JPH0378744B2 - - Google Patents

Info

Publication number
JPH0378744B2
JPH0378744B2 JP58010199A JP1019983A JPH0378744B2 JP H0378744 B2 JPH0378744 B2 JP H0378744B2 JP 58010199 A JP58010199 A JP 58010199A JP 1019983 A JP1019983 A JP 1019983A JP H0378744 B2 JPH0378744 B2 JP H0378744B2
Authority
JP
Japan
Prior art keywords
shrinkable film
metal
dry
deposited
film
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
JP58010199A
Other languages
Japanese (ja)
Other versions
JPS59138052A (en
Inventor
Takashi Yamada
Masahiko Ono
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Toppan Inc
Original Assignee
Toppan Printing Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Toppan Printing Co Ltd filed Critical Toppan Printing Co Ltd
Priority to JP58010199A priority Critical patent/JPS59138052A/en
Publication of JPS59138052A publication Critical patent/JPS59138052A/en
Publication of JPH0378744B2 publication Critical patent/JPH0378744B2/ja
Granted legal-status Critical Current

Links

Classifications

    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M50/00Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
    • H01M50/10Primary casings, jackets or wrappings of a single cell or a single battery
    • H01M50/116Primary casings, jackets or wrappings of a single cell or a single battery characterised by the material
    • H01M50/121Organic material
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M50/00Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
    • H01M50/10Primary casings, jackets or wrappings of a single cell or a single battery
    • H01M50/116Primary casings, jackets or wrappings of a single cell or a single battery characterised by the material
    • H01M50/117Inorganic material
    • H01M50/119Metals
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M50/00Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
    • H01M50/10Primary casings, jackets or wrappings of a single cell or a single battery
    • H01M50/116Primary casings, jackets or wrappings of a single cell or a single battery characterised by the material
    • H01M50/124Primary casings, jackets or wrappings of a single cell or a single battery characterised by the material having a layered structure
    • H01M50/126Primary casings, jackets or wrappings of a single cell or a single battery characterised by the material having a layered structure comprising three or more layers
    • H01M50/129Primary casings, jackets or wrappings of a single cell or a single battery characterised by the material having a layered structure comprising three or more layers with two or more layers of only organic material
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10Energy storage using batteries

Description

【発明の詳細な説明】 本発明は乾電池の外装に用いられる収縮性ラベ
ルの製造方法に関する。
DETAILED DESCRIPTION OF THE INVENTION The present invention relates to a method for manufacturing a shrinkable label used for the exterior of a dry battery.

従来、アルカリマンガン乾電池は、メタルジヤ
ケツトの外装によりその胴部を覆われている。こ
のメタルジヤケツトは金属箔を含む積層材料であ
るが、このため、金属印刷、金属箔のカツト、カ
ーリング、カツプリング、及び乾電池の端部でか
しめるという作業を要する。
Conventionally, the body of an alkaline manganese dry battery is covered with an exterior metal jacket. This metal jacket is a laminated material containing metal foil, and therefore requires operations such as metal printing, cutting of the metal foil, curling, coupling, and caulking with the edge of a dry battery.

また、乾電池の外周は日本工業規格で統一化さ
れていて、その外径は一定である。しかし、一方
では、その電池の容量は内容薬剤量と比例するも
のであり、内容量をより多くすることで電池性能
を向上できるのである。
Furthermore, the outer circumference of a dry cell battery is standardized according to Japanese Industrial Standards, and its outer diameter is constant. However, on the other hand, the capacity of the battery is proportional to the amount of drug content, and battery performance can be improved by increasing the content.

本発明者等は、これらの事情に鑑みて種々検討
をした結果、金属蒸着した収縮性フイルムに粘着
剤を塗布して収縮性ラベルを作成し、これを上記
のメタルジヤケツトの代わりに用いれば、金属印
刷等の工程が不要なこと、メタルジヤケツトより
も薄いので、電池の内容量を多くすることができ
ることに想到した。
As a result of various studies in view of these circumstances, the present inventors created a shrinkable label by applying an adhesive to a metal-deposited shrinkable film, and used this in place of the metal jacket described above. The inventors came up with the idea that processes such as metal printing are unnecessary, and since it is thinner than a metal jacket, the internal capacity of the battery can be increased.

