JPH04117301A - Preservative of freshness of cut flower and freshness preservation - Google Patents
Preservative of freshness of cut flower and freshness preservationInfo
- Publication number
- JPH04117301A JPH04117301A JP23563490A JP23563490A JPH04117301A JP H04117301 A JPH04117301 A JP H04117301A JP 23563490 A JP23563490 A JP 23563490A JP 23563490 A JP23563490 A JP 23563490A JP H04117301 A JPH04117301 A JP H04117301A
- Authority
- JP
- Japan
- Prior art keywords
- freshness
- cut flowers
- preservative
- flowers
- cut
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000003755 preservative agent Substances 0.000 title claims abstract description 13
- 230000002335 preservative effect Effects 0.000 title abstract 6
- 238000004321 preservation Methods 0.000 title 1
- -1 azole-substituted cyclopentanol Chemical class 0.000 claims abstract description 21
- 239000004480 active ingredient Substances 0.000 claims abstract description 8
- 125000000217 alkyl group Chemical group 0.000 claims abstract description 4
- 238000000034 method Methods 0.000 claims description 19
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 6
- 239000000126 substance Substances 0.000 claims description 4
- 125000005843 halogen group Chemical group 0.000 claims description 3
- 229910052757 nitrogen Inorganic materials 0.000 claims description 3
- 125000004433 nitrogen atom Chemical group N* 0.000 claims description 3
- 230000000694 effects Effects 0.000 abstract description 8
- 239000003086 colorant Substances 0.000 abstract description 3
- 238000003306 harvesting Methods 0.000 abstract description 2
- 241000218922 Magnoliophyta Species 0.000 abstract 1
- 229910052736 halogen Inorganic materials 0.000 abstract 1
- 150000002367 halogens Chemical class 0.000 abstract 1
- 238000004383 yellowing Methods 0.000 abstract 1
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 18
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 13
- 239000000203 mixture Substances 0.000 description 9
- 238000009472 formulation Methods 0.000 description 8
- 150000001875 compounds Chemical class 0.000 description 7
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 description 6
- 239000007864 aqueous solution Substances 0.000 description 6
- 239000008103 glucose Substances 0.000 description 6
- 238000002360 preparation method Methods 0.000 description 5
- 235000000346 sugar Nutrition 0.000 description 4
- 150000008163 sugars Chemical class 0.000 description 4
- 240000006497 Dianthus caryophyllus Species 0.000 description 3
- 235000009355 Dianthus caryophyllus Nutrition 0.000 description 3
- 235000004789 Rosa xanthina Nutrition 0.000 description 3
- 241000109329 Rosa xanthina Species 0.000 description 3
- CZMRCDWAGMRECN-UGDNZRGBSA-N Sucrose Chemical compound O[C@H]1[C@H](O)[C@@H](CO)O[C@@]1(CO)O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O1 CZMRCDWAGMRECN-UGDNZRGBSA-N 0.000 description 3
- 229930006000 Sucrose Natural products 0.000 description 3
- WQZGKKKJIJFFOK-VFUOTHLCSA-N beta-D-glucose Chemical compound OC[C@H]1O[C@@H](O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-VFUOTHLCSA-N 0.000 description 3
- 239000000843 powder Substances 0.000 description 3
- 238000002791 soaking Methods 0.000 description 3
- 239000005720 sucrose Substances 0.000 description 3
- BJEPYKJPYRNKOW-REOHCLBHSA-N (S)-malic acid Chemical compound OC(=O)[C@@H](O)CC(O)=O BJEPYKJPYRNKOW-REOHCLBHSA-N 0.000 description 2
