JPH0457894A - Purified candelilla wax, its preparation, and solid cosmetic composition containing the same - Google Patents
Purified candelilla wax, its preparation, and solid cosmetic composition containing the sameInfo
- Publication number
- JPH0457894A JPH0457894A JP2170879A JP17087990A JPH0457894A JP H0457894 A JPH0457894 A JP H0457894A JP 2170879 A JP2170879 A JP 2170879A JP 17087990 A JP17087990 A JP 17087990A JP H0457894 A JPH0457894 A JP H0457894A
- Authority
- JP
- Japan
- Prior art keywords
- candelilla wax
- wax
- solid cosmetic
- same
- preparation
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000004204 candelilla wax Substances 0.000 title claims abstract description 34
- 235000013868 candelilla wax Nutrition 0.000 title claims abstract description 34
- 229940073532 candelilla wax Drugs 0.000 title claims abstract description 34
- IUJAMGNYPWYUPM-UHFFFAOYSA-N hentriacontane Chemical compound CCCCCCCCCCCCCCCCCCCCCCCCCCCCCCC IUJAMGNYPWYUPM-UHFFFAOYSA-N 0.000 title claims abstract description 34
- 239000002537 cosmetic Substances 0.000 title claims abstract description 21
- 239000007787 solid Substances 0.000 title claims description 15
- 239000000203 mixture Substances 0.000 title description 3
- 239000002253 acid Substances 0.000 claims abstract description 17
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims abstract description 12
- 238000004519 manufacturing process Methods 0.000 claims description 6
- 238000010438 heat treatment Methods 0.000 claims description 4
- 239000003921 oil Substances 0.000 abstract description 17
- 239000001993 wax Substances 0.000 abstract description 12
- 230000035900 sweating Effects 0.000 abstract description 11
- 238000000227 grinding Methods 0.000 abstract description 7
- 235000019198 oils Nutrition 0.000 description 16
- 239000003795 chemical substances by application Substances 0.000 description 13
- 239000000843 powder Substances 0.000 description 7
- 150000001298 alcohols Chemical class 0.000 description 5
- 230000000052 comparative effect Effects 0.000 description 5
- 239000000049 pigment Substances 0.000 description 5
- -1 polyethylene Polymers 0.000 description 5
- 230000000694 effects Effects 0.000 description 4
- 229930195733 hydrocarbon Natural products 0.000 description 4
- 150000002430 hydrocarbons Chemical class 0.000 description 4
- 229920005989 resin Polymers 0.000 description 4
- 239000011347 resin Substances 0.000 description 4
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- 239000004203 carnauba wax Substances 0.000 description 3
- 235000013869 carnauba wax Nutrition 0.000 description 3
- 235000014113 dietary fatty acids Nutrition 0.000 description 3
- 239000000194 fatty acid Substances 0.000 description 3
- 229930195729 fatty acid Natural products 0.000 description 3
- 235000021588 free fatty acids Nutrition 0.000 description 3
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 3
- 239000004615 ingredient Substances 0.000 description 3
- 239000002994 raw material Substances 0.000 description 3
- 238000012360 testing method Methods 0.000 description 3
- 239000004215 Carbon black (E152) Substances 0.000 description 2
- 239000004166 Lanolin Substances 0.000 description 2
- 239000004698 Polyethylene Substances 0.000 description 2
- 235000013871 bee wax Nutrition 0.000 description 2
- 239000012166 beeswax Substances 0.000 description 2
- 239000004359 castor oil Substances 0.000 description 2
- 235000019438 castor oil Nutrition 0.000 description 2
- 239000012185 ceresin wax Substances 0.000 description 2
- 238000007796 conventional method Methods 0.000 description 2
- 239000003974 emollient agent Substances 0.000 description 2
- 238000011156 evaluation Methods 0.000 description 2
- 150000004665 fatty acids Chemical class 0.000 description 2
- 235000011187 glycerol Nutrition 0.000 description 2
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 description 2
- 235000019388 lanolin Nutrition 0.000 description 2
- 229940039717 lanolin Drugs 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 230000035515 penetration Effects 0.000 description 2
- 229920000573 polyethylene Polymers 0.000 description 2