しかるに、金属蒸着した収縮性フイルムにいわ
ゆる感圧粘着剤を塗布すると、感圧粘着剤中に含
まれる溶剤あるいは溶剤乾燥時の熱によつて収縮
性フイルムが収縮してしまい、得られるラベルは
収縮性が全くないか、あつても当初の収縮性ラベ
ルよりずつと収縮性の悪いものであつた。
However, when a so-called pressure-sensitive adhesive is applied to a metal-deposited shrinkable film, the shrinkable film shrinks due to the solvent contained in the pressure-sensitive adhesive or the heat generated when the solvent dries, and the resulting label does not shrink. They either had no elasticity, or if they did, they were far less elastic than the original shrinkable labels.

本願発明は以上のような事情に基づいてなされ
たもので、感圧粘着剤中に含まれる溶剤あるいは
溶剤乾燥時の熱によつて収縮せず、ラベル製造後
の長期保存においてもその寸法が安定で、しかも
70℃以上の温度で速やかに収縮して乾電池胴部に
密着する乾電池用外装ラベルの製造方法を提供す
ることを目的として、検討を重ねた結果完成され
たもので、すなわち本発明は、離型紙上に感圧粘
着剤を塗布し、充分に溶剤を乾燥した後、この感
圧粘着剤層に非収縮性(非シユリンク性)フイル
ムを貼り合わせると共に、この非収縮性フイルム
に接着剤を介して乾電池の円周方向に収縮する金
属蒸着した収縮性(シユリンク性)フイルムを貼
り合わせ、離型紙をカツトすることなく、収縮性
フイルム及び非収縮性フイルムを使用する大きさ
にカツトすることにより乾電池用外装ラベルを製
造することを特徴とする乾電池用外装ラベルの製
造方法である。
The present invention has been made based on the above-mentioned circumstances, and it does not shrink due to the solvent contained in the pressure-sensitive adhesive or the heat during drying of the solvent, and its dimensions are stable even during long-term storage after label production. And, moreover
The present invention was completed as a result of repeated studies with the aim of providing a method for manufacturing an exterior label for a dry cell battery that quickly shrinks at a temperature of 70°C or higher and adheres tightly to the body of a dry cell battery. After applying a pressure-sensitive adhesive on top and thoroughly drying the solvent, a non-shrinkable (non-shrinkable) film is attached to this pressure-sensitive adhesive layer, and the non-shrinkable film is coated with an adhesive. By laminating metal-deposited shrinkable (shrinkable) film that shrinks in the circumferential direction of the dry battery, and cutting the shrinkable film and non-shrinkable film to the size to be used without cutting the release paper, it is possible to make a dry cell battery. This is a method for manufacturing an exterior label for a dry battery, characterized by manufacturing an exterior label.

以下、図面の第1図〜第4図を用いて本発明を
説明する。図面の第1図及び第2図は、離型紙か
ら剥離する前の本発明のラベルの断面図、第3図
a〜bは本発明のラベルを乾電池に適用する方法
を説明する断面図(但し第3図a〜bにおいて乾
電池内部の構造は省略してある)、第4図は第3
図の結果得られたラベル付乾電池の斜視図であ
る。
Hereinafter, the present invention will be explained using FIGS. 1 to 4 of the drawings. 1 and 2 of the drawings are cross-sectional views of the label of the present invention before being peeled off from the release paper, and Figures 3 a to b are cross-sectional views illustrating a method of applying the label of the present invention to a dry battery (however, (The internal structure of the dry cell battery is omitted in Figures 3a-b), and Figure 4 shows the
It is a perspective view of the labeled dry battery obtained as a result of the figure.

