JPH04131184A - Additive chemical for preparing electrolyzed bactericidal solution of hypochlorous acid - Google Patents
Additive chemical for preparing electrolyzed bactericidal solution of hypochlorous acidInfo
- Publication number
- JPH04131184A JPH04131184A JP2249755A JP24975590A JPH04131184A JP H04131184 A JPH04131184 A JP H04131184A JP 2249755 A JP2249755 A JP 2249755A JP 24975590 A JP24975590 A JP 24975590A JP H04131184 A JPH04131184 A JP H04131184A
- Authority
- JP
- Japan
- Prior art keywords
- solution
- nacl
- water
- value
- hypochlorous acid
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000000126 substance Substances 0.000 title claims abstract description 28
- 239000000654 additive Substances 0.000 title claims abstract description 24
- 230000000996 additive effect Effects 0.000 title claims abstract description 23
- QWPPOHNGKGFGJK-UHFFFAOYSA-N hypochlorous acid Chemical compound ClO QWPPOHNGKGFGJK-UHFFFAOYSA-N 0.000 title claims description 25
- 230000000844 anti-bacterial effect Effects 0.000 title abstract description 4
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 claims abstract description 74
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims abstract description 70
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 68
- 239000011780 sodium chloride Substances 0.000 claims abstract description 38
- 235000002639 sodium chloride Nutrition 0.000 claims description 34
- 239000000243 solution Substances 0.000 abstract description 36
- 238000005868 electrolysis reaction Methods 0.000 abstract description 9
- 239000000203 mixture Substances 0.000 abstract description 2
- 239000008151 electrolyte solution Substances 0.000 abstract 2
- 230000000717 retained effect Effects 0.000 abstract 2
- 230000007935 neutral effect Effects 0.000 abstract 1
- 150000003839 salts Chemical class 0.000 abstract 1
- 239000007864 aqueous solution Substances 0.000 description 13
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 11
- 239000000460 chlorine Substances 0.000 description 11
- 229910052801 chlorine Inorganic materials 0.000 description 11
- 230000001954 sterilising effect Effects 0.000 description 9
- 239000011575 calcium Substances 0.000 description 6
- 238000000034 method Methods 0.000 description 5
- 239000000047 product Substances 0.000 description 5
- 238000001556 precipitation Methods 0.000 description 3
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 2
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- 229910052791 calcium Inorganic materials 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 238000007865 diluting Methods 0.000 description 2
- 238000004090 dissolution Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 230000003472 neutralizing effect Effects 0.000 description 2
- 238000004659 sterilization and disinfection Methods 0.000 description 2
- BVKZGUZCCUSVTD-UHFFFAOYSA-M Bicarbonate Chemical compound OC([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-M 0.000 description 1
- 108091006629 SLC13A2 Proteins 0.000 description 1
- NKWPZUCBCARRDP-UHFFFAOYSA-L calcium bicarbonate Chemical compound [Ca+2].OC([O-])=O.OC([O-])=O NKWPZUCBCARRDP-UHFFFAOYSA-L 0.000 description 1
- 229910000020 calcium bicarbonate Inorganic materials 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- 235000010216 calcium carbonate Nutrition 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- WQYVRQLZKVEZGA-UHFFFAOYSA-N hypochlorite Inorganic materials Cl[O-] WQYVRQLZKVEZGA-UHFFFAOYSA-N 0.000 description 1
- -1 hypochlorite ions Chemical class 0.000 description 1
- 239000006193 liquid solution Substances 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000008399 tap water Substances 0.000 description 1
- 235000020679 tap water Nutrition 0.000 description 1
- 239000003643 water by type Substances 0.000 description 1
Landscapes
- Treatment Of Water By Oxidation Or Reduction (AREA)
- Water Treatment By Electricity Or Magnetism (AREA)
- Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)
Abstract
Description
【発明の詳細な説明】
〔発明の利用分野〕
本発明は電解によって次亜塩素酸含有殺菌水を製造する
のに適した添加薬液に関する。DETAILED DESCRIPTION OF THE INVENTION [Field of Application of the Invention] The present invention relates to an additive chemical solution suitable for producing hypochlorous acid-containing sterilized water by electrolysis.
