JPH04370177A - Floor wax - Google Patents
Floor waxInfo
- Publication number
- JPH04370177A JPH04370177A JP3147663A JP14766391A JPH04370177A JP H04370177 A JPH04370177 A JP H04370177A JP 3147663 A JP3147663 A JP 3147663A JP 14766391 A JP14766391 A JP 14766391A JP H04370177 A JPH04370177 A JP H04370177A
- Authority
- JP
- Japan
- Prior art keywords
- wax
- component
- floor
- insect repellent
- molecular weight
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000002728 pyrethroid Substances 0.000 claims abstract description 7
- 239000000077 insect repellent Substances 0.000 claims description 40
- 241001674044 Blattodea Species 0.000 abstract description 35
- 230000000694 effects Effects 0.000 abstract description 18
- 230000002940 repellent Effects 0.000 abstract description 18
- 239000005871 repellent Substances 0.000 abstract description 18
- 239000004615 ingredient Substances 0.000 abstract description 15
- 230000001846 repelling effect Effects 0.000 abstract description 6
- 230000001105 regulatory effect Effects 0.000 abstract 1
- 239000001993 wax Substances 0.000 description 79
- 239000011347 resin Substances 0.000 description 16
- 229920005989 resin Polymers 0.000 description 16
- 238000012360 testing method Methods 0.000 description 14
- 230000000052 comparative effect Effects 0.000 description 7
- YREQHYQNNWYQCJ-UHFFFAOYSA-N etofenprox Chemical compound C1=CC(OCC)=CC=C1C(C)(C)COCC1=CC=CC(OC=2C=CC=CC=2)=C1 YREQHYQNNWYQCJ-UHFFFAOYSA-N 0.000 description 7
- 239000004925 Acrylic resin Substances 0.000 description 6
- 229920000178 Acrylic resin Polymers 0.000 description 6
- 239000005896 Etofenprox Substances 0.000 description 6
- 230000007423 decrease Effects 0.000 description 6
- 229950005085 etofenprox Drugs 0.000 description 6
- 238000011156 evaluation Methods 0.000 description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 5
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 4
- 230000000740 bleeding effect Effects 0.000 description 4
- 239000007787 solid Substances 0.000 description 4
- ZCVAOQKBXKSDMS-AQYZNVCMSA-N (+)-trans-allethrin Chemical compound CC1(C)[C@H](C=C(C)C)[C@H]1C(=O)OC1C(C)=C(CC=C)C(=O)C1 ZCVAOQKBXKSDMS-AQYZNVCMSA-N 0.000 description 3
- FJDPATXIBIBRIM-QFMSAKRMSA-N (1R)-trans-cyphenothrin Chemical compound CC1(C)[C@H](C=C(C)C)[C@H]1C(=O)OC(C#N)C1=CC=CC(OC=2C=CC=CC=2)=C1 FJDPATXIBIBRIM-QFMSAKRMSA-N 0.000 description 3
- FMTFEIJHMMQUJI-NJAFHUGGSA-N 102130-98-3 Natural products CC=CCC1=C(C)[C@H](CC1=O)OC(=O)[C@@H]1[C@@H](C=C(C)C)C1(C)C FMTFEIJHMMQUJI-NJAFHUGGSA-N 0.000 description 3
- 229940024113 allethrin Drugs 0.000 description 3
- 230000035622 drinking Effects 0.000 description 3
- 239000003995 emulsifying agent Substances 0.000 description 3
- 239000000839 emulsion Substances 0.000 description 3
- RLLPVAHGXHCWKJ-UHFFFAOYSA-N permethrin Chemical compound CC1(C)C(C=C(Cl)Cl)C1C(=O)OCC1=CC=CC(OC=2C=CC=CC=2)=C1 RLLPVAHGXHCWKJ-UHFFFAOYSA-N 0.000 description 3
- 241000238657 Blattella germanica Species 0.000 description 2
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 2
- 241000238631 Hexapoda Species 0.000 description 2
- 239000011248 coating agent Substances 0.000 description 2
- 238000000576 coating method Methods 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 229960000490 permethrin Drugs 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- XLOPRKKSAJMMEW-SFYZADRCSA-M (R,R)-chrysanthemate Chemical compound CC(C)=C[C@@H]1[C@@H](C([O-])=O)C1(C)C XLOPRKKSAJMMEW-SFYZADRCSA-M 0.000 description 1
- DTCCVIYSGXONHU-CJHDCQNGSA-N (z)-2-(2-phenylethenyl)but-2-enedioic acid Chemical compound OC(=O)\C=C(C(O)=O)\C=CC1=CC=CC=C1 DTCCVIYSGXONHU-CJHDCQNGSA-N 0.000 description 1
- -1 2-(p-ethoxyphenyl)-2-methylpropyl Chemical group 0.000 description 1
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 239000002518 antifoaming agent Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 229920006026 co-polymeric resin Polymers 0.000 description 1
- 229940079593 drug Drugs 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 238000009408 flooring Methods 0.000 description 1
- 229910052731 fluorine Inorganic materials 0.000 description 1
- 239000011737 fluorine Substances 0.000 description 1
- 238000009434 installation Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 235000013873 oxidized polyethylene wax Nutrition 0.000 description 1
- 239000004209 oxidized polyethylene wax Substances 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 239000003755 preservative agent Substances 0.000 description 1
- 230000002335 preservative effect Effects 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 229920002803 thermoplastic polyurethane Polymers 0.000 description 1
- 239000000080 wetting agent Substances 0.000 description 1
Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
Description
【０００１】0001
【産業上の利用分野】この発明は、ゴキブリ等の虫を寄
せ付けないようにする床ワックスに関する。BACKGROUND OF THE INVENTION 1. Field of the Invention This invention relates to a floor wax that keeps out insects such as cockroaches.
