JPH042793A - Method for removing scale on steel strip - Google Patents

Method for removing scale on steel strip

Info

Publication number
JPH042793A
JPH042793A JP10368490A JP10368490A JPH042793A JP H042793 A JPH042793 A JP H042793A JP 10368490 A JP10368490 A JP 10368490A JP 10368490 A JP10368490 A JP 10368490A JP H042793 A JPH042793 A JP H042793A
Authority
JP
Japan
Prior art keywords
flow rate
steel strip
spray
scale
strip
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP10368490A
Other languages
Japanese (ja)
Inventor
Yoshihiko Ishikawa
石川 吉彦
Kiyotaka Toyofuku
豊福 清隆
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Nippon Steel Corp
Original Assignee
Sumitomo Metal Industries Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Sumitomo Metal Industries Ltd filed Critical Sumitomo Metal Industries Ltd
Priority to JP10368490A priority Critical patent/JPH042793A/en
Publication of JPH042793A publication Critical patent/JPH042793A/en
Pending legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23GCLEANING OR DE-GREASING OF METALLIC MATERIAL BY CHEMICAL METHODS OTHER THAN ELECTROLYSIS
    • C23G3/00Apparatus for cleaning or pickling metallic material
    • C23G3/02Apparatus for cleaning or pickling metallic material for cleaning wires, strips, filaments continuously
    • C23G3/023Apparatus for cleaning or pickling metallic material for cleaning wires, strips, filaments continuously by spraying

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Cleaning And De-Greasing Of Metallic Materials By Chemical Methods (AREA)

Abstract

PURPOSE:To satisfactorily remove scale on a steel strip and to increase work efficiency by establishing relation between the transfer speed of the strip and the flow rate of spray every time and material or coiling temp. of the strip varies from that of the preceding strip and controlling the flow rate of spray in accordance with the measured transfer speed. CONSTITUTION:A flowmeter 12 is fixed in an acid soln. feeding pipe 9 and measured flow rate is outputted to a flow rate controller 13. This controller 13 outputs a signal to a pump controller 15 on the basis of the flow rate and a signal outputted from a device 14 for setting the flow rate of spray so that the flow rate of spray from spray nozzles 4-6 is made optimum. The setting device 14 calculates the optimum flow rate of spray from various tables with inputted data on the basis of a signal from a speed sensor 16 for measuring the speed of a steel strip S and signals from a host computer 17 with the inputted material, width, thickness and coiling temp. of the strip S. The optimum flow rate is outputted to the flow rate controller 13.

Description

【発明の詳細な説明】 (産業上の利用分野) 本発明は、鋼帯のスケールを除去する方法に係り、特に
スプレー式酸洗槽を用いて連続搬送されてくる鋼帯のス
ケールを高能率に除去する方法に関するものである。
Detailed Description of the Invention (Field of Industrial Application) The present invention relates to a method for removing scale from a steel strip, and in particular, a method for removing scale from a continuously conveyed steel strip using a spray pickling tank with high efficiency. This article relates to a method for removing such substances.

(従来の技術) 連続搬送されてくる鋼帯のスケールを除去するための酸
洗設備としては、浸漬式とスプレー式のものが一般的で
あるが、近年、これらの酸洗設備よりも酸洗効率の良い
スプレー式酸洗槽を用いたものが開発され、使用される
ようになってきた。
(Prior art) Immersion-type and spray-type pickling equipment are generally used to remove scale from continuously transported steel strips, but in recent years, pickling equipment has become more popular than these pickling equipment. A highly efficient spray pickling tank has been developed and is now in use.

このスプレー式酸洗槽を用いた方式は、酸洗ラインタン
クの入側及び出側から鋼帯の幅方向に酸液をスプレーす
ると共に、酸液ラインタンク内で対流する酸液との接触
によってもスケールを除去する方法である。
This method using a spray-type pickling tank sprays acid solution in the width direction of the steel strip from the inlet and outlet sides of the pickling line tank, and at the same time, the acid solution is sprayed in the width direction of the steel strip from the inlet and outlet sides of the pickling line tank. is also a method of removing scale.

