JPH0361740B2 - - Google Patents
Info
- Publication number
- JPH0361740B2 JPH0361740B2 JP59032893A JP3289384A JPH0361740B2 JP H0361740 B2 JPH0361740 B2 JP H0361740B2 JP 59032893 A JP59032893 A JP 59032893A JP 3289384 A JP3289384 A JP 3289384A JP H0361740 B2 JPH0361740 B2 JP H0361740B2
- Authority
- JP
- Japan
- Prior art keywords
- golden
- decorative
- alloy
- precious metals
- colored
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 229910000881 Cu alloy Inorganic materials 0.000 claims description 12
- 239000010970 precious metal Substances 0.000 claims description 9
- 239000010949 copper Substances 0.000 claims description 7
- 239000011572 manganese Substances 0.000 claims description 6
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 3
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 claims description 3
- 229910052802 copper Inorganic materials 0.000 claims description 3
- 229910052748 manganese Inorganic materials 0.000 claims description 3
- 229910052782 aluminium Inorganic materials 0.000 claims description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 2
- 239000000956 alloy Substances 0.000 description 9
- 229910045601 alloy Inorganic materials 0.000 description 8
- 238000005260 corrosion Methods 0.000 description 6
- 230000007797 corrosion Effects 0.000 description 6
- 241000784726 Lycaena thetis Species 0.000 description 4
- 210000004243 sweat Anatomy 0.000 description 4
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- 229910001020 Au alloy Inorganic materials 0.000 description 2
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 2
- 239000003353 gold alloy Substances 0.000 description 2
- JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- FFRBMBIXVSCUFS-UHFFFAOYSA-N 2,4-dinitro-1-naphthol Chemical compound C1=CC=C2C(O)=C([N+]([O-])=O)C=C([N+]([O-])=O)C2=C1 FFRBMBIXVSCUFS-UHFFFAOYSA-N 0.000 description 1
- 229910001369 Brass Inorganic materials 0.000 description 1
- 229910017767 Cu—Al Inorganic materials 0.000 description 1
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 1
- 238000005275 alloying Methods 0.000 description 1
- 239000010951 brass Substances 0.000 description 1
- 239000004202 carbamide Substances 0.000 description 1
- 239000010931 gold Substances 0.000 description 1
- 238000007654 immersion Methods 0.000 description 1
- 230000003993 interaction Effects 0.000 description 1
- 229910000765 intermetallic Inorganic materials 0.000 description 1
- 229910052741 iridium Inorganic materials 0.000 description 1
- 239000004310 lactic acid Substances 0.000 description 1
- 235000014655 lactic acid Nutrition 0.000 description 1
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 229910052762 osmium Inorganic materials 0.000 description 1
- 229910052763 palladium Inorganic materials 0.000 description 1
- 229910052697 platinum Inorganic materials 0.000 description 1
- 229910052703 rhodium Inorganic materials 0.000 description 1
- 229910052707 ruthenium Inorganic materials 0.000 description 1
- 229910052709 silver Inorganic materials 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- 238000009864 tensile test Methods 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
Landscapes
- Preventing Corrosion Or Incrustation Of Metals (AREA)
- Adornments (AREA)
Description
本発明は、装飾用金合金の代用として用いられ
る黄金色系銅合金に関するものである。
近年の省資源化に伴い、装飾用金合金の代用と
して黄金色系合金材料が要求されている。
一般に装飾品に於いては、耐食性、機械的性質
が良好であることが具備条件の一つとされてい
る。更には、これ等の装飾品は装飾性の面から、
複雑な加工が施される為、その加工が容易である
こと、さらにその色が黄金色に近いことも併せて
要求されている。
ところで、装飾用黄金色系材料として用いられ
