JPH0362689B2 - - Google Patents
Info
- Publication number
- JPH0362689B2 JPH0362689B2 JP60213892A JP21389285A JPH0362689B2 JP H0362689 B2 JPH0362689 B2 JP H0362689B2 JP 60213892 A JP60213892 A JP 60213892A JP 21389285 A JP21389285 A JP 21389285A JP H0362689 B2 JPH0362689 B2 JP H0362689B2
- Authority
- JP
- Japan
- Prior art keywords
- weight
- surfactant
- present
- general formula
- following general
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- KWIUHFFTVRNATP-UHFFFAOYSA-N glycine betaine Chemical compound C[N+](C)(C)CC([O-])=O KWIUHFFTVRNATP-UHFFFAOYSA-N 0.000 claims description 20
- 239000000203 mixture Substances 0.000 claims description 17
- 239000004094 surface-active agent Substances 0.000 claims description 17
- 239000002585 base Substances 0.000 claims description 14
- 125000000217 alkyl group Chemical group 0.000 claims description 11
- 150000003839 salts Chemical class 0.000 claims description 11
- 239000003945 anionic surfactant Substances 0.000 claims description 10
- 229960003237 betaine Drugs 0.000 claims description 10
- 239000002280 amphoteric surfactant Substances 0.000 claims description 9
- 125000003342 alkenyl group Chemical group 0.000 claims description 8
- 150000001413 amino acids Chemical class 0.000 claims description 7
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 7
- 239000000194 fatty acid Substances 0.000 claims description 7
- 229930195729 fatty acid Natural products 0.000 claims description 7
- 150000004665 fatty acids Chemical class 0.000 claims description 7
- 125000004432 carbon atom Chemical group C* 0.000 claims description 6
- 150000001412 amines Chemical class 0.000 claims description 5
- 229910052783 alkali metal Inorganic materials 0.000 claims description 3
- 150000001340 alkali metals Chemical class 0.000 claims description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 3
- 239000000126 substance Substances 0.000 description 7
- 239000006260 foam Substances 0.000 description 6
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 5
- 238000001556 precipitation Methods 0.000 description 5
- 230000000052 comparative effect Effects 0.000 description 4
- 238000011156 evaluation Methods 0.000 description 4
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- ZRALSGWEFCBTJO-UHFFFAOYSA-N Guanidine Chemical compound NC(N)=N ZRALSGWEFCBTJO-UHFFFAOYSA-N 0.000 description 2
- WCUXLLCKKVVCTQ-UHFFFAOYSA-M Potassium chloride Chemical compound [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 description 2
- 235000009827 Prunus armeniaca Nutrition 0.000 description 2
- 244000018633 Prunus armeniaca Species 0.000 description 2
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 2
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 238000004140 cleaning Methods 0.000 description 2
- 239000003599 detergent Substances 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000005187 foaming Methods 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- LXCFILQKKLGQFO-UHFFFAOYSA-N methylparaben Chemical compound COC(=O)C1=CC=C(O)C=C1 LXCFILQKKLGQFO-UHFFFAOYSA-N 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 238000011160 research Methods 0.000 description 2
- 229940071089 sarcosinate Drugs 0.000 description 2
- 239000000344 soap Substances 0.000 description 2
- ZUFONQSOSYEWCN-UHFFFAOYSA-M sodium;2-(methylamino)acetate Chemical compound [Na+].CNCC([O-])=O ZUFONQSOSYEWCN-UHFFFAOYSA-M 0.000 description 2
- 238000005406 washing Methods 0.000 description 2
