JPH04163082A - Printing paper susceptible to highly detailed printing - Google Patents
Printing paper susceptible to highly detailed printingInfo
- Publication number
- JPH04163082A JPH04163082A JP2285969A JP28596990A JPH04163082A JP H04163082 A JPH04163082 A JP H04163082A JP 2285969 A JP2285969 A JP 2285969A JP 28596990 A JP28596990 A JP 28596990A JP H04163082 A JPH04163082 A JP H04163082A
- Authority
- JP
- Japan
- Prior art keywords
- plastic film
- paper
- printing
- pigment
- fixing layer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 238000007639 printing Methods 0.000 title claims abstract description 22
- 239000002985 plastic film Substances 0.000 claims abstract description 29
- 229920006255 plastic film Polymers 0.000 claims abstract description 29
- 239000000049 pigment Substances 0.000 claims abstract description 13
- 238000000034 method Methods 0.000 claims abstract description 12
- -1 polypropylene Polymers 0.000 abstract description 10
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 abstract description 8
- 239000004743 Polypropylene Substances 0.000 abstract description 6
- 239000000463 material Substances 0.000 abstract description 6
- 229920001155 polypropylene Polymers 0.000 abstract description 6
- 239000011230 binding agent Substances 0.000 abstract description 5
- 239000011347 resin Substances 0.000 abstract description 5
- 229920005989 resin Polymers 0.000 abstract description 5
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 abstract description 4
- 229910000019 calcium carbonate Inorganic materials 0.000 abstract description 4
- 239000004698 Polyethylene Substances 0.000 abstract description 3
- 238000010030 laminating Methods 0.000 abstract description 3
- 229920000573 polyethylene Polymers 0.000 abstract description 3
- 239000002270 dispersing agent Substances 0.000 abstract description 2
- 239000000377 silicon dioxide Substances 0.000 abstract description 2
- 235000012239 silicon dioxide Nutrition 0.000 abstract description 2
- 230000006978 adaptation Effects 0.000 abstract 1
- 230000002708 enhancing effect Effects 0.000 abstract 1
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 description 12
- 239000010410 layer Substances 0.000 description 8
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 6
- 239000004793 Polystyrene Substances 0.000 description 4
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 4
- 239000011248 coating agent Substances 0.000 description 4
- 238000000576 coating method Methods 0.000 description 4
- 239000000203 mixture Substances 0.000 description 4
- 229920002223 polystyrene Polymers 0.000 description 4
- 239000002904 solvent Substances 0.000 description 4
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 4
- 239000002344 surface layer Substances 0.000 description 3
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 2
- 238000005452 bending Methods 0.000 description 2
- ZFMQKOWCDKKBIF-UHFFFAOYSA-N bis(3,5-difluorophenyl)phosphane Chemical compound FC1=CC(F)=CC(PC=2C=C(F)C=C(F)C=2)=C1 ZFMQKOWCDKKBIF-UHFFFAOYSA-N 0.000 description 2
- BVKZGUZCCUSVTD-UHFFFAOYSA-N carbonic acid Chemical compound OC(O)=O BVKZGUZCCUSVTD-UHFFFAOYSA-N 0.000 description 2
- 230000015271 coagulation Effects 0.000 description 2
- 238000005345 coagulation Methods 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000006260 foam Substances 0.000 description 2
- 238000003475 lamination Methods 0.000 description 2
- 238000004804 winding Methods 0.000 description 2
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 1
- 239000004677 Nylon Substances 0.000 description 1
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 1
