting in a water-resistant coating with a thickness of approximately 50 μm. As it is 2
After using the product for several months, the areas where the film was applied remained clean, but black spot-like mold developed on the areas where the film was not applied. Furthermore, this coating did not peel off and was stable to heat.
〔実施例 ２〕
グルコマンナン６重量部、カラギナン４重量
部、グリセリン10重量部を混練し、80℃に加熱し
たところさらさらした粉体が得られた。この粉体
１重量部に対して40重量部の水を加え、約70℃に
加温して溶融し粘稠な液体を得た。この液体を平
滑な金属板上に塗布し、温風により乾燥し、約
80μ厚の耐水性フイルムを得た。このフイルムは
可食性であり、各種食品を包装し、違和感なくそ
のまま食べることができた。[Example 2] 6 parts by weight of glucomannan, 4 parts by weight of carrageenan, and 10 parts by weight of glycerin were kneaded and heated to 80°C to obtain a smooth powder. 40 parts by weight of water was added to 1 part by weight of this powder and heated to about 70°C to melt and obtain a viscous liquid. This liquid is applied onto a smooth metal plate, dried with warm air, and then
A water-resistant film with a thickness of 80μ was obtained. This film was edible, and various foods could be wrapped in it and eaten without any discomfort.
〔比較例 １〕
800重量部の水にグリセリン10重量部を加えて
攪拌し、更にグルコマンナン６重量部及びカラギ
ナン４重量部を加えて常温に放置し、ゆつくりと
膨潤させながら70〜80℃に加温して粘稠な液体を
得た。この液体を平滑な金属板板上に塗布し約
80μ厚のフイルムを製膜しようとしたが、乾燥し
たところ薄い被膜は鱗片状に剥がれて製膜不可能
であつた。そこで、可能な限度で厚いフイルムを
製膜しようとしたが、平均厚み１mm程度にしても
乾燥が進行すると共に収縮し、極端な厚みムラを
生じ千切れる部分が多発して製膜不可能であつ
た。[Comparative Example 1] 10 parts by weight of glycerin was added to 800 parts by weight of water, stirred, 6 parts by weight of glucomannan and 4 parts by weight of carrageenan were added, and the mixture was left at room temperature and heated to 70 to 80°C while slowly swelling. A viscous liquid was obtained by heating. Apply this liquid onto a smooth metal plate and
An attempt was made to form a film with a thickness of 80 μm, but upon drying, the thin film peeled off in the form of scales, making it impossible to form a film. Therefore, an attempt was made to make a film as thick as possible, but even if the average thickness was about 1 mm, it would shrink as drying progressed, resulting in extreme thickness unevenness and many tearing parts, making it impossible to make a film. Ta.
Claims (1)
糖類及びオリゴ糖から選ばれた少なくとも１種か
らなる系の中でグルコマンナンと他の天然多糖類
を混練し、反応させてなるグルコマンナン組成
物。 ２ 多価アルコール、糖アルコール、単糖類、二
糖類及びオリゴ糖から選ばれた少なくとも１種か
らなる系の中でグルコマンナンと他の天然多糖類
をアルカリと混練し、反応させてなるグルコマン
ナン組成物。[Claims] 1. Glucomannan and other natural polysaccharides are kneaded and reacted in a system consisting of at least one selected from polyhydric alcohols, sugar alcohols, monosaccharides, disaccharides, and oligosaccharides. glucomannan composition. 2. A glucomannan composition obtained by kneading and reacting glucomannan and other natural polysaccharides with an alkali in a system consisting of at least one selected from polyhydric alcohols, sugar alcohols, monosaccharides, disaccharides, and oligosaccharides. thing.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP60-121594 | 1985-06-06 | ||
| JP12159485 | 1985-06-06 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS6296060A JPS6296060A (en) | 1987-05-02 |
| JPH0467945B2 true JPH0467945B2 (en) | 1992-10-29 |
Family
ID=14815117
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP60267273A Granted JPS6296060A (en) | 1985-06-06 | 1985-11-29 | Glucomannan composition |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS6296060A (en) |
Families Citing this family (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH022320A (en) * | 1988-06-14 | 1990-01-08 | Kazuo Hara | Production of gel like foods |
| JPH04960A (en) * | 1990-04-18 | 1992-01-06 | Sharp Corp | Facsimile equipment |
| JP3579753B2 (en) * | 1995-09-07 | 2004-10-20 | 武憲 加藤 | How to improve the quality of cut konjac gel |
| JP2002095427A (en) * | 2000-09-22 | 2002-04-02 | Nikken Chem Co Ltd | Devil's tongue for refrigeration and method for producing the same |
| JP5729721B2 (en) * | 2011-07-20 | 2015-06-03 | 日清オイリオグループ株式会社 | Flower paste |
| JP7420373B2 (en) * | 2019-12-10 | 2024-01-23 | アスザックフーズ株式会社 | Konnyaku food and its manufacturing method |
Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS51112533A (en) * | 1975-03-27 | 1976-10-05 | Sumitomo Bakelite Co | Process for preparing edible film |
| JPS5270039A (en) * | 1975-12-08 | 1977-06-10 | Sumitomo Bakelite Co | Edible packed body |
| JPS55148064A (en) * | 1979-04-11 | 1980-11-18 | Mars Ltd | Edible substance |
| JPS5618555A (en) * | 1979-07-20 | 1981-02-21 | Nippon Oil & Fats Co Ltd | Edible film |
| JPS5651740A (en) * | 1979-09-18 | 1981-05-09 | Ciba Geigy Ag | Colorrcoupler combined material |
| JPS5774072A (en) * | 1980-10-29 | 1982-05-10 | Yamanouchi Pharmaceut Co Ltd | Granule of dietary fiber and its preparation |
| JPS60219238A (en) * | 1984-04-14 | 1985-11-01 | Hayashibara Biochem Lab Inc | Formed product containing slowly disintegrating pullulan and its production |
-
1985
- 1985-11-29 JP JP60267273A patent/JPS6296060A/en active Granted
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS51112533A (en) * | 1975-03-27 | 1976-10-05 | Sumitomo Bakelite Co | Process for preparing edible film |
| JPS5270039A (en) * | 1975-12-08 | 1977-06-10 | Sumitomo Bakelite Co | Edible packed body |
| JPS55148064A (en) * | 1979-04-11 | 1980-11-18 | Mars Ltd | Edible substance |
| JPS5618555A (en) * | 1979-07-20 | 1981-02-21 | Nippon Oil & Fats Co Ltd | Edible film |
| JPS5651740A (en) * | 1979-09-18 | 1981-05-09 | Ciba Geigy Ag | Colorrcoupler combined material |
| JPS5774072A (en) * | 1980-10-29 | 1982-05-10 | Yamanouchi Pharmaceut Co Ltd | Granule of dietary fiber and its preparation |
| JPS60219238A (en) * | 1984-04-14 | 1985-11-01 | Hayashibara Biochem Lab Inc | Formed product containing slowly disintegrating pullulan and its production |
Also Published As
| Publication number | Publication date |
|---|---|
| JPS6296060A (en) | 1987-05-02 |
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