JPH0433320B2 - - Google Patents
Info
- Publication number
- JPH0433320B2 JPH0433320B2 JP61311695A JP31169586A JPH0433320B2 JP H0433320 B2 JPH0433320 B2 JP H0433320B2 JP 61311695 A JP61311695 A JP 61311695A JP 31169586 A JP31169586 A JP 31169586A JP H0433320 B2 JPH0433320 B2 JP H0433320B2
- Authority
- JP
- Japan
- Prior art keywords
- weight
- formula
- water
- liquid detergent
- detergent composition
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 13
- 239000000203 mixture Substances 0.000 claims description 12
- 239000003599 detergent Substances 0.000 claims description 7
- 239000004816 latex Substances 0.000 claims description 7
- 229920000126 latex Polymers 0.000 claims description 7
- 239000007788 liquid Substances 0.000 claims description 7
- 239000002245 particle Substances 0.000 claims description 5
- 230000000844 anti-bacterial effect Effects 0.000 claims description 4
- 229920000642 polymer Polymers 0.000 claims description 4
- 239000003899 bactericide agent Substances 0.000 claims description 2
- 239000004094 surface-active agent Substances 0.000 claims description 2
- 239000002253 acid Chemical group 0.000 claims 1
- 125000000217 alkyl group Chemical group 0.000 claims 1
- 125000004432 carbon atom Chemical group C* 0.000 claims 1
- 125000000753 cycloalkyl group Chemical group 0.000 claims 1
- 229910052736 halogen Inorganic materials 0.000 claims 1
- 150000002367 halogens Chemical group 0.000 claims 1
- 125000000623 heterocyclic group Chemical group 0.000 claims 1
- 125000000592 heterocycloalkyl group Chemical group 0.000 claims 1
- 229910052739 hydrogen Inorganic materials 0.000 claims 1
- 239000001257 hydrogen Substances 0.000 claims 1
- 125000004435 hydrogen atom Chemical class [H]* 0.000 claims 1
- 125000004433 nitrogen atom Chemical group N* 0.000 claims 1
- 125000000547 substituted alkyl group Chemical group 0.000 claims 1
- 235000019645 odor Nutrition 0.000 description 9
- 238000005406 washing Methods 0.000 description 8
- 238000004140 cleaning Methods 0.000 description 4
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 3
- 208000008454 Hyperhidrosis Diseases 0.000 description 3
- 230000018044 dehydration Effects 0.000 description 3
- 238000006297 dehydration reaction Methods 0.000 description 3
- 238000001035 drying Methods 0.000 description 3
- 208000013460 sweaty Diseases 0.000 description 3
- 239000008399 tap water Substances 0.000 description 3
- 235000020679 tap water Nutrition 0.000 description 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 2
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 description 2
- 239000000645 desinfectant Substances 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 239000000178 monomer Substances 0.000 description 2
- -1 polyoxyethylene Polymers 0.000 description 2
- 108091064702 1 family Proteins 0.000 description 1
- CMCBDXRRFKYBDG-UHFFFAOYSA-N 1-dodecoxydodecane Chemical compound CCCCCCCCCCCCOCCCCCCCCCCCC CMCBDXRRFKYBDG-UHFFFAOYSA-N 0.000 description 1
- DPBJAVGHACCNRL-UHFFFAOYSA-N 2-(dimethylamino)ethyl prop-2-enoate Chemical compound CN(C)CCOC(=O)C=C DPBJAVGHACCNRL-UHFFFAOYSA-N 0.000 description 1
- QMYCJCOPYOPWTI-UHFFFAOYSA-N 2-[(1-amino-1-imino-2-methylpropan-2-yl)diazenyl]-2-methylpropanimidamide;hydron;chloride Chemical compound Cl.NC(=N)C(C)(C)N=NC(C)(C)C(N)=N QMYCJCOPYOPWTI-UHFFFAOYSA-N 0.000 description 1
- 240000005109 Cryptomeria japonica Species 0.000 description 1
- 238000007664 blowing Methods 0.000 description 1
- 125000002091 cationic group Chemical group 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000012459 cleaning agent Substances 0.000 description 1
- 229910001873 dinitrogen Inorganic materials 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000007730 finishing process Methods 0.000 description 1