図面の第1図において、1は収縮性フイルムを
示している。この材質は任意のもので良いが、例
えば一軸延伸した収縮塩ビフイルムが使用でき
る。後述するように乾電池に適用する際の便か
ら、一軸延伸した収縮性フイルム、特に縦方向
(フイルムを押出し成形する際の押出し方向)に
延伸したシユリンクフイルムが好ましい。
In FIG. 1 of the drawings, 1 indicates a shrinkable film. Any material may be used for this material, and for example, uniaxially stretched shrink PVC film can be used. As will be described later, for ease of application to dry batteries, a uniaxially stretched shrinkable film, particularly a shrinkable film stretched in the longitudinal direction (the direction of extrusion when the film is extruded) is preferred.

また、2はこのシユリンクフイルム1に蒸着さ
れた金属蒸着層を示している。この蒸着金属は
鉄、銅、ニツケル等任意の金属を用いることがで
きるが、アルミニウムが安価であり、また簡便で
ある。
Further, 2 indicates a metal vapor deposited layer deposited on this shrink film 1. Any metal such as iron, copper, or nickel can be used as the vapor-deposited metal, but aluminum is inexpensive and convenient.

また11は非収縮性フイルムを示しており、例
えば塩ビフイルムである。
Further, numeral 11 indicates a non-shrinkable film, such as a vinyl chloride film.

一方、シリコン加工等の離型加工を施した離型
紙4の離型加工面に感圧粘着剤3を塗布し、十分
に乾燥して溶剤を除去し、対いでこの感圧粘着剤
3面に前記非収縮性フイルム11を貼り合わせ
る。なお、金属蒸着した収縮性フイルム1と非収
縮性フイルム11は、非収縮性フイルム11と感
圧粘着剤層3との貼りあわせの前に貼り合わされ
ていても良いし、その後に貼り合わせても良い。
いずれにしても、収縮性フイルム1と非収縮性フ
イルム11の貼り合わせに用いられる接着剤7
は、粘着剤3と異なつて、ラベルとなつた際に粘
着性を有する必要はないから、ドライラミネート
に用いられる通常の接着剤を用いることができ
る。
On the other hand, the pressure-sensitive adhesive 3 is applied to the release surface of the release paper 4 that has been subjected to release processing such as silicone processing, and the solvent is removed by sufficiently drying. The non-shrinkable film 11 is pasted together. Note that the metal-deposited shrinkable film 1 and the non-shrinkable film 11 may be pasted together before the non-shrinkable film 11 and the pressure-sensitive adhesive layer 3 are pasted together, or they may be pasted together after that. good.
In any case, the adhesive 7 used to bond the shrinkable film 1 and the non-shrinkable film 11
Unlike the adhesive 3, the adhesive does not need to have adhesive properties when formed into a label, so a normal adhesive used for dry lamination can be used.

また、印刷インキ5は、蒸着前の収縮性フイル
ム1に施した後、金属蒸着しても良いし、金属蒸
着した収縮性フイルム1を非収縮性フイルム11
に貼り合わせた後、この収縮性フイルム1に印刷
インキを施しても良い。
Further, the printing ink 5 may be applied to the shrinkable film 1 before vapor deposition, and then metal vapor-deposited, or the metal-deposited shrinkable film 1 may be transferred to the non-shrinkable film 11.
After bonding, printing ink may be applied to this shrinkable film 1.

蒸着するに先立つて、例えば、黄色の染料を混
合した蒸着アンダーニス6を塗布し、この後金属
蒸着層2を形成したもので、他の点は第1図と同
様である。
Prior to vapor deposition, a vapor deposition undervarnish 6 containing, for example, a yellow dye was applied, and then a metal vapor deposition layer 2 was formed.Other points are the same as in FIG. 1.

第1図〜第2図において、感圧粘着剤3として
は、例えば、アクリル酸エステル、アクリル酸共
重合物、天然ゴム等の主剤に、エステルガム、ロ
ジン、クマロン等の粘着付与剤やポリブテン、ジ
オクチルフタレート、ヒマシ油等の可塑剤等を配
合したものが使用できる。
In FIGS. 1 and 2, the pressure-sensitive adhesive 3 includes, for example, a main ingredient such as acrylic ester, acrylic acid copolymer, natural rubber, etc., a tackifier such as ester gum, rosin, or coumaron, and polybutene, etc. Those containing plasticizers such as dioctyl phthalate and castor oil can be used.

