JPH0369700A - Cellulosic heat-insulation material and production thereof - Google Patents

Cellulosic heat-insulation material and production thereof

Info

Publication number
JPH0369700A
JPH0369700A JP20628689A JP20628689A JPH0369700A JP H0369700 A JPH0369700 A JP H0369700A JP 20628689 A JP20628689 A JP 20628689A JP 20628689 A JP20628689 A JP 20628689A JP H0369700 A JPH0369700 A JP H0369700A
Authority
JP
Japan
Prior art keywords
paper
cellulose
heat insulating
insulating material
material according
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP20628689A
Other languages
Japanese (ja)
Inventor
Yoshihiro Tamura
田村 芳弘
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
TAMURA MEIBOKU KK
Original Assignee
TAMURA MEIBOKU KK
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by TAMURA MEIBOKU KK filed Critical TAMURA MEIBOKU KK
Priority to JP20628689A priority Critical patent/JPH0369700A/en
Publication of JPH0369700A publication Critical patent/JPH0369700A/en
Pending legal-status Critical Current

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  • Dry Formation Of Fiberboard And The Like (AREA)
  • Building Environments (AREA)
  • Paper (AREA)

Abstract

PURPOSE:To obtain the subject heat-insulation material suitable for heat- insulation, sound-absorption and sound-shielding use by crushing paper into fine fibrous state and coarse paper pieces, applying an aqueous emulsion adhesive and an adhesive to the crushed composition, scattering and laminating the mixture and adjusting the water-content and the bulk density to respective specific levels. CONSTITUTION:The objective cellulosic heat-insulation material can be produced by producing (A) a composition composed of (i) fine fibrous material produced by thoroughly crushing a paper (product) and (ii) coarse paper pieces having a dimension of <=10mm and produced by roughly crushing the paper to an extent to leave the form of paper, applying or scattering (B) an aqueous emulsion type adhesive and (C) an adhesive to the composition A and laminating the mixture to form a mat having a water-content of <=20% and a bulk density of 0.03-0.06.

Description

【発明の詳細な説明】[Detailed description of the invention]

[産業上の利用分野] 本発明は、主として建築物の断熱・吸音・遮音および結
露防止の目的で利用されるセルロース系の断熱材に関す
るものである。
[Industrial Application Field] The present invention relates to a cellulose-based heat insulating material used mainly for the purpose of heat insulation, sound absorption, sound insulation, and prevention of dew condensation in buildings.

【従来の技術】[Conventional technology]

