JPH0367641A - Treatment agent for tire cord - Google Patents
Treatment agent for tire cordInfo
- Publication number
- JPH0367641A JPH0367641A JP1205089A JP20508989A JPH0367641A JP H0367641 A JPH0367641 A JP H0367641A JP 1205089 A JP1205089 A JP 1205089A JP 20508989 A JP20508989 A JP 20508989A JP H0367641 A JPH0367641 A JP H0367641A
- Authority
- JP
- Japan
- Prior art keywords
- treatment agent
- surfactant
- agent
- tire cord
- group
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 41
- -1 amide compound Chemical class 0.000 claims abstract description 15
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims abstract description 12
- 239000004094 surface-active agent Substances 0.000 claims abstract description 11
- 229920000728 polyester Polymers 0.000 claims abstract description 10
- 239000003995 emulsifying agent Substances 0.000 claims abstract description 9
- 238000009499 grossing Methods 0.000 claims abstract description 8
- 239000002480 mineral oil Substances 0.000 claims abstract description 7
- 239000003945 anionic surfactant Substances 0.000 claims abstract description 5
- 241001465754 Metazoa Species 0.000 claims abstract description 4
- 239000002280 amphoteric surfactant Substances 0.000 claims abstract description 4
- 239000010775 animal oil Substances 0.000 claims abstract description 4
- 239000003093 cationic surfactant Substances 0.000 claims abstract description 4
- 235000015112 vegetable and seed oil Nutrition 0.000 claims abstract description 4
- 239000008158 vegetable oil Substances 0.000 claims abstract description 4
- 239000002736 nonionic surfactant Substances 0.000 claims abstract description 3
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 6
- 239000000194 fatty acid Substances 0.000 claims description 6
- 229930195729 fatty acid Natural products 0.000 claims description 6
- 239000001993 wax Substances 0.000 claims description 3
- 235000010446 mineral oil Nutrition 0.000 abstract description 6
- 238000000034 method Methods 0.000 abstract description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 3
- 239000010779 crude oil Substances 0.000 abstract description 2
- 238000004519 manufacturing process Methods 0.000 abstract description 2
- 239000000839 emulsion Substances 0.000 abstract 1
- 239000000126 substance Substances 0.000 abstract 1
- 230000000052 comparative effect Effects 0.000 description 9
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 8
- RPACBEVZENYWOL-XFULWGLBSA-M sodium;(2r)-2-[6-(4-chlorophenoxy)hexyl]oxirane-2-carboxylate Chemical compound [Na+].C=1C=C(Cl)C=CC=1OCCCCCC[C@]1(C(=O)[O-])CO1 RPACBEVZENYWOL-XFULWGLBSA-M 0.000 description 8
- 239000000853 adhesive Substances 0.000 description 6
- 230000001070 adhesive effect Effects 0.000 description 6
- POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical compound CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 description 6
- OQILCOQZDHPEAZ-UHFFFAOYSA-N octyl palmitate Chemical compound CCCCCCCCCCCCCCCC(=O)OCCCCCCCC OQILCOQZDHPEAZ-UHFFFAOYSA-N 0.000 description 6
- QZULIRBSQUIUTA-CLFAGFIQSA-N bis[(z)-octadec-9-enyl] hexanedioate Chemical compound CCCCCCCC\C=C/CCCCCCCCOC(=O)CCCCC(=O)OCCCCCCCC\C=C/CCCCCCCC QZULIRBSQUIUTA-CLFAGFIQSA-N 0.000 description 4
- 238000005461 lubrication Methods 0.000 description 4
