JPH046681B2 - - Google Patents
Info
- Publication number
- JPH046681B2 JPH046681B2 JP27962084A JP27962084A JPH046681B2 JP H046681 B2 JPH046681 B2 JP H046681B2 JP 27962084 A JP27962084 A JP 27962084A JP 27962084 A JP27962084 A JP 27962084A JP H046681 B2 JPH046681 B2 JP H046681B2
- Authority
- JP
- Japan
- Prior art keywords
- insect repellent
- oil
- indicator
- paper
- liquid
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000000077 insect repellent Substances 0.000 claims description 91
- 239000000463 material Substances 0.000 claims description 74
- 239000007788 liquid Substances 0.000 claims description 43
- 239000010410 layer Substances 0.000 claims description 31
- 239000003795 chemical substances by application Substances 0.000 claims description 21
- 239000000758 substrate Substances 0.000 claims description 11
- 239000000203 mixture Substances 0.000 claims description 7
- 229940057995 liquid paraffin Drugs 0.000 claims description 6
- 239000002346 layers by function Substances 0.000 claims description 2
- 230000001747 exhibiting effect Effects 0.000 claims 1
- -1 4-methyl-4-hepten-1-yn-3-yl Chemical group 0.000 description 6
- 239000011230 binding agent Substances 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 239000003921 oil Substances 0.000 description 4
- XLOPRKKSAJMMEW-SFYZADRCSA-M (R,R)-chrysanthemate Chemical compound CC(C)=C[C@@H]1[C@@H](C([O-])=O)C1(C)C XLOPRKKSAJMMEW-SFYZADRCSA-M 0.000 description 3
- 239000004743 Polypropylene Substances 0.000 description 3
- 239000000123 paper Substances 0.000 description 3
- 229920001155 polypropylene Polymers 0.000 description 3
- 229920003002 synthetic resin Polymers 0.000 description 3
- 239000000057 synthetic resin Substances 0.000 description 3
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- 238000000576 coating method Methods 0.000 description 2
- 239000003086 colorant Substances 0.000 description 2
- 229920000126 latex Polymers 0.000 description 2
- 239000004816 latex Substances 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- LLMLSUSAKZVFOA-UHFFFAOYSA-N 3-(2,2-dichlorovinyl)-2,2-dimethylcyclopropanecarboxylic acid Chemical compound CC1(C)C(C=C(Cl)Cl)C1C(O)=O LLMLSUSAKZVFOA-UHFFFAOYSA-N 0.000 description 1
- 239000004925 Acrylic resin Substances 0.000 description 1
- 229920000178 Acrylic resin Polymers 0.000 description 1
- 235000002566 Capsicum Nutrition 0.000 description 1
- 239000006002 Pepper Substances 0.000 description 1
- 235000016761 Piper aduncum Nutrition 0.000 description 1
- 235000017804 Piper guineense Nutrition 0.000 description 1
- 244000203593 Piper nigrum Species 0.000 description 1
- 235000008184 Piper nigrum Nutrition 0.000 description 1
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- 239000004480 active ingredient Substances 0.000 description 1