【０００２】0002
【従来の技術】従来より、家庭内に生息するゴキブリ等
の虫を排除する目的で種々の薬剤が開発され、使用され
ている。例えば、ゴキブリを誘い出して捕らえる、ある
いはゴキブリに薬剤を食べさせ脱水状態にして殺してし
まうもの等、種々の形式のゴキブリ排除手段が使用され
ている。2. Description of the Related Art Conventionally, various drugs have been developed and used for the purpose of eliminating insects such as cockroaches living in homes. For example, various types of cockroach removal methods are used, such as luring cockroaches and trapping them, or feeding the cockroaches with chemicals to dehydrate them and kill them.
【０００３】0003
【発明が解決しようとする課題】しかしながら、このよ
うな形式のゴキブリ排除手段は、ゴキブリを誘い出して
はじめて効果を奏するものであり、飲食店などの客が飲
食する場所での設置は不向きである。すなわち、ゴキブ
リは飲食をする者にとって極めて不快なものであり、こ
のようなゴキブリを、飲食に使用される一定のエリアに
は一切出現させない、ゴキブリ排除手段の提供が望まれ
ていた。[Problems to be Solved by the Invention] However, this type of cockroach eliminating means is effective only after attracting cockroaches, and is not suitable for installation in places where customers eat and drink, such as restaurants. That is, cockroaches are extremely unpleasant for people who eat and drink, and it has been desired to provide a means for eliminating cockroaches that does not allow such cockroaches to appear in a certain area used for eating and drinking.
【０００４】この発明は、上記の事情に鑑みてなされた
ものであって、一定のエリア（例えば、飲食に使用され
る場所）にゴキブリを寄せ付けない忌避効果により、該
エリア内へのゴキブリの進入を一切排除するとともに、
このようなゴキブリの忌避効果を、床材に塗布する床ワ
ックスに持たせ、これによってゴキブリを一定のエリア
から忌避させる忌避効果を、床ワックスを一定期間毎に
塗布させる作業により奏させることができる極めて作業
性の高い、忌避効果を有する床ワックスの提供を目的と
する。[0004] This invention was made in view of the above circumstances, and has a repellent effect that prevents cockroaches from entering a certain area (for example, a place used for eating and drinking). In addition to completely eliminating
Such a cockroach repellent effect can be imparted to the floor wax applied to the flooring material, and the repellent effect of repelling cockroaches from a certain area can be achieved by applying the floor wax at regular intervals. The purpose of the present invention is to provide a floor wax with extremely high workability and a repellent effect.
【０００５】[0005]
【課題を解決するための手段】上記目的を達成するため
に、本発明では、ワックス成分に、ピレスロイド系の防
虫忌避成分を添加したものであり、前記ワックス成分の
平均分子量を１０００〜５００００とし、かつ前記防虫
忌避成分を０．０２〜５重量％の割合で含有させたこと
を特徴としている。[Means for Solving the Problems] In order to achieve the above object, in the present invention, a pyrethroid insect repellent component is added to a wax component, and the wax component has an average molecular weight of 1,000 to 50,000, Moreover, it is characterized in that the insect repellent component is contained in a proportion of 0.02 to 5% by weight.
【０００６】[0006]
【作用】この発明によれば、床ワックスの主体となるワ
ックス成分に、ピレスロイド系の防虫忌避成分を添加し
、かつワックス成分の平均分子量を１０００〜５０００
０に、かつ、防虫忌避成分を０．０２〜５重量％の割合
とすることにより、ゴキブリを極めて高い忌避率で忌避
させることが確認され、かつその高い忌避率を長期に亙
って維持できることが確認された。なお、前記ワックス
成分の平均分子量に上限（５００００）と下限（１００
０）とを設けたのは以下の理由による。すなわち、ワッ
クス成分の分子量が上限を越えて大きくなると、ワック
ス成分である樹脂を構成する分子に、防虫忌避成分のブ
リードが阻害されるからであり、また、樹脂の分子量が
下限より小さくなると、防虫忌避成分をブリードさせる
効果が得られるものの、床面上に塗布した際の樹脂被膜
の厚さが薄いものとなり、床ワックスとしての性能（光
沢，耐水性等）が低下するからである。また、前記防虫
忌避成分の含有割合に上限（５重量％）と下限（０．０
２重量％）とを設けたのは以下の理由による。
すなわち、前記防虫忌避成分の含有割合が、下限よりも
小さいとゴキブリを忌避させる能力が劣るからであり、
また、上限を越えて大きくなると、防虫忌避成分がワッ
クス成分中に均一に分散されにくくなり、かつ床ワック
スの価格面での経済性が低下するからである。[Operation] According to the present invention, a pyrethroid insect repellent component is added to the wax component that is the main component of the floor wax, and the average molecular weight of the wax component is adjusted to 1000 to 5000.