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 3
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 description 3
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 description 3
- 239000005639 Lauric acid Substances 0.000 description 3
- 239000005642 Oleic acid Substances 0.000 description 3
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 description 3
- 235000019484 Rapeseed oil Nutrition 0.000 description 3
- NTPFJSYVROWMFR-CLFAGFIQSA-N [(z)-octadec-9-enyl] 3-[3-[(z)-octadec-9-enoxy]-3-oxopropyl]sulfanylpropanoate Chemical compound CCCCCCCC\C=C/CCCCCCCCOC(=O)CCSCCC(=O)OCCCCCCCC\C=C/CCCCCCCC NTPFJSYVROWMFR-CLFAGFIQSA-N 0.000 description 3
- 235000019438 castor oil Nutrition 0.000 description 3
- 239000004359 castor oil Substances 0.000 description 3
- 238000007598 dipping method Methods 0.000 description 3
- 150000002148 esters Chemical class 0.000 description 3
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 description 3
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 3
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 3
- BARWIPMJPCRCTP-CLFAGFIQSA-N oleyl oleate Chemical compound CCCCCCCC\C=C/CCCCCCCCOC(=O)CCCCCCC\C=C/CCCCCCCC BARWIPMJPCRCTP-CLFAGFIQSA-N 0.000 description 3
- 239000000344 soap Substances 0.000 description 3
- KBPLFHHGFOOTCA-UHFFFAOYSA-N 1-Octanol Chemical compound CCCCCCCCO KBPLFHHGFOOTCA-UHFFFAOYSA-N 0.000 description 2
- SVTBMSDMJJWYQN-UHFFFAOYSA-N 2-methylpentane-2,4-diol Chemical compound CC(O)CC(C)(C)O SVTBMSDMJJWYQN-UHFFFAOYSA-N 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 150000004665 fatty acids Chemical class 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- UHGIMQLJWRAPLT-UHFFFAOYSA-N octadecyl dihydrogen phosphate Chemical class CCCCCCCCCCCCCCCCCCOP(O)(O)=O UHGIMQLJWRAPLT-UHFFFAOYSA-N 0.000 description 2
- 239000003921 oil Substances 0.000 description 2
- 235000019198 oils Nutrition 0.000 description 2
- BARWIPMJPCRCTP-UHFFFAOYSA-N oleic acid oleyl ester Natural products CCCCCCCCC=CCCCCCCCCOC(=O)CCCCCCCC=CCCCCCCCC BARWIPMJPCRCTP-UHFFFAOYSA-N 0.000 description 2
- 150000003242 quaternary ammonium salts Chemical class 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- HVLLSGMXQDNUAL-UHFFFAOYSA-N triphenyl phosphite Chemical compound C=1C=CC=CC=1OP(OC=1C=CC=CC=1)OC1=CC=CC=C1 HVLLSGMXQDNUAL-UHFFFAOYSA-N 0.000 description 2
- LDMOEFOXLIZJOW-UHFFFAOYSA-N 1-dodecanesulfonic acid Chemical compound CCCCCCCCCCCCS(O)(=O)=O LDMOEFOXLIZJOW-UHFFFAOYSA-N 0.000 description 1
- SUQPHYAFSSXBNB-UHFFFAOYSA-N 16-methylheptadecyl dihydrogen phosphate Chemical compound CC(C)CCCCCCCCCCCCCCCOP(O)(O)=O SUQPHYAFSSXBNB-UHFFFAOYSA-N 0.000 description 1
- GSAHAZJWNMHSNI-UHFFFAOYSA-N 2,2-bis(dodecanoyloxymethyl)butyl dodecanoate Chemical compound CCCCCCCCCCCC(=O)OCC(CC)(COC(=O)CCCCCCCCCCC)COC(=O)CCCCCCCCCCC GSAHAZJWNMHSNI-UHFFFAOYSA-N 0.000 description 1
- CTTJWXVQRJUJQW-UHFFFAOYSA-N 2,2-dioctyl-3-sulfobutanedioic acid Chemical class CCCCCCCCC(C(O)=O)(C(C(O)=O)S(O)(=O)=O)CCCCCCCC CTTJWXVQRJUJQW-UHFFFAOYSA-N 0.000 description 1
- HIAHPXLWIQVPMP-UHFFFAOYSA-N 20-aminoicosane-1,1-diol Chemical compound NCCCCCCCCCCCCCCCCCCCC(O)O HIAHPXLWIQVPMP-UHFFFAOYSA-N 0.000 description 1
- KWIUHFFTVRNATP-UHFFFAOYSA-N Betaine Natural products C[N+](C)(C)CC([O-])=O KWIUHFFTVRNATP-UHFFFAOYSA-N 0.000 description 1