- KIUKXJAPPMFGSW-DNGZLQJQSA-N (2S,3S,4S,5R,6R)-6-[(2S,3R,4R,5S,6R)-3-Acetamido-2-[(2S,3S,4R,5R,6R)-6-[(2R,3R,4R,5S,6R)-3-acetamido-2,5-dihydroxy-6-(hydroxymethyl)oxan-4-yl]oxy-2-carboxy-4,5-dihydroxyoxan-3-yl]oxy-5-hydroxy-6-(hydroxymethyl)oxan-4-yl]oxy-3,4,5-trihydroxyoxane-2-carboxylic acid Chemical compound CC(=O)N[C@H]1[C@H](O)O[C@H](CO)[C@@H](O)[C@@H]1O[C@H]1[C@H](O)[C@@H](O)[C@H](O[C@H]2[C@@H]([C@@H](O[C@H]3[C@@H]([C@@H](O)[C@H](O)[C@H](O3)C(O)=O)O)[C@H](O)[C@@H](CO)O2)NC(C)=O)[C@@H](C(O)=O)O1 KIUKXJAPPMFGSW-DNGZLQJQSA-N 0.000 description 1
- BJEPYKJPYRNKOW-REOHCLBHSA-N (S)-malic acid Chemical compound OC(=O)[C@@H](O)CC(O)=O BJEPYKJPYRNKOW-REOHCLBHSA-N 0.000 description 1
- PSBDWGZCVUAZQS-UHFFFAOYSA-N (dimethylsulfonio)acetate Chemical compound C[S+](C)CC([O-])=O PSBDWGZCVUAZQS-UHFFFAOYSA-N 0.000 description 1
- IIZPXYDJLKNOIY-JXPKJXOSSA-N 1-palmitoyl-2-arachidonoyl-sn-glycero-3-phosphocholine Chemical compound CCCCCCCCCCCCCCCC(=O)OC[C@H](COP([O-])(=O)OCC[N+](C)(C)C)OC(=O)CCC\C=C/C\C=C/C\C=C/C\C=C/CCCCC IIZPXYDJLKNOIY-JXPKJXOSSA-N 0.000 description 1
- BQJLEQAXRYBKPQ-UHFFFAOYSA-N 2-amino-2-methylpropane-1,1-diol Chemical compound CC(C)(N)C(O)O BQJLEQAXRYBKPQ-UHFFFAOYSA-N 0.000 description 1
- XMTCKNXTTXDPJX-UHFFFAOYSA-N 3-oxoalanine Chemical compound O=CC(N)C(O)=O XMTCKNXTTXDPJX-UHFFFAOYSA-N 0.000 description 1
- ODHCTXKNWHHXJC-VKHMYHEASA-N 5-oxo-L-proline Chemical compound OC(=O)[C@@H]1CCC(=O)N1 ODHCTXKNWHHXJC-VKHMYHEASA-N 0.000 description 1
- 241001116389 Aloe Species 0.000 description 1
- 239000004475 Arginine Substances 0.000 description 1
- 239000005711 Benzoic acid Substances 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 229920002134 Carboxymethyl cellulose Polymers 0.000 description 1
- 235000017788 Cydonia oblonga Nutrition 0.000 description 1
- KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 description 1
- ODKSFYDXXFIFQN-BYPYZUCNSA-P L-argininium(2+) Chemical compound NC(=[NH2+])NCCC[C@H]([NH3+])C(O)=O ODKSFYDXXFIFQN-BYPYZUCNSA-P 0.000 description 1
- KDXKERNSBIXSRK-YFKPBYRVSA-N L-lysine Chemical compound NCCCC[C@H](N)C(O)=O KDXKERNSBIXSRK-YFKPBYRVSA-N 0.000 description 1
- KDXKERNSBIXSRK-UHFFFAOYSA-N Lysine Natural products NCCCCC(N)C(O)=O KDXKERNSBIXSRK-UHFFFAOYSA-N 0.000 description 1
- 239000004472 Lysine Substances 0.000 description 1
- CHJJGSNFBQVOTG-UHFFFAOYSA-N N-methyl-guanidine Natural products CNC(N)=N CHJJGSNFBQVOTG-UHFFFAOYSA-N 0.000 description 1
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 1
- 229920001218 Pullulan Polymers 0.000 description 1
- 239000004373 Pullulan Substances 0.000 description 1
- 229920002125 Sokalan® Polymers 0.000 description 1
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- QNAYBMKLOCPYGJ-UHFFFAOYSA-M alaninate Chemical compound CC(N)C([O-])=O QNAYBMKLOCPYGJ-UHFFFAOYSA-M 0.000 description 1
- 235000011399 aloe vera Nutrition 0.000 description 1
- BJEPYKJPYRNKOW-UHFFFAOYSA-N alpha-hydroxysuccinic acid Natural products OC(=O)C(O)CC(O)=O BJEPYKJPYRNKOW-UHFFFAOYSA-N 0.000 description 1
- 229940009868 aluminum magnesium silicate Drugs 0.000 description 1
- WMGSQTMJHBYJMQ-UHFFFAOYSA-N aluminum;magnesium;silicate Chemical compound [Mg+2].[Al+3].[O-][Si]([O-])([O-])[O-] WMGSQTMJHBYJMQ-UHFFFAOYSA-N 0.000 description 1
- CBTVGIZVANVGBH-UHFFFAOYSA-N aminomethyl propanol Chemical compound CC(C)(N)CO CBTVGIZVANVGBH-UHFFFAOYSA-N 0.000 description 1
- ODKSFYDXXFIFQN-UHFFFAOYSA-N arginine Natural products OC(=O)C(N)CCCNC(N)=N ODKSFYDXXFIFQN-UHFFFAOYSA-N 0.000 description 1
