JPH04208214A - Hair dye for hair, its production and method for dyeing hair - Google Patents

Abstract

PURPOSE:To obtain a hair dye for hair capable of permeating a mordant capable of forming a complex with a vegetable pigment dye and forming a color and the above-mentioned vegetable pigment dye into hair tissues, polymerizing fine particles of metallic low molecular substances with the aforementioned vegetable pigment dye and coloring the hair by ionizing the mordant, providing the first agent and using the above-mentioned vegetable pigment dye permeating into the hair tissues as the second agent. CONSTITUTION:A hair dye composed of the first agent consisting essentially of a mordant composed of a metal of iron, chromium, manganese, etc., without damaging human bodies, an alcohol and purified water and the second agent consisting essentially of a vegetable pigment dye such as hematin, henna tannin or catechin, an alcohol and purified water. The first agent is permeated into hair tissues and ionized to provide a mordant. The resultant mordant as fine particles of metallic low molecular substances is made to remain in the hair tissues. The second agent is then permeated into the hair tissues to combine and polymerize the fine particles of the metallic low-molecular substances remaining in the above-mentioned tissues with the aforementioned dye in the hair tissues. Thereby, the hair tissues are incorporated, colored and fixed during the polymerization.

Description

[Detailed Description of the Invention] [Industrial Application Field] The present invention uses a mordant that forms a complex with a plant pigment dye to develop color, which is ionized and used as the first agent, and a plant pigment dye that penetrates into the hair tissue, which is used as the second agent. The first agent is infiltrated into the hair tissue to cause the ionized mordant to remain in the hair tissue as fine particles of low metal molecules, and the second agent is infiltrated into the hair tissue to remove the remaining fine particles of low metal molecules. The present invention relates to a hair dye for hair that is chemically combined and polymerized within the hair tissue, envelops the hair tissue during polymerization, develops and fixes color, and dyes the hair, a method for producing the same, and a method for dyeing the hair.

[Prior Art] Conventional hair dyes and hair dyeing methods are broadly classified into those that fix chemically synthesized pigments in the hair and those that dye hair with vegetable dyes.

In the former hair dye and hair dyeing method, first, the hair tissue is forcibly relaxed and expanded with a strong alkaline solution, and then,
This method involves infiltrating a low-molecular-weight pigment derivative (mainly tar-based) into the hair tissue, and then penetrating a forced oxidizing agent to cause oxidation (forced or accelerated) double bonding of the pigment within the hair tissue to develop color. Fix it and dye the hair. Thereafter, after 5 to 30 minutes, the excess hair dye applied to the hair is thoroughly washed away with hot water or water while observing the progress of oxidation bonding, thereby dyeing the hair.

The latter hair dye and hair dyeing method is a liquid or paste-like hair dye containing a mordant mixed with a vegetable pigment dye, and has a combination of color development with the mordant present in the hair, natural color development, natural oxidation color development, and color development. Hair is dyed in anticipation of oxidative color development due to frictional heat generated during brushing.

[Problems to be Solved by the Invention] The hair dye and hair dyeing method that fixes the chemically synthesized pigment in the hair can dye hair in a short time of about 5 to 30 minutes, and is not widely used. has the advantage of low cost,
Since the hair is forcibly relaxed and expanded using an alkaline solution (using ammonia), there was a problem in that it caused significant damage to the hair and skin.

It took two to three months to recover from this damage.

At the same time, forced oxidizing agents (hydrogen peroxide, etc.) significantly damage hair and skin, leading to frequent inflammation and breakouts.

Furthermore, tar-based pigment derivatives (suspected of being carcinogenic) penetrate and are absorbed into the body, producing antibodies, and with continued use, many people become allergic. - There is a problem that when people develop allergies, it becomes painful to dye their hair due to side effects such as rashes and rashes.

Furthermore, the biggest problem with conventional hair dyes that fix chemically synthesized pigments within the hair is that they can only dye hair that is exposed from the scalp. The gray parts of my hair grew longer, and I had to dye my hair frequently to prevent it from growing black.

Next, hair dyes that dye hair with vegetable pigments have the advantage of being effective in hair growth and hair loss prevention without damaging the hair or skin because they use vegetable pigments. However, there were problems such as the inability to dye hair and extremely low hair dyeing rate.

The reason why hair cannot be dyed is that the plant pigment dye and mordant are mixed in the hair dye, and the combined color development is completed in the hair dye, so even if it penetrates into the hair tissue, the polymerization color will not develop. This is because the colored binding molecules cannot be dyed, and even if they enter the hair tissue, they easily escape when the hair is washed.Therefore, there was a problem in that the hair could not be dyed.

Also, individuals (humans) that have mordants (coloring aids) in their hair.
The problem was that it was extremely rare, and the effectiveness rate was extremely low.

By the way, the cause of gray hair is said to be due to malnutrition of the scalp, especially the subcutaneous cells, which causes the hair follicles and hair roots to age, and as a result, the ability to produce melanin pigment decreases, causing hair to gradually turn gray. There is.

For this reason, rather than dyeing only the hair exposed from the scalp, it nourishes the scalp, promotes the activation of subcutaneous hair receptacles and hair roots, and promotes the normal production of melanin within the hair roots. Moreover, the hair dye penetrates into the hair tissue,
Hair dye and hair dye that combine with metals such as iron remaining in the hair to produce a black insoluble compound, which can restore gray hair to black, without damaging the hair, and without causing skin diseases. There was a strong desire to develop a method.