- DPUOLQHDNGRHBS-UHFFFAOYSA-N Brassidinsaeure Natural products CCCCCCCCC=CCCCCCCCCCCCC(O)=O DPUOLQHDNGRHBS-UHFFFAOYSA-N 0.000 description 1
- URXZXNYJPAJJOQ-UHFFFAOYSA-N Erucic acid Natural products CCCCCCC=CCCCCCCCCCCCC(O)=O URXZXNYJPAJJOQ-UHFFFAOYSA-N 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- KWIUHFFTVRNATP-UHFFFAOYSA-O N,N,N-trimethylglycinium Chemical compound C[N+](C)(C)CC(O)=O KWIUHFFTVRNATP-UHFFFAOYSA-O 0.000 description 1
- VCUFZILGIRCDQQ-KRWDZBQOSA-N N-[[(5S)-2-oxo-3-(2-oxo-3H-1,3-benzoxazol-6-yl)-1,3-oxazolidin-5-yl]methyl]-2-[[3-(trifluoromethoxy)phenyl]methylamino]pyrimidine-5-carboxamide Chemical compound O=C1O[C@H](CN1C1=CC2=C(NC(O2)=O)C=C1)CNC(=O)C=1C=NC(=NC=1)NCC1=CC(=CC=C1)OC(F)(F)F VCUFZILGIRCDQQ-KRWDZBQOSA-N 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- 239000004721 Polyphenylene oxide Substances 0.000 description 1
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 description 1
- 241001125046 Sardina pilchardus Species 0.000 description 1
- NWGKJDSIEKMTRX-AAZCQSIUSA-N Sorbitan monooleate Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O NWGKJDSIEKMTRX-AAZCQSIUSA-N 0.000 description 1
- LWZFANDGMFTDAV-BURFUSLBSA-N [(2r)-2-[(2r,3r,4s)-3,4-dihydroxyoxolan-2-yl]-2-hydroxyethyl] dodecanoate Chemical compound CCCCCCCCCCCC(=O)OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O LWZFANDGMFTDAV-BURFUSLBSA-N 0.000 description 1
- MEESPVWIOBCLJW-KTKRTIGZSA-N [(z)-octadec-9-enyl] dihydrogen phosphate Chemical compound CCCCCCCC\C=C/CCCCCCCCOP(O)(O)=O MEESPVWIOBCLJW-KTKRTIGZSA-N 0.000 description 1
- QTIMEBJTEBWHOB-PMDAXIHYSA-N [3-[(z)-octadec-9-enoyl]oxy-2,2-bis[[(z)-octadec-9-enoyl]oxymethyl]propyl] (z)-octadec-9-enoate Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OCC(COC(=O)CCCCCCC\C=C/CCCCCCCC)(COC(=O)CCCCCCC\C=C/CCCCCCCC)COC(=O)CCCCCCC\C=C/CCCCCCCC QTIMEBJTEBWHOB-PMDAXIHYSA-N 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 150000001413 amino acids Chemical class 0.000 description 1
- JBIROUFYLSSYDX-UHFFFAOYSA-M benzododecinium chloride Chemical compound [Cl-].CCCCCCCCCCCC[N+](C)(C)CC1=CC=CC=C1 JBIROUFYLSSYDX-UHFFFAOYSA-M 0.000 description 1
- 229960003237 betaine Drugs 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 235000019864 coconut oil Nutrition 0.000 description 1
- 239000003240 coconut oil Substances 0.000 description 1
- YRIUSKIDOIARQF-UHFFFAOYSA-N dodecyl benzenesulfonate Chemical compound CCCCCCCCCCCCOS(=O)(=O)C1=CC=CC=C1 YRIUSKIDOIARQF-UHFFFAOYSA-N 0.000 description 1
- TVACALAUIQMRDF-UHFFFAOYSA-N dodecyl dihydrogen phosphate Chemical class CCCCCCCCCCCCOP(O)(O)=O TVACALAUIQMRDF-UHFFFAOYSA-N 0.000 description 1
- RSNDQTNQQQNXRN-UHFFFAOYSA-N dodecyl dihydrogen phosphite Chemical compound CCCCCCCCCCCCOP(O)O RSNDQTNQQQNXRN-UHFFFAOYSA-N 0.000 description 1
- MOTZDAYCYVMXPC-UHFFFAOYSA-N dodecyl hydrogen sulfate Chemical compound CCCCCCCCCCCCOS(O)(=O)=O MOTZDAYCYVMXPC-UHFFFAOYSA-N 0.000 description 1
- 229940043264 dodecyl sulfate Drugs 0.000 description 1
- 229940071161 dodecylbenzenesulfonate Drugs 0.000 description 1
- 230000001804 emulsifying effect Effects 0.000 description 1