- 239000005725 8-Hydroxyquinoline Substances 0.000 description 2
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 2
- KRKNYBCHXYNGOX-UHFFFAOYSA-K Citrate Chemical compound [O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O KRKNYBCHXYNGOX-UHFFFAOYSA-K 0.000 description 2
- NOQGZXFMHARMLW-UHFFFAOYSA-N Daminozide Chemical compound CN(C)NC(=O)CCC(O)=O NOQGZXFMHARMLW-UHFFFAOYSA-N 0.000 description 2
- FEWJPZIEWOKRBE-JCYAYHJZSA-N Dextrotartaric acid Chemical compound OC(=O)[C@H](O)[C@@H](O)C(O)=O FEWJPZIEWOKRBE-JCYAYHJZSA-N 0.000 description 2
- NWBJYWHLCVSVIJ-UHFFFAOYSA-N N-benzyladenine Chemical compound N=1C=NC=2NC=NC=2C=1NCC1=CC=CC=C1 NWBJYWHLCVSVIJ-UHFFFAOYSA-N 0.000 description 2
- ZSILVJLXKHGNPL-UHFFFAOYSA-L S(=S)(=O)([O-])[O-].[Ag+2] Chemical compound S(=S)(=O)([O-])[O-].[Ag+2] ZSILVJLXKHGNPL-UHFFFAOYSA-L 0.000 description 2
- 239000005708 Sodium hypochlorite Substances 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- FEWJPZIEWOKRBE-UHFFFAOYSA-N Tartaric acid Natural products [H+].[H+].[O-]C(=O)C(O)C(O)C([O-])=O FEWJPZIEWOKRBE-UHFFFAOYSA-N 0.000 description 2
- BJEPYKJPYRNKOW-UHFFFAOYSA-N alpha-hydroxysuccinic acid Natural products OC(=O)C(O)CC(O)=O BJEPYKJPYRNKOW-UHFFFAOYSA-N 0.000 description 2
- 239000000969 carrier Substances 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 235000015165 citric acid Nutrition 0.000 description 2
- 239000003337 fertilizer Substances 0.000 description 2
- 230000012010 growth Effects 0.000 description 2
- 239000003966 growth inhibitor Substances 0.000 description 2
- 239000001630 malic acid Substances 0.000 description 2
- 235000011090 malic acid Nutrition 0.000 description 2
- 235000015097 nutrients Nutrition 0.000 description 2
- 150000007524 organic acids Chemical class 0.000 description 2
- 235000005985 organic acids Nutrition 0.000 description 2
- 229960003540 oxyquinoline Drugs 0.000 description 2
- MCJGNVYPOGVAJF-UHFFFAOYSA-N quinolin-8-ol Chemical compound C1=CN=C2C(O)=CC=CC2=C1 MCJGNVYPOGVAJF-UHFFFAOYSA-N 0.000 description 2
- SUKJFIGYRHOWBL-UHFFFAOYSA-N sodium hypochlorite Chemical compound [Na+].Cl[O-] SUKJFIGYRHOWBL-UHFFFAOYSA-N 0.000 description 2
- 235000002906 tartaric acid Nutrition 0.000 description 2
- 239000011975 tartaric acid Substances 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- FHVDTGUDJYJELY-UHFFFAOYSA-N 6-{[2-carboxy-4,5-dihydroxy-6-(phosphanyloxy)oxan-3-yl]oxy}-4,5-dihydroxy-3-phosphanyloxane-2-carboxylic acid Chemical compound O1C(C(O)=O)C(P)C(O)C(O)C1OC1C(C(O)=O)OC(OP)C(O)C1O FHVDTGUDJYJELY-UHFFFAOYSA-N 0.000 description 1
- 241000332371 Abutilon x hybridum Species 0.000 description 1
- 241000132092 Aster Species 0.000 description 1
- 241000972773 Aulopiformes Species 0.000 description 1
- 241000894006 Bacteria Species 0.000 description 1
- 235000007516 Chrysanthemum Nutrition 0.000 description 1
- 240000005250 Chrysanthemum indicum Species 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- 241000511009 Eustoma exaltatum subsp. russellianum Species 0.000 description 1
- 241000735332 Gerbera Species 0.000 description 1
- 241000208818 Helianthus Species 0.000 description 1
- 235000003222 Helianthus annuus Nutrition 0.000 description 1
- 239000005909 Kieselgur Substances 0.000 description 1
- 241000234435 Lilium Species 0.000 description 1
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 239000002671 adjuvant Substances 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 229940072056 alginate Drugs 0.000 description 1