It has been confirmed that cockroaches can be repelled at an extremely high repellency rate by setting the insect repellent component to 0.02 to 5% by weight, and that this high repellency rate can be maintained over a long period of time. was confirmed. Note that the average molecular weight of the wax component has an upper limit (50,000) and a lower limit (100,000
0) was provided for the following reasons. In other words, if the molecular weight of the wax component exceeds the upper limit, the insect repellent component will be inhibited from bleeding into the molecules that make up the wax component resin, and if the molecular weight of the resin is lower than the lower limit, the insect repellent component will This is because, although the effect of bleeding the repellent component is obtained, the thickness of the resin coating when applied to the floor surface becomes thin, and the performance (gloss, water resistance, etc.) as a floor wax decreases. In addition, the upper limit (5% by weight) and lower limit (0.0% by weight) of the content of the insect repellent component
2% by weight) was provided for the following reason. That is, if the content ratio of the insect repellent component is lower than the lower limit, the ability to repel cockroaches will be poor.
Moreover, if the size exceeds the upper limit, it becomes difficult to uniformly disperse the insect repellent component into the wax component, and the economical efficiency of the floor wax in terms of price decreases.
【０００７】[0007]
【実施例】以下、本発明の一実施例を図１〜図５に基づ
いて説明する。本発明に係る「防虫忌避効果を有する床
ワックス」は、ワックス成分としてアクリル樹脂系、ウ
レタン樹脂系のものが使用され、防虫忌避成分としてピ
レスロイド系のものが使用されたものであり、これらワ
ックス成分と防虫忌避成分とに、水等の添加材（場合に
よっては乳化剤を添加）を加え、これらを攪拌機により
混合攪拌することにより得られるものである。DESCRIPTION OF THE PREFERRED EMBODIMENTS An embodiment of the present invention will be described below with reference to FIGS. 1 to 5. The "floor wax having an insect repellent effect" according to the present invention uses an acrylic resin type or urethane resin type as a wax component, and a pyrethroid type as an insect repellent component, and these wax components It is obtained by adding additives such as water (in some cases, an emulsifier is added) to the insect repellent and insect repellent component, and mixing and stirring them using a stirrer.
【０００８】なお、前記アクリル樹脂系のワックス成分
としては、例えば「商品名：２ー４７１オリゴマータイ
プ（アクリル樹脂の分子量６０００〜８０００）」、「
商品名：２ー４７２オリゴマー／ポリマータイプ（アク
リル樹脂の分子量１０００００以下）」が使用され、ま
た、防虫忌避成分として、ピレスロイド系のエトフェン
プロックス（２−（ｐ−エトキシフェニル）−２−メチ
ルプロピル−３−フェノキシベンジルエーテル：商品名
「トレボン」）、サイフェノスリン（（ＲＳ）−α−シ
アノ−３−フェノキシベンジル（１Ｒ）−シス／トラン
ス−クリサンテマート）、ペルメトリン（３−フェノキ
シベンジル−ｄｉ−シス／トランス−３（２，２−ジク
ロロビニル）−２，２ジメチル−１−シクロプロパンカ
ルボキシレート：商品名「エクスミン」）、アレスリン
（３−アリル−２−メチルシクロペンタ−２−エン−４
−オン−１−イル クリサンテマート）といったもの
が使用される。[0008] As the acrylic resin wax component, for example, "Product name: 2-471 oligomer type (acrylic resin molecular weight 6000-8000)", "
Product name: 2-472 oligomer/polymer type (acrylic resin molecular weight 100,000 or less) is used, and as an insect repellent ingredient, pyrethroid etofenprox (2-(p-ethoxyphenyl)-2-methylpropyl) is used. -3-phenoxybenzyl ether: trade name "Trebon"), cyphenothrin ((RS)-α-cyano-3-phenoxybenzyl (1R)-cis/trans-chrysanthemate), permethrin (3-phenoxybenzyl- di-cis/trans-3(2,2-dichlorovinyl)-2,2dimethyl-1-cyclopropanecarboxylate: trade name "Exmin"), allethrin (3-allyl-2-methylcyclopent-2-ene) -4
-on-1-yl chrysanthemate).
【０００９】また、前記ワックス成分である樹脂は平均
分子量が１０００〜５００００、好ましくは３０００〜
２００００のものを用いることが好ましい。これは、樹
脂の平均分子量が例えば５００００を越えて大きくなる
と、樹脂を構成する分子に、防虫忌避成分のブリードが
阻害されるからであり、また、樹脂の平均分子量が例え
ば１０００より低下すると、防虫忌避成分をブリードさ
せることができるものの、床面上に塗布した際の樹脂被
膜の厚さが薄いものとなり、床ワックスとしての性能（
光沢，耐水性等）が低下するからである。また、防虫忌
避成分は、全体量に対して０．０２〜５重量％ の割合
で混合させることが好ましい。これは０．０２重量％
よりも少ないとゴキブリを忌避させる能力が劣ったもの
になるからであり、また、５重量％を越えると、防虫忌
避成分がワックス成分中に均一に分散されにくくなり、
かつ床ワックスの価格面での経済性も低下するからであ
る。なお、以下の説明において、ワックス成分の平均分
子量が１０００〜５００００であり、かつ防虫忌避成分
が０．０２〜５重量％の割合で含有されている床ワック
スを、本発明に係わる床ワックスと表現する。[0009] Furthermore, the resin which is the wax component has an average molecular weight of 1,000 to 50,000, preferably 3,000 to 50,000.