- DPUOLQHDNGRHBS-KTKRTIGZSA-N erucic acid Chemical compound CCCCCCCC\C=C/CCCCCCCCCCCC(O)=O DPUOLQHDNGRHBS-KTKRTIGZSA-N 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- ZUVCYFMOHFTGDM-UHFFFAOYSA-N hexadecyl dihydrogen phosphate Chemical compound CCCCCCCCCCCCCCCCOP(O)(O)=O ZUVCYFMOHFTGDM-UHFFFAOYSA-N 0.000 description 1
- 229940051250 hexylene glycol Drugs 0.000 description 1
- 238000007654 immersion Methods 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 229940057995 liquid paraffin Drugs 0.000 description 1
- 230000001050 lubricating effect Effects 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- DVEKCXOJTLDBFE-UHFFFAOYSA-N n-dodecyl-n,n-dimethylglycinate Chemical compound CCCCCCCCCCCC[N+](C)(C)CC([O-])=O DVEKCXOJTLDBFE-UHFFFAOYSA-N 0.000 description 1
- CSWFWSPPZMEYAY-UHFFFAOYSA-N octadecyl dihydrogen phosphite Chemical compound CCCCCCCCCCCCCCCCCCOP(O)O CSWFWSPPZMEYAY-UHFFFAOYSA-N 0.000 description 1
- FATBGEAMYMYZAF-KTKRTIGZSA-N oleamide Chemical compound CCCCCCCC\C=C/CCCCCCCC(N)=O FATBGEAMYMYZAF-KTKRTIGZSA-N 0.000 description 1
- 239000004209 oxidized polyethylene wax Substances 0.000 description 1
- 235000013873 oxidized polyethylene wax Nutrition 0.000 description 1
- 239000012188 paraffin wax Substances 0.000 description 1
- 235000021317 phosphate Nutrition 0.000 description 1
- AQSJGOWTSHOLKH-UHFFFAOYSA-N phosphite(3-) Chemical class [O-]P([O-])[O-] AQSJGOWTSHOLKH-UHFFFAOYSA-N 0.000 description 1
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 1
- 229920000570 polyether Polymers 0.000 description 1
- 230000003014 reinforcing effect Effects 0.000 description 1
- 235000019512 sardine Nutrition 0.000 description 1
- HWCHICTXVOMIIF-UHFFFAOYSA-M sodium;3-(dodecylamino)propanoate Chemical compound [Na+].CCCCCCCCCCCCNCCC([O-])=O HWCHICTXVOMIIF-UHFFFAOYSA-M 0.000 description 1
- 235000011067 sorbitan monolaureate Nutrition 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 150000003871 sulfonates Chemical class 0.000 description 1
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
- 239000012209 synthetic fiber Substances 0.000 description 1
- 229920002994 synthetic fiber Polymers 0.000 description 1
- OHRVKCZTBPSUIK-UHFFFAOYSA-N tridodecyl phosphate Chemical compound CCCCCCCCCCCCOP(=O)(OCCCCCCCCCCCC)OCCCCCCCCCCCC OHRVKCZTBPSUIK-UHFFFAOYSA-N 0.000 description 1
- DECPGQLXYYCNEZ-UHFFFAOYSA-N tris(6-methylheptyl) phosphite Chemical compound CC(C)CCCCCOP(OCCCCCC(C)C)OCCCCCC(C)C DECPGQLXYYCNEZ-UHFFFAOYSA-N 0.000 description 1
- SVETUDAIEHYIKZ-IUPFWZBJSA-N tris[(z)-octadec-9-enyl] phosphate Chemical compound CCCCCCCC\C=C/CCCCCCCCOP(=O)(OCCCCCCCC\C=C/CCCCCCCC)OCCCCCCCC\C=C/CCCCCCCC SVETUDAIEHYIKZ-IUPFWZBJSA-N 0.000 description 1
Landscapes
- Reinforced Plastic Materials (AREA)
- Tyre Moulding (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
Description
【発明の詳細な説明】 ［産業上の利用分野］ 本発明はタイヤコード用処理剤に関する。[Detailed description of the invention] [Industrial application field] The present invention relates to a tire cord treatment agent.
［従来の技術］
従来、ポリエステルタイヤコード用処理剤として、ポリ
エーテル系の界面活性剤が使われている。[Prior Art] Conventionally, polyether-based surfactants have been used as processing agents for polyester tire cords.
［発明が解決しようとする課題］
しかし、上記のようなタイヤコード用処理剤は、接着剤
処理、所謂デイツプ処理後の強力ダウン防止には、不十
分である。[Problems to be Solved by the Invention] However, the above-mentioned tire cord treatment agents are insufficient for preventing strong down after adhesive treatment, so-called dip treatment.
