JPH0354300A - Aromatic composition, and use thereof in detergent product - Google Patents

Abstract

PURPOSE: To provide a perfume compsn. which exhibits odorproof effect during use even when perfume properties are at a low level and is useful for detergents, a body odor preventing agent, etc., by bringing an odor strength index, bed smell decreasing value or odor decreasing value into a specified numeral range.

CONSTITUTION: A fragrant compsn. wherein a material exhibiting an odor strength index of smaller than 110 and a bad smell decreasing value or an odor decreasing value of at least 0.25 is used in a detergent, a compsn. for conditioning of a fiber product, a body odor preventing agent, etc., is provided. This compsn. (less than 5% are incorporated in a detergent) consists six classification [classification 1: phenolic substances (e.g. isoamylsalicylate), classification 2: refined oils, essential oils, extracts, resins and synthetic oils (e.g. Bergamot AB 430), classification 3: aldehydes and ketones (e.g. 7-acetyl-1,1,3,4,4,6- hexamethyltetralin), classification 4: nitrogen-contg. compd. (e.g. isobutylquinoline), classification 5: esters and classification 6: alcohols and ethers] and among these, at least 5 kinds of ingredients are incorporated.

COPYRIGHT: (C)1991,JPO

Description

DETAILED DESCRIPTION OF THE INVENTION The present invention relates to compositions of aromatic materials and their use in laundry products.

According to a particular embodiment, the present invention provides a combination of such aromatic compositions and detergent powders, such as l! I grains), liquids (especially e.g. m
textile cleaning liquids), soaps and washing bars and pastes,
The present invention relates to combinations with compositions for conditioning textile products (e.g. in liquid or solid sheet form) and compositions for deodorant body odor (e.g. axillary deodorants).

[This European Patent Application No. 0003171 and 0003]
No. 172 (Unilev6r) and U.S. Patent No. 430
No. 4,679 (1.ever) (and references cited therein) discloses a wide range of known examples of perfume compositions, particularly for use in detergents.

European Patent Application Nos. 0003171 and 0003
No. 172 further discloses compositions in which the perfume composition IJt has a deodorizing effect upon use.

Other examples of perfume compositions and their application to enzyme-containing detergents are found in JP-A-57-85898 and JP-A-57-85900 (
Lion Corp) and Yoneda Patent No. 4515705
No. (Procter & Ga.). European Patent Application No. 0147191 (IJn i
Lever) discloses another example of a perfume composition that has not only odor control properties but also stability in the presence of bleaching compositions. Furthermore, GB 1589866 describes the use of citrate or esters of acetyl citrate (e.g. citric acid triethyl ester) as deodorants in soap bars.
It is proposed to add 3%. Surprisingly, certain compositions of aromatic materials, even if they themselves have low or imperceptible levels of aromaticity (low odor intensity), exert an odor control effect during use. It was found that it was possible to obtain This is advantageous in many applications where strong fragrance is not desired, but odor control is welcome.

According to one aspect of the invention, (a) an odor intensity test as described
Less than about 110 (
The Odor Intensity Index is often less than about 105, preferably less than about 100.
x) and (b) Yo0-/Pa Patent Application No. 0147191
Malodour Reduction Value of at least about 0.25, preferably at least about 0.5 when tested according to the test procedure described in
e) or at least about 0.25 when tested according to the test procedure described in European Patent Application No. 0003172, the disclosures of which are hereby incorporated by reference. Preferably an odor reduction value of at least about 0.5 (OdourRec!ucti
There is provided a composition of aromatic material having a value of 100% on Value. As used herein, the terms "perfume" and "fragrant" also extend to compositions whose odor intensity is so low as to be imperceptible in use.

A suitable selection of examples of perfume materials for incorporating into such compositions is provided, for example, in the Examples below. More generally, any of a wide range of fragrance materials may be used, provided that the selection criteria are such that they provide an odor control effect and the odor intensity index of the composition formed is as above. It can be blended into the composition.

For more extensive instructions for the selection of materials to provide an odor control effect, see European Patent Application No. 014719, both of which are hereby incorporated by reference.
No. 1 and No. 0003172, and U.S. Patent No. 430
No. 4679. It is useful if the bulk of the individual components selected for the composition similarly individually have an Odor Intensity Index of less than about 110, preferably less than about 100, or even lower. However, small amounts of higher strength materials t1 may also be tolerated, for example for the purpose of adjusting the mild perfume characteristics that may be provided by the overall composition.