次亜塩素酸水溶液はｐＨ８以上では次亜塩素酸イオン（
ＣＩＯ→となり、殺菌力が次亜塩素酸（ＨＣＩＯ）の場
合に比較して著しく減少する。Hypochlorous acid aqueous solution has hypochlorite ions (
CIO→, and the bactericidal power is significantly reduced compared to the case of hypochlorous acid (HCIO).
しかしｐ Ｈ３〜７の範囲ではＨＣｌ０の形で保たれ、
殺菌力が飛躍的に増大することが知られており（第２図
参照）、従って、ｐＨ３〜７の次亜塩素酸水は残留塩素
濃度が３０〜６０ｐｐｍ程度の低濃度でもｐＨ８の残留
塩素濃度２００ｐｐｍ程度の殺菌水と同等の殺菌効果が
得られる。そこでこの種の殺菌水を得る方法として、塩
化ナトリウム水溶液を電解して陽極室側にｐＨ３〜７の
次亜塩素酸水を得ることが行われている。However, in the pH range of 3 to 7, it is maintained in the form of HCl0,
It is known that the bactericidal power increases dramatically (see Figure 2). Therefore, hypochlorous acid water with a pH of 3 to 7 has a residual chlorine concentration of pH 8 even if the residual chlorine concentration is as low as 30 to 60 ppm. The same sterilizing effect as sterilizing water of about 200 ppm can be obtained. Therefore, as a method for obtaining this type of sterilized water, a sodium chloride aqueous solution is electrolyzed to obtain hypochlorous acid water having a pH of 3 to 7 on the anode chamber side.
ところがＮａＣｌは２５％近くの濃度になると常温では
溶解に非常に時間がかかり、沈澱していることを知らな
いでいると所定量のＮａＣｌを添加したにもかかわらず
、所定のｐＨ値及び所定濃度の次亜塩素酸殺菌水が生成
されないという問題か生ずる。However, when NaCl reaches a concentration close to 25%, it takes a very long time to dissolve at room temperature. The problem arises that hypochlorous acid sterilized water is not produced.
また、塩化ナトリウム水溶液の原水中には主に重炭酸カ
ルシウムＣａ （ＨＣＯ３） ｙの形でカルシウムＣａ
が溶は込んでいるので塩化ナトリウム水溶液の電解処理
中にＣａが析出し、これが陰極に付着することによって
電解電圧が上昇したり、電解電流が流れにくくなるとい
うトラブルが生ずる。同様の原因で流水抵抗が大きくな
り、供給水量が下がるため、特に、水を連続的に通水し
て電解する電解装置では連続運転ができなくなってしま
う。In addition, in the raw water of sodium chloride aqueous solution, calcium is mainly present in the form of calcium bicarbonate, Ca (HCO3) y.
Since Ca is dissolved in the aqueous solution, Ca precipitates during the electrolytic treatment of the aqueous sodium chloride solution, and this adheres to the cathode, causing problems such as an increase in the electrolytic voltage and a difficulty in the flow of electrolytic current. Due to similar reasons, water flow resistance increases and the amount of water supplied decreases, making it impossible to operate continuously, especially in electrolyzers that electrolyze water by continuously passing water through it.
そこで、本件特許出願人は原水に塩化ナトリウムを添加
するとともに、塩酸水溶液を添加して電解を行う殺菌水
製造方法を開発し、平成２年８月１０日に平成２年特許
出願第２１３２８１号として特許出願をした。Therefore, the applicant of this patent developed a method for producing sterilized water in which sodium chloride is added to raw water and a hydrochloric acid aqueous solution is added to perform electrolysis. I filed a patent application.
