JPH04367457A - Cover tape film and mounting part package using the same - Google Patents
Cover tape film and mounting part package using the sameInfo
- Publication number
- JPH04367457A JPH04367457A JP15538391A JP15538391A JPH04367457A JP H04367457 A JPH04367457 A JP H04367457A JP 15538391 A JP15538391 A JP 15538391A JP 15538391 A JP15538391 A JP 15538391A JP H04367457 A JPH04367457 A JP H04367457A
- Authority
- JP
- Japan
- Prior art keywords
- film
- oxide compound
- resin
- cover tape
- transparent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 229920005989 resin Polymers 0.000 claims abstract description 60
- 239000011347 resin Substances 0.000 claims abstract description 60
- 239000010410 layer Substances 0.000 claims abstract description 33
- -1 tin oxide compound Chemical class 0.000 claims abstract description 25
- 239000000843 powder Substances 0.000 claims abstract description 21
- 239000002245 particle Substances 0.000 claims abstract description 19
- 239000011230 binding agent Substances 0.000 claims abstract description 18
- 239000004831 Hot glue Substances 0.000 claims abstract description 17
- 239000002985 plastic film Substances 0.000 claims abstract description 12
- 229910001887 tin oxide Inorganic materials 0.000 claims abstract description 12
- 229910003437 indium oxide Inorganic materials 0.000 claims abstract description 9
- 229920003023 plastic Polymers 0.000 claims abstract description 8
- 239000002131 composite material Substances 0.000 claims abstract description 5
- 239000010408 film Substances 0.000 abstract description 56
- 238000004140 cleaning Methods 0.000 abstract description 3
- 239000013039 cover film Substances 0.000 abstract 1
- 238000000576 coating method Methods 0.000 description 23
- 239000011248 coating agent Substances 0.000 description 17
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 15
- 239000004020 conductor Substances 0.000 description 13
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 12
- 238000000034 method Methods 0.000 description 12
- 239000002904 solvent Substances 0.000 description 10
- NLZUEZXRPGMBCV-UHFFFAOYSA-N Butylhydroxytoluene Chemical compound CC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 NLZUEZXRPGMBCV-UHFFFAOYSA-N 0.000 description 8
- 239000000853 adhesive Substances 0.000 description 8
- 230000001070 adhesive effect Effects 0.000 description 8
- 239000000243 solution Substances 0.000 description 8
- 239000013078 crystal Substances 0.000 description 7
- 238000007789 sealing Methods 0.000 description 6
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 5
- 230000000694 effects Effects 0.000 description 5
- 239000007788 liquid Substances 0.000 description 5
- 239000012046 mixed solvent Substances 0.000 description 5
- 229920000728 polyester Polymers 0.000 description 5
- 229920006395 saturated elastomer Polymers 0.000 description 5
- 238000003756 stirring Methods 0.000 description 5
- 239000004094 surface-active agent Substances 0.000 description 5
- 238000012360 testing method Methods 0.000 description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 5
- 239000012790 adhesive layer Substances 0.000 description 4
- 239000002216 antistatic agent Substances 0.000 description 4
- 239000003795 chemical substances by application Substances 0.000 description 4
- JHIVVAPYMSGYDF-UHFFFAOYSA-N cyclohexanone Chemical compound O=C1CCCCC1 JHIVVAPYMSGYDF-UHFFFAOYSA-N 0.000 description 4
- 239000006185 dispersion Substances 0.000 description 4
- 230000009477 glass transition Effects 0.000 description 4
- 239000011159 matrix material Substances 0.000 description 4
- 238000002156 mixing Methods 0.000 description 4
- 229920006255 plastic film Polymers 0.000 description 4
- 229920002037 poly(vinyl butyral) polymer Polymers 0.000 description 4
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 3
- WEVYAHXRMPXWCK-UHFFFAOYSA-N Acetonitrile Chemical compound CC#N WEVYAHXRMPXWCK-UHFFFAOYSA-N 0.000 description 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 3
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 3
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 description 3
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 3
- 229920006223 adhesive resin Polymers 0.000 description 3
- 239000003945 anionic surfactant Substances 0.000 description 3
- 239000003093 cationic surfactant Substances 0.000 description 3
- 229920006026 co-polymeric resin Polymers 0.000 description 3
- 150000001875 compounds Chemical class 0.000 description 3
- 239000012153 distilled water Substances 0.000 description 3
- 229910052738 indium Inorganic materials 0.000 description 3
- APFVFJFRJDLVQX-UHFFFAOYSA-N indium atom Chemical compound [In] APFVFJFRJDLVQX-UHFFFAOYSA-N 0.000 description 3
- PJXISJQVUVHSOJ-UHFFFAOYSA-N indium(iii) oxide Chemical compound [O-2].[O-2].[O-2].[In+3].[In+3] PJXISJQVUVHSOJ-UHFFFAOYSA-N 0.000 description 3
- 239000012948 isocyanate Substances 0.000 description 3
- 150000002513 isocyanates Chemical class 0.000 description 3
- 238000004898 kneading Methods 0.000 description 3
- 230000007774 longterm Effects 0.000 description 3
- 229910044991 metal oxide Inorganic materials 0.000 description 3
- 150000004706 metal oxides Chemical class 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 239000002736 nonionic surfactant Substances 0.000 description 3
- 229920006267 polyester film Polymers 0.000 description 3
- 229920000642 polymer Polymers 0.000 description 3
- 230000008569 process Effects 0.000 description 3
- 239000004576 sand Substances 0.000 description 3
- 239000007787 solid Substances 0.000 description 3
- YEJRWHAVMIAJKC-UHFFFAOYSA-N 4-Butyrolactone Chemical compound O=C1CCCO1 YEJRWHAVMIAJKC-UHFFFAOYSA-N 0.000 description 2
- IAZDPXIOMUYVGZ-UHFFFAOYSA-N Dimethylsulphoxide Chemical compound CS(C)=O IAZDPXIOMUYVGZ-UHFFFAOYSA-N 0.000 description 2
- PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 description 2
- ZHNUHDYFZUAESO-UHFFFAOYSA-N Formamide Chemical compound NC=O ZHNUHDYFZUAESO-UHFFFAOYSA-N 0.000 description 2
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 2
- SECXISVLQFMRJM-UHFFFAOYSA-N N-Methylpyrrolidone Chemical compound CN1CCCC1=O SECXISVLQFMRJM-UHFFFAOYSA-N 0.000 description 2
- 239000004677 Nylon Substances 0.000 description 2
- 239000004372 Polyvinyl alcohol Substances 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- 239000002280 amphoteric surfactant Substances 0.000 description 2
- 229910052787 antimony Inorganic materials 0.000 description 2
- WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 2
- 125000004429 atom Chemical group 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 230000007423 decrease Effects 0.000 description 2
- SWXVUIWOUIDPGS-UHFFFAOYSA-N diacetone alcohol Chemical compound CC(=O)CC(C)(C)O SWXVUIWOUIDPGS-UHFFFAOYSA-N 0.000 description 2
- WBTCZEPSIIFINA-MSFWTACDSA-J dipotassium;antimony(3+);(2r,3r)-2,3-dioxidobutanedioate;trihydrate Chemical compound O.O.O.[K+].[K+].[Sb+3].[Sb+3].[O-]C(=O)[C@H]([O-])[C@@H]([O-])C([O-])=O.[O-]C(=O)[C@H]([O-])[C@@H]([O-])C([O-])=O WBTCZEPSIIFINA-MSFWTACDSA-J 0.000 description 2
- IOUCSUBTZWXKTA-UHFFFAOYSA-N dipotassium;dioxido(oxo)tin Chemical compound [K+].[K+].[O-][Sn]([O-])=O IOUCSUBTZWXKTA-UHFFFAOYSA-N 0.000 description 2
- 230000005611 electricity Effects 0.000 description 2
- 239000003822 epoxy resin Substances 0.000 description 2
- 239000005038 ethylene vinyl acetate Substances 0.000 description 2
- 238000001914 filtration Methods 0.000 description 2
- 229910052731 fluorine Inorganic materials 0.000 description 2
- 239000011737 fluorine Substances 0.000 description 2
- HJOVHMDZYOCNQW-UHFFFAOYSA-N isophorone Chemical compound CC1=CC(=O)CC(C)(C)C1 HJOVHMDZYOCNQW-UHFFFAOYSA-N 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 229920001778 nylon Polymers 0.000 description 2
- 229920001200 poly(ethylene-vinyl acetate) Polymers 0.000 description 2
- 229920003229 poly(methyl methacrylate) Polymers 0.000 description 2
- 229920000647 polyepoxide Polymers 0.000 description 2
- 239000004926 polymethyl methacrylate Substances 0.000 description 2
- 239000004814 polyurethane Substances 0.000 description 2
- 229920002451 polyvinyl alcohol Polymers 0.000 description 2
- 239000004800 polyvinyl chloride Substances 0.000 description 2
- 229920000915 polyvinyl chloride Polymers 0.000 description 2
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 2
- 239000012945 sealing adhesive Substances 0.000 description 2
- 239000004065 semiconductor Substances 0.000 description 2
- 229920002050 silicone resin Polymers 0.000 description 2
- 238000010186 staining Methods 0.000 description 2
- 238000003860 storage Methods 0.000 description 2
- 229920000468 styrene butadiene styrene block copolymer Polymers 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- XOLBLPGZBRYERU-UHFFFAOYSA-N tin dioxide Chemical compound O=[Sn]=O XOLBLPGZBRYERU-UHFFFAOYSA-N 0.000 description 2
- 238000002834 transmittance Methods 0.000 description 2
- 238000011179 visual inspection Methods 0.000 description 2
- RYHBNJHYFVUHQT-UHFFFAOYSA-N 1,4-Dioxane Chemical compound C1COCCO1 RYHBNJHYFVUHQT-UHFFFAOYSA-N 0.000 description 1
