JPH04303909A - Resin molded electronic component - Google Patents

Resin molded electronic component

Info

Publication number
JPH04303909A
JPH04303909A JP3068193A JP6819391A JPH04303909A JP H04303909 A JPH04303909 A JP H04303909A JP 3068193 A JP3068193 A JP 3068193A JP 6819391 A JP6819391 A JP 6819391A JP H04303909 A JPH04303909 A JP H04303909A
Authority
JP
Japan
Prior art keywords
resin
silver
conductive paste
electronic component
lead terminals
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP3068193A
Other languages
Japanese (ja)
Inventor
Masaharu Yoshinaga
吉長 雅治
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
NEC Corp
Original Assignee
NEC Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by NEC Corp filed Critical NEC Corp
Priority to JP3068193A priority Critical patent/JPH04303909A/en
Publication of JPH04303909A publication Critical patent/JPH04303909A/en
Pending legal-status Critical Current

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22FWORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
    • B22F1/00Metallic powder; Treatment of metallic powder, e.g. to facilitate working or to improve properties
    • B22F1/05Metallic powder characterised by the size or surface area of the particles
    • B22F1/052Metallic powder characterised by the size or surface area of the particles characterised by a mixture of particles of different sizes or by the particle size distribution

Landscapes

  • Conductive Materials (AREA)

Abstract

PURPOSE:To prevent a fine crack from being produced in an element by a heat shock at a soldering operation by a method wherein a conductive paste composed of a thermoset resin containing a metal powder which is composed of silver or of an alloy of silver and palladium is applied and formed as an external electrode and a lead terminal is connected and hardened simultaneously. CONSTITUTION:A laminated ceramic capactor element 10 which has been formed by cutting and baking a laminated sheet in which a dielectric 1 and an internal electrode 2 have been laminated and thermocompression-bonded has dimensions of 2.5X5.6X1.2mm. The element 10 is coated with a conductive paste using a thermoset resin in such a way that lead terminals 4 sandwich the lengthwise direction of the element 10 and that the lead terminals 4 and revealed end parts of the internal electrode for the element 10 are wrapped. The paste is hardened by using a drier; external electrodes 3 are formed. The conductive paste using said thermoset resin is manufactured in the following manner: a silver powder having a particle size of 1 to 3mum and a scale-shaped silver powder having a long diameter of 10 to 25mum are mixed in the weight ratio of 1:1 to form a silver powder; the silver powder, is mixed with an epoxy resin in the weight ratio of 7:3; and this mixture is kneaded by using a three-roll mill.

Description

【発明の詳細な説明】[Detailed description of the invention]

【0001】0001

【産業上の利用分野】本発明は樹脂外装型電子部品に関
し、特に内部素子の外部電極の形成及びリード端子の接
続に関する。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to resin-clad electronic components, and more particularly to the formation of external electrodes of internal elements and the connection of lead terminals.

【0002】0002

【従来の技術】従来の樹脂外装型電子部品について図面
により説明する。図2は従来の樹脂外装型電子部品の平
断面図およびこれに用いる素子の斜視図である。これら
従来例は積層セラミックコンデンサの場合を例として示
している。
2. Description of the Related Art A conventional resin-clad electronic component will be explained with reference to the drawings. FIG. 2 is a plan cross-sectional view of a conventional resin-clad electronic component and a perspective view of an element used therein. These conventional examples are exemplified by multilayer ceramic capacitors.

【0003】図2(b)に示す如く、誘電体1と内部電
極2を積層し熱圧着したのち切断して焼成した積層セラ
ミックコンデンサ素子20(以後素子20と略称)を形
成する。次に図2(a)に示す如く、内部電極の露出し
た相対向する2つの端面に導電性ペーストを塗布し60
0℃〜800℃の温度で焼成し外部電極23を形成する
。この導電性ペーストは、銀や銀とパラジウムの金属粉
末とガラスフリットと有機溶剤と樹脂を混合し三本ロー
ルミルで混練して製造される。
As shown in FIG. 2(b), a multilayer ceramic capacitor element 20 (hereinafter abbreviated as element 20) is formed by laminating a dielectric 1 and an internal electrode 2, bonding them by thermocompression, cutting and firing. Next, as shown in FIG. 2(a), a conductive paste is applied to the two exposed end surfaces of the internal electrodes facing each other.
The external electrode 23 is formed by firing at a temperature of 0° C. to 800° C. This conductive paste is produced by mixing silver or silver and palladium metal powder, glass frit, an organic solvent, and a resin, and kneading the mixture in a three-roll mill.