It is preferable to use 20,000. This is because if the average molecular weight of the resin becomes larger than, for example, 50,000, the insect repellent component will be inhibited from bleeding into the molecules that make up the resin, and if the average molecular weight of the resin is lower than, for example, 1,000, the insect repellent component will be inhibited. Although it is possible to bleed out the repellent components, the thickness of the resin film when applied to the floor surface is thin, and its performance as a floor wax (
This is because gloss, water resistance, etc.) decrease. Further, it is preferable that the insect repellent component be mixed in a proportion of 0.02 to 5% by weight based on the total amount. This is 0.02% by weight
If the amount is less than 5% by weight, the ability to repel cockroaches will be inferior, and if it exceeds 5% by weight, it will be difficult for the insect repellent component to be uniformly dispersed in the wax component.
Moreover, the economical efficiency in terms of the price of the floor wax also decreases. In the following explanation, a floor wax in which the wax component has an average molecular weight of 1,000 to 50,000 and contains an insect repellent component in a proportion of 0.02 to 5% by weight is referred to as the floor wax according to the present invention. do.
【００１０】以下、図１の表を参照して、本発明に係る
床ワックスと、これらと比較される比較例としての床ワ
ックスについて説明し、更に図２を参照して、本発明に
係わる床ワックスが比較例のものより優れていることを
、実験データを用いて証明する。図１において、サンプ
ル番号（１）〜（１０）で示す床ワックスの内、サンプ
ル番号（１），（２），（４）で示すものは本発明に係
わる床ワックスであり、サンプル番号（３），（５）〜
（１０）で示すものは、本発明と比較される比較例とし
ての床ワックスである。なお、図１の表に示される「ア
クリル樹脂エマルジョン」としては固型分濃度３０重量
％に調整したものが使用される。アクリル樹脂の具体例
については既に述べた。また、「ポリエチレンワックス
エマルジョン」としては酸化ポリエチレンワックスエマ
ルジョン、アライド−シーグラム社、ＡＣ−３９２、固
型分濃度４０重量％が使用される。「レベリング剤」と
してはＳＭＡレジン２６２５Ａ、スチレン・マレイン酸
共重合樹脂、固型分濃度１５重量％が使用される。
「湿潤剤」としてはチバガイギー社、Ｄ−ダインＳ−１
００、フッ素系界面活性剤、固型分濃度２５重量％が使
用される。「消泡剤」としてはｗａｃｋｅｒ−Ｓｉｌｉ
ｃｏｎｅｓ−Ｃｏｒｐ、ＳＷＳー２１１が使用される。
また、「防腐剤」としてはホルマリン３７％水溶液が使
用される。The floor wax according to the present invention and the floor wax as a comparative example to be compared with these will be explained below with reference to the table in FIG. 1, and further with reference to FIG. The superiority of the wax over that of the comparative example is demonstrated using experimental data. In FIG. 1, among the floor waxes indicated by sample numbers (1) to (10), those indicated by sample numbers (1), (2), and (4) are floor waxes according to the present invention; ), (5) ~
What is indicated by (10) is a floor wax as a comparative example to be compared with the present invention. The "acrylic resin emulsion" shown in the table of FIG. 1 is used with a solid content concentration of 30% by weight. Specific examples of acrylic resin have already been described. Further, as the "polyethylene wax emulsion", oxidized polyethylene wax emulsion, Allied-Seagram Company, AC-392, solid content concentration 40% by weight is used. As the "leveling agent", SMA resin 2625A, styrene-maleic acid copolymer resin, solid content concentration 15% by weight is used. As a "wetting agent", Ciba Geigy, D-Dyne S-1
00, a fluorine-based surfactant, and a solid content concentration of 25% by weight is used. Wacker-Sili as an “antifoaming agent”
cones-Corp, SWS-211 is used. Further, a 37% aqueous formalin solution is used as the "preservative".
【００１１】そして、図１の成分表と、図１のサンプル
番号に対応したゴキブリ忌避性能と床ワックス性能とを
まとめた図２を参照して判るように、ワックス成分であ
る樹脂の平均分子量が１０００〜５００００の範囲にあ
る、本発明に係わる（１），（２），（４）の床ワック
スは、忌避率の評価が「１（極めて良い）」と「２（良
い）」であり、また、床ワックス性能も「○（良い）」
ことが確認された。また、これらの床ワックスの中で、
床ワックス（４）の１ケ月後の忌避率の評価が「２（良
い）」となっているのは、ワックス成分の平均分子量が
２０００と比較的低い低分子体であるために、ワックス
成分の防虫忌避成分（ペルメトリン）がブリードされ過
ぎ、これによって１ケ月の長期に亙って極めて良いとさ
れる「１」の忌避効果を維持できなかったと考えられる
。そして、このような実験結果から、（１），（２），
（４）の床ワックスは、少なくとも１ケ月に亙って「１
（極めて良い）」と「２（良い）」という高い忌避率を
維持することができるから、１ケ月毎の床ワックスの塗
布作業により、前述した高い忌避率を継続的に維持でき
る効果が得られるものである。[0011] As can be seen from the ingredient list in Figure 1 and Figure 2 which summarizes the cockroach repellent performance and floor wax performance corresponding to the sample numbers in Figure 1, the average molecular weight of the resin that is the wax component is The floor waxes (1), (2), and (4) according to the present invention, which are in the range of 1,000 to 50,000, have repellency ratings of "1 (very good)" and "2 (good)", Also, the floor wax performance is ``○ (good)''.