そして、その際板接続部ではスケール付着量が多いため
、該部分での鋼帯搬送速度を減速し、酸洗ラインタンク
通過時間を長くして対処していた。
At that time, since there was a large amount of scale adhering to the plate joints, the conveyance speed of the steel strip at these parts was reduced and the time taken for the steel strip to pass through the pickling line tank was lengthened.

(発明が解決しようとする課題) しかしながら、上記スプレー式酸洗槽によるスケール除
去方法では、スプレー流量を一定とし、鋼帯によって、
酸液の温度、濃度を変えた後は鋼帯搬送速度のみを可変
としてスケールの除去を行っていた。
(Problem to be solved by the invention) However, in the scale removal method using the spray pickling tank, the spray flow rate is kept constant and the steel strip is used to remove the scale.
After changing the temperature and concentration of the acid solution, scale was removed by changing only the steel strip conveyance speed.

従って、酸洗設備内の入・出側設備のサイクルタイム不
足や板接続部通過等の要因で鋼帯搬送速度が変動した場
合には、酸洗ラインタンクの通過時間が変化するため、
酸洗ムラや過酸洗等が発生し、製品不良が生じるという
問題があった。
Therefore, if the steel strip conveyance speed fluctuates due to factors such as insufficient cycle time of the input/output equipment in the pickling equipment or passing through plate connections, the passage time of the pickling line tank will change.
There was a problem in that uneven pickling, over-pickling, etc. occurred, resulting in product defects.

本発明は、かかる従来の問題点に鑑みて成されたもので
あり、品質良好な製品を高能率で製造可能とするスケー
ル除去方法を提供することを目的としている。
The present invention has been made in view of such conventional problems, and an object of the present invention is to provide a scale removal method that makes it possible to manufacture products of good quality with high efficiency.

(課題を解決するための手段) 上記目的を達成するために、本発明に係る第1のスケー
ル除去方法は、連続的に搬送されてくる鋼帯に対し、所
要間隔を存して相対向する方向にその幅方向に亘って酸
液をスプレーすると共に、前記鋼帯を浸漬せしめる酸液
を対流させ、その接触によってスケールを除去する方法
において、鋼帯の材質、厚さ、巻取り温度毎に鋼帯搬送
速度と鋼帯単位面積当たりのスプレー流量の関係を予め
求めてテーブル化しておき、搬送速度の検出値とこのテ
ーブル化した関係に基づいてスプレー流量を制御するこ
ととしているのである。
(Means for Solving the Problems) In order to achieve the above object, the first scale removal method according to the present invention is such that a steel strip that is continuously conveyed is faced to the steel strip at a required interval. In this method, scale is removed by spraying an acid solution across the width of the steel strip and causing convection of the acid solution that immerses the steel strip. The relationship between the steel strip conveyance speed and the spray flow rate per unit area of the steel strip is determined in advance and tabulated, and the spray flow rate is controlled based on the detected value of the conveyance speed and this tabulated relationship.

また第2のスケール除去方法は、前記第1の方法におい
て、前記テーブルに加えて更に板材接続部におけるライ
ン減速量を予め入力しておき、スケール除去前の搬送ラ
イン中において板材の接続部を検知し、先行材のボトム
部がスケール除去ラインに搬入される時にライン速度を
減速すると共に、先行材と後行材のテーブル化した関係
のうちのどちらか大きい方のスプレー流量を選択するこ
ととしているのである。
A second scale removal method is the first method in which, in addition to the table, the line deceleration amount at the plate connection part is input in advance, and the plate connection part is detected in the conveyance line before scale removal. However, when the bottom part of the preceding material is carried into the scale removal line, the line speed is reduced, and the spray flow rate is selected whichever is larger from the tabulated relationship between the preceding material and the following material. It is.

(実 施 例) 以下本発明方法を添付図面に示す一実施例に基づいて説
明する。
(Example) The method of the present invention will be explained below based on an example shown in the attached drawings.