- LIZUIDJZIMVBRV-UHFFFAOYSA-N 2,4-diisocyanato-1-methylbenzene;2,2-dimethylbutane Chemical compound CCC(C)(C)C.CC1=CC=C(N=C=O)C=C1N=C=O LIZUIDJZIMVBRV-UHFFFAOYSA-N 0.000 description 1
- XNWFRZJHXBZDAG-UHFFFAOYSA-N 2-METHOXYETHANOL Chemical compound COCCO XNWFRZJHXBZDAG-UHFFFAOYSA-N 0.000 description 1
- KXGFMDJXCMQABM-UHFFFAOYSA-N 2-methoxy-6-methylphenol Chemical compound [CH]OC1=CC=CC([CH])=C1O KXGFMDJXCMQABM-UHFFFAOYSA-N 0.000 description 1
- UHKPXKGJFOKCGG-UHFFFAOYSA-N 2-methylprop-1-ene;styrene Chemical compound CC(C)=C.C=CC1=CC=CC=C1.C=CC1=CC=CC=C1 UHKPXKGJFOKCGG-UHFFFAOYSA-N 0.000 description 1
- DDFHBQSCUXNBSA-UHFFFAOYSA-N 5-(5-carboxythiophen-2-yl)thiophene-2-carboxylic acid Chemical compound S1C(C(=O)O)=CC=C1C1=CC=C(C(O)=O)S1 DDFHBQSCUXNBSA-UHFFFAOYSA-N 0.000 description 1
- DKPFZGUDAPQIHT-UHFFFAOYSA-N Butyl acetate Natural products CCCCOC(C)=O DKPFZGUDAPQIHT-UHFFFAOYSA-N 0.000 description 1
- 229910001111 Fine metal Inorganic materials 0.000 description 1
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 1
- 229920000877 Melamine resin Polymers 0.000 description 1
- 239000004640 Melamine resin Substances 0.000 description 1
- NTIZESTWPVYFNL-UHFFFAOYSA-N Methyl isobutyl ketone Chemical compound CC(C)CC(C)=O NTIZESTWPVYFNL-UHFFFAOYSA-N 0.000 description 1
- UIHCLUNTQKBZGK-UHFFFAOYSA-N Methyl isobutyl ketone Natural products CCC(C)C(C)=O UIHCLUNTQKBZGK-UHFFFAOYSA-N 0.000 description 1
- FXHOOIRPVKKKFG-UHFFFAOYSA-N N,N-Dimethylacetamide Chemical compound CN(C)C(C)=O FXHOOIRPVKKKFG-UHFFFAOYSA-N 0.000 description 1
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 1
- 229920000571 Nylon 11 Polymers 0.000 description 1
- 229920000299 Nylon 12 Polymers 0.000 description 1
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 1
- XURCIPRUUASYLR-UHFFFAOYSA-N Omeprazole sulfide Chemical compound N=1C2=CC(OC)=CC=C2NC=1SCC1=NC=C(C)C(OC)=C1C XURCIPRUUASYLR-UHFFFAOYSA-N 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- 239000002033 PVDF binder Substances 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 1
- 239000004952 Polyamide Substances 0.000 description 1
- 239000005062 Polybutadiene Substances 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- 229920001214 Polysorbate 60 Polymers 0.000 description 1
- 239000004793 Polystyrene Substances 0.000 description 1
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- 229920001807 Urea-formaldehyde Polymers 0.000 description 1
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 description 1
- 238000005299 abrasion Methods 0.000 description 1
- 150000008065 acid anhydrides Chemical class 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 229920000180 alkyd Polymers 0.000 description 1
- 150000003973 alkyl amines Chemical class 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 125000000129 anionic group Chemical group 0.000 description 1
- 239000012298 atmosphere Substances 0.000 description 1
- 229920001400 block copolymer Polymers 0.000 description 1
- 239000002981 blocking agent Substances 0.000 description 1
- 230000000903 blocking effect Effects 0.000 description 1
- 229910052794 bromium Inorganic materials 0.000 description 1
- FACXGONDLDSNOE-UHFFFAOYSA-N buta-1,3-diene;styrene Chemical compound C=CC=C.C=CC1=CC=CC=C1.C=CC1=CC=CC=C1 FACXGONDLDSNOE-UHFFFAOYSA-N 0.000 description 1
- 239000006229 carbon black Substances 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 230000000295 complement effect Effects 0.000 description 1
- 238000003851 corona treatment Methods 0.000 description 1
- 239000007822 coupling agent Substances 0.000 description 1
- 238000002788 crimping Methods 0.000 description 1
- HPXRVTGHNJAIIH-UHFFFAOYSA-N cyclohexanol Chemical compound OC1CCCCC1 HPXRVTGHNJAIIH-UHFFFAOYSA-N 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 238000000151 deposition Methods 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- 208000028659 discharge Diseases 0.000 description 1
- TVQLLNFANZSCGY-UHFFFAOYSA-N disodium;dioxido(oxo)tin Chemical compound [Na+].[Na+].[O-][Sn]([O-])=O TVQLLNFANZSCGY-UHFFFAOYSA-N 0.000 description 1
- 239000002270 dispersing agent Substances 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 238000010894 electron beam technology Methods 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- 229920006244 ethylene-ethyl acrylate Polymers 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 230000005669 field effect Effects 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 239000010419 fine particle Substances 0.000 description 1
- 238000010304 firing Methods 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 150000002367 halogens Chemical group 0.000 description 1
- FUZZWVXGSFPDMH-UHFFFAOYSA-N hexanoic acid Chemical compound CCCCCC(O)=O FUZZWVXGSFPDMH-UHFFFAOYSA-N 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 230000007062 hydrolysis Effects 0.000 description 1
- 238000006460 hydrolysis reaction Methods 0.000 description 1
- 230000003301 hydrolyzing effect Effects 0.000 description 1
- 230000002209 hydrophobic effect Effects 0.000 description 1
- 150000002472 indium compounds Chemical class 0.000 description 1
- 238000007689 inspection Methods 0.000 description 1
- 229920000554 ionomer Polymers 0.000 description 1
- ZXEKIIBDNHEJCQ-UHFFFAOYSA-N isobutanol Chemical compound CC(C)CO ZXEKIIBDNHEJCQ-UHFFFAOYSA-N 0.000 description 1
- JMMWKPVZQRWMSS-UHFFFAOYSA-N isopropanol acetate Natural products CC(C)OC(C)=O JMMWKPVZQRWMSS-UHFFFAOYSA-N 0.000 description 1
- 229940011051 isopropyl acetate Drugs 0.000 description 1
- GWYFCOCPABKNJV-UHFFFAOYSA-N isovaleric acid Chemical compound CC(C)CC(O)=O GWYFCOCPABKNJV-UHFFFAOYSA-N 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 238000010030 laminating Methods 0.000 description 1
- 238000003475 lamination Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 229910017604 nitric acid Inorganic materials 0.000 description 1
- 239000004745 nonwoven fabric Substances 0.000 description 1
- 125000005010 perfluoroalkyl group Chemical group 0.000 description 1
- 229920001568 phenolic resin Polymers 0.000 description 1
- 239000005011 phenolic resin Substances 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 238000009832 plasma treatment Methods 0.000 description 1
- 239000002798 polar solvent Substances 0.000 description 1
- 229920000058 polyacrylate Polymers 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 229920001230 polyarylate Polymers 0.000 description 1
- 229920002857 polybutadiene Polymers 0.000 description 1
- 229920001083 polybutene Polymers 0.000 description 1
- 239000004417 polycarbonate Substances 0.000 description 1
- 229920000515 polycarbonate Polymers 0.000 description 1
- 229920006289 polycarbonate film Polymers 0.000 description 1
- 229920001225 polyester resin Polymers 0.000 description 1
- 239000004645 polyester resin Substances 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920000139 polyethylene terephthalate Polymers 0.000 description 1
- 239000005020 polyethylene terephthalate Substances 0.000 description 1
- 229920000098 polyolefin Polymers 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 229920005996 polystyrene-poly(ethylene-butylene)-polystyrene Polymers 0.000 description 1
- 229920002635 polyurethane Polymers 0.000 description 1
- 229920005749 polyurethane resin Polymers 0.000 description 1
- 239000011118 polyvinyl acetate Substances 0.000 description 1
- 229920002689 polyvinyl acetate Polymers 0.000 description 1
- 229920002981 polyvinylidene fluoride Polymers 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- FVSKHRXBFJPNKK-UHFFFAOYSA-N propionitrile Chemical compound CCC#N FVSKHRXBFJPNKK-UHFFFAOYSA-N 0.000 description 1
- RUOJZAUFBMNUDX-UHFFFAOYSA-N propylene carbonate Chemical compound CC1COC(=O)O1 RUOJZAUFBMNUDX-UHFFFAOYSA-N 0.000 description 1
- 230000002441 reversible effect Effects 0.000 description 1
- 229910052703 rhodium Inorganic materials 0.000 description 1
- 229910000077 silane Inorganic materials 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 238000009751 slip forming Methods 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229940079864 sodium stannate Drugs 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 230000003068 static effect Effects 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- HXJUTPCZVOIRIF-UHFFFAOYSA-N sulfolane Chemical compound O=S1(=O)CCCC1 HXJUTPCZVOIRIF-UHFFFAOYSA-N 0.000 description 1
- 229920001187 thermosetting polymer Polymers 0.000 description 1
- 239000010409 thin film Substances 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 239000002966 varnish Substances 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
Abstract
Description
【0001】0001
【産業上の利用分野】本発明は各種電子部品、精密部品
およびICなどの表面実装部品、とりわけICなどの静
電破壊に弱い能動部品の収納、搬送に使用される実装部
品包装体およびこれに使用されるカバーテープフィルム
に関する。[Industrial Application Field] The present invention relates to a mounted component package used for storing and transporting various electronic components, precision components, and surface mount components such as ICs, especially active components susceptible to electrostatic damage such as ICs, and Regarding the cover tape film used.
