JPH04284242A - Light-weight composite panel - Google Patents

Light-weight composite panel

Info

Publication number
JPH04284242A
JPH04284242A JP7364791A JP7364791A JPH04284242A JP H04284242 A JPH04284242 A JP H04284242A JP 7364791 A JP7364791 A JP 7364791A JP 7364791 A JP7364791 A JP 7364791A JP H04284242 A JPH04284242 A JP H04284242A
Authority
JP
Japan
Prior art keywords
inorganic
thermosetting resin
composite panel
layer
lightweight
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
JP7364791A
Other languages
Japanese (ja)
Inventor
Takuya Koga
卓哉 古賀
Toshiyuki Suzuki
敏之 鈴木
Masayuki Inazu
稲津 正幸
Masami Urabe
浦辺 正美
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Nippon Steel Chemical and Materials Co Ltd
Original Assignee
Nippon Steel Chemical Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Nippon Steel Chemical Co Ltd filed Critical Nippon Steel Chemical Co Ltd
Priority to JP7364791A priority Critical patent/JPH04284242A/en
Publication of JPH04284242A publication Critical patent/JPH04284242A/en
Withdrawn legal-status Critical Current

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  • Laminated Bodies (AREA)
  • Finishing Walls (AREA)

Abstract

PURPOSE:To provide a lightweight composite panel, which has the large degree of freedom of molding and is utilized particularly as a wall material and a flooring material. CONSTITUTION:A lightweight composite panel is composed of double layer structure constituted of a surface layer 5 mainly comprising reinforcing fibers, inorganic powder and a thermosetting resin and a core layer 6 consisting of an inorganic lightweight aggregate 3 covered with a composition mainly comprising inorganic powder or inorganic short fiber and the thermosetting resin.

Description

【発明の詳細な説明】[Detailed description of the invention]

【0001】0001

【産業上の利用分野】本発明は壁材、床材等に使用され
る寸法安定性、耐火性、軽量性に優れた軽量複合パネル
に関するものである。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a lightweight composite panel that is excellent in dimensional stability, fire resistance, and light weight and is used for wall materials, floor materials, etc.

【0002】0002

【従来技術】一般に、建築物の壁及び床材等に利用され
るパネルは寸法安定性、軽量化に優れ高強度である必要
がある。 このための材料として、軽石を主体とするコ
ア層と、無機質繊維で強化された表層からなる熱硬化性
樹脂軽量成形体については公知である(特公昭59−1
3473号公報)。しかし、この方法では使用する無機
質粉体によっては、軽石と無機質粉体との比重差が大き
くなり、この両者が分離、偏積するために、成形操作が
複雑となる欠点を有していた。また、使用できる無機質
粉体に制約を与えていた。
2. Description of the Related Art Generally, panels used for walls and floors of buildings need to have excellent dimensional stability, light weight, and high strength. As a material for this purpose, a lightweight thermosetting resin molded body consisting of a core layer mainly made of pumice and a surface layer reinforced with inorganic fibers is known (Japanese Patent Publication No. 59-1
Publication No. 3473). However, this method has the drawback that, depending on the inorganic powder used, the difference in specific gravity between the pumice and the inorganic powder becomes large, and the two become separated and unevenly stacked, making the molding operation complicated. Additionally, there are restrictions on the inorganic powders that can be used.

【0003】0003

【発明が解決しようとする課題】本発明は上記のような
軽石と無機質粉体の使用により派生する問題を解決し、
さらに軽量化かつ成形の自由度の大きい複合パネルを提
供することを目的とするものである。
[Problems to be Solved by the Invention] The present invention solves the problems arising from the use of pumice and inorganic powder as described above.
The object of the present invention is to provide a composite panel that is further lightweight and has a greater degree of freedom in shaping.

【0004】0004

【課題を解決するための手段】本発明は上記の問題点を
解決するために研究を行い、従来使用の無機質軽量骨材
の表面をあらかじめ無機質粉体ないしは無機質短繊維と
熱硬化性樹脂で被覆したものをコア層の骨材として使用
し、強化用繊維と無機質粉体及び熱硬化性樹脂を主体と
する表面層と一体化することにより、軽量性、加工性、
厚み精度に優れた3層構造の複合材料として使用出来る
ことを見出したものである。
[Means for Solving the Problems] The present invention has been conducted in order to solve the above problems, and the surface of the conventionally used inorganic lightweight aggregate is coated in advance with inorganic powder or inorganic short fibers and thermosetting resin. This material is used as the aggregate for the core layer, and by integrating it with the surface layer mainly composed of reinforcing fibers, inorganic powder, and thermosetting resin, it is lightweight, easy to process,
It was discovered that it can be used as a three-layer composite material with excellent thickness accuracy.