- VLPFTAMPNXLGLX-UHFFFAOYSA-N trioctanoin Chemical compound CCCCCCCC(=O)OCC(OC(=O)CCCCCCC)COC(=O)CCCCCCC VLPFTAMPNXLGLX-UHFFFAOYSA-N 0.000 description 2
- RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 description 1
- 239000004606 Fillers/Extenders Substances 0.000 description 1
- KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 description 1
- 235000019485 Safflower oil Nutrition 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- 239000006096 absorbing agent Substances 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 239000010775 animal oil Substances 0.000 description 1
- 229940053200 antiepileptics fatty acid derivative Drugs 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 230000003796 beauty Effects 0.000 description 1
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 1
- 238000004040 coloring Methods 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 239000010696 ester oil Substances 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 239000003205 fragrance Substances 0.000 description 1
- 239000003906 humectant Substances 0.000 description 1
- 239000007934 lip balm Substances 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 239000010445 mica Substances 0.000 description 1
- 229910052618 mica group Inorganic materials 0.000 description 1
- 239000002480 mineral oil Substances 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 230000009965 odorless effect Effects 0.000 description 1
- 239000012860 organic pigment Substances 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 229920001083 polybutene Polymers 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 239000003755 preservative agent Substances 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 235000005713 safflower oil Nutrition 0.000 description 1
- 239000003813 safflower oil Substances 0.000 description 1
- 229920002545 silicone oil Polymers 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 description 1
- 239000002966 varnish Substances 0.000 description 1
- 235000015112 vegetable and seed oil Nutrition 0.000 description 1
- 239000008158 vegetable oil Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Landscapes
- Cosmetics (AREA)
- Fats And Perfumes (AREA)
Abstract
Description
【発明の詳細な説明】
〔産業上の利用分野〕
本発明は、極性油剤の固形化能に優れたキャンデリラワ
ックス及びその製法、並びにこれを含有する固形化粧料
に関する。DETAILED DESCRIPTION OF THE INVENTION [Field of Industrial Application] The present invention relates to candelilla wax that has excellent ability to solidify polar oils, a method for producing the same, and a solid cosmetic containing the same.
〔従来の技術及び発明が解決しようとする課題〕従来、
固形化粧料には、ヒマシ油、グリセリン脂肪酸誘導体、
ラノリン誘導体、天然油剤等の極性油剤と、キャンデリ
ラワックス、カルナバワックス、ビーズワックス等の天
然ワックス、オシケライト、セレシンワックス等の炭化
水素ワックス、ポリエチレンワックス等の合成炭化水素
ワックスなどの固形化剤が併用されている。[Problems to be solved by conventional techniques and inventions] Conventionally,
Solid cosmetics include castor oil, glycerin fatty acid derivatives,
Polar oils such as lanolin derivatives and natural oils are used in combination with solidifying agents such as natural waxes such as candelilla wax, carnauba wax, and beeswax, hydrocarbon waxes such as osikelite and ceresin wax, and synthetic hydrocarbon waxes such as polyethylene wax. has been done.
これらのうち、極性油剤は、その分子中に水酸基、カル
ボキシル基等の極性部分を含むため、皮膚に対する付着
性やエモリエント性を向上させる等の効果を有する。ま
た、このような極性油剤の固化には、天然ワックスであ
るキャンデリラワックス、カルナバワックス、ビーズワ
ックスが好ましく、特に炭化水素とエステルをバランス
良く含むキャンデリラワックスが有効であることが知ら
れている。Among these, polar oils contain polar moieties such as hydroxyl groups and carboxyl groups in their molecules, and therefore have effects such as improving adhesion to the skin and emollient properties. In addition, natural waxes such as candelilla wax, carnauba wax, and beeswax are preferred for solidifying such polar oils, and it is known that candelilla wax, which contains a good balance of hydrocarbons and esters, is particularly effective. .
しかしながら、キャンデリラワックスは極性油剤の固形
化剤としては有効であるものの、遊離脂肪酸、アルコー
ル及び樹脂分等を含むため、特有の色及び臭いを有し、
これを含有する固形化粧料においては、経時的に発汗、
発粉等を生じるという問題があった。However, although candelilla wax is effective as a solidifying agent for polar oils, it has a unique color and odor because it contains free fatty acids, alcohol, resin, etc.
In solid cosmetics containing this, sweating over time,
There was a problem that powder generation occurred.