この方法では塩酸ＨＣＩの添加により、ＣａＣＯ３↓＋
２ ＨＣＩ →Ｃａ Ｃｌ ｚ ＋ Ｈ２ＣＯｙの反応
が行われ、ＣａＣ０，はＣａＣ］、の形で液中に溶解し
Ｃａの付着が解消されるとともに、ＭＣＩは中和作用に
より電解処理水のｐＨ値を所望の値３〜７に下げる働き
をし、−石二鳥の効果が得られる。In this method, by adding hydrochloric acid HCI, CaCO3↓+
2 HCI → Ca Cl z + H2COy reaction takes place, CaC0, is dissolved in the solution in the form of It works to lower the value to the desired value of 3 to 7, resulting in the effect of killing two birds.
しかしながら、上記特許出願の方法では塩化ナトリウム
ＮａＣｌ及び塩酸ＨＣＩの所定濃度の水溶液を原水に対
して別々に添加していたため、このような二液性の薬液
を添加して電解殺菌水を製造しようとすると厳密な調合
が保証されにくく、特に、いずれか一方の薬液供給ポン
プ等が故障したりすると調合比率がくるい、目的のｐＨ
値が得られなくなるという問題がある。However, in the method of the above-mentioned patent application, aqueous solutions of sodium chloride (NaCl) and hydrochloric acid (HCI) at predetermined concentrations were separately added to raw water. In this case, it is difficult to guarantee precise mixing, and in particular, if one of the chemical supply pumps breaks down, the mixing ratio will be distorted, and the desired pH will not be achieved.
There is a problem that the value cannot be obtained.
従って、本発明の主たる目的は所定量の水に予めＨＣＩ
とＮａＣｌを混合、溶解させた一液性の電解次亜塩素酸
殺菌水製造用添加薬液を提供することにより、上記の問
題を同時に解決することにある。Therefore, the main objective of the present invention is to add HCl to a predetermined amount of water in advance.
The purpose of the present invention is to simultaneously solve the above problems by providing a one-component additive chemical solution for producing electrolytic hypochlorous acid sterilized water in which NaCl and NaCl are mixed and dissolved.
ところで、電解により次亜塩素酸殺菌水を製造する場合
の原水には水道水、地下水などいろいろな水質の水が使
用されるが、これらの水を殺菌力の強いｐＨ３〜７、残
留塩素濃度３０〜６０Ｔ）ｌ）ｍの範囲の殺菌水に生成
するべく添加薬液中のＮａｃＩとＨＣＩの濃度比率をそ
の都度求めることはきわめて煩雑であり、専門知識を要
する。By the way, when producing hypochlorous acid sterilized water by electrolysis, water of various qualities such as tap water and underground water is used as raw water, but these waters have a strong sterilizing power with a pH of 3 to 7 and a residual chlorine concentration of 30. It is extremely complicated and requires specialized knowledge to determine each time the concentration ratio of NacI and HCI in the additive chemical solution to produce sterilized water in the range of ~60T)l)m.
従って、本発明の他の目的はいろいろな水質の水に対し
、上記範囲のｐＨ値と残留塩素濃度の殺菌水が得られる
ように予めＮａＣｌとＨＣＩの濃度比率を所定範囲に設
定した前記−液性の添加薬液を提供することにある。Therefore, another object of the present invention is to prepare the above-mentioned solution with a concentration ratio of NaCl and HCI set in advance in a predetermined range so as to obtain sterilized water with a pH value and residual chlorine concentration in the above range for water of various water quality. The purpose of this invention is to provide a chemical solution with additives.
本発明の上記目的は、塩酸水溶液に食塩ＮａＣ１を溶解
させてなる電解次亜塩素酸殺菌水製造用添加薬液によっ
て達成される。The above object of the present invention is achieved by an additive chemical solution for producing electrolytic hypochlorous acid sterilized water, which is prepared by dissolving common salt NaC1 in an aqueous hydrochloric acid solution.
本発明の他の目的は、ＮａＣｌ１度が１０％〜３０％で
あって、塩酸濃度がＮａＣｌの濃度の６分の１〜３分の
１の比率で含まれている電解次亜塩素酸殺菌水製造用添
加薬液によって達成される。Another object of the present invention is electrolytic hypochlorous acid sterilization water containing 10% to 30% of NaCl and a hydrochloric acid concentration of 1/6 to 1/3 of the concentration of NaCl. This is achieved through additive chemical solutions for manufacturing.