- 235000010233 benzoic acid Nutrition 0.000 description 1
- 150000001721 carbon Chemical group 0.000 description 1
- 239000001768 carboxy methyl cellulose Substances 0.000 description 1
- 235000010948 carboxy methyl cellulose Nutrition 0.000 description 1
- 239000008112 carboxymethyl-cellulose Substances 0.000 description 1
- 229920006317 cationic polymer Polymers 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 239000006071 cream Substances 0.000 description 1
- SWSQBOPZIKWTGO-UHFFFAOYSA-N dimethylaminoamidine Natural products CN(C)C(N)=N SWSQBOPZIKWTGO-UHFFFAOYSA-N 0.000 description 1
- 239000003792 electrolyte Substances 0.000 description 1
- 239000000284 extract Substances 0.000 description 1
- 239000003205 fragrance Substances 0.000 description 1
- 239000000499 gel Substances 0.000 description 1
- 229930182478 glucoside Natural products 0.000 description 1
- 150000008131 glucosides Chemical class 0.000 description 1
- 239000008233 hard water Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 229920002674 hyaluronan Polymers 0.000 description 1
- 229960003160 hyaluronic acid Drugs 0.000 description 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 1
- MTNDZQHUAFNZQY-UHFFFAOYSA-N imidazoline Chemical compound C1CN=CN1 MTNDZQHUAFNZQY-UHFFFAOYSA-N 0.000 description 1
- 239000000787 lecithin Substances 0.000 description 1
- 235000010445 lecithin Nutrition 0.000 description 1
- 229940067606 lecithin Drugs 0.000 description 1
- 239000002075 main ingredient Substances 0.000 description 1
- 239000001630 malic acid Substances 0.000 description 1
- 235000011090 malic acid Nutrition 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 239000004292 methyl p-hydroxybenzoate Substances 0.000 description 1
- 235000010270 methyl p-hydroxybenzoate Nutrition 0.000 description 1
- 229960002216 methylparaben Drugs 0.000 description 1
- 230000003020 moisturizing effect Effects 0.000 description 1
- 235000011837 pasties Nutrition 0.000 description 1
- -1 polyoxyethylene Polymers 0.000 description 1
- 239000001103 potassium chloride Substances 0.000 description 1
- 235000011164 potassium chloride Nutrition 0.000 description 1
- 239000003755 preservative agent Substances 0.000 description 1
- 235000019423 pullulan Nutrition 0.000 description 1
- 229940079889 pyrrolidonecarboxylic acid Drugs 0.000 description 1
- 239000001397 quillaja saponaria molina bark Substances 0.000 description 1
- 229930182490 saponin Natural products 0.000 description 1
- 150000007949 saponins Chemical class 0.000 description 1
- 235000017709 saponins Nutrition 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 239000002453 shampoo Substances 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- 229940045920 sodium pyrrolidone carboxylate Drugs 0.000 description 1
- IWIUXJGIDSGWDN-UQKRIMTDSA-M sodium;(2s)-2-(dodecanoylamino)pentanedioate;hydron Chemical compound [Na+].CCCCCCCCCCCC(=O)N[C@H](C([O-])=O)CCC(O)=O IWIUXJGIDSGWDN-UQKRIMTDSA-M 0.000 description 1
- HYRLWUFWDYFEES-UHFFFAOYSA-M sodium;2-oxopyrrolidine-1-carboxylate Chemical compound [Na+].[O-]C(=O)N1CCCC1=O HYRLWUFWDYFEES-UHFFFAOYSA-M 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 150000005846 sugar alcohols Polymers 0.000 description 1
- 229940117986 sulfobetaine Drugs 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 229920003169 water-soluble polymer Polymers 0.000 description 1
Description
［産業上の利用分野］
本発明は、新規な身体用洗浄剤組成物に関する
ものである。更に詳しくは、ぬめり感がなく、安