ている合金としてはZn30wt％、残部Cuより成る
黄銅合金があるが、この合金は耐食性、機械的性
質が悪く、複雑な形状に加工しづらいという欠点
があつた。
本発明は、上記の欠点を解消せんが為になされ
たものであり、銅系合金で耐食性、加工性、機械
的性質に優れ、かつ黄金色を有する装飾用黄金色
系銅合金を提供せんとするものである。
本発明による装飾用黄金色系銅合金はA12.5〜
10wt％、Mn0.1〜7wt％、貴金属0.1〜1.8wt％、
残部Cuより成りMnと貴金属の合計が2wt％以上
である合金である。
本発明による装飾用黄金色系銅合金に於いて、
Alを添加した理由は、AlはCuと合金を作つた際
に表面に安定な酸化被膜を作り、耐食性を向上す
ると共に、黄金色の合金が得られる為であり、
2.5wt％未満ではその効果が薄く、10wt％を超え
ると金属間化合物を作り、薄板に加工することが
困難になる為である。
また、Mnを添加した理由は、MnはCuと合金
することにより耐食性を向上すると共に、引張り
強さ、硬さ、伸びを大きくする為であり、0.1wt
％未満ではその効果が薄く、7wt％を超えると加
工性が著しく低下してくる為である。
また、貴金属を添加した理由は、貴金属の微量
添加によりCu−Al合金の耐食性をさらに向上さ
せる為であり、0.1wt％未満ではその効果が薄く、
1.8wt％を超えてもあまり顕著な変化が見られな
くなる為である。ここで言う貴金属とは、Au、
Ag、Pt、Pd、Rh、Ru、Ir、Osを含めてのこと
である。なお、マンガンと貴金属の合計が2wt％
以上とすることで、銅、アルミニウム、マンガ
ン、貴金属の相互作用により、目的とする課題を
解決できるものである。
以下本発明による装飾用黄金色系銅合金の効果
を明瞭ならしめる為に実施例及び従来例について
述べる。
第１表に示す成分組成の実施例１〜４の装飾用
黄金色系銅合金と従来例１、２の装飾用黄金色系
銅合金の色、加工性、耐汗性、機械的性質につい
てテストしたところ第２表のような結果を得た。
The present invention relates to a golden copper alloy used as a substitute for decorative gold alloys. With the recent efforts to save resources, golden alloy materials are required as a substitute for decorative gold alloys. In general, one of the requirements for decorative items is that they have good corrosion resistance and mechanical properties. Furthermore, these ornaments are decorative,
Because it requires complicated processing, it is also required that the processing be easy and that the color be close to golden yellow. Incidentally, an alloy used as a decorative golden-colored material is a brass alloy consisting of 30wt% Zn and the balance Cu, but this alloy has the drawbacks of poor corrosion resistance and mechanical properties, and is difficult to process into complex shapes. It was hot. The present invention was made in order to eliminate the above-mentioned drawbacks, and it is an object of the present invention to provide a decorative golden-colored copper alloy that is a copper-based alloy and has excellent corrosion resistance, workability, and mechanical properties, and has a golden color. It is something to do. The decorative golden copper alloy according to the present invention is A12.5~
10wt%, Mn0.1~7wt%, precious metals 0.1~1.8wt%,
It is an alloy in which the balance is Cu and the total amount of Mn and precious metals is 2wt% or more. In the decorative golden copper alloy according to the present invention,
The reason for adding Al is that when Al forms an alloy with Cu, it forms a stable oxide film on the surface, improving corrosion resistance and producing a golden-colored alloy.
This is because if the content is less than 2.5wt%, the effect will be weak, and if it exceeds 10wt%, intermetallic compounds will be formed, making it difficult to process into a thin plate. In addition, the reason for adding Mn is that Mn improves corrosion resistance by alloying with Cu, and also increases tensile strength, hardness, and elongation.
This is because if it is less than 7wt%, the effect will be weak, and if it exceeds 7wt%, the workability will be significantly reduced. In addition, the reason for adding precious metals is to further improve the corrosion resistance of the Cu-Al alloy by adding a small amount of precious metals, and if it is less than 0.1wt%, the effect will be weak.
This is because even if the content exceeds 1.8wt%, no significant change is observed. The precious metals mentioned here are Au,
This includes Ag, Pt, Pd, Rh, Ru, Ir, and Os. Furthermore, the total amount of manganese and precious metals is 2wt%.
