JPH0455444A - Filler for rubber compound - Google Patents
Filler for rubber compoundInfo
- Publication number
- JPH0455444A JPH0455444A JP2167480A JP16748090A JPH0455444A JP H0455444 A JPH0455444 A JP H0455444A JP 2167480 A JP2167480 A JP 2167480A JP 16748090 A JP16748090 A JP 16748090A JP H0455444 A JPH0455444 A JP H0455444A
- Authority
- JP
- Japan
- Prior art keywords
- filler
- combustion ash
- combustion
- coal
- waste
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000000945 filler Substances 0.000 title claims abstract description 33
- 229920001971 elastomer Polymers 0.000 title claims abstract description 18
- 150000001875 compounds Chemical class 0.000 title claims abstract description 16
- 238000002485 combustion reaction Methods 0.000 claims abstract description 32
- 239000002440 industrial waste Substances 0.000 claims abstract description 16
- 239000003245 coal Substances 0.000 claims abstract description 9
- 239000002245 particle Substances 0.000 claims abstract description 8
- 239000000446 fuel Substances 0.000 claims abstract description 7
- 239000002956 ash Substances 0.000 abstract description 25
- 238000000034 method Methods 0.000 abstract description 8
- 239000000203 mixture Substances 0.000 abstract description 7
- 230000003014 reinforcing effect Effects 0.000 abstract description 7
- 239000010893 paper waste Substances 0.000 abstract description 2
- 239000013502 plastic waste Substances 0.000 abstract description 2
- 239000011369 resultant mixture Substances 0.000 abstract 2
- 230000001788 irregular Effects 0.000 abstract 1
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 8
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 8
- 238000009472 formulation Methods 0.000 description 6
- 239000004927 clay Substances 0.000 description 5
- 239000002699 waste material Substances 0.000 description 5
- 229910000019 calcium carbonate Inorganic materials 0.000 description 4
- 230000000052 comparative effect Effects 0.000 description 4
- 238000005469 granulation Methods 0.000 description 4
- 230000003179 granulation Effects 0.000 description 4
- 239000004576 sand Substances 0.000 description 4
- 230000000704 physical effect Effects 0.000 description 3
- 235000008733 Citrus aurantifolia Nutrition 0.000 description 2
- 229920002943 EPDM rubber Polymers 0.000 description 2
- 235000011941 Tilia x europaea Nutrition 0.000 description 2
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 2
- 239000006229 carbon black Substances 0.000 description 2
- 239000003610 charcoal Substances 0.000 description 2
- 239000011256 inorganic filler Substances 0.000 description 2
- 229910003475 inorganic filler Inorganic materials 0.000 description 2
- 239000004571 lime Substances 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- 239000003921 oil Substances 0.000 description 2
- 239000003973 paint Substances 0.000 description 2
- 238000011084 recovery Methods 0.000 description 2
- 239000000377 silicon dioxide Substances 0.000 description 2
- 239000010802 sludge Substances 0.000 description 2
- 238000004073 vulcanization Methods 0.000 description 2
- 239000011787 zinc oxide Substances 0.000 description 2
- 235000014692 zinc oxide Nutrition 0.000 description 2
- 235000002918 Fraxinus excelsior Nutrition 0.000 description 1
- 241001441571 Hiodontidae Species 0.000 description 1
- 235000010627 Phaseolus vulgaris Nutrition 0.000 description 1
- 244000046052 Phaseolus vulgaris Species 0.000 description 1
- 235000021355 Stearic acid Nutrition 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 229910052570 clay Inorganic materials 0.000 description 1
- 239000010883 coal ash Substances 0.000 description 1
- 239000010849 combustible waste Substances 0.000 description 1
- 238000009841 combustion method Methods 0.000 description 1
- 238000013329 compounding Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 230000001747 exhibiting effect Effects 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 239000000395 magnesium oxide Substances 0.000 description 1
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 1
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 1
- 239000008188 pellet Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 229920001084 poly(chloroprene) Polymers 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 239000010734 process oil Substances 0.000 description 1
- 235000012239 silicon dioxide Nutrition 0.000 description 1
- 239000000779 smoke Substances 0.000 description 1
- 239000008117 stearic acid Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 238000009423 ventilation Methods 0.000 description 1
- 239000010920 waste tyre Substances 0.000 description 1
- 239000002916 wood waste Substances 0.000 description 1
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W30/00—Technologies for solid waste management
- Y02W30/50—Reuse, recycling or recovery technologies
- Y02W30/62—Plastics recycling; Rubber recycling
Landscapes
- Separation, Recovery Or Treatment Of Waste Materials Containing Plastics (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
Description
【発明の詳細な説明】
〈産業上の利用分野〉
本発明は、ゴム配合物用充填剤に関する。特に、可燃性
産業廃棄物からの燃焼灰の有効利用を図ることのできる
ゴム配合物用充填剤に関する。DETAILED DESCRIPTION OF THE INVENTION <Industrial Field of Application> The present invention relates to fillers for rubber compounds. In particular, the present invention relates to fillers for rubber compounds that can effectively utilize combustion ash from combustible industrial waste.