［課題を解決するための手段］
本発明者らは、上記の実情に鑑み、ポリエステルのデイ
ツプ後、強力ダウン防止性を発揮するタイヤコード用処
理剤を得るべく鋭意検討した結果、本発明に到達した。[Means for Solving the Problems] In view of the above-mentioned circumstances, the inventors of the present invention have conducted extensive studies to obtain a tire cord treatment agent that exhibits strong down-prevention properties after polyester dips, and as a result, have arrived at the present invention. did.
すなわち本発明は、実質的にエーテル型界面活性剤を含
まず、アニオン界面活性剤、カチオン界面活性剤、両性
界面活性剤、スパン系非イオン界面活性剤およびアミド
化合物からなる群より選ばれる乳化剤と、鉱物油、動植
物油、脂肪酸エステルおよびワックスからなる群より選
ばれる平滑剤成分とからなるタイヤコード用処理剤であ
る。That is, the present invention essentially does not contain an ether type surfactant and contains an emulsifier selected from the group consisting of an anionic surfactant, a cationic surfactant, an amphoteric surfactant, a span type nonionic surfactant, and an amide compound. , a smoothing agent component selected from the group consisting of mineral oil, animal and vegetable oil, fatty acid ester, and wax.
本発明における乳化剤成分であるアニオン界面活性剤と
しては、ホスフェート（トリラウリルホスフエート、ト
リオレイルホスフェート、ステアリルホスフェートに塩
、オレイルホスフェートＮａ塩、セチルホスフェートＮ
ａ塩、ラウリルホスフェートに塩など）、ホスファイト
（トリイソオクチルホスファイト、トリフェニルホスフ
ァイト、オレイルホスファイト、ステアリルホスファイ
ト、ラウリルホスファイトなど）、サルフェート（ラウ
リルサルフェートＮａ塩１、ナタネ油の硫酸化部Ｎａ塩
、ヒマシ油の硫酸化部Ｎａ塩、オレイルオレートの硫酸
化物Ｎａ塩など）、スルフォネート（ラウリルスルホネ
ートＮａ塩、ドデシルベンゼンスルホン酸Ｎａ塩など）
脂肪酸石鹸（オレイン酸石鹸、エルシン酸石鹸など）な
どがあげられる。カチオン界面活性剤としてはアミン塩
型（ジヒドロキシエチルステアリルアミン、サパミンＡ
型、アーコベルＡ型など）、第４級アンモニウム塩型（
ラウリルジメチルベンジルアンモニウムクロライド、サ
パミン型第４級アンモニウム塩など）などがあげられる
。両性界面活性剤としては、アミノ酸型活性剤（ラウリ
ルアミノプロピオン酸ナトリウムなど）、ベタイン型活
性剤（ラウリルジメチルベタインなど）などがあげられ
る。スパン系型界面活性剤としてはスパン２０． ス
パン８０などがあげられる。アミド化合物としては脂肪
族アルカノールアミド（ラウリル酸ジェタノールアミド
、オレイン酸ジェタノールアミドなど）、脂肪酸アミド
（オレイン酸アミドなど）などがあげられる。好ましい
ものはアニオン界面活性剤、アミド化合物およびその併
用である。The anionic surfactants which are emulsifier components in the present invention include phosphates (trilauryl phosphate, trioleyl phosphate, stearyl phosphate salt, oleyl phosphate Na salt, cetyl phosphate N
a salt, salts of lauryl phosphate, etc.), phosphites (triisooctyl phosphite, triphenyl phosphite, oleyl phosphite, stearyl phosphite, lauryl phosphite, etc.), sulfates (lauryl sulfate Na salt 1, sulfuric acid of rapeseed oil) Sulfonates (Na salt of lauryl sulfonate, Na salt of dodecylbenzenesulfonate, etc.)
Examples include fatty acid soaps (oleic acid soap, erucic acid soap, etc.). As cationic surfactants, amine salt type (dihydroxyethylstearylamine, sapamin A
type, Arcobel type A, etc.), quaternary ammonium salt type (
lauryldimethylbenzylammonium chloride, sapamin-type quaternary ammonium salt, etc.). Examples of amphoteric surfactants include amino acid type surfactants (such as sodium lauryl aminopropionate) and betaine type surfactants (such as lauryl dimethyl betaine). As a span type surfactant, span 20. Examples include span 80. Examples of the amide compound include aliphatic alkanolamides (lauric acid jetanolamide, oleic acid jetanolamide, etc.), fatty acid amides (oleic acid amide, etc.). Preferred are anionic surfactants, amide compounds, and combinations thereof.
