JPH04180599A - Sliding material - Google Patents

Sliding material

Info

Publication number
JPH04180599A
JPH04180599A JP29014890A JP29014890A JPH04180599A JP H04180599 A JPH04180599 A JP H04180599A JP 29014890 A JP29014890 A JP 29014890A JP 29014890 A JP29014890 A JP 29014890A JP H04180599 A JPH04180599 A JP H04180599A
Authority
JP
Japan
Prior art keywords
sliding
alloy
base material
aluminum
oxide film
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP29014890A
Other languages
Japanese (ja)
Inventor
Kenichiro Futamura
憲一朗 二村
Keiichiro Otsu
大津 恵一郎
Takeshi Higuchi
武 樋口
Kenji Takenaka
健二 竹中
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Toyota Industries Corp
Taiho Kogyo Co Ltd
Original Assignee
Taiho Kogyo Co Ltd
Toyoda Automatic Loom Works Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Taiho Kogyo Co Ltd, Toyoda Automatic Loom Works Ltd filed Critical Taiho Kogyo Co Ltd
Priority to JP29014890A priority Critical patent/JPH04180599A/en
Publication of JPH04180599A publication Critical patent/JPH04180599A/en
Pending legal-status Critical Current

Links

Abstract

PURPOSE:To produce a sliding member having a sliding surface excellent in seizuring resistance by forming an anodic oxide film on the sliding surface of an Al-alloy sliding member and plating the surface with specified metal or alloy. CONSTITUTION:A sliding member with a light metal such as Al or an Al alloy as its base material 1 is conventionally anodized to form a dense and hard anodic oxide film 2 excellent in wear resistance on its surface with good adhesion. A plating layer 3 of a soft metal such as Pb, In, Sn or their alloy is then formed on the film 2 by electroplating. Consequently, the base metal such as Al and an Al alloy easy to adhere in sliding is not exposed on the sliding surface, its seizure to the counterpart member is prevented, and a sliding member excellent in durability is obtained.

Description

【発明の詳細な説明】 [技術分野] 本発明は、軸受なとの摺動面に使用される摺動材料に関
するものである。
DETAILED DESCRIPTION OF THE INVENTION [Technical Field] The present invention relates to a sliding material used for a sliding surface such as a bearing.

[従来技術] 従来、例えば自動車の空調システムには、軸と平行に設
けられた複数個のシリンダボアをもつシリンダブロック
と、該シリンダブロック内において回転軸により回転さ
れる斜板と、該シリンダボア内に摺動自在に嵌合された
ピストンと、該ピストンと該斜・板との間に介在し、該
斜板の回転により該ピストンを往復運動させるシューと
で構成される摺動向をもつ斜板式コンプレッサか知られ
ている。
[Prior Art] Conventionally, for example, an air conditioning system for an automobile includes a cylinder block having a plurality of cylinder bores provided in parallel with an axis, a swash plate rotated by a rotating shaft within the cylinder block, and a cylinder block within the cylinder bore. A swash plate type compressor with a sliding mechanism, which is composed of a piston fitted in a slidable manner, and a shoe interposed between the piston and the swash plate and causing the piston to reciprocate as the swash plate rotates. or known.

斜板式コンプレッサにおいては、一般に斜板、シューは
軽量化等の面からアルミニウムやアルミニウム合金が使
用されて(する。ここで斜板やシューの摺動向には大き
な荷重及び大きな、滑り速1度が作用することから、斜
板やシューの摺動面は焼付きしやすい問題が競る。特に
斜板やシューの母材を形成するアルミニウムあるいはア
ルミニウム合金が凝着しやすいために、始動時の無潤滑
の状態とか、摺動荷重が大きいような苛酷な摺動条件下
では焼付きしやすいという問題がある。また滑り軸受の
摺動向においても同様な摺動条件となっていや・ [1発明の目的] 本発明は上記問題を克服するもので、耐焼付性に優れた
摺動材料を提供することを目的とする。
In swash plate type compressors, the swash plate and shoes are generally made of aluminum or aluminum alloy from the viewpoint of weight reduction.The sliding movement of the swash plate and shoes is subject to large loads and large sliding speeds of 1 degree. Because of this, the sliding surfaces of the swash plate and shoes are susceptible to seizing.In particular, the aluminum or aluminum alloy that forms the base material of the swash plate and shoes tends to adhere, so if there is no lubrication during startup, There is a problem that seizure is likely to occur under severe sliding conditions such as when the sliding bearing is in a state of ] The present invention overcomes the above problems and aims to provide a sliding material with excellent seizure resistance.