- 235000010443 alginic acid Nutrition 0.000 description 1
- 229920000615 alginic acid Polymers 0.000 description 1
- 150000005215 alkyl ethers Chemical class 0.000 description 1
- 230000000844 anti-bacterial effect Effects 0.000 description 1
- 229910000278 bentonite Inorganic materials 0.000 description 1
- 239000000440 bentonite Substances 0.000 description 1
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 239000000645 desinfectant Substances 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- 238000007865 diluting Methods 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 229940079593 drug Drugs 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 230000003203 everyday effect Effects 0.000 description 1
- 230000009969 flowable effect Effects 0.000 description 1
- 239000003112 inhibitor Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 150000002823 nitrates Chemical class 0.000 description 1
- 235000016709 nutrition Nutrition 0.000 description 1
- 235000021317 phosphate Nutrition 0.000 description 1
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 1
- 230000008635 plant growth Effects 0.000 description 1
- IWZKICVEHNUQTL-UHFFFAOYSA-M potassium hydrogen phthalate Chemical compound [K+].OC(=O)C1=CC=CC=C1C([O-])=O IWZKICVEHNUQTL-UHFFFAOYSA-M 0.000 description 1
- 230000035755 proliferation Effects 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 235000019515 salmon Nutrition 0.000 description 1
- 239000001509 sodium citrate Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
- 230000005068 transpiration Effects 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
Description
【発明の詳細な説明】
〔産業上の利用分野〕
本発明は、切花の鮮度保持剤およびそれを使用する切花
の鮮度保持方法に関し、より詳しくは、花沓等の収穫後
の切花の花弁および茎葉の萎凋を防止し、花色および葉
色を長時間保持させる新しい切花の鮮度保持剤およびこ
れを使用する切花の鮮度保持方法に関する。[Detailed Description of the Invention] [Industrial Application Field] The present invention relates to a freshness-preserving agent for cut flowers and a method for preserving the freshness of cut flowers using the same. The present invention relates to a new cut flower freshness preserving agent that prevents stem and leaf wilting and retains flower and leaf colors for a long period of time, and a method for keeping cut flowers fresh using the same.
従来より行われている収穫後の切花鮮度保持方法には、
大別して次のようなものがある。Traditional methods of preserving cut flower freshness after harvest include:
They can be broadly classified as follows.
■ 切花の切り口を浸漬する水の腐敗や、切り口からの
細菌の繁殖を抑制して切花の腐敗を防止し、かつ導管閉
鎖を少なくし、良好な水揚げを確保する方法。■ A method that prevents cut flowers from rotting by suppressing the spoilage of the water that soaks them and the proliferation of bacteria from the cut ends, and also reduces the number of duct closures and ensures good landings.
■ 積極的に栄養分を補給する方法。■ How to actively replenish nutrients.
■ 生長抑制剤を用いて、老化および消耗を遅らせる方
法。■ Methods of slowing aging and wasting using growth inhibitors.
■ 葉の気孔開閉を抑制して、水分の蒸散を少なくする
方法。■ A method to reduce water transpiration by suppressing the opening and closing of leaf stomata.
上記■の方法において、腐敗防止のためには、次亜塩素
酸ソーダ、８−ヒドロキシキノリンのクエン酸塩等の殺
菌剤や、チオ硫酸銀などのエチレン生成抑制剤が用いら
れている。In the method (2) above, to prevent spoilage, disinfectants such as sodium hypochlorite and citrate of 8-hydroxyquinoline, and ethylene production inhibitors such as silver thiosulfate are used.
■の方法における栄養剤としては、糖類（ブドウ糖、蔗
糖など）、肥料分などが用いられている。As nutrients in method (2), sugars (glucose, sucrose, etc.), fertilizers, etc. are used.
