JPH037340B2 - - Google Patents
Info
- Publication number
- JPH037340B2 JPH037340B2 JP60202099A JP20209985A JPH037340B2 JP H037340 B2 JPH037340 B2 JP H037340B2 JP 60202099 A JP60202099 A JP 60202099A JP 20209985 A JP20209985 A JP 20209985A JP H037340 B2 JPH037340 B2 JP H037340B2
- Authority
- JP
- Japan
- Prior art keywords
- degree
- etherification
- fish
- binder
- viscosity
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 241000251468 Actinopterygii Species 0.000 claims description 14
- 239000011230 binding agent Substances 0.000 claims description 12
- 238000006266 etherification reaction Methods 0.000 claims description 12
- 229920002134 Carboxymethyl cellulose Polymers 0.000 claims description 8
- 239000001768 carboxy methyl cellulose Substances 0.000 claims description 8
- 235000010948 carboxy methyl cellulose Nutrition 0.000 claims description 8
- 239000008112 carboxymethyl-cellulose Substances 0.000 claims description 8
- 150000003839 salts Chemical class 0.000 claims description 8
- 239000007864 aqueous solution Substances 0.000 claims description 5
- 238000002156 mixing Methods 0.000 claims description 5
- 235000008331 Pinus X rigitaeda Nutrition 0.000 claims description 2
- 235000011613 Pinus brutia Nutrition 0.000 claims description 2
- 241000018646 Pinus brutia Species 0.000 claims description 2
- 235000019688 fish Nutrition 0.000 description 13
- 239000008188 pellet Substances 0.000 description 11
- 229940105329 carboxymethylcellulose Drugs 0.000 description 6
- 235000019733 Fish meal Nutrition 0.000 description 3
- 229920002907 Guar gum Polymers 0.000 description 3
- 239000004467 fishmeal Substances 0.000 description 3
- 235000013305 food Nutrition 0.000 description 3
- 239000000665 guar gum Substances 0.000 description 3
- 235000010417 guar gum Nutrition 0.000 description 3
- 229960002154 guar gum Drugs 0.000 description 3
- 235000019512 sardine Nutrition 0.000 description 3
- 239000011734 sodium Substances 0.000 description 3
- 241000555825 Clupeidae Species 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- 238000010521 absorption reaction Methods 0.000 description 2
- 235000010443 alginic acid Nutrition 0.000 description 2
- 229920000615 alginic acid Polymers 0.000 description 2
- 230000007423 decrease Effects 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000010257 thawing Methods 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- IXPNQXFRVYWDDI-UHFFFAOYSA-N 1-methyl-2,4-dioxo-1,3-diazinane-5-carboximidamide Chemical compound CN1CC(C(N)=N)C(=O)NC1=O IXPNQXFRVYWDDI-UHFFFAOYSA-N 0.000 description 1
- 241000473391 Archosargus rhomboidalis Species 0.000 description 1
- 241001635206 Conger conger Species 0.000 description 1
- 241000239366 Euphausiacea Species 0.000 description 1
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 241000442132 Lactarius lactarius Species 0.000 description 1
- 241000277338 Oncorhynchus kisutch Species 0.000 description 1
- 241000269908 Platichthys flesus Species 0.000 description 1
- 241001600434 Plectroglyphidodon lacrymatus Species 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- 241001125046 Sardina pilchardus Species 0.000 description 1
- 241000269821 Scombridae Species 0.000 description 1
- 241001441722 Takifugu rubripes Species 0.000 description 1
- 241001504592 Trachurus trachurus Species 0.000 description 1
- DPXJVFZANSGRMM-UHFFFAOYSA-N acetic acid;2,3,4,5,6-pentahydroxyhexanal;sodium Chemical compound [Na].CC(O)=O.OCC(O)C(O)C(O)C(O)C=O DPXJVFZANSGRMM-UHFFFAOYSA-N 0.000 description 1
- 150000003863 ammonium salts Chemical class 0.000 description 1
- 150000008064 anhydrides Chemical class 0.000 description 1
- 159000000007 calcium salts Chemical class 0.000 description 1
- 125000002057 carboxymethyl group Chemical group [H]OC(=O)C([H])([H])[*] 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 201000010099 disease Diseases 0.000 description 1
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 description 1