[発明の構成] 本発明の摺動材料は、アルミニウム又はアルミニウム合
金よりなる母材と、該母材の表面を覆って形成された陽
極酸化被膜と、該陽極酸化被膜の上面に鉛、インジウム
、錫またはそれらの合金よりなるメッキ層で構成される
表面層とからなることを特徴とする。
[Structure of the Invention] The sliding material of the present invention includes a base material made of aluminum or an aluminum alloy, an anodic oxide film formed to cover the surface of the base material, and lead, indium, and a surface layer consisting of a plating layer made of tin or an alloy thereof.

本発明の摺動材料は、アルミニウム又はアルミニウム合
金を母材としている。アルミニウム合金としては例えば
A1−高3i系合金、AI −31−M0系合金、AI
 −3i −Cu−M(]系合金、又は3iを含まない
A1合金を使用できる。母材は、硬質粗大粒子をアルミ
ニウム又はアルミニウム合金のマトリックス中に含むも
のを使用するのが好ましい。ここで、硬質粗大粒子とは
、硬さがHv300以上より好ましくは600以上で、
平均粒径が10μ以上、より好ましくは平均粒径が20
〜100μの粒径をもつものをいい、例えば初晶シリコ
ンがある。
The sliding material of the present invention uses aluminum or an aluminum alloy as a base material. Examples of aluminum alloys include A1-high 3i alloy, AI-31-M0 alloy, and AI
A -3i -Cu-M ()-based alloy or an A1 alloy that does not contain 3i can be used. It is preferable to use a matrix containing hard coarse particles in an aluminum or aluminum alloy matrix. Here, Hard coarse particles have a hardness of Hv 300 or more, preferably 600 or more,
The average particle size is 10μ or more, more preferably the average particle size is 20μ.
It refers to particles with a particle size of ~100μ, such as primary crystal silicon.

硬質粗大粒子を含む代表的な母材材料として、アルシル
合金が知られている。このアルシル合金はシリコン含有
率が13〜30重量%程度と共晶組成以上の高いシリコ
ン含有量をもち、マトリックス中に初晶シリコンを有す
る。
Arcil alloy is known as a typical base material containing hard coarse particles. This Alsil alloy has a silicon content of about 13 to 30% by weight, which is higher than the eutectic composition, and has primary crystal silicon in the matrix.

硬質粗大粒子を含む伯の母材としては、アルミニウムー
マンガン金属間化合物、アルミニウムーシリコン−マン
ガン金属間化合物、アルミニウムー鉄金属間化合物、ア
ルミニウムー鉄−マンカン金属間化合物、アルミニウム
ークロム金属間化合物等の硬質粗大粒子を含むアルミニ
ウム合金がある。母材が硬質粗大粒子を含む場合には、
例えば初晶シリコンを有するアルシル合金の場合には、
母材自体がすぐれた摺動特性をもつため、きびしい摺動
条件で使用する斜板ヤシューの母材として適する。尚、
場合によっては母材として、シリコン含有量を共晶組成
以下例えば1%程度と低くし、マトリックス中に初晶シ
リコンを有しないアルミニウムーシリコン系合金を用い
てもよい。
Examples of base metals containing hard coarse particles include aluminum-manganese intermetallic compounds, aluminum-silicon-manganese intermetallic compounds, aluminum-iron intermetallic compounds, aluminum-iron-mankan intermetallic compounds, and aluminum-chromium intermetallic compounds. There are aluminum alloys containing hard coarse particles such as. When the base material contains hard coarse particles,
For example, in the case of an arsil alloy containing primary silicon,
Since the base material itself has excellent sliding properties, it is suitable as the base material for swash plate swash plates used under severe sliding conditions. still,
In some cases, the base material may be an aluminum-silicon alloy having a low silicon content, for example, about 1% below the eutectic composition, and having no primary silicon in the matrix.