〈従来の技術〉
従来、可燃性産業廃棄物は、焼却炉で、燃焼させ、生じ
た残渣および燃焼灰は、いわゆる、通風によって煙道に
運ばれる微粉状灰も含めてほとんど埋立に使用していた
。<Conventional technology> Conventionally, combustible industrial waste was burned in an incinerator, and most of the resulting residue and combustion ash, including the so-called pulverized ash carried into the flue by ventilation, was used for landfill. Ta.
〈発明が解決しようとする課題〉
しかし、埋立地の確保は必ずしも容易でなく、また、遠
距離輸送費および環境関連法規制の観点から、燃焼灰の
処理は、ますます困難となり重要な問題となりつつある
。<Problems to be solved by the invention> However, it is not always easy to secure a landfill site, and in view of long-distance transportation costs and environmental laws and regulations, the disposal of combustion ash has become increasingly difficult and an important issue. It's coming.
一方、ゴム配合物の技術分野において、クレー、シリカ
、炭酸カルシウム等の補強性ないし増量性充填剤に代る
安価な充填剤の開発が望まれている。On the other hand, in the technical field of rubber compounds, there is a desire to develop inexpensive fillers to replace reinforcing or bulking fillers such as clay, silica, calcium carbonate, and the like.
本発明は、上記にかんがみて、可燃性産業廃棄物の燃焼
灰の有効利用を図ることができ、かつ、従来の補強性・
増量性充填剤に比して安価に提供できるゴム配合物用充
填剤を提供することを目的とする。In view of the above, the present invention makes it possible to effectively utilize the combustion ash of combustible industrial waste, and to improve the reinforcing properties and
An object of the present invention is to provide a filler for rubber compounds that can be provided at a lower cost than bulking fillers.
く課題を解決するための手段〉
本発明者らは、上記課題を解決するために、鋭意開発に
努力をした結果、所定の条件で得た可燃性産業廃棄物の
燃焼灰がゴム配合物用充填剤として、利用可能であると
の新たな知見を得て、本発明に想到した。Means for Solving the Problems In order to solve the above problems, the present inventors have made extensive efforts in development, and as a result, the combustion ash of combustible industrial waste obtained under predetermined conditions has been found to be suitable for use in rubber compounds. The present invention was conceived based on the new finding that it can be used as a filler.
即ち、本発明のゴム配合物用充填剤は、可燃性産業廃棄
物に補助燃料として石炭を添加して燃焼し、該燃焼によ
り得られた微粉状燃焼灰であって、粒径５０μｍ以下の
ものからなることを特徴とする。That is, the filler for rubber compounds of the present invention is pulverized combustion ash obtained by adding coal as an auxiliary fuel to combustible industrial waste and burning it, which has a particle size of 50 μm or less. It is characterized by consisting of.