- 230000009477 glass transition Effects 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- GSGDTSDELPUTKU-UHFFFAOYSA-N nonoxybenzene Chemical compound CCCCCCCCCOC1=CC=CC=C1 GSGDTSDELPUTKU-UHFFFAOYSA-N 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 125000001302 tertiary amino group Chemical group 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
Description
〔産業上の利用分野〕
本発明は液体洗浄剤組成物、更に詳細には衣類
への殺菌性および抗菌性に優れた液体洗浄剤組成
物に関する。
〔従来の技術及びその問題点〕
従来、家庭における洗濯は、洗浄、すすぎ、脱
水、乾燥の行程よりなり、これを経て汚れた衣類
の再生が成されている。一般的に洗浄には水道水
或いは風呂の残り湯を、すすぎには水道水を使用
し、乾燥は太陽光照射の下に行なわれることが理
想的であるとされ、これをもつて衛生的にも問題
無く仕上げることが可能となる。
しかしながら、必らずしも斯かる理想的な状況
で洗濯が出来るとは限らず、洗濯したにもかかわ
らず、汗くささが残つてしまつたり、或いは湿つ
たまま放置していた為に汗くささが発生してしま
うような問題が生じている。例えば、雨天の為、
不十分な乾燥のままでとり込みタンス等へ収納し
た場合とか、最も著しい例としては洗濯機の脱水
槽に入れたまで、外出等の理由で、しばらく放置
した後に乾燥した場合に汗くささ等の異臭が発生
しやすい。更にまた、高温多湿な夏季において、
使つたままでおいた雑巾、タオル等が異臭を発
し、使用に当つて不快感を受けることがしばしば
生じていた。
〔問題点を解決するための手段〕
斯かる実状において、本発明者らは、理想的な
洗濯・仕上げ行程を経なかつた場合、即ち衣類を
湿つた状態で長時間放置した場合においても、乾
燥後に異臭が発生せず、かつ清潔に仕上げること
が出きる洗浄剤を得べく鋭意研究した結果、カチ
オン性基又は３級アミノ基を有する高分子ラテツ
クスと殺菌剤を併用すれば、上記目的を達成する
ことが出来ることを見い出し、本発明を完成し
た。
すなわち本発明は次の３成分(a)，(b)および(c)、
(a) 界面活性剤 ５〜50重量％
(b) 次の一般式（）又は（）
[Industrial Field of Application] The present invention relates to a liquid detergent composition, and more particularly to a liquid detergent composition that has excellent bactericidal and antibacterial properties for clothing. [Prior Art and its Problems] Conventionally, washing at home consists of the steps of washing, rinsing, spin-drying, and drying, and soiled clothes are recycled through these steps. In general, it is said that it is ideal to use tap water or leftover hot water from a bath for cleaning, tap water for rinsing, and drying under sunlight. can be completed without any problem. However, it is not always possible to wash clothes under such ideal conditions, and even after washing, the clothes may still be sweaty or sweaty because they have been left damp. There is a problem that occurs. For example, due to rainy weather,
If the clothes are left in a dryer and stored in a drawer, etc., or in the most extreme case, they are left in the dehydration tank of a washing machine, or for reasons such as going out, the clothes may become sweaty and dry after being left for a while. Unusual odors are likely to occur. Furthermore, in the hot and humid summer,
Wipes, towels, etc. that have been left unused emit a strange odor, which often causes discomfort when used. [Means for Solving the Problems] Under such circumstances, the inventors of the present invention have proposed that even if the ideal washing/finishing process is not performed, that is, if the clothes are left damp for a long time, they will not dry properly. As a result of intensive research to create a cleaning agent that does not produce a foreign odor and leaves a clean finish, we found that the above objective can be achieved by using a polymer latex with cationic or tertiary amino groups in combination with a disinfectant. They discovered that it is possible to do this and completed the present invention. That is, the present invention comprises the following three components (a), (b) and (c), (a) surfactant 5 to 50% by weight, (b) the following general formula () or ()
本発明の液体洗浄剤組成物で洗浄すれば、理想
的な条件下で洗浄・仕上げ行程が成されなくて
も、使用後の異臭の発生を大巾に抑制することが
出来る。例えば、ススギ行程を風呂の残り湯で行
なつた場合には、通常の洗剤では洗濯の直後には
さほど異臭は感じなくとも放置すると異臭を発す
る様になるが、本発明液体洗浄剤組成物を使用す
ることにより、この異臭を抑えることが可能とな
る。また、水道水でのススギをし、脱水槽中に長
く放置した後に、雨天等の理由により室内で竿乾
燥した場合、手ふきタオルを繰返し使用する場合
あるいは雑巾を繰返し使用する場合にも効果的に
異臭を抑えることが可能である。
〔実施例〕
次に参考例及び実施例を挙げて本発明を更に詳
しく説明する。
参考例 １
（） 攪拌機付きセパラブルフラスコに水343
ｇ、ポリオキシエチレン（35）ノニルフエニル
エーテル21ｇ及び２，2′−アゾビス（２−アミ
ジノプロパン）塩酸塩0.8ｇを水８ｇに溶解し
た液を仕込み、窒素で充分置換した。次いで窒
