JPH0453260B2 - - Google Patents
Info
- Publication number
- JPH0453260B2 JPH0453260B2 JP60034998A JP3499885A JPH0453260B2 JP H0453260 B2 JPH0453260 B2 JP H0453260B2 JP 60034998 A JP60034998 A JP 60034998A JP 3499885 A JP3499885 A JP 3499885A JP H0453260 B2 JPH0453260 B2 JP H0453260B2
- Authority
- JP
- Japan
- Prior art keywords
- berberine
- filter paper
- concentration
- test
- patent blue
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 229910052736 halogen Inorganic materials 0.000 claims description 33
- -1 halogen ions Chemical class 0.000 claims description 33
- OJVABJMSSDUECT-UHFFFAOYSA-L berberin sulfate Chemical compound [O-]S([O-])(=O)=O.C1=C2CC[N+]3=CC4=C(OC)C(OC)=CC=C4C=C3C2=CC2=C1OCO2.C1=C2CC[N+]3=CC4=C(OC)C(OC)=CC=C4C=C3C2=CC2=C1OCO2 OJVABJMSSDUECT-UHFFFAOYSA-L 0.000 claims description 29
- 239000004177 patent blue V Substances 0.000 claims description 27
- 235000012736 patent blue V Nutrition 0.000 claims description 27
- 238000012360 testing method Methods 0.000 claims description 26
- YBHILYKTIRIUTE-UHFFFAOYSA-N berberine Chemical compound C1=C2CC[N+]3=CC4=C(OC)C(OC)=CC=C4C=C3C2=CC2=C1OCO2 YBHILYKTIRIUTE-UHFFFAOYSA-N 0.000 claims description 13
- 229940093265 berberine Drugs 0.000 claims description 13
- QISXPYZVZJBNDM-UHFFFAOYSA-N berberine Natural products COc1ccc2C=C3N(Cc2c1OC)C=Cc4cc5OCOc5cc34 QISXPYZVZJBNDM-UHFFFAOYSA-N 0.000 claims description 13
- 150000003836 berberines Chemical class 0.000 claims description 13
- 238000000034 method Methods 0.000 claims description 12
- 239000002904 solvent Substances 0.000 claims description 10
- 239000011259 mixed solution Substances 0.000 claims description 9
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 8
- 239000003960 organic solvent Substances 0.000 claims description 6
- 238000004816 paper chromatography Methods 0.000 claims description 6
- 239000012085 test solution Substances 0.000 claims description 6
- 239000000049 pigment Substances 0.000 claims description 5
- 238000006243 chemical reaction Methods 0.000 claims description 3
- DHAHKSQXIXFZJB-UHFFFAOYSA-O patent blue V Chemical compound C1=CC(N(CC)CC)=CC=C1C(C=1C(=CC(=C(O)C=1)S(O)(=O)=O)S(O)(=O)=O)=C1C=CC(=[N+](CC)CC)C=C1 DHAHKSQXIXFZJB-UHFFFAOYSA-O 0.000 claims 4
- RTMBGDBBDQKNNZ-UHFFFAOYSA-L C.I. Acid Blue 3 Chemical compound [Ca+2].C1=CC(N(CC)CC)=CC=C1C(C=1C(=CC(=C(O)C=1)S([O-])(=O)=O)S([O-])(=O)=O)=C1C=CC(=[N+](CC)CC)C=C1.C1=CC(N(CC)CC)=CC=C1C(C=1C(=CC(=C(O)C=1)S([O-])(=O)=O)S([O-])(=O)=O)=C1C=CC(=[N+](CC)CC)C=C1 RTMBGDBBDQKNNZ-UHFFFAOYSA-L 0.000 description 23
- 239000007788 liquid Substances 0.000 description 15
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 9
- 150000003839 salts Chemical class 0.000 description 9
- 238000011088 calibration curve Methods 0.000 description 8
- 239000000203 mixture Substances 0.000 description 8
- 239000000243 solution Substances 0.000 description 7
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 6
- 238000010586 diagram Methods 0.000 description 5
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 4
- 230000001174 ascending effect Effects 0.000 description 3
- 238000000926 separation method Methods 0.000 description 3
- 238000010998 test method Methods 0.000 description 3
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 2
- 150000001298 alcohols Chemical class 0.000 description 2
- 229930013930 alkaloid Natural products 0.000 description 2
- 238000004587 chromatography analysis Methods 0.000 description 2
- ORMNPSYMZOGSSV-UHFFFAOYSA-N dinitrooxymercury Chemical compound [Hg+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O ORMNPSYMZOGSSV-UHFFFAOYSA-N 0.000 description 2
- 238000000691 measurement method Methods 0.000 description 2
- SQGYOTSLMSWVJD-UHFFFAOYSA-N silver(1+) nitrate Chemical compound [Ag+].[O-]N(=O)=O SQGYOTSLMSWVJD-UHFFFAOYSA-N 0.000 description 2
