JPH04361099A - Metallic design pattern transfer foil and manufacture thereof - Google Patents
Metallic design pattern transfer foil and manufacture thereofInfo
- Publication number
- JPH04361099A JPH04361099A JP16360791A JP16360791A JPH04361099A JP H04361099 A JPH04361099 A JP H04361099A JP 16360791 A JP16360791 A JP 16360791A JP 16360791 A JP16360791 A JP 16360791A JP H04361099 A JPH04361099 A JP H04361099A
- Authority
- JP
- Japan
- Prior art keywords
- layer
- transparent
- film
- base film
- pattern printing
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000011888 foil Substances 0.000 title claims abstract description 30
- 238000004519 manufacturing process Methods 0.000 title claims description 5
- 238000007639 printing Methods 0.000 claims abstract description 67
- 229920005989 resin Polymers 0.000 claims abstract description 23
- 239000011347 resin Substances 0.000 claims abstract description 23
- 238000000576 coating method Methods 0.000 claims abstract description 13
- 239000011248 coating agent Substances 0.000 claims abstract description 11
- 230000001681 protective effect Effects 0.000 claims abstract description 11
- 239000010410 layer Substances 0.000 claims description 116
- 239000010408 film Substances 0.000 claims description 51
- 229910052751 metal Inorganic materials 0.000 claims description 39
- 239000002184 metal Substances 0.000 claims description 39
- 238000007740 vapor deposition Methods 0.000 claims description 16
- 239000012790 adhesive layer Substances 0.000 claims description 10
- 239000011104 metalized film Substances 0.000 claims description 5
- 238000000034 method Methods 0.000 claims description 5
- 238000010030 laminating Methods 0.000 claims 1
- 230000001070 adhesive effect Effects 0.000 abstract description 12
- 239000000853 adhesive Substances 0.000 abstract description 11
- 230000008020 evaporation Effects 0.000 abstract 6
- 238000001704 evaporation Methods 0.000 abstract 6
- 239000000976 ink Substances 0.000 description 15
- 229920000877 Melamine resin Polymers 0.000 description 8
- 239000004640 Melamine resin Substances 0.000 description 6
- 239000000463 material Substances 0.000 description 6
- 229920003023 plastic Polymers 0.000 description 6
- 239000004033 plastic Substances 0.000 description 6
- 238000007650 screen-printing Methods 0.000 description 5
- 239000004753 textile Substances 0.000 description 5
- 238000000151 deposition Methods 0.000 description 4
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- 229920001807 Urea-formaldehyde Polymers 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- -1 polypropylene Polymers 0.000 description 3
- GZVHEAJQGPRDLQ-UHFFFAOYSA-N 6-phenyl-1,3,5-triazine-2,4-diamine Chemical compound NC1=NC(N)=NC(C=2C=CC=CC=2)=N1 GZVHEAJQGPRDLQ-UHFFFAOYSA-N 0.000 description 2
- 239000004925 Acrylic resin Substances 0.000 description 2
- 229920000178 Acrylic resin Polymers 0.000 description 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
- 239000000020 Nitrocellulose Substances 0.000 description 2
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 description 2
- 229920000180 alkyd Polymers 0.000 description 2
- 229910052782 aluminium Inorganic materials 0.000 description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
- 229920002301 cellulose acetate Polymers 0.000 description 2
- 239000012461 cellulose resin Substances 0.000 description 2
- 238000005260 corrosion Methods 0.000 description 2
- 230000007797 corrosion Effects 0.000 description 2
- JHIVVAPYMSGYDF-UHFFFAOYSA-N cyclohexanone Chemical compound O=C1CCCCC1 JHIVVAPYMSGYDF-UHFFFAOYSA-N 0.000 description 2
- 230000008021 deposition Effects 0.000 description 2
- 239000012046 mixed solvent Substances 0.000 description 2
- 229920001220 nitrocellulos Polymers 0.000 description 2
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 2
- 229920000139 polyethylene terephthalate Polymers 0.000 description 2
- 239000005020 polyethylene terephthalate Substances 0.000 description 2
- 239000011241 protective layer Substances 0.000 description 2
- 238000001771 vacuum deposition Methods 0.000 description 2
- RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 description 1
- 229920000298 Cellophane Polymers 0.000 description 1
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- GYHNNYVSQQEPJS-UHFFFAOYSA-N Gallium Chemical compound [Ga] GYHNNYVSQQEPJS-UHFFFAOYSA-N 0.000 description 1
- NTIZESTWPVYFNL-UHFFFAOYSA-N Methyl isobutyl ketone Chemical compound CC(C)CC(C)=O NTIZESTWPVYFNL-UHFFFAOYSA-N 0.000 description 1
- UIHCLUNTQKBZGK-UHFFFAOYSA-N Methyl isobutyl ketone Natural products CCC(C)C(C)=O UIHCLUNTQKBZGK-UHFFFAOYSA-N 0.000 description 1
- 239000004962 Polyamide-imide Substances 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 description 1
- 229920001800 Shellac Polymers 0.000 description 1
- 239000006087 Silane Coupling Agent Substances 0.000 description 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 1
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- 229920002433 Vinyl chloride-vinyl acetate copolymer Polymers 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- 239000000956 alloy Substances 0.000 description 1
- 229910045601 alloy Inorganic materials 0.000 description 1
- 229920003180 amino resin Polymers 0.000 description 1
- ZLKFKSFPHWZMOC-UHFFFAOYSA-N butyl acetate;4-methylpentan-2-one Chemical compound CC(C)CC(C)=O.CCCCOC(C)=O ZLKFKSFPHWZMOC-UHFFFAOYSA-N 0.000 description 1