本発明の電解次亜塩素酸殺菌水製造用添加薬液はＨＣＩ
水溶液とＮａＣ１を一液の溶液に調合しであるのでＨＣ
Ｉの中和作用によって生成される殺菌水のｐＨ値をより
少ない消費電力で３〜７に下げることができるとともに
、カルシウムＣａの析出が防止される。The additive chemical solution for producing electrolyzed hypochlorous acid sterilized water of the present invention is HCI
Since the aqueous solution and NaCl are mixed into a single solution, HC
The pH value of the sterilizing water produced by the neutralizing action of I can be lowered to 3 to 7 with less power consumption, and precipitation of calcium Ca is prevented.
また、ＨＣＩ水溶液にＮａＣｌを溶かすのでＮａｃＩの
溶解効率が良くなり、ＮａＣｌの沈澱によって殺菌水の
ｐＨや残留塩素濃度が意に反して変動することがない。Furthermore, since NaCl is dissolved in the HCI aqueous solution, the dissolution efficiency of Nacl is improved, and the pH and residual chlorine concentration of the sterilizing water do not change unexpectedly due to precipitation of NaCl.
また、添加薬液中のＮａＣｌの濃度を１０％〜３０％と
し、塩酸濃度がＮａＣｌの上記濃度の６分の１乃至３分
の１の濃度になるように調合比率を設定した上記添加薬
液を原水に添加して電解すると、無隔膜電解による電解
生成水はその全量がｐＨ３〜７の範囲に保持され、また
、型棒間を電解隔膜で仕切った有隔膜電解による電解生
成水も、陽極側の電解生成水と陰極側の電解生成水を混
合したものは全体としてｐＨ３〜７の範囲に保持される
。In addition, the concentration of NaCl in the additive chemical solution was set to 10% to 30%, and the mixing ratio was set so that the concentration of hydrochloric acid was 1/6 to 1/3 of the above concentration of NaCl. When electrolyzed, the total amount of electrolytically produced water by non-diaphragm electrolysis is maintained in the pH range of 3 to 7, and the electrolytically produced water by diaphragm electrolysis, in which the mold rods are partitioned by an electrolytic diaphragm, is also kept at pH 3 to 7. The mixture of the electrolytically produced water and the electrolytically produced water on the cathode side is maintained in the pH range of 3 to 7 as a whole.
すなわち、このｐ）Ｔ値の範囲の次亜塩素酸水溶液は残
留塩素のほとんどがＨＯＣＩの形で保たれ最も殺菌力の
強い水となる。That is, in a hypochlorous acid aqueous solution within this p)T value range, most of the residual chlorine is kept in the form of HOCI, making it water with the strongest sterilizing power.
〔発明の実施例〕
本発明の薬液は電解工程を経て次亜塩素酸含有殺菌水を
製造する際に、電解される原水に混合する添加薬液であ
り、基本的には塩酸水溶液を混合して作った溶媒に食塩
ＮａＣ１を溶解してなるものである。[Embodiments of the Invention] The chemical solution of the present invention is an additive chemical solution that is mixed with electrolyzed raw water when producing hypochlorous acid-containing sterilized water through an electrolysis process, and is basically mixed with an aqueous hydrochloric acid solution. It is made by dissolving common salt NaCl in the prepared solvent.
すでに述べたように、次亜塩素酸水溶液はｐ Ｈ３〜７
の範囲にあるときに殺菌力が最も強いから、本発明の添
加薬液は各種水質の原水に使用した場合に生成される電
解次亜塩素酸殺菌水製品のＴ） Ｈ値が常にこの範囲に
なるように予め塩酸及びＮａＣ１の濃度比率を特定して
おくのが有利である。As already mentioned, hypochlorous acid aqueous solution has a pH of 3 to 7.