第1図に例示した様にこの摺動材料で構成される摺動面
は、母材1の表面を陽極酸化被膜2が覆い、その上面に
表面層3の軟質金属のメッキ層が形成されている。この
ようにすれば、例えば、潤滑油が供給されない異常な条
件下でかなり長時間にわたって軸受が運転され、そのた
め表面層が損耗した場合には、陽極酸化被膜が摺動面に
表出することになる。その結果、凝簀をおこしやすいア
ルミニウムやアルミニウム合金の母材は摺動向に表出せ
ず、耐焼付性に優れたものとなる。そして陽極酸化被膜
の上面に形成する固体1lil滑層は薄くしてもその効
果を保持することができる。
As illustrated in FIG. 1, the sliding surface made of this sliding material consists of a base material 1 whose surface is covered with an anodic oxide film 2, and a surface layer 3, a soft metal plating layer, formed on the top surface. There is. In this way, for example, if the bearing is operated for a considerable period of time under abnormal conditions without lubricating oil, and the surface layer is worn out as a result, the anodic oxide film will be exposed on the sliding surface. Become. As a result, the aluminum or aluminum alloy base material, which tends to cause agglomeration, is not exposed in the sliding motion, resulting in excellent seizure resistance. The solid lil lubricant layer formed on the upper surface of the anodic oxide film can maintain its effectiveness even if it is made thin.

母材の表面を覆う陽極酸化被膜は、アルミニウムやアル
ミニウム合金を陽極酸化によって形成される被膜である
。このアルミニウムの陽極酸化被膜は一般に、緻密で硬
いため耐摩耗性が大きく、かつ、母材に対して密着性が
よい。アルミニウムの陽極酸化被膜としては硬くて緻密
なバリヤ層を使用してもよく、又、バリヤ層の上に多孔
質層を形成して使用してもよい。アルミニウムの陽極酸
化被膜は2μ〜20μがよい。陽極酸化法としてはシュ
ウ酸洗、WtilI法、シュウ酸・硫酸混液法、クロム
酸法等が使用できる。
The anodic oxide film that covers the surface of the base material is a film that is formed by anodic oxidation of aluminum or aluminum alloy. This anodic oxide film of aluminum is generally dense and hard, so it has high wear resistance and good adhesion to the base material. A hard and dense barrier layer may be used as the aluminum anodic oxide film, or a porous layer may be formed on the barrier layer. The aluminum anodic oxide film preferably has a thickness of 2μ to 20μ. As the anodic oxidation method, oxalic pickling, WtilI method, oxalic acid/sulfuric acid mixture method, chromic acid method, etc. can be used.

本発明の摺動材料を特色づける摺動面は、表面か鉛、イ
ンジウム、錫およびその合金のメッキ層で構成された表
面層を形成している。この表面層はその母材との間に陽
極酸化被膜が形成された上面で母材表面を被覆するので
、凝着をおこしやすいアルミニウムヤアルミニウム合金
の母材表面が摺動向に表出するのを阻止して潤滑性を高
めることができる。
The sliding surface of the sliding material of the present invention has a surface layer formed of a plating layer of lead, indium, tin, and an alloy thereof. This surface layer covers the surface of the base material with an anodized film formed between it and the base material, so it prevents the surface of the base material of aluminum and aluminum alloy, which is prone to adhesion, from being exposed during the sliding movement. can be prevented to improve lubricity.