また、■の方法における生長抑制剤としては、ベンジル
アデニン、Ｂ−ナインなどが用いられ、また、■の方法
における気孔開閉剤としては、８−ヒドロキシキノリン
のクエン酸塩や糖類などが使用されている。In addition, benzyladenine, B-nine, etc. are used as growth inhibitors in method (2), and citrate of 8-hydroxyquinoline, sugars, etc. are used as stomatal opening and closing agents in method (2). There is.
しかしながら、上記公知の方法は、あらゆる種類の切花
に対して、安全にして充分な鮮度保持効果を示すもので
なかったり、使用方法が複雑で、かつ、使用場面が限定
されるものであったり、或いは毒性面から取扱に充分注
意を要する薬剤を使用するものであったりするなどの問
題点を有していた。したがって、従来から、これ等公知
の方法に比して、より優れた鮮度保持効果を常に安定し
て示す新しい薬剤とその利用による切花の鮮度保持技術
の開発が要望されていた。However, the above-mentioned known methods do not have a safe and sufficient freshness-preserving effect on all kinds of cut flowers, are complicated to use, and have limited use situations. Another problem is that it involves the use of drugs that require careful handling due to toxicity. Therefore, there has been a demand for the development of a new chemical that consistently and stably exhibits a superior freshness-preserving effect compared to these known methods, and a technique for preserving the freshness of cut flowers using the same.
本発明の目的は、従来の方法における欠点をことごとく
解決し、各種の切花をより長期にわたり、安定して新鮮
な状態に保ち、茎葉やっほみ、花等を順調に生育、開花
させる新しい切花鮮度保持剤および切花の鮮度保持方法
を提供することにある。The purpose of the present invention is to solve all the shortcomings of conventional methods, keep various cut flowers in a stable and fresh state for a longer period of time, and create a new cut flower freshness method that allows stems, leaves, flowers, etc. to grow and bloom smoothly. An object of the present invention is to provide a preserving agent and a method for preserving the freshness of cut flowers.
本発明者等は、安価で安全、かつ簡便な方法で、切花の
鮮度保持をはかることについて、鋭意研究を行なった結
果、以下に示す式（Ａ）で示されるアゾール置換シクロ
ペンタノール誘導体を含有する水に、切花の切り口を一
定時間浸漬すると、切花の保存期間を延長できることを
見いだし、更にこれらアゾール置換シクロペンタノール
誘導体が、各種切花における葉の萎凋、貧化を防止、並
びに花弁の萎凋を防止し、優れた鮮度保持効果を生じる
ことを見いだし、本発明を完成するに至った。The present inventors have conducted extensive research into maintaining the freshness of cut flowers using an inexpensive, safe, and simple method. It was discovered that the storage period of cut flowers could be extended by soaking the cut ends of the cut flowers in water for a certain period of time.Furthermore, these azole-substituted cyclopentanol derivatives prevented the withering and deterioration of the leaves of various cut flowers, as well as the withering of the petals. The present inventors have discovered that the present invention can be prevented and produce an excellent freshness-keeping effect, leading to the completion of the present invention.
即ち、本発明の切花の鮮度保持剤は、下記式（１）で示
されるアゾール置換シクロペンタノール誘導体を有効成
分として含有することを特徴とする。That is, the cut flower freshness-preserving agent of the present invention is characterized by containing an azole-substituted cyclopentanol derivative represented by the following formula (1) as an active ingredient.
また、本発明の切花の鮮度保持方法は、下記（１）で示
されるアゾール置換シクロペンタノール誘導体を有効成
分として使用することを特徴とする。Furthermore, the method for preserving the freshness of cut flowers of the present invention is characterized by using an azole-substituted cyclopentanol derivative shown in (1) below as an active ingredient.
以下余白
（式中、Ａは窒素原子またはＣＨ基を表し、Ｒ１および
Ｒ２は、それぞれ独立に水素原子または０１〜Ｃ，アル
キル基を表し、Ｘは水素原子またはハロゲン原子を表す
。）
以下、本発明について詳細に説明する。The following margins (In the formula, A represents a nitrogen atom or a CH group, R1 and R2 each independently represent a hydrogen atom or an alkyl group, and X represents a hydrogen atom or a halogen atom.) The invention will be explained in detail.