【0005】以下本発明を図面に従って詳細に説明する
。図1において、符号1はそれぞれの表層を構成する無
機質粉体と熱硬化性樹脂の混合物、2は強化用繊維、3
は無機質軽量骨材、4は被覆層である。なお、これらに
よって表面層5及びコア層6を構成する。そこで、本発
明に係る無機質粉体1としては、炭酸カルシュウム、ケ
イ砂、アルミナ、マイカ、ガラスパウダ−、ガラスバル
−ン、フライアッシュ、海砂、ミルドファイバ−等の一
般に熱硬化性樹脂充填材として用いられる無機質粉体が
それぞれ単独において、或いは組み合わせて使用可能で
ある。また、被覆層4は、これら無機質粉体、いわゆる
、粉体状ないし粒体状を対象とするものと、一方無機質
短繊維にはこれら無機質のガラス状、鱗片状、繊維状体
のものをここでは区別して使用するものとする。更に、
熱硬化性樹脂としては、フェノ−ル樹脂、ユリア樹脂、
メラミン樹脂、エポキシ樹脂、不飽和ポリエステル樹脂
等の汎用のものであれば良い。熱硬化性樹脂の添加量は
使用する無機質粉体の種類や樹脂の種類によって多少異
なり、個々の場合に応じて設定すべきであるが、要求性
能、経済性の観点から、表層混合物1は無機質粉体10
0重量部に対して熱硬化性樹脂が10〜50部の範囲が
望ましい。また、コア層混合物1は熱硬化性樹脂に対し
て任意の割合で無機質粉体ないしは無機質短繊維が配合
される。また、1及び4には必要に応じて撥水剤、滑剤
等の添加剤を配合することも出来る。
The present invention will be explained in detail below with reference to the drawings. In FIG. 1, reference numeral 1 indicates a mixture of inorganic powder and thermosetting resin constituting each surface layer, 2 indicates reinforcing fiber, and 3
4 is an inorganic lightweight aggregate, and 4 is a covering layer. Note that these constitute the surface layer 5 and the core layer 6. Therefore, the inorganic powder 1 according to the present invention is generally used as a thermosetting resin filler such as calcium carbonate, silica sand, alumina, mica, glass powder, glass balloon, fly ash, sea sand, milled fiber, etc. The inorganic powders used can be used alone or in combination. In addition, the coating layer 4 is made of these inorganic powders, so-called powders or granules, and on the other hand, the inorganic short fibers are made of these inorganic glass-like, scale-like, or fibrous materials. Let's use them separately. Furthermore,
Thermosetting resins include phenolic resin, urea resin,
Any general-purpose material such as melamine resin, epoxy resin, or unsaturated polyester resin may be used. The amount of thermosetting resin added varies somewhat depending on the type of inorganic powder and resin used, and should be set according to each individual case. However, from the viewpoint of required performance and economical efficiency, surface layer mixture 1 is made of inorganic material. Powder 10
The thermosetting resin is desirably in a range of 10 to 50 parts per 0 parts by weight. Further, in the core layer mixture 1, inorganic powder or inorganic short fibers are blended in an arbitrary ratio to the thermosetting resin. Furthermore, additives such as water repellents and lubricants can be added to 1 and 4 as necessary.

【0006】次に、強化用繊維2については、ガラス繊
維、ロックウ−ル、カ−ボン繊維、金属繊維等の無機質
繊維、ナイロン繊維、ポリエステル繊維、ビニロン繊維
、アラミド繊維等の有機質繊維があるが、成形操作上か
らは収束されたストランド状の繊維が好ましい。更に、
無機質軽量骨材は軽石、火山れき、パ−ライト、膨張頁
岩、水砕スラグ等で、必要に応じて粒径を調製して使用
する。
Next, as for reinforcing fibers 2, there are inorganic fibers such as glass fiber, rock wool, carbon fiber, and metal fiber, and organic fibers such as nylon fiber, polyester fiber, vinylon fiber, and aramid fiber. From the viewpoint of molding operations, converged strand-like fibers are preferred. Furthermore,
Inorganic lightweight aggregates include pumice, volcanic rubble, perlite, expanded shale, and granulated slag, and the particle size is adjusted as necessary.