【0002】0002
【従来の技術】一般にキャリアテープ用カバーテープフ
ィルムとしては、従来厚さ10〜50μmの二軸延伸ポ
リエステルフィルムまたはポリエステル/ポリオレフィ
ンの2層共押し出しフィルムをベースフィルムとし、こ
れに易開封性接着剤層として、スチレン−ブタジエン−
スチレンブロック共重合樹脂、エチレン−酢酸ビニル共
重合樹脂単体もしくはこれにポリブテンを配合したもの
、ナイロン樹脂およびポリウレタン樹脂などを10〜3
0μmの厚みに、フィルム積層法かコーティング法によ
って形成されたものが広く用いられている。[Prior Art] Generally, as a cover tape film for a carrier tape, a biaxially oriented polyester film or a two-layer polyester/polyolefin coextruded film with a thickness of 10 to 50 μm is used as a base film, and an easy-open adhesive layer is added to this base film. As, styrene-butadiene-
Styrene block copolymer resin, ethylene-vinyl acetate copolymer resin alone or blended with polybutene, nylon resin, polyurethane resin, etc.
Those formed with a thickness of 0 μm by a film lamination method or a coating method are widely used.
【0003】このカバーテープフィルムは、表面実装部
品を収納する凹部(以下キャビティと称す)を、帯電防
止または導電性樹脂シートに連続的に形成したキャリア
テープに各種部品を収納後、蓋をかぶせるようにして載
せ、該カバーテープフィルムの両端をキャリアテープに
ヒートシール接着するもので、収納、搬送時には部品の
脱落を防止し、チップマウンターなどの自動実装機によ
る部品実装時にはキャリアテープ本体より剥離除去され
て使用されるものである。[0003] This cover tape film is a carrier tape in which recesses (hereinafter referred to as cavities) for storing surface-mounted components are continuously formed in an antistatic or conductive resin sheet, and the various components are stored in the carrier tape and then a lid is placed on the carrier tape. Both ends of the cover tape film are heat-sealed and bonded to the carrier tape, which prevents components from falling off during storage and transportation, and prevents them from being peeled off from the carrier tape body when mounting components using an automatic mounting machine such as a chip mounter. It is used in
【0004】0004
【発明が解決しようとする課題】この様に、カバーテー
プフィルムは、その製造工程および使用工程で巻出し、
巻き取りが数回行われると同時に、キャリアテープより
剥離されるため、剥離時に電化の移動が生じ、フィルム
自体が帯電し易く、帯電した場合にはキャリアテープか
らカバーテープを剥離する際に、収納部品がカバーテー
プフィルム側に静電付着してしまい該キャリアテープの
キャビティより脱落したり、位置がずれたりして自動実
装が困難になるという問題や、相補型MOS−IC、ト
ランジスタ、トランジスタ・ロジック、電界効果型MO
S−トランジスタ、バイポーラトランジスタ、ショット
キダイオード等の静電気に弱い半導体素子(一般に能動
部品と称する)は、帯電したカバーテープフィルムに接
触した場合、放電により静電破壊してしまうという問題
を生じる。そこでこれらカバーテープフィルムは、一般
に帯電防止剤を該ヒートシール接着剤層に練り込んだり
、金属や金属酸化物を表面に蒸着したり、該帯電防止剤
を表面にコーティングして薄膜を形成したりして用いら
れる。また、カバーテープフィルムにおいて帯電防止効
果が得られるための表面抵抗としては、109 Ω以下
、望ましくは107 Ω以下が必要であると言われてい
る。[Problems to be Solved by the Invention] In this way, the cover tape film is unwound during its manufacturing process and usage process.
As the cover tape is peeled off from the carrier tape at the same time as it is wound several times, electricity transfers during peeling, and the film itself is easily charged. There are problems such as parts electrostatically adhering to the cover tape film side and falling out of the carrier tape cavity or being misaligned, making automatic mounting difficult, and complementary MOS-IC, transistor, transistor logic. , field effect MO
Semiconductor elements (generally referred to as active components) that are sensitive to static electricity, such as S-transistors, bipolar transistors, and Schottky diodes, suffer from electrostatic damage due to discharge when they come into contact with a charged cover tape film. Therefore, these cover tape films are generally made by incorporating an antistatic agent into the heat-sealing adhesive layer, depositing metal or metal oxide on the surface, or coating the surface with the antistatic agent to form a thin film. It is used as Further, it is said that the surface resistance of a cover tape film to obtain an antistatic effect is required to be 10 9 Ω or less, preferably 10 7 Ω or less.
【0005】このような帯電防止効果を与えるのに有効
な手段として、接着剤層にカーボンブラックや金属微粉
等の導電性粉末を加える方法があるが、トップテープフ
ィルムは、該フィルムを通して部品のマーキング文字を
確認したり、目視検査する必要があるため透明性が要求
されるので実用的に採用できない。それ故、トップテー
プフィルム表面の導電性を高める方法として、透明もし
くは半透明な界面活性剤を用いる帯電防止法、すなわち
アニオン系活性剤、カチオン系活性剤、非イオン性活性
剤、両性活性剤などの界面活性剤をフィルムの接着剤層
に練り込んだり、フィルム表面にコーティングして、カ
バーテープフィルム表面に親水性とイオン性を与える方
法が一般に行われている。そのような帯電防止剤に用い
る界面活性剤としては、脂肪族第4級アンモニウム塩型
カチオン系界面活性剤、カルボキシベタイン型両性界面
活性剤、高級アルコールリン酸エステル・ナトリウム塩
などのアニオン系界面活性剤、ポリオキシエチレンソル
ビタン脂肪酸エステル、ポリオキシエチレンアルキルア
ミンなどの非イオン性界面活性剤が挙げられる。[0005] As an effective means for providing such an antistatic effect, there is a method of adding conductive powder such as carbon black or fine metal powder to the adhesive layer. Transparency is required because it is necessary to check the characters and perform a visual inspection, so it cannot be used practically. Therefore, as a method to increase the conductivity of the top tape film surface, antistatic methods using transparent or translucent surfactants, such as anionic surfactants, cationic surfactants, nonionic surfactants, amphoteric surfactants, etc. A commonly used method is to knead a surfactant into the adhesive layer of the film or coat the surface of the film to impart hydrophilicity and ionicity to the surface of the cover tape film. Surfactants used in such antistatic agents include aliphatic quaternary ammonium salt type cationic surfactants, carboxybetaine type amphoteric surfactants, and anionic surfactants such as higher alcohol phosphate ester sodium salts. Examples include nonionic surfactants such as surfactants, polyoxyethylene sorbitan fatty acid esters, and polyoxyethylene alkyl amines.
【0006】上記帯電防止剤は、粉末状、水溶液状、油
溶液状として市販されており、ヒートシール性接着剤層
に練り込むか、該フィルムの表面にコーティングして用
いられる。しかし、■一般に、界面活性剤はフィルム面
において、−COO− M+ 、−OSO3−M+、(
以上のMはH、Na、Kなどの元素原子)、[−N(C
H3)2 −]+ X− (XはCl、Br等のハロゲ
ン元素原子)、−OH、−(CH2CH2 O)n −
などの親水基を大気中に向けて配列させ、その吸湿性に
よって電気抵抗を低下させるものであるから、大気中の
湿度に左右されやすく、また、常温常湿(5〜35℃、
45〜85%RH)において表面抵抗が109 Ω以上
であり、上記した半導体素子の静電破壊防止には役立た
ない、■接着剤層に練り込む場合には、接着剤樹脂と帯
電防止剤との相溶性が問題となり、相溶性が不良の場合
には接着剤層表面にブリードして、ヒートシール接着性
能を劣化させる場合がある、■フィルム表面へコーティ
ングしたものは、湿気中に溶け出して帯電防止効果が失
われやすい、等の問題点があった。The above-mentioned antistatic agent is commercially available in the form of a powder, an aqueous solution, or an oil solution, and is used by being kneaded into the heat-sealing adhesive layer or by coating the surface of the film. However, ■Generally, surfactants have the following properties on the film surface: -COO- M+, -OSO3-M+, (
The above M is an element atom such as H, Na, K, etc.), [-N(C
H3)2 -]+ X- (X is a halogen element atom such as Cl or Br), -OH, -(CH2CH2O)n -
Hydrophilic groups such as these are arranged toward the atmosphere, and their hygroscopicity lowers the electrical resistance.