This was confirmed. Also, among these floor waxes,
The reason why the repellency rate of floor wax (4) after one month is "2 (good)" is because the wax component is a low molecular weight substance with a relatively low average molecular weight of 2000. It is thought that the insect repellent component (permethrin) was bled out too much, and as a result, the repellent effect of "1", which is considered to be extremely good, could not be maintained for a long period of one month. From these experimental results, (1), (2),
(4) The floor wax should be used for at least one month.
It is possible to maintain a high repellency rate of 2 (very good) and 2 (good), so by applying floor wax every month, you can achieve the effect of continuously maintaining the high repellency rate mentioned above. It is something.
【００１２】また、比較例として挙げた（３）の床ワッ
クスは、ワックス成分の樹脂の平均分子量が５００と小
さく、ゴキブリ忌避効果は「１（極めて良い）」である
ものの、床ワックス性能が「×（悪い）」ことが確認さ
れた。これは、前述したよう、平均分子量が１０００よ
り低下すると、床面上に塗布した際の樹脂被膜の厚さが
薄いものとなり、床ワックスとしての性能（光沢，耐水
性等）が低下するからである。また、比較例として挙げ
た（６）（７）の床ワックスは、ワックス成分の樹脂の
平均分子量が１０００００と大きく、床ワックス性能が
「○（良い）」ものの、ゴキブリ忌避効果を示す忌避率
の評価が「３（悪い）」、「４（極めて悪い）」となっ
て劣っていることが確認された。これは、前述したよう
に、ワックス成分の平均分子量が大きいと、ワックス成
分である樹脂を構成する分子に、防虫忌避成分のブリー
ドが阻害されるからであると考えられる。[0012] In addition, in the floor wax (3) cited as a comparative example, the average molecular weight of the resin of the wax component is as low as 500, and although the cockroach repelling effect is ``1 (extremely good)'', the floor wax performance is ``1 (extremely good)''. × (bad)” was confirmed. This is because, as mentioned above, when the average molecular weight is lower than 1000, the thickness of the resin film when applied to the floor surface becomes thin, and the performance as a floor wax (gloss, water resistance, etc.) decreases. be. In addition, in the floor waxes (6) and (7) cited as comparative examples, the average molecular weight of the resin of the wax component is as large as 100,000, and although the floor wax performance is "○ (good)", the repellency rate showing the cockroach repellent effect is low. The evaluations were ``3 (poor)'' and ``4 (extremely poor),'' confirming that the product was inferior. This is thought to be because, as described above, when the average molecular weight of the wax component is large, the insect repellent component is inhibited from bleeding into the molecules constituting the resin, which is the wax component.
【００１３】また、比較例として挙げた（５）の床ワッ
クスは、ワックス成分である樹脂の平均分子量が１００
０〜５００００の範囲内にあるものであるが、可塑剤で
ある乳化剤が添加されたものであり、これによってゴキ
ブリ忌避効果を示す忌避率の評価が「３（悪い）」、「
４（極めて悪い）」となって劣っていることが確認され
た。すなわち、乳化剤の添加により、防虫忌避成分がミ
セル状に閉じこめられてブリードし難くなると考えられ
る。また、比較例として挙げた（８）〜（１０）の床ワ
ックスは、防虫忌避成分を含んでいないものであり、こ
れによって、当然にゴキブリ忌避効果を示す忌避率の評
価が「４（極めて悪い）」となっている。[0013] In addition, in the floor wax (5) mentioned as a comparative example, the average molecular weight of the resin which is the wax component is 100.
Although it is in the range of 0 to 50,000, it contains an emulsifier, which is a plasticizer, and the evaluation of the repellency rate, which shows the cockroach repelling effect, is "3 (poor)", "
4 (extremely poor)" and was confirmed to be inferior. That is, it is thought that the addition of an emulsifier causes the insect repellent component to be confined in a micellar form, making it difficult for it to bleed. In addition, the floor waxes (8) to (10) listed as comparative examples do not contain any insect repellent ingredients, and as a result, the evaluation of the repellency rate, which naturally indicates the cockroach repellent effect, is ``4 (extremely poor)''. )”.