【0007】次に、本発明パネルの製造手段の一例につ
いて述べる。表層用原料として、無機質粉体に熱硬化性
樹脂を配合し、両者を混合撹拌或いは混練する。液状樹
脂の場合は必要な流動性となるまで溶剤を蒸発調整し、
無機質粉体と熱硬化性樹脂の乾式混合物1を造る。次い
でこの混合物1に強化用繊維2を配合して、適当な離型
用シ−トの上に一定量散布し、表面層用マットを形成す
る。このとき特にストランド状の繊維を使用した場合に
は、混合物1と強化用繊維2とをあらかじめ混合するこ
となしに、離型用のシ−トの上に混合物1を散布し、次
いでストランド状の繊維を散布し、さらにその上に再度
混合物1を散布する操作によって、強化用繊維2が無機
質粉体と熱硬化性樹脂の混合物1に分散したマットを形
成することができる。 この方法によっては繊維を機械
的に損傷せず、同時に配合量の自由度を大きくできる。
Next, an example of the means for manufacturing the panel of the present invention will be described. As a raw material for the surface layer, a thermosetting resin is blended with an inorganic powder, and both are mixed, stirred, or kneaded. In the case of liquid resin, adjust the solvent by evaporation until the required fluidity is achieved.
A dry mixture 1 of inorganic powder and thermosetting resin is prepared. Next, reinforcing fibers 2 are blended into this mixture 1, and a certain amount of the reinforcing fibers 2 are sprinkled onto a suitable release sheet to form a mat for the surface layer. At this time, especially when strand-shaped fibers are used, mix 1 is sprinkled on a release sheet without mixing mixture 1 and reinforcing fiber 2 in advance, and then strand-shaped fibers are used. By scattering the fibers and then again scattering the mixture 1 thereon, a mat in which the reinforcing fibers 2 are dispersed in the mixture 1 of inorganic powder and thermosetting resin can be formed. Depending on this method, the fibers are not mechanically damaged and at the same time the degree of freedom in blending amount can be increased.

【0008】次いで、コア層用原料として、無機質軽量
骨材3に無機質粉体と熱硬化性樹脂の混合物1を配合し
、加熱または少量の水を加えて撹拌し、表面がこれら混
合物1で被覆された無機質軽量骨材を造り、この無機質
軽量骨材を表層用マットの上に散布し、コア層用マット
を形成する。さらにその上に上述の方法で表層用マット
を散布した後、熱プレスによって所定時間加熱圧縮し、
該マットを加熱硬化させて3層構造の複合パネルを形成
する。
Next, as a raw material for the core layer, a mixture 1 of inorganic powder and thermosetting resin is blended with the inorganic lightweight aggregate 3, heated or stirred with a small amount of water added, and the surface is coated with the mixture 1. This inorganic lightweight aggregate is then sprinkled on top of the mat for the surface layer to form the mat for the core layer. Furthermore, after dispersing the surface layer mat in the above-mentioned manner, it is heated and compressed for a predetermined period of time using a heat press.
The mat is heated and cured to form a three-layer composite panel.

【0009】また、他の発明とするコア層用原料として
は、無機質軽量骨材3に無機質短繊維と熱硬化性樹脂の
混合物1を配合し、加熱または少量の水を加えて撹拌し
、表面がこれら混合物1で被覆された無機質軽量骨材を
造り、この無機質軽量骨材を表層用マットの上に散布し
、コア層用マットを形成する。さらにその上に上述の方
法で表層用マットを散布した後、熱プレスによって所定
時間加熱圧縮し、該マットを加熱硬化させて3層構造の
複合パネルを形成する。
[0009] In addition, as a raw material for the core layer according to another invention, a mixture 1 of inorganic short fibers and a thermosetting resin is blended with an inorganic lightweight aggregate 3, and the mixture is heated or stirred with a small amount of water added to the surface. An inorganic lightweight aggregate coated with these mixtures 1 is prepared, and this inorganic lightweight aggregate is spread on a mat for the surface layer to form a mat for the core layer. Further, a mat for the surface layer is spread thereon by the method described above, and then heated and compressed for a predetermined period of time using a heat press to heat and harden the mat to form a three-layer composite panel.