Since the sterilizing power is strongest when it is within this range, the T)H value of the electrolyzed hypochlorous acid sterilized water product produced when the additive chemical solution of the present invention is used in raw water of various water quality will always be within this range. It is advantageous to specify the concentration ratio of hydrochloric acid and NaCl in advance.
ここで「電解次亜塩素酸殺菌水製品・とは薬液を添加し
た原水を電解して得た電解水及びこの電解水を電解しな
い原水で希釈したものを総称する。Here, ``electrolyzed hypochlorous acid sterilized water products'' collectively refers to electrolyzed water obtained by electrolyzing raw water to which a chemical solution has been added, and products obtained by diluting this electrolyzed water with raw water that is not electrolyzed.
そこで種々研究の結果、ＮａＣｌ濃度が１０％〜３０％
であって、且つ塩酸濃度が該ＮａＣｌの濃度の６分の１
乃至３分の１の比率で含まれている薬液はいろいろな水
質の原水に添加して電解した場合でも、ｐＨ３〜７の範
囲の次亜塩素酸殺菌水が得られ、」１記要請に応え得る
ことを児い出した。Therefore, as a result of various studies, the NaCl concentration was 10% to 30%.
and the concentration of hydrochloric acid is one-sixth of the concentration of NaCl.
Even when the chemical solution containing at a ratio of 1/3 to 1/3 is added to raw water of various quality and electrolyzed, hypochlorous acid sterilized water with a pH range of 3 to 7 can be obtained. I gave birth to what I could get.
実施例（］）
ＮａＣ１１０５ｇとＨＣＩ水溶液（３５％）５８川−を
原水で溶解して全量を１，０００−とする本発明の添加
薬液を得た。Example () 1105 g of NaC and 58 g of HCI aqueous solution (35%) were dissolved in raw water to obtain an additive chemical solution of the present invention having a total amount of 1,000 g.
この時のＮａＣｌ及びＨＣＩ濃度は以下の通りである。The NaCl and HCI concentrations at this time are as follows.
Ｎａ Ｃ］濃度 １０５−； ｌ、 ０００＝ Ｏ，
１０５＝ １０．５％ＨＣＩ濃度 ５８にＩ、 ０
ＯＯＸ ３５＝ ２．０％実施例（２）
ＮａＣ＋３００９とＨＣＩ水溶液（３５％）１５０ｒｒ
１１を原水で溶解して全量をｌ 、 ０００ ｍｌとす
る本発明の添加薬液を得た。NaC] concentration 105-; l, 000=O,
105 = 10.5% HCI concentration 58 to I, 0
OOX 35 = 2.0% Example (2) NaC+3009 and HCI aqueous solution (35%) 150rr
An additive chemical solution of the present invention was obtained by dissolving No. 11 in raw water to make a total volume of 1,000 ml.
このときのＮａＣＩ及びＨＣＩの濃度は以下の通りであ
る。The concentrations of NaCI and HCI at this time are as follows.
ＮａＣｌ濃度 ３００÷Ｌ ０ＯＯ＝ ００３−３０
％ＨＣＩ濃度 １５０−； Ｉ、 ０ＯＯＸ Ｏ，
３５＝ ５．２５％図は本発明による添加薬液を原水に
添加して無隔膜電解槽で電解し、得られた電解生成水を
原水で希釈して次亜塩素酸殺菌水製品として排出する装
置の概略説明図である。NaCl concentration 300÷L 0OO= 003-30
%HCI concentration 150-; I, 0OOX O,
35 = 5.25% The figure shows a device that adds the additive chemical solution according to the present invention to raw water, electrolyzes it in a non-diaphragm electrolytic cell, dilutes the obtained electrolyzed water with raw water, and discharges it as a hypochlorous acid sterilized water product. FIG.
