JPH0359659A - Device for processing photosensitive material - Google Patents

Device for processing photosensitive material

Info

Publication number
JPH0359659A
JPH0359659A JP19564589A JP19564589A JPH0359659A JP H0359659 A JPH0359659 A JP H0359659A JP 19564589 A JP19564589 A JP 19564589A JP 19564589 A JP19564589 A JP 19564589A JP H0359659 A JPH0359659 A JP H0359659A
Authority
JP
Japan
Prior art keywords
silver halide
halide photographic
developer
sensitive material
developing
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP19564589A
Other languages
Japanese (ja)
Inventor
Kiyoshi Sato
清 佐藤
Mikio Kawasaki
川崎 幹男
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Konica Minolta Inc
Original Assignee
Konica Minolta Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Konica Minolta Inc filed Critical Konica Minolta Inc
Priority to JP19564589A priority Critical patent/JPH0359659A/en
Publication of JPH0359659A publication Critical patent/JPH0359659A/en
Pending legal-status Critical Current

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  • Photographic Processing Devices Using Wet Methods (AREA)

Abstract

PURPOSE:To attain a stable development processing free from the uneveness of development by supplying a preprocessing liquid to the exposed surface of a silver halide phpotographic sensitive material and decreasing the contact angle of a developing soln. CONSTITUTION:A preprocessing stage A is so constituted as to supply the preprocessing liquid to the exposed surface of the silver halide photographic sensitive material 1 to decrease the contact angle theta of the developing soln. 10 and to improve the wettability of the developing soln. 10. The carrying path for the silver halide photographic sensitive material 1 is formed by carrying rollers 2 in this preprocessing stage. The silver halide photographic sensitive material 1 is formed by carrying rollers 2 in this preprocessing stage. The silver halide photographic sensitive material 1 in this carrying path is immersed into the preprocessing liquid of a preprocessing tank 3 and is carried to a developing stage B. The developing stage B is so constituted as to supply the developing soln. to the exposed surface of the silver halide photographic sensitive material to develope the surface without immersing the silver halide photographic sensitive material 1 in the developing soln. The wettability of the developing soln. is improved in such a mamer and the stable development processing free from the uneveness of development is attained.

Description

【発明の詳細な説明】 [a業上の利用分野〕 この発明は、露光された親水性コロイド層を有するハロ
ゲン化銀写真感光材料を、現像処理する感光材料処理装
置に関する。
DETAILED DESCRIPTION OF THE INVENTION [Field of Application in Industry A] The present invention relates to a photosensitive material processing apparatus for developing a silver halide photographic material having an exposed hydrophilic colloid layer.

[従来の技術] 親水性コロイド層を有するハロゲン化銀写真感光材料は
、自動現像機で現像処理されており、例えばハロゲン化
銀写真感光材料をローラ搬送機構で搬送し、現像槽に貯
溜されている十分な量の現像液中に、所定時間浸漬させ
て現像処理している。
[Prior Art] A silver halide photographic material having a hydrophilic colloid layer is developed in an automatic processor. For example, the silver halide photographic material is transported by a roller transport mechanism and stored in a developing tank. The film is developed by being immersed in a sufficient amount of developer solution for a predetermined period of time.

このハロゲン化銀写真感光材料の現像処理によって、現
像槽に貯溜された現像液中の有効成分を消費するため、
現像液の疲労劣化が生じる。また、現像液がアルカリの
場合のように経時Cよって、空気中の炭酸ガスを吸収し
中和反応で、アルカリ度が低下することや、酸素による
酸化に起因する経時疲労等によって劣化する。
During the development process of this silver halide photographic light-sensitive material, the active ingredients in the developer stored in the developer tank are consumed.
Fatigue deterioration of the developer occurs. Further, as in the case where the developing solution is alkaline, over time C, the developer absorbs carbon dioxide gas in the air and undergoes a neutralization reaction, resulting in a decrease in alkalinity, and deterioration due to fatigue over time due to oxidation by oxygen.