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 1
- 238000009313 farming Methods 0.000 description 1
- 235000011389 fruit/vegetable juice Nutrition 0.000 description 1
- 239000008103 glucose Substances 0.000 description 1
- 125000002791 glucosyl group Chemical group C1([C@H](O)[C@@H](O)[C@H](O)[C@H](O1)CO)* 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 235000020640 mackerel Nutrition 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 235000010755 mineral Nutrition 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 235000019629 palatability Nutrition 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 238000009372 pisciculture Methods 0.000 description 1
- 229920001495 poly(sodium acrylate) polymer Polymers 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000013535 sea water Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000000661 sodium alginate Substances 0.000 description 1
- 235000010413 sodium alginate Nutrition 0.000 description 1
- 229940005550 sodium alginate Drugs 0.000 description 1
- NNMHYFLPFNGQFZ-UHFFFAOYSA-M sodium polyacrylate Chemical compound [Na+].[O-]C(=O)C=C NNMHYFLPFNGQFZ-UHFFFAOYSA-M 0.000 description 1
- 230000004083 survival effect Effects 0.000 description 1
- 239000011782 vitamin Substances 0.000 description 1
- 229940088594 vitamin Drugs 0.000 description 1
- 229930003231 vitamin Natural products 0.000 description 1
- 235000013343 vitamin Nutrition 0.000 description 1
Landscapes
- Feed For Specific Animals (AREA)
- Fodder In General (AREA)
Description
本発明は養魚餌料用粘結剤に関するものであ
る。近年、ハマチ、鯛、ヒラメ、アジ、トラフ
グ、ギンザケ等の海面養殖が盛んになつている
が、これら養魚用の餌料として、利用されている
ものは、イワシ、サバ、コウナゴ、オオナゴ、オ
キアミなどの冷凍魚を露天、海水等で解凍し、こ
れをミンチ状もしくはブツ切り状にした生餌を給
与している。そのため、解凍時に生餌の品質低下
を起したり、解凍時の解凍汁液や投餌後の残餌に
より、魚場の汚染を生じ、ひいては赤潮の発生原
因ともなり、疾病多発につながり、生残率、成長
率の低下として、大きな問題となつている。
これらの現状に対して、養魚用餌料において、
冷凍魚を凍結状態のまま、適宜の大きさに破枠し
て、これを魚粉、ビタミン、ミネラル等を配合し
た粉末餌料、いわゆるマツシユに混合した後、任
意形状(一般にはペレツト状)に形成してなる養
魚用餌料は知られている。また粘結剤としてアル
ギン酸塩とカルシウム塩、さらにグアーガム等を
配合してなる養魚用餌料も、知られている。さら
にはアルギン酸塩、グアーガムおよびカルボキシ
メチルセルロース塩からなる粘結剤も提案されて
いる。
これらの粘結剤による養魚用餌料は生餌(凍結
魚、解凍魚のミンチ)1/マツシユ1の配合割合
にして、造粒されたもの(一般にモイストペレツ
トと称される)が基本配合となつている。
また、粒子の大きさも直径5〜7mmが通常であ
る。
しかしながら、最近、経済性や養殖魚の嗜好性
成長度合等から生餌2〜4/マツシユ1の配合、
さらにはモイストペレツトの大きさが直径3mm〜
30mmと巾広く要望されるようになつてきた。
本発明者は、これらの要望を満足させるべく、
鋭意研究の結果、本発明に到達したものである。
即ち、本発明はエーテル化度0.6以上〜0.8未満
で、1%水溶液、粘度9000cps以上のカルボキシ
メチルセルロース塩を含有することを特徴とする
生餌とマツシユからなる養魚餌料用粘結剤を提供
するものである。
本発明は、時に生餌とマツシユが2/1〜1/
2の配合割合(重量比)で、またペレツトのサイ
ズ直径3mm〜15mm[長さ5〜30mm]の対象におい
て、特に優れた効果を発揮する。
尚、エーテル化度は、セルロースの一つのグル
コース単位にカルボキシメチル基が、エーテル結
合でもつて、グルコースの水酸基を何個置換して
いるかを示すものである。
カルボキシメチルセルロースの塩としては、ナ
トリウム、カリウム、またはアンモニウム塩等を
挙げることができる。
粘結剤に要求される性質の一つとして、吸水生
があるが、カルボキシメチルセルロース塩に吸水
性を付与させるには重合度を大きくする、即ち、
粘度の大きいことが良いということが、認められ
ている。また、エーテル化度は極性基の多少を、
表わす指標であり、モイストペレツトのバインダ
ーの要件とする粘着性(接着性や、結合性)を左
右する。
本発明が、検討した結果、カルボキシメチルセ
ルロース塩のエーテル化度が低い場合は、粘着性
が弱く、崩れたり、こわれ易いモイストペレツト
ができる。他方エーテル化度が高い場合は、粘着
性が強く、小さい径のモイストペレツトにおいて
はベトつきを生じ、互いにくつつき、塊状化が起
こる。
このように、エーテル化度の大小がモイストペ
レツトの成形性に強く関与することを確認し、本
発明のエーテル化度0.6以上〜0.8未満の範囲にあ
るカルボキシメチルセルロース塩が、モイストペ
レツトの成型性に優れた効果を発揮することを見
い出したものである。
本発明の粘結剤に、他の粘結剤であるアルギン
酸ソーダ、グアーガム、ポリアクリル酸ソーダ等
を配合しても何等さしつかえない。
また、本発明粘結剤の配合量は、モイストペレ
ツトに対して、0.3〜10重量%、より好ましくは
1.0〜3.0重量%が、性能的、経済的にも有利であ
る。
以下に本発明を実施例により具体的に説明す
る。
実施例
魚粉[ホワイトフイツシユミール]97重量部
に、カルボキシメチルセルロースナトリウム塩
(以下CMC−Ma)[A](エーテル化度0.71、1
%水溶液粘度11000cps、粘度測定はBM型回転粘
度計ローターNo.4、ローター回転数30rpmによ
り、25℃にて無水物換算1%水溶液を測定した値
である。以下同じ)3重量部を均一に混合したマ
ツシユを得る。一方、連結したマイワシをラツシ
ヤーまたは鉄鎚等で細片化しチヨツパーで破砕し
て、凍結マイワシのミンチ生餌を得る。次い鎚で
得られたミンチ生餌50重量部に前記のマツシユ50
重量部をミキサー等で良く混合した後、これを造
粒機にて、プレート孔径3.1mmおよび9.6mmにより
モイストペレツトを得た。
表−1に、モイストペレツトの外観、物性を示
した。
比較品として、エーテル化度0.89、1%粘度
9900CPSのCMC−Na[B]、エーテル化度0.56、
1%粘度10500cpsのCMC−Na[C]を使用した
場合も併せて示した。
