JPH0425576A - Coating composition for water-base aerosol - Google Patents
Coating composition for water-base aerosolInfo
- Publication number
- JPH0425576A JPH0425576A JP2130825A JP13082590A JPH0425576A JP H0425576 A JPH0425576 A JP H0425576A JP 2130825 A JP2130825 A JP 2130825A JP 13082590 A JP13082590 A JP 13082590A JP H0425576 A JPH0425576 A JP H0425576A
- Authority
- JP
- Japan
- Prior art keywords
- weight
- parts
- water
- meth
- acrylate
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000000443 aerosol Substances 0.000 title claims description 15
- 239000008199 coating composition Substances 0.000 title claims description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 44
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims abstract description 24
- 229920001577 copolymer Polymers 0.000 claims abstract description 18
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 claims abstract description 11
- 230000009477 glass transition Effects 0.000 claims abstract description 8
- 229920000180 alkyd Polymers 0.000 claims abstract description 7
- 239000000178 monomer Substances 0.000 claims abstract description 5
- 150000001732 carboxylic acid derivatives Chemical class 0.000 claims abstract 2
- 239000000126 substance Substances 0.000 claims description 9
- 239000004925 Acrylic resin Substances 0.000 claims description 7
- 229920000178 Acrylic resin Polymers 0.000 claims description 7
- -1 acrylic ester Chemical class 0.000 claims description 3
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 3
- 125000004432 carbon atom Chemical group C* 0.000 claims description 2
- 238000007865 diluting Methods 0.000 claims description 2
- 230000003472 neutralizing effect Effects 0.000 claims description 2
- 239000000049 pigment Substances 0.000 abstract description 14
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 abstract description 13
- 239000000203 mixture Substances 0.000 abstract description 11
- 229920005989 resin Polymers 0.000 abstract description 9
- 239000011347 resin Substances 0.000 abstract description 9
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 abstract description 7
- 238000000889 atomisation Methods 0.000 abstract description 6
- 238000005507 spraying Methods 0.000 abstract description 4
- 238000003860 storage Methods 0.000 abstract description 4
- 238000013329 compounding Methods 0.000 abstract description 2
- 239000006185 dispersion Substances 0.000 abstract description 2
- 239000000463 material Substances 0.000 abstract description 2
- 125000000896 monocarboxylic acid group Chemical group 0.000 abstract 1
- 238000005204 segregation Methods 0.000 abstract 1
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 19
- ARXJGSRGQADJSQ-UHFFFAOYSA-N 1-methoxypropan-2-ol Chemical compound COCC(C)O ARXJGSRGQADJSQ-UHFFFAOYSA-N 0.000 description 14
- OZAIFHULBGXAKX-UHFFFAOYSA-N 2-(2-cyanopropan-2-yldiazenyl)-2-methylpropanenitrile Chemical compound N#CC(C)(C)N=NC(C)(C)C#N OZAIFHULBGXAKX-UHFFFAOYSA-N 0.000 description 8
- 229910052799 carbon Inorganic materials 0.000 description 8
- 239000011248 coating agent Substances 0.000 description 8
- 238000000576 coating method Methods 0.000 description 8
- 239000003973 paint Substances 0.000 description 8
- 238000000926 separation method Methods 0.000 description 8
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 7
- LCGLNKUTAGEVQW-UHFFFAOYSA-N Dimethyl ether Chemical compound COC LCGLNKUTAGEVQW-UHFFFAOYSA-N 0.000 description 7
- 235000011114 ammonium hydroxide Nutrition 0.000 description 7
- 210000003298 dental enamel Anatomy 0.000 description 7
- 239000012299 nitrogen atmosphere Substances 0.000 description 7
- 238000003756 stirring Methods 0.000 description 7
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 6
- 239000002253 acid Substances 0.000 description 6
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 5
- 230000000052 comparative effect Effects 0.000 description 5
- 239000003380 propellant Substances 0.000 description 5
- 239000011550 stock solution Substances 0.000 description 5
- POAOYUHQDCAZBD-UHFFFAOYSA-N 2-butoxyethanol Chemical compound CCCCOCCO POAOYUHQDCAZBD-UHFFFAOYSA-N 0.000 description 4
- QUSNBJAOOMFDIB-UHFFFAOYSA-N Ethylamine Chemical compound CCN QUSNBJAOOMFDIB-UHFFFAOYSA-N 0.000 description 4
- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 description 4
- 239000003795 chemical substances by application Substances 0.000 description 4
- 239000002994 raw material Substances 0.000 description 4
- 239000000243 solution Substances 0.000 description 4
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 3
- JAHNSTQSQJOJLO-UHFFFAOYSA-N 2-(3-fluorophenyl)-1h-imidazole Chemical compound FC1=CC=CC(C=2NC=CN=2)=C1 JAHNSTQSQJOJLO-UHFFFAOYSA-N 0.000 description 3
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 3
- ZNQVEEAIQZEUHB-UHFFFAOYSA-N 2-ethoxyethanol Chemical compound CCOCCO ZNQVEEAIQZEUHB-UHFFFAOYSA-N 0.000 description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 3
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 3
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- ZMANZCXQSJIPKH-UHFFFAOYSA-N Triethylamine Chemical compound CCN(CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-N 0.000 description 3
- 230000002776 aggregation Effects 0.000 description 3
- 239000002518 antifoaming agent Substances 0.000 description 3
- 238000005260 corrosion Methods 0.000 description 3
- 230000007797 corrosion Effects 0.000 description 3
- GMSCBRSQMRDRCD-UHFFFAOYSA-N dodecyl 2-methylprop-2-enoate Chemical compound CCCCCCCCCCCCOC(=O)C(C)=C GMSCBRSQMRDRCD-UHFFFAOYSA-N 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- LVHBHZANLOWSRM-UHFFFAOYSA-N methylenebutanedioic acid Natural products OC(=O)CC(=C)C(O)=O LVHBHZANLOWSRM-UHFFFAOYSA-N 0.000 description 3
- 239000007921 spray Substances 0.000 description 3