従来まり紙および紙製品やパルプ等のセルロース系繊維
は優れた断熱性や吸音・遮音性を示すことから、これら
の繊維を単味で、あるいは防燃、防かび・防虫処理を施
して建物の壁、床下、天井裏等の空間部分に注入して断
熱性を持たせることが行なわれてきた。これらは一般に
吹き込み工法あるいはブローイング工法といわれている
。 また、セルロース繊維等のチップ状物から成形体を形成
する方法としては、従来公知のグラスウールマットや繊
維板の製造方法を準用して、古紙などの紙および紙製品
粉砕物に接着剤を塗布した後、散布積層して板状あるい
はマット状とすることが、容易に考えられる。 [発明が解決しようとする課題] 従来の技術で述べたものにあっては、下記のような問題
点を有していた。 すなわち、前者である工法は、建物の空間部分の形状に
とられれることなく施工でき、また、空間部内の柱、間
柱や胴ふち等の間に間隙を生じさせないという利点はあ
るが、マット状や板状の断熱材を施工する場合と較べて
、現場施工の制約上製品の品質の均一性に欠け、また粉
塵が発生し、比較的作業時間が長い等の作業性に劣ると
いう欠点がある。 また、セルロース繊維の定着性を改善するために水性の
接着剤を併用して施工されることも多いが、その場合は
接着剤中の湿分が抜は切らないために結露の発生を助長
する原因ともなっていた。 後者であるマット状とする方法では、製品の機械的強度
と断熱性・遮音性を同時に満足させることは難しく、ま
た、品質の安定した製品が得られないという欠点が生じ
る。 本願は、従来の技術の有するこのような問題点に鑑みな
されたものであり、その目的とするところは1次のよう
な事のできるものをを提供しようとするものである。 すなわち、セルロース系繊維の特徴を失わせることなく
、あらかじめ板状またはマット状の断熱材を形成するこ
とを可能ならしめ、産業上、大きな効果を発揮させよう
とするものである。 [課題を解決するための手段] 本発明者は、上記した問題点を解決するために、詳細な
検討を行なった結果、使用する紙および紙製品粉砕物の
形状および組成が得られる製品の品質に大きく関わって
いることを見出し、本発明に到達した。 すなわち1本発明は紙および紙製品を粉砕して得られる
繊維状物に水性エマルジョン型接着剤あるいは粘着剤を
所定の割合で塗布し、そのものを散布積層した後、過剰
の水分を乾燥除去し、マット状の成形体とするが、その
際、原料として用いる紙および紙製品を粗く破砕して得
た紙としての形状を残している10mm以下、3m劇以
上の大組紙片と1Ilfilの篩目を通る微細なセルロ
ース繊維の混合物としたことを基本的な第一の特徴とす
るものである。 すなわち、本発明では、この損紙片部分が100重量部
に対して、微細繊維部分が300〜1000重量部の割
合となるように調節した。 紙粉珍物がl am以下の微細繊維のみから構成されて
いる場合は、接着剤量に対して機械的強度の優れた製品
は得られず、また、接着剤を多用すると相対的に製品密
度が増加し、結果として断熱性が損なわれる。 一方、数IIIm程度の損紙片のみから構成されている
場合は、機械的強度は大きいものの、製品密度も大きく
、また、紙片間で形成される内部空隙も大きくなるので
、空気透過抵抗が減少し、やはり断熱性が損なわれる結
果となる。 これに対して本発明の構成では、微細繊維のマトリック
スの中に粗大紙片が分散した構造を形成する。 しかも、この粗大紙片は、大部分は微細繊維を介在して
結合されているが、部分的には紙片間で結合している。 このため、粗大紙片が機械的強度を効果的に分担し、微
細繊維単味の場合と比べて、相対的に少ない接着剤量で
機械的強度の優れた製品とすることができる。 さらに、粗大紙片単味の場合に生じた大容積の空隙は微
細繊維で充填された状態となり、より細分化された空隙
に変えられている。 そのため、空気透過抵抗は増大し、また、微細繊維の存
在によって製品密度も低下しているので、接着剤使用量
が少ないことと相まって、断熱性・遮音性にも優れた製
品とすることができる。 当然のことながら、紙組成物の形状および組成がこの範
囲からはずれた場合には、それぞれ単味で用いた結果に
近づくことになり、実用的な製品とはなり得ない。 [作用] 効果と共に説明する。 [発明の実施例] 実施例について図面を参照して説明する。 水分を約10%に調整した古紙を粉砕し、1lI11以
上の粗大紙片100重量部に対して、lll11以下の
微細繊維が300〜1000重量部となるように調製す
る。 この古紙粉砕調製物をブロアを用いて、毎時100Kg
の割合で吐出し、さらに、この吐出物中に固形分濃度2
5%に調節した水性アクリル系エマルジョン型接着剤を
スプレーガンな用いて毎時40Kgの割合で噴霧し、気
流下で両者を混合して古紙粉砕調製物に接着剤を点状に
塗布する。接着剤が塗布された古紙粉砕物はそのまま速
やかに積層する。 この接着剤の配合量は古紙粉砕物に対して5〜15%の
範囲、接着剤の固形分濃度は25〜50%の範囲とする
ことが望ましい。 なぜならば、接着剤量が少ない場合には必要な機械的強
度が得られず、また、過剰の場合には製品密度が増加し
断熱性が低下する。 接着剤の固形分濃度は、低い場合には接着剤と繊維との
混合が妨害され、高い場合には製品水分量が大きくなり
、後段の乾燥操作に支障を来す。 また、接着剤量の多い場合と同様に製品密度の増加を招
く。 このように、接着剤配合量、接着剤の固形分濃度を適宜
に設定することによって、積層物の水分量を調節し、製
品密度を調節することが可能である。 また、必要があれば積層後、圧縮操作を加えることによ
っても密度の調節は可能である。 次に、積層物は加熱または、および通気によって水分2
0%以下となるように乾燥される。 水分を20%以下とすることにより、紙片および繊維間
の接着層は強固なものとなり、施工時に行なわれる通常
のハンドリング操作によって、形状の崩壊などを生じさ
せない効果が生じる。 積層物はあらかじめ要求される製品と同じ厚さに仕上げ
られている場合は、そのまま製品とする。 また、重層されている場合は、乾燥後、所定の厚さに切
り出して製品とする。 このようにして得られた製品の代表的な性質は次の通り
である。 水    分    15% 密    度    0.04 熱伝導率  0.034 なお、本発明のバリエーションとして1本構成の粗大紙
片の一部または全部を他の類似の形状の物質、例えば、
イナワラ、バガス、麻、イグサ、籾穀等の天然植物質繊
維、天然および化学繊維からなる糸状物、布片、あるい
はガラス繊維、ロックウール等の鉱物質繊維で置換する
ことが可能である。 これらの場合は、微押セルロース繊維によって断熱性・
遮音性が分担されているので、粗大紙片を用いた場合と
類似の効果が得られるが、機械的強度はさらに向上する
。 また、この積層操作をプラスチックシート、クロス、合
板および金属板上で行なうことにより、これらと一体化
した製品を得ることが可能である。 さらに、この変形として、サンドイッチ構造としたもの
、セルロース系断熱材の中層にこれらの材料を配置した
ものの製造が可能である。 さらに、積層操作後、セルロース系断熱材の表面部分に
合成樹脂を塗布、硬化させて、強化用の被覆を形成する
ことも可能である。 これらの手段により、さらに機械的強度の優れた製品を
得ることができる。 また、古紙粉砕物はあらかじめ防燃、防虫、防かび加工
を行なうことも可能で、この場合は得られる製品にこれ
らの性質が付与されるので、実用上効果は大なるものが
ある。 さらに、古紙粉砕物をあらかじめ撥水処理しておくこと
によって塗布された接着剤液滴の繊維内の浸透が抑制さ
れるので、より少量の接着剤で繊維同志を点状に結着す
ることが可能となり、断熱性および物性をさらに向上さ
せることができる。 [発明の効果] 本発明は、上述の通り構成されているので次に記載する
効果を奏する。 本発明のセルロース系断熱材は、紙および紙製品を破砕
して得た粗紙片と微細繊維状物質との混合物を接着剤を
用いてマット状に成形することによって、強度的性質と
熱的性質をこの両要素にそれぞれ分担させ、これらの機
能をバランスよく合わせ持った材料としたものである。 このことによって、セルロース系の断熱材料を品質の均