In many specific embodiments, the compositions of the invention weigh at least 30% by weight. ≦, for example at least 35% by weight ≦ or at least 40% musk.

If the above amount or other amount of musk is present, G
alaxolide (registered trademark) (IFF) (classification 3 below) and 7' or Traseol ide (registered trademark)
(Quest) It is useful to select from musk such as (Category 4 below).

According to another aspect of the invention, there is provided a detergent composition suitable for cleaning ti textiles, the composition comprising: (a) optionally at least about 0.03% musk by weight of the detergent composition; b) at least about 0.07% of other fragrance ingredients, with the proviso that fragrance ingredients (a) and (
b) has an overall odor intensity index of less than 100;
The entire aggregate of aromatic components shall pass any of the odor reduction tests described above.

According to the invention, compositions of fragrant materials with low odor intensity can be added to various detergents and personal care products, such as:
t (non-limiting amount), usually about 0.1% or more, up to about 0.1-0.3% in textile cleaning compositions, and up to about 0.8% in concentrated textile cleaning compositions; Up to about 0.3% in conditioning liquids, up to about 5% in sheet textile conditioning solid preparations, and about 0.2-1.8% in soap and detergent bars and pastes are useful. In a specific embodiment, the present invention further provides deodorant perfume ingredients, such as European Patent Application No. 014719
Bleach Stability Test as described in Bleach Sta.
Sodium perborate 4 according to the
Contains components that are considered stable in the presence of hydrate and N,N,++',+i'-tetraacetylethylenediamine (TAED), and has a malodor reduction value measured by the malodor reduction value test. 0.25 to 3.0, and provides a deodorizing fragrance having a characteristically low odor intensity as otherwise specified herein.

Such odor-preventing perfumes may contain from 50 to 100% by weight (e.g., bleach-stable) odor-preventing perfume ingredients and from 0 to 50 weight percent of other components, the odor-preventing perfume ingredients including, for example At least 50% glue boxidase damaging capacity or at least 1
, 1 Raoult Variance Ratio (Raoult Varianc
e Ratio) and is considered stable in the presence of perboric acid tetrahydrate and N,N,N,N''-tetraacetylethylenediamine (TAED) according to bleach stability tests, and the components is Class 1: Phenolic substance, Class 2
Essential oils, extracts, resins and synthetic oils (add AB), classification 3
: Aldehydes and ketones, Class 4: Nitrogen-containing components and polycyclic compounds, Class 5: Esters, Class 6: Alcohols and ethers. When the ingredient can fall into two or more categories, the ingredient is assigned to the younger or lowest numbered category, and the ingredient preferably contains a) at least one deodorant fragrance from each of Categories 1, 2, and 4; b) the odor-resistant perfume contains ingredients from at least 4 of the 6 classes; and C) all ingredients present in the deodorant perfume at a concentration of less than 0.5% by weight. is selected to be excluded from requirements (,i) and (b),
[ Sodium dodecylbenzenesulfonate 9Cl. -I
s alcohol 7E04 Sodium tripolyphosphate 33-alkali sodium silicate 6-sodium carboxymethylcellulose Magnesium monosilicate
1 ethylenediaminetetraacetic acid
0.2 Sodium sulfate
15 water
iii. rinsing and drying the washed fabric specimen to provide a 'untreated'fabric;
iv) Rewash half of the "untreated" fabric specimens in a washing machine with a standard cleaning powder containing 0.2% by weight of the test bleach-stable fragrance, rinse, and re-dry the "treated" fabric. V) providing a test specimen such that each shirt has a "treated" fabric insert in one axillary area and an "untreated" fabric insert in the other axillary area according to a statistical design; vi) inserting the treated and untreated fabric specimens into the axillary region of a clean polyester cotton shirt;
The subjects were selected from those whose axillary body odor was not excessively strong and the difference between the two axillary body odors was not large.vii) The body odor of the fabric insert was assessed after 5 hours, and three people were trained. Ratings from O to 5 by female assessors (
0 represents no odor, 5 represents a very strong malodor) The olfactory intensity of the malodor was recorded, and the olfactory intensity of the malodor was recorded in the table below. Weak 0. 0533 average
0.224 strong
0.875 Very strong 3.57
vii) calculating the average score of the treated and untreated fabrics and determining the average score of the untreated fabrics; Calculate the odor reduction value of the bleach-stable fragrance by subtracting the average score of the treated fabric from 0 when measured by a malodor reduction value test that includes the step of determining that it is a fragrance.
．． It has an odor reduction value of 25-3.0 and the bleach stability test consists of: i) blending the fragrance material into a standard unscented cleaning powder and incubating the blended powder in a closed container at 20°C for 7 days; and ii) dividing the blended powder into two parts and adding sodium perborate tetrahydrate and TAED granules or sodium sulfate (acting as an inert filler in place of TAED) to each part; Composition standard unscented powder
7676 Test fragrance material 0.2
0.2 Sodium perborate tetrahydrate l313
TAED granules (65% TAED) 10.
preparing test and control formulations having 8 sodium sulfate 1o,8; iii.
) incubation of the test and control powders in a closed container at 45° C. for a further 7 days; and iv) assessment by 20 people trained to discern by smell which of the three powder samples are significantly different from the others. Using a group of people ^me
rican Society for Testing
and Materials (1969) “Manu”
al on Sensory TestingMeth
A fragrance material is bleach stable if less than 9 out of 20 assessors assess the test and control powder samples according to the standard triangle test as described in and a step of determining that the fragrance ingredient is a deodorizing fragrance ingredient.