By doing so, the intended problem can be solved through the interaction of copper, aluminum, manganese, and precious metals. Examples and conventional examples will be described below in order to clarify the effects of the decorative golden copper alloy according to the present invention. Tests were conducted on the color, workability, sweat resistance, and mechanical properties of the decorative golden-colored copper alloys of Examples 1 to 4 and the decorative golden-colored copper alloys of Conventional Examples 1 and 2 with the component compositions shown in Table 1. As a result, the results shown in Table 2 were obtained.
【表】【table】
【表】【table】
【表】
なお、人工汗試験はNH4Cl 15.5ｇ／、NaCl
20ｇ／、酢酸2.5ｇ／、尿素５ｇ／、乳酸
15ｇ／、PH4.7の液組成で液温40℃、240時間浸
漬後判定した。
また、引張り試験は30％加工後、常温にて行つ
た。
上記で明らかなように本発明による装飾用黄金
色系銅合金は従来の装飾用黄金色系銅合金に比
し、耐汗性、加工性、機械的性質が優れ、かつ黄
金色を有してることが判る。
以上詳記した通り、本発明の装飾用黄金色系銅
合金は、耐汗性、加工性、機械的性質が優れかつ
黄金色を有しているので、従来の装飾用黄金色系
銅合金にとつて代わることのできる画期的なもの
と言える。[Table] For the artificial sweat test, NH 4 Cl 15.5g/, NaCl
20g/, acetic acid 2.5g/, urea 5g/, lactic acid
Judgment was made after immersion for 240 hours at a liquid temperature of 40°C with a liquid composition of 15g/pH4.7. In addition, the tensile test was conducted at room temperature after 30% processing. As is clear from the above, the decorative golden-colored copper alloy according to the present invention has excellent sweat resistance, workability, and mechanical properties, and has a golden color, compared to conventional decorative golden-colored copper alloys. I understand that. As detailed above, the decorative golden-colored copper alloy of the present invention has excellent sweat resistance, workability, and mechanical properties, and has a golden color, so it is superior to conventional decorative golden-colored copper alloys. It can be said to be an epoch-making product that can be replaced.
Claims (1)
7wt％、貴金属0.1〜1.8wt％、残部銅より成りマ
ンガンと貴金属の合計が2wt％以上である装飾用
黄金色系銅合金。1 Aluminum 2.5~10wt%, manganese 0.1~
A decorative golden-colored copper alloy consisting of 7wt%, precious metals 0.1 to 1.8wt%, and the balance copper, with a total of manganese and precious metals of 2wt% or more.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP3289384A JPS60177142A (en) | 1984-02-23 | 1984-02-23 | Golden copper alloy for ornamentation |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP3289384A JPS60177142A (en) | 1984-02-23 | 1984-02-23 | Golden copper alloy for ornamentation |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS60177142A JPS60177142A (en) | 1985-09-11 |
| JPH0361740B2 true JPH0361740B2 (en) | 1991-09-20 |
Family
ID=12371563
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP3289384A Granted JPS60177142A (en) | 1984-02-23 | 1984-02-23 | Golden copper alloy for ornamentation |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS60177142A (en) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| ITPD20050291A1 (en) * | 2005-10-10 | 2007-04-11 | Silmar Spa | LEAGUE FOR ORNAMENTAL ITEMS |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5760043A (en) * | 1980-09-30 | 1982-04-10 | Furukawa Electric Co Ltd:The | Electrically conductive copper alloy with corrosion and heat resistance |
| JPS57192239A (en) * | 1981-05-22 | 1982-11-26 | Furukawa Electric Co Ltd:The | Copper alloy useful as fin for car radiator |
-
1984
- 1984-02-23 JP JP3289384A patent/JPS60177142A/en active Granted
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5760043A (en) * | 1980-09-30 | 1982-04-10 | Furukawa Electric Co Ltd:The | Electrically conductive copper alloy with corrosion and heat resistance |
| JPS57192239A (en) * | 1981-05-22 | 1982-11-26 | Furukawa Electric Co Ltd:The | Copper alloy useful as fin for car radiator |
Also Published As
| Publication number | Publication date |
|---|---|
| JPS60177142A (en) | 1985-09-11 |
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