く手段の詳細な説明〉
以下、本発明のゴム配合物用充填剤について、詳細に説
明をする。なお、以下の説明で配合単位を示す「部」
「比」は、特にことわらない限り、重量単位である。Detailed Description of Means for Carrying Out the Invention> Hereinafter, the filler for rubber compounds of the present invention will be explained in detail. In addition, in the following explanation, "part" indicates the compounding unit.
"Ratios" are in units of weight unless otherwise specified.
（１）可燃性産業廃棄物に補助燃料として、石炭を添加
して燃焼させ、該燃焼により得られる微粉状燃焼灰をベ
ースとする。(1) Coal is added to combustible industrial waste as an auxiliary fuel and burned, and the pulverized combustion ash obtained by the combustion is used as the base.
■ここで、可燃性産業廃棄物とは、紙くず、プラスチッ
クくず、木くず、繊維くず、ゴムくず、廃タイヤ、廃油
、塗料かす、汚泥等の主成分が有機物であり、可燃性の
ものをいう。■Here, combustible industrial waste refers to waste paper, plastic waste, wood waste, fiber waste, rubber waste, waste tires, waste oil, paint scum, sludge, etc., which are primarily organic and flammable.
■補助燃料として使用する石炭は、汎用のボイラー用の
ものでよく、可燃性廃棄物１００部に対して、約３０部
以上とする。３０部未満では、燃焼効率が悪く（熱量不
足）なり、ボイラーとしての機能を果たしにくくなる。■Coal used as auxiliary fuel may be for general-purpose boilers, and should be approximately 30 parts or more per 100 parts of combustible waste. If it is less than 30 parts, the combustion efficiency will be poor (insufficient amount of heat) and it will be difficult to function as a boiler.
■燃焼方法は、特に限定されないが、流動床方式が望ま
しい、流動床方式の場合、石灰を粉砕する必要がなく（
安価）、また、得られる燃焼灰が不定形となり充填剤と
して補強効果が増す。■The combustion method is not particularly limited, but a fluidized bed method is preferable. In the case of a fluidized bed method, there is no need to crush lime (
In addition, the resulting combustion ash becomes amorphous and acts as a filler, increasing its reinforcing effect.
ここで流動床方式とは、：砂等の流動床に燃焼物（廃棄
物、石灰）を投入し、エアーで全体を流動させながら燃
焼させる方法をいう。Here, the fluidized bed method refers to a method in which combustible materials (waste, lime) are placed in a fluidized bed of sand, etc., and burned while being fluidized with air.
■第１図に本発明における燃焼灰の回収装置の流れ図を
示す。(2) Fig. 1 shows a flowchart of the combustion ash recovery device according to the present invention.
流動床式焼却炉ｌの底部には、砂粒子が供給されてブロ
ア（図示せず）で形成される流動床（燃焼部）３の上に
、可燃性産業廃棄物および石炭が投入可能とされている
。At the bottom of the fluidized bed incinerator 1, combustible industrial waste and coal can be fed onto a fluidized bed (combustion section) 3 that is supplied with sand particles and formed by a blower (not shown). ing.
具体的には、産業廃棄物が、ベルトコンベア５、定量供
給機６を経て焼却炉１の上方から、石炭が、ベルトコン
ベア８、定量供給機９等を経て焼却炉１の側壁から、そ
れぞれ流動床３に投入されて燃焼が行なわれる。このと
き、燃焼流動床３の底部には、燃焼残渣取出しコンベア
１１が配設され、該コンベア１１から炉外へ排出された
不燃物は、振動篩１３によって、砂と残量に篩分される
。分離回収された砂は、パケットコンベア１５、定量供
給機１６を経て、焼却炉ｌの側壁から流動床３へ還流さ
れる。Specifically, industrial waste flows from above the incinerator 1 via a belt conveyor 5 and quantitative feeder 6, and coal flows from the side wall of the incinerator 1 via a belt conveyor 8, quantitative feeder 9, etc. It is put into the bed 3 and combustion takes place. At this time, a combustion residue removal conveyor 11 is disposed at the bottom of the combustion fluidized bed 3, and the incombustibles discharged from the conveyor 11 to the outside of the furnace are sieved by a vibrating sieve 13 into sand and the remaining amount. . The separated and collected sand is returned to the fluidized bed 3 from the side wall of the incinerator 1 via a packet conveyor 15 and a quantitative feeder 16.