Deodorizing fragrance ingredients can be classified into six chemically defined categories. Flavor ingredients can be classified into four categories as shown below along with examples of ingredients to be assigned to each category.

1) Natural or common chemical compounds, such as hexyl salicylate. Most of the ingredients fall into this category.

2> Synthesis reaction products, isomer mixtures and optionally homologs, such as α-isomethylionone.

3) Natural oils and extracts, such as Siamese benzoinous resinoid.

4) Synthetic oils (e.g. class 3 analogues). This class includes materials that are not exact analogs of natural oils, but are obtained as a result of imitation or modification of certain natural oils, such as bergamot AB 430.

Components in categories 3) and 4) are often not chemically identified, but are commercially available.

If the material is a mixture (e.g. diluted with diethyl phthalate)
-t-amylsichexanone), for the purpose of this specification.
1 part of this ketone and 9 parts of diethyl phthalate
The use of 5% of the blend with 0.5% ketone and 4.5% diethyl phthalate. In preparing the most effective deodorant perfumes, it has been found to be advantageous to use ingredients that satisfy the riboxidase or morpholine test while also satisfying other conditions. These conditions are:) there are at least five different components that meet the following classifications, ii) there are components from at least four chemical classes (defined below), and ii
i) at least 50% by weight, preferably at least 55%, suitably from 60 to 100% by weight of the deodorizing perfume contains deodorizing perfume ingredients meeting the following classification; iv)
When a component is present in a perfume at a concentration of less than 0.5% by weight, this component is considered not to contribute to the effectiveness of the bleach-stable deodorizing perfume.

Each component is assigned to one of six categories. These classifications are Class 1: Phenolic substances, Class 2: Essential oils, extracts, resins and synthetic oils (referred to as AB), Class 3: Aldehydes and ketones, Class 4: Nitrogen-containing components, Class 5: Esters,
Category 6: Excluded from alcohol and ethers.

The following principles should be observed when assigning components to categories: If a component can fall into more than one category, the component is assigned to the first category in the above order, for example, the nitrogen-containing compound methylan I ranylate may also fall under category 5 as an ester, but it is assigned to category 4. assigned to. Similarly, ethyl salicylate with phenolic character is assigned to Category 1 rather than Category 5.

At least 50% glue boxidase inhibitory capacity (+.IC
or a Raoult Dispersion Ratio (RVR value) of at least 1.1 and a Bleach Stability Test (BST) panel rating of up to 9, meaning that it is bleach stable. Stability) Examples of deodorizing perfume ingredients are given below, along with their classification, molecular Ji(m), LIC and RVR values and BST Bunnel ratings as determined by the tests described above.