- 239000012752 auxiliary agent Substances 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- 239000004359 castor oil Substances 0.000 description 1
- 235000019438 castor oil Nutrition 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000004040 coloring Methods 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 description 1
- 238000005470 impregnation Methods 0.000 description 1
- 239000012784 inorganic fiber Substances 0.000 description 1
- 229940119170 jojoba wax Drugs 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 239000011259 mixed solution Substances 0.000 description 1
- 239000004745 nonwoven fabric Substances 0.000 description 1
- 239000005416 organic matter Substances 0.000 description 1
- 239000011087 paperboard Substances 0.000 description 1
- 230000035699 permeability Effects 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 239000010665 pine oil Substances 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 230000000717 retained effect Effects 0.000 description 1
- 229920002545 silicone oil Polymers 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 230000002459 sustained effect Effects 0.000 description 1
- 239000012209 synthetic fiber Substances 0.000 description 1
- 229920002994 synthetic fiber Polymers 0.000 description 1
Description
〔産業上の利用分野〕
本発明は、本来の防虫機能と防虫能表示器とし
ての機能を一体的に保持する防虫能表示器兼用防
虫剤に関する。
〔従来の技術〕
近時、旧来の揮散性固形防虫剤自体をそのまま
定形的に固化した防虫材に代つて、常温揮散性の
防虫薬液剤を合成樹脂などに含有させた構成の防
虫材が現に使用されてきており、さらには、この
ような防虫材に防虫能表示部分を一体的に構成さ
せた型式の防虫能表示器兼用の防虫材の開発も進
められている。
〔発明の課題〕
このような防虫材においては、その使用目的及
び使用場面により、大きさ、厚さ、その他の形状
の変化、防虫薬液剤の含有量、有効期限などに関
する多様性が強く要求されている。
このような状況下で、本発明は上記の如き大き
さ、厚さ、その他の形状の変化に影響されること
がない顕著でかつ安定な表示機能を有する防虫能
表示器兼用防虫材の提供を目的とする。
〔問題点を解決するための手段〕
上記の目的を達成するため本発明は防虫能表示
器兼用防虫材について、次の構成を採用した。即
ち、油液含有時に透明状に変性される防虫能表示
機能層を表面上に有し油不透過性模様層部分を含
むか若しくは含まない油透過性材を主材とする紙
状体、この紙状体の前記主材中に常温揮散性の油
性防虫薬液剤と前記防虫能表示機能層を透明状に
変性しない量の不揮散性助液剤との均一混合液が
含有せしめられてなる構成を特徴とする。
このように構成される本発明に於いて、含有す
べき均一混合液の活性成分である防虫薬液剤は常
温揮散性であることが要件とされ、例えば、０−
（２，２−ジクロロビニル）−０，０−ジメチルホ
スフエイト、４−メチル−４−ヘプテン−１−イ
ン−３−イル ｄ−シス，トランス−クリサンテ
マート、２，３，４，５，６−ペンタフルオロベ
ンジル ２，２−ジメチル−３−（２，２−ジク
ロロエテニル）−シクロプロパン−１−カルボキ
シレートなどを挙げることができる。また不揮散
性助液剤としては、上記した防虫薬液剤に対し化
学的に不活性であると共に均一に混合させること
ができ、かつ常温不揮散性であることが要件とさ
れ、例えば、流動パラフイン、ホホバオイル、シ
リコン油、ヒマシ油、パイン油、ハツカ油などを
挙げることができる。この不揮散性助液剤の量
は、上記した各構成要素の性質、量などによつて
も変わり得るが、顕著でかつ安定な表示機能を発
揮させる意味から、混合液全量に対し20（重量）
％以下が好ましい。
〔作 用〕
上記した構成を特徴とする本発明に係る防虫能
表示器兼用防虫材は、次のようにしてその防虫能
力の有無を顕著にしかも安定に表示する機能を有
する。
即ち、本発明に係る防虫能表示器兼用防虫材の
防虫能表示機能は、紙状体の主材内に含有保持さ
れる防虫薬液剤と不揮散性助液剤とよりなる前記
均一混合液の存在により透明化され、一方、この
防虫薬液剤の揮散消失により不透明となる。
前記均一混合液中の不揮散性助液剤は、紙状体
上の揮散面に於ける防虫薬液剤の揮散状態の均一
化及び揮散放出の円滑化を助長し、よつて、防虫
材の大きさ、厚さなどの形態に捉われることな
く、顕著でかつ安定な表示機能をもたらす。
〔実施例〕
次に、本発明を図に示す実施例に基づき詳細に
説明する。
本発明に係る実施例での防虫能表示器兼用防虫
材１を第１図に正面図で説明的に示す。この実施
例は、紙状体２が、下地色を有する油透過性の基
板材４とこの基板材４の一片面上に形成した油透