表面層の厚さ、種類等は、荷重の大きざ、摺動速度等の
条件を考慮して決められる。表面層の厚さとしては厚い
程好ましい。−殻内には2μ〜15μ程度が好ましい。
The thickness, type, etc. of the surface layer are determined in consideration of conditions such as the size of the load and the sliding speed. The thickness of the surface layer is preferably as thick as possible. - The inside of the shell is preferably about 2μ to 15μ.

上記表面層は、鉛、インジウム、錫などの金属およびそ
の合金がたとえば、電気メッキにより陽極酸化被膜の上
面に形成されている。
The surface layer is formed of metals such as lead, indium, tin, and alloys thereof on the upper surface of the anodized film by electroplating, for example.

[発明の効果] 本発明の摺動材料で構成される摺動面は、アルミニウム
またはアルミニウム合金の母材の上面が陽極酸化被膜で
覆われ、その上面を軟質金属のメッキにより形成された
表面層で構成されている。
[Effects of the Invention] In the sliding surface made of the sliding material of the present invention, the upper surface of the base material of aluminum or aluminum alloy is covered with an anodized film, and the upper surface is covered with a surface layer formed by plating with a soft metal. It consists of

このため凝着しやすいアルミニウムやアルミニウム合金
の母材は摺動面に表出されていない。従って本発明の摺
動材料で形成されるアルミニウム母材の摺動向は、耐焼
付性が優れたものとなる。
Therefore, the base material of aluminum or aluminum alloy, which tends to adhere, is not exposed on the sliding surface. Therefore, the sliding movement of the aluminum base material formed from the sliding material of the present invention has excellent seizure resistance.

また始動初期のように潤滑油が一時的に供給されない様
な条件で運転された場合においても、摺動面は、表面層
の働きにより焼付きが防止され、さらに陽極酸化被膜が
表面層の内側に存在して母材を保護するので、比較的長
時間にわたって焼付き等の不都合を防止することができ
る。また、母材と表面層との間に陽極酸化被膜が形成さ
れているので表面層が薄くても陽極酸化被膜が母材を覆
っているので、摺動面の焼付き防止することができる。
In addition, even when operating under conditions where lubricating oil is temporarily not supplied, such as at the initial stage of startup, the sliding surface is prevented from seizing by the action of the surface layer, and the anodized coating on the inside of the surface layer is Since the base metal is present in the base metal and protects the base material, inconveniences such as seizure can be prevented for a relatively long period of time. Further, since the anodic oxide film is formed between the base material and the surface layer, even if the surface layer is thin, the anodic oxide film covers the base material, so that seizure of the sliding surface can be prevented.

従って、本発明の摺動材料は耐久性に優れた摺動面を形
成できる。
Therefore, the sliding material of the present invention can form a sliding surface with excellent durability.

[実施例] 本発明の1実施例の摺動材料の断面模式図を第1図に示
す。
[Example] FIG. 1 shows a schematic cross-sectional view of a sliding material according to an example of the present invention.

(母材試料の製法) 斜板の母材1は第1表に示す各組成のものを用いた。(Production method of base material sample) As the base material 1 of the swash plate, those having the compositions shown in Table 1 were used.

(陽極酸化被膜の形成) 10〜15重量%の硫酸水溶液を使用し、浴温を20〜
25°Cに保持して上記で形成した各母材をそれぞれ陽
極とし、陰極に鉛板を用いて、電流密度2A/dm3で
直流電流を適宜時間通電して陽極酸化処理をおこなって
斜板の母材1の表面に陽極酸化波WA2を形成した。形
成した陽極酸化被膜2の膜厚を第1表に示す。
(Formation of anodic oxide film) Using a 10-15% by weight sulfuric acid aqueous solution, the bath temperature is 20-20% by weight.
Holding at 25°C, each base material formed above is used as an anode, a lead plate is used as a cathode, and DC current is applied for an appropriate time at a current density of 2A/dm3 to perform anodizing treatment to form a swash plate. Anodized waves WA2 were formed on the surface of the base material 1. Table 1 shows the thickness of the anodic oxide film 2 formed.