As far as possible, the names adopted for the ingredients listed below and the fragrance ingredients listed in the fragrance compositions of Examples 1 to 7 are as follows:
rfu++e and Flavor Chemical
als(^ro+naChemicals)” Vol.
ume I and II (1969), “Perfume
ancl Flavor Chemicals (＾r
oma Chemicals)” Volume I and II (1969) and WPerfume &Fla
vor Materials of Natural
Stefren Ar in “Origin” (1960)
The name used by ctander was used. If an ingredient is not listed by 8rctander, the chemical name is listed, and if the chemical name is unknown, the perfume manufacturer's product code name is listed. Synthetic oils with AB added are Que.
Please note that this is a commercially available product from St. International. Specific examples of fragrance ingredients are shown below. 1: Phenol isoamyl salicylate, rubacrol, clove leaf oil, ethyl salicylate, isoeugenol, hexyl salicylate. 100 1.48 164 100-222 BST Base note time Akadomari 2; Esbergamot AB 430 Kegeranium AB76 Rose AB380 Rose AB409 3; Aluhydrone 7-acetyl-1,1,3,4,4.6 hexamethyl Tetrahydride naphthalene p-t-amylcyclohexanone 2-n-heptylcyclobentanone α-isomethylionone β-methylnaphthyl ketone Family 4: Vertebra 7, Muisobutylquinoline Methyl anthranilate S Meng Sheng Disaster 69 1.37 AB 0.97 l,29 1.28 1.34 1.03 1.10 1.05 1,13 0,96 1.10 1,20 o-t-butyl hexyl acetate diethyl phthalate nonane Diol-13- 5'acetate nonanolide-1,4 1-nonyl acetate i-nonylformate phenylethyl phenyl acetate 0 6: Alcohol Cinnamyl alcohol Dimyrcetol 1,3,4,6,7.8- Hexahydro 4, 6, 6,
7,8.8-Hexamethylcyclopentyl γ-2-penzobilan (Galaxolide) 52 79 16 100 1.08 1,20 l. 17 0.87 0.83 1.49 1.22 1.28 1.22 Hydroxymethylisobrobylcyclobentane 60 1.23
142 83a-Methyldodecahydro 6,5.9a-}limethylnaphtho2(2J-b)furan 58 1.
30230 5-tetrahydromugol
24 1.23 158 8 Bleach-labile (therefore, when formulated in the presence of bleach materials, does not appear to contribute substantially to the odor control properties of the fragrance)
Examples of fragrance ingredients are listed below.

Siamese benzoin resinoid benzyl salicylate bergamot AB 37 pt-butyl hexyl acetate BST Li! lJI Entrance Director Keio Note Point 87--14 0 1.58228 1758 0
．． 97 175 1054 0.98
198 10p-t-Butyl-α-methylhydrozinnamaldehyde (Lilial) Coumarin Ethyl Wanilinke' Geranium oil Bourbon 74 - 204 58 1.22 146 100 1.43 152 28 1.29 154 LRG 201 (well-known resolic acid ester 'I 100 1.
21 196 Mousse de chene Yugo
98 1.29 182β~Naphthyl methyl ether 100 - 158 Ovovanox resinoid 96 1.33 150 Bachuri oil 76 1.25
140 petitgrain oil 34 1
．． 27 175 Phenylethyl alcohol 22
1.24 122 Pimento leaf oil
100-165 Pomelanzole AB
314 Among the 100 or more ingredients listed, the ingredients suitable for relatively mild air strength are the ingredient (a) included in the following examples, Benoregamo Nto AB, hexynoresalicylate, Rose AB380, diethyl phthalate,
With a certain component (b) from nonanediol 1,3-diacetate, isononyl acetate, cinnamyl alcohol, sham benzoin resinoid, benzyl salicylate, pt-butyl-α-methylhydrocinnamaldehyde, obovanox resinoid be.

The deodorizing perfume should preferably contain at least 5 different ingredients from at least 4 classes, preferably 5 or 6 classes. However, it is possible, and in fact usually advantageous, to use more than six different ingredients in formulating a fragrance. Ideally, most if not all fragrances are prepared from odor-resistant fragrance ingredients. Ingredients present in deodorizing perfumes for purposes other than obtaining an odor-preventing effect, e.g. additives such as antioxidants, may be excluded from the validity of the above instructions to the extent that such ingredients are necessary for said other purpose. . The levels of additives commonly present in fragrances or flavored products are well established in conventional materials and can be readily determined in new materials so that there is no difficulty in applying the above exclusions.

The sample is assessed by a group of appropriate number of assessors (for example, 34) trained to score the strength of the sample using numerical estimation methods. This is a ratio scoring method in which the relative intensity of each sample is scored as a ratio to the intensity of a range of odor standards (here benzyl acetate diluted with dibrobylene glycol at various concentrations).