- GOXQRTZXKQZDDN-UHFFFAOYSA-N 2-Ethylhexyl acrylate Chemical compound CCCCC(CC)COC(=O)C=C GOXQRTZXKQZDDN-UHFFFAOYSA-N 0.000 description 2
- SOGAXMICEFXMKE-UHFFFAOYSA-N Butylmethacrylate Chemical compound CCCCOC(=O)C(C)=C SOGAXMICEFXMKE-UHFFFAOYSA-N 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 description 2
- VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- 238000004220 aggregation Methods 0.000 description 2
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical group CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 description 2
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 2
- 239000012895 dilution Substances 0.000 description 2
- 238000010790 dilution Methods 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 238000005342 ion exchange Methods 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 description 2
- 150000002978 peroxides Chemical class 0.000 description 2
- 230000000704 physical effect Effects 0.000 description 2
- 238000001556 precipitation Methods 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 2
- 239000003021 water soluble solvent Substances 0.000 description 2
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 description 1
- WDQMWEYDKDCEHT-UHFFFAOYSA-N 2-ethylhexyl 2-methylprop-2-enoate Chemical compound CCCCC(CC)COC(=O)C(C)=C WDQMWEYDKDCEHT-UHFFFAOYSA-N 0.000 description 1
- OMIGHNLMNHATMP-UHFFFAOYSA-N 2-hydroxyethyl prop-2-enoate Chemical compound OCCOC(=O)C=C OMIGHNLMNHATMP-UHFFFAOYSA-N 0.000 description 1
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 1
- 229920000298 Cellophane Polymers 0.000 description 1
- WOBHKFSMXKNTIM-UHFFFAOYSA-N Hydroxyethyl methacrylate Chemical compound CC(=C)C(=O)OCCO WOBHKFSMXKNTIM-UHFFFAOYSA-N 0.000 description 1
- CERQOIWHTDAKMF-UHFFFAOYSA-M Methacrylate Chemical compound CC(=C)C([O-])=O CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 description 1
- LSDPWZHWYPCBBB-UHFFFAOYSA-N Methanethiol Chemical compound SC LSDPWZHWYPCBBB-UHFFFAOYSA-N 0.000 description 1
- GYCMBHHDWRMZGG-UHFFFAOYSA-N Methylacrylonitrile Chemical compound CC(=C)C#N GYCMBHHDWRMZGG-UHFFFAOYSA-N 0.000 description 1
- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 description 1
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 1
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 238000005054 agglomeration Methods 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 239000007869 azo polymerization initiator Substances 0.000 description 1
- 235000015278 beef Nutrition 0.000 description 1
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 150000001735 carboxylic acids Chemical class 0.000 description 1
- 239000012986 chain transfer agent Substances 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 239000010960 cold rolled steel Substances 0.000 description 1
- 238000007334 copolymerization reaction Methods 0.000 description 1
- LDHQCZJRKDOVOX-NSCUHMNNSA-N crotonic acid Chemical compound C\C=C\C(O)=O LDHQCZJRKDOVOX-NSCUHMNNSA-N 0.000 description 1
- 238000000113 differential scanning calorimetry Methods 0.000 description 1
- 239000002270 dispersing agent Substances 0.000 description 1
- 125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 239000002320 enamel (paints) Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- UIWXSTHGICQLQT-UHFFFAOYSA-N ethenyl propanoate Chemical compound CCC(=O)OC=C UIWXSTHGICQLQT-UHFFFAOYSA-N 0.000 description 1
- SUPCQIBBMFXVTL-UHFFFAOYSA-N ethyl 2-methylprop-2-enoate Chemical compound CCOC(=O)C(C)=C SUPCQIBBMFXVTL-UHFFFAOYSA-N 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 239000004088 foaming agent Substances 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 238000010528 free radical solution polymerization reaction Methods 0.000 description 1
- 239000001530 fumaric acid Substances 0.000 description 1
- 231100001261 hazardous Toxicity 0.000 description 1
- 229920001519 homopolymer Polymers 0.000 description 1
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 1
- 239000011976 maleic acid Substances 0.000 description 1
- 239000004570 mortar (masonry) Substances 0.000 description 1
- 239000000025 natural resin Substances 0.000 description 1
- 238000006386 neutralization reaction Methods 0.000 description 1
- 150000002825 nitriles Chemical class 0.000 description 1
- 125000002347 octyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 150000001451 organic peroxides Chemical class 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 238000010422 painting Methods 0.000 description 1
- XNGIFLGASWRNHJ-UHFFFAOYSA-L phthalate(2-) Chemical compound [O-]C(=O)C1=CC=CC=C1C([O-])=O XNGIFLGASWRNHJ-UHFFFAOYSA-L 0.000 description 1
- 231100000614 poison Toxicity 0.000 description 1
- 230000007096 poisonous effect Effects 0.000 description 1
- 239000002685 polymerization catalyst Substances 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 230000002269 spontaneous effect Effects 0.000 description 1
- 229920003002 synthetic resin Polymers 0.000 description 1
- 239000000057 synthetic resin Substances 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
- LDHQCZJRKDOVOX-UHFFFAOYSA-N trans-crotonic acid Natural products CC=CC(O)=O LDHQCZJRKDOVOX-UHFFFAOYSA-N 0.000 description 1
Abstract
Description
【発明の詳細な説明】
〔産業上の利用分野〕
本発明は、光沢、安定性、色分かれ、耐水性、耐候性の
良い水性エアゾール用塗料組成物に関する。DETAILED DESCRIPTION OF THE INVENTION [Industrial Application Field] The present invention relates to an aqueous aerosol coating composition that has good gloss, stability, color separation, water resistance, and weather resistance.
従来のエアゾール塗料は、天然樹脂や合成樹脂からなる
ビヒクル成分を、トルエン、酢酸エチル、メチルエチル
ケトン等の有機溶剤に溶解し、使用している。しかし、
これらの溶剤は可燃性か強く、人体に有害なものか多い
ため取り扱いおよび使用上多くの問題点かあった。Conventional aerosol paints use a vehicle component made of natural or synthetic resin dissolved in an organic solvent such as toluene, ethyl acetate, or methyl ethyl ketone. but,
These solvents are often flammable or strong, and often harmful to the human body, posing many problems in handling and use.