従って、極性油剤の固形化剤として有効であり、しかも
これを配合した固形化粧料において経時的な発汗、発粉
等を生じない固形化剤が望まれていた。Therefore, there has been a desire for a solidifying agent that is effective as a solidifying agent for polar oils and does not cause sweating, powdering, etc. over time in solid cosmetics containing this solidifying agent.
かかる実情において、本発明者らは鋭意研究を行なった
結果、遊離脂肪酸、遊離アルコール及び樹脂分を除去し
て得られた酸価が９以下のキャンデリラワックスは、極
性油剤の固形化能に優れ、色及び臭いが改善され、また
これを配合した固形化粧料は、経時的な発汗、発粉等が
抑制され、しかも使用感に優れたものであることを見出
し、本発明を完成した。Under these circumstances, the present inventors conducted intensive research and found that candelilla wax, which is obtained by removing free fatty acids, free alcohols, and resin components and has an acid value of 9 or less, has excellent solidifying ability for polar oil agents. The present invention has been completed based on the discovery that solid cosmetics containing the same have improved color and odor, suppress sweating and powdering over time, and have an excellent feeling of use.
すなわち、本発明は、酸価が９以下であることを特徴と
するキャンデリラワックス及びその製法、並びにこれを
含有する固形化粧料を提供するものである。That is, the present invention provides candelilla wax characterized by an acid value of 9 or less, a method for producing the same, and a solid cosmetic containing the same.
本発明の９以下の酸価を有するキャンデリラワックスは
、例えば酸価が１４〜２４のキャンデリラワックス及び
低級アルコールを５０〜７０℃に加熱し、当該加熱によ
る可溶分を除去することによって製造される。The candelilla wax of the present invention having an acid value of 9 or less can be produced, for example, by heating candelilla wax having an acid value of 14 to 24 and a lower alcohol to 50 to 70°C and removing the soluble content caused by the heating. be done.
本発明において、原料として用いられる酸価が１４〜２
４のキャンデリラワックスは通常化粧料に使用されるも
のであれば特に制限されず、例えば下記のような組成を
有するものである。In the present invention, the acid value used as the raw material is 14 to 2.
Candelilla wax No. 4 is not particularly limited as long as it is normally used in cosmetics, and for example, it has the following composition.
炭化水素 約５０％ワックス酸
とアルコールのニス 約３０％チル
遊離酸 約７〜９％本発明方
法を実施するには、このキャンデリラワックスを１〜１
０倍量の低級アルコールに加え、５０〜７０℃で５〜１
０分加熱し、可溶分を除去することにより行なわれる。Hydrocarbons: about 50% wax acid and alcohol varnish; about 30% chilled free acids; about 7-9%.
In addition to 0 times the amount of lower alcohol, 5 to 1 at 50 to 70℃
This is done by heating for 0 minutes and removing soluble components.
低級アルコールとしては、例えばメタノール、エタノー
ル等が挙げられる。Examples of lower alcohols include methanol and ethanol.
また、可溶分を除去するには、例えば熱時（４０℃以上
）濾過することにより、不溶分を分取すればよい。これ
により、原料のキャンデリラワックス中に含まれていた
遊離脂肪酸、遊離アルコール及び樹脂分が除去され、酸
価が９以下のキャンデリラワックスが得られる。Further, in order to remove the soluble content, the insoluble content may be separated by, for example, filtration at a temperature of 40° C. or higher. As a result, free fatty acids, free alcohols, and resin components contained in the raw material candelilla wax are removed, and candelilla wax having an acid value of 9 or less is obtained.
本発明の固形化粧料は、上記のようにして得られた酸価
が９以下のキャンデリラワックスを固形化剤として用い
、通常化粧料に用いられる粉体、液状油剤等と組み合わ
せて通常の方法に従って製造することができる。酸化が
９以下のキャンデリラワックスは、全組成中に１〜４０
重量％、特に５〜３０重量％配合するのが好ましい。ま
た、固形化剤として、これ以外に通常の化粧料に用いら
れる固形ワックスを併用することもできる。The solid cosmetic of the present invention can be produced by a conventional method using candelilla wax with an acid value of 9 or less obtained as described above as a solidifying agent, and combining it with powder, liquid oil, etc. commonly used in cosmetics. can be manufactured according to Candelilla wax with an oxidation level of 9 or less is 1 to 40 in the entire composition.
It is preferable to blend it in an amount of 5 to 30% by weight, particularly 5 to 30% by weight. Moreover, as a solidifying agent, a solid wax used in ordinary cosmetics can also be used in combination.