この現像液の疲労を回復させる方法として、特開昭50
−144502号、特開昭54−62004号、特開昭
55−115039号、特開昭56−12645号の各
公報には、現像補充液を現像処理量に応じて連続的又は
間欠的に補充することにより、現像液の疲労を回復する
手段が提案されている。
As a method to recover from the fatigue of this developer,
-144502, JP-A No. 54-62004, JP-A-55-115039, and JP-A-56-12645, the developer replenisher is continuously or intermittently replenished according to the amount of development processing. A method has been proposed for recovering the developer from fatigue.

[発明が解決しようとする課題] しかし、これらはいずれも最初の一回目の現像7夜成分
と、その後の現像液成分とは異なり厳密には一回毎に特
性の違った写真処理ができる不具合があり、写真の仕上
り性能が不安定である。
[Problems to be Solved by the Invention] However, in all of these, there is a problem that the photographic processing has different characteristics each time, unlike the first development 7-night component and the developer component after that. , and the photo finishing performance is unstable.

このため、現像槽C貯溜した現像液にハロゲン化銀写真
感光材料を浸漬しないで、ハロゲン化銀写真感光材料の
露光面に現像液を供給して現像処理することが考えられ
るが、この場合にはハロゲン化銀写真感光材料に少量の
現像液を均一に供給する必要がある。
For this reason, it is conceivable that the silver halide photographic light-sensitive material is not immersed in the developer stored in the developing tank C, but the developer is supplied to the exposed surface of the silver halide photographic light-sensitive material for development processing. It is necessary to uniformly supply a small amount of developer to the silver halide photographic light-sensitive material.

しかしながら、少量の現像液を供給して処理する場合に
は現像液の供給が不均一になり易く、現像ムラが生じ、
安定した処理ができないため、所定の感度、階調度等の
感光的特性が得られない等の問題がある。
However, when processing by supplying a small amount of developer, the supply of developer tends to be uneven, resulting in uneven development.
Since stable processing cannot be performed, there are problems such as the inability to obtain predetermined photosensitive characteristics such as sensitivity and gradation.

この発明は、このような実状を考慮してなされたもので
、現像液のぬれ性をよくし、現像ムラがなく安定した現
像処理ができ、所定の感度、階調度等の感光的特性が得
られる感光材料処理装置を提供することを目的としてい
る。
This invention was made in consideration of the above-mentioned circumstances, and it improves the wettability of the developer, enables stable development processing without uneven development, and provides photosensitive characteristics such as predetermined sensitivity and gradation. The purpose of the present invention is to provide a photosensitive material processing apparatus that can be used.

[課題を解決するための手段] 前記課題を解決するため、この発明の感光材料処理装置
は、支持体の両面に親木性コロイド層を有するハロゲン
化銀写真感光材料の露光面に、ハイドロキノン類を含有
する現像液の供給を、このハロゲン化銀写真感光材料を
現像液中に浸漬しないで行ない処理する感光材料処理装
置において、前記ハロゲン化銀写真感光材料の露光面に
現像液を供給する現像工程の前に、ハロゲン化銀写真感
光材料の露光面に前処理液を供給し、現像液の接触角を
小さくする前処理工程を備えることを特徴としている。
[Means for Solving the Problems] In order to solve the above-mentioned problems, the photosensitive material processing apparatus of the present invention includes hydroquinones on the exposed surface of a silver halide photographic light-sensitive material having a wood-philic colloid layer on both sides of the support. In a photosensitive material processing apparatus in which the silver halide photographic light-sensitive material is supplied with a developer containing a developer without immersing the silver halide photographic light-sensitive material in the developer, the developer is supplied to the exposed surface of the silver halide photographic light-sensitive material. The method is characterized in that it includes a pretreatment step in which a pretreatment liquid is supplied to the exposed surface of the silver halide photographic light-sensitive material to reduce the contact angle of the developer.