- 239000004359 castor oil Substances 0.000 description 1
- 235000019438 castor oil Nutrition 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- 239000011651 chromium Substances 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 238000004040 coloring Methods 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 239000002537 cosmetic Substances 0.000 description 1
- 238000005034 decoration Methods 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 229920001971 elastomer Polymers 0.000 description 1
- 239000003822 epoxy resin Substances 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 229910052733 gallium Inorganic materials 0.000 description 1
- 239000011086 glassine Substances 0.000 description 1
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 239000010931 gold Substances 0.000 description 1
- LNEPOXFFQSENCJ-UHFFFAOYSA-N haloperidol Chemical compound C1CC(O)(C=2C=CC(Cl)=CC=2)CCN1CCCC(=O)C1=CC=C(F)C=C1 LNEPOXFFQSENCJ-UHFFFAOYSA-N 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- FUZZWVXGSFPDMH-UHFFFAOYSA-N hexanoic acid Chemical compound CCCCCC(O)=O FUZZWVXGSFPDMH-UHFFFAOYSA-N 0.000 description 1
- NUKZAGXMHTUAFE-UHFFFAOYSA-N hexanoic acid methyl ester Natural products CCCCCC(=O)OC NUKZAGXMHTUAFE-UHFFFAOYSA-N 0.000 description 1
- 229910052738 indium Inorganic materials 0.000 description 1
- APFVFJFRJDLVQX-UHFFFAOYSA-N indium atom Chemical compound [In] APFVFJFRJDLVQX-UHFFFAOYSA-N 0.000 description 1
- 239000012948 isocyanate Substances 0.000 description 1
- 238000003475 lamination Methods 0.000 description 1
- 239000000944 linseed oil Substances 0.000 description 1
- 235000021388 linseed oil Nutrition 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 150000002688 maleic acid derivatives Chemical class 0.000 description 1
- 238000001465 metallisation Methods 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 239000000025 natural resin Substances 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 235000019198 oils Nutrition 0.000 description 1
- 229910052763 palladium Inorganic materials 0.000 description 1
- 229920001568 phenolic resin Polymers 0.000 description 1
- 239000005011 phenolic resin Substances 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 229910052697 platinum Inorganic materials 0.000 description 1
- 229920002037 poly(vinyl butyral) polymer Polymers 0.000 description 1
- 229920006122 polyamide resin Polymers 0.000 description 1
- 229920002312 polyamide-imide Polymers 0.000 description 1
- 229920000515 polycarbonate Polymers 0.000 description 1
- 239000004417 polycarbonate Substances 0.000 description 1
- 229920005668 polycarbonate resin Polymers 0.000 description 1
- 239000004431 polycarbonate resin Substances 0.000 description 1
- 229920000647 polyepoxide Polymers 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 229920001225 polyester resin Polymers 0.000 description 1
- 239000004645 polyester resin Substances 0.000 description 1
- 229920013716 polyethylene resin Polymers 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 229920002635 polyurethane Polymers 0.000 description 1
- 239000004814 polyurethane Substances 0.000 description 1
- 229920000915 polyvinyl chloride Polymers 0.000 description 1
- 239000004800 polyvinyl chloride Substances 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 239000004208 shellac Substances 0.000 description 1
- ZLGIYFNHBLSMPS-ATJNOEHPSA-N shellac Chemical compound OCCCCCC(O)C(O)CCCCCCCC(O)=O.C1C23[C@H](C(O)=O)CCC2[C@](C)(CO)[C@@H]1C(C(O)=O)=C[C@@H]3O ZLGIYFNHBLSMPS-ATJNOEHPSA-N 0.000 description 1
- 229940113147 shellac Drugs 0.000 description 1
- 235000013874 shellac Nutrition 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 229910052709 silver Inorganic materials 0.000 description 1
- 239000004332 silver Substances 0.000 description 1
- 229920003002 synthetic resin Polymers 0.000 description 1
- 239000000057 synthetic resin Substances 0.000 description 1
- 229920002803 thermoplastic polyurethane Polymers 0.000 description 1
- 229910052718 tin Inorganic materials 0.000 description 1
- 239000011135 tin Substances 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 description 1
- 239000002383 tung oil Substances 0.000 description 1
- 238000007738 vacuum evaporation Methods 0.000 description 1
- 239000003981 vehicle Substances 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
- 230000037303 wrinkles Effects 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
Landscapes
- Printing Methods (AREA)
- Decoration By Transfer Pictures (AREA)
Abstract
Description
【０００２】0002
【産業上の利用分野】本発明は、自動車等の内装材、化
粧品容器、キャップ、汎用パッケージ、インモールド成
形品、弱電製品、高級襖、欄間、着物、帯、衣服、木工
品、プラスチック加工品、工芸品、民芸品などの装飾に
使用する転写箔に関する。更に詳しくは平面から立体的
な図柄印刷と全面ないしは任意の部分にメタリック感の
ある装飾が可能な転写箔に関する。[Industrial Application Fields] The present invention is applicable to interior materials for automobiles, etc., cosmetic containers, caps, general-purpose packages, in-mold molded products, light electrical products, high-grade sliding doors, transoms, kimonos, obi, clothing, wood products, and plastic processed products. , Concerning transfer foil used for decoration of crafts, folk art, etc. More specifically, the present invention relates to a transfer foil that is capable of printing flat to three-dimensional designs and decorating the entire surface or any part with a metallic feel.