【0010】0010

【作用】このようにして、本発明の複合パネルは表面を
無機質粉体ないしは無機質短繊維と熱硬化性樹脂の混合
物で被覆した無機質軽量骨材を使用したものである。被
覆層は圧縮されて点状に接触し、その後で伝熱により熱
硬化性樹脂が反応硬化するので、無機質軽量骨材は相互
に接着一体化される。このとき軽量骨材の表面に樹脂の
みを添加して被覆しようとしても、樹脂は多孔質の表面
に浸透し有効な接着層を形成しない。被覆層は無機質軽
量骨材をほぼ均一に覆っておりシェル状の強化層を形成
するので、これらの軽量骨材の強度を大きく改善する。 また、軽量骨材は点状に接着されているので粒子間隙も
多く残存し、コア層の軽量化が保たれ、かつ、断熱性が
向上する。さらに、繊維質で強化された表面層がコア層
のこの片面、または両面に配置されており、一体で成形
されるので、表層とコア層の結合も強固なものとなり、
合理的な2層または3層構造が形成される。このように
、あらかじめ軽量骨材表面を無機質粉体ないしは無機質
短繊維で被覆することにより、軽量骨材と無機質粉体な
いしは無機質短繊維の層の分離・偏積等を防ぐことがで
きた。そのため、比重差の大きい粉体ないしは短繊維も
軽量骨材と併用することが可能となり、軽量骨材の強化
、耐火性等性能付与の自由度を大きくできた。
[Operation] Thus, the composite panel of the present invention uses an inorganic lightweight aggregate whose surface is coated with a mixture of inorganic powder or inorganic short fibers and a thermosetting resin. The coating layer is compressed and comes into point-like contact, and then the thermosetting resin reacts and hardens due to heat transfer, so that the inorganic lightweight aggregates are bonded and integrated with each other. At this time, even if an attempt is made to coat the surface of the lightweight aggregate by adding only a resin, the resin will penetrate into the porous surface and will not form an effective adhesive layer. The covering layer substantially uniformly covers the inorganic lightweight aggregates and forms a shell-like reinforcing layer, which greatly improves the strength of these lightweight aggregates. In addition, since the lightweight aggregate is bonded in dots, many gaps between particles remain, which keeps the core layer lightweight and improves its heat insulation properties. Furthermore, since the surface layer reinforced with fibers is placed on one or both sides of the core layer and is integrally molded, the bond between the surface layer and the core layer is strong.
A reasonable two-layer or three-layer structure is formed. In this way, by coating the surface of the lightweight aggregate with inorganic powder or short inorganic fibers in advance, it was possible to prevent the layers of the lightweight aggregate and the inorganic powder or short fibers from separating or stacking up unevenly. Therefore, it has become possible to use powder or short fibers with a large difference in specific gravity in combination with lightweight aggregates, increasing the degree of freedom in imparting properties such as strengthening and fire resistance to lightweight aggregates.

【0011】[0011]

【実施例1】以下、実施例により本発明をさらに具体的
に説明する。ブレ−ン値1500cm2/gのフライア
ッシュ74重量部、ノボラックタイプフェノ−ル樹脂1
3重量部、25mmの長さのガラス繊維チョップドスト
ランド13重量部を離型用シ−トの上に毎平方メ−トル
当り1.53kgの割合で均等に散布し表面層とし、次
に粒径4mm〜1mmの範囲に調整した火山れき60重
量部にフライアッシュ34.5重量部、ノボラックタイ
プフェノ−ル樹脂5重量部、パラフィン0.5重量部を
混合して撹拌し、火山れきの表面を被覆する。この被覆
された火山れきを表面層の上に散布してコア層とする。 さらに、このコア層の上に再度表面層を散布して3層構
造のマットとする。該マットを熱プレスに挿入して、温
度150℃、最大圧力10kg/cm2で10分間圧縮
して、3層構造の複合パネルを得る。このようにして造
られた複合パネルは次のような性質となる。 厚み          13mm 比重          0.80 曲げ強さ      150kg/cm2吸水膨張率 
   0.1% 加工率        鋸による切断、釘打ち固定可能
[Example 1] Hereinafter, the present invention will be explained in more detail with reference to Examples. 74 parts by weight of fly ash with Blaine value of 1500 cm2/g, 1 part of novolac type phenolic resin
3 parts by weight of chopped glass fiber strands with a length of 25 mm and 13 parts by weight were evenly spread on the mold release sheet at a rate of 1.53 kg per square meter to form a surface layer, and then the particle size was 34.5 parts by weight of fly ash, 5 parts by weight of novolac type phenol resin, and 0.5 parts by weight of paraffin were mixed with 60 parts by weight of volcanic debris adjusted to a size of 4 mm to 1 mm, and the mixture was stirred to coat the surface of the volcanic debris. Cover. This coated volcanic rubble is spread over the surface layer to form a core layer. Furthermore, a surface layer is again sprinkled on top of this core layer to form a mat with a three-layer structure. The mat is inserted into a heat press and compressed for 10 minutes at a temperature of 150° C. and a maximum pressure of 10 kg/cm 2 to obtain a three-layer composite panel. The composite panel made in this way has the following properties. Thickness 13mm Specific gravity 0.80 Bending strength 150kg/cm2 Water absorption expansion coefficient
0.1% Processing rate Can be cut with a saw and fixed by nailing