一なマット状の工業製品として供給し、断熱施工の合理
化、簡略化を実現した。 すなわち、グラスウール、ロックウールなどの断熱材料
より機能的に優れたセルロース系の断熱材を、これらと
同様の手段で施工することを可能とした。
Traditionally, cellulose fibers such as paper, paper products, and pulp exhibit excellent heat insulation, sound absorption, and sound insulation properties, so these fibers can be used alone or with flame-retardant, mold-proof, and insect-proof treatments to build buildings. It has been injected into spaces such as walls, under floors, and attic areas to provide insulation. These methods are generally called blowing methods or blowing methods. In addition, as a method for forming a molded body from chip-like materials such as cellulose fibers, an adhesive is applied to paper such as waste paper and crushed paper products by applying a conventionally known manufacturing method for glass wool mats and fiberboards. After that, it is easily possible to spread and laminate the material to form a plate or mat. [Problems to be Solved by the Invention] The conventional techniques described above have the following problems. In other words, the former construction method has the advantage that it can be constructed regardless of the shape of the building's space, and does not create gaps between columns, studs, edges, etc. in the space, but Compared to the case of installing sheet-shaped insulation materials, there are drawbacks such as a lack of uniformity in product quality due to on-site construction constraints, and poor workability such as generation of dust and relatively long work time. . In addition, water-based adhesives are often used in combination to improve the adhesion of cellulose fibers, but in this case, the moisture in the adhesive cannot be removed, which promotes the formation of dew condensation. It was also the cause. In the latter method of forming a mat, it is difficult to simultaneously satisfy the mechanical strength and heat insulation/sound insulation properties of the product, and it also has the disadvantage that a product with stable quality cannot be obtained. The present application has been made in view of the problems of the prior art, and its purpose is to provide something that can do the following. That is, the present invention aims to make it possible to form a plate-like or mat-like heat insulating material in advance without losing the characteristics of cellulose fibers, and to bring about great industrial effects. [Means for Solving the Problems] In order to solve the above-mentioned problems, the inventor of the present invention has conducted a detailed study, and as a result, the quality of the product obtained by the shape and composition of the paper and paper product pulverized material to be used has been determined. The present invention was achieved based on the discovery that this is largely related to That is, 1 the present invention applies a water-based emulsion type adhesive or pressure-sensitive adhesive at a predetermined ratio to a fibrous material obtained by crushing paper and paper products, spreads and laminates the adhesive, and then dries and removes excess water. A mat-like molded product is formed by roughly crushing the paper and paper products used as raw materials and using large paper pieces of 10 mm or less and 3 m or more in size that retain the paper shape and a 1Ilfil sieve. The first basic feature is that it is a mixture of fine cellulose fibers that can pass through it. That is, in the present invention, the ratio of the fine fiber portion was adjusted to be 300 to 1000 parts by weight to 100 parts by weight of the waste paper piece