このため、エアゾール塗料を弱燃性もしくは、不燃性と
し非危険物とするために種々のエアゾール用塗料か検討
され、溶剤としてトリクレン等の塩素化合物、噴射剤と
してフルオロカーホンを用い、弱燃性としたものもある
か、これらにおいても溶剤か有毒であったり、フルオロ
カーホンによるオゾン破壊の問題かある。For this reason, various aerosol paints have been studied in order to make aerosol paints weakly flammable or non-flammable and non-hazardous. There are also problems with these, such as solvents, poisonous substances, and ozone depletion due to fluorocarbons.
また、水溶性樹脂を用い、噴射剤としてジメチルエーテ
ル等を使用した水性エアゾール用塗料か検討されている
。Also, a water-based aerosol paint using a water-soluble resin and dimethyl ether as a propellant is being considered.
しかし、これらの水性エアゾール用塗料は、顔料および
ジメチルエーテル等の噴射剤を充填しエアソ−ル化した
場合、貯蔵安定性か悪い、色分かれか著しい、光沢かて
ない、顔料分散性か悪い、スプレー時の微粒化か悪いな
と欠点かあった。However, when these water-based aerosol paints are filled with pigments and propellants such as dimethyl ether and made into aerosols, they have poor storage stability, significant color separation, lack of gloss, poor pigment dispersibility, and spray problems. There was a drawback that it was probably due to the atomization of time.
本発明者らはこれらの欠点、特に顔料と噴射剤を充填し
、エアゾール化した状態での光沢、安定性、色分かれを
改善した水性エアゾール用塗料を得るへく鋭意検討の結
果、本発明に到達した。The present inventors have conducted intensive studies to overcome these drawbacks, particularly in order to obtain a water-based aerosol paint that improves gloss, stability, and color separation when filled with pigments and propellants and is turned into an aerosol. Reached.
すなわち、本発明はメタクリル酸メチル３０〜６０重量
％、好ましくは２０〜５０重量％、スチレン１０〜３０
重量％、好ましくは１５〜２０重量％、炭素数４〜１８
の（メタ）アクリル酸エステル１０〜４０重量％、好ま
しくは２０〜３０重量％、水酸基を含んだ（メタ）アク
リル酸エステル３〜１０重量％、好ましくは４〜８重量
％、エチレン性不飽和カルボン酸３〜１０重量％、好ま
しくは５〜８重量％、その他の共重合可能な単量体０〜
２０重量％から得られた共重合体を揮発性の塩基性物質
で中和、水希釈して得られ、数平均分子ｊ１５０００〜
２００００、ガラス転移温度３０〜６００℃、ＳＰ値９
５〜１０．５のアクリル系水性樹脂と、２〜２０重量％
のアルキッド樹脂とからなる塗料組成物であり、顔料と
噴射剤を充填し、エアソール化した状態で色分かれかな
く、光沢、安定性、顔料分散性、スプレー時の微粒化性
、耐水性、耐候性か優れた水性エアゾール用塗料組成物
である。That is, the present invention uses 30 to 60% by weight of methyl methacrylate, preferably 20 to 50% by weight, and 10 to 30% by weight of styrene.
% by weight, preferably 15-20% by weight, carbon number 4-18
(meth)acrylic acid ester 10 to 40% by weight, preferably 20 to 30% by weight, (meth)acrylic acid ester containing a hydroxyl group 3 to 10% by weight, preferably 4 to 8% by weight, ethylenically unsaturated carboxyl. 3 to 10% by weight of acid, preferably 5 to 8% by weight, and 0 to 10% of other copolymerizable monomers.
It is obtained by neutralizing the copolymer obtained from 20% by weight with a volatile basic substance and diluting it with water, and the number average molecule is j15000~
20000, glass transition temperature 30-600℃, SP value 9
5 to 10.5 acrylic water-based resin and 2 to 20% by weight
It is a coating composition consisting of an alkyd resin filled with pigment and a propellant, and when airsoled, it does not separate in color, and has gloss, stability, pigment dispersibility, atomization during spraying, water resistance, and weather resistance. This is a water-based aerosol coating composition with excellent properties.
以下、詳しく説明する。This will be explained in detail below.
本発明で使用するメタクリル酸メチルの使用量か３０重
量％未満ては乾燥性や硬度が不十分て、６０重量％を越
えると塗面状態や耐酸性、耐水性が悪くなる。If the amount of methyl methacrylate used in the present invention is less than 30% by weight, the drying properties and hardness will be insufficient, and if it exceeds 60% by weight, the coated surface condition, acid resistance, and water resistance will deteriorate.
本発明で使用するスチレンの使用量は、１０重量％未満
では十分な光沢、耐酸性、耐水性が得られず３０重量％
を越えると、水希釈性が悪く、安定性が低下し、塗膜の
光沢も悪くなる。If the amount of styrene used in the present invention is less than 10% by weight, sufficient gloss, acid resistance, and water resistance cannot be obtained, so the amount of styrene used is 30% by weight.
If it exceeds this value, the water dilutability will be poor, the stability will be reduced, and the gloss of the coating film will also be poor.
本発明で使用する炭素数４〜１８の（メタ）アクリル酸
エステルとしては、（メタ）アクリル酸（イソ）ブチル
、（メタ）アクリル酸オクチル、（メタ）アクリル酸２
エチルヘキンル、（メタ）アクリル酸ラウリル、（メタ
）アクリル酸トリデンル等か挙げられ、５重量％未満て
は耐水、耐食性低下となり、２０重量％を越えると硬度
低下となる。また、ガラス転移温度の調整および物性の
バランスを図るため、炭素数４以上か必要で、炭素数か
１８を越えると共重合性か悪くなり、ｌｔｉ候性、水希
釈性、安定性か低下する。The (meth)acrylic esters having 4 to 18 carbon atoms used in the present invention include (iso)butyl (meth)acrylate, octyl (meth)acrylate, and di(meth)acrylate.
Examples include ethylhexyl, lauryl (meth)acrylate, and tridenyl (meth)acrylate. If the content is less than 5% by weight, water resistance and corrosion resistance will decrease, and if it exceeds 20% by weight, hardness will decrease. In addition, in order to adjust the glass transition temperature and balance the physical properties, it is necessary to have a carbon number of 4 or more, and if the carbon number exceeds 18, the copolymerizability will deteriorate, and the lti resistance, water dilutability, and stability will decrease. .