【０００３】0003
【従来の技術】従来よりメタリック図柄転写箔は有った
が、それはおおむね次のように構成されていた。BACKGROUND OF THE INVENTION Metallic pattern transfer foils have been available in the past, but they were generally constructed as follows.
【０００４】Ａ）透明ベースフイルムの片面にリリース
層を塗布し、該リリース層上に図柄印刷層を印刷し、該
図柄印刷層上に直接にまたは一旦メジウム層を塗布し、
全面金属蒸着層を蒸着し、要すれば該金属蒸着層上に接
着剤層を順次形成したものが知られている。 またＢ
）透明ベースフイルムの片面にリリース層を塗布し、該
リリース層上に図柄印刷層を印刷し、該図柄印刷層上に
直接にまたは一旦メジウム層を塗布し、全面金属蒸着層
を蒸着し、該金属蒸着層の不要部分を残してレジスト膜
を塗布し、次いで金属腐食液中で露出している金属蒸着
層を溶解除去し、要すれば全面にあるいは該レジスト膜
上にあるいは所望部分に接着剤層を順次形成したものが
知られている。A) Coating a release layer on one side of a transparent base film, printing a pattern printing layer on the release layer, directly or once coating a medium layer on the pattern printing layer,
It is known that a metal vapor deposition layer is deposited on the entire surface, and if necessary, an adhesive layer is sequentially formed on the metal vapor deposition layer. Also B
) Coating a release layer on one side of a transparent base film, printing a pattern printing layer on the release layer, coating the pattern printing layer directly or once with a medium layer, depositing a metal vapor deposition layer on the entire surface, and A resist film is applied leaving unnecessary parts of the metal vapor deposited layer, and then the exposed metal vapor deposited layer is dissolved and removed in a metal corrosive liquid, and if necessary, an adhesive is applied to the entire surface or on the resist film or to a desired part. One in which layers are formed sequentially is known.
【０００５】これらのメタリック図柄転写箔はいずれも
その製造工程中に金属蒸着層を全面に真空蒸着する工程
が含まれるために種々の制限を受けた。[0005] All of these metallic pattern transfer foils are subject to various limitations because their manufacturing process includes a step of vacuum-depositing a metal deposition layer over the entire surface.
【０００６】たとえば、半連続式真空蒸着機の最小蒸着
加工数量（たいていは１ｍ幅６０００ｍ長さ程度）にあ
わせて商品企画する必要が有り、特に多種類のデザイン
で少量の需要、たとえば、高級襖、欄間、着物、帯、衣
服、木工品、プラスチック加工品、工芸品、民芸品など
の需要には応じられないという問題点が有った。また真
空中でガス放出の多い印刷インキの使用はできず、特に
印刷インキの盛り上がった捺染やスクリーン印刷はイン
キからのガス放出が多く採用できなかった。したがって
ビロード調、レザー調、シボ感のある図柄印刷は採用で
きなかった。またＢ）の場合には、図柄印刷とレジスト
膜との位置関係を金属蒸着層を介して行うために繊細な
見当合わせが極めて難しく歩留が悪くなるなどの問題点
が有った。更にまたＢ）の場合には、金属腐食液中で処
理しなければならないので透明ベースフイルムをはじめ
リリース層、図柄印刷層、メジウム層を構成する材料に
は十分に耐食性を考慮したものから選定する必要が有っ
た。[0006] For example, it is necessary to plan a product according to the minimum deposition processing quantity of a semi-continuous vacuum evaporation machine (usually about 1 m wide and 6000 m long), and especially if there is a demand for small quantities with a wide variety of designs, for example, high-quality sliding doors. There was a problem in that they could not meet the demand for transoms, kimonos, obi, clothing, woodwork, plastic products, crafts, folk crafts, etc. In addition, printing inks that release a lot of gas in a vacuum cannot be used, and in particular, textile printing and screen printing with raised printing ink cannot be used because the ink releases a lot of gas. Therefore, velvet-like, leather-like, or grained designs could not be used. In the case of B), since the positional relationship between the pattern printing and the resist film is established through the metal vapor deposited layer, it is extremely difficult to achieve delicate registration, resulting in poor yield. Furthermore, in the case of B), since the metal must be treated in a corrosive solution, the materials constituting the transparent base film, release layer, pattern printing layer, and medium layer should be selected with sufficient corrosion resistance in mind. There was a need.
【０００７】[0007]
【発明が解決しようとする課題】したがって、本発明は
従来のタイプＡ）透明ベースフイルムの片面にリリース
層を塗布し、該リリース層上に図柄印刷層を印刷し、該
図柄印刷層上に直接にまたは一旦メジウム層を塗布し、
全面金属蒸着層を蒸着し、要すれば該金属蒸着層上に接
着剤層を順次形成したもの。あるいはタイプＢ）透明ベ
ースフイルムの片面にリリース層を塗布し、該リリース
層上に図柄印刷層を印刷し、該図柄印刷層上に直接にま
たは一旦メジウム層を塗布し、全面金属蒸着層を蒸着し
、該金属蒸着層の不要部分を残してレジスト膜を塗布し
、次いで金属腐食液中で露出している金属蒸着層を溶解
除去し、要すれば全面にあるいは該レジスト膜上にある
いは所望部分に接着剤層を順次形成したものが有してい
た種々の課題を解決使用とするもので有る。[Problems to be Solved by the Invention] Therefore, the present invention is a conventional type A) in which a release layer is coated on one side of a transparent base film, a pattern printing layer is printed on the release layer, and a pattern printing layer is directly printed on the pattern printing layer. or once a medium layer is applied,
A metal vapor deposited layer is deposited on the entire surface, and if necessary, an adhesive layer is sequentially formed on the metal vapor deposited layer. Or Type B) Coat a release layer on one side of a transparent base film, print a pattern printing layer on the release layer, directly or once coat a medium layer on the pattern printing layer, and then evaporate a metal vapor deposition layer on the entire surface. Then, a resist film is applied leaving unnecessary parts of the metal vapor deposited layer, and then the exposed metal vapor deposited layer is dissolved and removed in a metal corrosive solution, and if necessary, it is coated on the entire surface or on the resist film or a desired part. It is intended to solve various problems that existed with those in which adhesive layers were sequentially formed.