【0004】次に素子20の相対向する外部電極23を
リード端子24ではさみ半田26で半田付けし素子20
とリード端子24を接続、固定し全体を外装樹脂25で
被覆し樹脂外装型電子部品とする。
Next, the opposing external electrodes 23 of the element 20 are sandwiched between the lead terminals 24 and soldered with solder 26, and the element 20
and lead terminals 24 are connected and fixed, and the whole is covered with an exterior resin 25 to form a resin-clad electronic component.

【0005】[0005]

【発明が解決しようとする課題】上述した従来の樹脂外
装型電子部品は、リード端子とチップを半田付けによっ
て接続するため、積層セラミックコンデンサのように半
田付け時の熱ショックにより素子に微細なクラックが発
生することがあった。微細なクラックが発生したものは
、通常の電気的な検査では除去できないものが多く、さ
らに市場で使用中に信頼性が低下しショート等の不良に
至るものがあるという問題点があった。
[Problems to be Solved by the Invention] In the conventional resin-clad electronic components described above, the lead terminals and the chip are connected by soldering, so that, like multilayer ceramic capacitors, thermal shock during soldering causes minute cracks in the element. sometimes occurred. Many of the products with minute cracks cannot be removed by ordinary electrical inspection, and there are also problems in that some products deteriorate in reliability during use on the market, leading to defects such as short circuits.

【0006】本発明の目的は、半田付け時の熱ショック
による素子の微細なクラックの発生を防ぎ、素子の微細
なクラックによる信頼性の低下を防ぐことが出来、かつ
安価な生産設備で対応できる樹脂外装型電子部品を提供
することにある。
An object of the present invention is to prevent the occurrence of minute cracks in an element due to thermal shock during soldering, to prevent a decrease in reliability due to minute cracks in the element, and to be able to cope with the problem using inexpensive production equipment. Our objective is to provide resin-clad electronic components.

【0007】[0007]

【課題を解決するための手段】本発明の樹脂外装型電子
部品は、内部電極端面を露出した2つの端面に外部電極
を被着形成したうえ、前記外部電極上にリード端子を固
着接続し全体を絶縁性樹脂で被覆してなる樹脂外装型電
子部品において、前記外部電極として銀又は、銀とパラ
ジウムの合金からなる金属粉末を含む熱硬化性の樹脂か
らなる導電性ペーストを被着形成し同時にリード端子を
接続し硬化させることにより構成される。
[Means for Solving the Problems] In the resin-clad electronic component of the present invention, external electrodes are adhered to two end surfaces of which the internal electrode end surfaces are exposed, and lead terminals are firmly connected to the external electrodes. In a resin-clad electronic component formed by coating with an insulating resin, a conductive paste made of a thermosetting resin containing metal powder made of silver or an alloy of silver and palladium is deposited as the external electrode, and at the same time. It is constructed by connecting lead terminals and curing them.

【0008】[0008]

【実施例】次に本発明について図面を参照して説明する
。図1は本発明の一実施例の樹脂外装型電子部品の平断
面図、およびこれに用いる素子の斜視図である。
DESCRIPTION OF THE PREFERRED EMBODIMENTS Next, the present invention will be explained with reference to the drawings. FIG. 1 is a plan cross-sectional view of a resin-clad electronic component according to an embodiment of the present invention, and a perspective view of an element used therein.

【0009】図1において、1は誘電体、2は内部電極
、10は積層セラミックコンデンサ素子、3は金属粉末
を含む熱硬化樹脂からなる導電性ペーストを被着形成し
た外部電極、4はリード端子、5は外装樹脂である。
In FIG. 1, 1 is a dielectric, 2 is an internal electrode, 10 is a multilayer ceramic capacitor element, 3 is an external electrode coated with a conductive paste made of a thermosetting resin containing metal powder, and 4 is a lead terminal. , 5 is an exterior resin.