- YKTSYUJCYHOUJP-UHFFFAOYSA-N [O--].[Al+3].[Al+3].[O-][Si]([O-])([O-])[O-] Chemical compound [O--].[Al+3].[Al+3].[O-][Si]([O-])([O-])[O-] YKTSYUJCYHOUJP-UHFFFAOYSA-N 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- 229920002301 cellulose acetate Polymers 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 229910052570 clay Inorganic materials 0.000 description 1
- 238000009820 dry lamination Methods 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 238000007765 extrusion coating Methods 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 239000012943 hotmelt Substances 0.000 description 1
- 239000004816 latex Substances 0.000 description 1
- 229920000126 latex Polymers 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000001459 lithography Methods 0.000 description 1
- ZLNQQNXFFQJAID-UHFFFAOYSA-L magnesium carbonate Chemical compound [Mg+2].[O-]C([O-])=O ZLNQQNXFFQJAID-UHFFFAOYSA-L 0.000 description 1
- 239000001095 magnesium carbonate Substances 0.000 description 1
- 229910000021 magnesium carbonate Inorganic materials 0.000 description 1
- 239000010445 mica Substances 0.000 description 1
- 229910052618 mica group Inorganic materials 0.000 description 1
- 229920001778 nylon Polymers 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
- 238000007645 offset printing Methods 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 239000004800 polyvinyl chloride Substances 0.000 description 1
- 229920000915 polyvinyl chloride Polymers 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- 238000009816 wet lamination Methods 0.000 description 1
- 239000011787 zinc oxide Substances 0.000 description 1
- XOOUIPVCVHRTMJ-UHFFFAOYSA-L zinc stearate Chemical compound [Zn+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O XOOUIPVCVHRTMJ-UHFFFAOYSA-L 0.000 description 1
Landscapes
- Ink Jet Recording Methods And Recording Media Thereof (AREA)
- Paper (AREA)
Abstract
Description
【発明の詳細な説明】
（産業上の利用分野）
本発明は水や湿分によって表面に凹凸を生じる事な（、
従来合成紙が使用されていた分野に使用できる印刷用紙
で、高精細な印刷をするための印刷用紙に関するもので
ある。[Detailed Description of the Invention] (Industrial Application Field) The present invention prevents unevenness from occurring on the surface due to water or moisture.
This printing paper can be used in fields where synthetic paper has traditionally been used, and relates to printing paper for high-definition printing.
（従来の技術）
従来の合成紙は、基材にプラスチックフィルムを使用し
たものが一般的で、 平坦性、平滑性が良好なため、高
精細な印刷用紙に使用されていた。(Prior Art) Conventional synthetic paper generally uses plastic film as its base material, and because of its good flatness and smoothness, it has been used for high-definition printing paper.
特に、ジメチルホルムアミドを溶剤とした湿式凝固法に
より得られる合成紙は、平滑度が高く、独特の多孔質構
造を持った表層が得られ、高精細な印刷が可能である。In particular, synthetic paper obtained by a wet coagulation method using dimethylformamide as a solvent has high smoothness and a surface layer with a unique porous structure, allowing for high-definition printing.
（発明が解決しようとする問題点）
然し乍ら、上記のプラスチックフィルムを基材とした合
成紙は一般に価格が高く、特に厚手のものは、平坦なフ
ィルムを得にくい上に非常に高価格であり、そのほか次
のような問題点もある。(Problems to be Solved by the Invention) However, synthetic paper based on the above-mentioned plastic film is generally expensive, and especially thick ones are difficult to obtain a flat film and are very expensive. There are other problems as well:
即ち、断裁やスリット等の加工性が悪く、カールしやす
い上に、−旦カールすると、そのカ−ル癖が直りにくい
こと、又引裂強度が弱し１等の問題点がある。That is, it has problems such as poor workability in cutting and slitting, easy curling, difficulty in straightening the curl once curled, and low tear strength.
（！！題を解決するための手段）
上記問題点を解決するため本発明では、基紙と該基紙に
顔料を混入したプラスチックフィルム、或いは発泡プラ
スチックフィルムを貼合したものを基材として、その上
にインク定着層を設けることにより高精細な印刷ができ
る安価な印刷用紙を提供するものである。(Means for Solving the Problem) In order to solve the above problems, the present invention uses a base paper and a plastic film mixed with a pigment or a foamed plastic film bonded to the base paper as a base material. By providing an ink fixing layer thereon, an inexpensive printing paper capable of high-definition printing is provided.