定性良好なゲル状の身体用洗浄剤組成物に関す
る。
［従来の技術］
身体用の洗浄剤組成物としては、従来より、石
鹸やＮ−アシルグルタミン酸塩を主成分とする固
状、ペースト状、ゲル状、クリーム状、液状等の
各洗浄剤組成物が知られている。しかしながらこ
れらの製品群は、洗浄力、及び洗浄後のすすぎ易
さという点においては、満足できるが、泡立ち、
泡質の点においては十分満足できるものではなか
つた。ここで言うすすぎ易さとは、洗浄後の皮膚
がぬるぬる感じるような、ぬめり感がない事を意
味する。一方、シヤンプー等の洗浄剤基剤として
用いられるサルフエート系の界面活性剤は、泡立
ちが早く、軽い泡質という特徴が有るものの、同
じアニオン界面活性剤でありながら、ぬめり感が
強く、頭髪の洗浄には適しているが、身体用とし
ての使用感は悪く、主剤として用いられる事はな
かつた。また同じ理由により、ベタイン系界面活
性剤も、主基剤として、身体用洗浄剤組成物に用
いられる事は稀である。従つて、これらのサルフ
エート系アニオン界面活性剤、及びベタイン系界
面活性剤は、特定の組合せ領域にて増粘ゲル化す
る事が、特開昭60−141797『ゲル状組成物』によ
り知られているが、硬水中での良好な泡立ち、及
び軽い泡質という特徴を有しながらも、身体用洗
浄剤組成物としては、その特徴的なぬめり感によ
り、主基剤としての使用は、好ましくないもので
あるのが現状である。
［発明が解決しようとする問題点］
本発明者らはこうした事情にかんがみ、サルフ
エート系アニオン界面活性剤及びベタイン系界面
活性剤の特定の組合せ領域にて生成するゲル状組
成物に対し、ぬめり感を改良し、すすぎ易くし、
且つ低温で析出等の不都合の生じない安定性良好
な、身体用洗浄剤組成物を得るべく鋭意研究を重
ねた結果、特定のアニオン界面活性剤と、ベタイ
ン系界面活性剤を特定の比率で組合せた界面活性
剤ベースに対し、アミノ酸系界面活性剤及び高級
脂肪酸弱塩基塩を加える事により上記問題を解決
し得る事を見出し、この知見に基づいて、本発明
を完成するに至つた。
［問題点を解決するための手段］
即ち、本発明は、（）下記一般式(A)
R1O（CH2CH2）aSO3M ……(A)
（式中、Ｒは平均炭素原子数８〜20のアルキル基
又はアルケニル基、Ｍはアルカリ金属又は有機ア
ミン類を表す。ａは０〜３の数を表す。）で表さ
れるアニオン界面活性剤の一種又は二種以上２〜
20重量％と（）ベタイン系両性界面活性剤の一
種又は二種以上３〜25重量％と（）アミノ酸系
界面活性剤と（）高級脂肪酸弱塩基塩および
（）水とからなり（）：（）のモル比が１：
10〜４：１であり、（）＋（）が４〜20重量％
である組成物を配合してなる粘度（cps）800〜
55000の身体用洗浄剤組成物。
以下、本発明の構成について詳述する。
本発明で用いられる下記一般式(A)で表されるア
ニオン界面活性剤は一般にはサルフエート系アニ
オン界面活性剤と呼ばれる。
式中、R1は平均炭素原子数８〜20のアルキル
又はアルケニル基、Ｍはアルカリ金属又は有機ア
ミン類を表し、ａは０〜３の整数である。
該アニオン界面活性剤を市販で求めるならば、
東邦化学製のSP−40、AP−30、TA−40などが
ある。
本発明においては、これらのうちから一種又は
二種以上が任意に選ばれて用いられる。
R1O（CH2CH2）aSO3M ……
本発明で用いられるベタイン系両性界面活性剤
としては、下記一般式(B)
で表されるアミドベタイン型両性界面活性剤［市
販としてはレボン2000（三洋化成）、アノンBDF
（日本油脂）などがある］、あるいは下記一般式(C)
で表されるアミドスルフオベタイン型両性界面活
性剤［市販としてはロンザイン−CS（ロンザ）、
ミラタインCBS（ミラノール）などがある］、
あるいは下記一般式(D)
で表されるベタイン型両性界面活性剤［市販とし
てはアノンBL（日本油脂）、デハイトンAB−30
（ヘンケル）などがある］、あるいは下記一般式(E)
で表されるスルフオベタイン型両性界面活性剤
［市販としてはロンザイン12CS（ロンザ）などが
ある］、あるいは下記一般式(F)
で表されるイミダゾリニウム型両性界面活性剤
［市販としてはオバゾリン662−Ｎ（東邦化学）ア
ノンGLM（日本油脂）などがある］
｛(B)〜(F)の式中、R2は平均炭素原子数９〜17の
アルキル基又はアルケニル基、R3は平均炭素原
子数10〜18のアルキル基又はアルケニル基であ
る。ｘは２〜４の整数であり、ｙは０〜３の整数
であり、ｚは１〜２の整数である。｝で表される
界面活性剤をあげることができ、これらのうちか
ら一種又は二種以上を任意に用いることができ
る。
配合量は、（）アニオン界面活性剤が界面活
性剤ベース全量中の２〜20重量％、（）ベタイ
ン系両性界面活性剤が界面活性剤ベース全量中の
３〜25重量％で、（）：（）のモル比が１：10
〜４：１の範囲である。モル比が上記の範囲を逸
脱するときは充分な粘度が得られない。また、
（）が２重量％未満あるいは（）が３重量％
未満のときは同様に充分な粘度が得られず、逆に
（）が20重量％を越えるかあるいは（）が25
重量％を越えた場合はペースト状の不均一物とな
つてしまう。
本発明に用いるアミノ酸系界面活性剤として
は、下記一般式(G)
で表されるｎ−アシルグルタミン酸塩［市販品と
してはアミソフトLS−11、アミソフトCT−
12（味の素）などがある。］、あるいは下記一般式
(H)又は(I)
で表される、Ｎ−アシル、Ｎ−アルキルアミノ酸
塩［(H)の市販品としては、サルコシネートLN−
30、サルコシネートLT−30（日光ケミカル）、ソ
イポンSLE（川研フアインケミカル）などがあ
る。］
［(I)の市販品としては、アラニネートLT−30
（日光ケミカル）、アラノンALE（川研フアインケ
ミカル）などがある。］
であり、これらの中から、一種又は二種以上を任
意に用いる事ができる。(G)の式中Ｒは平均炭素原
子数８〜20のアルキル基又はアルケニル基、Ｍは
アルキル金属又は有機アミン類又は水素原子を表
し、モノ塩が好ましく、(H)、(I)の式中Ｒは平均炭
素原子数８〜20のアルキル基又はアルケニル基、
Ｍは、アルキル金属又は有機アミン類を表す。ま
た、本発明で用いる高級脂肪酸弱塩基塩として
は、下記一般式(J)
RCOOM ……(J)
で表すことができ、弱塩基としては、トリエタノ
ンールアミン、２−アミノ−２−メチルプロパノ
ール、２−アミノ−２−メチルプロパンジオー
ル、リジン、アルギニン、グアニジン等が例示で
きる。(J)の式中Ｒは平均炭素原子数８〜20のアル
キル基又はアルケニル基を表す。本発明において
は、これらのうちから一種又は二種以上を任意に
用いる事ができる。
本発明のアミノ酸系界面活性剤及び高級脂肪酸
弱塩基塩の配合量は４〜20重量％である。アミノ
酸系界面活性剤及び高級脂肪酸弱塩基塩が４％未
満であるとき、ぬめり感改善効果が十分ではな
く、20％をこえると、ゲル状又は、ペースト状を
保つ事が難しく、粘度が200cps未満となり、且
つ、低温で析出等の不都合を生じ、低温安定性が
不良となつてしまう。
本発明の身体用洗浄剤組成物の粘度は、800〜
55000cpsである。800cps未満では液状で、使用中
にすぐに流れてしまい、身体用洗浄剤としては好
ましくない。また、55000cpsを超えると、ぬめり
感を生じ、さらにペースト状に近い状態になるた
め、使用性が好ましくない。
本発明の身体用洗浄剤組成物の製造にはとくに
制限はなく、各配合成分を順不同に加えればよ
い。
本発明の身体用洗浄剤組成物には、上記の必須
構成成分に加えて必要に応じて、さらにPHコント
ロール成分としての酸やアルカリなど、また
EDTAおよびその塩、リンゴ酸及びその塩や防
腐剤として、メチルパラベン、安息香酸及びその
塩などを配合する事ができる。
その他の添加剤としては、プルラン、カルボキ
メチルセルロース、カルボキシビニルポリマー、