portion. If the paper dust item is composed only of fine fibers of less than 1 am, it will not be possible to obtain a product with excellent mechanical strength compared to the amount of adhesive, and if too much adhesive is used, the product density will be relatively low. increases, resulting in a loss of insulation. On the other hand, if it is made up of only several pieces of broken paper, the mechanical strength is high, but the density of the product is also large, and the internal voids formed between the pieces of paper are also large, so the air permeation resistance is reduced. , this also results in loss of heat insulation properties. In contrast, the structure of the present invention forms a structure in which coarse paper pieces are dispersed in a matrix of fine fibers. In addition, most of these coarse pieces of paper are bonded through fine fibers, but some of them are bonded between the paper pieces. Therefore, the coarse paper pieces effectively share the mechanical strength, and a product with excellent mechanical strength can be obtained with a relatively small amount of adhesive compared to the case of using only fine fibers. Furthermore, the large-volume voids that occur when using a single piece of coarse paper are filled with fine fibers, and are transformed into more finely divided voids. As a result, air permeation resistance increases, and the presence of fine fibers also reduces product density, which, combined with the reduced amount of adhesive used, makes it possible to create a product with excellent heat and sound insulation properties. . Naturally, if the shape and composition of the paper composition deviate from this range, the results will approach those obtained when each is used alone, and it will not be a practical product. [Effect] This will be explained along with the effects. [Embodiments of the Invention] Examples will be described with reference to the drawings. Used paper whose water content has been adjusted to about 10% is pulverized so that fine fibers with a size of 11 or less are 300 to 1000 parts by weight per 100 parts by weight of coarse paper pieces with a size of 11 or more. This waste paper pulverized preparation was processed using a blower at a rate of 100 kg per hour.
Furthermore, the solid content concentration in this discharged material is 2.
An aqueous acrylic emulsion type adhesive adjusted to 5% is sprayed using a spray gun at a rate of 40 kg per hour, and the adhesive is dotted onto the waste paper pulverized preparation by mixing them under an air stream. The crushed waste paper coated with adhesive is immediately stacked as is. It is desirable that the blending amount of this adhesive is in the range of 5 to 15% based on the crushed waste paper, and the solid content concentration of the adhesive is in the range of 25 to 50%. This is because if the amount of adhesive is small, the required mechanical strength cannot be obtained, and if it is excessive, the product density increases and the heat insulation properties decrease. If the solid content concentration of the adhesive is low, mixing of the adhesive and fibers will be hindered, and if it is high, the moisture content of the product will increase, which will interfere with the subsequent drying operation. Further, as in the case where the amount of adhesive is large, the density of the product increases. In this way, by appropriately setting the blending amount of the adhesive and the solid content concentration of the adhesive, it is possible to adjust the moisture content of the laminate and the product density. Further, if necessary, the density can be adjusted by applying a compression operation after lamination. Next, the laminate is heated or vented to absorb moisture.