【０００８】すなわちこれら従来のメタリック図柄転写
箔はいずれもその製造工程中に金属蒸着層を全面に真空
蒸着する工程が含まれるために種々の制限、たとえば、
半連続式真空蒸着機の最小蒸着加工数量（たいていは１
ｍ幅６０００ｍ長さ程度）にあわせて商品企画する必要
が有り、特に多種類のデザインで少量の需要、たとえば
、高級襖、欄間、着物、帯、衣服、木工品、プラスチッ
ク加工品、工芸品、民芸品などの需要には応じられない
という問題点が有った。また真空中でガス放出の多い印
刷インキの使用はできず、特に印刷インキの盛り上がっ
た捺染やスクリーン印刷はインキからのガス放出が多く
採用できなかった。したがってビロード調、レザー調、
シボ感のある図柄印刷は採用できなかった。またＢ）の
場合には、図柄印刷とレジスト膜との位置関係を金属蒸
着層を介して行うために繊細な検討合わせが極めて難し
く歩留が悪くなるなどの問題点が有った。更にまたＢ）
の場合には、金属腐食液中で処理しなければならないの
で透明ベースフイルムをはじめリリース層、図柄印刷層
、メジウム層を構成する材料には十分に耐食性を考慮し
たものから選定する必要が有った、などの前記種々の問
題点を解決することが目的である。[0008] In other words, all of these conventional metallic pattern transfer foils have various limitations, such as:
Minimum deposition processing quantity for semi-continuous vacuum deposition machines (usually 1
It is necessary to plan products according to the size (approximately 6,000 m width and length), especially for small-scale demand with a wide variety of designs, such as high-quality sliding doors, transoms, kimonos, obi, clothing, woodwork, plastic processed products, crafts, etc. There was a problem in that they could not meet the demand for folk crafts and other items. In addition, printing inks that release a lot of gas in a vacuum cannot be used, and in particular, textile printing and screen printing with raised printing ink cannot be used because the ink releases a lot of gas. Therefore, velvet-like, leather-like,
It was not possible to print a pattern with a grainy appearance. In the case of B), since the positional relationship between the pattern printing and the resist film is determined through the metal vapor deposited layer, it is extremely difficult to make delicate considerations, resulting in poor yield. Furthermore, B)
In this case, the material must be treated in a metal corrosive solution, so the materials constituting the transparent base film, release layer, pattern printing layer, and medium layer must be selected with sufficient corrosion resistance in mind. The purpose is to solve the various problems mentioned above.
【０００９】すなわち、本発明は特に多種類のデザイン
で少量の需要、たとえば、高級襖、欄間、着物、帯、衣
服、木工品、プラスチック加工品、工芸品、民芸品など
の需要には応じられ、真空中でのガス放出の多い印刷イ
ンキの使用や、特に印刷インキの盛り上がった捺染やス
クリーン印刷が採用でき、したがってビロード調、レザ
ー調、シボ感のある図柄印刷も採用でき、その上、図柄
印刷と金属蒸着層などの位置関係も極めて簡単に整合あ
るいは所望量ずらすことも任意にできるメタリック図柄
転写箔を提供することにある。That is, the present invention cannot particularly meet the demand for small quantities with a wide variety of designs, such as high-quality sliding doors, transoms, kimonos, obi, clothing, woodwork, plastic products, crafts, and folk crafts. , it is possible to use printing inks that emit a lot of gas in a vacuum, and especially textile printing and screen printing with raised printing ink. Therefore, it is also possible to print patterns with a velvet-like, leather-like, or grained feel. It is an object of the present invention to provide a metallic pattern transfer foil in which the positional relationship between the printing and the metal vapor deposition layer can be very easily aligned or shifted by a desired amount.
【００１０】0010
【課題を解決するための手段】本発明のメタリック図柄
転写箔は、１）透明ベースフイルム（Ａ）の片面上に要
すれば透明リリース層を介して、図柄印刷層を設けた透
明ベースフイルム（Ａ）の図柄印刷層を設けた側に、透
明な接着性付与層を介して金属蒸着層を形成することを
採用したことを特徴とする。[Means for Solving the Problems] The metallic pattern transfer foil of the present invention comprises: 1) a transparent base film (A) with a pattern printing layer provided on one side of the transparent base film (A), if necessary via a transparent release layer; It is characterized in that a metal vapor deposition layer is formed on the side where the pattern printing layer of A) is provided, with a transparent adhesion imparting layer interposed therebetween.
【００１１】本発明は上記構成１）、すなわち透明ベー
スフイルム（Ａ）の片面上に要すれば透明リリース層を
介して、図柄印刷層を設けた透明ベースフイルム（Ａ）
の図柄印刷層を設けた側に、透明な接着性付与層を介し
て金属蒸着層を形成する構成としたので、特に多種類の
デザインで少量の需要、たとえば、高級襖、欄間、着物
、帯、衣服、木工品、プラスチック加工品、工芸品、民
芸品などの需要にも応じられ、真空中でのガス放出の多
い印刷インキの使用や、特に印刷インキの盛り上がった
捺染やスクリーン印刷が採用でき、したがってビロード
調、レザー調、シボ感のある図柄印刷も採用でき、その
上、図柄印刷と金属蒸着層などの位置関係も極めて簡単
に整合あるいは所望量ずらすことも任意にできるメタリ
ック図柄転写箔を提供することを可能としたものである
。The present invention has the above configuration 1), that is, a transparent base film (A) in which a pattern printing layer is provided on one side of the transparent base film (A) via a transparent release layer if necessary.
