JPH0446178B2 - - Google Patents
Info
- Publication number
- JPH0446178B2 JPH0446178B2 JP62124429A JP12442987A JPH0446178B2 JP H0446178 B2 JPH0446178 B2 JP H0446178B2 JP 62124429 A JP62124429 A JP 62124429A JP 12442987 A JP12442987 A JP 12442987A JP H0446178 B2 JPH0446178 B2 JP H0446178B2
- Authority
- JP
- Japan
- Prior art keywords
- ruthenium
- collection
- silica
- adsorption
- ruthenium tetroxide
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 21
- 229910001927 ruthenium tetroxide Inorganic materials 0.000 claims description 20
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 17
- 239000000377 silicon dioxide Substances 0.000 claims description 6
- 238000001035 drying Methods 0.000 claims description 2
- KJTLSVCANCCWHF-UHFFFAOYSA-N Ruthenium Chemical compound [Ru] KJTLSVCANCCWHF-UHFFFAOYSA-N 0.000 description 15
- 229910052707 ruthenium Inorganic materials 0.000 description 15
- 238000001179 sorption measurement Methods 0.000 description 14
- 239000000499 gel Substances 0.000 description 13
- 239000000126 substance Substances 0.000 description 11
- 230000002285 radioactive effect Effects 0.000 description 10
- 239000000741 silica gel Substances 0.000 description 9
- 229910002027 silica gel Inorganic materials 0.000 description 9
- 229960001866 silicon dioxide Drugs 0.000 description 9
- 150000001875 compounds Chemical class 0.000 description 8
- 239000000463 material Substances 0.000 description 8
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 6
- 239000003795 chemical substances by application Substances 0.000 description 6
- 238000002474 experimental method Methods 0.000 description 5
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 4
- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 description 4
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 4
- 230000002378 acidificating effect Effects 0.000 description 4
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 4
- 239000004927 clay Substances 0.000 description 4
- 229910052751 metal Inorganic materials 0.000 description 4
- 239000002184 metal Substances 0.000 description 4
- 229910052760 oxygen Inorganic materials 0.000 description 4
- 239000001301 oxygen Substances 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- 230000004992 fission Effects 0.000 description 3
- 239000011521 glass Substances 0.000 description 3
- 238000005259 measurement Methods 0.000 description 3
- 239000007800 oxidant agent Substances 0.000 description 3
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- 229910052770 Uranium Inorganic materials 0.000 description 2
- 239000003463 adsorbent Substances 0.000 description 2
- 229910052792 caesium Inorganic materials 0.000 description 2
- TVFDJXOCXUVLDH-UHFFFAOYSA-N caesium atom Chemical compound [Cs] TVFDJXOCXUVLDH-UHFFFAOYSA-N 0.000 description 2
- GNTDGMZSJNCJKK-UHFFFAOYSA-N divanadium pentaoxide Chemical compound O=[V](=O)O[V](=O)=O GNTDGMZSJNCJKK-UHFFFAOYSA-N 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- JKQOBWVOAYFWKG-UHFFFAOYSA-N molybdenum trioxide Chemical compound O=[Mo](=O)=O JKQOBWVOAYFWKG-UHFFFAOYSA-N 0.000 description 2
- 239000003758 nuclear fuel Substances 0.000 description 2
- 239000012285 osmium tetroxide Substances 0.000 description 2
- 229910000489 osmium tetroxide Inorganic materials 0.000 description 2
- 150000002927 oxygen compounds Chemical class 0.000 description 2
- 239000011148 porous material Substances 0.000 description 2
- 230000005855 radiation Effects 0.000 description 2
- 239000002516 radical scavenger Substances 0.000 description 2
- KJTLSVCANCCWHF-NJFSPNSNSA-N ruthenium-103 Chemical compound [103Ru] KJTLSVCANCCWHF-NJFSPNSNSA-N 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 229960004029 silicic acid Drugs 0.000 description 2
- DNYWZCXLKNTFFI-UHFFFAOYSA-N uranium Chemical compound [U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U][U] DNYWZCXLKNTFFI-UHFFFAOYSA-N 0.000 description 2