It is dried so that it becomes 0% or less. By controlling the moisture content to 20% or less, the adhesive layer between the paper pieces and the fibers becomes strong, and there is an effect that the shape does not collapse during normal handling operations performed during construction. If the laminate has already been finished to the same thickness as the required product, it can be used as a product. In addition, if there are multiple layers, after drying, the product is cut out to a predetermined thickness. Typical properties of the product thus obtained are as follows. Moisture: 15% Density: 0.04 Thermal conductivity: 0.034 As a variation of the present invention, a part or all of one large piece of paper may be replaced with another similarly shaped material, for example,
It is possible to replace it with natural vegetable fibers such as rice straw, bagasse, hemp, rush, and rice grains, threads made of natural and chemical fibers, pieces of cloth, or mineral fibers such as glass fibers and rock wool. In these cases, micro-pressed cellulose fibers provide insulation and
Since the sound insulation properties are shared, an effect similar to that obtained using coarse paper pieces can be obtained, but the mechanical strength is further improved. Moreover, by carrying out this lamination operation on plastic sheets, cloth, plywood, and metal plates, it is possible to obtain products integrated with these. Furthermore, as a variation of this, it is possible to manufacture a sandwich structure or one in which these materials are placed in the middle layer of a cellulosic insulation material. Furthermore, after the lamination operation, it is also possible to apply a synthetic resin to the surface portion of the cellulose-based heat insulating material and harden it to form a reinforcing coating. By these means, it is possible to obtain a product with even better mechanical strength. Furthermore, the crushed waste paper can be treated in advance with fireproofing, insectproofing, and moldproofing, and in this case, these properties are imparted to the resulting product, which has great practical effects. Furthermore, by pre-water-repelling the crushed waste paper, the penetration of applied adhesive droplets into the fibers is suppressed, making it possible to bind fibers together in dots with a smaller amount of adhesive. This makes it possible to further improve the heat insulation properties and physical properties. [Effects of the Invention] Since the present invention is configured as described above, it produces the following effects. The cellulose-based heat insulating material of the present invention has strong strength and thermal properties by forming a mixture of coarse paper pieces obtained by crushing paper and paper products and fine fibrous material into a mat shape using an adhesive. These two elements are assigned their respective functions, and the material has a well-balanced combination of these functions. As a result, we have been able to supply cellulose-based insulation materials as mat-like industrial products of uniform quality, and have realized rationalization and simplification of insulation construction. In other words, it has become possible to construct a cellulose-based heat insulating material that is functionally superior to heat insulating materials such as glass wool and rock wool using the same method.