また、焼却炉１の上方から煙道１８へ導入される燃焼灰
は、サイクロン２１、酸化炉２２によって一次捕獲（灰
ＡＩ）され、空気予熱器２４、白煙防止熱交換器２５に
よって二次捕獲（灰Ａ２）さらに、バッグフィルタ２７
によって最終捕獲（灰Ａ３）される０本発明の充填剤と
して使用するのは、通常、この最終捕獲されたもの燃焼
灰Ａ３を使用するのが、粒径が小さく、かつ、異物も少
ないため望ましい、しかし、−次捕獲、二次捕獲された
燃焼灰Ａ１、Ａ２も、振動ミル等で微粉砕さらには、分
級等の工程を経れば使用可能である。In addition, combustion ash introduced into the flue 18 from above the incinerator 1 is primarily captured (ash AI) by the cyclone 21 and the oxidation furnace 22, and is secondarily captured by the air preheater 24 and white smoke prevention heat exchanger 25. (Ash A2) Furthermore, bag filter 27
It is usually preferable to use this final captured combustion ash A3 as the filler of the present invention because the particle size is small and there are few foreign substances. However, the combustion ashes A1 and A2 that have been captured secondarily can also be used if they are pulverized using a vibrating mill or the like, and further subjected to a process such as classification.
なお、第１図中、１９はボイラの気水器、２０は熱交換
器である。In addition, in FIG. 1, 19 is a steamer of a boiler, and 20 is a heat exchanger.
（２）上記のようにして得た燃焼灰は、通常、必要によ
り、破砕機、振動ミル等により破砕し、その後、分級機
により５０ＬＬｍ以下に分級する。(2) The combustion ash obtained as described above is usually crushed using a crusher, a vibration mill, etc., if necessary, and then classified into 50 LLm or less using a classifier.
ここで５０Ｌｔｍを超えると、ゴム配合物における分散
性が悪くなって望ましくない。If it exceeds 50 Ltm, the dispersibility in the rubber compound will deteriorate, which is undesirable.
そして、必然的ではないが、取扱い性の見地から造粒機
により、造粒してゴム配合物用充填剤とする。造粒方法
としては、湿式連続押出造粒、湿式ペレット造粒、乾式
加圧造粒の方法を挙げることができる。Then, although not necessarily, from the viewpoint of ease of handling, it is granulated using a granulator to form a filler for rubber compounds. Examples of the granulation method include wet continuous extrusion granulation, wet pellet granulation, and dry pressure granulation.
（３）こうして、製造したゴム配合物用充填剤は、後述
の実施例で示す如く、ゴム配合物においてクレーや炭酸
カルシウム等の無機充填剤に代えて使用した場合、ゴム
常態物性において、実用に耐える物性を示す、そして、
可燃性産業廃棄物を主とする燃焼灰であるため、コスト
的にも１／３〜１１５と有利である。(3) As shown in the examples below, the filler for rubber compounds produced in this way has practical properties in terms of normal physical properties of rubber when used in place of inorganic fillers such as clay and calcium carbonate in rubber compounds. exhibiting physical properties that endure, and
Since the combustion ash is mainly composed of combustible industrial waste, it is advantageous in terms of cost at 1/3 to 115%.