[Summary of the Invention The present invention has been made in response to the above-mentioned demands,
The mordant that forms a complex with the plant pigment dye and develops color is ionized and used as the first agent, the plant pigment dye that penetrates into the hair tissue is used as the second agent, and the mordant that has been ionized by penetrating the first agent into the hair tissue is used as the metal. The second agent is left in the hair tissue as low-molecular particles, the second agent is permeated into the hair tissue, and the remaining metal low-molecular particles are combined and polymerized within the hair tissue, enclosing the hair tissue during polymerization. An object of the present invention is to provide a hair dye for hair, a method for producing the same, and a method for dyeing the same.

[Means for Solving the Problems] The present invention employs the following means to solve the above problems.

First, the first invention is to form a first agent from a mordant made of iron, chromium, manganese, and other metals that do not harm the human body, alcohol, and purified water, and use hematin, henna tannin, catechin, and other vegetable pigments or dyes. This hair dye is characterized in that the second part is formed from a mixed vegetable pigment dye, coconut oil or other oil, alcohol, and purified water, and consists of the first part and the second part.

Next, the second invention is to add a mordant made of iron, chromium, manganese, and other metals that are not harmful to the human body to purified water, stir and mix to mix uniformly, and add alcohol to this solution and stir and mix. A first agent is prepared by adding hematin, henna tannin, catechin, and other plant pigment dyes, or a plant pigment dye obtained by mixing them, to purified water and stirring to mix them uniformly. Coconut oil or other oil agent is added and stirred to mix it uniformly, alcohol is added to this solution and stirred and mixed to mix it uniformly to form a second part, and these first part and second part are mixed. A method for producing a hair dye characterized by comprising:

Furthermore, in the third invention, a mordant that forms a complex with a plant pigment dye and develops color is ionized as the first agent, a vegetable pigment dye that gradually penetrates into the hair tissue is used as the second agent, and the second agent is applied to the hair from which stains have been removed. 1 agent is applied, the hair tissue is gently expanded to allow the mordant to penetrate into the hair tissue, and then the hair is dried and the ionized mordant is deeply penetrated into the hair tissue to form microparticles of the metal low molecule of the mordant into the hair. After that, a second agent is applied to the hair to gradually penetrate the plant pigment dye into the hair tissue, and the small metal particles remaining in the hair tissue and the plant pigment dye are absorbed into the hair tissue. This hair dyeing method is characterized by repeating compounding and polymerization to create a polymer, and during the polymerization, hair tissue is encapsulated to develop and fix the color, thereby dyeing the hair.

[Function] Next, the properties and roles of each raw material constituting the hair dye of the present invention,
Explain the efficacy etc.

The first agent is a mordant made of iron, chromium, manganese and other metals that do not harm the human body, coconut oil and other oils, polyoxyethylene glyceryl and other emulsifiers, 1,3-butyl glycol and other humectants, alcohol, refined Consists of water, preservatives, anti-inflammatory agents, trace amounts of coloring matter and fragrance.

The mordant is made of an ionizable metal, and is appropriately selected from iron, copper, aluminum, nickel, manganese, etc., for example. By selecting this mordant, various colors can be obtained. Iron, chromium, manganese, etc. are effective in obtaining a black color.

These hair dye mordants are selected from safe substances that do not harm the human body and are recognized as food or food additives.

Coconut oil and other oils desirably have the property of being compatible with water and easily gelling, and for example, vegetable oils such as coconut oil are most suitable. This oil agent has the effect of penetrating the plant pigment dye into the hair tissue.

Polyoxyethylene glyceryl and other emulsifiers have the effect of emulsifying the oil and the solvent, and have the function of making the first agent creamy.

1.3 Butyl glycol and other humectants maintain the moisturizing properties of the hair.

Alcohol has the effect of relaxing and expanding the hair tissue, allowing the mordant to penetrate slowly into the hair tissue, and also has a bactericidal effect that does not spoil the solution.

Purified water acts as a solvent that dissolves the mordant and other raw materials to form a solution.

The preservative has a preservative effect on the solution, the anti-inflammatory agent prevents the occurrence of scalp irritation, eczema, etc., and the pigment is a coloring agent, which is used to color the first agent in a desired color, such as green. do.

The fragrance is a young fragrance, and by appropriately selecting and using various fragrances such as bouquet, it is possible to make the first agent into a desired fragrance. It also has a deodorizing effect on various raw materials mixed with it, and has a deodorizing effect on metal ions, pigments, and auxiliaries that penetrate the hair.

The above-mentioned raw materials do not undergo any chemical reactions during the mixing process during the manufacturing process, and the efficacy of each of them remains unique even after commercialization, and when they are mixed together, their combined effects can also be achieved. As a result, it is possible to further exhibit the efficacy and effects of the various raw materials that have been blended.

Next, the second agent is hematin, henna tannin, catechin and other vegetable pigment dyes or vegetable pigment dyes mixed with them, coconut oil and other oils, polyoxyethylene glyceryl and other emulsifiers, 1.3-butyl glycol and other moisturizing agents. It consists of alcohol, purified water, preservatives, anti-inflammatory agents, trace amounts of coloring matter, and fragrance.

Hematin is a plant pigment obtained from a leguminous plant native to India, which penetrates into the protein fibers of the hair and combines with mordants such as trace amounts of iron that remain in the hair. Produces insoluble compounds of color. It does not dissolve in water and does not fade even when hair is washed. In addition, hematin produces the pigment in the hair and at the same time has a hair growth effect.