カチオン性ポリマー、ケイ酸アルミニウムマグネ
シウムシリケート等の水溶性高分子、多価アルコ
ール、ピロリドンカルボン酸、ピロリドンカルボ
ン酸ナトリウム、ヒアルロン酸、ポリオキシエチ
レンアルキルグルコシドエーテル等の保湿剤、レ
シチン、サポニン、アロエ、マルメロ、オウバ
ク、杏仁等の天然抽出物、塩化ナトリウム、塩化
カリウム、クエン酸、等の電解質、香料、色剤を
含ませることができる。
もちろんこれらは、本発明の目的を損なわない
質的、量的条件下で使用されなければならない。
［実施例］
次に実施例によつて本発明をさらに詳細に説明
する。本発明はこれにより限定されるものではな
い。配合量は重量％である。また、効果の判定は
以下の試験法、評価法によつた。
(1) すすぎ易さ
パネル10名に、35℃の温水で、洗顔試験を行
わせ、比較例１の資料と比較して、すすぎ易い
＋２、ややすすぎ易い＋１、同等０、ややすす
ぎにくい−１、すすぎにくい−２と、評価点数
をつけた。10名の評価の合計点に従つて、次の
ように判定した。
20〜11……◎
10〜１……○
０〜−20×……
(2) 安定性
低温（−５℃、１ケ月）で、析出、分離等の
不都合が生じない事。
安定……○
やや析出……△
析出……×
(3) 粘度
単一円筒型回転粘度計（精機工業研究所製）
を用いて、30℃で測定した。
実施例１〜７，比較例１
[Industrial Field of Application] The present invention relates to a novel body cleansing composition. More specifically, the present invention relates to a gel-like body cleansing composition that does not have a slimy feel and has good stability. [Prior Art] As body cleansing compositions, various cleansing compositions such as solid, pasty, gel, cream, and liquid containing soap or N-acylglutamate as a main component have conventionally been used. It has been known. However, although these product groups are satisfactory in terms of cleaning power and ease of rinsing after cleaning, they do not foam,
The foam quality was not completely satisfactory. Ease of rinsing here means that there is no slimy feeling, such as when the skin feels slimy after washing. On the other hand, sulfate-based surfactants, which are used as bases for detergents such as shampoo, have the characteristics of quick foaming and light foam, but although they are also anionic surfactants, they have a strong slimy feel and are difficult to wash hair. Although it was suitable for use in the body, it did not feel good when used on the body and was never used as a main ingredient. For the same reason, betaine surfactants are also rarely used as the main base in body cleansing compositions. Therefore, it is known from JP-A-60-141797 "Gel Composition" that these sulfate-based anionic surfactants and betaine-based surfactants thicken and gel in a specific combination region. However, although it has the characteristics of good foaming in hard water and light foam quality, it is not preferable to use it as the main base for body cleansing compositions due to its characteristic slimy feel. The current situation is that it is a thing. [Problems to be Solved by the Invention] In view of these circumstances, the present inventors have developed a gel-like composition produced in a specific combination region of a sulfate-based anionic surfactant and a betaine-based surfactant that has a slimy feel. improved, easier to rinse,
As a result of extensive research in order to obtain a body cleansing composition that is stable and does not cause problems such as precipitation at low temperatures, we have found a combination of a specific anionic surfactant and a betaine surfactant in a specific ratio. The inventors have discovered that the above problems can be solved by adding an amino acid surfactant and a weak base salt of a higher fatty acid to the surfactant base, and based on this knowledge, they have completed the present invention. [Means for Solving the Problems] That is, the present invention has the following general formula (A) R 1 O (CH 2 CH 2 ) aSO 3 M ... (A) (wherein, R is an average carbon atom 1 or 2 or more anionic surfactants represented by 8 to 20 alkyl or alkenyl groups, M represents an alkali metal or organic amines, and a represents a number from 0 to 3.