このハロゲン化銀写真感光材料は例えばXレイ等の高感
度フィルムであり、支持体の両面に少なくとも親水性コ
ロイド層を有するもので、この支持体は透明材料で形成
されている。このハロゲン化銀写真感光材料は、例えば
この出願人が先に出願した特開昭63−23154号公
報に記載のものが、感度、カブリ、粒状性C優れ、また
ゼラチン量が少なくてもすり傷薫化や圧力減感が少なく
、好ましく用いられる。
This silver halide photographic light-sensitive material is a high-sensitivity film such as X-ray, and has at least a hydrophilic colloid layer on both sides of a support, which is made of a transparent material. This silver halide photographic light-sensitive material, for example, the one described in Japanese Unexamined Patent Application Publication No. 63-23154 previously filed by the applicant, has excellent sensitivity, fogging, and graininess C, and even with a small amount of gelatin, scratches may occur. It is preferably used because it causes less smoke and pressure desensitization.

ハロゲン化銀写真感光材料の両面への現像液の供給は、
ハロゲン化銀写真感光材料を搬送させて行なうことが好
ましく、この搬送は横方向でも縦方向でもよいが、縦方
向に搬送して供給するようにすると、装置の設置面積を
小さくすることができ、好ましい。
Supplying the developer to both sides of the silver halide photographic material is as follows:
It is preferable to convey the silver halide photographic light-sensitive material, and this conveyance may be carried out horizontally or vertically, but if it is conveyed and supplied vertically, the installation area of the apparatus can be reduced, preferable.

また、このハロゲン化銀写真感光材料への現像波の供給
は、ハロゲン化銀写真感光材料を貯溜された現像液中に
浸漬しないで供給することであり、このような供給によ
って現像処理に必要な所定量の現像液を供給することが
でき、現像液の経時疲労を防止すると共に、現像?夜の
節約になる。
In addition, the development wave is supplied to the silver halide photographic light-sensitive material by supplying the silver halide photographic light-sensitive material without immersing it in the stored developer. It is possible to supply a predetermined amount of developer, prevent fatigue of the developer over time, and also prevent the developer from developing. It will save you a night.

この現像液の供給はハロゲン化銀写真感光材料の露光面
に、現像液を塗り付け、或いはシャワー、または噴霧等
の手段で行なわれ、この現像液の供給は1回に限らず、
数回に行なうようにしてもよい。
This developer is supplied by applying the developer to the exposed surface of the silver halide photographic light-sensitive material, or by showering, spraying, or the like, and the developer is supplied not only once, but also by
You may do this several times.

この発明の現像液に用いられるハイドロキノン類として
は、ハイドロキノン、クロロハイドロキノン、メチルハ
イドロキノン等が挙げられるが、ハイドロキノンが好ま
しく用いられる。この添加量は、現像液IA当り1g〜
20g、好ましくは5g〜15gである。
Hydroquinones used in the developer of the present invention include hydroquinone, chlorohydroquinone, methylhydroquinone, etc., and hydroquinone is preferably used. The amount added is 1g to 1g per developer IA.
20g, preferably 5g to 15g.

また、この発明の現像液には、特開昭63−10158
号で示されるような3−ピラゾリドン系現像主薬、ジア
ルデヒド系硬膜剤、インダゾール系、ベンツイミダゾー
ル系、ペンツトリアゾール系、メルカプトチアゾール系
から選ばれたカブリ防止剤、その化キレート剤、緩衝剤
、アルカリ剤、溶解助剤、pH調整剤、現像促進剤、界
面活性剤等も必要に応じて添加されても良い。
Further, the developing solution of this invention includes Japanese Patent Application Laid-Open No. 63-10158
Antifoggants selected from 3-pyrazolidone-based developing agents, dialdehyde-based hardeners, indazole-based, benzimidazole-based, penztriazole-based, and mercaptothiazole-based agents, their chelating agents, buffers, Alkali agents, solubilizing agents, pH adjusters, development accelerators, surfactants, etc. may also be added as necessary.