The metal vapor deposited layer is formed on the side with the pattern printing layer through the transparent adhesion layer, so it can be used especially in small quantities with a wide variety of designs, such as high-quality sliding doors, transoms, kimonos, and obi belts. , clothing, woodwork, plastic products, handicrafts, folk crafts, etc., and it is possible to use printing ink that releases a lot of gas in a vacuum, as well as textile printing and screen printing in which the printing ink is raised. Therefore, velvet-like, leather-like, and grained pattern printing can be used.Furthermore, the positional relationship between the pattern printing and the metal vapor deposition layer can be very easily aligned or shifted by a desired amount using metallic pattern transfer foil. This makes it possible to provide the following information.
【００１２】本発明は上記構成２）、すなわち前記の優
れたメタリック図柄転写箔を製造する方法をも提供する
もので、上記構成２）では、
手順１ 透明ベースフイルム（Ａ）の片面上に要すれ
ば透明リリース層を塗布形成し、次いで図柄印刷層を印
刷し、更に図柄印刷層に一致または一致することなく透
明ベースフイルムの全面にまたは部分的に透明な接着性
付与層を塗布形成した図柄印刷フイルム（Ａ’）を作る
。
手順２ 透明ベースフイルム（Ｂ）の片面上に要すれ
ば透明リリース層を塗布形成し、次いで全面に金属蒸着
層を蒸着形成し、更に金属蒸着層の全面に無色透明また
は有色透明な保護樹脂層を塗布形成した金属蒸着フイル
ム（Ｂ’）を作る。手順３ 手順１および手順２で作
った図柄印刷フイルム（Ａ’）と金属蒸着フイルム（Ｂ
’）とをそれぞれの透明な接着性付与層と保護樹脂層側
とを内側にして貼り合わせて後、透明ベースフイルム（
Ｂ）を剥離して、図柄印刷フイルム（Ａ’）の透明な接
着性付与層の位置する部分のみに金属蒸着フイルム（Ｂ
’）の保護樹脂層および金属蒸着層を貼り合わせる。の
構成としたので、透明ベースフイルム（Ａ）の片面上に
要すれば透明リリース層を介して、図柄印刷層を設けた
透明ベースフイルム（Ａ）の図柄印刷層を設けた側に、
透明な接着性付与層を介して金属蒸着層を形成したメタ
リック図柄転写箔を提供することを可能としたものであ
る。[0012] The present invention also provides the above configuration 2), that is, a method for manufacturing the above-mentioned excellent metallic pattern transfer foil. Then, a transparent release layer is coated and formed, then a pattern printing layer is printed, and a transparent adhesive layer is coated on the entire surface or a part of the transparent base film without matching or not matching the pattern printing layer. Make a printing film (A'). Step 2: If necessary, coat and form a transparent release layer on one side of the transparent base film (B), then form a metal vapor deposition layer on the entire surface, and then apply a colorless transparent or colored transparent protective resin layer on the entire surface of the metal vapor deposition layer. A metal evaporated film (B') is prepared by coating. Step 3 Combine the pattern printed film (A') and metallized film (B) made in Steps 1 and 2.
') and the transparent base film (
B) is peeled off and the metallized film (B) is applied only to the area where the transparent adhesion imparting layer of the pattern printed film (A') is located.
') The protective resin layer and metal vapor deposition layer are bonded together. Since the structure is as follows, the pattern printing layer is provided on one side of the transparent base film (A) via a transparent release layer if necessary, and the pattern printing layer is provided on the side of the transparent base film (A) on which the pattern printing layer is provided.
This makes it possible to provide a metallic pattern transfer foil in which a metal vapor deposition layer is formed via a transparent adhesion imparting layer.
【００１３】つぎに実施例をあげて本発明を説明する。Next, the present invention will be explained with reference to examples.
【００１４】[0014]
【実施例】本発明のメタリック図柄転写箔において用い
る透明ベースフイルム（Ａ）としては、特に制限はなく
、充分な自己保持性を有する通常の印刷に用いられるも
のであればいずれも用いられる。たとえばポリエステル
樹脂、ポリアミド樹脂、ポリアミドイミド樹脂、ポリエ
チレン樹脂、ポリプロピレン樹脂、セルロースアセテー
ト樹脂、ポリカーボネート樹脂、ポリ塩化ビニル樹脂な
どの樹脂系フイルムや、セロハン紙、グラシン紙などの
半透明のフイルム状物もしくはシート状物があげられる
。EXAMPLES The transparent base film (A) used in the metallic pattern transfer foil of the present invention is not particularly limited, and any film that has sufficient self-retention properties and is used in ordinary printing can be used. For example, resin films such as polyester resin, polyamide resin, polyamideimide resin, polyethylene resin, polypropylene resin, cellulose acetate resin, polycarbonate resin, and polyvinyl chloride resin, and translucent film-like materials or sheets such as cellophane paper and glassine paper. Items like this can be given.