平滑剤成分である鉱物油としては、精製スピンドル油、
流動パラフィンなどがあげらる。動植物油としては、イ
ワシ油、−ヤシ油、ヒマシ油などがあげられる。脂肪酸
エステルとしては、オクチルパルミテート、オレイルオ
レートなどの１価エステル、ジオレイルアジペート、ジ
オレイルチオジプロピオネートなどの２価エステル、
トリメチロールプロパントリラウレート、ペンタエリス
リトールテトラオレートなどの多価エステルなどがあげ
られる。またワックスとしてはパラフィンワックス、酸
化ポリエチレンワックスなどがあげられる。これらのう
ち好ましいものは、脂肪酸エステルである。Mineral oil, which is a smoothing agent component, includes refined spindle oil,
Examples include liquid paraffin. Examples of animal and vegetable oils include sardine oil, coconut oil, and castor oil. Examples of fatty acid esters include monovalent esters such as octyl palmitate and oleyl oleate, divalent esters such as dioleyl adipate and dioleyl thiodipropionate,
Examples include polyvalent esters such as trimethylolpropane trilaurate and pentaerythritol tetraoleate. Examples of the wax include paraffin wax and oxidized polyethylene wax. Preferred among these are fatty acid esters.
本発明において、処理剤は実質的にエーテル型界面活性
剤を含まないものである。エーテル型界面活性剤を含ん
だ場合、デイツプ後の強力の低下が大きくなる。乳化剤
成分の含有量は、通常２０〜５０％、好ましくは２５〜
５０％である。平滑剤成分の含有量は通常５０〜８０％
、好ましくは５０〜７５％である。乳化剤成分が２０％
未満となり、平滑剤成分８０％を越えると乳化性が不良
となり、乳化剤成分が５０９Ａを越え、平滑剤成分が５
０％未満となると対金属の平滑性が悪くなる。In the present invention, the processing agent is substantially free of ether type surfactants. If an ether type surfactant is included, the strength after dipping will be greatly reduced. The content of the emulsifier component is usually 20 to 50%, preferably 25 to 50%.
It is 50%. The content of smoothing agent component is usually 50-80%
, preferably 50 to 75%. Emulsifier component is 20%
If the leveling agent component exceeds 80%, the emulsifying property becomes poor, and if the leveling agent component exceeds 509A, the leveling agent component
If it is less than 0%, the smoothness of the metal will deteriorate.
本発明の処理剤は、タイヤコード、特にポリエステルタ
イヤコードに使用できる。The treatment agent of the present invention can be used for tire cords, especially polyester tire cords.
本発明の処理剤のタイヤコードに対する付着量は、タイ
ヤコードの種類、形態、太さ等で種々変えることが出来
るが、タイヤコードの重量に対して、通常０．１〜５％
、好ましくは、０．２〜３％である。The amount of the treatment agent of the present invention attached to the tire cord can be varied depending on the type, shape, thickness, etc. of the tire cord, but it is usually 0.1 to 5% based on the weight of the tire cord.
, preferably 0.2 to 3%.
処理剤の使用方法は通常と同じでよく、例えば非含水（
原油又は低粘度鉱物油で希釈）の形、又は水で乳化した
エマルシロンの形でローラー給油法、ノズル給油法、ス
プレー給油法及び浸漬給油法等の公知の方法により、タ
イヤコードの製造工程〜仕上げ工程の任意の位置で給油
することができる。The treatment agent can be used in the same way as usual, such as non-hydrous (
From the manufacturing process to the finishing of tire cords, the process is carried out using known methods such as roller lubrication, nozzle lubrication, spray lubrication, and immersion lubrication in the form of emulsilon (diluted with crude oil or low viscosity mineral oil) or emulsified with water. Lubricating can be done at any point in the process.
［実施例コ
以下、実施例及び比較例により本発明を説明するが、本
発明はこれに限定されるものではない。[Examples] The present invention will be explained below with reference to Examples and Comparative Examples, but the present invention is not limited thereto.
