JPH0461915B2 - - Google Patents
Info
- Publication number
- JPH0461915B2 JPH0461915B2 JP59128934A JP12893484A JPH0461915B2 JP H0461915 B2 JPH0461915 B2 JP H0461915B2 JP 59128934 A JP59128934 A JP 59128934A JP 12893484 A JP12893484 A JP 12893484A JP H0461915 B2 JPH0461915 B2 JP H0461915B2
- Authority
- JP
- Japan
- Prior art keywords
- cleaning
- weight
- cleaning composition
- cleaning agent
- stains
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 238000004140 cleaning Methods 0.000 claims description 22
- 239000000203 mixture Substances 0.000 claims description 11
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 claims description 9
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 6
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical group [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 claims description 6
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical group [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 6
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 claims description 6
- 239000002280 amphoteric surfactant Substances 0.000 claims description 5
- 150000008044 alkali metal hydroxides Chemical class 0.000 claims description 4
- 150000005846 sugar alcohols Polymers 0.000 claims description 4
- 235000011187 glycerol Nutrition 0.000 claims description 3
- 239000000470 constituent Substances 0.000 claims description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 2
- 239000012459 cleaning agent Substances 0.000 description 20
- 230000000052 comparative effect Effects 0.000 description 8
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 6
- -1 for example Substances 0.000 description 6
- 229910052751 metal Inorganic materials 0.000 description 5
- 239000002184 metal Substances 0.000 description 5
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 4
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 4
- 229910052802 copper Inorganic materials 0.000 description 4
- 239000010949 copper Substances 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 239000007788 liquid Substances 0.000 description 4
- 229910052708 sodium Inorganic materials 0.000 description 4
- 239000011734 sodium Substances 0.000 description 4
- RGHNJXZEOKUKBD-SQOUGZDYSA-N D-gluconic acid Chemical compound OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C(O)=O RGHNJXZEOKUKBD-SQOUGZDYSA-N 0.000 description 3
- 239000003599 detergent Substances 0.000 description 3
- 238000001035 drying Methods 0.000 description 3
- 229910052742 iron Inorganic materials 0.000 description 3
- DHMQDGOQFOQNFH-UHFFFAOYSA-N Glycine Chemical compound NCC(O)=O DHMQDGOQFOQNFH-UHFFFAOYSA-N 0.000 description 2
- 230000007797 corrosion Effects 0.000 description 2
- 238000005260 corrosion Methods 0.000 description 2
- KWIUHFFTVRNATP-UHFFFAOYSA-N glycine betaine Chemical compound C[N+](C)(C)CC([O-])=O KWIUHFFTVRNATP-UHFFFAOYSA-N 0.000 description 2
- 239000003112 inhibitor Substances 0.000 description 2
- 239000002932 luster Substances 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 239000004094 surface-active agent Substances 0.000 description 2
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 description 1