また、粉体としては、通常の化粧料に用いられるもので
あれば特に制限されず、例えば染料、体質顔料、無機白
色顔料、無機有色顔料、有機顔料、有機粉末、バール剤
等を使用することができる。Further, the powder is not particularly limited as long as it is used in ordinary cosmetics, and for example, dyes, extender pigments, inorganic white pigments, inorganic colored pigments, organic pigments, organic powders, bur agents, etc. may be used. I can do it.
液状油剤としても、通常の化粧料に用いられるものであ
れば特に制限されず、例えば鉱物油、動植物油、高級脂
肪酸油、高級脂肪酸エステル油、高級アルコール、シリ
コーン油等を使用することができる。The liquid oil agent is not particularly limited as long as it is used in ordinary cosmetics, and for example, mineral oils, animal and vegetable oils, higher fatty acid oils, higher fatty acid ester oils, higher alcohols, silicone oils, etc. can be used.
また、本発明の固形化粧料には、さらに通常の化粧料に
用いられる樹脂、高分子、界面活性剤、高級アルコール
、香料、保湿剤、防腐剤、美容成分、酸化防止剤、紫外
線吸収剤、溶剤等を本発明の効果を損なわない範囲で配
合することができる。In addition, the solid cosmetic of the present invention further includes resins, polymers, surfactants, higher alcohols, fragrances, humectants, preservatives, beauty ingredients, antioxidants, ultraviolet absorbers, which are used in ordinary cosmetics, Solvents and the like may be added within a range that does not impair the effects of the present invention.
そして本発明の固形化粧料は、例えば口紅、リップクリ
ーム、アイシャドウ、ファンデーションなどとして適用
することができる。The solid cosmetic of the present invention can be applied as, for example, lipstick, lip balm, eye shadow, foundation, and the like.
以下、実施例を挙げて本発明をさらに詳細に説明するが
、本発明はこれらに限定されるものではない。Hereinafter, the present invention will be explained in more detail with reference to Examples, but the present invention is not limited thereto.
実施例１
（１）キャンデリラワックスの製造
市販キャンデリラワックス（酸価Ｉ７．６、水酸基価６
８．２ 、野田ワックス社製）５０ｇを熱エタノール５
００ｇ中に溶解分散し、約５０℃でエタノール不溶分を
分取した。Example 1 (1) Production of candelilla wax Commercially available candelilla wax (acid value I7.6, hydroxyl value 6)
8.2 (manufactured by Noda Wax Co., Ltd.) 50g with hot ethanol 5
The solution was dissolved and dispersed in 0.00 g of water, and the ethanol-insoluble matter was separated at about 50°C.
得られたキャンデリラワックスは、酸価８．５４、水酸
基価５０，１であり、微黄色無臭であった。The obtained candelilla wax had an acid value of 8.54, a hydroxyl value of 50.1, and was slightly yellow and odorless.
（２） （１）で得たキャンデリラワックスについて、
これを化粧料に用いられる各種油剤と組合わせた際の硬
度及び発汗の有無を、原料として用いた市販キャンデリ
ラワックスと比較して評価した。結果を第１表に示す。(2) Regarding the candelilla wax obtained in (1),
The hardness and sweating when combined with various oils used in cosmetics were evaluated by comparing with commercially available candelilla wax used as a raw material. The results are shown in Table 1.
く評価方法〉
硬度：固形分が１５％になるよう、各々の成分を調製し
、全国に充填した後、２５℃での針入度を測定した。Evaluation method> Hardness: Each component was prepared so that the solid content was 15%, and after filling the product nationwide, the penetration was measured at 25°C.
針入度測定条件
レオメータ−ＮＲＭ−２００２０（不動工業■製）
針の直径 ３＋ｎｍ
針の降下速度 ５ｃｍ／ｍｉｎ
発汗：硬度の評価と同様にして、各成分を全国に充填固
化後、室温〜５０℃まで昇温（１℃／ｍ１ｎ）させたと
きの合冊表面の発汗状態を観察した。Penetration measurement conditions Rheometer - NRM-20020 (manufactured by Fudo Kogyo ■) Needle diameter 3+nm Needle descent speed 5cm/min Sweating: In the same manner as the hardness evaluation, after filling and solidifying each component nationwide, room temperature to 50℃ The state of perspiration on the surface of the book was observed when the temperature was raised to 1° C./m1n.