素ガスを吹き込んで攪拌しながら62℃に加温
し、ｎ−ブチルアクリレート97ｇ及びＮ−
N′−ジメチルアミノエチルアクリレート３ｇ
を約２時間を要して滴下し、更に７時間重合を
おこなつた。反応終了後冷却し、200メツシユ
の金網で過しラテツクスＡ（ｎ−ブチルアク
リレート／ジメチルアミノエチルアクリレート
＝97／３、残存モノマー量は300ppm）を得た。
（） （）で得たラテツクスＡを90℃で４時
間水蒸気蒸留し、残存モノマー量40ppmの精製
ラテツクスＡ（重量平均粒子径0.07μ、粒子径が
0.005〜0.2μのものは全体の100％；ガラス転位
温度217°K）を得た。
実施例 １
家族４人（男38才、女35才、男８才、女６才）
が入浴した風呂の残り湯を、洗濯水及びススギ水
として下記の試験を行なつた。
（組成）
ポリオキシエチレンア（EO付加モル数9.8）ラ
ウリルエーテル 20（％）
精製ラテツクスＡ ０又は３
エタノール 10
殺菌剤（第１表） ０又は0.01
水 バランス
（試験方法）
第１表に示す各種殺菌剤を添加した、上記組成
の液体洗浄剤組成物を製造し、それぞれの１％溶
液２中で新しいタオルを10回もみ洗した。次い
でよく水をしぼり、新しく２の風呂残り湯を入
れて同様に10回、もみすすぎを行ない、よく水を
しぼつた後、再度同様の操作を繰り返した。更に
洗濯機の脱水槽を用いて脱水し、温度20℃、湿度
65％の恒温室で24時間放置・乾燥した。斯くして
得られた処理タオルをビニール袋に入れ、30℃に
て２日間放置し、その臭いを３人のパネラー（女
30才、女25才、男31才）にて判定した。その結果
を第１表に示す。
By cleaning with the liquid cleaning composition of the present invention, it is possible to greatly suppress the occurrence of unpleasant odors after use, even if the cleaning and finishing steps are not performed under ideal conditions. For example, when the Susugi process is carried out with leftover bath water, with ordinary detergents, even if you do not notice much of an odor immediately after washing, it will start to emit an odor when left unused, but when using the liquid detergent composition of the present invention, By using it, it is possible to suppress this unpleasant odor. It is also effective when the rod is dried indoors due to rain or other reasons after rinsing it with tap water and leaving it in the dehydration tank for a long time, or when the hand towel is repeatedly used, or when the rag is used repeatedly. It is possible to suppress unpleasant odors. [Example] Next, the present invention will be described in more detail with reference to Reference Examples and Examples. Reference example 1 () 343 ml of water in a separable flask with a stirrer
A solution prepared by dissolving 21 g of polyoxyethylene (35) nonylphenyl ether and 0.8 g of 2,2'-azobis(2-amidinopropane) hydrochloride in 8 g of water was charged, and the mixture was sufficiently purged with nitrogen. Next, the mixture was heated to 62°C while blowing nitrogen gas and stirring, and 97 g of n-butyl acrylate and N-
N'-dimethylaminoethyl acrylate 3g
was added dropwise over a period of about 2 hours, and polymerization was continued for an additional 7 hours. After the reaction was completed, it was cooled and filtered through a 200-mesh wire mesh to obtain latex A (n-butyl acrylate/dimethylaminoethyl acrylate = 97/3, residual monomer amount: 300 ppm). () The latex A obtained in () was steam-distilled at 90°C for 4 hours to obtain purified latex A with a residual monomer content of 40 ppm (weight average particle size 0.07μ, particle size
0.005 to 0.2μ (100% of the total; glass transition temperature 217°K) was obtained. Example 1 Family of 4 (male 38 years old, female 35 years old, male 8 years old, female 6 years old)
The following tests were conducted using the remaining hot water from the bath in which the subjects had taken a bath as washing water and Japanese cedar water. (Composition) Polyoxyethylene (EO addition moles 9.8) Lauryl ether 20 (%) Purified latex A 0 or 3 Ethanol 10 Bactericide (Table 1) 0 or 0.01 Water Balance (Test method) Various types shown in Table 1 A liquid detergent composition of the above composition with added disinfectant was prepared and fresh towels were massaged 10 times in each 1% solution 2. Next, the water was thoroughly wrung out, and the remaining bath water from step 2 was poured in, and the same process was repeated 10 times. After rinsing the water thoroughly, the same operation was repeated. Furthermore, the water is dehydrated using the dehydration tank of the washing machine, and the temperature and humidity are 20°C.