- RMZNXRYIFGTWPF-UHFFFAOYSA-N 2-nitrosoacetic acid Chemical compound OC(=O)CN=O RMZNXRYIFGTWPF-UHFFFAOYSA-N 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- 239000004471 Glycine Substances 0.000 description 1
- DRAJWRKLRBNJRQ-UHFFFAOYSA-N Hydroxycarbamic acid Chemical class ONC(O)=O DRAJWRKLRBNJRQ-UHFFFAOYSA-N 0.000 description 1
- QNAYBMKLOCPYGJ-REOHCLBHSA-N L-alanine Chemical compound C[C@H](N)C(O)=O QNAYBMKLOCPYGJ-REOHCLBHSA-N 0.000 description 1
- FSVCELGFZIQNCK-UHFFFAOYSA-N N,N-bis(2-hydroxyethyl)glycine Chemical compound OCCN(CCO)CC(O)=O FSVCELGFZIQNCK-UHFFFAOYSA-N 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 1
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 235000004279 alanine Nutrition 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 150000001414 amino alcohols Chemical class 0.000 description 1
- 239000003945 anionic surfactant Substances 0.000 description 1
- 235000015278 beef Nutrition 0.000 description 1
- 229960003237 betaine Drugs 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-N carbonic acid Chemical class OC(O)=O BVKZGUZCCUSVTD-UHFFFAOYSA-N 0.000 description 1
- 229920003064 carboxyethyl cellulose Polymers 0.000 description 1
- 239000002738 chelating agent Substances 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 239000004519 grease Substances 0.000 description 1
- MTNDZQHUAFNZQY-UHFFFAOYSA-N imidazoline Chemical compound C1CN=CN1 MTNDZQHUAFNZQY-UHFFFAOYSA-N 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 1
- 229910052622 kaolinite Inorganic materials 0.000 description 1
- 229910021645 metal ion Inorganic materials 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 239000002736 nonionic surfactant Substances 0.000 description 1
- 230000035515 penetration Effects 0.000 description 1
- 235000021317 phosphate Nutrition 0.000 description 1
- 229920001495 poly(sodium acrylate) polymer Polymers 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 235000018102 proteins Nutrition 0.000 description 1
- 102000004169 proteins and genes Human genes 0.000 description 1
- 108090000623 proteins and genes Proteins 0.000 description 1
- NNMHYFLPFNGQFZ-UHFFFAOYSA-M sodium polyacrylate Chemical compound [Na+].[O-]C(=O)C=C NNMHYFLPFNGQFZ-UHFFFAOYSA-M 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 239000011550 stock solution Substances 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
Landscapes
- Detergent Compositions (AREA)
Description
〔産業上の利用分野〕
本発明は、グリル、オーブン等の炭化した油汚
れ、ダクト内にたまつたグリース等をすばやく、
しかも金属を腐蝕させることなく洗浄するための
洗浄剤組成物に関するものである。
〔従来の技術及び問題点〕
従来、この種の洗浄剤はいくつか提案されてい
るが、これら公知の洗浄剤は次のような欠点を有
する。
洗浄力が弱い。
洗浄後に被洗物の光沢がなくなる。
高温時に洗浄を行なうと洗浄剤液がすぐに乾
固してしまい、作業性が悪くなつたり、洗浄剤
液が飛散して危険である。
被洗物が鉄やステンレスや銅の場合、腐蝕し
てしまう。
〔問題点を解決するための手段〕
本発明者らは、種々検討を重ねた結果、上記欠
点を改良した全く新しい優れた性能を有する洗浄
剤組成物を見い出し本発明に至つた。
即ち、本発明は必須の構成成分として、
アルカリ金属水酸化物 ５〜30重量％
トリエタノールアミン ５〜50重量％
多価アルコール ５〜60重量％
両性界面活性剤 0.5〜10重量％
水 残部
を含有することを特徴とする炭化した油汚れを洗
浄できる洗浄剤組成物を提供するものである。
本発明の必須成分のうち、アルカリ金属水酸化
物は、油汚れや蛋白質汚れを分解し、被洗物から
剥離する働きがあり、水酸化ナトリウム、水酸化
カリウムが特に好ましい。
一方、トリエタノールアミンは、油汚れを溶解
させるための溶剤、被洗物上に浮き出た金属イオ
ンをキレートし、金属表面に光沢を出すためのキ
レート剤、さらに洗浄後の金属表面の腐蝕防止剤
として働く。またトリエタノールアミンは、沸点
が277℃と高いので、高温洗浄時での洗浄剤液が
短時間に乾固するのを防止する働きがあり、プロ
ピレングリコール、グリセリン等の、この目的に