過性で低屈折率の地色層５とによりなる主材３
と、この主材３がその基板材４部を介して貼着さ
れた油不透過性シート８とによりなり、この紙状
材２の主材３内に防虫薬液剤１１としての４−メ
チル−４−ヘプテン−１−イン−３−イル ｄ−
シス，トランス−クリサンテマートと、助液剤１
２としての流動パラフインとの均一混合液１０が
含有せしめられている。なお、７は下地色面であ
る。
この実施例に於いて、基板材４としては、混合
液１０を含有保持すると共に、その中の防虫薬液
剤が徐放的に揮散するように構成された紙、板
紙、合成繊維混抄紙、不織布、フエルト状織物あ
るいは布帛状無機繊維などを、例えば縦10mm、横
28mmの大きさに裁断して用いることができる。ま
た地色層５は防虫表示機能層であるが、例えば白
色系着色料については無定形シリカ、カリオン、
炭酸カルシウム、又はパルプ粉末などの有機物を
適用することができ、またこのような着色料を基
板材４面上に定着させるために酢酸ビニル、
EVA、NBR、SBR、アクリル系その他のラテツ
クスなどの結合剤が用いられ、この結合剤が用い
られ、この結合剤の混入比率を適宜選定すること
により地色層５での油透過性が適度に設定され
る。
また下地色層面７が、地色層５の下層位置であ
つて基板材４面上に顔料、染料などの着色料と前
記した結合剤とによりなる油透過性の下地色層に
より形成されることもある。
またシート材８は、ポリプロピレン等の合成樹
脂材など油不透過性材を板状又はフイルム状に形
成して用いられる。
この実施例に於いて、地色層５は均一混合液１
０の存在により透明化され、この防虫能表示器兼
用防虫材１の表示機能面６は下地色を呈する。そ
して、この防虫能表示器兼用防虫材１はその使用
に際し、その表示機能面６から防虫薬液剤１１が
徐放的に揮散放出される。このとき、助液剤１２
は防虫薬液剤１１の地色層５へさらにはその表示
機能面６へ移動を助長し、さらにはこの防虫薬液
剤１１を表示機能面６の全域に亘つて平均化する
ように作用する。次に防虫薬液剤１１のほぼ全量
が揮散放出された後の防虫能表示器兼用防虫材１
では地色層５が不透明となり、表示機能面６は地
色層５面上の地色を呈することになる。このと
き、助液剤１２は防虫薬液剤１１の消失直前まで
地色層５の透明化状態を維持するように作用す
る。
このようにして、この防虫能表示器兼用防虫材
１に於いて、防虫能についての表示変化が防虫効
果の消減時期に合致して生じる。
次に、第２の実施例としては、主材３上に油不
透過性の模様層１３を含む構成の防虫能表示器兼
用防虫材１′を第２図及び第３図に斜視図、Ａ−
Ａ縦断面図で示す。この第２の実施例は、模様層
部１３が地色層５の下層位置であつて基板材４面
上に部分的な塗布形態で構成されており、他の構
成部は前記した第１の実施例と同じ構成をなす。
この模様層部１３としては、アクリル樹脂、ポリ
プロピレン等の合成樹脂、SBR等のラテツクス
などの油不透過性の形成材を用いて、塗布法又は
各種の印刷法を適用することによつて形成され
る。
この第２の実施例に於いて、均一混合液１０は
模様層部１３の上層をなす地色層部分５′にも及
んで地色層５全体が透明化され、この防虫能表示
器兼用防虫材１の表示機能面は下地色と共に模様
層部１３による模様を現わす。また防虫薬液剤１
１が表示機能面６から揮散されそのほぼ全量が放
出された後には前記第１の実施例での場合と同様
に、その地色層が不透明となつて表示機能面６は
地色層５面上の地色を呈することになり、このと
き、前記模様層１３による模様の消去も顕著であ
る。
試験例 １
紙材（縦：100mm、横：150mm、厚：0.5mm）を
基板材４とし、この基板材４面上に無定形シリカ
を着色物質とし、これに結合剤を１対１（重量）
部の割合で混合した塗布液を35ｇ／m2（dry）で
形成した地色層５を有する主材３、この主材３を
ポリプロピレン製シート材８上に接着して紙状体
２とした。
次に、４−メチル−４−ヘプテン−１−イン−
３−イル ｄ−シス，トランス−クリサンテマー
トと流動パラフインとの均一混合液１０（流動パ
ラフイン含量；16（重量）％）を調製した。
この混合液１０を前記紙状体２内に含浸機を用
いて含浸させ、紙状体２内に2.4ｇの混合液１０
が含有された。なお、この場合、防虫薬液剤１１
の含有量は2.0ｇであつた。このとき表示機能面
６は透明化され、防虫材はその下地色である赤色
系の色相を呈した。
この防虫能表示器兼用防虫材１を初春から初夏
（15〜28℃）の時期に洋服箪笥内に設置した。こ
の結果、１日当り10mgの割合で防虫薬液剤１１が
揮散消失したことを確認し、約６ケ月の期間内有
効な防虫効果を発揮し、約６ケ月後の２〜３日間
にてその表示機能面６が全体として均一に白く変
色したことを確認した。
試験例 ２
次に、試験例１での紙状体２に対し、次表１の
割合で助液剤１２として流動パラフインを混入し
て得られる種々の均一混合液10μを夫々含浸含
有せしめ検体とした。
この検体について、夫々その含有する防虫薬液
剤１１を完全に揮散消失せしめてその検体の色調
を確認した。なお、ブランクとしては、何も含浸
されない紙状体２とした。
[Industrial Field of Application] The present invention relates to an insect repellent that serves both as an insect repellent indicator and as an insect repellent indicator, which integrally maintains the original insect repellent function and the function as an insect repellent indicator. [Prior art] In recent years, instead of the conventional insect repellent material made by solidifying the volatile solid insect repellent itself into a fixed shape, insect repellent materials have been developed that consist of a synthetic