【００１５】フイルム厚さとしては３〜１００μｍ、好
ましくは６〜２５μｍのものを用いるのが、しわや亀裂
などのないメタリック図柄転写箔の製造が用意にできる
点から好ましい。It is preferable to use a film having a thickness of 3 to 100 .mu.m, preferably 6 to 25 .mu.m, since it is possible to easily produce a metallic pattern transfer foil without wrinkles or cracks.
【００１６】本発明のメタリック図柄転写箔において必
要に応じて用いる透明リリース層としては、繊維素系樹
脂、メラミン系樹脂、尿素系樹脂、尿素−メラミン系樹
脂、ベンゾグアナミン系樹脂を単独またはこれらの混合
物を主成分とした樹脂塗膜があげられる。The transparent release layer used as necessary in the metallic pattern transfer foil of the present invention may be a cellulose resin, a melamine resin, a urea resin, a urea-melamine resin, or a benzoguanamine resin, singly or in a mixture thereof. Examples include resin coatings containing as the main component.
【００１７】リリース層の厚さとしては特に制限はなく
０．１〜２μｍ程度の範囲から適宜採用される。The thickness of the release layer is not particularly limited and may be appropriately selected from a range of about 0.1 to 2 μm.
【００１８】本発明のメタリック図柄転写箔において用
いる図柄印刷層として用いる印刷インキには特に制限は
なく、通常の印刷に用いられるものであればいずれも用
いられる。たとえば、アマニ油、桐油、脱水ヒマシ油な
どの乾性油、セラック、ロジン、エステルゴム、繊維素
系樹脂、メラミン系樹脂、尿素系樹脂、尿素−メラミン
系樹脂、ベンゾグアナミン系樹脂、フェノール系樹脂、
アルキッド系樹脂などの天然樹脂、合成樹脂をビヒクル
とし、これに染料顔料などの着色料、必要に応じてドラ
イーやなどを混合した印刷インキがあげられる。The printing ink used as the pattern printing layer in the metallic pattern transfer foil of the present invention is not particularly limited, and any ink that is used in normal printing can be used. For example, drying oils such as linseed oil, tung oil, dehydrated castor oil, shellac, rosin, ester rubber, cellulose resins, melamine resins, urea resins, urea-melamine resins, benzoguanamine resins, phenolic resins,
Examples include printing inks that use natural resins such as alkyd resins or synthetic resins as a vehicle, and mix them with colorants such as dyes and pigments, and if necessary, dry powder.
【００１９】図柄印刷層の厚さとしては特に制限はなく
０．１〜５００μｍ程度の範囲から適宜採用される。The thickness of the pattern printing layer is not particularly limited and may be suitably selected from a range of about 0.1 to 500 μm.
【００２０】本発明のメタリック図柄転写箔において透
明な接着性付与層に用いる接着剤としては特に制限はな
く、通常の転写箔において用いられる接着剤から適宜選
択し用いられる。たとえばポリエステル−イソシアネー
ト系の接着剤が平面から立体的な図柄印刷層に対しても
柔軟に対応できてその上、接着性にも優れているので好
ましい。また接着剤中には適宜色材が添加されたもので
あってもよい。The adhesive used in the transparent adhesion-imparting layer in the metallic pattern transfer foil of the present invention is not particularly limited, and may be appropriately selected from adhesives used in ordinary transfer foils. For example, polyester-isocyanate-based adhesives are preferred because they can be flexibly applied to planar to three-dimensional pattern printing layers and have excellent adhesive properties. Further, a coloring material may be appropriately added to the adhesive.
【００２１】透明な接着性付与層の厚さとしては特に制
限はなく０．１〜５００μｍ程度の範囲から適宜採用さ
れる。[0021] The thickness of the transparent adhesion-imparting layer is not particularly limited and may be suitably selected from a range of about 0.1 to 500 μm.
【００２２】本発明のメタリック図柄転写箔において金
属蒸着層に用いる金属としては特に制限はなく亜鉛、ア
ルミニウム、ガリウム、インジウム、錫、ニッケル、銀
、金、銅、珪素、クロム、チタン、白金、パラジウムな
どの金属単体もしくはその合金などが好ましく用いられ
る。[0022] In the metallic pattern transfer foil of the present invention, the metal used in the metal vapor deposition layer is not particularly limited, and includes zinc, aluminum, gallium, indium, tin, nickel, silver, gold, copper, silicon, chromium, titanium, platinum, and palladium. Elemental metals such as or alloys thereof are preferably used.
【００２３】金属蒸着層の厚さとしては特に制限はなく
１０〜２００ｎｍ程度の範囲から適宜採用される。The thickness of the metal vapor deposited layer is not particularly limited and may be suitably selected from a range of about 10 to 200 nm.
【００２４】本発明のメタリック図柄転写箔においては
、金属蒸着層の表面に保護層を設けてもよい。保護層を
形成するための樹脂としては、たとえばアクリル系樹脂
、塩化ビニルー酢酸ビニル共重合体、ポリビニルブチラ
ール、ポリカーボネート、ニトロセルロース、セルロー
スアセテート、ウレタン系樹脂、尿素系樹脂、メラミン
系樹脂、尿素ーメラミン系樹脂、エポキシ系樹脂、アル
キッド系樹脂、アミノアルキッド系樹脂、ロジン変性マ
レイン酸樹脂などの単独または混合物や、シランカップ
リング剤の塗膜があげられる。In the metallic pattern transfer foil of the present invention, a protective layer may be provided on the surface of the metal vapor deposited layer. Examples of the resin for forming the protective layer include acrylic resin, vinyl chloride-vinyl acetate copolymer, polyvinyl butyral, polycarbonate, nitrocellulose, cellulose acetate, urethane resin, urea resin, melamine resin, and urea-melamine resin. Examples include resins, epoxy resins, alkyd resins, aminoalkyd resins, rosin-modified maleic acid resins, etc. alone or in mixtures, and coatings with silane coupling agents.