Henna tannin is a plant pigment that is obtained by hot water extraction and purification of the dried whole plant of Henna tannin, which penetrates into the protein fibers of the hair and contains trace amounts of iron that remain in the hair. When combined with a mordant such as, it produces a black or dark brown insoluble compound.

It does not dissolve in water and does not fade even when hair is washed. In addition, henna tannin produces pigments in the hair and at the same time has a hair growth effect.

Catechin is a plant pigment that is obtained by extracting and purifying dried Takasaburo leaves and fruits with hot water.It penetrates into the protein fibers of the hair and remains in the fibers, including trace amounts of iron. It has the effect of combining with a mordant to form a black or dark brown insoluble compound, which does not dissolve in water and does not fade even when hair is washed.

Catechin also produces hair pigments and has a hair growth effect.

The above-mentioned plant dyes such as hematin are selected from plants that have been used as medicinal herbs, nourishing tonics, hair dyes, beauty products, cosmetics, and dyes in their respective production areas for many years, and are safe. It is an excellent plant pigment dye or a substance with its efficacy.

Coconut oil and other oils desirably have the property of being compatible with water and easily gelling, and for example, vegetable oils such as coconut oil are most suitable. This oil agent has the effect of penetrating the plant pigment dye into the hair tissue.

Polyoxyethylene glyceryl and other emulsifiers have the function of emulsifying the oil and solvent, and have the function of finishing the second agent in a cream-like form.

1.3 Butyl glycol and other humectants maintain the moisturizing properties of the hair.

Alcohol has the effect of relaxing and expanding the hair tissue, allowing the mordant to penetrate slowly into the hair tissue, and also has a bactericidal effect that does not spoil the solution.

Purified water acts as a solvent that dissolves the mordant and other raw materials to form a solution.

The preservative has a preservative effect on the solution, the anti-inflammatory agent prevents the occurrence of hair rashes, eczema, etc., and the pigment is a coloring agent, which is used to color the second agent in a desired color, such as green. do.

The fragrance is a young fragrance, and by appropriately selecting and using various fragrances such as bouquet, it is possible to make the second agent into a desired fragrance. It also has a deodorizing effect on various raw materials mixed with it, and has a deodorizing effect on metal ions, pigments, and auxiliaries that penetrate the hair.

When a plant extract mixture is added to the second agent as a humectant, it can exhibit a hair growth effect in addition to the hair dyeing effect. For example, the following are optimal as plant extract mixtures.

Jasperia japonica extract is a moisturizer and nutrient, and the plant extract extracted from Jasper japonica has a strong moisturizing effect and hair growth effect.

Hypericum perforatum extract is a moisturizer and nutrient, and the extract obtained from Hypericum perforatum has moisturizing and hair growth effects.

Capsicum tincture is a moisturizer and nutrient, and the extract obtained from capsicum has moisturizing and hair-growth effects.

Both of these three types, Hypericum perforatum, and Capsicum tincture, are moisturizers and nutrients made from herbal medicines, and by using these three types alone or in combination, in addition to the individual effects of each, The combined effects of these two factors combine to nourish the subcutaneous hair receptacles, hair roots, hair, and scalp.

The above-mentioned raw materials do not undergo any chemical reactions during the mixing process during the manufacturing process, and the efficacy of each of them remains unique even after commercialization, and when they are mixed together, their combined effects can also be achieved. As a result, it is possible to further exhibit the efficacy and effects of the various raw materials that have been blended.

Next, the effects of the hair dye and hair dyeing method of the present invention will be explained below.

When the first agent, which is made by ionizing a mordant made of a metal that does not harm the human body, such as iron, which forms a complex with plant pigments such as hematin and develops color, is applied to the hair from which dirt has been removed, the hair tissue is affected by the action of alcohol. The hair is gently dilated to allow the mordant to fully penetrate into the hair tissue.

Next, when the hair is dried naturally or with hot air to scatter water and alcohol, the ionized mordant that has penetrated deeply into the hair tissue can remain in the hair tissue as fine particles of ionized metal low molecules.

After that, a second agent containing a vegetable pigment dye is applied to the hair, and when the vegetable pigment dye is gradually penetrated into the hair tissue by the action of the oil agent, the ionized metal low molecules remaining in the hair tissue are removed. The fine particles and the plant pigment dye are repeatedly combined and polymerized within the hair tissue to create a polymer, and during the polymerization, the hair tissue is encapsulated to develop and fix the color, thereby making it possible to dye hair.

That is, the hair dyeing method of the present invention involves infiltrating and fixing the extremely small molecules of the mordant main component that are highly bonded with the plant pigment dye into the hair tissue, and then the small molecules of the plant pigment dye gradually penetrating into the hair tissue. It is characterized by the fact that it combines with the mordant component that has previously been penetrated and fixed, and develops color. Furthermore, it is also unique in that the plant pigment dye and the main mordant components, which are extremely small molecules, repeatedly form double bonds while entwining with the hair tissue, deepening the color development, and becoming a polymer that is fixed to the hair tissue.

The hair dye of the present invention does not require forced relaxation or forced reaction of the hair during the hair dyeing process, and can form a double bond and color at room temperature, and there is no risk of damaging the hair or skin.

The hair dye of the present invention nourishes the scalp and restores subcutaneous nutrition, activates subcutaneous cells, especially hair follicles and hair root cells, and stimulates the hair growth that the subcutaneous cells originally possessed. It can also be activated.