resin containing a liquid insect repellent agent that is volatile at room temperature. In addition, progress is being made in the development of a type of insect repellent material that also serves as an insect repellent indicator, in which an insect repellent indicator part is integrated with such an insect repellent material. [Problems to be solved by the invention] Such insect repellent materials are strongly required to have diversity in terms of size, thickness, other changes in shape, content of insect repellent liquid, expiration date, etc., depending on the purpose and scene of use. ing. Under these circumstances, the present invention aims to provide an insect repellent material that also serves as an insect repellent indicator and has a remarkable and stable display function that is not affected by changes in size, thickness, and other shapes as described above. purpose. [Means for Solving the Problems] In order to achieve the above object, the present invention employs the following configuration for an insect repellent material that also serves as an insect repellent indicator. In other words, a paper-like material whose main material is an oil-permeable material that has an insect-repellent display function layer on its surface that changes to a transparent state when it contains an oil liquid, and which may or may not contain an oil-impermeable pattern layer. A structure in which the main material of the paper-like material contains a uniform mixture of an oil-based insect repellent liquid volatile at room temperature and a non-volatile auxiliary liquid agent in an amount that does not change the insect repellent ability display functional layer to a transparent state. Features. In the present invention configured as described above, it is required that the insect repellent solution, which is the active ingredient of the uniform mixture, be volatile at room temperature, for example, 0-
(2,2-dichlorovinyl)-0,0-dimethylphosphate, 4-methyl-4-hepten-1-yn-3-yl d-cis,trans-chrysanthemate, 2,3,4,5, Examples include 6-pentafluorobenzyl 2,2-dimethyl-3-(2,2-dichloroethenyl)-cyclopropane-1-carboxylate. In addition, non-volatile auxiliary liquid agents are required to be chemically inert to the above-mentioned insect repellent liquid agents, to be able to be mixed uniformly, and to be non-volatile at room temperature, such as liquid paraffin, Examples include jojoba oil, silicone oil, castor oil, pine oil, and pepper oil. The amount of this non-volatile auxiliary liquid agent may vary depending on the properties and amounts of each of the above-mentioned components, but in order to exhibit a remarkable and stable display function, the amount of non-volatile auxiliary liquid agent is 20 (by weight) based on the total amount of the mixed liquid.