45 to 85% RH), the surface resistance is 109 Ω or more, and it is not useful for preventing the electrostatic damage of semiconductor elements described above. Compatibility becomes a problem, and if the compatibility is poor, it may bleed onto the surface of the adhesive layer and deteriorate the heat-sealing performance.■ Coatings applied to the film surface may dissolve in moisture and become electrostatically charged. There were problems such as the prevention effect being easily lost.
【0007】これらの問題を解決するために、本発明者
は、先に有機導電体である7,7,8,8,−テトラシ
アノキノジメタン錯体(以下TCNQ錯体と略記)にお
いて、ドナーが異なる該錯体を数種混合して耐熱性およ
び信頼性を向上する試みや、アルキル基置換のTCNQ
錯体を用いる試みを実施してきた。しかし、これらTC
NQ錯体を用いた場合は、TCNQ錯体がドナーとTC
NQのイオン的結合であるため、高温高湿条件(60℃
、95%Rh)下で長期間保存すると導電性が低下して
しまう問題と同時に、これらTCNQ錯体を用いたもの
は、高分子マトリックスの溶媒溶液中にTCNQ錯体を
溶解し、これを基材となるベースフィルムに塗工し、溶
剤を揮発乾燥してマトリックス樹脂中に針状の結晶を析
出し、該針状結晶が接触することにより導電性を得てい
る。そのためこの針状結晶が該高分子マトリックス樹脂
層より突出し、これを実使用においてヒートシールを長
時間実施した場合、加熱されたシールヘッド表面に、こ
のマトリックス樹脂層より突出した針状結晶が折れて付
着してシールヘッドをよごすと共に、付着した結晶がシ
ールヘッドの熱により粘着性を帯びてカバーテープを持
ち上げシール不可能となるので、定期的にシールヘッド
を清掃する必要があった。更に、該キャリアテープのキ
ャビティに電子部品を内在し、カバーテープをシールし
てテーピングを終了した段階において、内在する電子部
品の向きや、未充填の有無を目視にて確認する検査を実
施するが、この検査の段階において、検査者の手袋など
に該TCNQの針状結晶が付着してしまう問題と同時に
、このTCNQ錯体の微細な結晶が電子部品に付着して
半田付け性を低下させてしまうなどといった問題があっ
た。In order to solve these problems, the present inventor first developed an organic conductor, 7,7,8,8,-tetracyanoquinodimethane complex (hereinafter abbreviated as TCNQ complex), in which the donor was Attempts have been made to improve heat resistance and reliability by mixing several types of different complexes, and TCNQ with alkyl group substitution has been made.
Attempts have been made to use complexes. However, these T.C.
When an NQ complex is used, the TCNQ complex interacts with the donor and TC.
Because it is an ionic bond of NQ, high temperature and high humidity conditions (60℃
At the same time, there is a problem that the conductivity decreases when stored for a long period of time under conditions such as The resin is coated on a base film, and the solvent is evaporated and dried to precipitate needle-shaped crystals in the matrix resin, and the needle-shaped crystals come into contact with each other to obtain conductivity. Therefore, these acicular crystals protrude from the polymer matrix resin layer, and when heat sealing is performed for a long time in actual use, the acicular crystals protruding from the matrix resin layer may break on the heated seal head surface. The adhered crystals not only dirty the seal head, but also become sticky due to the heat of the seal head, lifting the cover tape and making it impossible to seal, so it was necessary to periodically clean the seal head. Furthermore, when electronic components are contained in the cavity of the carrier tape and the cover tape is sealed and taping is completed, an inspection is performed to visually confirm the orientation of the electronic components contained therein and whether or not they are unfilled. At this testing stage, there is the problem that the needle-shaped crystals of TCNQ adhere to the gloves of the inspector, and at the same time, the fine crystals of this TCNQ complex adhere to electronic components, reducing solderability. There were such problems.
【0008】また、上記したTCNQ錯体などの有機導
電体にかえ、高温高湿条件下における信頼性の向上と、
シールヘッドへの付着などの問題を解決するために、金
属酸化物導電材料についても種々の検討を実施したが、
高温高湿条件下の信頼性、導電性、シールヘッドへの付
着の点では問題はないものの、十分な透明性を得ること
ができないという問題があった。[0008] In addition, instead of using an organic conductor such as the above-mentioned TCNQ complex, it is possible to improve reliability under high temperature and high humidity conditions.
In order to solve problems such as adhesion to seal heads, various studies were conducted on metal oxide conductive materials.
Although there were no problems in terms of reliability, conductivity, and adhesion to the seal head under high temperature and high humidity conditions, there was a problem in that sufficient transparency could not be obtained.
【0009】[0009]
【課題を解決するための手段】本発明者はこれら上記し
た問題点を解決するために、上記した透明導電材料の種
類および粒径について鋭意検討を実施した結果、透明プ
ラスチックフィルムの表面に、平均粒径が0.3μm以
下の酸化スズ化合物および/または酸化インジウム化合
物の微粉末とバインダー樹脂とから成る透明導電性樹脂
層を設け、裏面にホットメルト接着剤層を設けた透明性
複合カバーテープフィルムと、帯電防止または導電性の
樹脂シートに実装部品を収納する凹部を連続的に設けた
キャリアテープとよりなり、該ホットメルト接着剤層で
該キャリアテープが易開封性に熱シールされていること
を特徴とする実装部品包装体を見出し本発明を完成させ
た。[Means for Solving the Problems] In order to solve the above-mentioned problems, the inventors of the present invention have conducted intensive studies on the type and particle size of the above-mentioned transparent conductive material, and have found that the average A transparent composite cover tape film provided with a transparent conductive resin layer consisting of fine powder of a tin oxide compound and/or indium oxide compound with a particle size of 0.3 μm or less and a binder resin, and a hot melt adhesive layer provided on the back side. and a carrier tape comprising an antistatic or conductive resin sheet with continuous recesses for accommodating the mounted components, and the carrier tape is heat-sealed with the hot melt adhesive layer for easy opening. The present invention was completed by discovering a mounted component package characterized by the following.
【0010】以下、図面を用いて本発明を詳細に説明す
る。図1(a)に示すように、本発明のカバーテープフ
ィルムは、透明プラスチックフィルム1の表面に、透明
導電性樹脂層2、裏面に易開封性ホットメルト接着層3
を設けたもので、(b)に示すように、実装部品を収納
する凹部4を連続的に設けたキャリアテープ5をこれに
より熱シールする。透明導電材料としては上記したよう
に、酸化スズ化合物または酸化インジウム化合物であっ
て、これら化合物としては、酸化スズや酸化インジウム
単体および酸化スズや酸化インジウムに異種元素がドー
プされたものであり、これらドープされる異種元素とし
ては、アンチモンやフッ素、リン等の他、インジウムに
はスズ、スズにはインジウム等が例示され、これら異種
元素をドープすることにより、導電性を向上することが
できる。これら透明導電材料の粒径は、大きすぎるとバ
インダー樹脂に配合して透明導電性樹脂層とした場合、
可視光線が該導電性材料粒子により乱反射され光線透過
率が低下すると共に、バインダー樹脂表面に該導電性材
料粒子が突出し、微細な凹凸を形成して該フィルムの曇
価(ヘーズ)が上昇し、透明性が低下するという問題を
生じるため、該透明導電材料の平均粒径は可視光波長よ
り短い0.3μm以下であって、90%以上の粒子が0
.5μm以下の範囲に入るようにすればよい。しかし平
均粒径が0.05μmより小さくなると、得られる透明
導電性樹脂層の表面抵抗がいちじるしく上昇して前述し
た必要な表面抵抗より高くなるおそれがあるので、該透
明導電材料の平均粒径を0.05〜0.3μmの範囲と
するのが好ましい。The present invention will be explained in detail below with reference to the drawings. As shown in FIG. 1(a), the cover tape film of the present invention has a transparent conductive resin layer 2 on the surface of a transparent plastic film 1, and an easy-open hot melt adhesive layer 3 on the back surface.
As shown in (b), a carrier tape 5 having continuous recesses 4 for accommodating mounted components is heat-sealed by this. As mentioned above, the transparent conductive material is a tin oxide compound or an indium oxide compound, and these compounds include tin oxide, indium oxide alone, and tin oxide or indium oxide doped with a different element. Examples of the different elements to be doped include antimony, fluorine, phosphorus, etc., as well as tin for indium and indium for tin. By doping with these different elements, conductivity can be improved. If the particle size of these transparent conductive materials is too large, when combined with a binder resin to form a transparent conductive resin layer,
Visible light is diffusely reflected by the conductive material particles, reducing light transmittance, and the conductive material particles protrude on the surface of the binder resin, forming fine irregularities and increasing the haze of the film. To avoid the problem of decreased transparency, the average particle size of the transparent conductive material is 0.3 μm or less, which is shorter than the wavelength of visible light, and 90% or more of the particles are 0.3 μm or less.
.. It may be within the range of 5 μm or less. However, if the average particle size is smaller than 0.05 μm, the surface resistance of the resulting transparent conductive resin layer may increase significantly and become higher than the above-mentioned required surface resistance. It is preferably in the range of 0.05 to 0.3 μm.