本発明で使用する水酸基を含んだ（メタ）アクリル酸エ
ステルとしては、（メタ）アクリル酸２ヒドロキンエチ
ル、（メタ）アクリル酸ヒドロキンプロピル等が挙げら
れる。これらは、安定性、色分かれ性の良い水性塗料を
得るうえて重要な成分てあり、３重量％未満ては十分な
水希釈性、安定性か得られず１０重量％を越えると耐水
性か悪くなる。Examples of the (meth)acrylic acid ester containing a hydroxyl group used in the present invention include dihydroquinethyl (meth)acrylate, hydroquinepropyl (meth)acrylate, and the like. These are important components for obtaining water-based paints with good stability and color separation; if it is less than 3% by weight, sufficient water dilutability and stability cannot be obtained, and if it exceeds 10% by weight, water resistance may not be obtained. Deteriorate.
本発明で使用するエチレン性不飽和カルボン酸としては
、（メタ）アクリル酸、イタコン酸、クロトン酸、マレ
イン酸、フマル酸およびこれらのハーフエステル類等が
挙げられ、３重量％未満ては水希釈性が悪く、１０重量
％を越えると耐食性、耐水性が悪く顔料の凝集か起こり
易くなる。Ethylenically unsaturated carboxylic acids used in the present invention include (meth)acrylic acid, itaconic acid, crotonic acid, maleic acid, fumaric acid, and half esters thereof, and if less than 3% by weight, diluted with water. If it exceeds 10% by weight, corrosion resistance and water resistance will be poor, and pigment agglomeration is likely to occur.
本発明で使用できるその他の共重合可能な単量体として
は、アクリロニトリル、メタクリロニトリル、酢酸ビニ
ル、プロピオン酸ビニル、アクリル酸メチル、（メタ）
アクリル酸エチル、（メタ）アクリル酸（イソ）プロピ
ル等か挙げられる。Other copolymerizable monomers that can be used in the present invention include acrylonitrile, methacrylonitrile, vinyl acetate, vinyl propionate, methyl acrylate, (meth)
Examples include ethyl acrylate and (iso)propyl (meth)acrylate.
本発明で使用する揮発性の塩基性物質としては、アンモ
ニア、モノエチルアミン、ンエチルアミン、トリエチル
アミン、モノエタノールアミン、ジメチルメタノールア
ミン等か挙げられる。この塩基性物質の使用量は、前記
共重合体中のカルホキシル基当量の６０〜１５０％を中
和する量とされる。Examples of the volatile basic substance used in the present invention include ammonia, monoethylamine, ethylamine, triethylamine, monoethanolamine, dimethylmethanolamine, and the like. The amount of the basic substance to be used is such as to neutralize 60 to 150% of the carboxyl group equivalents in the copolymer.
本発明で得られる共重合体の数平均分子量は５０００〜
２００００で、５０００未満ては耐水性、耐薬品性、塗
装時の微粒化が悪＜、２００００を越えると粘度が高す
き、作業性か悪くなる。また、この共重合体のガラス転
移温度は３０〜６０°Ｃてあり、３０’Ｃ未満ては不粘
着性か悪く、硬度か不十分てあり、６０’Ｃを越えると
乾燥後、塗膜の割れか起こる。ガラス転移温度の測定は
示差走査熱量測定で行った。また次の理論式からも算出
てきる。The number average molecular weight of the copolymer obtained in the present invention is 5000~
If it is less than 5,000, water resistance, chemical resistance, and atomization during coating will be poor; if it exceeds 20,000, the viscosity will be high and workability will be poor. In addition, the glass transition temperature of this copolymer is 30 to 60°C, and if it is less than 30'C, it is not tack-free or has insufficient hardness, and if it exceeds 60'C, the coating film will deteriorate after drying. Cracks may occur. The glass transition temperature was measured by differential scanning calorimetry. It can also be calculated from the following theoretical formula.
Ｔｇ Ｔｇ＋ Ｔｇ２ ＴｇｎＴ
ｇ：共重合体のガラス転移温度
Ｔｇ、、各ホモポリマーのガラス転移温度Ｗ、、：各モ
ノマーの重量分率
さらに、この共重合体のＳＰ値は９５〜１０．５てあり
、９５未満ては水希釈性、エナメル安定性か悪く、ｌ
Ｏ，５を越えると耐水性、耐食性が悪くなる。Tg Tg+ Tg2 TgnT
g: Glass transition temperature Tg of the copolymer, Glass transition temperature W of each homopolymer, .: Weight fraction of each monomer Furthermore, the SP value of this copolymer is 95 to 10.5, and less than 95. has poor water dilutability and enamel stability.
If it exceeds O.5, water resistance and corrosion resistance will deteriorate.
また、本発明でのＳＰ値は次の式から求められる。Further, the SP value in the present invention is obtained from the following formula.
ＳＰ値−（ΔＥ ／ Ｖ ） ｌ／２
ΔＥ：モル蒸発工不ルキー
■０モル体積
本発明における共重合体の重合は特に限定されないか、
水溶性溶媒を用いた溶液重合法によって行うことか好ま
しい。重合用触媒としては、アゾビスイソブチロニトリ
ルの如き、アゾ系重合開始剤や過酸化ヘンソイルの如き
有機過酸化物なとか用いられる。また、分子量調節を目
的に、メルカプタンのような連鎖移動剤を用いることも
てきる。SP value - (ΔE/V) l/2 ΔE: molar evaporation coefficient ■0 molar volume Is the polymerization of the copolymer in the present invention not particularly limited?
It is preferable to carry out by a solution polymerization method using a water-soluble solvent. As the polymerization catalyst, an azo polymerization initiator such as azobisisobutyronitrile or an organic peroxide such as hensyl peroxide may be used. Furthermore, a chain transfer agent such as a mercaptan may be used for the purpose of controlling the molecular weight.
また、水溶性溶媒としては、エチレングリコールエチル
エーテル、エチレングリコールブチルエーテル、イソプ
ロピルアルコール、ｎ−フロビルアルコールなとか用い
られる。Further, as the water-soluble solvent, ethylene glycol ethyl ether, ethylene glycol butyl ether, isopropyl alcohol, n-furobyl alcohol, etc. are used.