本発明において有効成分として用いる上記式（Ｉ）で示
されるアゾール置換シクロペンタノール誘導体は、特開
昭８２−１４９８６７号公報或いは特開平Ｌ−９３５７
４号公報に記載された物質である。なお、これ等の公報
には、本発明における上記のアゾール置換シクロペンタ
ノール誘導体が、殺菌作用および植物生長調節作用を有
し、農園芸用薬剤として使用されることが記載されてい
るが、それ等が切花保存に有効であることは、同等開示
されていない。したがって、本発明における上記のアゾ
−ル置換シクロペンタノール誘導体が、切花の鮭用保持
効果を示すことは、驚くべきことである。The azole-substituted cyclopentanol derivative represented by the above formula (I) used as an active ingredient in the present invention is disclosed in JP-A-82-149867 or JP-A-L-9357.
This is a substance described in Publication No. 4. Incidentally, these publications state that the azole-substituted cyclopentanol derivative of the present invention has bactericidal activity and plant growth regulating activity, and is used as an agricultural and horticultural agent. It is not disclosed that these methods are effective for preserving cut flowers. Therefore, it is surprising that the azole-substituted cyclopentanol derivative of the present invention exhibits the effect of retaining cut flowers for salmon.
本発明において使用する上記式（１）で示さするアゾー
ル置換シクロペンタノール誘導体の具４４例を表１に示
す。Table 1 shows 44 examples of the azole-substituted cyclopentanol derivative represented by the above formula (1) used in the present invention.
なお、表１の立体異性体の表示において、Ａと８は、そ
れぞれ下記の立体構造を有することを庁（式中、Ａ、Ｒ
’ 、Ｒ２およびＸは、上記したと同意義を有する。）
し
表
表
１ （続き）
表
■ （続き）
■）
化合物番号（５０）〜（５２）は各々Ｒ１とＲ２の真性
体の混合物である。In addition, in the display of stereoisomers in Table 1, A and 8 are each shown to have the following steric structure (in the formula, A, R
', R2 and X have the same meanings as described above. ) Table 1 (Continued) Table ■ (Continued) ■) Compound numbers (50) to (52) are mixtures of the intrinsic forms of R1 and R2, respectively.
本発明において、上記式（Ｉ）で示されるアゾール置換
シクロペンタノール誘導体は、水溶液の形態で切花に適
用することができる。その使用時における水中濃度は、
浸漬時間、浸漬時の環境、切花の種類、数量、製剤の種
類等によっても異るが、通常１〜ＬＯＯＯｐｐｍ 、好
ましくは５〜ｌｏＯｐｐｍｃ７）範囲で使用する。その
際、ブドウ糖や蔗糖などの糖類０，２〜１．５％や、ク
エン酸、酒石酸、リンゴ酸などの有機酸類０．００５〜
１．５％と併用すれば、特に効果的である。In the present invention, the azole-substituted cyclopentanol derivative represented by the above formula (I) can be applied to cut flowers in the form of an aqueous solution. The concentration in water at the time of use is
Although it varies depending on the soaking time, the environment during soaking, the type and quantity of cut flowers, the type of preparation, etc., it is usually used in the range of 1 to LOOOppm, preferably 5 to LOOOppmc7). At that time, 0.2 to 1.5% of sugars such as glucose and sucrose, and 0.005 to 1.5% of organic acids such as citric acid, tartaric acid, and malic acid.
Particularly effective when used in combination with 1.5%.
本発明における上記式（Ｉ）で示されるアゾール置換シ
クロペンタノール誘導体は、使用に適した濃度の含有水
を調製して使用すればよく、最初から、使用に適した濃
度の含有水を調製して使用しても、また、式（Ｉ）で示
されるアゾール置換シクロペンタノール誘導体を高濃度
に含有する製剤を、使用時に水で希釈して調製し、使用
することもできる。The azole-substituted cyclopentanol derivative represented by the above formula (I) in the present invention can be used by preparing water containing water at a concentration suitable for use. Alternatively, a preparation containing a high concentration of the azole-substituted cyclopentanol derivative represented by formula (I) can be prepared and used by diluting it with water before use.