Fragrance 1. % (±0.1 g) or as pure or dipropylene glycol diluent 1. %(±0
．． 1 g) in a 7 zl white soda S. N. B. Place in a screw neck vial.
Each sample is coded and presented to a panel of assessors at least twice in random order. A total of at least 6 participants each day over 2 days by at least 16 panellists.
Four tests (or sufficient to reach statistical significance) are performed on each sample. Assessments are performed in an environmentally controlled assessment room using colored lighting to ensure that the springlist is not influenced by slight color differences between samples. Individual test values are normalized and averaged to obtain a match strength rating for each sample. The perceived strength is expressed in arbitrary units and is obtained from the match magnitude estimate, which represents the ratio of perceived strengths, as follows.

Each springlist was required to assess the intensity of each non-test aromatic control sample (benzyl acetate in 10% dipropylene glycol) and the reference sample. Next, the intensity values (size estimates) of the control samples were used to normalize all assessment values for each spring list as follows. Alternatively, the normalized values of the samples were integrated for all spring lists to obtain the matching value (phased average) for the entire panel. Or, during the ceremony, ! ．． - odor intensity index of sample k across the panel, (ix
) t = sample odor intensity (magnitude estimate) reported by the jth panellist, (1.), = normalized data for one panelist, n - number of samples, J = number of panelists, K = samples number, (ij+=control odor intensity (magnitude estimate) reported by the Jth spring list. The invention will now be described in more detail by means of non-limiting examples.

Aromatic compositions suitable for use in the present invention were prepared as follows. Seedling 2.0 Cedarwood oil (from Virginia) 2.0
Cinnamyl alcohol 13.0 Diethyl phthalate 5. O Galaxolide DEP (50:50 mixture with diethyl phthalate) 4.0 Geranyl phenyl acetate 1.0
Guaiac wood oil (rectified) 4.0 Linalyl benzoate e. o Mossy AB 7004 (*) 3.0
Phenylethyl phenyl acetate 20.0
Rose base AB 7003 (*) 40. O
Traseol ide (Quest) ioo. o (*) (Commercial product from Quest International 1) The odor type of this composition is mild floral,
moss, rose and musk. The composition has a low odor intensity and (among others) about 0.2% by weight of the detergent composition.
It is suitable for blending into detergent compositions for cleaning textile products at a blending ratio of . Another aromatic composition of the present invention was prepared as follows. I Roasted 8.0 Benzyl Alcohol 7.5 Benzyl Salicylate 2.0 Cedarwood Oil (Virginia) 20.
O Galaxolide DEP1. OG
risalva (10% dibrobylene glycol solution>
(IFF) 5.0 11ercolyn D (tlercu
les) 3.0 Isobutyl benzoate 20 Isobutyl cinnamate 1.0 Linalyl cinnamate 5.0 Mossbase AB 7004 (*) 20.0
Lily of the valley base AB 7001 (end) 5. O
Tonalid (7-acetyl-1,1,3,4,4
．． 6-Hexamethyltetrahydronaphthalene>(Polak's Fruital Works) 2
0. O Traseol ide (*) too. o The odor types of this composition are mild wood, moss, lily of the valley and musk. Another highly suitable composition of very low odor intensity was prepared as follows.

2L Roasted 5.0 Benzyl alcohol 4.0 Benzyl cinnamate 20.0 Benzyl salicylate 1.0 Cinnamyl cinnamate 5.0 Diethyl phthalate 8. O Galaxolide DEP20,O
Jasmine AB 7002 (book) 5.0 Linalyl cinnamate 2.0 Sandalone AC 80
2 (Car) 30.O Traseolide (
*) too. o The odor type of this composition is mild sweet, floral and musky. Another example of the fragrance composition of the present invention was prepared as follows. °C 18.0 Benzyl salicylate 2.0 Diethyl phthalate 5.0 Ethylene brachylate 10. O Galaxolide DEP20.0
Lily of the valley AB 7001 (book) 2. 0
Phenylethyl salicylate 2.0 Sandal
one AC 802(*)3.0 Sandel
a (Givaudan) 38. O Traseol
ide (*) 100.0 The odor type of this preparation is mild lily of the valley and musk. Another example of a composition of the invention was prepared as follows.

Ri Ei 5.0 Benzyl alcohol 8.0 Benzyl benzoate 5.0 Benzyl cinnamate 5.0 Carnation AB 7005 (*) 2.
0 Copaiba Balsam 10. O Galaxo! ide DEP15
．． 0 Hexyl salicylate 15.0 Jasmine base AB 7002 (*)
35. O Traseolide (*) 100.0 The odor type of this formulation is mild spicy jasmine and musk.