- 206010000369 Accident Diseases 0.000 description 1
- GUTLYIVDDKVIGB-OUBTZVSYSA-N Cobalt-60 Chemical compound [60Co] GUTLYIVDDKVIGB-OUBTZVSYSA-N 0.000 description 1
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 1
- 229910021536 Zeolite Inorganic materials 0.000 description 1
- 239000003929 acidic solution Substances 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 229910001854 alkali hydroxide Inorganic materials 0.000 description 1
- 150000008044 alkali metal hydroxides Chemical class 0.000 description 1
- 229910001583 allophane Inorganic materials 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 239000003637 basic solution Substances 0.000 description 1
- 229940117975 chromium trioxide Drugs 0.000 description 1
- WGLPBDUCMAPZCE-UHFFFAOYSA-N chromium trioxide Inorganic materials O=[Cr](=O)=O WGLPBDUCMAPZCE-UHFFFAOYSA-N 0.000 description 1
- GAMDZJFZMJECOS-UHFFFAOYSA-N chromium(6+);oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[Cr+6] GAMDZJFZMJECOS-UHFFFAOYSA-N 0.000 description 1
- 239000002734 clay mineral Substances 0.000 description 1
- 239000000084 colloidal system Substances 0.000 description 1
- 235000019646 color tone Nutrition 0.000 description 1
- 239000000356 contaminant Substances 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- LRCFXGAMWKDGLA-UHFFFAOYSA-N dioxosilane;hydrate Chemical compound O.O=[Si]=O LRCFXGAMWKDGLA-UHFFFAOYSA-N 0.000 description 1
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 1
- KZHJGOXRZJKJNY-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Si]=O.O=[Al]O[Al]=O.O=[Al]O[Al]=O.O=[Al]O[Al]=O KZHJGOXRZJKJNY-UHFFFAOYSA-N 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 238000007667 floating Methods 0.000 description 1
- 239000000446 fuel Substances 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 229910052732 germanium Inorganic materials 0.000 description 1
- GNPVGFCGXDBREM-UHFFFAOYSA-N germanium atom Chemical compound [Ge] GNPVGFCGXDBREM-UHFFFAOYSA-N 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 1
- 229910052622 kaolinite Inorganic materials 0.000 description 1
- 238000002386 leaching Methods 0.000 description 1
- 229910052744 lithium Inorganic materials 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 150000007522 mineralic acids Chemical class 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 229910052863 mullite Inorganic materials 0.000 description 1
- 230000003472 neutralizing effect Effects 0.000 description 1
- 210000000056 organ Anatomy 0.000 description 1
- -1 platinum group metals Chemical class 0.000 description 1
- 238000010248 power generation Methods 0.000 description 1
- 239000012857 radioactive material Substances 0.000 description 1
- 239000000941 radioactive substance Substances 0.000 description 1
- 238000010992 reflux Methods 0.000 description 1
- 238000012958 reprocessing Methods 0.000 description 1
- 239000011435 rock Substances 0.000 description 1
- 150000003304 ruthenium compounds Chemical class 0.000 description 1
- 239000004065 semiconductor Substances 0.000 description 1
- RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 description 1
- 235000012239 silicon dioxide Nutrition 0.000 description 1
- 239000002689 soil Substances 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 229910052713 technetium Inorganic materials 0.000 description 1
- GKLVYJBZJHMRIY-UHFFFAOYSA-N technetium atom Chemical compound [Tc] GKLVYJBZJHMRIY-UHFFFAOYSA-N 0.000 description 1
- 238000009423 ventilation Methods 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
- 239000010457 zeolite Substances 0.000 description 1
Landscapes
- Sampling And Sample Adjustment (AREA)
- Separation Of Gases By Adsorption (AREA)
- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP62124429A JPS63287549A (ja) | 1987-05-20 | 1987-05-20 | 四酸化ルテニウムの捕集剤 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP62124429A JPS63287549A (ja) | 1987-05-20 | 1987-05-20 | 四酸化ルテニウムの捕集剤 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS63287549A JPS63287549A (ja) | 1988-11-24 |