実施例１
（本発明の処理剤）
オクチルパルミテート ８０％オレイルオレ
ートの
硫酸化部Ｎａ塩 ２０％
ラウリン酸ジェタノールアミド １０％アルケニルコ
ハク酸 １０％実施例２
（本発明の処理剤）
オクチルパルミテート ３０％ジオレイルア
ジペート ２０％ナタネ油の硫酸化部Ｎａ塩
１５％ラウリン酸ジェタノールアミド
ジオクチルスルホサクシネート
トリラウリルホスフェート
実施例３
（本発明の処理剤）
ジオレイルアジペート
オレイルオレートの
硫酸化部Ｎａ塩
ダイマー酸アミン中和物
ジオクチルスルホサクシネート
イソステアリルホスフェートに塩
実施例４
（本発明の処理剤）
ジオレイルチオジプロピオネート
ナタネ油の硫酸化部Ｎａ塩
オレイン酸ジェタノールアミド
アルケニルコハク酸
ジオクチルスルホサクシネート
インステアリルホスフェートに塩
比較例１
１０％
１０％
１５％
５０％
１５％
２０％
１０％
５％
５０％
１５％
１０％
１０％
１０％
５％
（比較処理剤）
ジオレイルアジペート ６０％オクチルアル
コールＰＯ１ＥＯ
付加物 １０％
ヒマシ油（ＥＯ）２０ ３０％（注）上記
および以下においてＰＯはプロピレンオキサイド、ＥＯ
はエチレンオキサイド（ＥＯ）２０はＥＯ２０モル付加
物を言う。Example 1 (Treatment agent of the present invention) Octyl palmitate 80% Na salt of sulfated part of oleyl oleate 20% Lauric acid jetanolamide 10% Alkenylsuccinic acid 10% Example 2 (Treatment agent of the present invention) Octyl palmitate 30% dioleyl adipate 20% Na salt of sulfated part of rapeseed oil 15% lauric acid jetanolamide dioctyl sulfosuccinate trilauryl phosphate Example 3 (Treatment agent of the present invention) Dioleyl adipate Na salt of sulfated part of oleyl oleate Dimer acid amine neutralized product Dioctylsulfosuccinate Salt to isostearyl phosphate Example 4 (Treatment agent of the present invention) Dioleylthiodipropionate Sulfated portion of rapeseed oil Na salt Oleic acid jetanolamide Alkenyl succinate Dioctylsulfosuccinate Salt in natein stearyl phosphate Comparative Example 1 10% 10% 15% 50% 15% 20% 10% 5% 50% 15% 10% 10% 10% 5% (Comparative treatment agent) Dioleyl adipate 60% octyl alcohol PO1EO Adduct 10% Castor oil (EO) 20 30% (Note) In the above and below, PO is propylene oxide, EO
ethylene oxide (EO) 20 refers to an adduct of 20 moles of EO.
比較例２
（比較処理剤）
ヘキシレングリコールＰＯ１ＥＯ
付加物 ６０％
オクチルアルコールＰＯ，ＥＯ
付加物 ４０％
比較例３
（比較処理剤）
ジオレイルチオジプロピオネート ５０％硬化ヒマシ油
（ＥＯ）２０ ３０％高級アルコール（ＥＯ）
７ ２０％試験例１
ポリエステルタイヤコード糸に実施例１〜４及び比較例
１〜３に示す処理剤を１重量％になるよう給油した。こ
の給油糸について生コード強力、デイツプ後強力を測定
した。この結果を表−１に示す。Comparative example 2 (Comparative treatment agent) Hexylene glycol PO1EO adduct 60% Octyl alcohol PO, EO adduct 40% Comparative example 3 (Comparative treatment agent) Dioleyl thiodipropionate 50% Hydrogenated castor oil (EO) 20 30% Higher alcohol (EO)
7 20% Test Example 1 Polyester tire cord yarn was oiled with the treatment agents shown in Examples 1 to 4 and Comparative Examples 1 to 3 to a concentration of 1% by weight. The raw cord strength and the strength after dipping were measured for this oiled yarn. The results are shown in Table-1.