That is, first of all, the slow action of herbal medicine extracts such as Aspergillus perforatum extract, Hypericum perforatum extract, and capsicum tincture on the scalp hair follicles and hair roots activates the cells of the hair follicles and hair roots and promotes the natural growth of hair. , and promotes the normal production of melanin pigment. That is, it has the effect of promoting the physiological inertia inherent in the human body that produces black hair.

These effects are produced based on natural physiological functions to improve hair growth.

In addition, the second agent, a vegetable pigment dye such as hematin, penetrates into the internal tissue of the hair with the help of an oil agent in an aqueous solution, and the vegetable dye such as hematin combines with the mordant such as a small amount of iron remaining in the hair, resulting in a black color. It produces insoluble compounds that gradually change the gray areas of the hair to its natural black color.

Next, a method for dyeing hair using the hair dye of the present invention will be explained.

In the hair dye of the present invention, the first agent is a beige liquid, does not precipitate and separate, and has a smooth feel when picked up.
There is a slight metallic scent of iron and other mordants. Also, when a small amount of fragrance is added, the metallic scent disappears and a slight scent of the added fragrance remains.

Next, the second agent is a yellowish-brown liquid, does not precipitate, has a smooth feel when picked up, and has a slightly bluish smell of plant pigments such as hematin.

Furthermore, when a small amount of fragrance is added, the fragrance of the plant pigment dye such as hematine disappears, and a slight fragrance of the added fragrance remains.

In addition, when an emulsifier is added in the process of manufacturing the hair dye of the present invention, the first agent is a beige cream that has a sticky feel when picked up and has a slight amount of metal from the mordant such as iron. It smells a little. Also, when a small amount of fragrance is added, the metallic scent disappears and a slight scent of the added fragrance remains.

Next, the second agent is a yellowish-brown cream, has a sticky feel when picked up, and has a slightly bluish smell of plant pigments such as hematin. Furthermore, when a small amount of fragrance is added, the fragrance of the plant dye such as hematin disappears, and a slight fragrance of the added fragrance remains.

In principle, the hair dye of the present invention is applied to the entire hair once a day (in the morning or at night, etc.). When applying, first, after washing the hair, apply the first agent all over the hair as if rinsing the hair. After rinsing off the first agent, dry the hair to remove moisture and alcohol, and then apply the second agent in the same way as a hair conditioner.

There are no significant differences among individuals, ages, genders, etc., and hair is generally dyed a deep gray color after one application, after hair dyeing, and when washed with water.

When the hair is rubbed and dyed for about a week and then washed with water, the hair is dyed to the dark brown color of the average Japanese hair.

If application of the hair dye of the present invention is discontinued after the entire hair has turned black, gray hair will begin to appear about two months after discontinuation, so continued use is required thereafter.

This continuous use only needs to be effective enough to maintain the physiological inertia of the human body that produces black hair, and there is no need to apply it every day, and there are not many individual differences, age differences, gender differences, etc. It is possible to maintain black hair sufficiently by applying it about once a week, and the effect of the hair dye of the present invention can be exhibited.

Next, the operation of the method for producing the hair dye of the present invention will be explained.

In the hair dye of the present invention, first, a mordant of iron, chromium, manganese, and other metals that are not harmful to the human body is added to purified water, and the mixture is uniformly mixed by stirring at a temperature of about 70 to 80 degrees Celsius. do.

Here, these raw materials for the first agent are mixed because they have the property of being easily miscible with each other and are 70%
This is because it is most easily dissolved at a temperature of about 80°C to 80°C, and therefore the mixing operation can be carried out easily and efficiently.

After cooling the uniformly mixed solution to room temperature,
Alcohol is added and mixed by stirring to obtain a first agent.

Next, hematin, henna tannin, catechin, and other plant pigment dyes are used alone or in combination with hematin, henna tannin, catechin, and other plant pigment dyes, and the plant pigment dyes are added to purified water at 70°C to 80°C. Mix uniformly by stirring at different temperatures. Coconut oil and other oils are added to this solution and mixed uniformly by stirring at a temperature of about 70°C to 80°C.

After cooling the uniformly mixed solution to room temperature,
Alcohol is added and mixed by stirring to obtain a second agent.

Here, the reason why the oil agent is mixed at a temperature of about 70° C. to 80° C. is to facilitate the mixing of the added vegetable pigment dye such as hematin.

Also, when adding a plant extract mixture as a moisturizer,
Selection of a temperature of around 70°C to 80'C does not reduce the effectiveness of the hair growth extracts added, such as Oriental perforatum extract, Hypericum perforatum extract, and capsicum tincture, and also improves the mixing state, making the overall mixing process easier and more efficient. This is to do so.

In the present invention, the blending ratio of plant pigments such as hematin is 0.2 to 5% by weight, but if this blending ratio is 5% by weight or more, when applied to the hair and scalp, All of the plant pigments such as hematin do not penetrate into the hair roots and hair, and a portion of it adheres to the hair surface and is not only wasted, but also the adhering portion adheres to hands, bedding, hats, etc., making it inconvenient to use. becomes.

Furthermore, if the blending ratio of hematin is less than 0.2% by weight, the hair blackening effect cannot be effectively exhibited.

[Effects of the Invention] By having the above configuration, the present invention allows the extremely small molecules of the mordant main component that are highly bonded to the plant pigment dye to penetrate and fix in the hair tissue in advance, and then the small molecules of the plant pigment dye gradually penetrate into the hair tissue. It penetrates into the hair tissue and combines with the mordant component that had previously penetrated and fixed, producing color. That is, the plant pigment dye and the main mordant components, which are extremely small molecules, repeatedly form double bonds while entwining with the hair tissue, deepening the color development, and becoming a polymer that can be fixed to the hair tissue.