It was left to dry for 24 hours in a 65% temperature room. The treated towel thus obtained was placed in a plastic bag and left at 30°C for 2 days, and the odor was evaluated by three panelists (female).
30 years old, female 25 years old, male 31 years old). The results are shown in Table 1.
【表】【table】
Claims (1)
アルキル基若しくは置換アルキル基又は水素であ
り、三者は同一でも異なつていてもよく、又は三
者のうち二者が連結して隣接する窒素原子と共に
複素環、シクロアルキル基、ヘテロシクロアルキ
ル基を形成してもよく、Ｙはハロゲンまたは酸残
基を示す） で表わされるカチオン性基又は３級アミノ基を有
する高分子ラテツクスを高分子として
0.01〜10重量％ (c) 水に不溶性又は難溶性の殺菌剤
0.001〜５重量％ を含有することを特徴とする衣料用液体洗浄剤組
成物。 ２ 高分子ラテツクスの平均粒子径（重量平均）
が0.005〜0.2μｍで、かつ粒子径0.005〜0.2μｍの
ものが全体の95重量％以上である特許請求の範囲
第１項記載の衣料用液体洗浄剤組成物。[Scope of Claims] 1. The following three components (a), (b) and (c) (a) Surfactant 5 to 50% by weight (b) The following general formula () or () [Formula] [Formula ] (In the formula, R 1 , R 2 and R 3 are an alkyl group or substituted alkyl group having 1 to 18 carbon atoms, or hydrogen, and the three groups may be the same or different, or two of the three groups may be the same or different. may be linked together to form a heterocycle, cycloalkyl group, or heterocycloalkyl group together with adjacent nitrogen atoms, and Y represents a halogen or an acid residue). Polymer latex as a polymer
0.01-10% by weight (c) Bactericide insoluble or sparingly soluble in water
A liquid detergent composition for clothing, characterized in that it contains 0.001 to 5% by weight. 2 Average particle diameter of polymer latex (weight average)
2. The liquid detergent composition for clothing according to claim 1, wherein the composition has a particle size of 0.005 to 0.2 μm, and 95% by weight or more of the total particle size is 0.005 to 0.2 μm.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP31169586A JPS63162799A (en) | 1986-12-26 | 1986-12-26 | Liquid detergent composition |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP31169586A JPS63162799A (en) | 1986-12-26 | 1986-12-26 | Liquid detergent composition |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS63162799A JPS63162799A (en) | 1988-07-06 |
| JPH0433320B2 true JPH0433320B2 (en) | 1992-06-02 |
Family
ID=18020351
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP31169586A Granted JPS63162799A (en) | 1986-12-26 | 1986-12-26 | Liquid detergent composition |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS63162799A (en) |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2001064785A (en) * | 1999-08-25 | 2001-03-13 | The Inctec Inc | Draining agent |
| JP5677102B2 (en) * | 2011-01-19 | 2015-02-25 | ライオン株式会社 | Bleaching composition and washing method using the same |
| US10435652B2 (en) | 2014-02-14 | 2019-10-08 | Lonza Ltd. | Liquid laundry detergent composition for clothing |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS58152806A (en) * | 1982-02-16 | 1983-09-10 | ロレアル | Hair, skin or nail treatment composition |
-
1986
- 1986-12-26 JP JP31169586A patent/JPS63162799A/en active Granted
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS58152806A (en) * | 1982-02-16 | 1983-09-10 | ロレアル | Hair, skin or nail treatment composition |
Also Published As
| Publication number | Publication date |
|---|---|
| JPS63162799A (en) | 1988-07-06 |
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