〈発明の作用・効果〉
本発明のゴム配合物用充填剤は、可燃性産業廃棄物に補
助燃料として石炭を添加して燃焼し、該燃焼により得ら
れた微粉状燃焼灰であって、５０μｍ以下の粒径のもの
からなる構成により、上述の試験例で示した如く、従来
の補強性ないし増量性の無機充填剤の代りに使用可能で
ある。<Actions and Effects of the Invention> The filler for rubber compounds of the present invention is produced by adding coal as an auxiliary fuel to combustible industrial waste and burning it, and the pulverized combustion ash obtained by the combustion is 50 μm thick. As shown in the above-mentioned test example, the structure consisting of the following particle sizes allows it to be used in place of conventional reinforcing or bulking inorganic fillers.
従って、本発明は、可燃性産業廃棄物の燃焼灰の有効利
用を図ることができ、かつ、従来の補強性ないし増量性
充填剤に比して安価に提供できるという効果を奏する。Therefore, the present invention has the advantage that it is possible to effectively utilize the combustion ash of combustible industrial waste, and it can be provided at a lower cost than conventional reinforcing or bulking fillers.
なお、本発明の発明性に直接影響を与えるものではない
が、微粉状石炭灰からなるゴム配合物用充填剤の技術が
特開昭５９−１８９１４４号公報に開示されている。Although it does not directly affect the inventiveness of the present invention, a technique for producing a filler for rubber compounds made of finely powdered coal ash is disclosed in JP-A-59-189144.
〈実施例〉
（１）次に、第１図に示す焼却設備を用いて、産業廃棄
物／石炭＝２／１の比で混合燃焼させて得た燃焼灰（Ａ
３）を４０μｍ以下に分級して、造粒（平均粒径：５０
０μｍ）して充填剤を得た。<Example> (1) Next, using the incineration equipment shown in Figure 1, combustion ash (A
3) is classified to 40 μm or less and granulated (average particle size: 50
0 μm) to obtain a filler.
当該充填剤を下記ＣＲ配合処方において、市販クレーと
配合量を対応させて比較例・実施例のＣＲ配合物を調製
した。なお、産業廃棄物の主成分は、汚泥、廃油、プラ
スチックくず、塗料かすであった。また、燃焼灰の主成
分は二酸化ケイ素、酸化アルミニウムであった。Comparative Examples and Examples of CR formulations were prepared by using the filler in the following CR formulation and matching the amount of the filler with that of commercially available clay. The main components of industrial waste were sludge, waste oil, plastic scraps, and paint scum. The main components of the combustion ash were silicon dioxide and aluminum oxide.
１１皿豆五１
ＣＲ（ネオプレニ／Ｖｌｌｋ） １００部Ｆ
ＥＦカーボンブラック ５０部亜鉛華
５部酸化マグネシウム
４部可塑剤 ２０部加硫剤
１部クレー又は本発明充填剤
変量＊昭和電工・デュポン■製造販売
上記各実施例・比較例の配合物について、ムーニー特性
（ＪＩＳ Ｋ ６３００） 、加硫特性（ＪＳＲ型キュ
ラストメータ使用）、初期物性（ＪＩＳに６３０１ ：
成形条件１７０℃×１０分）を測定した結果を第１表に
示す。11 plates of beans 1 CR (Neoprene/Vllk) 100 copies F
EF carbon black 50 parts zinc white
5 parts magnesium oxide
4 parts plasticizer 20 parts vulcanizing agent
1 part clay or filler of the present invention Variable *Showa Denko/DuPont ■Manufactured and sold For the formulations of each of the above examples and comparative examples, Mooney properties (JIS K 6300), vulcanization properties (using JSR type Curelastometer), initial Physical properties (JIS 6301:
Table 1 shows the results of measurements under molding conditions (170°C x 10 minutes).
第１表の結果から、本発明の充填剤は、クレーの代りに
、実用上使用可能であることが分る。From the results in Table 1, it can be seen that the filler of the present invention can be practically used in place of clay.
（２）上記（１）で得たのと同じ充填剤を、下記ＥＰＤ
Ｍ配合処方において、市販重質炭酸カルシウム（炭カル
）と配合量を対応させて比較例・実施例のＥＰＤＭ配合
物を調製した。(2) The same filler obtained in (1) above was added to the following EPD.