In this way, the hair dye of the present invention does not require forced relaxation or forced reaction of the hair during the hair dyeing process, and can form heavy bonds and color at room temperature, and there is no risk of damaging the hair or skin. It's something that doesn't exist.

In addition, the present invention nourishes the scalp and restores subcutaneous nutrition, activates subcutaneous cells, especially hair follicles and hair root cells, and exerts the hair growth effect that subcutaneous cells originally had. You can also do it.

That is, first of all, the slow action of herbal medicine extracts such as Aspergillus perforatum extract, Hypericum perforatum extract, and capsicum tincture, and plant dyes such as hematin, henna tannin, or catechin on the scalp hair follicles and hair roots causes the hair follicles and hair roots to be damaged. Activates cells, promotes natural hair growth, and promotes normal production of melanin pigment. That is, it has the effect of promoting the physiological inertia inherent in the human body that produces black hair.

These effects are produced based on natural physiological functions to improve hair growth.

Furthermore, the present invention is continuously applied to the skin of the scalp, allowing it to penetrate subcutaneously and slowly acting on the hair follicles and hair roots, activating the hair follicles and hair root cells, promoting natural hair growth, and at the same time promoting melanin. It promotes the normal production of pigment and can restore gray hair to black based on the natural physiological effects of the human body.

[Example] Embodiments of the present invention will be described in detail below.

Experimental Example 1 2 g of iron powder (ferrous sulfate) (along with a trace amount of coloring matter and fragrance) was added to 72 g of purified water, and the mixture was stirred and mixed at a temperature of around 70° C. to mix uniformly.

After cooling the uniformly mixed solution to room temperature,
26 g of cetanol was added and mixed by stirring to obtain 100 g of the first agent.

This first agent is in the form of a beige liquid, does not precipitate, has a smooth feel when picked up, and has a slight scent of the added fragrance.

Next, 2g of liquid hematin (along with a trace amount of pigment and fragrance)
was added to 65 g of purified water and mixed by stirring back and forth for 5 minutes at a temperature of around 70'C. After cooling the uniformly mixed solution to room temperature, 33 g of cetanol was added and mixed by stirring to mix uniformly. Thus, 100 g of the second agent was obtained.

This second agent is in the form of a yellow-brown liquid, does not precipitate, has a smooth feel when picked up, and has a slight scent of the added fragrance.

Experimental Example 2 2 g of iron powder (ferrous sulfate) (along with trace amounts of pigment and fragrance) was added to 63 g of purified water, stirred and mixed at a temperature of around 80°C to mix uniformly, and 10 g of coconut oil 1 polyoxy Ethylene glyceryl Log, 1,3 butyl glycoyl 5g 80
Stir and mix at a temperature of around 80°C to mix uniformly, gradually add this solution to the above solution, further stir and mix at a temperature of around 80°C to mix uniformly, and after returning this solution to room temperature. 10 g of cetanol was added and further stirred and mixed to obtain a uniform mixture, yielding 100 g of the first agent.

This first agent is beige in color and creamy, has a sticky feel when taken into the hand, and has a slight scent of the added fragrance.

Next, 1g of liquid hematin (along with a trace amount of pigment and fragrance)
Add to 64 g of purified water and mix uniformly by stirring at a temperature of around 80°C, and add 10 g of coconut oil, 1 log of polyoxyethylene glyceryl, and 5 g of 1,3-butyl glycoyl at a temperature of around 80°C. Stir and mix to mix uniformly. Gradually add this solution to the above solution and further stir and mix at a temperature of around 80°C to mix uniformly. After returning this solution to room temperature, add 10 g of cetanol. The mixture was further stirred and mixed to obtain a second agent.

This second agent is yellowish brown and creamy, has a sticky feel when taken into the hand, and has a slight scent of the added fragrance.

Experimental example 3 Iron powder (ferrous sulfate) 2g (with a trace amount of coloring matter and vanilla)
was added to 62.8 g of purified water and stirred and mixed at a temperature of around 80°C to mix uniformly. 5 g of liquid paraffin, 3 g of avocado oil, 2 g of squalene oil, 7 g of polyoxyethylene glyceryl, 3 g of triethylammonium chloride.
g11.3-butyl glycoyl 3g1 anhydrous collagen 1g
1 1 g of white lanolin 1 0.2 g of paraben are stirred and mixed at a temperature of around 800C to mix uniformly, and this solution is gradually added to the above solution, and further stirred and mixed at a temperature of around 80'C to mix uniformly. After returning this solution to room temperature, add 10 g of cetanol and stir to mix evenly.
00g of the first agent was obtained.

This first agent is beige in color and creamy, has a sticky feel when taken into the hand, and has a slight vanilla scent.

Next, add 1 g of liquid hematin (along with a small amount of pigment and vanilla) to 63.8 g of purified water, stir and mix at a temperature of around 80°C to mix uniformly, 5 g of liquid paraffin, 3 g of avocado oil, 2 g of squalene oil, and 1 g of liquid paraffin. 7g polyoxyethylene glyceryl 11.3-butyl glycoyl 2g
1 Anhydrous Collagen 2g 1 Plant Extract Mixture (Japanese Orchid Extract, Hypericum Perforatum Extract, Capsicum Tincture, etc.)
3g 1 glycyrrhetinic acid 1g 1 paraben 0.2g 80
Stir and mix at a temperature of around 80°C to mix uniformly, add this solution gradually to the above solution, further stir and mix at a temperature of around 80°C to mix uniformly, and return this solution to room temperature. Afterwards, 10 g of cetanol was added and further stirred and mixed to obtain a homogeneous mixture, yielding 100 g of rod 2 agent.