(表面層の形成) 上記の方法で陽極酸化被膜2を形成した各母材1の表面
に、電気メッキにより表に示す組成の軟質金属メッキに
よる表面層3を形成した。形成した表面層3の膜厚を第
1表に示す。
(Formation of Surface Layer) On the surface of each base material 1 on which the anodic oxide film 2 was formed by the above method, a surface layer 3 of soft metal plating having the composition shown in the table was formed by electroplating. Table 1 shows the thickness of the formed surface layer 3.

この各試料の斜板の実機テストを、潤滑油を通常の10
%の量とし相手材は5UT−2焼入れを用い、運転時間
を15分間とし、回転数3000rl)III 、40
00rl)m 、5000rl)m r実施シタ。
The swash plate of each sample was tested on an actual machine, and the lubricating oil was
%, the mating material was 5UT-2 quenched, the operating time was 15 minutes, and the rotation speed was 3000 rl) III, 40
00rl)m, 5000rl)mr implementation site.

結果を第1表に示す。本実施例No 1〜11の摺動材
料はこの試験に合格した。なお、比較例のNo12は表
面層3を形成しない場合であり、N。
The results are shown in Table 1. The sliding materials of Examples Nos. 1 to 11 passed this test. Note that Comparative Example No. 12 is a case where the surface layer 3 is not formed, and is N.

13は陽極酸化被膜2を形成せず表面層3を母材1に直
接形成した場合である。前者のNo12は合格したが、
後者のNo13は焼付きか発生し陽極酸化被膜の形成が
必要であることを示している。
13 is a case where the surface layer 3 was directly formed on the base material 1 without forming the anodic oxide film 2. I passed the former No. 12, but
The latter No. 13 indicates that seizure has occurred and it is necessary to form an anodic oxide film.

第2表に示す各組成の母材1を鋳造し、圧延と焼鈍を適
当回数繰返し、その後これらの合金と裏板鋼板とを圧接
してバイメタル材とし、これを焼鈍した後、所定形状の
すへり軸受に加工して母材1とした。以下は上記と同じ
処理をおこなった。
The base metal 1 of each composition shown in Table 2 is cast, rolled and annealed an appropriate number of times, and then these alloys and a back steel plate are pressure-welded to form a bimetallic material. It was processed into an edge bearing and used as base material 1. The following process was the same as above.

各試料について焼付試験および疲労試験をおこなった。A seizure test and a fatigue test were conducted on each sample.

結果を第2表に示す。The results are shown in Table 2.

なお、焼付試験は、試験機:ジャーナル型軸受試験機、
回転数:5000rpm、潤滑油ニア、5W−30、油
温:140℃、相手軸:545C焼入れ、軸粗ざ:Q、
8μmRZ、面圧:120に!j/dの条件で、潤滑油
の供給をとめて焼付までの時間を測定した。
In addition, the seizure test was performed using a testing machine: journal type bearing testing machine,
Rotation speed: 5000 rpm, lubricating oil near, 5W-30, oil temperature: 140℃, mating shaft: 545C quenching, shaft roughness: Q,
8μmRZ, surface pressure: 120! The lubricating oil supply was stopped and the time until seizure was measured under the conditions of j/d.

疲労試験は、試験機二回転荷重試験機、回転数二800
0rpm、潤滑油:10W−30、油温:160℃、相
手軸:850C焼入れ、軸粗さ二〇。
The fatigue test was performed using a two-rotation load tester with a rotation speed of 2800.
0 rpm, lubricating oil: 10W-30, oil temperature: 160℃, mating shaft: 850C quenching, shaft roughness 20.