【0011】これら、微細な粒子を製造する方法として
は水溶性でPH=8〜12の弱アルカリ領域で加水分解
が可能なスズまたはインジウム化合物、例えばスズ酸カ
リウムやスズ酸ナトリウムあるいは硝酸インジウムや硫
酸インジウム等を上記弱アルカリ領域で加水分解してゾ
ルを生成させ、これを濾過した後、乾燥、焼成して得る
ことができる。また、上記したような異種元素をドープ
したい場合は、水溶性の該ドープ元素化合物、例えばア
ンチモンの場合は酒石酸アンチモニルカリウム、フッ素
の場合はフッ化アンモニウムを溶解させておくことで各
元素をドープした微粉末を得ることができる。[0011] As a method for producing these fine particles, tin or indium compounds that are water-soluble and can be hydrolyzed in a weakly alkaline region of pH 8 to 12, such as potassium stannate, sodium stannate, indium nitrate, or sulfuric acid, are used. It can be obtained by hydrolyzing indium or the like in the above-mentioned weak alkaline region to generate a sol, filtering the sol, then drying and firing. In addition, when it is desired to dope a different element as mentioned above, each element can be doped by dissolving a water-soluble compound of the doping element, for example, potassium antimonyl tartrate in the case of antimony, or ammonium fluoride in the case of fluorine. A fine powder can be obtained.
【0012】本発明のカバーテープは、上記のようにし
て得られる透明導電性微粉末を、適宜な溶剤等に溶解し
たバインダー樹脂中に配合、分散して導電性インクとし
、これを該透明プラスチックフィルムに適宜な方法で塗
工して、透明導電性樹脂層を形成し、該プラスチックフ
ィルムの反対面に易開封性のホットメルト接着剤層を形
成することによって得られる。上記透明導電性粉末を配
合、分散させるバインダー樹脂としては、使用される透
明プラスチックフィルムとの密着性および透明性が高い
ことが必要である。さらに該透明導電性樹脂層を形成す
る手法は前述のように塗工により形成されることが好ま
しいことから、該バインダー樹脂は汎用溶剤に溶解する
必要があり、なおかつ実使用においてはヒートシールさ
れることから、加熱されたシールヘッドに当接して該バ
インダー樹脂が軟化し粘着性を帯びてしまうと、カバー
テープフィルムがシールヘッドに付着してしまうスティ
ッキング現象を生じ、作業に支障をきたすので、シール
ヘッドに所定の時間当接させても粘着性を帯びないよう
な耐熱性が必要である。The cover tape of the present invention is prepared by blending and dispersing the transparent conductive fine powder obtained as described above in a binder resin dissolved in a suitable solvent to form a conductive ink. It is obtained by coating a film using an appropriate method to form a transparent conductive resin layer, and forming an easily openable hot melt adhesive layer on the opposite side of the plastic film. The binder resin used to blend and disperse the transparent conductive powder needs to have high adhesion and transparency to the transparent plastic film used. Furthermore, since the transparent conductive resin layer is preferably formed by coating as described above, the binder resin needs to be dissolved in a general-purpose solvent, and in actual use, it is heat-sealed. Therefore, if the binder resin softens and becomes sticky when it comes into contact with a heated seal head, a sticking phenomenon occurs in which the cover tape film adheres to the seal head, which hinders sealing operations. It must have heat resistance so that it does not become sticky even if it is brought into contact with the head for a predetermined period of time.
【0013】このようなバインダー樹脂としては、熱硬
化性ポリウレタン(PU)や高ガラス転移点の飽和共重
合ポリエステル、エポキシ樹脂(EP)、フェノール樹
脂(PF)、ポリメタクリル酸メチル(PMMA)に代
表されるポリアクリレート、ポリカーボネート(PC)
、ユリア樹脂、メラミン樹脂、アルキッド樹脂、ナイロ
ン11および12、ポリビニルブチラール(PVB)、
ポリビニルアルコール(PVA)、フッ素系樹脂、シリ
コーン樹脂(SR)などの単体もしくは2種以上の混合
物の使用が好ましく、これらの樹脂中にその耐熱性を向
上させる目的で、イソシアネート、酸無水物、アミン化
合物等の硬化剤を適宜配合することは任意であるととも
に、イソシアネート系の硬化剤を使用した場合、その硬
化促進のために60℃×72時間の加温エイジングにお
いて、得られるトップテープフィルム同士がブロッキン
グしないように、パーフロロアルキル基を含有するブロ
ック共重合体に例示されるブロッキング防止剤等を添加
することも任意とされる。Typical binder resins include thermosetting polyurethane (PU), saturated copolymer polyester with a high glass transition point, epoxy resin (EP), phenolic resin (PF), and polymethyl methacrylate (PMMA). polyacrylate, polycarbonate (PC)
, urea resin, melamine resin, alkyd resin, nylon 11 and 12, polyvinyl butyral (PVB),
It is preferable to use a single substance or a mixture of two or more of polyvinyl alcohol (PVA), fluororesin, silicone resin (SR), etc. In order to improve the heat resistance of these resins, isocyanates, acid anhydrides, and amines are added. It is optional to add a curing agent such as a compound, and when an isocyanate-based curing agent is used, the resulting top tape film is aged at 60°C for 72 hours to promote curing. In order to prevent blocking, it is optional to add an antiblocking agent, etc., as exemplified by block copolymers containing perfluoroalkyl groups.
【0014】更に、バインダー樹脂として、無溶剤で塗
工できるなどのメリットと同時に、加工速度を向上でき
るなどのメリットから、紫外線硬化樹脂または電子線硬
化樹脂を用いてもよい。Further, as the binder resin, an ultraviolet curable resin or an electron beam curable resin may be used because of the advantages of not only being able to be coated without a solvent but also improving processing speed.
【0015】これらバインダー樹脂に配合する透明導電
性微粉末の割合は、少なすぎると所望の導電性を得るこ
とができないし、多すぎると基材のプラスチックフィル
ムに対する透明導電性樹脂層の密着力が低下すると同時
に、導電性粒子の間をバインダー樹脂が充填できず間隙
ができて透明性が低下するという問題があるので、導電
性微粉末とバインダー樹脂の総重量に対して、導電性微
粉末が40〜85重量%とすればよい。[0015] If the proportion of the transparent conductive fine powder added to the binder resin is too small, the desired conductivity cannot be obtained, and if it is too large, the adhesion of the transparent conductive resin layer to the plastic film of the base material is reduced. At the same time, there is a problem that the binder resin cannot fill between the conductive particles, creating gaps and reducing transparency, so the conductive fine powder is The content may be 40 to 85% by weight.
【0016】また、これらバインダー樹脂を溶解する溶
剤としては、樹脂の溶解性および塗工するプラスチック
フィルムの耐溶剤性を考慮して汎用溶剤の中から適宜選
択すればよく、具体的には、メタノール、エタノール、
n−プロパノール、i−プロパノール、n−ブタノール
、i−ブタノール、ジアセトンアルコール、シクロヘキ
サノールなどのアルコール類、アセトン、シクロヘキサ
ノン、メチルエチルケトン、メチルイソブチルケトン、
ホロン、イソホロン等のケトン類、エチレングリコール
モノメチルエーテル、カルビトール、ジオキサン等のエ
ーテル類、酢酸エチル、酢酸ブチル、酢酸イソプロピル
等のエステル類、トルエン、キシレン、ソルベントナフ
サ等の芳香族類、ジメチルホルムアミド、ジメチルアセ
トアミド、プロピレンカーボネート、γ−ブチロラクト
ン、ジメチルスルフォキシド、スルホラン、フォルムア
マイド、N−メチル−2−ピロリドン、アセトニトリル
、プロピオニトリル等の極性溶剤および水の単体あるい
は2種以上の混合溶剤が例示される。[0016] The solvent for dissolving these binder resins may be appropriately selected from general-purpose solvents, taking into account the solubility of the resin and the solvent resistance of the plastic film to be coated. ,ethanol,
Alcohols such as n-propanol, i-propanol, n-butanol, i-butanol, diacetone alcohol, cyclohexanol, acetone, cyclohexanone, methyl ethyl ketone, methyl isobutyl ketone,
Ketones such as holone and isophorone, ethers such as ethylene glycol monomethyl ether, carbitol and dioxane, esters such as ethyl acetate, butyl acetate and isopropyl acetate, aromatics such as toluene, xylene and solvent naphtha, dimethylformamide, Examples include polar solvents such as dimethylacetamide, propylene carbonate, γ-butyrolactone, dimethyl sulfoxide, sulfolane, formamide, N-methyl-2-pyrrolidone, acetonitrile, propionitrile, and water alone or as a mixed solvent of two or more. be done.
【0017】該導電性微粉末は、上記溶剤に溶解された
バインダー樹脂溶液に配合された後、これを均一に分散
することによって得られるが、この分散方法としてはス
パイラルミキサー、プラネタリーミキサー、ディスパー
サー、ハイブリッドミキサーなどのブレード型撹拌混練
装置によりプレミキシングを行った後、ボールミル、振
動ミル、サンドミルなどのボール型混練装置や三本ロー
ルなどのロール型混練装置を用いて分散を徹底化するの
が望ましい。[0017] The conductive fine powder is obtained by blending it into the binder resin solution dissolved in the above solvent and then uniformly dispersing it. As a dispersion method, a spiral mixer, a planetary mixer, or a dispersion method can be used. After premixing is performed using a blade-type stirring and kneading device such as a parser or hybrid mixer, thorough dispersion is performed using a ball-type kneading device such as a ball mill, vibration mill, or sand mill, or a roll-type kneading device such as a triple roll. is desirable.