表−１
生コード、デイツプ後コードの強力の測定ｎ＝２０
試料糸： ポリエステルタイヤ撚糸コード（１５００ｄ
ｅ、 ２８８ｆｌｌ）Ｘ ２の湯洗系処理剤付着量：
１．０重量％
測定装置：島津オートグラフ
（デイツプ条件）
一金工業社製ディップマシン使用
（測定条件）
第一ヒーターゾー７ １５０℃、 １２０秒第二ヒータ
ーゾーン ２４０°Ｃ，９０秒接着剤付着量 ５
％
接着剤： ペクサル／ＲＦＬ液使用
表−１の結果から本発明の処理剤はいずれも比較例に比
べ有意的にデイツプ後強力が高い。Table-1 Measurement of strength of raw cord and cord after dip n = 20 Sample yarn: Polyester tire twisted cord (1500 d
e, 288fl) X 2 hot water cleaning treatment agent adhesion amount:
1.0% by weight Measuring device: Shimadzu Autograph (dip conditions) Use of dip machine manufactured by Ichikin Kogyo Co., Ltd. (measurement conditions) First heater zone 7 150°C, 120 seconds Second heater zone 240°C, 90 seconds Adhesive adhesion Amount 5
% Adhesive: Use of Pexal/RFL liquid From the results in Table 1, all of the processing agents of the present invention have significantly higher strength after dipping than the comparative examples.
「発明の効果コ 本発明の処理剤は、下記効果を奏する。“The effect of invention” The processing agent of the present invention has the following effects.
１）本発明は接着剤処理を施されたポリエステルタイヤ
コードまたは織物の強度低下の防止をするができる。す
なわち、本発明の処理剤は、合成繊維、特にポリエステ
ル繊維でタイヤ補強用コードを製造する場合、コードと
ゴムとの間の接着に必要な接着剤を塗布し、次いでコー
ドを高温下で接着剤を固化させる所謂デイツプ処理後で
もコード強力が大幅に低下する事がない。1) The present invention can prevent a decrease in strength of polyester tire cords or fabrics treated with adhesive. That is, when producing tire reinforcing cords from synthetic fibers, particularly polyester fibers, the processing agent of the present invention applies an adhesive necessary for adhesion between the cord and rubber, and then heats the cords with the adhesive at high temperatures. Even after the so-called dip treatment that solidifies the cord, the strength of the cord does not decrease significantly.
］０６Ｍ １３／４０]06M 13/40
Claims (1)
界面活性剤、カチオン界面活性剤、両性界面活性剤、ス
パン系非イオン界面活性剤およびアミド化合物からなる
群より選ばれる乳化剤と、鉱物油、動植物油、脂肪酸エ
ステルおよびワックスからなる群より選ばれる平滑剤成
分とからなるタイヤコード用処理剤。 ２、該処理剤がポリエステルタイヤコード用処理剤であ
る請求項１記載の処理剤。 ３、処理剤の重量に基づいて、乳化剤成分を２０〜５０
％、平滑剤成分を５０〜８０％含有する請求項１又は２
記載の処理剤。[Claims] 1. Substantially free of ether type surfactants and selected from the group consisting of anionic surfactants, cationic surfactants, amphoteric surfactants, span type nonionic surfactants, and amide compounds. A treatment agent for tire cords, comprising an emulsifying agent such as the above, and a smoothing agent component selected from the group consisting of mineral oils, animal and vegetable oils, fatty acid esters, and waxes. 2. The processing agent according to claim 1, wherein the processing agent is a processing agent for polyester tire cords. 3. Based on the weight of the processing agent, add 20 to 50% of the emulsifier component.
%, containing 50 to 80% of a smoothing agent component.
Treatment agent as described.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP1205089A JPH0367641A (en) | 1989-08-08 | 1989-08-08 | Treatment agent for tire cord |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP1205089A JPH0367641A (en) | 1989-08-08 | 1989-08-08 | Treatment agent for tire cord |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH0367641A true JPH0367641A (en) | 1991-03-22 |
Family
ID=16501247
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP1205089A Pending JPH0367641A (en) | 1989-08-08 | 1989-08-08 | Treatment agent for tire cord |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH0367641A (en) |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5296236A (en) * | 1976-01-30 | 1977-08-12 | Allied Chem | Polyester yarn |
| JPS5610454A (en) * | 1979-07-06 | 1981-02-02 | Bridgestone Tire Co Ltd | Complex consisting of steel cord and rubber and its manufacture |
-
1989
- 1989-08-08 JP JP1205089A patent/JPH0367641A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5296236A (en) * | 1976-01-30 | 1977-08-12 | Allied Chem | Polyester yarn |
| JPS5610454A (en) * | 1979-07-06 | 1981-02-02 | Bridgestone Tire Co Ltd | Complex consisting of steel cord and rubber and its manufacture |
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