こうして、離型紙4上に、感圧粘着剤3、非収
縮性フイルム11、金属蒸着した収縮性フイルム
1を積層した後、離型紙4をカツトすることな
く、非収縮性フイルム11及び金属蒸着した収縮
性フイルム1を使用する大きさにカツトすること
によりラベル9を製造する。
In this way, the pressure sensitive adhesive 3, the non-shrinkable film 11, and the metal-deposited shrinkable film 1 were laminated on the release paper 4, and then the non-shrinkable film 11 and the metal-deposited film were laminated without cutting the release paper 4. A label 9 is manufactured by cutting the shrinkable film 1 into a size to be used.

こうして得られたラベル9は、第3図aに示す
ように、離型紙4から剥離して、乾電池10胴部
の外周に接着する。この時、収縮性フイルム1の
延伸した方向(収縮する方向)が乾電池10の円
周方向になるようにすることが好ましい。この後
加熱してラベルを収縮させる。すると、第3図b
に示すように、乾電池10胴部の両端ではその収
縮が激しく、従来のメタルジヤケツトをかしめた
時と同様の状態になる。この時の斜視図が第4図
に示すものである。
The label 9 thus obtained is peeled off from the release paper 4 and adhered to the outer periphery of the body of the dry battery 10, as shown in FIG. 3a. At this time, it is preferable that the direction in which the shrinkable film 1 is stretched (the direction in which it shrinks) is the circumferential direction of the dry battery 10. This is followed by heating to shrink the label. Then, Figure 3b
As shown in FIG. 2, the shrinkage is severe at both ends of the body of the dry battery 10, resulting in a state similar to when a conventional metal jacket is crimped. A perspective view at this time is shown in FIG.

本発明は以上述べた通りで、このため、以下、
(イ)〜(ホ)の効果を有する。
The present invention is as described above, and therefore, the following:
It has the effects of (a) to (e).

(イ) 収縮性フイルムの収縮性を損なうことなく感
圧粘着剤層を設けることができる。
(a) A pressure-sensitive adhesive layer can be provided without impairing the shrinkability of the shrinkable film.

(ロ) 電池の円周方向に収縮するラベルを用いるの
で、端部が電池の端部に沿つてかしめられる。
(b) Since a label that shrinks in the circumferential direction of the battery is used, the edges are crimped along the edges of the battery.

(ハ) 従来のメタルジヤケツトに比べて安価であ
り、その取り扱いもはるかに容易である。
(c) It is cheaper than conventional metal jackets and is much easier to handle.

(ニ) 従来のメタルジヤケツトに比べて薄いので、
それだけ電池の内容量を大きくすることがで
き、容量を大きくすることができる。
(d) It is thinner than conventional metal jackets, so
The internal capacity of the battery can be increased accordingly, and the capacity can be increased accordingly.

(ホ) 60℃程度の温度の長期保存で寸法安定性が良
く、しかも100℃以上の温度で速やかに収縮す
る。
(e) It has good dimensional stability when stored for long periods at a temperature of about 60℃, and also shrinks quickly at a temperature of 100℃ or higher.

【図面の簡単な説明】[Brief explanation of drawings]

図面の第1図及び第2図は離型紙から剥離する
前の本発明のラベルの断面図、第3図a,bは本
発明のラベルを乾電池に適用する方法を説明する
ための説明断面図(但し電池内部の構造は図示を
省略してある)、第4図はラベル付乾電池の斜視
図である。 1……収縮性フイルム、2……金属蒸着層、3
……感圧粘着剤、4……離型紙、5……印刷イン
キ、6……蒸着アンダーニス、7……接着剤、9
……ラベル、10……乾電池、11……非収縮性
フイルム。
Figures 1 and 2 of the drawings are cross-sectional views of the label of the present invention before being peeled off from the release paper, and Figures 3 a and b are explanatory cross-sectional views for explaining the method of applying the label of the present invention to dry batteries. (However, the internal structure of the battery is not shown.) FIG. 4 is a perspective view of the labeled dry battery. 1...Shrinkable film, 2...Metal deposited layer, 3
...Pressure sensitive adhesive, 4 ... Release paper, 5 ... Printing ink, 6 ... Vapor-deposited undervarnish, 7 ... Adhesive, 9
... Label, 10 ... Dry battery, 11 ... Non-shrinkable film.