- 239000011780 sodium chloride Substances 0.000 description 2
- 239000012086 standard solution Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- CPELXLSAUQHCOX-UHFFFAOYSA-M Bromide Chemical compound [Br-] CPELXLSAUQHCOX-UHFFFAOYSA-M 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 description 1
- POIRVLZGTSWEMG-UHFFFAOYSA-N Magnoflorin Natural products N1CCC2=CC(OC)=C(O)C3=C2C1CC1=CC=C(OC)C(O)=C13 POIRVLZGTSWEMG-UHFFFAOYSA-N 0.000 description 1
- PTPHDVKWAYIFRX-UHFFFAOYSA-N Palmatine Natural products C1C2=C(OC)C(OC)=CC=C2C=C2N1CCC1=C2C=C(OC)C(OC)=C1 PTPHDVKWAYIFRX-UHFFFAOYSA-N 0.000 description 1
- 229910021607 Silver chloride Inorganic materials 0.000 description 1
- 238000001042 affinity chromatography Methods 0.000 description 1
- 150000003797 alkaloid derivatives Chemical class 0.000 description 1
- 150000001412 amines Chemical group 0.000 description 1
- 239000001055 blue pigment Substances 0.000 description 1
- 238000009535 clinical urine test Methods 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 238000005443 coulometric titration Methods 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 229940079593 drug Drugs 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 229910052731 fluorine Inorganic materials 0.000 description 1
- 239000011737 fluorine Substances 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- 150000002367 halogens Chemical class 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 229960002523 mercuric chloride Drugs 0.000 description 1
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 1
- 229910052753 mercury Inorganic materials 0.000 description 1
- LWJROJCJINYWOX-UHFFFAOYSA-L mercury dichloride Chemical compound Cl[Hg]Cl LWJROJCJINYWOX-UHFFFAOYSA-L 0.000 description 1
- 229910001510 metal chloride Inorganic materials 0.000 description 1
- 229910021645 metal ion Inorganic materials 0.000 description 1
- QUCQEUCGKKTEBI-UHFFFAOYSA-N palmatine Chemical compound COC1=CC=C2C=C(C3=C(C=C(C(=C3)OC)OC)CC3)[N+]3=CC2=C1OC QUCQEUCGKKTEBI-UHFFFAOYSA-N 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 239000008213 purified water Substances 0.000 description 1
- 229910052709 silver Inorganic materials 0.000 description 1
- 239000004332 silver Substances 0.000 description 1
- HKZLPVFGJNLROG-UHFFFAOYSA-M silver monochloride Chemical compound [Cl-].[Ag+] HKZLPVFGJNLROG-UHFFFAOYSA-M 0.000 description 1
- 229910001961 silver nitrate Inorganic materials 0.000 description 1
- 239000002689 soil Substances 0.000 description 1
- 235000014347 soups Nutrition 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
- 210000002700 urine Anatomy 0.000 description 1
Classifications
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N30/00—Investigating or analysing materials by separation into components using adsorption, absorption or similar phenomena or using ion-exchange, e.g. chromatography or field flow fractionation
- G01N30/90—Plate chromatography, e.g. thin layer or paper chromatography
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T436/00—Chemistry: analytical and immunological testing
- Y10T436/19—Halogen containing
Landscapes
- Physics & Mathematics (AREA)
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Analytical Chemistry (AREA)
- Biochemistry (AREA)
- General Health & Medical Sciences (AREA)
- General Physics & Mathematics (AREA)
- Immunology (AREA)
- Pathology (AREA)
- Investigating Or Analyzing Non-Biological Materials By The Use Of Chemical Means (AREA)
- Investigating Or Analysing Biological Materials (AREA)
Priority Applications (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP60034998A JPS61194357A (ja) | 1985-02-22 | 1985-02-22 | ペーパークロマトグラフィー用ハロゲンイオンの濃度測定試験紙及びその測定法 |