第1図は本発明方法を実施するための装置及びその制御
系統を示した図面であり、図中1は酸洗対象となる鋼帯
Sの搬送経路に設けられた酸洗ラインタンクである。そ
してこの酸洗ラインタンク1内の入側と出側には夫々鋼
帯Sを搬送するためのピンチロール2が配設されると共
に、これらピンチロール2の直下には堰板3が設けられ
ている。
FIG. 1 is a drawing showing an apparatus for carrying out the method of the present invention and its control system, and in the figure, 1 is a pickling line tank provided on the conveyance path of the steel strip S to be pickled. Pinch rolls 2 for conveying the steel strip S are provided on the inlet and outlet sides of the pickling line tank 1, respectively, and a weir plate 3 is provided directly below the pinch rolls 2. There is.

またこれらピンチロール2の内側には搬送ラインに向け
て酸液の噴射ノズル4.5が対向配置され、鋼帯Sの表
裏面に形成付着したスケールを0.8〜3.0 kg/
cjの圧力で噴射される噴射酸液で除去するように成さ
れている。6は再噴射ノズル4.5間において鋼帯Sを
浸漬すべく供給された酸液7に対流を起こさせる側面噴
射ノズルであり、この対流酸液によってもスケールの除
去が行われる。
In addition, acid liquid spray nozzles 4.5 are disposed inside these pinch rolls 2 to face the conveyance line, and remove 0.8 to 3.0 kg of scale formed and adhered to the front and back surfaces of the steel strip S.
It is designed to be removed with an injected acid solution injected at a pressure of cj. Reference numeral 6 denotes a side injection nozzle that causes convection in the acid solution 7 supplied to immerse the steel strip S between the re-injection nozzles 4.5, and this convection acid solution also removes scale.

8は酸液供給配管9を介して、前記噴射ノズル4.5及
び6に循環タンク10内の酸液7を送る循環ポンプであ
り、余分な酸液7はリターン配管11を介して循環タン
ク10に戻されるようになっている。
Reference numeral 8 denotes a circulation pump that sends the acid solution 7 in the circulation tank 10 to the injection nozzles 4.5 and 6 via the acid solution supply pipe 9, and excess acid solution 7 is sent to the circulation tank 10 via the return pipe 11. It is set to be returned to .

12は前記酸液供給配管9の途中に介設された流量計で
あり、これら流量計12での検出流量は流量制御装置1
3に出力される。この流量制御装置13では前記流量計
12からの流量値と、スプレー流量設定装置14からの
出力信号に基づいて噴射ノズル4.5及び6からの噴射
流量が最適値。
Reference numeral 12 denotes a flow meter interposed in the middle of the acid liquid supply pipe 9, and the flow rate detected by these flow meters 12 is determined by the flow rate control device 1.
3 is output. In this flow rate control device 13, the injection flow rates from the injection nozzles 4.5 and 6 are set to optimal values based on the flow rate value from the flow meter 12 and the output signal from the spray flow rate setting device 14.

になるようポンプ制御装置15に信号を出力する。A signal is output to the pump control device 15 so that

ところで、スプレー流量設定装置14は、鋼帯Sの速度
検出装置16からの出力信号と、鋼帯Sの材質、板幅、
板厚、巻取温度を入力された上位計算機17からの現在
の前記各値の出力信号に基づいて、予め入力しである各
種テーブルから最適のスプレー流量を求めて流量制御装
置13に出力するものである。
By the way, the spray flow rate setting device 14 uses the output signal from the speed detection device 16 of the steel strip S, the material of the steel strip S, the strip width,
Based on the current output signal of each value from the host computer 17 into which the plate thickness and winding temperature are input, the optimal spray flow rate is determined from various tables input in advance and output to the flow rate control device 13. It is.

次にスプレー流量設定装置14に予め入力しである各種
テーブルについて説明する。
Next, various tables that are input in advance to the spray flow rate setting device 14 will be explained.