【００１４】ここで、図２に示したゴキブリ忌避効果を
示す忌避率の測定法について、図３を参照して具体的に
説明する。図３に符号１で示すものは、縦４０ｃｍ、横
６０ｃｍ、高さ２０ｃｍの試験槽であり、試験槽１内の
４カ所に、測定対象となる処理体（図１の（１）〜（１
０）で示す成分のワックスが塗布された床タイル）２と
、無処理体（防虫忌避成分を含まないワックスであり、
かつ前記処理体２と同一のワックスが塗布された床タイ
ル）３とを置き、また、これら処理体２と無処理体３と
の上面には、ゴキブリが隠れるためのシェルター４，５
をそれぞれ置いた。また、前記試験槽１の中央部にはゴ
キブリを中央におびき寄せるための餌及び水６を置いた
。なお、前記処理体２は、ホモジニアス系床タイル上に
、各ワックス成分を二度塗りし、乾燥後試験に使用した
。そして、このようにワックス処理した処理体２と無処
理体３とを配置した試験槽１に、チャバネゴキブリ成虫
の雄雌をそれぞれ１０頭ずつと、幼虫を１０頭、合計で
３０頭のゴキブリを入れ、処理体２上の内のゴキブリの
存在数により、該処理体２の忌避性を試験開始直後と１
ケ月後について調べた。[0014] Here, the method for measuring the repellency rate showing the cockroach repelling effect shown in FIG. 2 will be specifically explained with reference to FIG. 3. 3 is a test tank with a length of 40 cm, a width of 60 cm, and a height of 20 cm, and four locations inside the test tank 1 are marked with treated bodies ((1) to (1) in FIG. 1) to be measured.
Floor tiles coated with wax having the ingredients shown in 0) 2) and untreated body (wax that does not contain insect repellent ingredients)
A floor tile (3) coated with the same wax as the treated body 2 is placed, and shelters 4, 5 for cockroaches to hide are placed on the upper surfaces of the treated body 2 and untreated body 3.
were placed respectively. In addition, bait and water 6 were placed in the center of the test tank 1 to attract cockroaches to the center. In addition, for the treated body 2, each wax component was applied twice on a homogeneous floor tile, and after drying, it was used for the test. Then, in the test tank 1 in which the wax-treated body 2 and the untreated body 3 were arranged, a total of 30 cockroaches, 10 male and female adult German cockroaches and 10 larvae, were placed. , depending on the number of cockroaches present on the treated body 2, the repellency of the treated body 2 is determined between immediately after the start of the test and 1
I looked into it after a few months.
【００１５】以上のような試験法により、チャバネゴキ
ブリに対する処理体２の忌避率を以下のように算出した
。
すなわち、忌避率［％］＝１００×（Ａ−Ｂ）／Ａ但し
、Ａは全ゴキブリの頭数、Ｂは処理体２上にいるゴキブ
リの頭数である。忌避率に対する評価は次の通りである
。すなわち、忌避率が１００〜８０％の場合は「１（極
めて良い）」、忌避率が８０〜６０％の場合は「２（良
い）」、忌避率が６０〜４０％の場合は「３（悪い）」
、忌避率が４０％以下の場合は「４（極めて悪い）」で
ある。Using the test method described above, the repellency of treated body 2 against German cockroaches was calculated as follows. That is, repellency rate [%] = 100 x (A-B)/A However, A is the total number of cockroaches, and B is the number of cockroaches on the treatment body 2. The evaluation of the repellency rate is as follows. In other words, if the repellency rate is 100-80%, it will be ``1 (very good)'', if the repellency rate is 80-60%, it will be ``2 (good)'', and if the repellency rate is 60-40%, it will be ``3 ( bad)"
If the repellency rate is 40% or less, it is rated "4 (extremely bad)".
【００１６】次に、本発明に係る「防虫忌避効果を有す
る床ワックス」のワックス成分である樹脂の平均分子量
を１０００〜５００００、好ましくは３０００〜２００
００と設定する理由について図４のグラフを参照して説
明し、更に同ワックスにおいて、防虫忌避成分を０．０
２〜５重量％とした理由について、図５のグラフを参照
して説明する。Next, the average molecular weight of the resin which is the wax component of the "floor wax having an insect repellent effect" according to the present invention is 1000 to 50000, preferably 3000 to 200.
The reason for setting the insect repellent component to 0.00 will be explained with reference to the graph in Figure 4.
The reason for setting the content to 2 to 5% by weight will be explained with reference to the graph of FIG.
【００１７】《図４のグラフについて》アクリル系のワ
ックス成分、忌避成分、その他の成分の重量％を一定と
して、ワックス成分の分子量を変化させていった場合の
忌避率について試験した。すなわち、分子量の異なる種
々のアクリル系のワックスについて、分子量と忌避率と
の関係について調べた。その結果、グラフを参照して解
るように、分子量が１０００〜５００００の範囲では忌
避率が８０％以上と高く、また、その中で、分子量が３
０００〜２００００の範囲では忌避率が９０％以上と特
に高いことが確認された。なお、この試験では防虫忌避
成分にエトフェンプロックスを使用し、試験開始から、
１ケ月経過したときの忌避率をプロットした。また、こ
の試験では、防虫忌避成分にエトフェンプロックスを使
用したが、これ以外のサイフェノスリン、アレスリンと
いった防虫忌避成分を使用しても図４のグラフと同様の
結果が得られることが確認されている。<Regarding the graph in FIG. 4> The repellency rate was tested by varying the molecular weight of the wax component while keeping the weight percentages of the acrylic wax component, repellent component, and other components constant. That is, the relationship between molecular weight and repellency was investigated for various acrylic waxes with different molecular weights. As a result, as can be seen from the graph, the repellency rate is as high as 80% or more in the molecular weight range of 1,000 to 50,000.