In the M formulation, EPDM formulations of comparative examples and examples were prepared by matching the blending amounts with commercially available heavy calcium carbonate (charcoal).
旦」」とＫｌ」しく方
ＥＰＤＭ （三井ＥＰＴ３０９１１ｋ） １００部
ＦＥＦカーボンブラック １００部亜鉛華
５部ステアリン酸
１部
プロセスオイル ４０部硫 黄
−１，５部加硫促進剤
２部炭カル又は本発明充填剤 変量＊三井
石油化学■製造販売
上記各実施例・比較例の配合物について、上記（１）と
同様の各試験項目について測定した結果を第２表に示す
。EPDM (Mitsui EPT30911k) 100 parts FEF carbon black 100 parts zinc white
5 parts stearic acid
1 part process oil 40 parts sulfur
-1.5 parts vulcanization accelerator
2-Part Charcoal or Filler of the Present Invention Variable * Mitsui Petrochemical ■ Manufacture and Sales Table 2 shows the results of measurements for the same test items as in (1) above for the formulations of the above Examples and Comparative Examples.
第２表の結果から、本発明の充填剤は、炭酸カルシウム
の代りに、実用上使用可能であることが分る。From the results in Table 2, it can be seen that the filler of the present invention can be practically used in place of calcium carbonate.
第１図は本発明の充填剤のベースとなる燃焼灰の回収装
置の一例を示す流れ図である。
１・・・焼却炉、
３・・・流動床（燃焼部）、
Ａ１、Ａ２、Ａ３・・・燃焼灰。
特
許
出
願
人
豊田合成株式会社
トヨタ自動車株式会社FIG. 1 is a flowchart showing an example of a combustion ash recovery apparatus which is the base of the filler of the present invention. 1... Incinerator, 3... Fluidized bed (combustion section), A1, A2, A3... Combustion ash. Patent applicant Toyoda Gosei Co., Ltd. Toyota Motor Corporation
Claims (1)
し、該燃焼により得られた微粉状燃焼灰であつて、５０
μｍ以下の粒径のものからなることを特徴とするゴム配
合物用充填剤。Coal is added as an auxiliary fuel to combustible industrial waste and burned, and the pulverized combustion ash obtained by the combustion is 50%
A filler for rubber compounds, characterized in that it consists of particles with a particle size of μm or less.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP16748090A JP2611857B2 (en) | 1990-06-26 | 1990-06-26 | Fillers for rubber compounds |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP16748090A JP2611857B2 (en) | 1990-06-26 | 1990-06-26 | Fillers for rubber compounds |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH0455444A true JPH0455444A (en) | 1992-02-24 |
| JP2611857B2 JP2611857B2 (en) | 1997-05-21 |
Family
ID=15850467
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP16748090A Expired - Lifetime JP2611857B2 (en) | 1990-06-26 | 1990-06-26 | Fillers for rubber compounds |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP2611857B2 (en) |
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO1998042779A1 (en) * | 1997-03-27 | 1998-10-01 | The Dow Chemical Company | Compositions of thermoplastic polymer and smelt |
| WO2000011056A1 (en) | 1998-08-20 | 2000-03-02 | Kaneka Corporation | Resin composition, polymer, and process for producing polymer |
| WO2008084651A1 (en) | 2007-01-12 | 2008-07-17 | Kaneka Corporation | Curable composition |
| WO2009011329A1 (en) | 2007-07-19 | 2009-01-22 | Kaneka Corporation | Curable composition |
| EP2233532A1 (en) | 2002-11-01 | 2010-09-29 | Kaneka Corporation | Curable composition |
| US11105089B2 (en) | 2015-08-18 | 2021-08-31 | 3M Innovative Properties Company | Self-sealing articles including elastic porous layer |
| US11365328B2 (en) | 2017-02-23 | 2022-06-21 | 3M Innovative Properties Company | Air and water barrier article including inelastic porous layer |
| US11731394B2 (en) | 2014-12-22 | 2023-08-22 | 3M Innovative Properties Company | Air and water barrier articles |
-
1990
- 1990-06-26 JP JP16748090A patent/JP2611857B2/en not_active Expired - Lifetime