【0018】また、この分散性を向上するために、分散
剤としてアニオン系、ノニオン系、カチオン系の各種界
面活性剤や、シラン系、チタン系、アルミニウム系など
の各種カップリング剤等を配合することは任意とされる
。[0018] In order to improve the dispersibility, various anionic, nonionic, and cationic surfactants and various coupling agents such as silane, titanium, and aluminum are added as dispersants. This is considered optional.
【0019】このようにして調整された透明導電性イン
クは以下に示す各種の塗工方法に合わせて適宜粘度およ
び固形分を調整された後、公知の塗工方法、具体的には
グラビアコーター、三本リバースコーター、オフセット
グラビアコーター等のロールコーターやメイヤーバー、
バーコーター、コンマコーターおよびエアナイフコータ
ー、さらにはディップコーターやスプレイコーター等を
用いて適宜の表面抵抗が得られる厚みに塗工、乾燥すれ
ばよいが、この厚みが厚すぎるとコストが高くなるので
、好ましくは0.2〜1.0μmの範囲の乾燥膜厚とす
るのがよい。After the viscosity and solid content of the transparent conductive ink prepared in this manner are appropriately adjusted according to the various coating methods shown below, the transparent conductive ink is coated using a known coating method, specifically, a gravure coater, Roll coaters such as triple reverse coaters and offset gravure coaters, Meyer bars,
It is sufficient to apply the coating to a thickness that provides an appropriate surface resistance using a bar coater, comma coater, air knife coater, or even a dip coater or spray coater, and then dry it. However, if this thickness is too thick, the cost will increase. The dry film thickness is preferably in the range of 0.2 to 1.0 μm.
【0020】また、本発明に使用する透明プラスチック
フィルムとしては、透明性の高い汎用のプラスチックフ
ィルムが用いられる。具体的には、ポリエチレンフィル
ム、ポリ塩化ビニルフィルム、ポリプロピレンフィルム
、ポリスチレンフィルム、ポリエチレンテレフタレート
フィルム、ポリカーボネートフィルム、ポリアリレート
フィルム、ポリフッ化ビニリデンフィルム、ポリアミド
フィルムの単体もしくはこれらの複合フィルムなどが例
示される。これら透明プラスチックフィルムは、透明導
電性樹脂層を形成することから、この密着性を向上させ
る目的で該表面をコロナ放電処理またはプラズマ処理を
行うことが好ましい。[0020] Furthermore, as the transparent plastic film used in the present invention, a general-purpose plastic film with high transparency is used. Specific examples include polyethylene film, polyvinyl chloride film, polypropylene film, polystyrene film, polyethylene terephthalate film, polycarbonate film, polyarylate film, polyvinylidene fluoride film, polyamide film, or composite films thereof. Since these transparent plastic films form a transparent conductive resin layer, their surfaces are preferably subjected to corona discharge treatment or plasma treatment for the purpose of improving this adhesiveness.
【0021】本発明のカバーテープフィルムは、上記の
ようにして得られたフィルムの反対面に易開封性のホッ
トメルト接着剤層を形成して得られるが、該接着剤に用
いられる樹脂としては、飽和共重合ポリエステル樹脂、
ポリビニルブチラール、塩化ビニル樹脂、エチレン−酢
酸ビニル共重合樹脂、ポリブタジエン樹脂、エチレン−
アクリル酸エチル共重合樹脂、ポリ酢酸ビニル樹脂、ア
イオノマー樹脂、スチレン−ブタジエン−スチレン共重
合樹脂、スチレン−イソブチレン−スチレン共重合樹脂
、スチレン−エチレン・ブチレン−スチレン共重合樹脂
、ナイロン樹脂、ポリビニルブチラール樹脂等の単体も
しくは2種以上の複合体が例示される。これらホットメ
ルト接着剤樹脂は、その樹脂の剥離強度を抑えるために
透明性を低下させない範囲において親水性もしくは疎水
性のシリカなどのフィラー等を配合することは任意とさ
れる。The cover tape film of the present invention is obtained by forming an easily openable hot melt adhesive layer on the opposite side of the film obtained as described above, and the resin used for the adhesive is , saturated copolymerized polyester resin,
Polyvinyl butyral, vinyl chloride resin, ethylene-vinyl acetate copolymer resin, polybutadiene resin, ethylene-
Ethyl acrylate copolymer resin, polyvinyl acetate resin, ionomer resin, styrene-butadiene-styrene copolymer resin, styrene-isobutylene-styrene copolymer resin, styrene-ethylene/butylene-styrene copolymer resin, nylon resin, polyvinyl butyral resin Examples include a single substance or a complex of two or more types. These hot melt adhesive resins may optionally contain hydrophilic or hydrophobic fillers such as silica, etc., to the extent that the transparency is not reduced, in order to suppress the peel strength of the resin.
【0022】また、これらのホットメルト接着剤樹脂層
を該ベースフィルムに形成する方法としては、該ベース
フィルムに上記ホットメルト接着樹脂をTダイより溶融
して押出してコーティングするか、または上記接着剤樹
脂を適宜な溶剤に溶解してワニスとし、上記の塗工方法
より適宜な方法を選択してコーティングにより形成して
もよいし、更には該接着剤がフィルム状である場合は、
熱ロールにてラミネートするか接着剤を用いて接着して
形成してもよい。[0022] The method of forming these hot melt adhesive resin layers on the base film includes coating the base film by melting and extruding the above hot melt adhesive resin through a T-die, or coating the base film with the above adhesive. The resin may be dissolved in an appropriate solvent to form a varnish, and the adhesive may be formed by coating by selecting an appropriate coating method from the above coating methods. Furthermore, if the adhesive is in the form of a film,
It may be formed by laminating with a hot roll or bonding using an adhesive.
【0023】このホットメルト接着剤の厚みとしては、
該接着剤も透明性が必要とされることから、厚すぎると
透明性が低下するし、薄すぎると十分な接着強度が得ら
れないので、0.5〜30μmの範囲、好ましくは1.
0〜20μmの範囲とすればよい。また、このカバーテ
ープは内在する電子部品を実装する際に、キャリアテー
プより剥離する必要があるため、該ホットメルト接着剤
の接着強度が過度に大きいとベースフィルムが破断して
しまうおそれがあるので易開封性とする必要があり、具
体的な剥離強度としては180度ピールにおいて10〜
100gf/mm、好ましくは20〜70gf/mmと
すればよい。[0023] The thickness of this hot melt adhesive is as follows:
Since the adhesive is also required to have transparency, if it is too thick, the transparency will decrease, and if it is too thin, sufficient adhesive strength will not be obtained.
It may be in the range of 0 to 20 μm. In addition, this cover tape needs to be peeled off from the carrier tape when mounting internal electronic components, so if the adhesive strength of the hot melt adhesive is excessively high, the base film may break. It must be easy to open, and the specific peel strength is 10~180 degrees peel.
It may be 100 gf/mm, preferably 20 to 70 gf/mm.
【0024】[0024]
【実施例】以下、実施例および比較例により、本発明を
具体的に説明する。
[実施例1]透明基材として厚さ25μmのポリエステ
ルフィルム「ルミラーRTタイプ」(東レ(株)製、商
品名)をベースフィルムとして使用した。易開封性ホッ
トメルト接着剤として、ガラス転移点2℃、環球法軟化
点115℃の飽和共重合ポリエステル「エリーテル R
UE−3221」(ユニチカ(株)製、商品名)を使用
し、この「エリーテル RUE−3221」100重量
部をトルエン/メチルエチルケトン(50/50容量%
)の混合溶剤233.3重量部に高速ディスパーサーを
用いて溶解し、粘度150cPのコーティング溶液Aを
調整した。次いで、ガラス転移点90℃、環球法軟化点
185℃の飽和共重合ポリエステル「エリーテル RU
E−3690」(ユニチカ(株)製、商品名)30重量
部を、メチルエチルケトン/トルエン(50/50)の
混合溶剤70重量部に高速ディスパーサーを用いて溶解
し、固形分30wt%のバインダー樹脂溶液を調整した
。このバインダー樹脂溶液30重量部に以下の工程にて
製造されたアンチモンドープの酸化スズ化合物微粉末を
30重量部、メチルエチルケトン/トルエン=1/1の
混合溶剤240重量部を配合した後、ディスパーサーを
用いて撹拌後、サンドミル処理を行って分散を完全なも
のとし、固形分13.0%で粘度200cpの透明導電
性インクBを調整した。[Examples] The present invention will be specifically explained below with reference to Examples and Comparative Examples. [Example 1] A polyester film "Lumirror RT Type" (manufactured by Toray Industries, Inc., trade name) having a thickness of 25 μm was used as a transparent base film. As an easy-to-open hot-melt adhesive, ``ELITEL R'' is a saturated copolymer polyester with a glass transition point of 2°C and a ring and ball softening point of 115°C.
UE-3221'' (manufactured by Unitika Co., Ltd., trade name), and 100 parts by weight of this ``Eritel RUE-3221'' was mixed with toluene/methyl ethyl ketone (50/50% by volume).