また、塩基性物質での中和および水希釈は、共重合終了
後の反応生成物中に撹拌下、塩基性物質および水を加え
る方法でも行うことかできる。Further, neutralization with a basic substance and dilution with water can also be carried out by adding the basic substance and water to the reaction product after completion of copolymerization while stirring.
本発明で使用するアルキッド樹脂は、スフレ−適性、塗
面状態、エナメル安定性等を向上させるために、不可欠
な成分であり、その添加方法は、水溶性アクリル樹脂を
共重合する時に添加するか、共重合した水溶性アクリル
樹脂に後から添加しても良い。The alkyd resin used in the present invention is an essential component in order to improve soufflé suitability, coating surface condition, enamel stability, etc., and its addition method is either by adding it when copolymerizing the water-soluble acrylic resin, or by adding it when copolymerizing the water-soluble acrylic resin. , may be added later to the copolymerized water-soluble acrylic resin.
アルキッド樹脂の添加量か２重量％以下では、安定性、
顔料分散性、スプレー時の微粒化か悪く、２０重量％を
越えると、耐水性、耐酸性等の塗膜物性か低下する。If the amount of alkyd resin added is less than 2% by weight, the stability
Pigment dispersibility and atomization during spraying are poor, and if it exceeds 20% by weight, physical properties of the coating film such as water resistance and acid resistance will deteriorate.
本発明には一般に市販されているアルキッド樹脂か使用
できる。Commercially available alkyd resins can be used in the present invention.
本発明の塗料組成物は、顔料およびンメチルエーテル等
の噴射剤を充填し、エアゾール化した状態での顔料分散
性、貯蔵安定性に優れており、色分かれかなく、光沢、
耐水性、耐候性の良い塗膜を形成するものである。また
、必要に応して消泡剤、分散剤、レヘリング剤等の任意
の添加剤を添加することもてきる。The coating composition of the present invention is filled with a pigment and a propellant such as methyl ether, and has excellent pigment dispersibility and storage stability in an aerosolized state, does not cause color separation, has gloss,
It forms a coating film with good water resistance and weather resistance. Further, optional additives such as an antifoaming agent, a dispersing agent, and a leveling agent may be added as necessary.
以下に、具体例を示し、作用効果を明確にする。Specific examples are shown below to clarify the effects.
（実施例１）
プロピレングリコールメチルエーテル４０重量部を２Ｑ
のフラスコに仕込み、窒素雰囲気中で撹拌下、１００°
Ｃに保持し、この中にメタクリル酸メチル５０重量部、
スチレン１５重量部、アクリル酸２−ヒドロキノエチル
５重量部、イタフン酸５重量部、アクリル酸ブチル１５
重量部、メタアクリル酸ブチル１０重量部、アゾビスイ
ソブチロニｌ−１）ル１重量部を３時間で滴下する。(Example 1) 40 parts by weight of propylene glycol methyl ether was added to 2Q
in a flask and heated at 100° under stirring in a nitrogen atmosphere.
C, in which 50 parts by weight of methyl methacrylate,
15 parts by weight of styrene, 5 parts by weight of 2-hydroquinoethyl acrylate, 5 parts by weight of itafonic acid, 15 parts by weight of butyl acrylate
parts by weight, 10 parts by weight of butyl methacrylate, and 1 part by weight of azobisisobutyronyl 1-1) were added dropwise over 3 hours.
滴下終了後、フラスコ内を１００°Ｃに保持し、４時間
撹拌する。その後、６０°Ｃ迄冷却し、２８％アンモニ
ア水ｌ水重量部、水５０重量部、イソプロピルアルコー
ル３０重量部を加える。After the dropwise addition is completed, the inside of the flask is maintained at 100°C and stirred for 4 hours. Thereafter, the mixture was cooled to 60°C, and 1 part by weight of 28% aqueous ammonia, 50 parts by weight of water, and 30 parts by weight of isopropyl alcohol were added.
得られた共重合物のＴｇは５６°Ｃ，ＳＰ値は９５、数
平均分子量は１７０００であった。上記の水溶性アクリ
ル樹脂に、日立化成工業（株）類フタルキットＷ−７６
０を５重量部添加した。The obtained copolymer had a Tg of 56°C, an SP value of 95, and a number average molecular weight of 17,000. The above water-soluble acrylic resin, Hitachi Chemical Co., Ltd. Phthal Kit W-76
0 was added in an amount of 5 parts by weight.
（実施例２）
エチレングリコールエチルエーテル５０重１ｔｅおよび
日立化成工業（株）ニスペル１２４ １０重量部を２Ｑ
のフラスコに仕込み、窒素雰囲気中で撹拌下、１２０°
Ｃに保持し、この中にメタクリル酸メチル４０重量部、
スチレン２０重量部、メタアクリル酸２−ヒトクキ／エ
チル５重量部、メタアクリル酸９重量部、アクリル酸２
−エチルヘキンル１６重量部、メタアクリル酸ラウリル
１０重量部、過酸化ヘンジイル３重量部を４時間で滴下
する。(Example 2) 2Q of 50 parts by weight of ethylene glycol ethyl ether and 10 parts by weight of Nispel 124 manufactured by Hitachi Chemical Co., Ltd.
in a flask and heated at 120° under stirring in a nitrogen atmosphere.
C, in which 40 parts by weight of methyl methacrylate,
20 parts by weight of styrene, 5 parts by weight of 2-methacrylate/ethyl methacrylate, 9 parts by weight of methacrylic acid, 2 parts by weight of acrylic acid
- 16 parts by weight of ethyl hequinyl, 10 parts by weight of lauryl methacrylate, and 3 parts by weight of hendiyl peroxide are added dropwise over 4 hours.
滴下終了後、フラスコ内を１２０°Ｃに保持し、４時間
撹拌する。その後、６０’Ｃ迄冷却し２８％アンモニア
水１０重量部、水５０重量部、イソプロヒルアルコール
２０重量部を加える。After completion of the dropwise addition, the inside of the flask was maintained at 120°C and stirred for 4 hours. Thereafter, the mixture was cooled to 60'C, and 10 parts by weight of 28% ammonia water, 50 parts by weight of water, and 20 parts by weight of isoproyl alcohol were added.
得られた共重合物のＴｇは３８°ｃ、ｓｐ値は９．８、
数平均分子量は８０００てあった。The Tg of the obtained copolymer was 38°C, the sp value was 9.8,
The number average molecular weight was 8,000.