使われる成分を減少させることができる。
金属の光沢を出すために洗ビン剤原料として、
または鉄板クリーナー原料としてグリコン酸ソー
ダが公知であるが、グリコン酸ソーダには、油汚
れを溶解させるための溶剤としての効果、金属表
面の腐蝕防止剤としての効果、さらには、高温洗
浄時での洗浄剤液が短時間に乾固してしまうのを
防ぐ効果は期待できず、トリエタノールアミンを
使用することによりこれらの効果を得ることがで
きる。尚、同じアミノアルコールであつても、モ
ノエタノールアミン、ジエタノールアミンでは充
分な結果は得られなかつた。
また、多価アルコールは、洗浄剤液が短時間に
乾固するのを防止する働きがあり、グリセリン、
プロピレングリコールが特に好ましい。
また両性界面活性剤は、他の洗浄剤成分がすば
やく作用するための浸透剤として働く。さらに、
汚れの再付着を防止する働きがあり、耐アルカリ
性、耐熱性に優れたものが好ましく、グリシン
型、アラニン型、ベタイン型、イミダゾリン型の
両性界面活性剤が好ましい。これら両性界面活性
剤以外の界面活性剤、例えば、LAS、高級アル
コールサルフエート、高級アルコールエトキシサ
ルフエート、アルカンスルホネート、ポリオキシ
エチレンアルキルエーテルフオスフエート等の陰
イオン界面活性剤、高級アルコールエトキシレー
ト、アルキルフエノールエトキシレート等の非イ
オン界面活性剤では、充分な浸透力、汚れの再付
着防止力が得られず、優れた洗浄性が得られな
い。
また、本発明の洗浄剤組成物は、必要に応じ
て、ヒドロキシエチルエチレンジアミノトリ酢酸
塩、ジヒドロキシエチルグリシン等のヒドロキシ
アミノカルボン酸塩、ポリアクリル酸ソーダ、ポ
リフマル酸ソーダ等のポリマーやコポリマー、グ
リコン酸ソーダ等のヒドロキシカルボン酸塩を含
有することができる。
また、カオリナイト、タルク、カルボキシエチ
ルセルロース等を適当量加えて、粘性を高め、ペ
ースト状の洗浄剤にすることもできる。
〔実施例及び効果〕
以下、実施例により本発明を更に詳細に説明す
る。
実施例１〜６、比較例１〜５
表１に示す組成を有する洗浄剤を調製し、その
洗浄性及び腐蝕性を評価した。尚、表中の数字は
配合の重量部である。
[Industrial Application Field] The present invention quickly removes carbonized oil stains from grills, ovens, etc., grease accumulated in ducts, etc.
Moreover, the present invention relates to a cleaning composition for cleaning metal without corroding it. [Prior Art and Problems] Several cleaning agents of this type have been proposed in the past, but these known cleaning agents have the following drawbacks. Cleaning power is weak. After washing, the object to be washed loses its luster. If cleaning is carried out at high temperatures, the cleaning agent liquid will dry up quickly, resulting in poor workability and danger of the cleaning agent liquid scattering. If the item to be washed is iron, stainless steel, or copper, it will corrode. [Means for Solving the Problems] As a result of various studies, the present inventors have discovered a completely new cleaning composition with excellent performance that improves the above-mentioned drawbacks, resulting in the present invention. That is, the present invention contains as essential constituents: alkali metal hydroxide 5-30% by weight, triethanolamine 5-50% by weight, polyhydric alcohol 5-60% by weight, amphoteric surfactant 0.5-10% by weight, and the remainder water. The present invention provides a cleaning composition capable of cleaning carbonized oil stains. Among the essential components of the present invention, alkali metal hydroxides have the function of decomposing oil stains and protein stains and peeling them off from items to be washed, and sodium hydroxide and potassium hydroxide are particularly preferred. On the other hand, triethanolamine is used as a solvent for dissolving oil stains, as a chelating agent for chelating metal ions floating on objects to be washed and giving gloss to metal surfaces, and as a corrosion inhibitor for metal surfaces after cleaning. Work as. In addition, triethanolamine has a high boiling point of 277°C, so it works to prevent the cleaning agent solution from drying up in a short time during high-temperature cleaning, and components such as propylene glycol and glycerin are used for this purpose. can be reduced. Used as a raw material for bottle detergent to bring out the luster of metals.