This second agent is yellowish brown and creamy, has a sticky feel when taken into the hand, and has a slight vanilla scent.

In this example, three types of oils, liquid paraffin, avocado oil, and squalene oil, are used, but hair can be effectively protected by using various oils.

Furthermore, triethylammonium chloride not only acts as an emulsifier but also has the function of gently spreading hair.

Clinical Trial Example 1 A clinical trial was conducted in which a 30-year-old man with gray hair applied the hair dye of the present invention obtained in Experimental Example 1 once a day (at night) to his gray hair and the scalp at its roots, and the following results were obtained. It was done.

With one application, hematin gradually penetrates into the hair tissue,
Approximately 60% of the iron content remaining in the hair tissue is combined with small particles of low-metal metal and polymerized within the hair tissue to create a polymer, which encapsulates the hair tissue during polymerization and fixes the hair in a grayish color. I let it happen.

With two applications, hematin gradually penetrates into the hair tissue.
A polymer is created by repeating polymerization in the hair tissue with microparticles of metal low molecules containing approximately 70% iron remaining in the hair tissue, and during polymerization, the hair tissue is encapsulated to form the hair. The color is fixed to a darker gray.

With three applications, hematin gradually penetrates into the hair tissue.
A polymer is created by repeating polymerization and combining with microparticles of metal low molecules containing about 75% iron remaining in the hair tissue, and during polymerization, the hair tissue is encapsulated to make the hair a second time. The color is fixed to a darker gray.

After 4 applications, hematin gradually penetrates into the hair tissue.
A polymer is created by repeating polymerization in the hair tissue with microparticles of low-metal metal containing approximately 77% iron remaining in the hair tissue, and during polymerization, the hair tissue is encapsulated to form the hair. The color is fixed to a darker gray.

As you repeat the application, the color of your hair gradually becomes darker, and in the first week of daily application, about 80% of the iron content is combined, and the hair becomes blackish brown, which is the average hair color of Japanese people. We were able to.

Trial Example 2 The hair dye of the present invention obtained in Experiment Example 1 was administered once a day (at night) to 40- and 50-year-old men and a 55-year-old woman with gray hair.
When a trial was conducted in which the product was rubbed on the scalp of gray hair and its roots, the same results as in Trial Example 1 were obtained.

From these clinical trials, it is understood that the hair dye of the present invention can exert its hair dyeing action regardless of age and gender.

Clinical Trial Example 3 A clinical trial was conducted in which a 30-year-old man with gray hair applied the hair dye of the present invention obtained in Experimental Example 2 once a day (at night) to his gray hair and the scalp at its roots, and the following results were obtained. It was done.

With one application, henna tannin gradually penetrates into the hair tissue, and combines with the metal low molecule fine particles of about 60% iron remaining in the hair tissue, repeating polymerization to create a polymer. During the polymerization, the hair tissue was encapsulated to fix the color of the hair in a light blackish brown color.

With two applications, henna tannin gradually penetrates into the hair tissue, and combines with the metal low-molecular particles of approximately 70% iron remaining in the hair tissue, repeating polymerization to create a polymer. During the polymerization, the hair tissue was encapsulated and the hair was colored and fixed in a darker blackish brown than the first time.

By applying it three times, henna tannin gradually penetrates into the hair tissue, and combines with the metal low-molecular particles of about 75% iron remaining in the hair tissue, repeating polymerization to create a polymer. During the polymerization, the hair tissue was encapsulated, and the color of the hair was fixed to a darker blackish brown than the second time.

By applying it four times, henna tannin gradually penetrates into the hair tissue, and combines with the metal low-molecular particles of approximately 77% iron remaining in the hair tissue, repeating polymerization to create a polymer. During the polymerization, the hair tissue was encapsulated, and the hair was colored and fixed to a darker brown color than in the third treatment.

As you repeat the application, the color of your hair gradually becomes darker, and in the first week of daily application, about 80% of the iron content is combined, and the hair becomes blackish brown, which is the average hair color of Japanese people. We were able to.

Trial Example 4 The hair dye of the present invention obtained in Experiment Example 2 was administered once a day (at night) to 40- and 50-year-old men and a 55-year-old woman with gray hair.
When a trial was conducted in which the product was rubbed on the scalp of gray hair and its roots, the same results as in Trial Example 1 were obtained.

From these clinical trials, it is understood that the hair dye of the present invention can exert its hair dyeing action regardless of age or gender.

Clinical Trial Example 5 A clinical trial was conducted in which a 30-year-old man with gray hair applied the hair dye of the present invention obtained in Experimental Example 3 once a day (at night) to his gray hair and the scalp at its roots, and the following results were obtained. It was done.

With one application, catechin gradually penetrates into the hair tissue, and repeats polymerization and combination with the metal low-molecular particles of about 60% iron remaining in the hair tissue, creating a polymer. The hair tissue was encapsulated inside, and the hair was colored and fixed in a light blackish brown color.

By applying it twice, catechin gradually penetrates into the hair tissue, and repeats polymerization and polymerization within the hair tissue with the fine metal particles containing approximately 70% iron remaining in the hair tissue, creating a polymer. The hair tissue was encapsulated inside, and the color of the hair was fixed to a darker blackish brown than the first time.