【0010】図1(b)に示す如く、誘電体1と内部電
極2とを積層し、熱圧着した積層板を切断し焼成して形
成した積層セラミックコンデンサ素子10(以後素子1
0と略称)は、本実施例の場合おおよそ2.5mm×5
.6mm×1.2mmの大きさを有する。この素子10
にリード端子4を素子10の長手方向をはさみリード端
子4と素子10の内部電極の露出した端部を包むように
熱硬化性樹脂を用いた導電性ペーストを塗布し、乾燥機
において150℃で30分硬化させ、外部電極3を形成
した。
As shown in FIG. 1(b), a multilayer ceramic capacitor element 10 (hereinafter referred to as element 1) is formed by laminating a dielectric 1 and an internal electrode 2, and cutting and firing a laminate plate which is bonded by thermocompression.
0) is approximately 2.5 mm x 5 in this example.
.. It has a size of 6 mm x 1.2 mm. This element 10
Apply a conductive paste using a thermosetting resin so as to sandwich the lead terminals 4 in the longitudinal direction of the element 10 and wrap the exposed ends of the lead terminals 4 and the internal electrodes of the element 10, and dry in a dryer at 150°C for 30 minutes. After curing, external electrodes 3 were formed.

【0011】熱硬化性樹脂を用いた導電性ペーストは、
粒径1〜3μmの銀粉末と長径10〜25μmの燐片状
の銀粉末を重量比1:1で混合した銀粉末とエポキシ樹
脂を重量比7:3で混合し、それを三本ロールミルで混
練して製造した。
[0011] The conductive paste using thermosetting resin is
Silver powder with a particle size of 1 to 3 μm and scaly silver powder with a major diameter of 10 to 25 μm were mixed at a weight ratio of 1:1, and an epoxy resin was mixed at a weight ratio of 7:3, and then mixed in a three-roll mill. Manufactured by kneading.

【0012】次に全体をエポキシなどの硬化性の外装樹
脂5で絶縁外装して本発明の樹脂外装型電子部品を得た
Next, the whole was insulated and covered with a hardening resin 5 such as epoxy to obtain a resin-covered electronic component of the present invention.

【0013】次に本発明実施例の樹脂外装型電子部品と
図2(a)に示す従来例の樹脂外装型電子部品について
電気的特性(静電容量,誘電損失)及びリード端子の引
っ張り強度を比較したが表1に示すように本発明の樹脂
外装型電子部品は従来例と同等の性能を有することが確
認された。なお何れの値も試験数の平均値で示した。
Next, the electrical characteristics (capacitance, dielectric loss) and tensile strength of the lead terminals were evaluated for the resin-clad electronic component according to the embodiment of the present invention and the conventional resin-clad electronic component shown in FIG. 2(a). A comparison was made, and as shown in Table 1, it was confirmed that the resin-clad electronic component of the present invention had performance equivalent to that of the conventional example. All values are shown as the average value of the number of tests.

【0014】[0014]

【0015】次に第二の実施例として粒径3〜6μmの
銀パラジウム合金粉末(銀:パラジウム=90:10)
とエポキシ樹脂を重量比7:3で混合し三本ロールミル
で混練して製造した導電ペーストで、素子10の内部電
極の露出した端部と素子10の長手方向をはさんだリー
ド端子4を包むように塗布し、乾燥機において150℃
で30分硬化させ、全体をエポキシ樹脂で絶縁外装して
樹脂外装型電子部品を得た。
Next, as a second example, silver-palladium alloy powder (silver: palladium = 90:10) with a particle size of 3 to 6 μm was used.
A conductive paste manufactured by mixing and epoxy resin at a weight ratio of 7:3 and kneading in a three-roll mill is used to wrap the exposed end of the internal electrode of the element 10 and the lead terminal 4 sandwiched in the longitudinal direction of the element 10. Apply and dry in a dryer at 150℃
After curing for 30 minutes, the whole was insulated and covered with epoxy resin to obtain a resin-covered electronic component.

【0016】第二の実施例で作成した樹脂外装型電子部
品について電気的特性(静電容量,誘電損失)及びリー
ド端子の引っ張り強度を測定した結果、従来例と同等の
性能を有することが確認された。
As a result of measuring the electrical characteristics (capacitance, dielectric loss) and tensile strength of the lead terminals of the resin-clad electronic component made in the second example, it was confirmed that it had the same performance as the conventional example. It was done.

【0017】導電性ペーストに用いる金属粉末に銀パラ
ジウム合金粉末を用いると銀粉末に比べマイグレーショ
ンによる耐湿性能に対する改善がはかられる。
When silver-palladium alloy powder is used as the metal powder used in the conductive paste, moisture resistance due to migration can be improved compared to silver powder.

【0018】しかし特性改善及び価格の面から合金中の
パラジウムの含有量は5〜30%とするのがよい。
However, from the viewpoint of property improvement and cost, the content of palladium in the alloy is preferably 5 to 30%.