20% by weight, () 3-25% by weight of one or more betaine-based amphoteric surfactants, () amino acid-based surfactant, () higher fatty acid weak base salt, and () water ():( ) molar ratio is 1:
The ratio is 10 to 4:1, and () + () is 4 to 20% by weight.
Viscosity (cps) of 800~
55000 body cleansing compositions. Hereinafter, the configuration of the present invention will be explained in detail. The anionic surfactant represented by the following general formula (A) used in the present invention is generally called a sulfate-based anionic surfactant. In the formula, R 1 represents an alkyl or alkenyl group having an average carbon number of 8 to 20, M represents an alkali metal or an organic amine, and a is an integer of 0 to 3. If you want the anionic surfactant commercially,
There are SP-40, AP-30, and TA-40 manufactured by Toho Chemical. In the present invention, one or more of these may be arbitrarily selected and used. R 1 O(CH 2 CH 2 )aSO 3 M... The betaine amphoteric surfactant used in the present invention has the following general formula (B): Amidobetaine type amphoteric surfactant represented by
(NOF)], or the following general formula (C) Amidosulfobetaine type amphoteric surfactant represented by [commercially available Lonzyne-CS (Lonza),
Milatine CBS (Milanor), etc.],
Or the following general formula (D) Betaine type amphoteric surfactant represented by
(Henkel)] or the following general formula (E) A sulfobetaine type amphoteric surfactant represented by [commercially available products include Lonzyne 12CS (Lonza)], or the following general formula (F) Imidazolinium type amphoteric surfactant represented by [Commercially available products include Obazoline 662-N (Toho Chemical), Anon GLM (Nippon Oil & Fats Co., Ltd.)] {In the formulas (B) to (F), R 2 is the average The alkyl group or alkenyl group having 9 to 17 carbon atoms, R 3 is an alkyl group or alkenyl group having an average number of 10 to 18 carbon atoms. x is an integer of 2 to 4, y is an integer of 0 to 3, and z is an integer of 1 to 2. }, and one or more of these may be used arbitrarily. The amount of the anionic surfactant is 2 to 20% by weight of the total surfactant base, () the betaine amphoteric surfactant is 3 to 25% by weight of the total surfactant base, and (): The molar ratio of () is 1:10
~4:1 range. When the molar ratio is outside the above range, sufficient viscosity cannot be obtained. Also,
() is less than 2% by weight or () is 3% by weight
Similarly, if it is less than 25%, sufficient viscosity cannot be obtained, and conversely, if () exceeds 20% by weight or ()
If it exceeds the weight percentage, it will become a paste-like non-uniform substance. The amino acid surfactant used in the present invention has the following general formula (G): n-acylglutamate represented by [commercially available products are Amisoft LS-11 and Amisoft CT-
12 (Ajinomoto), etc. ], or the following general formula
(H) or (I) N-acyl, N-alkyl amino acid salt [(H) is commercially available, such as sarcosinate LN-
30, Sarcosinate LT-30 (Nikko Chemical), and Soipon SLE (Kawaken Huain Chemical). ] [Alaninate LT-30 is a commercially available product of (I)
(Nikko Chemical) and Alanon ALE (Kawaken Huain Chemical). ] Among these, one or more types can be arbitrarily used. In the formula (G), R represents an alkyl group or alkenyl group having an average number of carbon atoms of 8 to 20, M represents an alkyl metal, an organic amine, or a hydrogen atom, and a monosalt is preferable; R is an alkyl group or alkenyl group having an average number of carbon atoms of 8 to 20,
M represents an alkyl metal or an organic amine. Further, the higher fatty acid weak base salt used in the present invention can be represented by the following general formula (J) RCOOM ... (J), and the weak base includes triethanolamine, 2-amino-2-methylpropanol , 2-amino-2-methylpropanediol, lysine, arginine, guanidine and the like. In the formula (J), R represents an alkyl group or an alkenyl group having an average number of carbon atoms of 8 to 20. In the present invention, one or more of these can be arbitrarily used. The blending amount of the amino acid surfactant and higher fatty acid weak base salt of the present invention is 4 to 20% by weight. When the amino acid surfactant and higher fatty acid weak base salt is less than 4%, the sliminess improvement effect is not sufficient, and when it exceeds 20%, it is difficult to maintain gel or paste form, and the viscosity is less than 200 cps. Moreover, problems such as precipitation occur at low temperatures, resulting in poor low-temperature stability. The viscosity of the body cleansing composition of the present invention is 800~
It is 55000cps. If it is less than 800 cps, it will be liquid and will flow easily during use, making it undesirable as a body cleansing agent. Moreover, if it exceeds 55,000 cps, it will feel slimy and will become more like a paste, making it unfavorable for usability. There are no particular restrictions on the production of the body cleansing composition of the present invention, and each component may be added in random order. In addition to the above-mentioned essential components, the body cleansing composition of the present invention may further contain acids, alkalis, etc. as PH control components, if necessary.