Strong difference” Hajime Nyobishiki The odor intensity index of the above example is shown below.

! ! lJ! Li Etanakami Konodashi Example 1
87 Example 285 Example 372 Example 479 Example 575 For comparison and calibration purposes, a standard preparation of benzyl acetate has the following odor intensity index.

L Omote Togoku 1% Benzyl acetate 545% Benzyl acetate
8910% Benzyl acetate 10220
%Benzyl acetate 10850% Benzyl acetate 120100% Benzyl acetate
132 (A standard sample of benzyl acetate is prepared as a dilute solution in dipropylene glycol.) This invention is susceptible to many variations that will occur to those skilled in the art, and all of the features described herein and in the cited references are susceptible to many variations. Covers combinations and subcombinations.

Claims (22)

[Claims] (1) Odor intensity index of less than 110 and at least 0.2
A composition of aromatic material having a malodor reduction value of 5 or an odor reduction value of at least 0.25. (2) an odor intensity index of less than 110 and at least 0.2;
powder detergents, liquid detergents, of compositions of aromatic materials having a malodor reduction value of 5 or an odor reduction value of at least 0.25;
Use as a fragrance composition in soap or detergent bars or pastes, liquid or solid textile conditioning compositions, or body odor control compositions. (3) A detergent composition for cleaning textile products containing a detergent surfactant and a detergent additive containing a fragrance composition, wherein the fragrance component content in the fragrance composition is (a) a detergent as an optional ingredient; at least about 0.03% musk by weight of the composition;
(b) at least about 0.07% by weight of other fragrance ingredients, wherein aromatic ingredients (a) (if present) and (b) collectively have an Odor Intensity Index of at least less than 110; A detergent composition characterized in that the aggregates of aromatic components in the composition collectively pass a malodor reduction test with a value of at least 0.25 or an odor reduction test with a value of at least 0.25. (4) A composition according to claim 1 or 3, characterized in that the aromatic materials or perfume components collectively have an odor intensity index of less than 105. (5) A composition according to claim 1 or 3, characterized in that the aromatic materials or perfume components collectively have an odor intensity index of less than 100. (6) Claim 3, characterized in that the aromaticity of the fragrance component in the detergent composition is so low that it is substantially unnoticeable during use.
The composition described in . (7) Fragrance compositions (considered as components other than those that individually constitute less than 0.5% of the composition) fall into the following six categories:
Namely, category 1 - phenolic substances, category 2 - essential oils, extracts,
Contains at least five different components of resins and synthetic oils, Category 3 - Aldehydes and ketones, Category 4 - Nitrogen-containing compounds and polycyclic compounds, Category 5 - Esters, Category 6 - Alcohols and ethers. of which at least four classes are represented in the composition (provided that if an individual ingredient can fall into more than one of these classes, the ingredient shall be assigned to the lowest numbered class). ) The composition according to claim 3, characterized in that: (8) Fragrance component or aromatic material is α-isomethylionone, Siamese benzoinous resinoid, bergamot AB430
; Isoamyl salicylate, carvacrol, clove leaf oil, ethyl salicylate, isoeugenol, hexyl salicylate, red thyme oil; Bergamot AB430,
Geranium AB76, Rose AB380, Rose AB4
09; 7-acetyl-1,1,3,4,4,6-hexamethyltetrahydronaphthalene, pt-amylcyclohexanone, 2-n-heptylcyclopentanone, α-
Isomethyl ionone, β-methyl naphthyl ketone; isobutylquinoline, methyl anthranilate; o-t-butylcyclohexyl acetate, diethyl phthalate,
Nonanediol-1,3-diacetate, nonanolide
1,4, i-nonyl acetate, i-nonylformate, phenylethyl phenyl acetate; cinnamyl alcohol, dimyl setol, 1,3,4,6,7,8-hexahydro-4,6,6,7,8, 8-Hexamethylcyclopenta-γ-2-benzopyran (Calaxoli