【００２５】以下に実施例をあげて本発明をさらに具体
的に説明するが、本発明はこれらの実施例のみに限定さ
れるものではない。[0025] The present invention will be explained in more detail with reference to Examples below, but the present invention is not limited to these Examples.
【００２６】実施例１
手順１
厚さ１２μｍの透明二軸延伸ポリエチレンテレフタレー
トフイルム（Ａ）の片面にメラミン系樹脂１０部（重量
部、以下同様）、メチルイソブチルケトン−酢酸ブチル
（２：１容量比）からなる混合溶剤２０部とからなるコ
ーティング溶液を塗布乾燥して厚さ２μｍのリリース層
を形成し、次いでこのリリース層面上に通常のグラビア
印刷用インキを用いてグラビア印刷法で所望の位置に多
色の図柄印刷層を形成し、次いでこの図柄印刷層および
露出しているリリース層の面上に所望の図柄にポリエス
テル系接着剤を塗布乾燥して厚さ２μｍの透明な接着性
付与層を形成して図柄印刷フイルム（Ａ’）を得た。Example 1 Procedure 1 On one side of a transparent biaxially stretched polyethylene terephthalate film (A) with a thickness of 12 μm, 10 parts of melamine resin (parts by weight, the same applies hereinafter) and methyl isobutyl ketone-butyl acetate (2:1 volume ratio) were applied. ) is coated and dried to form a release layer with a thickness of 2 μm.Next, a coating solution consisting of 20 parts of a mixed solvent consisting of A multicolor pattern printing layer is formed, and then a polyester adhesive is applied to the desired pattern on the surface of the pattern printing layer and the exposed release layer and dried to form a transparent adhesion imparting layer with a thickness of 2 μm. A pattern printed film (A') was obtained.
【００２７】手順２
一方、厚さ１２μｍの透明二軸延伸ポリエチレンテレフ
タレートフイルム（Ｂ）の片面にはメラミン系樹脂１０
部、メチルイソブチルケトン−酢酸ブチル（２：１容量
比）からなる混合溶剤２０部とからなるコーティング溶
液を塗布乾燥して厚さ２μｍのリリース層を形成し、次
いでこのリリース層面上にアルミニウム蒸着層を抵抗加
熱真空蒸着法で厚さ８０ｎｍに蒸着し形成し、次いでア
クリル樹脂３０部、アミノ樹脂１０部、ニトロセルロー
ス５部、トルエン２５部、メチルエチルケトン２５部、
シクロヘキサノン５部を混合した無色透明保護樹脂層を
形成して金属蒸着フイルム（Ｂ’）を得た。Step 2 On the other hand, on one side of the transparent biaxially stretched polyethylene terephthalate film (B) with a thickness of 12 μm, melamine resin 10
A coating solution consisting of 20 parts of a mixed solvent of methyl isobutyl ketone and butyl acetate (2:1 volume ratio) was coated and dried to form a release layer with a thickness of 2 μm, and then an aluminum vapor-deposited layer was formed on the surface of the release layer. was deposited to a thickness of 80 nm using a resistance heating vacuum deposition method, and then 30 parts of acrylic resin, 10 parts of amino resin, 5 parts of nitrocellulose, 25 parts of toluene, 25 parts of methyl ethyl ketone,
A colorless transparent protective resin layer containing 5 parts of cyclohexanone was formed to obtain a metallized film (B').
【００２８】手順３
次いで手順１で得られたフイルム（Ａ’）の透明な接着
性付与層側と手順２で得られたフイルム（Ｂ’）の保護
樹脂層側とを重ね合わせて熱圧着して貼り合せた後、透
明ベースフイルム（Ｂ）を剥離して、図柄印刷フイルム
（Ａ’）の透明な接着性付与層の位置する部分のみに金
属蒸着フイルム（Ｂ’）の保護樹脂層および金属蒸着層
を貼り合わせて本発明のメタリック図柄転写箔を得た。Step 3 Next, the transparent adhesive layer side of the film (A') obtained in Step 1 and the protective resin layer side of the film (B') obtained in Step 2 are overlapped and thermocompressed. After lamination, the transparent base film (B) is peeled off, and the protective resin layer and metal of the metallized film (B') are applied only to the area where the transparent adhesive layer of the pattern printing film (A') is located. The metallic pattern transfer foil of the present invention was obtained by bonding the vapor-deposited layers together.
【００２９】実施例２
実施例１で得た本発明のメタリック図柄転写箔のフイル
ム（Ａ）の反対面（転写層側）上にポリウレタン系接着
剤を塗布乾燥して厚さ３μｍの接着剤層を形成して接着
剤層を有する本発明のメタリック図柄転写箔を得た。Example 2 A polyurethane adhesive was applied on the opposite side (transfer layer side) of the film (A) of the metallic pattern transfer foil of the present invention obtained in Example 1 and dried to form an adhesive layer with a thickness of 3 μm. A metallic pattern transfer foil of the present invention having an adhesive layer was obtained.