Sodium glyconate is also known as a raw material for iron plate cleaners, but sodium glyconate has the effect of dissolving oil stains as a solvent, as a corrosion inhibitor for metal surfaces, and even when cleaning at high temperatures. The effect of preventing the detergent liquid from drying up in a short period of time cannot be expected, and these effects can be obtained by using triethanolamine. Incidentally, even when using the same amino alcohol, monoethanolamine and diethanolamine did not give sufficient results. In addition, polyhydric alcohol has the function of preventing the cleaning solution from drying up in a short period of time, and glycerin,
Propylene glycol is particularly preferred. Amphoteric surfactants also act as penetrants that allow other detergent ingredients to act quickly. moreover,
Preferably, the surfactant has the function of preventing dirt from re-deposition and has excellent alkali resistance and heat resistance, and amphoteric surfactants of glycine type, alanine type, betaine type, and imidazoline type are preferred. Surfactants other than these amphoteric surfactants, for example, anionic surfactants such as LAS, higher alcohol sulfates, higher alcohol ethoxy sulfates, alkanesulfonates, polyoxyethylene alkyl ether phosphates, higher alcohol ethoxylates, Nonionic surfactants such as alkyl phenol ethoxylates do not have sufficient penetration power or ability to prevent stains from re-deposition, and therefore cannot provide excellent cleaning performance. In addition, the cleaning composition of the present invention may optionally contain hydroxyaminocarboxylic acid salts such as hydroxyethylethylenediaminotriacetate and dihydroxyethylglycine, polymers and copolymers such as sodium polyacrylate and sodium polyfumarate, and glycone It can contain hydroxycarboxylic acid salts such as acid soda. It is also possible to add an appropriate amount of kaolinite, talc, carboxyethyl cellulose, etc. to increase the viscosity and make it into a paste-like cleaning agent. [Examples and Effects] Hereinafter, the present invention will be explained in more detail with reference to Examples. Examples 1 to 6, Comparative Examples 1 to 5 Cleaning agents having the compositions shown in Table 1 were prepared, and their cleaning properties and corrosivity were evaluated. Note that the numbers in the table are parts by weight of the formulation.
【表】【table】
【表】
(1) 洗浄性
牛肉を焼いて汚れた鉄製のグリドルを90℃に加
熱して上記洗浄剤を用いて洗浄を行なつたとこ
ろ、実施例１〜６の洗浄剤は、汚れの除去具合
い、作業性、洗浄後のグリドルの光沢、のいずれ
も素晴しい結果であつた。一方、比較例１の洗浄
剤は、汚れの除去具合い、洗浄後のグリドルの光
沢が不充分であつた。
比較例２の洗浄剤は、汚れの除去具合いが不充
分であつた。
比較例３の洗浄剤は、汚れの除去具合い、洗浄
後のグリドルの光沢が不充分であつた。
比較例４の洗浄例は、洗浄剤液がすぐ乾固して
しまい、作業性が悪かつた。
比較例５の洗浄剤は、汚れの除去具合いが不充
分であり、すすぎ時に、一旦剥離できた汚れが再
付着する現象が見られた。
また、実施例２の洗浄剤と比較例２の洗浄剤を
比べた場合、汚れの除去具合いに明らかな差があ
り、実施例２の洗浄剤が優れていた。このこと
は、トリエタノールアミンがグリコン酸ソーダよ
り効果的であることを示している。
(2) 腐蝕性
上記洗浄剤原液に銅板を40℃、24時間浸漬した
のち取り出し、銅板の外観を調べた結果、実施例
１〜６の洗浄剤はいずれも外観に何ら変化がなか
つた。
一方、比較例２と３の洗浄剤は、明らかに銅板
が白色を帯びて変化し、腐蝕されていた。[Table] (1) Cleanability When an iron griddle that had been stained by roasting beef was heated to 90°C and cleaned using the above cleaning agent, it was found that the cleaning agents of Examples 1 to 6 were effective in removing stains. The results were excellent in terms of condition, workability, and gloss of the griddle after cleaning. On the other hand, the cleaning agent of Comparative Example 1 was insufficient in removing stains and in producing a glossy griddle after cleaning. The cleaning agent of Comparative Example 2 was insufficient in removing stains. The cleaning agent of Comparative Example 3 was insufficient in terms of dirt removal and gloss of the griddle after cleaning. In the cleaning example of Comparative Example 4, the cleaning agent liquid dried up quickly, resulting in poor workability. The cleaning agent of Comparative Example 5 was insufficient in removing stains, and during rinsing, there was a phenomenon in which stains that had been removed once reattached. Furthermore, when the cleaning agent of Example 2 and the cleaning agent of Comparative Example 2 were compared, there was a clear difference in the degree of dirt removal, and the cleaning agent of Example 2 was superior. This indicates that triethanolamine is more effective than sodium glyconate. (2) Corrosivity A copper plate was immersed in the above cleaning agent stock solution at 40° C. for 24 hours, then taken out and the appearance of the copper plate was examined. As a result, there was no change in the appearance of any of the cleaning agents of Examples 1 to 6. On the other hand, with the cleaning agents of Comparative Examples 2 and 3, the copper plate clearly turned white and was corroded.