鋼帯の表裏面に形成付着した単位面積当たりのスケール
量は、鋼帯の材質及び熱延ラインでの巻取温度によって
異なる。第2図は巻取温度と酸洗時間の関係を示したも
のであるが、酸洗時間の長さはスケール付着量に比例す
るため、間接的にスケール付着量を表したものといえる
。この第2図は同一材質で板厚が異なるデータであるが
、板厚が厚くなるほど、又巻取温度が高いほどスケール
付着量が多くなるのが判る。また、本特性は材質が変化
した場合、経験的に上下方向でシフトすることが確認さ
れている。従って、第2図に示したスケール付着量の特
性より、スケール付着量は、鋼帯の材質、板幅、板厚、
巻取温度によって決まることが判る。
The amount of scale formed and adhered to the front and back surfaces of the steel strip per unit area varies depending on the material of the steel strip and the coiling temperature on the hot rolling line. FIG. 2 shows the relationship between the winding temperature and the pickling time, and since the length of the pickling time is proportional to the amount of scale attached, it can be said that it indirectly represents the amount of scale attached. FIG. 2 shows data for different plate thicknesses made of the same material, and it can be seen that the thicker the plate and the higher the winding temperature, the greater the amount of scale adhesion. Furthermore, it has been empirically confirmed that this characteristic shifts in the vertical direction when the material changes. Therefore, from the characteristics of scale adhesion shown in Figure 2, the scale adhesion amount depends on the steel strip material, strip width, plate thickness,
It can be seen that it is determined by the winding temperature.

ところで、鋼帯の表裏面に形成付着するスケールは第3
図に示すように、Fe0層18、Fe50.層19及び
Fe、03層20の三層構造であり、これを酸洗すれば
下記化学式の如くなってスケールが除去されることにな
る。
By the way, the scale that forms and adheres to the front and back surfaces of the steel strip is the third scale.
As shown in the figure, Fe0 layer 18, Fe50 . It has a three-layer structure of layer 19, Fe layer, and 03 layer 20, and if this layer is pickled, the scale will be removed as shown in the chemical formula below.

よって、このスケール除去のメカニズムからスプレー流
量を求めることは理論的には可能であるが、スケール付
着量はミクロ的にみれば均一ではない為、理論的に求め
たスプレー流量と実際のスケール除去に必要なスプレー
流量とは一致しない。
Therefore, it is theoretically possible to determine the spray flow rate from this scale removal mechanism, but since the amount of scale adhesion is not uniform from a microscopic perspective, the theoretical spray flow rate and actual scale removal may differ. Does not match required spray flow rate.

そこで本発明では、第4図〜第7図に示すような鋼種、
板厚毎の巻取温度・スプレー流量とライン速度の関係の
テーブルを予め各種作成しておき、これらテーブルに基
づいて最適のスプレー流量を出力するのである。
Therefore, in the present invention, steel types as shown in FIGS. 4 to 7,
Various tables are created in advance for the relationship between winding temperature, spray flow rate, and line speed for each sheet thickness, and the optimal spray flow rate is output based on these tables.

すなわち、第4図はハイカーボン材として550CHの
、第5図は一般材として5CPH2の、第6図は電磁鋼
板材として50 A 700の、第7図はその他の材料
としてIILc(極低炭素材)のものを夫々示す。
That is, Fig. 4 shows 550CH as a high carbon material, Fig. 5 shows 5CPH2 as a general material, Fig. 6 shows 50A 700 as an electromagnetic steel sheet material, and Fig. 7 shows IILc (ultra-low carbon material) as other materials. ) are shown respectively.

なお、第1図中の21は循環タンク10内の酸液7の温
度を測定する温度計、22は同じ酸液7の濃度を測定す
る濃度計であり、これら測定値も流量制御装置13に出
力されている。
In addition, 21 in FIG. 1 is a thermometer that measures the temperature of the acid solution 7 in the circulation tank 10, and 22 is a concentration meter that measures the concentration of the same acid solution 7. These measured values are also sent to the flow rate control device 13. It is being output.