（実施例３）
エチレングリコールエチルエーテル４０重ｊ１部を２Ｑ
のフラスコに仕込み、窒素雰囲気中で撹拌下、１１０°
ｃに保持し、この中にメタクリル酸メチル３５重量部、
スチレン２５重量部、アクリル酸２−ヒドロキンプロピ
ル５重量部、アクリル酸７重量部、アクリル酸エチル４
重量部、メタアクリル酸ラウリル１８重量部、アクリル
酸ブチル１０重量部、アゾビスイソブチロニトリル２重
量部を４時間で滴下する。(Example 3) 1 part of 40% ethylene glycol ethyl ether was added to 2Q
in a flask and heated at 110° under stirring in a nitrogen atmosphere.
c, in which 35 parts by weight of methyl methacrylate,
25 parts by weight of styrene, 5 parts by weight of 2-hydroquinepropyl acrylate, 7 parts by weight of acrylic acid, 4 parts by weight of ethyl acrylate
18 parts by weight of lauryl methacrylate, 10 parts by weight of butyl acrylate, and 2 parts by weight of azobisisobutyronitrile were added dropwise over 4 hours.
滴下終了後、フラスコ内を１１０℃に保持し、４時間撹
拌する。その後、６０’Ｃ迄冷却し、２８％アンモニア
水１０重量部、水３０重量部、イソプロピルアルコール
３０重量部を加える。After the dropwise addition is completed, the inside of the flask is maintained at 110°C and stirred for 4 hours. Thereafter, the mixture was cooled to 60'C, and 10 parts by weight of 28% ammonia water, 30 parts by weight of water, and 30 parts by weight of isopropyl alcohol were added.
得られた共重合物のＴｇは３５°ｃ、ｓｐ値は９８、数
平均分子量は１４０００てあった。The obtained copolymer had a Tg of 35°C, an sp value of 98, and a number average molecular weight of 14,000.
上記の水溶性アクリル樹脂に、播磨化成工業株式会社製
ＡＤ−１０３を１５重量部添加した。15 parts by weight of AD-103 manufactured by Harima Kasei Kogyo Co., Ltd. was added to the above water-soluble acrylic resin.
（比較例１）
プロピレングリコールメチルエーテル４０重量部を２Ｑ
のフラスコに仕込み、窒素雰囲気中で撹拌下、１２０°
Ｃに保持し、この中にメタクリル酸メチル３５重量部、
スチレン３０重量部、メタアクリル酸２−ヒドロキシエ
チル５重量部、アクリル酸５重量部、メタアクリル酸ラ
ウリル１０重量部、アクリル酸２−エチルヘキンル１５
重量部、アブビスイソブチロニトリル３重量部を３時間
で滴下する。(Comparative Example 1) 40 parts by weight of propylene glycol methyl ether was added to 2Q
in a flask and heated at 120° under stirring in a nitrogen atmosphere.
C, in which 35 parts by weight of methyl methacrylate,
30 parts by weight of styrene, 5 parts by weight of 2-hydroxyethyl methacrylate, 5 parts by weight of acrylic acid, 10 parts by weight of lauryl methacrylate, 15 parts by weight of 2-ethylhexyl acrylate
3 parts by weight of abbisisobutyronitrile were added dropwise over 3 hours.
滴下終了後、フラスコ内を１２０°Ｃに保持し、４時間
撹拌する。その後、６０°Ｃ迄冷却し、２８％アンモニ
ア水１０重量部、水５０重量部、イソプロピルアルコー
ル３０重量部を加える。After completion of the dropwise addition, the inside of the flask was maintained at 120°C and stirred for 4 hours. Thereafter, the mixture was cooled to 60°C, and 10 parts by weight of 28% ammonia water, 50 parts by weight of water, and 30 parts by weight of isopropyl alcohol were added.
得られた共重合物のＴｇは３７°ｃ、ｓｐ値は９．５、
数平均分子量は６０００てあった。これに、日立化成工
業（株）製フタル牛ノドＷ−７６０を１重量部添加した
。The Tg of the obtained copolymer was 37°C, the sp value was 9.5,
The number average molecular weight was 6,000. To this was added 1 part by weight of Phthalate Beef Throat W-760 manufactured by Hitachi Chemical Co., Ltd.
（比較例２）
プロピレングリコールメチルエーテル４ｏ重を部を２ｇ
のフラスコに仕込み、窒素雰囲気中で撹拌下、１００°
Ｃに保持し、この中にメタクリル酸メチル５０重量部、
スチレン１５重量部、アクリル酸２−ヒドロキシエチル
５重量部、イタコン酸５重量部、アクリルブチル２５重
量部、アゾビスイソブチロニトリル１重量部を３時間で
滴下する。(Comparative Example 2) Propylene glycol methyl ether 40 parts by weight 2g
in a flask and heated at 100° under stirring in a nitrogen atmosphere.
C, in which 50 parts by weight of methyl methacrylate,
15 parts by weight of styrene, 5 parts by weight of 2-hydroxyethyl acrylate, 5 parts by weight of itaconic acid, 25 parts by weight of acrylic butyl, and 1 part by weight of azobisisobutyronitrile are added dropwise over 3 hours.
滴下終了後、フラスコ内を１００’Ｃに保持し、４時間
撹拌する。その後、６０°Ｃ迄冷却し、２８％アンモニ
ア水Ｉ水重量部、水５ＯＮ量部、イソプロピルアルコー
ル３０重量部を加える。After completion of the dropwise addition, the inside of the flask was maintained at 100'C and stirred for 4 hours. Thereafter, the mixture was cooled to 60° C., and 28% aqueous ammonia I, 5 parts by weight of water, and 30 parts by weight of isopropyl alcohol were added.
得られた共重合物のＴｇは４５°ｃ、ｓｐ値は９７、数
平均分子量は、１９０００てあった。The obtained copolymer had a Tg of 45°C, an sp value of 97, and a number average molecular weight of 19,000.
この水溶性アクリル樹脂に日立化成工業（株）製フタル
キットＷ−７６０を３５重量部添加した。35 parts by weight of Phthalkit W-760 manufactured by Hitachi Chemical Co., Ltd. was added to this water-soluble acrylic resin.