| US06/829,110 US4744952A (en) | 1985-02-22 | 1986-02-14 | Test paper for determining the concentration of halogen ions by filter paper chromatography, and manufacturing process for and use of the same |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP60034998A JPS61194357A (ja) | 1985-02-22 | 1985-02-22 | ペーパークロマトグラフィー用ハロゲンイオンの濃度測定試験紙及びその測定法 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS61194357A JPS61194357A (ja) | 1986-08-28 |
| JPH0453260B2 true JPH0453260B2 (https=) | 1992-08-26 |
Family
ID=12429797
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP60034998A Granted JPS61194357A (ja) | 1985-02-22 | 1985-02-22 | ペーパークロマトグラフィー用ハロゲンイオンの濃度測定試験紙及びその測定法 |
Country Status (2)
| Country | Link |
|---|---|
| US (1) | US4744952A (https=) |
| JP (1) | JPS61194357A (https=) |
Families Citing this family (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0389563A4 (en) * | 1988-01-21 | 1991-01-23 | Boehringer Mannheim Corporation | Method and apparatus for analyte determination |
| US5334513A (en) * | 1988-05-17 | 1994-08-02 | Syntex (U.S.A.) Inc. | Method for immunochromatographic analysis |
| DE4019002A1 (de) * | 1990-06-13 | 1992-01-02 | Siemens Ag | Elektrodenanordnung fuer einen defibrillator |
| US5077221A (en) * | 1990-07-25 | 1991-12-31 | The Dow Chemical Company | Indirect detection thin layer chromatography of cations |
| US6096270A (en) * | 1998-05-04 | 2000-08-01 | Hapak Enterprises | Apparatus and methods useful in determining disinfectant effective concentration of hypochlorite ions |
| US6537823B1 (en) * | 2000-04-24 | 2003-03-25 | Sciteck Diagnostics, Inc. | Method for detection of bromine in urine using liquid chemistry dry chemistry test pads and lateral flow |
| US20030027350A1 (en) * | 2001-07-20 | 2003-02-06 | Smith Jack V. | Method for detection of bromine in urine using liquid chemistry, dry chemistry test pads, and lateral flow |
| US7041253B1 (en) * | 2002-07-23 | 2006-05-09 | Sun Biomedical Laboratories, Inc. | Sample collection and test device |
| MXPA06003183A (es) * | 2003-09-23 | 2006-06-23 | Oakville Hong Kong Co Ltd | Dispositivos de prueba de flujo lateral y metodos de uso. |
| US20060281188A1 (en) * | 2005-06-13 | 2006-12-14 | Cornell Research Foundation, Inc. | Ratiometric test strip and method |
| CN100356173C (zh) * | 2006-06-08 | 2007-12-19 | 王伟 | 一种乳癖安消制剂中功劳木含量的检测方法及测定标准 |
| US9128168B2 (en) | 2007-12-14 | 2015-09-08 | Cornell University | Method of determing excretion of sodium and other analytes |
| CN104077949A (zh) * | 2014-07-03 | 2014-10-01 | 沈阳大学 | 一种叶绿体色素纸层析分离方法 |
| CN111595839A (zh) * | 2020-05-19 | 2020-08-28 | 中科康磁医疗科技（苏州）有限公司 | 唾液葡萄糖检测试纸及其制备方法和应用 |
Family Cites Families (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US1913283A (en) * | 1932-03-18 | 1933-06-06 | Du Pont | Impregnated paper product |
| US2676874A (en) * | 1949-09-27 | 1954-04-27 | Devine John Berchmans | Method of and means for the rapid approximate quantitative estimation of chloride concentration in aqueous liquids |
| US3447904A (en) * | 1964-09-25 | 1969-06-03 | Miles Lab | Test indicator for the detection of chlorides |
| US3420205A (en) * | 1966-03-23 | 1969-01-07 | Miles Lab | Indicating device |
| US3510263A (en) * | 1968-01-05 | 1970-05-05 | Hach Chemical Co | Test papers,methods for carrying out chemical analyses and methods for making the test papers |
| US4094647A (en) * | 1976-07-02 | 1978-06-13 | Thyroid Diagnostics, Inc. | Test device |
| JPS5461986A (en) * | 1977-10-27 | 1979-05-18 | Toyo Roshi Kaisha | Substance and test piece for detecting chlorine in milk* and method of making said substance and test piece |
| JPS5844348A (ja) * | 1981-09-10 | 1983-03-15 | Kanto Giken Kogyo Kk | ガソリン中における燈油などの不純物の混入割合測定方法 |
-
1985
- 1985-02-22 JP JP60034998A patent/JPS61194357A/ja active Granted
-
1986
- 1986-02-14 US US06/829,110 patent/US4744952A/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| US4744952A (en) | 1988-05-17 |
| JPS61194357A (ja) | 1986-08-28 |
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