次に本発明について詳細に説明する。Next, the present invention will be explained in detail.
本発明の印刷用紙に使用する基紙としては、上質紙やア
ート紙、コート紙、キマスティングコート紙等種々のも
のから選択することができる。The base paper used for the printing paper of the present invention can be selected from various materials such as high-quality paper, art paper, coated paper, and mastering coated paper.
又、該基紙に貼合するプラスチックフィルムには、ポリ
プロピレン、ポリエチレン、ポリスチレン、ポリ塩化ビ
ニル、酢酸セルロース、ナイロン、ポリエステル等があ
り、これらの顔料混用体或いは発泡体が用いられる。The plastic film to be bonded to the base paper includes polypropylene, polyethylene, polystyrene, polyvinyl chloride, cellulose acetate, nylon, polyester, etc., and pigment mixtures or foams of these are used.
顔料としては二酸化珪素、炭酸カルシウム、炭酸マグネ
シウム、酸化亜鉛、水酸化アルミニウム、酸化チタン、
珪酸力ルンウム、珪酸アルミニウム、マイカ、クレイ、
タルク、アルミナ、ステアリンサン亜鉛、ステアリンサ
ン力ルンウム、ポリエチレン、ポリプロピレン、ポリス
チレン等が用いられる。Pigments include silicon dioxide, calcium carbonate, magnesium carbonate, zinc oxide, aluminum hydroxide, titanium oxide,
silicate, aluminum silicate, mica, clay,
Talc, alumina, zinc stearate, stearate, polyethylene, polypropylene, polystyrene, etc. are used.
貼合するプラスチックフィルムは、単にグラスチックフ
ィルムを用いるのではなく、その顔料混入体、或いは発
泡体を用いることにより貼合フィルムのコストを下げる
、或いは日色度。The plastic film to be laminated is not just a glass film, but a pigment-containing product or foam is used to reduce the cost of the laminated film, or to improve the photochromicity.
不透明度を上げる、クッンヨン性をもたせるなどの機能
を持たせることが出来る。It can have functions such as increasing opacity and giving it a smooth texture.
前記基紙、及びプラスチックフィルムの貼合は押し出し
ラミネーション、押し出しコーティング、ウェットラミ
ネーション、ドライラミネーション、ホットメルトラミ
ネーション等いずれの方法でもよい。The base paper and the plastic film may be laminated by any method such as extrusion lamination, extrusion coating, wet lamination, dry lamination, or hot melt lamination.
片面にのみプラスチックフィルムを貼合したものは、水
分により全体がカールしてしまうことがあるので、これ
を防止するために他の面にはコーティング等により防水
加工を施してもよい。プラスチックフィルムには、イン
キ定着層との密着を上げるため易接着処理をしてもよい
。If a plastic film is attached only to one side, the entire surface may curl due to moisture, so to prevent this, the other side may be waterproofed by coating or the like. The plastic film may be subjected to adhesion treatment to improve adhesion to the ink fixing layer.
前記プラスチックフィルム上に設けるインキ定着層は、
例えばバインダー樹脂、分散剤、可塑剤や顔料等から組
成されるものであり、プラスチックフィルム上への適用
には、湿式法や乾式法等周知の表層形成法を用いること
ができる。The ink fixing layer provided on the plastic film is
For example, it is composed of a binder resin, a dispersant, a plasticizer, a pigment, etc., and a well-known surface layer forming method such as a wet method or a dry method can be used for application onto a plastic film.
特にジメチルホルムアミドを溶剤とした湿式凝固法によ
り得られる合成紙は、平滑度が高く、独特の多孔質構造
を持った表層が得られ、高精細な印刷が可能である。In particular, synthetic paper obtained by a wet coagulation method using dimethylformamide as a solvent has high smoothness and a surface layer with a unique porous structure, allowing for high-definition printing.
両面にプラスチックフィルムを貼合したものは、必要に
応じてインキ定着層を両面又は片面に設けることができ
る。When plastic films are pasted on both sides, an ink fixing layer can be provided on both sides or one side, if necessary.