【００３０】[0030]
【発明の効果】本発明によるメタリック図柄転写箔およ
びその製法を用いれば、特に多種類のデザインで少量の
需要、たとえば、高級襖、欄間、着物、帯、衣服、木工
品、プラスチック加工品、工芸品、民芸品などの需要に
も応じられ、真空中でのガス放出の多い印刷インキの使
用や、特に印刷インキの盛り上がった捺染やスクリーン
印刷が採用でき、したがってビロード調、レザー調、シ
ボ感のある図柄印刷も採用でき、その上、図柄印刷と金
属蒸着層などの位置関係も極めて簡単に整合あるいは所
望量ずらすことも任意にできるメタリック図柄転写箔が
得られる。[Effects of the Invention] By using the metallic pattern transfer foil and its manufacturing method according to the present invention, it can be used especially in small quantities with a wide variety of designs, such as high-grade sliding doors, transoms, kimonos, obi, clothing, woodwork, plastic processed products, and crafts. In order to meet the demand for goods, folk crafts, etc., it is possible to use printing inks that release a lot of gas in a vacuum, and especially textile printing and screen printing with raised printing inks. A metallic pattern transfer foil can be obtained in which a certain pattern can be printed, and the positional relationship between the pattern printing and the metal vapor deposition layer can be very easily aligned or shifted by a desired amount.
Claims (3)
要すれば透明リリース層を介して、図柄印刷層を設けた
透明ベースフイルム（Ａ）の図柄印刷層を設けた側に、
透明な接着性付与層を介して金属蒸着層を形成したこと
を特徴とするメタリック図柄転写箔。1. A transparent base film (A) with a pattern printing layer provided on one side of the transparent base film (A), if necessary via a transparent release layer, on the side on which the pattern printing layer is provided,
A metallic pattern transfer foil characterized in that a metal vapor deposition layer is formed through a transparent adhesion imparting layer.
要すれば透明リリース層を介して、図柄印刷層を設けた
透明ベースフイルム（Ａ）の図柄印刷層を設けた側に、
透明な接着性付与層を介して金属蒸着層を形成したメタ
リック図柄転写箔が、下記の手順によって作られている
ことを特徴とするメタリック図柄転写箔の製造方法。 手順１ 透明ベースフイルム（Ａ）の片面上に要すれ
ば透明リリース層を塗布形成し、次いで図柄印刷層を印
刷し、更に図柄印刷層に一致または一致することなく透
明ベースフイルムの全面にまたは部分的に透明な接着性
付与層を塗布形成した図柄印刷フイルム（Ａ’）を作る
。 手順２ 透明ベースフイルム（Ｂ）の片面上に要すれ
ば透明リリース層を塗布形成し、次いで全面に金属蒸着
層を蒸着形成し、更に金属蒸着層の全面に無色透明また
は有色透明な保護樹脂層を塗布形成した金属蒸着フイル
ム（Ｂ’）を作る。 手順３ 手順１および手順２で作った図柄印刷フイル
ム（Ａ’）と金属蒸着フイルム（Ｂ’）とをそれぞれの
透明な接着性付与層側と保護樹脂層側とを内側にして貼
り合わせて後、透明ベースフイルム（Ｂ）を剥離して、
図柄印刷フイルム（Ａ’）の透明な接着性付与層の位置
する部分のみに金属蒸着フイルム（Ｂ’）の保護樹脂層
および金属蒸着層を貼り合わせる。2. A pattern printing layer is provided on one side of the transparent base film (A), if necessary via a transparent release layer, on the side on which the pattern printing layer is provided, of the transparent base film (A),
A method for manufacturing a metallic pattern transfer foil, characterized in that the metallic pattern transfer foil is produced by the following procedure, in which a metal vapor deposited layer is formed via a transparent adhesion imparting layer. Step 1: Coat and form a transparent release layer on one side of the transparent base film (A) if necessary, then print a pattern printing layer, and then print on the entire surface or part of the transparent base film without matching or not matching the pattern printing layer. A pattern printing film (A') is prepared by coating a transparent adhesive layer. Step 2: If necessary, coat and form a transparent release layer on one side of the transparent base film (B), then form a metal vapor deposition layer on the entire surface, and then apply a colorless transparent or colored transparent protective resin layer on the entire surface of the metal vapor deposition layer. A metal evaporated film (B') is prepared by coating. Step 3 After laminating the pattern printed film (A') and metallized film (B') made in Steps 1 and 2 with their respective transparent adhesion layer sides and protective resin layer sides facing inside. , peel off the transparent base film (B),
The protective resin layer and the metal vapor deposited layer of the metal vapor deposited film (B') are bonded to only the portion of the pattern printed film (A') where the transparent adhesion imparting layer is located.
イルム（Ａ）と反対面（転写層側）に全面または部分的
に接着剤層が設けられてなる請求項１および請求項２記
載の転写箔。 【０００１】3. The transfer foil according to claim 1, wherein an adhesive layer is provided entirely or partially on the surface of the metallic pattern transfer foil opposite to the transparent base film (A) (transfer layer side). 0001
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP16360791A JPH04361099A (en) | 1991-06-07 | 1991-06-07 | Metallic design pattern transfer foil and manufacture thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP16360791A JPH04361099A (en) | 1991-06-07 | 1991-06-07 | Metallic design pattern transfer foil and manufacture thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH04361099A true JPH04361099A (en) | 1992-12-14 |
Family
ID=15777148
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP16360791A Pending JPH04361099A (en) | 1991-06-07 | 1991-06-07 | Metallic design pattern transfer foil and manufacture thereof |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH04361099A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2008023896A (en) * | 2006-07-24 | 2008-02-07 | Nissha Printing Co Ltd | Sheet for simultaneously molding and decorating, and method for manufacturing the same |
-
1991
- 1991-06-07 JP JP16360791A patent/JPH04361099A/en active Pending
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2008023896A (en) * | 2006-07-24 | 2008-02-07 | Nissha Printing Co Ltd | Sheet for simultaneously molding and decorating, and method for manufacturing the same |
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