第１表から明らかな如く、本発明のキャンデリラワック
スを用いた場合には、市販のキャンデリラワックスを用
いた場合に比べ、硬度が高いものが得られ、また油剤の
種類によっては、充填物表面の発汗を抑えることができ
た。As is clear from Table 1, when using the candelilla wax of the present invention, a product with higher hardness can be obtained than when using commercially available candelilla wax, and depending on the type of oil agent, filler I was able to suppress surface sweating.
実施例２ 口紅：
（成分） （重量％）（２
）セレシンワックス
（３）カルナバワックス
（４）ラノリン
（５）トリオクタン酸グリセリル
（６）サフラワーオイル
（７）ヒマシ油
（８）マイカ
（９）チタン
０１着色顔料
（製法）
Ａ、（１）〜（７）を加熱溶解する。Example 2 Lipstick: (Ingredients) (Weight%) (2
) Ceresin wax (3) Carnauba wax (4) Lanolin (5) Glyceryl trioctanoate (6) Safflower oil (7) Castor oil (8) Mica (9) Titanium 01 color pigment (manufacturing method) A, (1) to ( 7) Heat and dissolve.
Ｂ、Ａに（８）〜αＯを加え、混練する。B. Add (8) to αO to A and knead.
２．０ ２．０ １０．０ １５．０ １０．０ 残量 適量 適量 適量 Ｃ，Ｂを溶解後、充填成型し、口紅を得る。2.0 2.0 10.0 15.0 10.0 Remaining amount Appropriate amount Appropriate amount Appropriate amount After dissolving C and B, filling and molding is performed to obtain a lipstick.
比較例１
実施例２において、（１）の精製キャンデリラワックス
のかわりに市販キャンデリラワックス（野田ワックス社
製）を用いた以外は実施例２と同様にして口紅を得た。Comparative Example 1 A lipstick was obtained in the same manner as in Example 2, except that commercially available candelilla wax (manufactured by Noda Wax Co., Ltd.) was used instead of the purified candelilla wax in (1).
試験例１
実施例２及び比較例１の口紅（直径１３ｍｍ）について
、実施例１の（２）と同様にして、硬度及び発汗、さら
に下記の方法により、発粉を評価した。結果を第２表に
示す。Test Example 1 The lipsticks (diameter 13 mm) of Example 2 and Comparative Example 1 were evaluated for hardness, perspiration, and powder generation in the same manner as in Example 1 (2). The results are shown in Table 2.
発粉：５０℃←５℃のサイクル（周期４８時間）で１ケ
月後の発粉状態を目視観察した。Powder generation: The state of powder generation was visually observed after one month in a cycle of 50°C←5°C (48 hour period).
第２表
本発明の口紅は、硬度が高く、しかも経時的な発汗や発
粉が生じなかった。Table 2 The lipsticks of the present invention had high hardness and did not cause sweating or powdering over time.
実施例３ ペンシル状アイライナー：（成分）
（重量％）（１）ポリエチレン
ワックス １３．０（２）精製キャンデリ
ラワックス ２０．０（実施例１（１）で得ら
れたもの）
（３）精製ハタロウ １５．０（
４）メチルフェニルポリシロキサン １０．０（５
）ポリブテン ５．０（６）
ロジン １０．０（７〕グ
リセリン脂肪酸エステル 残量（８）着色顔料
適量（製法）
Ａ、（１）〜（７）を加熱溶解する。Example 3 Pencil eyeliner: (ingredients)
(% by weight) (1) Polyethylene wax 13.0 (2) Purified candelilla wax 20.0 (obtained in Example 1 (1)) (3) Purified wax wax 15.0 (
4) Methylphenylpolysiloxane 10.0 (5
) Polybutene 5.0 (6)
Rosin 10.0 (7) Glycerin fatty acid ester Remaining amount (8) Coloring pigment Appropriate amount (Production method) A. Heat and dissolve (1) to (7).
Ｂ、Ａに（８）を加え、均一に分散する。Add (8) to B and A and disperse uniformly.
Ｃ，Ｂを成型し、ペンシル状アイライナーを得る。C and B are molded to obtain a pencil-like eyeliner.