この発明の前処理工程では、ハロゲン化銀写真感光材料
を前処理液槽へ浸漬させて、その露光面に前処理液を供
給するようにしてもよく、またハロゲン化銀写真感光材
料を前処理液槽へ浸漬させないで、前処理液を供給して
もよい。この前処理液は、水またはアルカリ性の水溶液
でもよく、好ましくはアルカリ可溶または水可溶の界面
活性剤を含んだものがよく、界面活性剤の種類は限定さ
れない。
In the pretreatment step of the present invention, the silver halide photographic light-sensitive material may be immersed in a pretreatment liquid tank and the pretreatment liquid may be supplied to the exposed surface of the silver halide photographic light-sensitive material. The pretreatment liquid may be supplied without being immersed in the liquid tank. This pretreatment liquid may be water or an alkaline aqueous solution, preferably containing an alkali-soluble or water-soluble surfactant, and the type of surfactant is not limited.

[作用] この発明では、前処理工程で、ハロゲン化銀写真感光材
料の露光面に前処理液を供給することにより、次の現像
工程でハロゲン化銀写真感光材料を現像液中に浸漬しな
いで供給するとき、現像液の接触角が小さくなってぬれ
性がよくなる。このため、ハロゲン化銀写真感光材料を
現像液中に浸漬しないで、少量の現像液で均一に供給で
き、現像ムラがなく、安定した現像が行なわれ、所定の
感度、階調度等の感光的特性が得られる。
[Function] In the present invention, by supplying a pretreatment liquid to the exposed surface of the silver halide photographic material in the pretreatment step, the silver halide photographic material is not immersed in the developer in the next development step. When the developer is supplied, the contact angle of the developer becomes smaller, improving wettability. Therefore, the silver halide photographic light-sensitive material can be uniformly supplied with a small amount of developer without immersing it in the developer, and stable development is performed without uneven development. characteristics are obtained.

[実施例] 以下、この発明の一実施例を添付図面に基づいて詳細に
説明する。
[Example] Hereinafter, an example of the present invention will be described in detail based on the accompanying drawings.

第1図はこの発明の実施例を適用した感光材料処理装置
の概略図、第2図は現像液の接触角を示す図である。
FIG. 1 is a schematic diagram of a photosensitive material processing apparatus to which an embodiment of the present invention is applied, and FIG. 2 is a diagram showing the contact angle of a developer.

この感光材料処理装置には、前処理工程Aと現像工程B
とが備えられている。
This photosensitive material processing apparatus includes a pretreatment process A and a development process B.
are provided.

前処理工程Aは、ハロゲン化銀写真感光材料1の露光面
に前処理液を供給し、第2図に示すように現像液10の
接触角θを小さくし、現像液10のぬれ性をよくするよ
うに構成されている。この前処理工程Aには、搬送ロー
ラ2によって、ハロゲン化銀写真感光材料1の搬送路が
形成されており、この搬送路はハロゲン化銀写真感光材
料1を前処理液槽3の前処理液中に浸漬させて、現像工
程Bへ搬送するようになっている。前処理液は前記した
ように、水またはアルカリ性の水溶液でもよく、好まし
くはアルカリ可溶または水可溶の界面活性剤を含んだも
のがよく、界面活性剤の種類は限定されない、なお、こ
の前処理液には、現像主薬を含まない。
In the pretreatment step A, a pretreatment liquid is supplied to the exposed surface of the silver halide photographic light-sensitive material 1 to reduce the contact angle θ of the developer 10 and improve the wettability of the developer 10, as shown in FIG. is configured to do so. In this pretreatment step A, a conveyance path for the silver halide photographic light-sensitive material 1 is formed by a conveyance roller 2, and this conveyance path passes the silver halide photographic light-sensitive material 1 through a pretreatment liquid in a pretreatment liquid tank 3. The material is immersed in the liquid and transported to the developing step B. As mentioned above, the pretreatment liquid may be water or an alkaline aqueous solution, preferably containing an alkali-soluble or water-soluble surfactant, and the type of surfactant is not limited. The processing solution does not contain a developing agent.

現像工程Bは、ハロゲン化銀写真感光材料1を現像液中
に浸漬しないで、現像液をハロゲン化銀写真感光材料の
露光面に供給して現像処理するように構成されている。
The developing step B is configured such that the silver halide photographic light-sensitive material 1 is not immersed in the developer, but a developer is supplied to the exposed surface of the silver halide photographic light-sensitive material for development processing.