4〜0.6μmRZ、面圧: 300KI/ctAの条
件で、潤滑油の供給をとめて焼付までの時間を測定した
The supply of lubricating oil was stopped and the time until seizure was measured under the conditions of 4 to 0.6 μm RZ and surface pressure: 300 KI/ctA.

比較例のNo12の陽極酸化被膜だけのものは耐焼付性
および耐疲労性が低い。
Comparative Example No. 12, which had only an anodic oxide coating, had low seizure resistance and fatigue resistance.

比較例のN013の陽極酸化被膜を形成しない場合では
、厚い表面層が存在するので耐焼付性はよいが、耐疲労
性が著しく劣っていた。
In the comparative example N013 in which no anodic oxide film was formed, the seizure resistance was good because of the presence of a thick surface layer, but the fatigue resistance was significantly poor.

実施例のNo 1〜11は、いずれも耐焼付性、耐疲労
性共に優れている。
Examples Nos. 1 to 11 are all excellent in both seizure resistance and fatigue resistance.

【図面の簡単な説明】[Brief explanation of drawings]

図面は本発明の実施例を示したもので、第1図は母材の
表面に陽極酸化被膜を形成し、その上方に軟質金属のメ
ッキによる潤滑剤層を形成した状態を模式的に示した断
面図である。 特許出願人  大豊工業株式会社 株式会社豊田自動織機製作所
The drawings show an embodiment of the present invention. Figure 1 schematically shows a state in which an anodic oxide film is formed on the surface of a base material, and a lubricant layer is formed by plating a soft metal above it. FIG. Patent applicant: Taiho Kogyo Co., Ltd. Toyota Industries Corporation

Claims (1)

【特許請求の範囲】[Claims]  アルミニウム又はアルミニウム合金よりなる母材と、
該母材の表面を覆って形成された陽極酸化被膜と、該陽
極酸化被膜の上面に鉛、インジウム、錫またはそれらの
合金よりなるメッキ層で構成される表面層とからなるこ
とを特徴とする摺動材料。
A base material made of aluminum or aluminum alloy,
It is characterized by comprising an anodic oxide film formed to cover the surface of the base material, and a surface layer consisting of a plating layer made of lead, indium, tin, or an alloy thereof on the upper surface of the anodic oxide film. sliding material.
JP29014890A 1990-10-26 1990-10-26 Sliding material Pending JPH04180599A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP29014890A JPH04180599A (en) 1990-10-26 1990-10-26 Sliding material

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP29014890A JPH04180599A (en) 1990-10-26 1990-10-26 Sliding material

Related Parent Applications (1)

Application Number Title Priority Date Filing Date
JP58129646A Division JPS6022080A (en) 1983-07-15 1983-07-15 Swash plate type compressor

Publications (1)

Publication Number Publication Date
JPH04180599A true JPH04180599A (en) 1992-06-26

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Family Applications (1)

Application Number Title Priority Date Filing Date
JP29014890A Pending JPH04180599A (en) 1990-10-26 1990-10-26 Sliding material

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Country Link
JP (1) JPH04180599A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0749188A2 (en) * 1995-06-13 1996-12-18 Nissin Electric Company, Limited Rotary section current transmitting mechanism

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5675592A (en) * 1979-11-26 1981-06-22 Ngk Insulators Ltd Sliding device

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5675592A (en) * 1979-11-26 1981-06-22 Ngk Insulators Ltd Sliding device

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0749188A2 (en) * 1995-06-13 1996-12-18 Nissin Electric Company, Limited Rotary section current transmitting mechanism
EP0749188A3 (en) * 1995-06-13 1997-03-05 Nissin Electric Co Ltd Rotary section current transmitting mechanism
US5827080A (en) * 1995-06-13 1998-10-27 Nissin Electric Co., Ltd. Rotary section current transmitting mechanism

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