（比較例３）
プロピレングリコールメチルエーテル４０重量部を２ａ
のフラスコに仕込み、窒素雰囲気中で撹拌下、１２０°
Ｃに保持し、この中にメタクリル酸メチル３０重量部、
スチレン３０重量部、メタアクリル酸２−ヒドロキンプ
ロピル４重量部、メタアクリル酸４重量部、アクリル酸
２−エチルヘキ／ル２８重量部、メタアクリル酸２−エ
チルヘキンル４重量部、アブビスイソブチロニトリル１
５重量部を３時間で滴下する。(Comparative Example 3) 40 parts by weight of propylene glycol methyl ether was added to 2a
in a flask and heated at 120° under stirring in a nitrogen atmosphere.
C, in which 30 parts by weight of methyl methacrylate,
30 parts by weight of styrene, 4 parts by weight of 2-hydroquinpropyl methacrylate, 4 parts by weight of methacrylic acid, 28 parts by weight of 2-ethylhexyl acrylate, 4 parts by weight of 2-ethylhexyl methacrylate, abbisisobutylene Nitrile 1
5 parts by weight are added dropwise over 3 hours.
滴下終了後、フラスコ内を１２０’Ｃに保持し、４時間
撹拌する。その後、６０°Ｃ迄冷却し、２８％アンモニ
ア水１０重量部、水５０重量部、イソプロピルアルコー
ル３０重量部を加える。After completion of the dropwise addition, the inside of the flask was maintained at 120'C and stirred for 4 hours. Thereafter, the mixture was cooled to 60°C, and 10 parts by weight of 28% ammonia water, 50 parts by weight of water, and 30 parts by weight of isopropyl alcohol were added.
得られた共重合物のＴｇは３５°Ｃ，ｓｐ値は９３、数
平均分子量は１００００てあった。これに、同様にフタ
ルキッドＷ−７６０を１０重量部添加した。The obtained copolymer had a Tg of 35°C, an sp value of 93, and a number average molecular weight of 10,000. To this, 10 parts by weight of Phthalkyd W-760 was added in the same manner.
（比較例４）
プロピレングリコールメチルエーテル４０１ｉ量部を２
Ｑのフラスコに仕込み、窒素雰囲気中で撹拌下、１１０
°Ｃに保持し、この中にメタクリル酸メチル６０重量部
、スチレン５重量部、アクリル酸２−ヒドロキンエチル
１５重量部、イタコン酸１３重量部、アクリル酸メチル
１１重量部、アソビスイソブチロニトリル１５重量部を
３時間で滴下する。(Comparative Example 4) 2 parts of propylene glycol methyl ether 401i
Q flask and stirred in a nitrogen atmosphere at 110
60 parts by weight of methyl methacrylate, 5 parts by weight of styrene, 15 parts by weight of 2-hydroquinethyl acrylate, 13 parts by weight of itaconic acid, 11 parts by weight of methyl acrylate, and azobisisobutyronitrile. 15 parts by weight are added dropwise over 3 hours.
滴下終了後、フラスコ内を１２０°Ｃに保持し、４時間
撹拌する。その後、６０°Ｃ迄冷却し、２８％アンモニ
ア水１０重量部、水５０重量部、イソフロビルアルコー
ル３０重量部を加える。After completion of the dropwise addition, the inside of the flask was maintained at 120°C and stirred for 4 hours. Thereafter, the mixture was cooled to 60°C, and 10 parts by weight of 28% aqueous ammonia, 50 parts by weight of water, and 30 parts by weight of isoflovir alcohol were added.
得られた共重合物のＴｇは７６°ｃＳｓｐ値は１０８、
数平均分子量はｌ ５０００てあった。The obtained copolymer had a Tg of 76°cSsp value of 108,
The number average molecular weight was 15000.
これにフタルキットＷ−７６ｏを１５重量部添加した。To this was added 15 parts by weight of Phthalkit W-76o.
次に、上記実施例および比較例で得られた水溶性樹脂溶
液を用いて、下記の配合でクリヤ、エナメル塗料を調製
し塗膜性能の評価を行なった。Next, using the water-soluble resin solutions obtained in the above Examples and Comparative Examples, clear and enamel paints were prepared with the following formulations, and the coating performance was evaluated.
表−１，２に示すように、優れた塗膜物性を持った水性
エアゾール用塗料か得られた。As shown in Tables 1 and 2, a water-based aerosol paint with excellent film properties was obtained.
原 料
水溶性樹脂溶液
ブチルセロソルブ
プロピレングリコールメチルエーテル
イオン交換水
消泡剤（Ｌ４７５）＊ル
ヘリング剤（ＢＹＫＯ）＊２
合 計
重量部
エナメル原液配合（白）
原 料
水溶性樹脂溶液
ブチルセロソルブ
フロピレンゲリコールメチルエーテル
イオン交換水
二酸化チタン（ＣＲ−８０）＊３
消泡剤（Ｌ４７５）
レヘリング剤（ＢＹＫＯ）
合 計
エナメル原液配合（黒）
原 料
水溶性樹脂溶液
ブチルセロソルブ
フロピレンゲリコールメチルエーテル
イオン交換水
カーホンブラ、り（ＭＡ−１００）＊４１肖泡剤 （Ｌ
４ ７ ５）
レヘリング剤（ＢＹＫＯ）
合 計
重量部
＊１ タウ ケミカル社
＊ ２ ： Ｂｙｋ−Ｃｈｅｍｉｅ社
＊３６原産業
＊４ 三菱化成
色分かれについては、上記臼と黒のエナメルを１で混合
して試料とした。Raw materials Water-soluble resin solution Butyl cellosolve propylene glycol methyl ether Ion-exchanged water Antifoaming agent (L475) * Ruchering agent (BYKO) *2 Total parts by weight Enamel stock solution blend (white) Raw materials Water-soluble resin solution Butyl cellosolve propylene glycol methyl Ether ion exchange water Titanium dioxide (CR-80) *3 Antifoaming agent (L475) Rehering agent (BYKO) Total Enamel stock solution combination (black) Raw materials Water-soluble resin solution Butyl cellosolve Furopylene gelicol Methyl ether Ion exchange water Carhombra, (MA-100) *41 foaming agent (L
4 7 5) Rehering agent (BYKO) Total parts by weight *1 Tau Chemical Co. *2: Byk-Chemie *36 Hara Sangyo *4 Mitsubishi Kasei For color separation, mix the above mortar and black enamel in 1. It was used as a sample.