印刷方法としては、凹版、平版、凸版、孔版などがある
が、いずれの方法でもよい。Printing methods include intaglio, lithography, letterpress, and stencil printing, and any method may be used.
（実施例）
・実施例１
７０ｇ／ゴの紙（８５μ）に、炭酸カルンウムを混入し
たポリプロピレンフィルム（１０μ）を両面貼合した後
、易接着処理をし、下記組成の塗布液をブレードコータ
ーで塗布し、水中に１分間浸漬した後に９０℃の熱水中
に５秒間浸漬し、その後風乾すると厚さ３０μのインキ
定着層が形成された。(Example) ・Example 1 After laminating a polypropylene film (10μ) mixed with carunium carbonate on both sides of a 70g/g paper (85μ), it was treated to facilitate adhesion, and a coating solution with the following composition was applied using a blade coater. It was coated, immersed in water for 1 minute, then immersed in hot water at 90° C. for 5 seconds, and then air-dried to form an ink fixing layer with a thickness of 30 μm.
ポリスチレン（バインダー樹脂） １００ｉジメチ
ルホルムアミド（溶媒） ６０（ＨＥジオクチル
アジペート （可塑性）２０部酸化チタン（顔料）５０
部
炭酸カルシウム ２００部得られた印
刷用紙をオフセット印刷機にかけ、プロセスインキを用
いて印刷をした。その結果印刷用紙の網点の再現性が良
く、精細な印刷物が得ちれた。カール住、折り曲げ性も
良好であり、引裂強度は巻方向で１４４ｇ、幅方向で３
３０ｇであった。Polystyrene (binder resin) 100i Dimethylformamide (solvent) 60 (HE dioctyl adipate (plasticity) 20 parts Titanium oxide (pigment) 50
200 parts of calcium carbonate The obtained printing paper was applied to an offset printing machine and printed using process ink. As a result, the reproducibility of halftone dots on printing paper was good, and fine prints were obtained. It has good curling and bending properties, and the tear strength is 144 g in the winding direction and 3 in the width direction.
It was 30g.
・実施例２
７０ｇ／ｍ’の紙（８５μ）に、炭酸力ルンウムを混入
したポリプロピレンフィルム（１０μ）を両面貼合した
後、易接着処理をし、下記組成の塗布液をブレードコー
ターで塗布し、熱風乾燥機で乾燥し厚さ１０μのインキ
定着層が形成された。・Example 2 After laminating a polypropylene film (10μ) mixed with carbonic acid on both sides of 70g/m' paper (85μ), it was treated to facilitate adhesion, and a coating liquid with the following composition was applied with a blade coater. The ink fixing layer was dried in a hot air dryer to form an ink fixing layer with a thickness of 10 μm.
アクリルスチレン系ラテックス
（バインダー樹脂）６０邪
水
１００部酸化チタン ３Ｑ部炭
酸力ルンウム １００邪界面活性剤
１０邪得られた印刷用紙を実
施例１と同様に印刷した所、網点の再現性が良く、精細
な印刷物が得られた。カール性、折り曲げ性、引裂強度
は実施例１と同様に良好であった。Acrylic styrene latex (binder resin) 60 evil water
100 parts titanium oxide 3Q parts carbonic acid 100 parts surfactant 10 parts When the obtained printing paper was printed in the same manner as in Example 1, fine prints with good reproducibility of halftone dots were obtained. The curling properties, bending properties, and tear strength were as good as in Example 1.
・比較例
１００μのポリプロピレンフィルムに、下記組成の塗布
液をブレードコーターで塗布し、水中に１分間浸漬した
後に９０℃の熱水中に５秒間浸漬し、その後風乾すると
厚さ３０μのインキ定着層が形成された。・Comparative Example A coating solution with the following composition was applied to a 100 μm polypropylene film using a blade coater, immersed in water for 1 minute, then immersed in 90°C hot water for 5 seconds, and then air-dried to form an ink fixing layer with a thickness of 30 μm. was formed.