Claims (1)
浄できる洗浄剤組成物。 ２ 多価アルコールがプロピレングリコール、グ
リセリン或いはこれらの混合物から選ばれること
を特徴とする特許請求の範囲第１項記載の洗浄剤
組成物。 ３ アルカリ金属水酸化物が水酸化ナトリウム、
水酸化カリウム或いはこれらの混合物から選ばれ
ることを特徴とする特許請求の範囲第１項記載の
洗浄剤組成物。[Claims] 1. As essential constituents: Alkali metal hydroxide 5-30% by weight Triethanolamine 5-50% by weight Polyhydric alcohol 5-60% by weight Amphoteric surfactant 0.5-10% by weight Water Balance A cleaning composition capable of cleaning carbonized oil stains, characterized by containing the following. 2. The cleaning composition according to claim 1, wherein the polyhydric alcohol is selected from propylene glycol, glycerin, or a mixture thereof. 3 The alkali metal hydroxide is sodium hydroxide,
The cleaning composition according to claim 1, characterized in that it is selected from potassium hydroxide or a mixture thereof.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP59128934A JPS619500A (en) | 1984-06-22 | 1984-06-22 | Detergent composition |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP59128934A JPS619500A (en) | 1984-06-22 | 1984-06-22 | Detergent composition |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS619500A JPS619500A (en) | 1986-01-17 |
| JPH0461915B2 true JPH0461915B2 (en) | 1992-10-02 |
Family
ID=14997014
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP59128934A Granted JPS619500A (en) | 1984-06-22 | 1984-06-22 | Detergent composition |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS619500A (en) |
Families Citing this family (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS61291694A (en) * | 1985-06-17 | 1986-12-22 | 旭電化工業株式会社 | Detergent |
| JPS61296098A (en) * | 1985-06-25 | 1986-12-26 | ティーポール株式会社 | Solid detergent |
| JPS6234998A (en) * | 1985-08-08 | 1987-02-14 | 花王株式会社 | Alkali detergent composition |
| JPH0699717B2 (en) * | 1986-03-28 | 1994-12-07 | 日東化学株式会社 | Alkaline cleaner |
| US5336445A (en) * | 1990-03-27 | 1994-08-09 | The Procter & Gamble Company | Liquid hard surface detergent compositions containing beta-aminoalkanols |
| US5540864A (en) * | 1990-12-21 | 1996-07-30 | The Procter & Gamble Company | Liquid hard surfce detergent compositions containing zwitterionic detergent surfactant and monoethanolamine and/or beta-aminoalkanol |
| AU3473093A (en) * | 1992-01-23 | 1993-09-01 | Procter & Gamble Company, The | Liquid hard surface detergent compositions containing zwitterionic and cationic detergent surfactants and monoethanolamine and/or beta-aminoalkanol |
| US5536451A (en) * | 1992-10-26 | 1996-07-16 | The Procter & Gamble Company | Liquid hard surface detergent compositions containing short chain amphocarboxylate detergent surfactant |
| ES2143030T3 (en) * | 1993-11-12 | 2000-05-01 | Procter & Gamble | LIQUID DETERGENT COMPOSITIONS FOR HARD SURFACES, CONTAINING AMPHOTERO AND PERFUME DETERGENT SURFACTANT. |
| US5531933A (en) * | 1993-12-30 | 1996-07-02 | The Procter & Gamble Company | Liquid hard surface detergent compositions containing specific polycarboxylate detergent builders |
| JP2002030299A (en) * | 2000-07-17 | 2002-01-31 | Nippon Parkerizing Co Ltd | Aqueous alkali detergent for removing scaled coating sludge and method for removing scaled coating sludge |
| JP4841660B2 (en) * | 2009-06-26 | 2011-12-21 | ユニチカ株式会社 | Cleaning liquid for polyamide resin molded body and cleaning method using the same |
| WO2012035673A1 (en) * | 2010-09-17 | 2012-03-22 | ユニチカ株式会社 | Polyamide resin composition, method for producing polyamide resin composition, and article obtained by forming polyamide resin composition |
| JP6871606B2 (en) * | 2017-04-18 | 2021-05-12 | 株式会社ニイタカ | Cleaning agent composition for iron plate cleaning and iron plate cleaning method |
-
1984
- 1984-06-22 JP JP59128934A patent/JPS619500A/en active Granted
Also Published As
| Publication number | Publication date |
|---|---|
| JPS619500A (en) | 1986-01-17 |
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