) was dissolved in 233.3 parts by weight of a mixed solvent using a high-speed disperser to prepare a coating solution A having a viscosity of 150 cP. Next, a saturated copolymer polyester "ELITEL RU" having a glass transition point of 90°C and a ring and ball softening point of 185°C was used.
30 parts by weight of "E-3690" (manufactured by Unitika Co., Ltd., trade name) was dissolved in 70 parts by weight of a mixed solvent of methyl ethyl ketone/toluene (50/50) using a high-speed disperser to obtain a binder resin with a solid content of 30 wt%. A solution was prepared. After blending 30 parts by weight of antimony-doped tin oxide compound fine powder produced in the following process and 240 parts by weight of a mixed solvent of methyl ethyl ketone/toluene = 1/1 to 30 parts by weight of this binder resin solution, a disperser was added. After stirring using the ink, a sand mill treatment was performed to complete the dispersion, and a transparent conductive ink B having a solid content of 13.0% and a viscosity of 200 cp was prepared.
【0025】上記アンチモンドープ酸化スズ化合物微粉
末は、スズ酸カリウム300gと酒石酸アンチモニルカ
リウム36.0gを蒸留水664gに溶解し、次いでこ
の水溶液を45℃に調整された容量2リットルの蒸留水
に撹拌および超音波を印加しながら添加し、該温度調節
された水浴のPHを8.5になるように硝酸を添加しな
がら加水分解により導電性粒子が分散したゾル液を調整
した後、これを濾過して濾紙上に残ったものを蒸留水で
洗浄し、得られた粒子を乾燥した後空気中にて200℃
から600℃まで4時間をかけて昇温し、さらに650
℃で2時間焼成して、平均粒径0.17μmで90%ま
での粒子が3.3μm以内である酸化スズ化合物微粉末
を作製した。The antimony-doped tin oxide compound fine powder is obtained by dissolving 300 g of potassium stannate and 36.0 g of potassium antimonyl tartrate in 664 g of distilled water, and then adding this aqueous solution to 2 liters of distilled water adjusted to 45°C. After adding nitric acid while stirring and applying ultrasonic waves and adjusting the pH of the temperature-controlled water bath to 8.5, a sol solution in which conductive particles are dispersed is prepared by hydrolysis. After filtration, the particles remaining on the filter paper were washed with distilled water, and the resulting particles were dried and heated at 200°C in the air.
to 600℃ over 4 hours, and further to 650℃.
C. for 2 hours to produce a tin oxide compound fine powder with an average particle size of 0.17 .mu.m and 90% of the particles being within 3.3 .mu.m.
【0026】上記にて作製したコーティング溶液Aおよ
び透明導電性インクBを、各々線数150メッシュ、深
度50μmのグラビア版と線数200メッシュ、深度2
5μmのグラビア版を両面同時塗工可能な2色グラビア
コーターに設置し、前記ポリエステルフィルムの一面に
A→Bの順に反転させて両面コーティング・乾燥を実施
し、その後、40℃にて3日間エージングを実施した。
この際、透明導電性インクB100重量部に対して、イ
ソシアネート系硬化剤「CAT−10」(東洋モートン
(株)製、商品名)1.0重量部を添加、撹拌して使用
した。Coating solution A and transparent conductive ink B prepared above were each applied to a gravure plate with a line count of 150 mesh and a depth of 50 μm and a line count of 200 mesh and a depth of 2.
A 5 μm gravure plate was installed in a two-color gravure coater that can coat both sides simultaneously, and the polyester film was coated on both sides by inverting it from A to B in the order of B, followed by aging at 40 ° C. for 3 days. was carried out. At this time, 1.0 parts by weight of an isocyanate curing agent "CAT-10" (manufactured by Toyo Morton Co., Ltd., trade name) was added to 100 parts by weight of transparent conductive ink B, and the mixture was stirred.
【0027】得られた乾燥塗膜の厚さはコーティング液
Aが3μm、コーティング液Bが0.2μmであった。
得られたカバーテープフィルムの透明導電性樹脂層にD
C100Vを印加して表面抵抗を測定したところ、平均
値5.0×106 Ω、最大値6.0×106 Ω、最
小値4.5×106 Ωであって非常に安定しており、
その光線透過率は82%、ヘイズは10以下であり、耐
摩耗性について、100gfの荷重を加えて不織布を該
透明導電性樹脂層にこすりつけて試験した結果、50回
のラビングにおいても不織布に樹脂層が付着することは
なく、導電性にも大きな変化は見られなかった。ついで
これに、所定の幅にスリット加工を実施し、幅1mmの
ヒートシールヘッドによってポリ塩化ビニル製IC用キ
ャリアテープ「シンエツキャリア」(信越ポリマー(株
)製、商品名)にシールヘッド温度180℃で圧着時間
0.3秒にてシールを繰り返ししたところ、従来のTC
NQ錯体を用いたものは約6000ショットでスティキ
ング現象が発生し、シールヘッドの清掃が必要となった
のに対し、本発明のカバーテープフィルムは、10万シ
ョットをすぎてもシールヘッドの汚れは認められず、ス
ティッキング現象も起きなかった。また、その平均剥離
接着強度は38gf/mmであり、最大64gf/mm
、最小25gf/mmであり良好な強度を示した。The thickness of the dried coating film obtained was 3 μm for coating liquid A and 0.2 μm for coating liquid B. D on the transparent conductive resin layer of the obtained cover tape film
When applying C100V and measuring the surface resistance, the average value was 5.0 x 106 Ω, the maximum value was 6.0 x 106 Ω, and the minimum value was 4.5 x 106 Ω, which was very stable.
The light transmittance is 82%, the haze is 10 or less, and the abrasion resistance was tested by rubbing the nonwoven fabric against the transparent conductive resin layer with a load of 100 gf. The layers did not stick together, and no significant change in conductivity was observed. This was then slit to a predetermined width, and a seal head temperature of 180°C was applied to the polyvinyl chloride IC carrier tape "Shin-Etsu Carrier" (manufactured by Shin-Etsu Polymer Co., Ltd., trade name) using a heat seal head with a width of 1 mm. When sealing was repeated with a crimping time of 0.3 seconds, the conventional TC
The cover tape film using the NQ complex developed a sticking phenomenon after about 6,000 shots and required cleaning of the seal head, whereas the cover tape film of the present invention does not cause staining of the seal head even after 100,000 shots. was not observed, and no sticking phenomenon occurred. In addition, its average peel adhesion strength is 38 gf/mm, and the maximum is 64 gf/mm.
, the minimum strength was 25 gf/mm, showing good strength.
【0028】[比較例1]実施例1における透明導電性
インクBに代えて、高分子マトリックスとして、ガラス
転移点90℃、環球法軟化点185℃の飽和共重合ポリ
エステル「エリーテル RUE−3690」(ユニチカ
(株)製、商品名)10重量部を、シクロヘキサノン/
トルエン(70/30)の混合溶剤500重量部に高速
ディスパーサーを用いて溶解し、この中にN−n−ブチ
ルイソキノリニウム−メチル−TCNQ錯体(日東化学
工業(株)製、試作品)5.3重量部と、N−n−ブチ
ル−N−メチルモルホリニウム−メチル−TCNQ錯体
(日東化学工業(株)製、試作品)2.7重量部を添加
し、ディスパーサーを用いて撹拌溶解後、サンドミル処
理を行い、さらに濾紙(ワットマンフィルターペーパー
No.3)によって濾過を行った。得られた液100重
量部にトルエンジイソシアネート−トリメチルプロパン
アダクトプレポリマー「コロネートL」(日本ポリウレ
タン工業(株)製、商品名)0.25重量部とブロッキ
ング防止剤「モディパーF」(日本油脂(株)製、商品
名)0.1重量部を添加した後、再度ディスパーサーで
撹拌し、粘度20cPのコーティング溶液Cを調整した
。その他については実施例−1と同様に実施し、上記コ
ーティング液Cについては乾燥膜厚0.1μmであった
。得られたトップテープフィルムの該コーティング液C
による塗膜にDC100Vを印加して表面抵抗を測定し
たところ、平均値2.5×106 Ω、最大値3.0×
106 Ω、最小値2.0×106 Ωであった。図2
に高温高湿下の表面抵抗の変化を、表1にラビングテス
トおよびロングランテストの結果を示す。[Comparative Example 1] In place of the transparent conductive ink B in Example 1, a saturated copolymerized polyester "ELITEL RUE-3690" (with a glass transition point of 90°C and a ring and ball softening point of 185°C) was used as a polymer matrix. 10 parts by weight of Unitika Co., Ltd. (trade name), cyclohexanone/
Dissolve Nn-butylisoquinolinium-methyl-TCNQ complex (manufactured by Nitto Kagaku Kogyo Co., Ltd., prototype) in 500 parts by weight of a mixed solvent of toluene (70/30) using a high-speed disperser. ) and 2.7 parts by weight of N-n-butyl-N-methylmorpholinium-methyl-TCNQ complex (manufactured by Nitto Kagaku Kogyo Co., Ltd., prototype), and using a disperser. After stirring and dissolving the mixture, it was subjected to a sand mill treatment and further filtered through a filter paper (Whatman filter paper No. 3). To 100 parts by weight of the obtained liquid, 0.25 parts by weight of toluene diisocyanate-trimethylpropane adduct prepolymer "Coronate L" (manufactured by Nippon Polyurethane Industries, Ltd., trade name) and anti-blocking agent "Modiper F" (Nippon Oil & Fats Co., Ltd.) were added. After adding 0.1 part by weight (trade name, manufactured by )), stirring was performed again using a disperser to prepare a coating solution C having a viscosity of 20 cP. The rest was carried out in the same manner as in Example-1, and the coating liquid C had a dry film thickness of 0.1 μm. The coating liquid C of the obtained top tape film
When the surface resistance was measured by applying DC100V to the coating film, the average value was 2.5×106 Ω, and the maximum value was 3.0×
The resistance was 106 Ω, and the minimum value was 2.0×106 Ω. Figure 2
Table 1 shows the changes in surface resistance under high temperature and high humidity conditions, and Table 1 shows the results of the rubbing test and long run test.