【0012】0012

【実施例2】ブレ−ン値1500cm2/gのフライア
ッシュ74重量部、ノボラックタイプフェノ−ル樹脂1
3重量部、25mmの長さのガラス繊維チョップドスト
ランド13重量部を離型用シ−トの上に毎平方メ−トル
当り1.53kgの割合で均等に散布し表面層とし、次
に粒径4mm〜1mmの範囲に調整した火山れき70重
量部に5mm以下のガラス短繊維24.5重量部、ノボ
ラックタイプフェノ−ル樹脂5重量部、パラフィン0.
5重量部を混合して撹拌し、火山れきの表面を被覆する
。この被覆された火山れきを表面層の上に散布してコア
層とする。さらに、このコア層の上に再度表面層を散布
して3層構造のマットとする。該マットを熱プレスに挿
入して、温度150℃、最大圧力10kg/cm2で1
0分間圧縮して、3層構造の複合パネルを得る。このよ
うにして造られた複合パネルは次のような性質となる。 厚み          20mm 比重          0.75 曲げ強さ      200kg/cm2吸水膨張率 
   0.1% 加工率        鋸による切断、釘打ち固定可能
[Example 2] 74 parts by weight of fly ash with Blaine value of 1500 cm2/g, 1 part of novolac type phenolic resin
3 parts by weight of chopped glass fiber strands with a length of 25 mm and 13 parts by weight were evenly spread on the mold release sheet at a rate of 1.53 kg per square meter to form a surface layer, and then the particle size was 70 parts by weight of volcanic debris adjusted to a range of 4 mm to 1 mm, 24.5 parts by weight of short glass fibers of 5 mm or less, 5 parts by weight of novolac type phenolic resin, and 0.0 parts by weight of paraffin.
5 parts by weight are mixed and stirred to coat the surface of the volcanic rubble. This coated volcanic rubble is spread over the surface layer to form a core layer. Furthermore, a surface layer is again sprinkled on top of this core layer to form a mat with a three-layer structure. Insert the mat into a heat press and press at a temperature of 150°C and a maximum pressure of 10kg/cm2.
Compress for 0 minutes to obtain a three-layer composite panel. The composite panel made in this way has the following properties. Thickness 20mm Specific gravity 0.75 Bending strength 200kg/cm2 Water absorption expansion coefficient
0.1% Processing rate Can be cut with a saw and fixed by nailing

【0013】[0013]

【発明の効果】以上述べたように、本発明では、無機質
軽量骨材の表面をあらかじめ無機質粉体ないしは無機質
短繊維と熱硬化性樹脂で被覆したものをコア層の骨材と
して使用し、強化用繊維と無機質粉体及び熱硬化性樹脂
を主体とする表面層と一体化することにより、軽量性、
加工性、厚み精度に優れた3層構造の複合材料であり、
特に壁材、床材等の軽量複合パネルとして利用度の高い
製品にある。
As described above, in the present invention, inorganic lightweight aggregate whose surface is coated with inorganic powder or inorganic short fibers and a thermosetting resin is used as the aggregate for the core layer to strengthen it. By integrating the fiber and the surface layer mainly composed of inorganic powder and thermosetting resin, it is lightweight and
It is a three-layer composite material with excellent workability and thickness accuracy.
This is especially true for products that are frequently used as lightweight composite panels for wall materials, flooring materials, etc.