以上が第1の本発明方法であるが、第2の本発明方法で
はこの第1の本発明方法に加えて更に板接続部における
スプレー流量の制御をも行うのである。板接続部では鋼
種、板幅等が変化し、スケール発生量も変化するため、
この変化に合わせてスプレー流量を適正に制御する必要
があるからである。
The above is the first method of the present invention, but in the second method of the present invention, in addition to the first method of the present invention, the spray flow rate at the plate connection portion is also controlled. At plate connections, the steel type, plate width, etc. change, and the amount of scale generated also changes.
This is because it is necessary to appropriately control the spray flow rate in accordance with this change.

従って、第2の本発明方法を実施するためには、更に板
接続部の検出装置23を別途設ける必要があり、この検
出信号を前記スプレー流量設定装置14及びライン速度
制御装置(図示せず)に出力するのである。すると、ラ
イン速度制御装置ではこの検出信号に基づいて先行材の
ボトム部が酸洗ラインタンク1内に搬入される時にライ
ン速度の減速指令を出す。
Therefore, in order to carry out the second method of the present invention, it is necessary to separately provide a detection device 23 for the plate connection portion, and this detection signal is transmitted to the spray flow rate setting device 14 and the line speed control device (not shown). It outputs to . Then, based on this detection signal, the line speed control device issues a line speed deceleration command when the bottom portion of the preceding material is carried into the pickling line tank 1.

一方、スプレー流量設定装置14では、前記検出信号に
基づいて先行材と後行材のテーブル(第1の発明のテー
ブルとは異なるテーブル)を比較し、どちらか大きい方
のスプレー流量となるように前記減速指令と同時に流量
制御装置13に出力するのである。
On the other hand, the spray flow rate setting device 14 compares the tables for the preceding material and the following material (different tables from the table of the first invention) based on the detection signal, and sets the spray flow rate to be the larger one. It is output to the flow rate control device 13 at the same time as the deceleration command.

上記したライン速度、スプレー流量で後行材のトップ部
名のスケール除去を行い、後行材のトップ部が酸洗ライ
ンタンクlから搬出される時にライン速度は元に戻され
、一方、スプレー流量も後行材のスケールを除去するの
に適したものに制御される。
The top part of the trailing material is scaled at the above line speed and spray flow rate, and when the top part of the trailing material is carried out from the pickling line tank l, the line speed is returned to the original value, while the spray flow rate is It is also controlled to be suitable for removing scale from trailing materials.

なお、トップ部、ボトム部の長さは接続点から任意の長
さを予め設定しておく。また、本実施例では酸洗ライン
タンク1、一つについて説明したが、酸洗うインタンク
は通数個直列状に配置されている。更に、第1図中の2
4はストリップSを浸漬するために酸液の溢出量を可及
的に少なくするためのスライディングスキッド、25は
浸漬カバーである。
Note that the lengths of the top portion and the bottom portion are set in advance to arbitrary lengths from the connection point. Further, in this embodiment, one pickling line tank 1 has been described, but several pickling in-tanks are arranged in series. Furthermore, 2 in Figure 1
4 is a sliding skid for immersing the strip S to minimize the amount of acid solution spilling out, and 25 is a dipping cover.

(発明の効果) 本発明は以上説明したような方法であるため、良好なス
ケール除去と、エネルギ原単位の低下、並びに作業能率
の向上が図れることになる。
(Effects of the Invention) Since the present invention is a method as described above, it is possible to achieve good scale removal, a reduction in energy consumption, and an improvement in work efficiency.

【図面の簡単な説明】[Brief explanation of drawings]