The present invention relates to a binder for fish feed. In recent years, marine farming of yellowtail, sea bream, flounder, horse mackerel, tiger puffer, coho salmon, etc. has become popular, but the food used for these fish farms is sardines, mackerel, sea eel, giant eel, krill, etc. Frozen fish is thawed in the open air or in seawater, etc., and then minced or cut into pieces and live bait is fed. As a result, the quality of live bait decreases when it thaws, and the thawing juice and leftover bait after thawing cause contamination of fish grounds, which in turn causes the occurrence of red tide, leading to frequent diseases and poor survival. This has become a major problem as the economic growth rate and growth rate decline. In response to these current conditions, in fish feed,
Frozen fish is cut into pieces of appropriate size while frozen, mixed with powdered feed containing fishmeal, vitamins, minerals, etc., so-called matsushi, and then formed into any shape (generally pellet-like). Fish feed for fish farming is known. Also known are fish feeds containing alginates, calcium salts, and guar gum as binders. Furthermore, binders consisting of alginates, guar gum and carboxymethylcellulose salts have been proposed. The basic composition of fish feed using these binders is granulated food (generally called moist pellets) at a mixing ratio of 1 part raw food (minced frozen fish, thawed fish) to 1 part matushi. ing. Further, the particle size is usually 5 to 7 mm in diameter. However, recently, due to economic efficiency and the palatability and growth rate of farmed fish, a combination of 2 to 4 pieces of live bait/1 piece of matsushi, etc.
Furthermore, the size of the moist pellets is 3 mm in diameter.
Widths as wide as 30mm have become widely requested. In order to satisfy these demands, the present inventor has
As a result of intensive research, we have arrived at the present invention. That is, the present invention provides a binder for fish feed consisting of live bait and pine nuts, characterized by containing a carboxymethylcellulose salt having a degree of etherification of 0.6 or more and less than 0.8, a 1% aqueous solution, and a viscosity of 9000 cps or more. It is. In the present invention, sometimes the raw bait and matsushi are 2/1 to 1/2
Particularly excellent effects are exhibited at a blending ratio (weight ratio) of 2 and when the pellet size is 3 mm to 15 mm in diameter [5 to 30 mm in length]. The degree of etherification indicates how many hydroxyl groups of glucose are substituted by carboxymethyl groups in one glucose unit of cellulose through ether bonds. Examples of salts of carboxymethylcellulose include sodium, potassium, or ammonium salts. One of the properties required of a binder is water absorption, but in order to impart water absorption to carboxymethylcellulose salt, the degree of polymerization must be increased, that is,
It is recognized that higher viscosity is better. In addition, the degree of etherification is determined by the amount of polar groups,
It is an index that indicates the adhesiveness (adhesiveness and bonding properties) required for the binder of moist pellets. As a result of studies conducted by the present invention, it has been found that when the degree of etherification of the carboxymethyl cellulose salt is low, moist pellets with weak adhesiveness and easily crumbling or breaking can be produced. On the other hand, if the degree of etherification is high, the stickiness is strong, and small-diameter moist pellets become sticky, stick to each other, and form clumps. In this way, it was confirmed that the degree of etherification has a strong influence on the moldability of moist pellets, and the carboxymethylcellulose salt of the present invention having a degree of etherification in the range of 0.6 or more to less than 0.8 was found to be effective in molding moist pellets. It has been discovered that it has excellent effects on sex. There is no problem in adding other binders such as sodium alginate, guar gum, and sodium polyacrylate to the binder of the present invention. Further, the blending amount of the binder of the present invention is 0.3 to 10% by weight, more preferably 0.3 to 10% by weight based on the moist pellets.