de), hydroxymethylisopropylcyclopentane, 3a-methyldodecahydro-6,6,9a-trimethyl-naphtho-2(2,1-b)-furan, and tetrahydromguol. The composition according to any one of claims 1 or 3 to 7. (9) The following (bleach-labile) ingredients with trace amounts of fragrance or aromatic materials: Siamese benzoic resinoid, benzyl salicylate, bergamot AB37, pt-butyl cyclohexyl acetate, pt-butyl alpha- Methylhydrocinnamylaldehyde (Lilyal), coumarin, ethyl vanillin, geranium oil Bourbon, resorcylic acid ester LRG201, Mouss
e de chene) Yugo, β-naphthyl methyl ether, opopanax resinoid, patchouli oil,
8. A composition according to any one of claims 1 or 3 to 7, characterized in that it comprises petitgrain oil, phenylethyl alcohol, pimento leaf oil, pomeranzole AB314. (10) The fragrance ingredient or aromatic material is bergamot base AB, hexyl salicylate, rose base AB380
, diethyl phthalate, nonanediol 1,3-diacetate, isononyl acetate, cinnamyl alcohol, sham benzoic resinoid, benzyl salicylate, p
-t-butyl α-methylhydrocinnamylaldehyde (
8. Composition according to any one of claims 1 or 3 to 7, characterized in that it comprises a component selected from Lyreal), Opopanax resinoid. (11) Fragrance ingredients or aromatic materials include cedarwood oil (produced in Virginia), cinnamyl alcohol, diethyl phthalate, Galaxolide, geranyl phenylacetate, guaiac wood oil (rectified), linalyl benzoate, moss base AB7004, phenylethyl phenylacetate, rose base Composition according to any one of claims 1 or 3 to 7, characterized in that it comprises a component selected from AB7003. (12) The fragrance ingredient or aromatic material is benzyl alcohol, benzyl salicylate, cedarwood oil (produced in Virginia), Galaxolide, diethyl phthalate,
Grisalva, Hercolyn D, Isobutyl Benzoate, Isobutyl Cinnamate, Linalyl Cinnamate, Moss Base AB7004, Lily of the Valley Base A
B7001, 7-acetyl-1,1,3,4,4,6-
Hexamethyltetrahydronaphthalene (Tonalid)
), Traseolide. (13) The fragrance ingredient or aromatic material is benzyl alcohol, benzyl cinnamate, benzyl salicylate, cinnamyl cinnamate, diethyl phthalate, Galax
olide, diethyl phthalate, jasmine base A
B7002, linalyl cinnamate, Sandalon
Composition according to any one of claims 1 or 3 to 7, characterized in that it comprises a component selected from eAC802, Traseolide. (14) The fragrance component or aromatic material is benzyl salicylate, diethyl phthalate, ethylene brasileate, Ga
laxolide, lily of the valley base AB7001, phenylethyl salicylate, Sandalone AC80
2. Sandela (Givaudan), Trase
8. A composition according to any one of claims 1 or 3 to 7, characterized in that it contains a component selected from olides. (15) The fragrance ingredient or aromatic material is benzyl alcohol, benzyl benzoate, benzyl cinnamate, carnation base AB7005, copaiba balsam, G
alaxolide, diethyl phthalate, hexyl salicylate, jasmine base AB7002, Tras
Composition according to any one of claims 1 or 3 to 7, characterized in that it comprises a component selected from eolides. (16) According to any one of claims 1 and 3 to 7, characterized in that the majority of the fragrance ingredients or aromatic materials are composed of components selected from the components listed in claims 8 to 15. Composition of. (17) The fragrance ingredient or aromatic material is mainly from claims 8 to 1.
8. A composition according to any one of claims 1 or 3 to 7, characterized in that it is composed of ingredients selected from those listed in item 5. (18) Any one of claims 1 or 3 to 7, characterized in that the majority of the perfume ingredients or aromatic materials are composed of ingredients selected from the ingredients listed in claims 8 and 10 to 15. The composition described in . (19) Claims 8 and 1 mainly consist of fragrance ingredients or aromatic materials.
8. A composition according to any one of claims 1 or 3 to 7, characterized in that it is composed of ingredients selected from those listed in 0 to 15. (20) Most of the fragrance ingredients or aromatic materials are as claimed in claim 10.
8. The composition according to any one of claims 1 and 3 to 7, characterized in that it is composed of ingredients selected from the ingredients listed in 15. (21) The perfume component or aromatic material according to any one of claims 1 or 3 to 7, characterized in that the perfume component or aromatic material is mainly composed of components selected from the components listed in claims 10 to 15. Composition. (22) The composition according to any one of 1 or 3 to 7, characterized in that the perfume ingredient or fragrant material is substantially bleach-stable.