It was confirmed that in the range of 000 to 20,000, the repellency rate was particularly high at 90% or more. In this test, etofenprox was used as the insect repellent ingredient, and from the start of the test,
The repellency rate after one month was plotted. In addition, although etofenprox was used as the insect repellent ingredient in this test, it was confirmed that results similar to the graph in Figure 4 could be obtained even if other insect repellent ingredients such as cyphenothrin and allethrin were used. ing.
【００１８】《図５のグラフについて》防虫忌避成分に
エトフェンプロックスを使用し、このエトフェンプロッ
クスの重量％を変化させていった場合の忌避率について
試験した。すなわち、含有されている防虫忌避成分の重
量％が異なる種々のワックスについて、防虫忌避成分の
重量％と忌避率との関係について調べた。その結果、グ
ラフを参照して解るように、防虫忌避成分が０．０２重
量％以上の床ワックスについては、８０％以上の高い忌
避率となることが確認された。なお、この試験では試験
開始から、１ケ月経過したときの忌避率をプロットした
。また、この試験では防虫忌避成分にエトフェンプロッ
クスを使用したが、これ以外のサイフェノスリン、アレ
スリンといった防虫忌避成分を使用しても図５のグラフ
と同様の結果が得られることが確認されている。また、
ワックス成分に分子量２００００のアクリル系ワックス
を用いたが、これ以外の分子量のアクリル系ワックス（
分子量１０００〜５００００）についても、図５のグラ
フと同様の結果が得られることが確認されている。
また、前記忌避率は、防虫忌避成分が５重量％となるま
では緩やかな上昇傾向をたどるが、これ以後については
、一定もしくは下降傾向となることが確認されている。<Regarding the graph in FIG. 5> Etofenprox was used as the insect repellent component, and the repellency rate was tested by varying the weight percent of this etofenprox. That is, the relationship between the weight percent of the insect repellent component and the repellency rate was investigated for various waxes containing different weight percent of the insect repellent component. As a result, as can be seen from the graph, it was confirmed that floor wax containing an insect repellent component of 0.02% by weight or more had a high repellency rate of 80% or more. In this test, the repellency rate was plotted one month after the start of the test. Additionally, although etofenprox was used as the insect repellent ingredient in this test, it was confirmed that results similar to the graph in Figure 5 could be obtained using other insect repellent ingredients such as cyphenothrin and allethrin. There is. Also,
Acrylic wax with a molecular weight of 20,000 was used as the wax component, but acrylic wax with a molecular weight other than this (
It has been confirmed that results similar to the graph in FIG. 5 can be obtained also for molecular weights of 1,000 to 50,000. Furthermore, it has been confirmed that the repellency rate follows a gradual upward trend until the insect repellent component reaches 5% by weight, but after this point, it remains constant or tends to decline.
【００１９】[0019]
【発明の効果】以上の説明から明らかなように、この発
明によれば、床ワックスの主体となるワックス成分に、
ピレスロイド系の防虫忌避成分を添加し、かつワックス
成分の平均分子量を１０００〜５００００に、かつ、防
虫忌避成分を０．０２〜５重量％の割合とすることによ
り、ゴキブリを極めて高い忌避率で忌避させることが確
認され、かつその高い忌避率を長期に亙って維持できる
ことが確認された。そして、このような忌避効果を有す
る床ワックスを、一定のエリア（例えば、飲食に使用さ
れる場所）に塗布することにより、該エリア内へのゴキ
ブリの進入を一切排除することができ、また、このよう
なゴキブリを一定のエリアから忌避させる効果を、通常
行われているワックスの塗布作業により奏させることが
でき、これによって極めて高い作業性を得ることができ
る。また、前記忌避効果を有する床ワックスは、少なく
とも１ケ月の長期に亙って高い忌避率を維持することが
できるから、１ケ月毎の床ワックスの塗布作業により、
前記高い忌避率を継続して維持できる効果が得られる。[Effects of the Invention] As is clear from the above explanation, according to the present invention, the main wax component of the floor wax contains
By adding a pyrethroid-based insect repellent component, and setting the average molecular weight of the wax component to 1000 to 50,000, and setting the proportion of the insect repellent component to 0.02 to 5% by weight, cockroaches are repelled with an extremely high repellency rate. It was confirmed that the high repellency rate could be maintained over a long period of time. By applying floor wax having such a repellent effect to a certain area (for example, a place used for eating and drinking), it is possible to completely prevent cockroaches from entering the area, and The effect of repelling cockroaches from a certain area can be achieved by the wax coating operation that is commonly performed, and thereby extremely high workability can be obtained. In addition, the floor wax having the repellent effect can maintain a high repellency rate for a long period of at least one month, so by applying the floor wax every month,
The effect of continuously maintaining the high repellency rate can be obtained.
【図１】床ワックスの成分を示す表である。FIG. 1 is a table showing the components of floor wax.
【図２】図１に示す床ワックスの性能評価を示す表。FIG. 2 is a table showing performance evaluation of the floor wax shown in FIG. 1.
【図３】ゴキブリの忌避効果を試験するための試験装置
を示す平面図。FIG. 3 is a plan view showing a test device for testing the cockroach repellent effect.
【図４】ワックス成分の平均分子量とゴキブリの忌避率
との関係を示すグラフ。FIG. 4 is a graph showing the relationship between the average molecular weight of a wax component and the cockroach repellency rate.