比較例２
実施例３において、（２）の精製キャンデリラワックス
のかわりに市販キャンデリラワックス（野田ワックス社
製）を用いた以外は実施例３と同様にしてペンシル状ア
イライナーを得た。Comparative Example 2 A pencil-shaped eyeliner was obtained in the same manner as in Example 3, except that commercially available Candelilla wax (manufactured by Noda Wax Co., Ltd.) was used instead of the purified Candelilla wax in (2).
試験例２
実施例３及び比較例２のペンシル状アイライナー（直径
３ ｍｍ）について、試験例１と同様にして、硬度、発
汗及び発粉を評価した。Test Example 2 The pencil-shaped eyeliners (diameter 3 mm) of Example 3 and Comparative Example 2 were evaluated in the same manner as Test Example 1 for hardness, sweating, and powdering.
本発明のペンシル状アイライナーの硬度は１５６ｇで、
比較例２の１３０ ｇに比べ硬度が高く、しかも経時的
な発汗、発粉も抑えられていた。The hardness of the pencil-shaped eyeliner of the present invention is 156g,
The hardness was higher than that of Comparative Example 2 (130 g), and sweating and powdering over time were also suppressed.
本発明のキャンデリラワックスは、酸価が９以下であり
、色及び臭いが改善され、従来のキャンデリラワックス
に比べ、極性油剤の固形化能に優れたものである。従っ
て、これを配合した本発明の固形化粧料は、固形化剤と
してのワックスの配合量が少なくてすむため、使用感に
優れたものであり、また極性油剤を予歪に配合すること
が可能であるため、これら油剤による皮膚に対する付着
性、エモリエント性等の効果を向上させることができる
。さらに、本発明の固形化粧料は、経時的な発汗、発粉
が抑制されたものである。The candelilla wax of the present invention has an acid value of 9 or less, has improved color and odor, and has an excellent ability to solidify polar oil agents compared to conventional candelilla wax. Therefore, the solid cosmetic of the present invention containing this product requires only a small amount of wax as a solidifying agent, so it has an excellent feel when used, and polar oils can be pre-distorted. Therefore, the effects of these oils on skin adhesion, emollient properties, etc. can be improved. Furthermore, the solid cosmetic of the present invention suppresses sweating and powdering over time.
以 上that's all
Claims (1)
ワックス。 ２、酸価が１４〜２４のキャンデリラワックスを低級ア
ルコールと共に加熱し、当該加熱による可溶分を除去す
ることを特徴とする請求項１記載のキャンデリラワック
スの製法。３、請求項１記載のキャンデリラワックスを
含有することを特徴とする固形化粧料。[Claims] 1. Candelilla wax having an acid value of 9 or less. 2. The method for producing candelilla wax according to claim 1, characterized in that candelilla wax having an acid value of 14 to 24 is heated together with a lower alcohol, and soluble components caused by the heating are removed. 3. A solid cosmetic containing the candelilla wax according to claim 1.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2170879A JPH0457894A (en) | 1990-06-28 | 1990-06-28 | Purified candelilla wax, its preparation, and solid cosmetic composition containing the same |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2170879A JPH0457894A (en) | 1990-06-28 | 1990-06-28 | Purified candelilla wax, its preparation, and solid cosmetic composition containing the same |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH0457894A true JPH0457894A (en) | 1992-02-25 |
Family
ID=15913010
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2170879A Pending JPH0457894A (en) | 1990-06-28 | 1990-06-28 | Purified candelilla wax, its preparation, and solid cosmetic composition containing the same |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH0457894A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2007077210A (en) * | 2005-09-12 | 2007-03-29 | Naris Cosmetics Co Ltd | Compound wax and oil-based cosmetic containing the same |
| ES2834658A1 (en) * | 2019-12-18 | 2021-06-18 | Univ Almeria | Beeswax Contaminant Removal Procedure (Machine-translation by Google Translate, not legally binding) |
-
1990
- 1990-06-28 JP JP2170879A patent/JPH0457894A/en active Pending
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2007077210A (en) * | 2005-09-12 | 2007-03-29 | Naris Cosmetics Co Ltd | Compound wax and oil-based cosmetic containing the same |
| ES2834658A1 (en) * | 2019-12-18 | 2021-06-18 | Univ Almeria | Beeswax Contaminant Removal Procedure (Machine-translation by Google Translate, not legally binding) |
| WO2021123485A1 (en) * | 2019-12-18 | 2021-06-24 | Universidad De Almería | Method for removing contaminants from beeswax |
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