給水部から原水をフロツイツチ−バルブ−流量計−逆止
弁を介して給水される原水に、予めＨＣｌとＮａＣｌを
一液に溶解させた本発明の薬液を添加して電解槽の下部
から連続的に通水しながら陰極と陽極に直流電解電圧を
印加して電解するとともに、電解槽の上部から原水を導
入し、この非電解原水で電解水を希釈した後、出口から
ｐＨ３〜７、残留塩素濃度３０〜６０ｐｐｍ程度の次亜
塩素酸殺菌水を製品として得るものである。The chemical solution of the present invention, in which HCl and NaCl are dissolved in one solution, is added to the raw water supplied from the water supply section through the flow meter, flow meter, and check valve, and the chemical solution is continuously supplied from the bottom of the electrolytic cell. While passing water through the cell, a DC electrolytic voltage is applied to the cathode and anode to perform electrolysis. Raw water is introduced from the top of the electrolytic tank, and after diluting the electrolyzed water with this non-electrolyzed raw water, the pH is 3 to 7 and the residual chlorine is removed from the outlet. Hypochlorous acid sterilized water with a concentration of about 30 to 60 ppm is obtained as a product.
尚、図では無隔膜電解槽を使用した場合を例示したが、
本発明の添加薬液は有隔膜の電解槽を使用する場合にも
同様に適用されることはもちろんである。In addition, although the figure illustrates the case where a membraneless electrolytic cell is used,
It goes without saying that the additive chemical solution of the present invention can be similarly applied to the case where an electrolytic cell with a diaphragm is used.
〔発明の効果〕
本発明の添加薬液はＨＣＩ水溶液にＮａＣｌが溶解され
ているのでＮａＣｌの溶解効率が良く、また、ＨＣＩの
中和作用により、生成される殺菌水のｐＨをより少ない
電力でｐＨ３〜７に調整できるとともにカルンウムの析
出も抑制できる。[Effects of the Invention] The additive chemical solution of the present invention has good NaCl dissolution efficiency because NaCl is dissolved in the HCI aqueous solution, and due to the neutralizing action of HCI, the pH of the sterilized water to be generated can be reduced to pH 3 with less electricity. -7 and can also suppress the precipitation of carunium.
しかも、−液性の溶液であるから、従来のように添加の
過程でＮａＣｌとＨＣＩの濃度比率がくろうことがな（
目的のｐＨ値及び残留塩素濃度の次亜塩素酸殺菌水が確
実に得られる。Moreover, since it is a -liquid solution, the concentration ratio of NaCl and HCI does not change during the addition process as in the conventional method.
Hypochlorous acid sterilized water with the desired pH value and residual chlorine concentration can be reliably obtained.
さらに、ＮａＣｌとＨＣＩの濃度比率を上記の範囲に特
定したー液性添加薬液を用いることにより、水質の異な
る各種の原水をｐＨ３〜７、残留塩素濃度３０〜６０ｐ
ｐｍの範囲の次亜塩素酸殺菌水に生成できるので面倒が
ない。また、添加薬液のＨＣＩ濃度は１０％以下である
ので市販が可能となり、専門知識のない一般需要者でも
安全に使用することができる。Furthermore, by using a liquid additive chemical solution, we specified the concentration ratio of NaCl and HCI within the above range, and by using a liquid additive, we were able to convert various types of raw water with different water quality to a pH of 3 to 7 and a residual chlorine concentration of 30 to 60 p.
Hypochlorous acid sterilization water can be generated within the pm range, so there is no hassle. Furthermore, since the HCI concentration of the additive chemical solution is 10% or less, it can be commercially available and can be used safely even by general users without specialized knowledge.
第１図は本発明による添加薬液を使用して次亜塩素酸殺
菌水を製造する装置の概略配管図、 第２図は残留遊離
塩素存在比とｐＨの関係を表わす図である。
特許出願人 株式会社オ ム コ 外１名代理人
弁理士 佐 藤 直 義第１図
第２図
〆
残留遊離塩素の存在比（幻FIG. 1 is a schematic piping diagram of an apparatus for producing hypochlorous acid sterilized water using the additive chemical solution according to the present invention, and FIG. 2 is a diagram showing the relationship between residual free chlorine abundance ratio and pH. Patent applicant Omco Co., Ltd. and one other agent
Patent Attorney Naoyoshi Sato Figure 1 Figure 2 Abundance ratio of residual free chlorine (phantom)
Claims (2)
次亜塩素酸殺菌水製造用添加薬液。(1) An additive chemical solution for producing electrolytic hypochlorous acid sterilized water, which is prepared by dissolving common salt NaCl in an aqueous hydrochloric acid solution.