ポリスチレン（バインダー樹脂） １００ｔＥジメ
チルホルムアミド（溶媒） ６００ｆＢジオクチ
ルアジペート （可塑性”） ２ＯＮ酸化チタン（
顔料）５０部
炭酸カルシウム ２００部得られたコ
ート紙を実施例１と同様の印刷をした所、網点の再現性
及び精細性は同等であったが、カールがみられ、折り曲
げ性も不良であった。引裂強度は巻方向で７０ｇ１幅方
向で３５ｇしかなかった。Polystyrene (binder resin) 100tE dimethylformamide (solvent) 600fB dioctyl adipate (plasticity) 2ON titanium oxide (
Pigment) 50 parts Calcium carbonate 200 parts When the obtained coated paper was printed in the same manner as in Example 1, the reproducibility and definition of the halftone dots were the same, but curling was observed and the bendability was poor. there were. The tear strength was 70 g in the winding direction and only 35 g in the width direction.
また、実施例のコストは比較例のコストの、１〜２割減
であり、コストも安価になった。Further, the cost of the example was 10 to 20% lower than that of the comparative example, and the cost was also lower.
（発明の効果）
本発明は、上述のように基紙に顔料混入プラスチックフ
ィルム或いは発泡プラスチックフィルムを貼合した基材
を用いるため、従来のプラスチックフィルムを基材とし
た合成紙に比較して安価に製造でき、高精細な印刷がで
きる。(Effects of the Invention) As described above, the present invention uses a base material in which a pigment-containing plastic film or a foamed plastic film is laminated to the base paper, so it is less expensive than conventional synthetic paper based on a plastic film. can be manufactured and high-definition printing is possible.
また、断裁やスリットなどの加工性、耐カール性も良好
である。又、引裂強度も同上するとともに折り曲げ性も
良好な印刷用紙が得られる等の効果がある。In addition, it has good workability such as cutting and slitting, and curl resistance. Further, there are effects such as the ability to obtain printing paper that has the same tear strength as above and also has good bendability.
Claims (3)
たプラスチックフィルムを貼合し、該プラスチックフィ
ルム上の少なくとも片面にイク定着層を設けたことを特
徴とする印刷用紙。(1) A printing paper comprising a base paper and a plastic film mixed with a pigment attached to at least one side of the base paper, and a fixing layer provided on at least one side of the plastic film.
ックフィルムを貼合し、該プラスチックフィルムの少な
くとも片面にインク定着層を設けたことを特徴とする印
刷用紙。(2) A printing paper comprising a base paper and a foamed plastic film bonded to at least one side of the base paper, and an ink fixing layer provided on at least one side of the plastic film.
する特許請求の範囲第１項および第２項に記載の印刷用
紙。(3) The printing paper according to claims 1 and 2, wherein the ink fixing layer is provided by a wet method.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2285969A JPH04163082A (en) | 1990-10-25 | 1990-10-25 | Printing paper susceptible to highly detailed printing |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2285969A JPH04163082A (en) | 1990-10-25 | 1990-10-25 | Printing paper susceptible to highly detailed printing |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH04163082A true JPH04163082A (en) | 1992-06-08 |
Family
ID=17698315
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2285969A Pending JPH04163082A (en) | 1990-10-25 | 1990-10-25 | Printing paper susceptible to highly detailed printing |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH04163082A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104204353A (en) * | 2012-01-13 | 2014-12-10 | 阿约威津斯优质纸有限公司 | Method for producing a sheet |
-
1990
- 1990-10-25 JP JP2285969A patent/JPH04163082A/en active Pending
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104204353A (en) * | 2012-01-13 | 2014-12-10 | 阿约威津斯优质纸有限公司 | Method for producing a sheet |
| CN104204353B (en) * | 2012-01-13 | 2017-08-15 | 阿约威津斯优质纸有限公司 | The method for manufacturing plate |
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