この現像工程Bでは対をなす搬送ローラ4が鉛直方向に
複数段に重ねて配置されており、ハロゲン化銀写真感光
材料1が露光後に搬送ローラ4で形成される搬送路上を
矢印C方向に送られ、現像処理が行なわれる。
In this developing step B, a pair of conveyance rollers 4 are arranged vertically in multiple stages, and the silver halide photosensitive material 1 is conveyed in the direction of arrow C on a conveyance path formed by the conveyance rollers 4 after exposure. and development processing is performed.

対をなす搬送ローラ4の上方にはそれぞれ対をなす供給
ノズル5が設けられ、この供給ノズル5の供給口5aは
搬送ローラ4の接触面方向へ向い、かつローラ面に対向
するように配置されている。
A pair of supply nozzles 5 are provided above the pair of conveyance rollers 4, and the supply ports 5a of the supply nozzles 5 are arranged so as to face the contact surface of the conveyance roller 4 and to face the roller surface. ing.

ハロゲン化銀写真感光材料1は搬送ローラ4の駆動によ
って矢印C方向へ搬送され、このハロゲン化銀写真感光
材料1が搬送されるとき、供給ノズル5の供給口5aか
ら現像液が供給される。この現像液は対をなす搬送ロー
ラ4の接触面方向へ流れて、ハロゲン化銀写真感光材料
1の両面に塗布される。このハロゲン化銀写真感光材料
1の露光面は前処理工程で、現像液の接触角が小さく、
ぬれ性がよくなっているから、現像液を均一に供給する
ことができ、現像ムラなく安定した処理ができ、所定の
感度、階調度等の感光的特性が得られる。
The silver halide photographic material 1 is conveyed in the direction of arrow C by the drive of the conveyance roller 4, and when the silver halide photographic material 1 is conveyed, a developer is supplied from the supply port 5a of the supply nozzle 5. This developer flows toward the contact surfaces of the pair of transport rollers 4 and is applied to both sides of the silver halide photographic material 1 . The exposed surface of this silver halide photographic light-sensitive material 1 has a small contact angle with the developer during the pretreatment process.
Since the wettability is improved, the developer can be supplied uniformly, stable processing can be performed without uneven development, and photosensitive characteristics such as predetermined sensitivity and gradation can be obtained.

それぞれの供給ノズル5からは新規な現像液が、ハロゲ
ン化銀写真感光材料1に供給され、上段の搬送ローラ4
から下方へ、さらに中断の搬送ローラ5から下方へ落下
し、さらに下段の搬送ローラ5から落下して廃棄され、
現像液は使い捨てとなっている。
A new developer is supplied from each supply nozzle 5 to the silver halide photographic light-sensitive material 1, and the developer is supplied to the upper transport roller 4.
, then further down from the interrupted conveyance roller 5 , and then from the lower conveyance roller 5 to be discarded.
The developer is disposable.

なお、最下段の搬送ローラ5の下方にトレーを配置して
、現像液をトレーへと落下するようにし、トレーには配
管を接続してポンプでトレー内の現像液を供給ノズルへ
と循環できるようにしてもよい。この場合、感光材料の
処理前であれば現像液が処理による現像疲労は生じてい
ないし、またwi環される現像液は大気との接触面積も
少ないので、炭酸ガス吸収Cよる経時疲労も少ないから
、再使用可能である。
In addition, a tray is arranged below the lowest transport roller 5 so that the developer falls onto the tray, and piping is connected to the tray so that a pump can circulate the developer in the tray to the supply nozzle. You can do it like this. In this case, before the photosensitive material is processed, the developing solution does not suffer from development fatigue due to processing, and since the developing solution that undergoes wiping has a small contact area with the atmosphere, there is little fatigue over time due to carbon dioxide absorption C. , reusable.