% or less is preferable. [Function] The insect repellent material that also functions as an insect repellent indicator according to the present invention, which is characterized by the above-described configuration, has the function of clearly and stably displaying the presence or absence of its insect repellent ability in the following manner. That is, the insect repellent ability display function of the insect repellent material that also serves as an insect repellent ability indicator according to the present invention is based on the presence of the uniform liquid mixture consisting of an insect repellent liquid agent and a non-volatile auxiliary liquid agent contained and retained within the main material of the paper-like material. On the other hand, it becomes opaque as the insect repellent liquid evaporates and disappears. The non-volatile auxiliary liquid in the uniform mixture helps to equalize the volatilization state of the insect repellent liquid agent on the volatilization surface of the paper-like material and to smooth the volatilization release, thereby reducing the size of the insect repellent material. , it provides a remarkable and stable display function regardless of the form such as thickness. [Example] Next, the present invention will be described in detail based on an example shown in the drawings. An insect repellent material 1 which also serves as an insect repellent indicator according to an embodiment of the present invention is illustrated in a front view in an explanatory manner in FIG. In this embodiment, the paper-like body 2 is mainly composed of an oil-permeable substrate material 4 having a base color and an oil-permeable base color layer 5 having a low refractive index formed on one side of the base material 4. material 3
This main material 3 is made up of an oil-impermeable sheet 8 pasted through the substrate material 4, and 4-methyl- as an insect repellent liquid agent 11 is contained in the main material 3 of this paper-like material 2. 4-Hepten-1-yn-3-yl d-
Cis, trans-chrysanthemate and auxiliary agent 1
A homogeneous mixed liquid 10 with liquid paraffin as 2 is contained. Note that 7 is the base color surface. In this embodiment, the substrate material 4 is paper, paperboard, paper mixed with synthetic fibers, or nonwoven fabric that is configured to contain and hold the mixed liquid 10 and to allow the insect repellent liquid therein to volatilize in a sustained manner. , felt-like fabric or fabric-like inorganic fiber, etc., for example, 10 mm in length and width.
Can be cut to 28mm size. The ground color layer 5 is an insect repellent display function layer, and for example, white colorants such as amorphous silica, carrion,
Organic matter such as calcium carbonate or pulp powder can be applied, and vinyl acetate,
A binder such as EVA, NBR, SBR, acrylic or other latex is used, and by appropriately selecting the mixing ratio of this binder, the oil permeability in the ground color layer 5 can be adjusted to an appropriate level. Set. Further, the base color layer surface 7 is located below the base color layer 5 and is formed on the surface of the substrate material 4 by an oil-permeable base color layer made of a colorant such as a pigment or dye and the above-mentioned binder. There is also. The sheet material 8 is formed from an oil-impermeable material such as a synthetic resin material such as polypropylene into a plate or film shape. In this embodiment, the ground color layer 5 is made of a uniform mixed liquid 1.
The display function surface 6 of this insect repellent material 1 that also serves as an insect repellent indicator exhibits a base color. When the insect repellent material 1 is used as an insect repellent indicator, the insect repellent liquid 11 is gradually volatilized and released from the display function surface 6. At this time, the auxiliary liquid agent 12
promotes the movement of the insect repellent liquid 11 to the ground color layer 5 and further to the display functional surface 6, and further acts to average out the insect repellent liquid 11 over the entire area of the display functional surface 6. Next, after almost the entire amount of the insect repellent liquid agent 11 has been volatilized and released, the insect repellent material 1 that also serves as an insect repellent indicator
In this case, the ground color layer 5 becomes opaque, and the display functional surface 6 exhibits the ground color on the surface of the ground color layer 5. At this time, the auxiliary liquid agent 12 acts to maintain the transparent state of the ground color layer 5 until just before the insect repellent liquid agent 11 disappears. In this way, in this insect repellent material 1 that also functions as an insect repellent indicator, the display change regarding the insect repellent ability occurs in accordance with the time when the insect repellent effect disappears. Next, as a second embodiment, an insect repellent material 1' which also serves as an insect repellent indicator and has an oil-impermeable pattern layer 13 on a main material 3 is shown in perspective views in FIGS. −
A is shown in a longitudinal cross-sectional view. In this second embodiment, the pattern layer portion 13 is located below the ground color layer 5 and is partially coated on the surface of the substrate material 4, and the other components are the same as those described above in the first embodiment. It has the same configuration as the embodiment.