EDTA and its salts, malic acid and its salts, and preservatives such as methylparaben and benzoic acid and its salts can be blended. Other additives include pullulan, carboxymethylcellulose, carboxyvinyl polymer,
Cationic polymers, water-soluble polymers such as aluminum magnesium silicate, polyhydric alcohols, pyrrolidone carboxylic acid, sodium pyrrolidone carboxylate, hyaluronic acid, moisturizing agents such as polyoxyethylene alkyl glucoside ether, lecithin, saponin, aloe, quince , natural extracts such as apricot root, apricot kernel, electrolytes such as sodium chloride, potassium chloride, citric acid, fragrances, and coloring agents. Of course, these must be used under qualitative and quantitative conditions that do not impair the purpose of the present invention. [Example] Next, the present invention will be explained in more detail with reference to Examples. The present invention is not limited thereby. The blending amount is in weight%. In addition, the evaluation of effectiveness was based on the following test methods and evaluation methods. (1) Ease of rinsing A panel of 10 people conducted a face washing test with warm water at 35℃, and compared to the data from Comparative Example 1, the results were as follows: Easy to rinse +2, easy to rinse +1, same 0, easy to rinse -1 It was given an evaluation score of -2 for being difficult to rinse. Judgments were made as follows based on the total score of the 10 evaluations. 20～11...◎ 10～1...○ 0～-20×... (2) Stability No problems such as precipitation or separation will occur at low temperatures (-5℃, 1 month). Stable...○ Slight precipitation...△ Precipitation...× (3) Viscosity Single cylindrical rotational viscometer (manufactured by Seiki Kogyo Research Institute)
Measurements were made at 30°C using Examples 1 to 7, Comparative Example 1
【表】 実施例８〜10，比較例２〜５【table】 Examples 8-10, Comparative Examples 2-5
【表】【table】
【表】 実施例11〜17，比較例６〜９【table】 Examples 11-17, Comparative Examples 6-9
【表】
［発明の効果］
本発明にあつては、泡立ちが早く、その泡質が
軽いサルフエート系界面活性剤と、ベタイン系界
面活性剤を用いて、特定の組合せ領域にて生成す
るゲルを応用し、その特徴を損なう事なく、ぬめ
り感の観点から従来頭髪用のみであつた用途を、
アミノ酸系界面活性剤及び高級脂肪酸弱塩基塩石
鹸を組み合わす事により、ぬめり感を改善した身
体用洗浄剤組成物を得る事ができた。
具備すべき性能として、皮膚安全性、洗浄力、
泡立ちも良好であつた。
さらに、本発明の身体用洗浄剤組成物は特別な
設備や、加熱、冷却などの工程が不要で、簡単な
撹拌操作のみによつて製造が可能であり、その点
でも優れた組成物という事ができる。[Table] [Effects of the Invention] The present invention uses a sulfate surfactant that foams quickly and has a light foam quality, and a betaine surfactant to form a gel in a specific combination area. We have applied this product to a product that was previously only used for hair due to its slimy feel, without sacrificing its characteristics.
By combining an amino acid surfactant and a higher fatty acid weak base salt soap, it was possible to obtain a body cleansing composition with improved sliminess. Performances that should be achieved include skin safety, detergency,
It also foamed well. Furthermore, the body cleansing composition of the present invention does not require any special equipment or processes such as heating or cooling, and can be manufactured by only a simple stirring operation, and is an excellent composition in that respect as well. I can do it.