式（１）で示されるアゾール置換シクロペンタノール誘
導体を高濃度に含有する製剤の形態としては、濃厚水溶
液、粉剤、水和剤、乳剤、フロアブル剤等をあげること
ができる。Forms of preparations containing a high concentration of the azole-substituted cyclopentanol derivative represented by formula (1) include concentrated aqueous solutions, powders, wettable powders, emulsions, flowable preparations, and the like.
製剤化に際しては、例えば、クレー、ベントナイト、珪
藻土などの固体担体、アセトン、キシレン、アルコール
などの液体担体、アルキル硫酸エステル塩、ポリオキシ
エチレンアルキルエーテルなどの界面活性剤、アルギン
酸塩、ＣＭＣなどの製剤補助剤を使用することができる
。For formulation, for example, solid carriers such as clay, bentonite, diatomaceous earth, liquid carriers such as acetone, xylene, alcohol, surfactants such as alkyl sulfate salts, polyoxyethylene alkyl ethers, formulations such as alginate, CMC, etc. Adjuvants can be used.
本発明において、式ＣＩ）で示されるアゾール置換シク
ロペンタノール誘導体を水溶液として使用する場合、更
に切花保存に適用される一般的な成分を、必要に応じて
併用することができる。In the present invention, when the azole-substituted cyclopentanol derivative represented by formula CI) is used as an aqueous solution, general components used for preserving cut flowers may be used in combination, if necessary.
例えば、（１）切花の切り口を浸漬している水の腐敗、
および切花の切り口や浸漬状態の茎の腐敗を防止するた
めに、次亜塩素酸ソーダ、チオ硫酸銀などの併用、（２
）切花の栄養源として、糖類（ブドウ糖、蔗糖など）、
肥料分（リン酸塩、硝酸塩など）などの併用、（３）切
り口を浸漬する水のｐＨを酸性にするために、有機酸類
（クエン酸、リンゴ酸、酒石酸など）、フタル酸水素カ
リウム、硫酸水素カリウムなど、の併用、（４）切花の
生長抑制のために、ベンジルアデニン、Ｂ−ナインなど
の併用、をあげることができる。For example, (1) rotting of the water in which cut ends of cut flowers are immersed;
In order to prevent rot of cut ends of cut flowers and soaked stems, use of sodium hypochlorite, silver thiosulfate, etc.
) As a nutritional source for cut flowers, sugars (glucose, sucrose, etc.),
Concomitant use of fertilizers (phosphates, nitrates, etc.); (3) organic acids (citric acid, malic acid, tartaric acid, etc.), potassium hydrogen phthalate, sulfuric acid to make the pH of the water in which the cuts are immersed acidic; (4) To suppress the growth of cut flowers, use of benzyladenine, B-nine, etc. can be used in combination.
また、本発明の切花鮮度保持剤は、各種の切花に対して
有効であるが、特に効果の得られる花の種類としては、
ガーベラ、バラ、カーネーション、キク、ユリ、トルコ
ギキョウ、キキョウ、ヒマワリ、アスターなどがあげら
れる。Furthermore, the cut flower freshness preserving agent of the present invention is effective for various types of cut flowers, but the types of flowers that are particularly effective are:
Examples include gerberas, roses, carnations, chrysanthemums, lilies, lisianthus, bellflowers, sunflowers, and asters.
また、これ等の花の品種についても、例えば、バラにつ
いては、極小軸系、小輪系、中軸系、大輪系など、また
、カーネーションについては、スタンダード系、スプレ
ー系、ニーロー系など、各種のものに広く有効である。In addition, regarding the varieties of these flowers, for example, for roses, there are various types such as micro-shaft type, small-flowered type, medium-flowered type, large-flowered type, etc., and for carnations, there are various types such as standard type, spray type, and knee-low type. It is widely effective for many things.