The pattern layer 13 is formed by applying a coating method or various printing methods using an oil-impermeable forming material such as acrylic resin, synthetic resin such as polypropylene, or latex such as SBR. Ru. In this second embodiment, the uniform mixed liquid 10 extends to the ground color layer portion 5' forming the upper layer of the pattern layer section 13, making the entire ground color layer 5 transparent, and this insect repellent which also serves as an insect repellent indicator. The display function surface of the material 1 shows the pattern formed by the pattern layer portion 13 together with the base color. Also, insect repellent liquid 1
1 is volatilized from the display functional surface 6 and almost the entire amount thereof is released, the ground color layer becomes opaque and the display functional surface 6 becomes the ground color layer 5, as in the case of the first embodiment. At this time, the pattern formed by the pattern layer 13 is significantly erased. Test example 1 A paper material (length: 100 mm, width: 150 mm, thickness: 0.5 mm) was used as the substrate material 4, amorphous silica was used as a coloring substance on the 4th surface of this substrate material, and a binder was added to this in a ratio of 1:1 (by weight). )
A main material 3 having a ground color layer 5 formed of a coating solution mixed at a ratio of 35 g/m 2 (dry), and this main material 3 was adhered onto a polypropylene sheet material 8 to form a paper-like material 2. . Next, 4-methyl-4-hepten-1-yn-
A homogeneous mixed solution 10 (liquid paraffin content: 16% (weight)) of 3-yl d-cis, trans-chrysanthemate and liquid paraffin was prepared. This mixed liquid 10 is impregnated into the paper-like body 2 using an impregnation machine, and 2.4 g of the mixed liquid 10 is impregnated into the paper-like body 2.
was contained. In this case, insect repellent liquid agent 11
The content was 2.0g. At this time, the display function surface 6 became transparent, and the insect repellent material took on a reddish hue, which is the base color of the insect repellent material. This insect repellent material 1 that also serves as an insect repellent indicator was installed in a clothes drawer from early spring to early summer (15 to 28°C). As a result, it was confirmed that insect repellent liquid agent 11 was volatilized and disappeared at a rate of 10 mg per day, and exhibited effective insect repellent effect within a period of approximately 6 months, and its display function was confirmed for 2 to 3 days after approximately 6 months. It was confirmed that the surface 6 was uniformly discolored to white as a whole. Test Example 2 Next, the paper-like material 2 in Test Example 1 was impregnated with 10μ of various uniform mixtures obtained by mixing liquid paraffin as the auxiliary liquid 12 in the proportions shown in Table 1 below to serve as specimens. . For each sample, the insect repellent liquid agent 11 contained therein was completely volatilized and the color tone of the sample was confirmed. Note that the blank was a paper-like material 2 that was not impregnated with anything.
上述のように、本発明によれば、防虫能表示器
兼用防虫材について、優れた防虫効果と共に、大
きさ、厚さ、その他の形状の変化に影響されるこ
とがない顕著で均一かつ安定な表示機能を使用目
的及び使用場面に応じた多様な形態で発揮させる
ことができる。
As described above, according to the present invention, the insect repellent material that also serves as an insect repellent indicator has an excellent insect repellent effect and a remarkable, uniform, and stable property that is not affected by changes in size, thickness, or other shapes. The display function can be displayed in various forms depending on the purpose and situation of use.
第１図…本発明に係る実施例での防虫能表示器
兼用防虫材の説明的正面図、第２図…同第２の実
施例での防虫能表示器兼用防虫材の斜視図、第３
図…同第２の実施例での防虫能表示器兼用防虫材
の説明的Ａ−Ａ縦断面図。
図面符号の説明、１……防虫能表示器兼用防虫
材、２……紙状体、３……主材、４……基板材、
５……地色層、８……油不透過性シート、１０…
…均一混合液、１１……防虫薬液剤、１２……助
液剤。
Fig. 1...An explanatory front view of the insect repellent material that also serves as an insect repellent indicator according to the embodiment of the present invention, Fig. 2...A perspective view of the insect repellent material that also serves as an insect repellent indicator in the second embodiment of the present invention, and Fig. 3.
Figure: An explanatory AA longitudinal cross-sectional view of the insect repellent material that also serves as an insect repellent indicator according to the second embodiment. Explanation of drawing symbols, 1...Insect repellent material that also serves as an insect repellent indicator, 2...Paper-like material, 3...Main material, 4...Substrate material,
5... Ground color layer, 8... Oil-impermeable sheet, 10...