【0029】[0029]
【表1】[Table 1]
【0030】[0030]
【発明の効果】本発明のカバーテープフィルムは、透明
導電性樹脂層に高温高湿条件における信頼性が高い金属
酸化物である酸化スズ化合物微粉末および酸化インジウ
ム微粉末を使用しているので、図2に示すように、長期
の高温高湿条件における保存においても表面抵抗が上昇
せず、更に粒子を従来の導電性粉末より小さくしたこと
により、従来の酸化スズ系の透明導電性樹脂層に比較し
て大幅に透明性を向上することができ、電子部品のマー
キング等の確認における視認性を大幅に向上することが
でき、よってこれらの確認工程の自動認識を可能とする
ものである。また、従来のTCNQ錯体等で問題となっ
ていた、長時間のヒートシールにおけるシールヘッドの
汚れおよびスティッキング問題および手袋等の導電材料
の付着問題について、本発明に用いている透明導電性微
粉末は酸化スズ化合物または酸化インジウム化合物微粉
末であり、無機導電体であるためにヒートシールにおけ
るシールヘッドに当接しても熔融または軟化して粘着性
を帯びることがないのでスティッキングを起こすことが
ない。更に使用している粒子が上記したように従来のも
のに比較して小さく、またTCNQ錯体のように結晶化
しないので、導電材が表面に露出していても該透明導電
性樹脂層より突出していることはなく、長期のシールテ
スト(ロングランテスト)においてもシールヘッドを清
掃するまでの期間が著しく延び、実質的に一つのシール
ヘッドでシールするロットが1万〜10万ショットであ
り、作業を中断して清掃する手間を解消することができ
る。また、同様に目視検査等においても手袋などへの導
電材料の付着による汚れなどがないことが確認された。[Effects of the Invention] The cover tape film of the present invention uses tin oxide compound fine powder and indium oxide fine powder, which are metal oxides that are highly reliable under high temperature and high humidity conditions, in the transparent conductive resin layer. As shown in Figure 2, the surface resistance does not increase even after long-term storage under high temperature and high humidity conditions, and by making the particles smaller than conventional conductive powders, it is possible to improve Transparency can be significantly improved in comparison, and visibility in checking markings on electronic components can be greatly improved, thereby enabling automatic recognition of these checking processes. In addition, the transparent conductive fine powder used in the present invention solves the problems of staining and sticking of the seal head during long-term heat sealing and adhesion of conductive materials such as gloves, which were problems with conventional TCNQ complexes. It is a fine powder of a tin oxide compound or an indium oxide compound, and since it is an inorganic conductor, it does not melt or soften and become sticky even when it comes into contact with the seal head in heat sealing, so it does not cause sticking. Furthermore, as mentioned above, the particles used are smaller than conventional ones and do not crystallize like the TCNQ complex, so even if the conductive material is exposed on the surface, it will not protrude from the transparent conductive resin layer. Even in long-term seal tests (long-run tests), the time it takes to clean the seal head is significantly extended, and in effect, the lot to be sealed with one seal head is 10,000 to 100,000 shots, making the work much easier. This eliminates the need for interrupted cleaning. Similarly, visual inspection etc. also confirmed that there was no stain caused by conductive material adhering to the gloves or the like.
【図1】(a)は本発明のカバーテープフィルムの縦断
面図、(b)はカバーテープで熱シールしたキャリアテ
ープよりなる実装部品包装体の縦断面図である。FIG. 1(a) is a longitudinal sectional view of a cover tape film of the present invention, and FIG. 1(b) is a longitudinal sectional view of a mounted component package made of a carrier tape heat-sealed with a cover tape.
【図2】本発明における実装部品包装体の高温高湿条件
(60℃−95%Rh)下の表面抵抗の変化を示すグラ
フである。FIG. 2 is a graph showing changes in surface resistance of the mounted component package according to the present invention under high temperature and high humidity conditions (60° C.-95% Rh).
1 透明プラスチックフィルム 2 透明導電性樹脂層 3 易開封性ホットメルト接着剤 4 凹部 5 キャリアテープ 1 Transparent plastic film 2 Transparent conductive resin layer 3. Easy-open hot melt adhesive 4 Recessed part 5 Carrier tape
Claims (2)
平均粒径が0.3μm以下の酸化スズ化合物および/ま
たは酸化インジウム化合物の微粉末とバインダー樹脂と
から成る透明導電性樹脂層を設け、裏面にホットメルト
接着剤層を設けたことを特徴とする透明性複合カバーテ
ープフィルム。[Claim 1] On the surface of a transparent plastic film,
A transparent conductive resin layer consisting of fine powder of a tin oxide compound and/or indium oxide compound with an average particle size of 0.3 μm or less and a binder resin is provided, and a hot melt adhesive layer is provided on the back side. Transparent composite cover tape film.
平均粒径が0.3μm以下の酸化スズ化合物および/ま
たは酸化インジウム化合物の微粉末とバインダー樹脂と
から成る透明導電性樹脂層を設け、裏面にホットメルト
接着剤層を設けた透明性複合カバーテープフィルムと、
帯電防止または導電性の樹脂シートに実装部品を収納す
る凹部を連続的に設けたキャリアテープとよりなり、該
ホットメルト接着剤層で該キャリアテープが易開封性に
熱シールされていることを特徴とする実装部品包装体。[Claim 2] On the surface of the transparent plastic film,
A transparent composite cover tape provided with a transparent conductive resin layer consisting of fine powder of a tin oxide compound and/or indium oxide compound with an average particle size of 0.3 μm or less and a binder resin, and a hot melt adhesive layer provided on the back side. film and
The carrier tape consists of an antistatic or conductive resin sheet with continuous recesses for storing the mounted components, and the carrier tape is heat-sealed with the hot melt adhesive layer for easy opening. Mounted parts package.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP15538391A JP2904613B2 (en) | 1991-05-31 | 1991-05-31 | Cover tape film and mounted component package using the same |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP15538391A JP2904613B2 (en) | 1991-05-31 | 1991-05-31 | Cover tape film and mounted component package using the same |
Publications (2)
Publication Number | Publication Date |
---|---|
JPH04367457A true JPH04367457A (en) | 1992-12-18 |
JP2904613B2 JP2904613B2 (en) | 1999-06-14 |
Family
ID=15604751
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP15538391A Expired - Lifetime JP2904613B2 (en) | 1991-05-31 | 1991-05-31 | Cover tape film and mounted component package using the same |
Country Status (1)
Country | Link |
---|---|
JP (1) | JP2904613B2 (en) |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2001075905A1 (en) * | 2000-04-03 | 2001-10-11 | Dai Nippon Printing Co., Ltd. | Transparent, electrically conductive and heat-sealable material and lidded container for carrier tape using the same |
US7455896B2 (en) | 2001-05-28 | 2008-11-25 | Denki Kagaku Kogyo Kabushiki Kaisha | Electronic component container |
WO2013054867A1 (en) * | 2011-10-14 | 2013-04-18 | 電気化学工業株式会社 | Cover tape |
-
1991
- 1991-05-31 JP JP15538391A patent/JP2904613B2/en not_active Expired - Lifetime
Cited By (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2001075905A1 (en) * | 2000-04-03 | 2001-10-11 | Dai Nippon Printing Co., Ltd. | Transparent, electrically conductive and heat-sealable material and lidded container for carrier tape using the same |
US6635343B2 (en) | 2000-04-03 | 2003-10-21 | Dai Nippon Printing Co., Ltd. | Transparent conductive heat sealing material and carrier tape lid using the same |
KR100768280B1 (en) * | 2000-04-03 | 2007-10-17 | 다이니폰 인사츠 가부시키가이샤 | Transparent, electrically conductive and heat-sealable material and lidded container for carrier tape using the same |
US7455896B2 (en) | 2001-05-28 | 2008-11-25 | Denki Kagaku Kogyo Kabushiki Kaisha | Electronic component container |
WO2013054867A1 (en) * | 2011-10-14 | 2013-04-18 | 電気化学工業株式会社 | Cover tape |
KR20140107183A (en) * | 2011-10-14 | 2014-09-04 | 덴끼 가가꾸 고교 가부시키가이샤 | Cover tape |
JPWO2013054867A1 (en) * | 2011-10-14 | 2015-03-30 | 電気化学工業株式会社 | Cover tape |
US9453146B2 (en) | 2011-10-14 | 2016-09-27 | Denka Company Limited | Cover tape |
TWI568650B (en) * | 2011-10-14 | 2017-02-01 | 電化股份有限公司 | Cover tape |
Also Published As
Publication number | Publication date |
---|---|
JP2904613B2 (en) | 1999-06-14 |
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