A content of 1.0 to 3.0% by weight is advantageous in terms of performance and economy. The present invention will be specifically explained below using examples. Example To 97 parts by weight of fish meal [white fish meal], carboxymethyl cellulose sodium salt (hereinafter referred to as CMC-Ma) [A] (degree of etherification 0.71, 1
% aqueous solution viscosity 11,000 cps, the viscosity was measured using a BM type rotational viscometer rotor No. 4 and a rotor rotation speed of 30 rpm for a 1% aqueous solution in terms of anhydride at 25°C. 3 parts by weight (the same applies hereinafter) are uniformly mixed to obtain mash. On the other hand, the connected sardines are cut into small pieces using a rasher or iron hammer, and crushed using a chopper to obtain minced raw frozen sardine bait. Next, add 50 parts by weight of the minced raw bait obtained using a hammer to 50 parts by weight of the above-mentioned mash.
After thoroughly mixing the weight parts with a mixer or the like, moist pellets were obtained using a granulator with plate hole diameters of 3.1 mm and 9.6 mm. Table 1 shows the appearance and physical properties of the moist pellets. As a comparison product, degree of etherification is 0.89, viscosity is 1%
CMC-Na[B] of 9900CPS, degree of etherification 0.56,
The case where CMC-Na [C] with a 1% viscosity of 10,500 cps was used is also shown.
【表】【table】
Claims (1)
液、粘度9000cps以上のカルボキシメチルセルロ
ース塩を含有することを特徴とする生餌とマツシ
ユからなる養魚餌料用粘結剤。 2 エーテル化度0.6以上〜0.8未満で1%水溶
液、粘度9000cps以上のカルボキシメチルセルロ
ース塩を含有することを特徴とする生餌とマツシ
ユが2/1〜1/2の配合割合(重量比)からな
る特許請求の範囲第1項記載の養魚餌料用粘結
剤。[Scope of Claims] 1. A binder for fish feed consisting of raw bait and pine nuts, characterized in that it contains a carboxymethylcellulose salt having a degree of etherification of 0.6 or more and less than 0.8, a 1% aqueous solution, and a viscosity of 9000 cps or more. 2. Raw bait and matsushi characterized by containing a carboxymethyl cellulose salt with a degree of etherification of 0.6 or more and less than 0.8, a 1% aqueous solution, and a viscosity of 9000 cps or more, in a mixing ratio (weight ratio) of 2/1 to 1/2. A binder for fish feed according to claim 1.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP60202099A JPS6261545A (en) | 1985-09-11 | 1985-09-11 | Binder for feed of fish farming |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP60202099A JPS6261545A (en) | 1985-09-11 | 1985-09-11 | Binder for feed of fish farming |
Publications (2)
Publication Number | Publication Date |
---|---|
JPS6261545A JPS6261545A (en) | 1987-03-18 |
JPH037340B2 true JPH037340B2 (en) | 1991-02-01 |
Family
ID=16451945
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP60202099A Granted JPS6261545A (en) | 1985-09-11 | 1985-09-11 | Binder for feed of fish farming |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPS6261545A (en) |
Families Citing this family (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS62248461A (en) * | 1986-03-24 | 1987-10-29 | Daicel Chem Ind Ltd | Production of fish raising feed |
JPS63192351A (en) * | 1987-02-02 | 1988-08-09 | Dai Ichi Kogyo Seiyaku Co Ltd | Fish farming feed in moist pellet state |
JPH01117752A (en) * | 1987-10-30 | 1989-05-10 | Daicel Chem Ind Ltd | Binder for feed used in culturing fish |
-
1985
- 1985-09-11 JP JP60202099A patent/JPS6261545A/en active Granted
Also Published As
Publication number | Publication date |
---|---|
JPS6261545A (en) | 1987-03-18 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
EXPY | Cancellation because of completion of term |