度がＮａＣｌの濃度の６分の１〜３分の１の比率で含ま
れている請求項（１）記載の電解次亜塩素酸殺菌水製造
用添加薬液。(2) The electrolytic hypochlorous acid according to claim (1), wherein the NaCl concentration is 10% to 30%, and the hydrochloric acid concentration is contained at a ratio of 1/6 to 1/3 of the concentration of NaCl. Additive chemical solution for producing sterilized water.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2249755A JP2627101B2 (en) | 1990-09-19 | 1990-09-19 | Additive chemicals for the production of electrolytic hypochlorous acid sterilized water |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2249755A JP2627101B2 (en) | 1990-09-19 | 1990-09-19 | Additive chemicals for the production of electrolytic hypochlorous acid sterilized water |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH04131184A true JPH04131184A (en) | 1992-05-01 |
| JP2627101B2 JP2627101B2 (en) | 1997-07-02 |
Family
ID=17197745
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2249755A Expired - Lifetime JP2627101B2 (en) | 1990-09-19 | 1990-09-19 | Additive chemicals for the production of electrolytic hypochlorous acid sterilized water |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP2627101B2 (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB2334968A (en) * | 1998-03-03 | 1999-09-08 | Univ Northumbria Newcastle | Apparatus and method for the electrolytic production of hypochlorite |
| WO2009098870A1 (en) | 2008-02-08 | 2009-08-13 | Noguchi Dental Medical Research Institute | Dental sterilizing water, method for producing the water, and device for producing the water |
| JP2011088149A (en) * | 2011-02-07 | 2011-05-06 | Bisansei Denkaisui Kenkyusho:Kk | Method of preparing electrolyzed water and composition |
| JP2013154305A (en) * | 2012-01-30 | 2013-08-15 | Ishida Co Ltd | Electrolytic water generating device |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| TWI723601B (en) | 2019-10-29 | 2021-04-01 | 超水國際股份有限公司 | Monobasic hypochlorous acid disinfectant and its production method |
| TWI727680B (en) | 2020-02-27 | 2021-05-11 | 超水國際股份有限公司 | Hypochlorous acid disinfectant and its production method |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3819329A (en) * | 1971-05-11 | 1974-06-25 | Morton Norwich Products Inc | Spray sanitizing system with electrolytic generator |
| JPS6148587A (en) * | 1984-08-14 | 1986-03-10 | Asahi Glass Co Ltd | Method for adding hydrochloric acid to electrolytic cell |
-
1990
- 1990-09-19 JP JP2249755A patent/JP2627101B2/en not_active Expired - Lifetime
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3819329A (en) * | 1971-05-11 | 1974-06-25 | Morton Norwich Products Inc | Spray sanitizing system with electrolytic generator |
| JPS6148587A (en) * | 1984-08-14 | 1986-03-10 | Asahi Glass Co Ltd | Method for adding hydrochloric acid to electrolytic cell |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB2334968A (en) * | 1998-03-03 | 1999-09-08 | Univ Northumbria Newcastle | Apparatus and method for the electrolytic production of hypochlorite |
| WO2009098870A1 (en) | 2008-02-08 | 2009-08-13 | Noguchi Dental Medical Research Institute | Dental sterilizing water, method for producing the water, and device for producing the water |
| JP2011088149A (en) * | 2011-02-07 | 2011-05-06 | Bisansei Denkaisui Kenkyusho:Kk | Method of preparing electrolyzed water and composition |
| JP2013154305A (en) * | 2012-01-30 | 2013-08-15 | Ishida Co Ltd | Electrolytic water generating device |
Also Published As
| Publication number | Publication date |
|---|---|
| JP2627101B2 (en) | 1997-07-02 |
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