... Homogeneous mixed liquid, 11 ... Insect repellent liquid agent, 12 ... Auxiliary liquid agent.
Claims (1)
機能層を表面上に有し油不透過性模様層部分を含
むか若しくは含まない油透過性材を主材とする紙
状体、この紙状体の前記主材中に常温揮散性の油
性防虫薬液剤と前記防虫能表示機能層を透明状に
変性しない量の不揮散性助液剤との均一混合液が
含有せしめられてなる構成を特徴とする防虫能表
示器兼用防虫材。 ２ 紙状体が、下地色を呈する油透過性の基板材
とこの基板材の一片面上に形成した油透過性で低
屈折率の地色層とによりなる主材と、この主材が
その基板材部を介して貼着された油不透過性シー
トとによりなる場合の特許請求の範囲第１項記載
の防虫能表示器兼用防虫材。 ３ 不揮散性助液剤が流動パラフインである場合
の特許請求の範囲第１項又は第２項記載の防虫能
表示器兼用防虫材。 ４ 均一混合液に於ける不揮散性助液剤の混入割
合が20（重量）％以下である場合の特許請求の範
囲第１項、第２項又は第３項記載の防虫能表示器
兼用防虫材。[Scope of Claims] 1. The main material is an oil-permeable material that has an insect-repellent display function layer on its surface that changes to a transparent state when containing oil and may or may not include an oil-impermeable pattern layer portion. a paper-like body, the main material of the paper-like body containing a uniform mixture of an oil-based insect repellent liquid volatile at room temperature and a non-volatile auxiliary liquid agent in an amount that does not change the insect repellent ability display functional layer to a transparent state; An insect repellent material that doubles as an insect repellent indicator and is characterized by its structure. 2. The paper-like material has a main material consisting of an oil-permeable substrate material exhibiting a base color and an oil-permeable low refractive index ground color layer formed on one side of this substrate material, and this main material is The insect repellent material that also serves as an insect repellent indicator as claimed in claim 1, wherein the insect repellent material is comprised of an oil-impermeable sheet attached via a substrate material. 3. The insect repellent material that also functions as an insect repellent indicator according to claim 1 or 2, wherein the non-volatile auxiliary liquid agent is liquid paraffin. 4. Insect repellent material that also serves as an insect repellent indicator as set forth in claim 1, 2, or 3, where the proportion of the nonvolatile auxiliary liquid in the uniform mixture is 20% (by weight) or less. .
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP27962084A JPS61152601A (en) | 1984-12-27 | 1984-12-27 | Insecticidal ability display device combinedly used as insecticidal material |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP27962084A JPS61152601A (en) | 1984-12-27 | 1984-12-27 | Insecticidal ability display device combinedly used as insecticidal material |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS61152601A JPS61152601A (en) | 1986-07-11 |
| JPH046681B2 true JPH046681B2 (en) | 1992-02-06 |
Family
ID=17613515
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP27962084A Granted JPS61152601A (en) | 1984-12-27 | 1984-12-27 | Insecticidal ability display device combinedly used as insecticidal material |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS61152601A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2004013828A1 (en) * | 2002-08-05 | 2004-02-12 | Mishima Paper Co., Ltd. | Term indicator |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2561976Y2 (en) * | 1990-07-20 | 1998-02-04 | 株式会社大阪製薬 | Insecticide or insect repellent with display function |
| JP4753404B2 (en) * | 2001-02-15 | 2011-08-24 | フマキラー株式会社 | Insect repellent display functional insect repellent |
| JP4733475B2 (en) * | 2004-09-07 | 2011-07-27 | 日本郵船株式会社 | Work scaffold equipment |
| US9913924B2 (en) * | 2016-05-25 | 2018-03-13 | S. C. Johnson & Son, Inc. | Dispensing device |
-
1984
- 1984-12-27 JP JP27962084A patent/JPS61152601A/en active Granted
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2004013828A1 (en) * | 2002-08-05 | 2004-02-12 | Mishima Paper Co., Ltd. | Term indicator |
Also Published As
| Publication number | Publication date |
|---|---|
| JPS61152601A (en) | 1986-07-11 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| EXPY | Cancellation because of completion of term |