【図面の簡単な説明】[Brief explanation of the drawing]

【図1】本発明によって得られる軽量複合パネルの構造
を示す正面断面図である。
FIG. 1 is a front sectional view showing the structure of a lightweight composite panel obtained by the present invention.

【符号の説明】[Explanation of symbols]

1  無機質粉体と熱硬化性樹脂の混合物、2  強化
用繊維、 3  無機質軽量骨材、 4  被覆層、 5  表面層、 6  コア層。
1. Mixture of inorganic powder and thermosetting resin, 2. Reinforcing fiber, 3. Inorganic lightweight aggregate, 4. Covering layer, 5. Surface layer, 6. Core layer.

Claims (2)

【特許請求の範囲】[Claims] 【請求項1】  強化用繊維、無機質粉体及び熱硬化性
樹脂を主体とする表面層と、無機質粉体及び未硬化の熱
硬化性樹脂を主体とする組成物で予め被覆されている無
機質軽量骨材からなるコア層で構成された複層構造から
成ることを特徴とする軽量複合パネル。
Claim 1: An inorganic lightweight material that is pre-coated with a surface layer mainly consisting of reinforcing fibers, an inorganic powder, and a thermosetting resin, and a composition mainly consisting of an inorganic powder and an uncured thermosetting resin. A lightweight composite panel characterized by having a multilayer structure consisting of a core layer made of aggregate.
【請求項2】  強化用繊維、無機質粉体及び熱硬化性
樹脂を主体とする表面層と、無機質短繊維及び未硬化の
熱硬化性樹脂を主体とする組成物で予め被覆されている
無機質軽量骨材からなるコア層で構成された複層構造か
ら成ることを特徴とする軽量複合パネル。
[Claim 2] An inorganic lightweight material pre-coated with a surface layer mainly consisting of reinforcing fibers, inorganic powder, and a thermosetting resin, and a composition mainly consisting of inorganic short fibers and an uncured thermosetting resin. A lightweight composite panel characterized by having a multilayer structure consisting of a core layer made of aggregate.
JP7364791A 1991-03-14 1991-03-14 Light-weight composite panel Withdrawn JPH04284242A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP7364791A JPH04284242A (en) 1991-03-14 1991-03-14 Light-weight composite panel

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP7364791A JPH04284242A (en) 1991-03-14 1991-03-14 Light-weight composite panel

Publications (1)

Publication Number Publication Date
JPH04284242A true JPH04284242A (en) 1992-10-08

Family

ID=13524293

Family Applications (1)

Application Number Title Priority Date Filing Date
JP7364791A Withdrawn JPH04284242A (en) 1991-03-14 1991-03-14 Light-weight composite panel

Country Status (1)

Country Link
JP (1) JPH04284242A (en)

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2000050233A1 (en) * 1999-02-22 2000-08-31 Sekisui Chemical Co., Ltd. Composite material and synthetic sleeper using the composite material
KR100417798B1 (en) * 2001-10-06 2004-02-05 조용준 Andesite and fiberglass mixed complex
US6972144B2 (en) 2002-04-19 2005-12-06 Hunter Paine Enterprises, Llc Composite structural material and method of making same
US8181580B2 (en) 2004-12-29 2012-05-22 Coda Capital Mangement Group, LLC Composite structural material and method of making the same
CN102862363A (en) * 2012-08-31 2013-01-09 苏州博云塑业有限公司 Hollow micro-sphere reinforced nylon plate material and preparation process thereof

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2000050233A1 (en) * 1999-02-22 2000-08-31 Sekisui Chemical Co., Ltd. Composite material and synthetic sleeper using the composite material
KR100417798B1 (en) * 2001-10-06 2004-02-05 조용준 Andesite and fiberglass mixed complex
US6972144B2 (en) 2002-04-19 2005-12-06 Hunter Paine Enterprises, Llc Composite structural material and method of making same
US8181580B2 (en) 2004-12-29 2012-05-22 Coda Capital Mangement Group, LLC Composite structural material and method of making the same
CN102862363A (en) * 2012-08-31 2013-01-09 苏州博云塑业有限公司 Hollow micro-sphere reinforced nylon plate material and preparation process thereof

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