Claims (1)
又はアルケニル基、Ｍはアルカリ金属又は有機ア
ミン類を表す。ａは０〜３の数を表す。）で表さ
れるアニオン界面活性剤の一種又は二種以上２〜
20重量％と（）ベタイン系両性界面活性剤の一
種又は二種以上３〜25重量％と（）アミノ酸系
界面活性剤と（）高級脂肪酸弱塩基塩および
（）水とからなり（）：（）のモル比が１：
10〜４：１であり、（）＋（）が４〜20重量％
である組成物を配合してなる粘度（cps）800〜
55000の身体用洗浄剤組成物。[Claims] 1 () The following general formula (A) R 1 O (CH 2 CH 2 )aSO 3 M ... (A) (wherein R is an alkyl group or alkenyl having an average number of carbon atoms of 8 to 20 group, M represents an alkali metal or an organic amine; a represents a number from 0 to 3.) One or more anionic surfactants represented by
20% by weight, () 3-25% by weight of one or more betaine-based amphoteric surfactants, () amino acid-based surfactant, () higher fatty acid weak base salt, and () water ():( ) molar ratio is 1:
The ratio is 10 to 4:1, and () + () is 4 to 20% by weight.
Viscosity (cps) of 800~
55000 body cleansing compositions.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP21389285A JPS6272796A (en) | 1985-09-27 | 1985-09-27 | Detergent composition for human body |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP21389285A JPS6272796A (en) | 1985-09-27 | 1985-09-27 | Detergent composition for human body |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS6272796A JPS6272796A (en) | 1987-04-03 |
| JPH0362689B2 true JPH0362689B2 (en) | 1991-09-26 |
Family
ID=16646740
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP21389285A Granted JPS6272796A (en) | 1985-09-27 | 1985-09-27 | Detergent composition for human body |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS6272796A (en) |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2775154B2 (en) * | 1988-04-26 | 1998-07-16 | 株式会社資生堂 | Anti-skin and anti-aging agents |
| BR9307795A (en) * | 1992-12-28 | 1995-11-21 | Procter & Gamble | Clear detergent gels |
| JP2006306908A (en) * | 2005-04-26 | 2006-11-09 | Nof Corp | Detergent composition |
| JP2015113355A (en) * | 2013-12-09 | 2015-06-22 | 松本油脂製薬株式会社 | Detergent composition |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS51121533A (en) * | 1975-04-17 | 1976-10-23 | Dai Ichi Kogyo Seiyaku Co Ltd | Toiletry for washing use |
| JPS5515110A (en) * | 1978-07-15 | 1980-02-02 | Toyo Contact Lens Co Ltd | Contact lens |
| JPS60132912A (en) * | 1983-12-21 | 1985-07-16 | Kao Corp | Shampoo composition |
-
1985
- 1985-09-27 JP JP21389285A patent/JPS6272796A/en active Granted
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS51121533A (en) * | 1975-04-17 | 1976-10-23 | Dai Ichi Kogyo Seiyaku Co Ltd | Toiletry for washing use |
| JPS5515110A (en) * | 1978-07-15 | 1980-02-02 | Toyo Contact Lens Co Ltd | Contact lens |
| JPS60132912A (en) * | 1983-12-21 | 1985-07-16 | Kao Corp | Shampoo composition |
Also Published As
| Publication number | Publication date |
|---|---|
| JPS6272796A (en) | 1987-04-03 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| JPH0470282B2 (en) | ||
| JPS6044600A (en) | Transparent liquid shower soap | |
| JP3908420B2 (en) | Cleaning composition | |
| JPH0461914B2 (en) | ||
| WO1995008615A1 (en) | Detergent composition | |
| JP2004002632A (en) | Detergent composition | |
| JPH0362689B2 (en) | ||
| JPH02218797A (en) | Detergent composition having low irritation | |
| WO2004029190A1 (en) | Novel surfactant and use thereof | |
| JP4636484B2 (en) | Cleaning composition | |
| JP4118482B2 (en) | Gel skin cleanser composition | |
| JP5191026B2 (en) | Cleaning composition | |
| US3975313A (en) | Solid amphoteric skin cleanser | |
| JP4181767B2 (en) | Liquid detergent composition | |
| JP2003336091A (en) | Detergent composition | |
| JP2018070825A (en) | Detergent composition | |
| JP2979285B2 (en) | Detergent composition | |
| JP2876173B2 (en) | Detergent composition | |
| JP6642828B2 (en) | Creamy cleaning fee | |
| JP2002161028A (en) | Composition for cleaning agent | |
| CN116098821B (en) | Cleaning composition containing surfactant system and application thereof | |
| JP3453646B2 (en) | Shampoo composition | |
| JP2002154947A (en) | Liquid body cleanser composition | |
| JP3770184B2 (en) | Hair cleaning composition | |
| JP4049485B2 (en) | Moisturizer |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| LAPS | Cancellation because of no payment of annual fees |