第1図は本発明方法を実施するための装置及びその制御
系統を示した図、第2図は巻取り温度と酸洗時間の関係
を示した図、第3図は鋼帯表裏面に形成付着するスケー
ルの説明図、第4図〜第7図はスプレー流量設定装置に
予め入力されているテーブルの一例を示す図である。 Sは鋼帯、1は酸洗ラインタンク、4〜6は噴射ノズル
、7は酸液、13は流量制御装置、14はスプレー流量
設定装置、16は速度検出装置、23は板接続部の検出
装置。 第3図 ライ:It度 (〜−R)
Fig. 1 is a diagram showing the apparatus and its control system for carrying out the method of the present invention, Fig. 2 is a diagram showing the relationship between winding temperature and pickling time, and Fig. 3 is a diagram showing the relationship between the winding temperature and the pickling time. The explanatory diagrams of attached scales, FIGS. 4 to 7, are diagrams showing an example of a table inputted in advance to the spray flow rate setting device. S is a steel strip, 1 is a pickling line tank, 4 to 6 are injection nozzles, 7 is an acid solution, 13 is a flow rate control device, 14 is a spray flow rate setting device, 16 is a speed detection device, 23 is a detection of plate connection part Device. Figure 3 Lie: It degree (~-R)

Claims (2)

【特許請求の範囲】[Claims] (1)連続的に搬送されてくる鋼帯に対し、所要間隔を
存して相対向する方向にその幅方向に亘って酸液をスプ
レーすると共に、前記鋼帯を浸漬せしめる酸液を対流さ
せ、その接触によってスケールを除去する方法において
、鋼帯の材質、厚さ、巻取り温度毎に鋼帯搬送速度と鋼
帯単位面積当たりのスプレー流量の関係を予め求めてテ
ーブル化しておき、搬送速度の検出値とこのテーブル化
した関係に基づいてスプレー流量を制御することを特徴
とする鋼帯のスケール除去方法。
(1) An acid solution is sprayed across the width of the continuously conveyed steel strip in opposing directions at a required interval, and the acid solution that immerses the steel strip is caused to circulate. In the method of removing scale by contact, the relationship between the steel strip conveyance speed and the spray flow rate per unit area of the steel strip is determined in advance for each steel strip material, thickness, and coiling temperature, and a table is prepared. A method for removing scale from a steel strip, characterized in that the spray flow rate is controlled based on the detected value and this tabled relationship.
(2)請求項1記載の方法において、前記テーブルに加
えて更に板材接続部におけるライン減速量を予め入力し
ておき、スケール除去前の搬送ライン中において板材の
接続部を検知し、先行材のボトム部がスケール除去ライ
ンに搬入される時にライン速度を減速すると共に、先行
材と後行材のテーブル化した関係のうちのどちらか大き
い方のスプレー流量を選択することを特徴とする鋼帯の
スケール除去方法。
(2) In the method according to claim 1, in addition to the table, the line deceleration amount at the plate joint is inputted in advance, and the plate joint is detected in the conveyance line before scale removal, and the line deceleration amount at the plate joint is detected. A steel strip characterized in that when the bottom part is carried into a scale removal line, the line speed is reduced and the spray flow rate is selected whichever is larger from the tabulated relationship between the leading material and the trailing material. How to remove scale.
JP10368490A 1990-04-19 1990-04-19 Method for removing scale on steel strip Pending JPH042793A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP10368490A JPH042793A (en) 1990-04-19 1990-04-19 Method for removing scale on steel strip

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP10368490A JPH042793A (en) 1990-04-19 1990-04-19 Method for removing scale on steel strip

Publications (1)

Publication Number Publication Date
JPH042793A true JPH042793A (en) 1992-01-07

Family

ID=14360609

Family Applications (1)

Application Number Title Priority Date Filing Date
JP10368490A Pending JPH042793A (en) 1990-04-19 1990-04-19 Method for removing scale on steel strip

Country Status (1)

Country Link
JP (1) JPH042793A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1999029928A3 (en) * 1997-12-05 1999-08-26 Acciai Speciali Terni Spa Process and apparatus for steel band spray pickling
JP2012132079A (en) * 2010-12-24 2012-07-12 Jfe Steel Corp Method and facility for producing steel sheet excellent in chemical conversion treatment property

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1999029928A3 (en) * 1997-12-05 1999-08-26 Acciai Speciali Terni Spa Process and apparatus for steel band spray pickling
JP2012132079A (en) * 2010-12-24 2012-07-12 Jfe Steel Corp Method and facility for producing steel sheet excellent in chemical conversion treatment property

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