【0019】上述したように本発明においては半田付を
することなく熱硬化性樹脂を使った導電性ペーストによ
り電極形成並びにリード端子付を150℃30分程度の
熱処理で行うので、半田付による熱ショックにより発生
するクラックは全く発生しない。従って市場においてク
ラックによる信頼性低下はない。
As mentioned above, in the present invention, electrode formation and lead terminal attachment are performed by heat treatment at 150°C for about 30 minutes using a conductive paste using a thermosetting resin without soldering. Cracks caused by shock do not occur at all. Therefore, there is no decrease in reliability due to cracks in the market.

【0020】[0020]

【発明の効果】以上説明したように本発明によれば、リ
ード端子を接続するために半田付けを行なわず、外部電
極の形成とリード端子の接続を行なうことができるので
、半田付け時の熱ショックによる素子の微細なクラック
の発生を防ぎ、素子の微細なクラックによる信頼性の低
下を防ぐという効果を有する。また、従来では外部電極
を焼成するために必要となる高価な焼成炉にかえて安価
な乾燥設備で生産に対応できるという効果を有する。
As explained above, according to the present invention, external electrodes can be formed and lead terminals can be connected without soldering to connect lead terminals. This has the effect of preventing the occurrence of minute cracks in the element due to shock, and preventing a decrease in reliability due to minute cracks in the element. Moreover, it has the effect that production can be carried out using inexpensive drying equipment instead of the expensive firing furnace that is conventionally required for firing the external electrodes.

【図面の簡単な説明】[Brief explanation of drawings]

【図1】本発明の一実施例の樹脂外装型電子部品の平断
面図、およびこれに使用する素子の斜視図である。
FIG. 1 is a plan cross-sectional view of a resin-clad electronic component according to an embodiment of the present invention, and a perspective view of an element used therein.

【図2】従来の樹脂外装型電子部品の一例の平断面図、
およびこれに使用する素子の斜視図である。
[Fig. 2] A cross-sectional plan view of an example of a conventional resin-clad electronic component.
and a perspective view of an element used therein.

【符号の説明】[Explanation of symbols]

1    誘電体 2    内部電極 3    熱硬化性樹脂を用いた導電性ペーストによる
外部電極 4    リード端子 5    外装樹脂 10    積層セラミックコンデンサ素子20   
 積層セラミックコンデンサ素子23    外部電極 24    リード端子 25    外装樹脂 26    半田
1 Dielectric 2 Internal electrode 3 External electrode 4 made of conductive paste using thermosetting resin Lead terminal 5 Exterior resin 10 Multilayer ceramic capacitor element 20
Multilayer ceramic capacitor element 23 External electrode 24 Lead terminal 25 Exterior resin 26 Solder

Claims (1)

【特許請求の範囲】[Claims] 【請求項1】  内部電極端面を露出した2つの端面に
外部電極を被着形成したうえ、前記外部電極上にリード
端子を固着接続し全体を絶縁性樹脂で被覆してなる樹脂
外装型電子部品において、前記外部電極として銀又は、
銀とパラジウムの合金からなる金属粉末を含む熱硬化性
の樹脂からなる導電性ペーストを被着形成し同時にリー
ド端子を接続し硬化させたことを特徴とする樹脂外装型
電子部品。
1. A resin-clad electronic component, in which external electrodes are formed on two exposed end faces of internal electrodes, lead terminals are firmly connected to the external electrodes, and the entire body is coated with an insulating resin. In the above, the external electrode is silver or
A resin-clad electronic component characterized in that a conductive paste made of a thermosetting resin containing metal powder made of an alloy of silver and palladium is deposited, and at the same time lead terminals are connected and hardened.
JP3068193A 1991-04-01 1991-04-01 Resin molded electronic component Pending JPH04303909A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP3068193A JPH04303909A (en) 1991-04-01 1991-04-01 Resin molded electronic component

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP3068193A JPH04303909A (en) 1991-04-01 1991-04-01 Resin molded electronic component

Publications (1)

Publication Number Publication Date
JPH04303909A true JPH04303909A (en) 1992-10-27

Family

ID=13366708

Family Applications (1)

Application Number Title Priority Date Filing Date
JP3068193A Pending JPH04303909A (en) 1991-04-01 1991-04-01 Resin molded electronic component

Country Status (1)

Country Link
JP (1) JPH04303909A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7081149B2 (en) * 2001-09-28 2006-07-25 Mitsubishi Materials Corporation Silver powder for silver clay and silver clay containing this silver powder

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7081149B2 (en) * 2001-09-28 2006-07-25 Mitsubishi Materials Corporation Silver powder for silver clay and silver clay containing this silver powder

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