また、前記した前処理工程Aは、この現像工程Bのよう
にハロゲン化銀写真感光材料1を前処理7夜に浸漬させ
ないで供給して、ハロゲン化銀写真感光材料1に供給す
る現像液のぬれ性をよくすることもできる。
In addition, in the pretreatment step A described above, as in this development step B, the silver halide photographic light-sensitive material 1 is supplied without being immersed for 7 nights in the pretreatment, and the developing solution supplied to the silver halide photographic light-sensitive material 1 is supplied. It can also improve wettability.

[発明の効果コ 以上説明したように、この発明の感光材料処理装置では
、ハロゲン化銀写真感光材料の露光面に現像液を供給す
る現像工程の前に、ハロゲン化銀写真感光材料の露光面
に前処理液を供給し、現像液の接触角を小さくする前I
A理工程を備えたから、ハロゲン化銀写真感光材料の露
光面のぬれ性がよくなり、現像工程で現像液を均一に供
給でき、現像ムラがなく安定した現像処理が行なわれ、
所定の感度、階調度等の感光的特性を得ることができる
[Effects of the Invention] As explained above, in the photosensitive material processing apparatus of the present invention, the exposed surface of the silver halide photographic material is Before I supply a pretreatment liquid to reduce the contact angle of the developer
Equipped with the A process, the wettability of the exposed surface of the silver halide photographic light-sensitive material is improved, the developer can be supplied uniformly during the development process, and stable development processing is performed without uneven development.
Photosensitive characteristics such as predetermined sensitivity and gradation can be obtained.

【図面の簡単な説明】[Brief explanation of drawings]

第1図はこの発明の実施例を適用した感光材料処理装置
の概略図、第2図は現像液の接触角を示す図である。 図中符号1はハロゲン化銀写真感光材料、2゜4は搬送
ローラ、3は前処理液槽、5は供給ノズル、Aは前処理
工程、Bは現像工程である。 特 許 出 願 人   コニカ株式会社第 来
FIG. 1 is a schematic diagram of a photosensitive material processing apparatus to which an embodiment of the present invention is applied, and FIG. 2 is a diagram showing the contact angle of a developer. In the figure, reference numeral 1 is a silver halide photographic light-sensitive material, 2.4 is a transport roller, 3 is a pretreatment liquid tank, 5 is a supply nozzle, A is a pretreatment step, and B is a development step. Patent applicant Konica Co., Ltd.

Claims (1)

【特許請求の範囲】[Claims] 支持体の両面に親水性コロイド層を有するハロゲン化銀
写真感光材料の露光面に、ハイドロキノン類を含有する
現像液の供給を、このハロゲン化銀写真感光材料を現像
液中に浸漬しないで行ない処理する感光材料処理装置に
おいて、前記ハロゲン化銀写真感光材料の露光面に現像
液を供給する現像工程の前に、ハロゲン化銀写真感光材
料の露光面に前処理液を供給し、現像液の接触角を小さ
くする前処理工程を備えることを特徴とする感光材料処
理装置。
A developing solution containing hydroquinones is supplied to the exposed surface of a silver halide photographic material having hydrophilic colloid layers on both sides of the support without immersing the silver halide photographic material in the developer. In the photosensitive material processing apparatus, before the development step of supplying a developer to the exposed surface of the silver halide photographic light-sensitive material, a pre-processing solution is supplied to the exposed surface of the silver halide photographic light-sensitive material, and the contact of the developer is carried out. A photosensitive material processing apparatus characterized by comprising a pretreatment step for reducing corners.
JP19564589A 1989-07-28 1989-07-28 Device for processing photosensitive material Pending JPH0359659A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP19564589A JPH0359659A (en) 1989-07-28 1989-07-28 Device for processing photosensitive material

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP19564589A JPH0359659A (en) 1989-07-28 1989-07-28 Device for processing photosensitive material

Publications (1)

Publication Number Publication Date
JPH0359659A true JPH0359659A (en) 1991-03-14

Family

ID=16344620

Family Applications (1)

Application Number Title Priority Date Filing Date
JP19564589A Pending JPH0359659A (en) 1989-07-28 1989-07-28 Device for processing photosensitive material

Country Status (1)

Country Link
JP (1) JPH0359659A (en)

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