Claims (1)

【特許請求の範囲】 1 離型紙上に感圧粘着剤を塗布し、十分に溶剤
を乾燥した後、この感圧粘着剤層に、非収縮性フ
イルムを貼り合わせると共に、この非収縮性フイ
ルムに接着剤を介して乾電池の円周方向に収縮す
る金属蒸着した収縮性フイルムを貼り合せ、離型
紙をカツトすることなく、収縮性フイルム及び非
収縮性フイルムを使用する大きさにカツトするこ
とにより乾電池用外装ラベルを形成することを特
徴とする乾電池用外装ラベルの製造方法。 2 金属蒸着した収縮性フイルムが、収縮性フイ
ルムに印刷インキを施した後、金属蒸着して成る
フイルムであることを特徴とする前記第1項記載
の乾電池用外装ラベルの製造方法。 3 金属蒸着した収縮性フイルムを非収縮性フイ
ルムに貼り合わせた後、この収縮性フイルムに印
刷インキを施すことを特徴とする前記第1項又は
第2項記載の乾電池用外装ラベルの製造方法。 4 収縮性フイルムが一軸延伸した収縮性フイル
ムであることを特徴とする前記第1項〜第3項の
いずれかに記載の乾電池用外装ラベルの製造方
法。
[Claims] 1. After applying a pressure-sensitive adhesive onto a release paper and thoroughly drying the solvent, a non-shrinkable film is laminated to this pressure-sensitive adhesive layer, and a non-shrinkable film is attached to the non-shrinkable film. Dry batteries can be made by bonding a metal-deposited shrinkable film that shrinks in the circumferential direction of the dry battery via an adhesive, and then cutting the shrinkable film and non-shrinkable film to the size to be used without cutting the release paper. 1. A method for producing an exterior label for a dry cell battery, the method comprising: forming an exterior label for a dry battery. 2. The method for producing an exterior label for a dry battery as described in item 1 above, wherein the metal-deposited shrinkable film is a film obtained by applying printing ink to the shrinkable film and then depositing metal on the shrinkable film. 3. The method for producing an exterior label for a dry cell according to item 1 or 2 above, which comprises bonding a metal-deposited shrinkable film to a non-shrinkable film and then applying printing ink to the shrinkable film. 4. The method for producing an exterior label for a dry battery according to any one of items 1 to 3 above, wherein the shrinkable film is a uniaxially stretched shrinkable film.
JP58010199A 1983-01-25 1983-01-25 Manufacture of exterior label for dry cell Granted JPS59138052A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP58010199A JPS59138052A (en) 1983-01-25 1983-01-25 Manufacture of exterior label for dry cell

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP58010199A JPS59138052A (en) 1983-01-25 1983-01-25 Manufacture of exterior label for dry cell

Publications (2)

Publication Number Publication Date
JPS59138052A JPS59138052A (en) 1984-08-08
JPH0378744B2 true JPH0378744B2 (en) 1991-12-16

Family

ID=11743604

Family Applications (1)

Application Number Title Priority Date Filing Date
JP58010199A Granted JPS59138052A (en) 1983-01-25 1983-01-25 Manufacture of exterior label for dry cell

Country Status (1)

Country Link
JP (1) JPS59138052A (en)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA1296891C (en) * 1984-08-16 1992-03-10 Rolf Will Multilayer adhesive label
US5262251A (en) * 1984-08-16 1993-11-16 Zweckform Etikettiertechnik Gmbh Multilayer adhesive label
US5747192A (en) * 1995-06-07 1998-05-05 Avery Dennison Corporation Single ply PSA labels for battery applications

Also Published As

Publication number Publication date
JPS59138052A (en) 1984-08-08

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