By applying it three times, catechin gradually penetrates into the hair tissue, and it combines with the metal low-molecular particles of about 75% iron remaining in the hair tissue, repeats polymerization to create a polymer, and polymerizes. The hair tissue was contained inside, and the color of the hair was fixed to a darker blackish brown than the second time.

After 4 times of application, catechin gradually penetrates into the hair tissue, and repeats polymerization and combination with the metal low-molecular particles of about 77% iron remaining in the hair tissue, creating a polymer. The hair tissue was encapsulated inside, and the color of the hair was fixed to a darker blackish brown than in the third treatment.

As you repeat the application, the color of your hair gradually becomes darker, and in the first week of daily application, about 80% of the iron content is combined, and the hair becomes blackish brown, which is the average hair color of Japanese people. We were able to.

Clinical Trial Example 6 The hair dye of the present invention obtained in Experimental Example 3 was administered once a day (at night) to 40- and 50-year-old men and 55-year-old women with gray hair.
When a trial was conducted in which the product was rubbed on the scalp of gray hair and its roots, the same results as in Trial Example 1 were obtained.

From these clinical trials, it is understood that the hair dye of the present invention can exert its hair dyeing action regardless of age and gender.

Clinical Trial Example 7 A clinical trial was conducted in which a 30-year-old man with gray hair applied the hair dye of the present invention obtained in Experimental Example 3 once a day (at night) to his gray hair and the scalp at its roots, and the following results were obtained. It was done.

With one application, the plant pigment dye made of a mixture of hematin, henna tannin, and catechin gradually penetrates into the hair tissue, and the metal low-molecular particles containing about 60% of the iron content remaining in the hair tissue and the hair tissue. A polymer was created by repeating compounding and polymerization, and during the polymerization, the hair tissue was encapsulated, fixing the color of the hair in a light blackish brown color.

By applying it twice, the plant pigment dye made of a mixture of hematin, henna tannin, and catechin gradually penetrates into the hair tissue, and the fine particles of metal low molecules containing about 70% of the iron content remaining in the hair tissue and the hair tissue. A polymer was created by repeating compounding and polymerization, and during the polymerization, the hair tissue was encapsulated and the hair was colored and fixed in a darker brown color than the first time.

-4+ -- By applying it three times, the plant pigment dye made of a mixture of hematin, henna tannin, and catechin gradually penetrates into the hair tissue, resulting in fine particles of metal low molecules with about 75% iron content remaining in the hair tissue. A polymer was created by repeating compounding and polymerization within the hair tissue, and during the polymerization, the hair tissue was encapsulated and the hair was colored and fixed in a darker black-brown color than the second time.

By applying it four times, the plant pigment dye made of a mixture of hematin, henna tannin, and hycatechin gradually penetrates into the hair tissue, and the metal low-molecular particles containing approximately 77% of the iron content remaining in the hair tissue and the hair tissue. A polymer was created by repeating compounding and polymerization, and during the polymerization, the hair tissue was encapsulated and the hair was colored and fixed in a darker blackish brown color than the third time.

As you repeat the application, the color of your hair gradually becomes darker, and in the first week of daily application, about 80% of the iron content is combined, and the hair becomes blackish brown, which is the average hair color of Japanese people. We were able to.

Clinical Trial Example 8 The hair dye of the present invention obtained in Experimental Example 3 was administered once a day (at night) to 40- and 50-year-old men and 55-year-old women with gray hair.
When a trial was conducted in which the product was rubbed on the scalp of gray hair and its roots, the same results as in Trial Example 1 were obtained.

From these clinical trials, it is understood that the hair dye of the present invention can exert its hair dyeing action regardless of age and gender.

Claims (10)