| JPH0446178B2 true JPH0446178B2 (forum.php) | 1992-07-29 |
Family
ID=14885268
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP62124429A Granted JPS63287549A (ja) | 1987-05-20 | 1987-05-20 | 四酸化ルテニウムの捕集剤 |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS63287549A (forum.php) |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1081478C (zh) * | 1997-07-21 | 2002-03-27 | 青岛海洋化工集团公司 | 硅铝胶凝胶粒产品 |
| CN101617065B (zh) | 2007-02-21 | 2011-11-23 | 乔治洛德方法研究和开发液化空气有限公司 | 在基底上形成钌基薄膜的方法 |
| US8859047B2 (en) | 2010-02-23 | 2014-10-14 | L'air Liquide, Societe Anonyme Pour L'etude Et L'exploitation Des Procedes Georges Claude | Use of ruthenium tetroxide as a precursor and reactant for thin film depositions |
| JP6071836B2 (ja) * | 2013-10-11 | 2017-02-01 | 京セラドキュメントソリューションズ株式会社 | 電子写真装置用トナー |
| JP6071837B2 (ja) * | 2013-10-11 | 2017-02-01 | 京セラドキュメントソリューションズ株式会社 | 電子写真装置用トナー |
-
1987
- 1987-05-20 JP JP62124429A patent/JPS63287549A/ja active Granted
Also Published As
| Publication number | Publication date |
|---|---|
| JPS63287549A (ja) | 1988-11-24 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| ES2414180T3 (es) | Material sólido nanocompuesto basado en hexa- y octa-cianometalatos, su procedimiento de preparación y procedimiento de fijación de contaminantes minerales mediante su uso | |
| Matyáš et al. | Functionalized silica aerogels: Advanced materials to capture and immobilize radioactive iodine | |
| JP6371936B2 (ja) | トリチウム吸着材、水中からのトリチウムの分離方法及びトリチウム吸着材の再生方法 | |
| Yang et al. | A new route to the stable capture and final immobilization of radioactive cesium | |
| Aneheim et al. | Affinity of charcoals for different forms of radioactive organic iodine | |
| JPH0446178B2 (forum.php) | ||
| Zhang et al. | Adsorption of hazardous gases in nuclear islands on monolayer MoS2 sheet | |
| Tranter et al. | An inorganic microsphere composite for the selective removal of 137Cesium from acidic nuclear waste solutions. 1: Equilibrium capacity and kinetic properties of the sorbent | |
| Tyupina et al. | Use of silver-containing sorbents in anionic species of radioactive iodine management in nuclear industry and the methods of obtaining them | |
| Riley et al. | Densification and immobilization of AgI-containing iodine waste forms using spark plasma sintering | |
| Kearney et al. | Encapsulation of iodine-loaded metallated silica materials by a geopolymer matrix | |
| Kulyukhin et al. | Synthesis of sorbents based on coarsely dispersed silica gel, containing nanoparticles of Ag compounds, for localization of volatile radioactive iodine compounds from the water vapor-air medium | |
| Wronkiewicz et al. | Effects of alpha and gamma radiation on glass reaction in an unsaturated environment | |
| JP2016099264A (ja) | 放射性物質を安全に処分する放射性物質吸着セラミックス | |
| Boyer et al. | Lead halide aerosols. Properties of environmental significance | |
| JP3987920B2 (ja) | 放射性ヨウ素ガスの固定化剤及びその固定化法 | |
| KR101636976B1 (ko) | 염이 함유된 요오드 흡착 물질 및 이를 이용한 방사성 요오드 제거 시스템 | |
| Zhu et al. | High-capacity adsorption and immobilization of Sr in organosilane-modified halloysite | |
| JP2902587B2 (ja) | 石炭灰を利用した放射性セシュームの捕集方法 | |
| JPS6087855A (ja) | 四酸化ルテニウムの捕集剤 | |
| Mishra et al. | Radiotracer technique in adsorption study XVI: an efficient removal of cadmium ions by sodium titanate from aqueous solutions | |
| Matsuoka et al. | Stability and chemical form of iodine sorbed on silver-exchanged zeolite X | |
| US9180428B1 (en) | Methods of capturing and immobilizing radioactive nuclei with metal fluorite-based inorganic materials | |
| Fukasawa et al. | Influences of impurities on iodine removal efficiency of silver alibina adsorbent | |
| Mishra et al. | Radiotracer technique in adsorption study—part VI. Adsorption of chromate ions on chromium (IV) oxide powder |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| EXPY | Cancellation because of completion of term |