したがって、本発明の切花鮮度保持剤の使用は、特定の
種類の花、品種のみに限定されるものではない。Therefore, the use of the cut flower freshness preserving agent of the present invention is not limited to specific types of flowers or varieties.
また、その使用の時期は、切花の出荷段階から、消費者
が切花を飾るときまで、高範囲の時期に使用可能である
。In addition, it can be used in a wide range of periods, from the time the cut flowers are shipped to when the cut flowers are displayed by the consumer.
以下に、製剤例と試験例によって、本発明を具体的に説
明するが、本発明の要旨を越えない限り、これ等の実施
例に限定されるものではない。The present invention will be specifically explained below using formulation examples and test examples, but the present invention is not limited to these examples unless the gist of the present invention is exceeded.
なお、製剤例中、「部」は「重量部」を意味する。In addition, in the formulation examples, "part" means "part by weight".
製剤例１
例示化合物（化合物番号４４） ０．００８部、ブドウ
糖１部、クエン酸０．１部、水９８．８９４部を混合し
て、水溶液にする。Formulation Example 1 0.008 parts of the exemplary compound (compound number 44), 1 part of glucose, 0.1 part of citric acid, and 98.894 parts of water are mixed to form an aqueous solution.
製剤例２
例示化合物（化合物番号４４） ０．６部、ブドウ糖４
９．７部、クエン酸４９．７部を混合して粉状の製剤に
し、これを水で所望の濃度に希釈して使用する。Formulation example 2 Exemplary compound (compound number 44) 0.6 parts, glucose 4
9.7 parts of citric acid and 49.7 parts of citric acid are mixed to form a powder preparation, which is used after being diluted with water to a desired concentration.
製剤例３
例示化合物（化合物番号４６） ０．００６部、ブドウ
糖１部、クエン酸０．１部、水９８．８９４部を混合し
て、水溶液にする。Formulation Example 3 0.006 parts of the exemplary compound (compound number 46), 1 part of glucose, 0.1 part of citric acid, and 98.894 parts of water are mixed to form an aqueous solution.
試験例１（後処理）
製剤例１および３の水溶液５００−を入れた三角フラス
コに、同じ生育段階にあり、新鮮な切花（バラ、カーネ
ーション）を５本浸漬し、１８〜２６℃の室内に置き、
毎日、減水した分の水の補給を行ない、各切花の花弁お
よび葉の萎凋などを観察、鑑賞価値を失う日数を数え、
切花の保存日数を求めた。それ等の結果を表２に示す。Test Example 1 (Post-treatment) Five fresh cut flowers (roses, carnations) at the same growth stage were immersed in an Erlenmeyer flask containing 500ml of the aqueous solutions of Formulation Examples 1 and 3, and placed in a room at 18 to 26°C. put,
Every day, we replenish the amount of water that has been lost, observe the wilting of the petals and leaves of each cut flower, and count the number of days that the flowers lose their ornamental value.
The number of days the cut flowers could be stored was determined. The results are shown in Table 2.
表２
〔発明の効果〕
本発明おける上記式（１）
で示されるアゾール
置換シクロペンタノール誘導体は、切花１度保持作用を
有する新規な有効成分であり、各種切花における葉の萎
凋、資化を防止、並びに花弁の萎凋を防止し、軒度保持
効果が優れている。したがって、本発明によれば、各種
の切花をより長期にわたり、安定して新鮮な状態に保ち
、茎葉やっほみ、花等を順調に生育、開花させることが
できる。Table 2 [Effects of the Invention] The azole-substituted cyclopentanol derivative represented by the above formula (1) in the present invention is a new active ingredient that has the effect of preserving cut flowers once, and is effective against leaf withering and assimilation in various cut flowers. It also prevents the wilting of petals and has an excellent effect on maintaining eaves strength. Therefore, according to the present invention, various cut flowers can be stably kept in a fresh state for a longer period of time, and the stems, leaves, flowers, etc. can be smoothly grown and bloomed.