エアゾール配合
原 料
容量％
ク
リヤ原液又はエナメル原液
ンメチルエーテル
計
（以
下
余
白）
基材・冷間圧延鋼板、（ＪＩＳ Ｇ ３１４１）ス
プレー性 ２０°Ｃ１一定時間、一定のノズルを通して
塗布。Aerosol compounding raw materials Volume % Clear stock solution or enamel stock solution / Methyl ether meter (blank below) Base material: Cold rolled steel plate, (JIS G 3141) Sprayability Apply through a fixed nozzle at 20°C for a fixed period of time.
水希釈性 原液の水希釈による粘度の増加、沈殿の発生
、顔料の凝集を調へた。Water dilutability: Increased viscosity, occurrence of precipitation, and aggregation of pigments due to dilution of the stock solution with water were controlled.
コハン目テスト １ｍｍ間隔に１００個のコハン目を形
成後、セロテープ剥離。Diagonal stitch test After forming 100 diagonal stitches at 1 mm intervals, remove the cellophane tape.
鉛筆硬度 三菱鉛筆ユニ使用。Pencil hardness: Uses Mitsubishi Pencil Uni.
光沢−・６０度鏡面光沢。Gloss: 60 degree mirror gloss.
耐水性・常温水に４８時間浸漬。Water resistant - immersed in room temperature water for 48 hours.
耐酸性 ５％硫酸に４８時間浸漬。Acid resistance: Soaked in 5% sulfuric acid for 48 hours.
ツルトスプレー 塩水噴霧４８時間浸漬。Tsuruto Spray - Soaked in salt water spray for 48 hours.
耐候性 ウェザ−メーター３００時間照射。外観にて判
定。Weather resistance Weather meter irradiation for 300 hours. Judging by appearance.
エナメル安定性 顔料分散後、４０’Ｃ１４週間後の顔
料の凝集、沈殿の有無
により判断。Enamel stability Judged by the presence or absence of pigment aggregation and precipitation 14 weeks after pigment dispersion at 40'C.
色わかれ性 塗装初期及び４０°Ｃ１２週間後の塗面状
態の差により判定。Color separation resistance Judged by the difference in the condition of the painted surface at the initial stage of painting and after 12 weeks at 40°C.
以上説明したように、この発明の水性エアゾル用塗料組
成物によれば、色分かれかなく、光沢か良好で、耐水性
、耐候性、面１薬品性に富む塗膜か得られ、貯蔵安定性
、顔料分散性、スプレー時の微粒化なとか優れるなとの
効果を得ることかできる。As explained above, according to the aqueous aerosol coating composition of the present invention, a coating film that does not cause color separation, has good gloss, is rich in water resistance, weather resistance, and chemical resistance, and has storage stability. It is possible to obtain excellent effects such as pigment dispersibility and atomization during spraying.
出願人 株式会社 アサヒペン 手 続 補 正 書 （自発）Applicant: Asahipen Co., Ltd. hand Continued Supplementary Positive book (spontaneous)
Claims (1)
３０重量％、炭素数４〜１８の（メタ）アクリル酸エス
テル１０〜４０重量％、水酸基を含んだ（メタ）アクリ
ル酸エステル３〜１０重量％、エチレン性不飽和カルボ
ン酸３〜１０重量％、その他の共重合可能な単量体０〜
２０重量％からなる共重合体を、揮発性の塩基性物質で
中和、水希釈して得られる数平均分子量５０００〜２０
０００、ガラス転移温度３０〜６００℃、ＳＰ値９．５
〜１０．５であるアクリル系水性樹脂と、２〜２０重量
％のアルキッド樹脂からなる水性エアゾール用塗料組成
物。Methyl methacrylate 30~60% by weight, styrene 10~
30% by weight, 10 to 40% by weight of (meth)acrylic ester having 4 to 18 carbon atoms, 3 to 10% by weight of (meth)acrylic ester containing a hydroxyl group, 3 to 10% by weight of ethylenically unsaturated carboxylic acid, Other copolymerizable monomers 0~
The number average molecular weight obtained by neutralizing a copolymer consisting of 20% by weight with a volatile basic substance and diluting with water is 5000 to 20.
000, glass transition temperature 30-600℃, SP value 9.5
An aqueous aerosol coating composition comprising an aqueous acrylic resin having a molecular weight of ~10.5 and an alkyd resin of 2 to 20% by weight.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2130825A JP2922583B2 (en) | 1990-05-21 | 1990-05-21 | Aqueous aerosol coating composition |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2130825A JP2922583B2 (en) | 1990-05-21 | 1990-05-21 | Aqueous aerosol coating composition |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH0425576A true JPH0425576A (en) | 1992-01-29 |
| JP2922583B2 JP2922583B2 (en) | 1999-07-26 |
Family
ID=15043593
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2130825A Expired - Fee Related JP2922583B2 (en) | 1990-05-21 | 1990-05-21 | Aqueous aerosol coating composition |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP2922583B2 (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102643590A (en) * | 2012-05-14 | 2012-08-22 | 汕头市鑫源化工有限公司 | Water-based paint and preparation method thereof |
| JP2018119088A (en) * | 2017-01-27 | 2018-08-02 | 大日本塗料株式会社 | Aqueous coating composition |
| JP2019081827A (en) * | 2017-10-30 | 2019-05-30 | 大日本塗料株式会社 | Aqueous coating material composition |
-
1990
- 1990-05-21 JP JP2130825A patent/JP2922583B2/en not_active Expired - Fee Related
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102643590A (en) * | 2012-05-14 | 2012-08-22 | 汕头市鑫源化工有限公司 | Water-based paint and preparation method thereof |
| JP2018119088A (en) * | 2017-01-27 | 2018-08-02 | 大日本塗料株式会社 | Aqueous coating composition |
| JP2019081827A (en) * | 2017-10-30 | 2019-05-30 | 大日本塗料株式会社 | Aqueous coating material composition |
Also Published As
| Publication number | Publication date |
|---|---|
| JP2922583B2 (en) | 1999-07-26 |
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