【図面の簡単な説明】[Brief explanation of drawings]

第1図は製造方法のフロー図である。 FIG. 1 is a flow diagram of the manufacturing method.

Claims (1)

【特許請求の範囲】 1、紙および紙製品を十分に粉砕して得た微細繊維状物
と、紙としての形状を残すよう に粗く破砕して得た10mm以下の粗大紙片からなる紙
組成物に、水性エマルジョン型 接着剤および接着剤を塗布、散布積層し、 水分20%以下、嵩密度0.03〜0.06のマット状
であることを特徴とするセルロー ス系断熱材。 2、紙および紙製品を十分に粉砕して得た微細繊維状物
と、紙としての形状を残すよう に粗く破砕して得た10mm以下の粗大紙片からなる紙
組成物に、水性エマルジョン型 接着剤および接着剤を塗布、散布積層した 後、過剰の水分を蒸発させ、水分20%以 下、嵩密度0.03〜0.06のマット状とすることを
特徴とするセルロース系断熱材の製造 方法。 3、粗大紙片の一部または全部がイナワラ、バガス、麻
、イグサ、籾穀などの天然植物 繊維質、天然および化学繊維からなる糸状 物、布からなるチップ、ガラス繊維で置換 されている請求項1記載のセルロース系断 熱材あるいは請求項2記載のセルロース系 断熱材の製造方法。 4、紙および紙製品があらかじめ撥水処理されている請
求項1記載のセルロース系断熱 材あるいは請求項2記載のセルロース系断 熱材の製造方法。 5、紙および紙製品があらかじめ防燃、防 虫、防カビ処理されている請求項1記載の セルロース系断熱材あるいは請求項2記載 のセルロース系断熱材の製造方法。 6、紙組成物の積層操作をプラスチックシート、クロス
、寒冷沙、クラフト紙、合板、 金属板上で行ない、これらの材料をセルロ ース系断熱材の片面に接合し、これらの材 料を積層操作終了後、速やかに上部に載置 しセルロース系断熱材の両面に接合すると 共に、積層操作途中でこれらの材料を載置 し、その後で積層を継続してセルロース系 断熱材の中層部にこれらの材料を配置一体 化した請求項1記載のセルロース系断熱材 あるいは請求項2記載のセルロース系断熱 材の製造方法。 7、マット状のものの表面に合成樹脂を塗 布、硬化させて、表層部を強化被覆した請 求項1記載のセルロース系断熱材あるいは 請求項2記載のセルロース系断熱材の製造 方法。
[Claims] 1. A paper composition consisting of fine fibrous material obtained by sufficiently crushing paper and paper products, and coarse paper pieces of 10 mm or less obtained by coarsely crushing paper so as to retain its paper shape. A cellulose-based heat insulating material, which is obtained by coating, scattering and laminating a water-based emulsion type adhesive and an adhesive, and having a moisture content of 20% or less and a bulk density of 0.03 to 0.06 in the form of a mat. 2. A water-based emulsion type adhesive is applied to a paper composition consisting of fine fibrous material obtained by sufficiently crushing paper and paper products, and coarse paper pieces of 10 mm or less obtained by coarsely crushing paper so as to retain its paper shape. A method for producing a cellulose-based heat insulating material, which comprises applying, spraying and laminating an agent or adhesive, and then evaporating excess moisture to form a matte shape with a moisture content of 20% or less and a bulk density of 0.03 to 0.06. . 3. A claim in which part or all of the large pieces of paper are replaced with natural plant fibers such as rice straw, bagasse, hemp, rush, and rice grains, threads made of natural and chemical fibers, chips made of cloth, and glass fibers. The cellulose-based heat insulating material according to claim 1 or the method for producing the cellulose-based heat insulating material according to claim 2. 4. The cellulose-based insulation material according to claim 1 or the method for producing a cellulose-based insulation material according to claim 2, wherein the paper and paper products are previously treated to be water-repellent. 5. The cellulose-based heat insulating material according to claim 1, or the method for producing the cellulose-based heat insulating material according to claim 2, wherein the paper and paper products have been previously subjected to fireproofing, insectproofing, and moldproofing treatment. 6. Perform the lamination operation of the paper composition on a plastic sheet, cloth, chilli sand, kraft paper, plywood, or metal plate, bond these materials to one side of the cellulose-based insulation material, and after the lamination operation is completed. , quickly place it on top and bond it to both sides of the cellulose-based insulation, place these materials in the middle of the lamination operation, and then continue laminating and apply these materials to the middle layer of the cellulose-based insulation. The cellulose-based heat insulating material according to claim 1 or the method for producing the cellulose-based heat insulating material according to claim 2, wherein the cellulose-based heat insulating material is arranged in an integrated manner. 7. The cellulose-based heat insulating material according to claim 1 or the method for producing the cellulose-based heat insulating material according to claim 2, wherein a synthetic resin is coated on the surface of the mat-like material and cured to strengthen the surface layer.
JP20628689A 1989-08-08 1989-08-08 Cellulosic heat-insulation material and production thereof Pending JPH0369700A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP20628689A JPH0369700A (en) 1989-08-08 1989-08-08 Cellulosic heat-insulation material and production thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP20628689A JPH0369700A (en) 1989-08-08 1989-08-08 Cellulosic heat-insulation material and production thereof

Publications (1)

Publication Number Publication Date
JPH0369700A true JPH0369700A (en) 1991-03-26

Family

ID=16520796

Family Applications (1)

Application Number Title Priority Date Filing Date
JP20628689A Pending JPH0369700A (en) 1989-08-08 1989-08-08 Cellulosic heat-insulation material and production thereof

Country Status (1)

Country Link
JP (1) JPH0369700A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH07189358A (en) * 1993-12-28 1995-07-28 Edorasu Kk Sound absorption board, and sound absorption and sound insulation structure
JP2010019026A (en) * 2008-07-11 2010-01-28 Fujita Corp Heat insulating panel

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5613155A (en) * 1979-07-12 1981-02-09 Koji Mitsuo Light-weight material
JPS6310248U (en) * 1986-07-09 1988-01-23

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5613155A (en) * 1979-07-12 1981-02-09 Koji Mitsuo Light-weight material
JPS6310248U (en) * 1986-07-09 1988-01-23

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH07189358A (en) * 1993-12-28 1995-07-28 Edorasu Kk Sound absorption board, and sound absorption and sound insulation structure
JP2010019026A (en) * 2008-07-11 2010-01-28 Fujita Corp Heat insulating panel

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