Claims (2)
ンタノール誘導体を有効成分として含有することを特徴
とする切花の鮮度保持剤。 ▲数式、化学式、表等があります▼（ I ） （式中、Ａは窒素原子またはＣＨ基を表し、Ｒ＾１およ
びＲ＾２は、それぞれ独立に水素原子またはＣ＿１〜Ｃ
＿３アルキル基を表し、Ｘは水素原子またはハロゲン原
子を表す。）(1) A cut flower freshness-preserving agent characterized by containing an azole-substituted cyclopentanol derivative represented by the following formula (I) as an active ingredient. ▲There are mathematical formulas, chemical formulas, tables, etc.▼(I) (In the formula, A represents a nitrogen atom or a CH group, and R^1 and R^2 each independently represent a hydrogen atom or C_1~C
_3 represents an alkyl group, and X represents a hydrogen atom or a halogen atom. )
ンタノール誘導体を有効成分として使用することを特徴
とする切花の鮮度保持方法。 ▲数式、化学式、表等があります▼（ I ） （式中、Ａは窒素原子またはＣＨ基を表し、Ｒ＾１およ
びＲ＾２は、それぞれ独立に水素原子またはＣ＿１〜Ｃ
＿３アルキル基を表し、Ｘは水素原子またはハロゲン原
子を表す。）(2) A method for preserving the freshness of cut flowers, which comprises using an azole-substituted cyclopentanol derivative represented by the following formula (I) as an active ingredient. ▲There are mathematical formulas, chemical formulas, tables, etc.▼(I) (In the formula, A represents a nitrogen atom or a CH group, and R^1 and R^2 each independently represent a hydrogen atom or C_1~C
_3 represents an alkyl group, and X represents a hydrogen atom or a halogen atom. )
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP23563490A JP2999527B2 (en) | 1990-09-07 | 1990-09-07 | Freshener and method for maintaining freshness of cut flowers |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP23563490A JP2999527B2 (en) | 1990-09-07 | 1990-09-07 | Freshener and method for maintaining freshness of cut flowers |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH04117301A true JPH04117301A (en) | 1992-04-17 |
| JP2999527B2 JP2999527B2 (en) | 2000-01-17 |
Family
ID=16988929
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP23563490A Expired - Fee Related JP2999527B2 (en) | 1990-09-07 | 1990-09-07 | Freshener and method for maintaining freshness of cut flowers |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP2999527B2 (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO1994024856A1 (en) * | 1993-05-01 | 1994-11-10 | British Technology Group Limited | Composition for treatment of plant material |
| WO1996032012A1 (en) * | 1995-04-12 | 1996-10-17 | Kureha Kagaku Kogyo K.K. | Effervescent granular preparation for keeping cut flower freshness |
| CN104472477A (en) * | 2014-12-18 | 2015-04-01 | 李金枝 | Fresh-keeping agent for cut gerbera flowers |
-
1990
- 1990-09-07 JP JP23563490A patent/JP2999527B2/en not_active Expired - Fee Related
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO1994024856A1 (en) * | 1993-05-01 | 1994-11-10 | British Technology Group Limited | Composition for treatment of plant material |
| US5710101A (en) * | 1993-05-01 | 1998-01-20 | British Technology Group Ltd. | Composition for treatment of plant material comprising an aminopurine and a sulfonated polyester or sulfonamide |
| WO1996032012A1 (en) * | 1995-04-12 | 1996-10-17 | Kureha Kagaku Kogyo K.K. | Effervescent granular preparation for keeping cut flower freshness |
| US6083535A (en) * | 1995-04-12 | 2000-07-04 | Kureha Kagaku Kogyo K.K. | Effervescent granular preparation for keeping cut flower freshness |
| CN104472477A (en) * | 2014-12-18 | 2015-04-01 | 李金枝 | Fresh-keeping agent for cut gerbera flowers |
Also Published As
| Publication number | Publication date |
|---|---|
| JP2999527B2 (en) | 2000-01-17 |
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