【図５】忌避成分の重量％とゴキブリの忌避率との関係
を示すグラフ。FIG. 5 is a graph showing the relationship between the weight percent of the repellent component and the cockroach repellency rate.
Claims (1)
忌避成分を添加してなり、前記ワックス成分の平均分子
量は１０００〜５００００であり、かつ前記防虫忌避成
分は０．０２〜５重量％の割合で含有されていることを
特徴とする床ワックス。1. A pyrethroid insect repellent component is added to a wax component, the wax component has an average molecular weight of 1,000 to 50,000, and the insect repellent component is contained in a proportion of 0.02 to 5% by weight. A floor wax characterized by:
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP3147663A JPH0776326B2 (en) | 1991-06-19 | 1991-06-19 | Floor wax |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP3147663A JPH0776326B2 (en) | 1991-06-19 | 1991-06-19 | Floor wax |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH04370177A true JPH04370177A (en) | 1992-12-22 |
| JPH0776326B2 JPH0776326B2 (en) | 1995-08-16 |
Family
ID=15435457
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP3147663A Expired - Lifetime JPH0776326B2 (en) | 1991-06-19 | 1991-06-19 | Floor wax |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH0776326B2 (en) |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH10175802A (en) * | 1996-12-19 | 1998-06-30 | Matsushita Electric Ind Co Ltd | Wax for insect pest repellence and its production |
| EP1270693A4 (en) * | 2000-09-11 | 2003-03-19 | Matsushita Electric Ind Co Ltd | Insect pest repelling film, insect pest repelling coating and method for their preparation |
| JP2005112811A (en) * | 2003-10-09 | 2005-04-28 | Michinori Arakawa | Beeswax wax having ingestion inhibiting action and method for producing the same |
| JP2005162740A (en) * | 2003-11-12 | 2005-06-23 | Sumitomo Chemical Co Ltd | Aqueous suspension agrochemical composition |
| JP2005162739A (en) * | 2003-11-12 | 2005-06-23 | Sumitomo Chemical Co Ltd | Agrochemical-containing fine particle and method for producing the same |
| WO2006092570A1 (en) * | 2005-03-02 | 2006-09-08 | Reckitt Benckiser (Australia) Pty Limited | Insect expellant floor cleaner additive comprising a synthetic pyrethroid |
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| JPS62149383A (en) * | 1985-12-23 | 1987-07-03 | Matsushita Electric Works Ltd | Surface treating agent for timber |
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| JPH0233683A (en) * | 1988-07-25 | 1990-02-02 | Casio Comput Co Ltd | Method and device for reproducing binary data and recording medium |
| JPH0255402A (en) * | 1988-08-20 | 1990-02-23 | Toko Inc | Dielectric filter |
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| JPS54105193A (en) * | 1978-02-06 | 1979-08-17 | Morizou Nakamura | Polymer for aqueous coating |
| JPS59227802A (en) * | 1983-06-08 | 1984-12-21 | Kanebo Ltd | Insecticidal resin composition |
| JPS62149383A (en) * | 1985-12-23 | 1987-07-03 | Matsushita Electric Works Ltd | Surface treating agent for timber |
| JPS62294471A (en) * | 1987-06-13 | 1987-12-21 | Hajime Murahama | Method for keeping cleanliness of floor surface |
| JPH0233683A (en) * | 1988-07-25 | 1990-02-02 | Casio Comput Co Ltd | Method and device for reproducing binary data and recording medium |
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Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH10175802A (en) * | 1996-12-19 | 1998-06-30 | Matsushita Electric Ind Co Ltd | Wax for insect pest repellence and its production |
| EP1270693A4 (en) * | 2000-09-11 | 2003-03-19 | Matsushita Electric Ind Co Ltd | Insect pest repelling film, insect pest repelling coating and method for their preparation |
| US7041306B2 (en) | 2000-09-11 | 2006-05-09 | Matsushita Electric Industrial Co., Ltd. | Insect pest-repellent film, insect pest-repellent paint and method for producing the same |
| JP2005112811A (en) * | 2003-10-09 | 2005-04-28 | Michinori Arakawa | Beeswax wax having ingestion inhibiting action and method for producing the same |
| JP2005162740A (en) * | 2003-11-12 | 2005-06-23 | Sumitomo Chemical Co Ltd | Aqueous suspension agrochemical composition |
| JP2005162739A (en) * | 2003-11-12 | 2005-06-23 | Sumitomo Chemical Co Ltd | Agrochemical-containing fine particle and method for producing the same |
| JP4649957B2 (en) * | 2003-11-12 | 2011-03-16 | 住友化学株式会社 | Aqueous suspension pesticide composition |
| JP4655592B2 (en) * | 2003-11-12 | 2011-03-23 | 住友化学株式会社 | Pesticide-containing fine particles and method for producing the same |
| WO2006092570A1 (en) * | 2005-03-02 | 2006-09-08 | Reckitt Benckiser (Australia) Pty Limited | Insect expellant floor cleaner additive comprising a synthetic pyrethroid |
| AU2006219778B2 (en) * | 2005-03-02 | 2012-05-24 | Reckitt Benckiser (Australia) Pty Limited | Insect expellant floor cleaner additive comprising a synthetic pyrethroid |
Also Published As
| Publication number | Publication date |
|---|---|
| JPH0776326B2 (en) | 1995-08-16 |
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