Cited By (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO1998042779A1 (en) * | 1997-03-27 | 1998-10-01 | The Dow Chemical Company | Compositions of thermoplastic polymer and smelt |
| US6281276B1 (en) | 1997-03-27 | 2001-08-28 | The Dow Chemical Company | Compositions of thermoplastic polymer and smelt |
| WO2000011056A1 (en) | 1998-08-20 | 2000-03-02 | Kaneka Corporation | Resin composition, polymer, and process for producing polymer |
| EP2233532A1 (en) | 2002-11-01 | 2010-09-29 | Kaneka Corporation | Curable composition |
| EP2233531A1 (en) | 2002-11-01 | 2010-09-29 | Kaneka Corporation | Curable composition |
| WO2008084651A1 (en) | 2007-01-12 | 2008-07-17 | Kaneka Corporation | Curable composition |
| WO2009011329A1 (en) | 2007-07-19 | 2009-01-22 | Kaneka Corporation | Curable composition |
| US11731394B2 (en) | 2014-12-22 | 2023-08-22 | 3M Innovative Properties Company | Air and water barrier articles |
| US11105089B2 (en) | 2015-08-18 | 2021-08-31 | 3M Innovative Properties Company | Self-sealing articles including elastic porous layer |
| US11512463B2 (en) | 2015-08-18 | 2022-11-29 | 3M Innovative Properties Company | Air and water barrier article with porous layer and liner |
| US11365328B2 (en) | 2017-02-23 | 2022-06-21 | 3M Innovative Properties Company | Air and water barrier article including inelastic porous layer |
Also Published As
| Publication number | Publication date |
|---|---|
| JP2611857B2 (en) | 1997-05-21 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| WO1995010489A1 (en) | Process for forming aggregate; and product | |
| KR20020052147A (en) | Method for treating combustible waste | |
| Onaka | Sewage can make Portland cement: a new technology for ultimate reuse of sewage sludge | |
| JPH0455444A (en) | Filler for rubber compound | |
| KR20020080541A (en) | Method for making a refuse derived fuel | |
| JPH03505778A (en) | Waste usage method and waste preparation equipment | |
| JP3165092B2 (en) | Synthetic resin composition and its products | |
| JP3457169B2 (en) | How to treat incinerated fly ash | |
| JP2001254915A (en) | Method for disposing chlorine-containing waste by combustion | |
| JPH0885797A (en) | Production of refuse-solidified fuel | |
| JP3602316B2 (en) | Thermoplastic bag | |
| JPH1133343A (en) | Blow agent for incinerator flue and flue gas treatment method | |
| EP0731897B1 (en) | Method for burning of municipal wastes and the use of the ash produced in the burning | |
| JP2004359771A (en) | Solid fuel utilizing waste and method for producing the fuel | |
| JP3463052B1 (en) | Waste fuel and waste combustion method | |
| JPH10503274A (en) | System for producing ash products and energy from waste | |
| JPH06106533A (en) | Method for manufacture of solid fuel from waste having plastic principally | |
| JPH11101423A (en) | Method of treating boiler combustion ash | |
| JPH07242889A (en) | Method for producing solid fuel | |
| CN106906021A (en) | A kind of utilization adsorbs the method that VOCs waste gas solid waste prepares generative fuel | |
| JP3377369B2 (en) | Thermoplastic garbage bag and garbage incineration method using thermoplastic resin bag | |
| JPH08176565A (en) | Production of solidified refuse fuel | |
| JP3390766B2 (en) | Incineration method and apparatus for waste containing tire waste | |
| JPH085034A (en) | Waste plastic burning apparatus | |
| JP2002038172A (en) | Waste plastic fuel |