[Claims] (1) The first agent is formed from a mordant made of iron, chromium, manganese, and other metals that do not harm the human body, alcohol, and purified water, and is made of hematin, henna tannin, catechin, and other plant pigments, or a mixture thereof. A second agent is formed from plant pigments, alcohol, and purified water, and these are combined with the first agent.
A hair dye comprising an agent and a second agent. (2) Mordants made of iron, chromium, manganese and other metals that do not harm the human body, coconut oil and other oils, polyoxyethylene glyceryl and other emulsifiers, 1.3-butyl glycol and other humectants, alcohol, and purified water. Forming the first agent, hematin, henna tannin, catechin and other vegetable pigment dyes or vegetable pigment dyes made by mixing them, coconut oil and other oils, polyoxyethylene glyceryl and other emulsifiers, 1.3-butyl glycol and others 2. The hair dye according to claim 1, wherein the second part is formed from a moisturizing agent, alcohol, and purified water, and consists of the first part and the second part. (3) 0.5 to 5% by weight of a mordant made of iron, chromium, manganese, and other metals that do not harm the human body, 5 to 15% by weight of coconut oil and other oils, and 5 to 15% by weight of polyoxyethylene glyceryl and other emulsifiers. %, 1.3-butyl glycol and other humectants 5 to 15% by weight, alcohol 7 to 35% by weight, purified water 43 to 72% by weight to form the first part, and hematin, henna tannin, catechin and other vegetable pigment dyes. or a vegetable pigment dye obtained by mixing them 0.2 to 5
5-15% by weight of coconut oil and other oils, 5-15% by weight of polyoxyethylene glyceryl and other emulsifiers,
1.3-butyl glycol and other humectants 5-15% by weight
, alcohol 7-35% by weight, purified water 43-72% by weight
The hair dye according to claim 1 or 2, characterized in that a second agent is formed from the first agent and the second agent. (4) Claim 1, 2 or 3, characterized in that the first and second agents contain a preservative, an anti-inflammatory agent, a trace amount of coloring matter, and a fragrance.
Hair dye as described. (5) Add a mordant made of iron, chromium, manganese, and other metals that are not harmful to the human body to purified water and stir and mix to mix uniformly, then add alcohol to this solution and stir and mix to mix uniformly. As the first agent, hematin, henna tannin, catechin, and other plant pigment dyes, or a vegetable pigment dye made by mixing them, are added to purified water and stirred to mix uniformly, and this solution is mixed with coconut oil, etc. It is characterized by adding an oil agent and stirring and mixing to mix uniformly, adding alcohol to this solution and stirring and mixing to mix uniformly to form a second part, and consisting of these first and second parts. A method for producing a hair dye. (6) Add a mordant made of iron, chromium, manganese and other metals that do not harm the human body to purified water, stir and mix to mix uniformly, and use coconut oil or other oils, polyoxyethylene glyceryl or other emulsifiers, etc. Stir and mix 1,3-butyl glycol and other humectants to mix uniformly, gradually add this solution to the above solution and further stir and mix to mix uniformly, add alcohol to this solution and further stir and mix. Mix uniformly to form a first agent, add hematin, henna tannin, catechin and other plant pigment dyes, or a vegetable pigment dye made by mixing them to purified water, stir and mix to uniformly mix, and Oils such as oil, emulsifiers such as polyoxyethylene glyceryl, humectants such as 1.3-butyl glycol are stirred and mixed uniformly, and this solution is
Gradually add to the solution and stir and mix to mix uniformly, add alcohol to this solution and further stir and mix to mix uniformly to obtain a second part, which consists of the first part and the second part. 6. The method for producing a hair dye according to claim 5. (7) Add 0.5 to 5% by weight of a mordant made of iron, chromium, manganese, and other metals that are not harmful to the human body to purified water.
2% by weight and stirred and mixed at a temperature of around 70°C to 80°C to mix uniformly, 5% to 15% by weight of coconut oil or other oil, 5% of polyoxyethylene glyceryl or other emulsifier.
-15% by weight of 1.3-butyl glycol and 5-15% by weight of other humectants are stirred and mixed at a temperature of around 70°C to 80°C to mix uniformly, and this solution is gradually added to the above solution. Further stir and mix at a temperature of around 80°C to 80°C to mix uniformly, and after returning the solution to room temperature, alcohol 7-1
Add 2.5% by weight and further stir and mix to form a first agent, which is hematin, henna tannin, catechin and other plant pigment dyes or a vegetable pigment dye made by mixing them 0.2-5 % by weight of purified water is added to 43-72% by weight of purified water, stirred and mixed at a temperature of around 70°C to 80°C to mix uniformly, 5-15% by weight of coconut oil and other oils, and polyoxyethylene glyceryl. 5 to 15% by weight of other emulsifiers and 5 to 15% by weight of 1.3-butyl glycol and other humectants are stirred and mixed at a temperature of around 70°C to 80°C to mix uniformly, and this solution is added to the above solution. Gradually add to 70℃
Further stir and mix at a temperature of ~80°C to mix uniformly, and after returning this solution to room temperature, add 7 to 12.8% by weight of alcohol and further stir and mix to mix uniformly to form the second part. 7. The method for producing a hair dye according to claim 5 or 6, comprising the first agent and the second agent. (8) Claim 5, 6 or 7, characterized in that the first and second agents contain a preservative, an anti-inflammatory agent, a trace amount of coloring matter, and a fragrance.
The method for producing the hair dye described. (9) Ionize the mordant that forms a complex with the plant pigment dye to develop color and use it as the first agent.The second agent is the plant pigment dye that gradually penetrates into the hair tissue.The first agent is applied to the hair from which dirt has been removed. Then, the hair tissue is gently expanded to allow the mordant to penetrate into the hair tissue, and then the hair is dried to allow the ionized mordant to penetrate deeply into the hair tissue and remain in the hair tissue as fine particles of low metal molecules of the mordant. After that, a second agent is applied to the hair to gradually penetrate the plant pigment dye into the hair tissue, and the metal low molecule fine particles remaining in the hair tissue and the plant pigment dye are combined within the hair tissue. A hair dyeing method that involves repeating polymerization to create a polymer, enveloping hair tissue during polymerization to develop and fix color, and dye hair. (10) Ionize iron and other mordants that form a complex with hematitin and other plant pigment dyes to develop color, and use this as the first agent;
The second agent is hematin or other vegetable pigment dye that gradually penetrates into the hair tissue, and the first agent is applied to the hair from which dirt has been removed, and the hair tissue is gently expanded by the action of alcohol or the like, and iron or other mordants are applied. permeate into the hair tissue, then dry the hair to allow ionized iron and other mordants to penetrate deeply into the hair tissue and leave them as fine particles of low metal molecules of iron and other mordants within the hair tissue. A second agent is applied to the hair, and hematin and other plant pigment dyes are gradually penetrated into the hair tissue by the action of polyoxyethylene glyceryl and other emulsifiers, and the fine particles of low-molecular metal and plant pigments remaining in the hair tissue are removed. is combined within the hair tissue,
10. The hair dyeing method according to claim 9, wherein the polymer is produced by repeating polymerization, and during the polymerization, hair tissue is encapsulated to develop and fix the color, thereby dyeing the hair.